WO2006073065A1 - 非燃焼型喫煙物品用炭素質熱源組成物 - Google Patents
非燃焼型喫煙物品用炭素質熱源組成物 Download PDFInfo
- Publication number
- WO2006073065A1 WO2006073065A1 PCT/JP2005/023592 JP2005023592W WO2006073065A1 WO 2006073065 A1 WO2006073065 A1 WO 2006073065A1 JP 2005023592 W JP2005023592 W JP 2005023592W WO 2006073065 A1 WO2006073065 A1 WO 2006073065A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat source
- carbonaceous heat
- calcium carbonate
- amount
- combustion
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
- A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/22—Cigarettes with integrated combustible heat sources, e.g. with carbonaceous heat sources
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F42/00—Simulated smoking devices other than electrically operated; Component parts thereof; Manufacture or testing thereof
- A24F42/10—Devices with chemical heating means
Definitions
- Carbonaceous heat source composition for non-combustible smoking articles is Carbonaceous heat source composition for non-combustible smoking articles
- the present invention relates to a carbonaceous heat source composition for non-combustion smoking articles.
- Tobacco smoke (aerosol through human taste 'olfaction by burning tobacco leaves)
- non-combustion-type smoking articles have been developed to enjoy tobacco flavor and aerosols without burning tobacco leaves instead of or in addition to tobacco.
- These non-combustion-type smoking articles include a heat source that is a heat generating member attached to the tip and a flavor generating material in which a flavor component is held on a suitable base material, and an aerosol that includes the heat source and the flavor component. It is physically separated from the savory flavor generating material.
- a heat source is burned and heated without burning the flavor generating material to generate an aerosol containing a flavor component, and the smoker inhales the aerosol. Taste the savory taste.
- JP-A-2-215373 discloses a heat source body containing metal carbide, carbon, and a binder.
- the combustion rate of the heat source is improved and the amount of carbon monoxide is reduced by controlling the particle size and specific surface area of the metal carbide.
- Japanese Patent Application Laid-Open No. 2-21 5373 discloses a heat source body containing a metal nitride, carbon, and a binder.
- the metal nitride generates a metal oxide by combustion, and this metal oxide promotes the conversion of carbon monoxide to carbon dioxide, thereby reducing the amount of carbon monoxide.
- U.S. Pat. No. 5595577 discloses a carbonaceous heat source containing metal oxides. In this heat source, the metal acid deposited on the heat source The amount of carbon monoxide is reduced by the compound.
- US Patent Publication US 2004/017322 9 A1 discloses a combustion material comprising an ultrafine metal catalyst. In this combustion material, the amount of carbon monoxide is reduced by the metal catalyst changing carbon monoxide to carbon dioxide.
- Japanese Patent Application Laid-Open No. 10-179112 discloses a heat source composition containing carbon, a binder, non-combustible graphite, and potassium. In this heat source composition, the amount of carbon monoxide is reduced by adjusting the amount of potassium.
- the present invention can further reduce the amount of carbon monoxide generated by combustion of a heat source without using a reliability problem due to the use of an additive such as an oxidation catalyst for carbon monoxide. It is an object of the present invention to provide a heat source composition for non-combustion smoking articles that does not cause a change in flavor due to the laceon.
- the present invention provides a carbonaceous heat source composition for non-combustion smoking articles, containing calcium carbonate in a proportion of 30 to 55% by weight.
- FIG. 1 is a cross-sectional view showing an example of a non-combustion smoking article.
- FIG. 2 is a temperature history graph inside a carbonaceous heat source during smoking combustion.
- the carbonaceous heat source composition for non-combustion smoking articles of the present invention contains 30 to 55% by weight of calcium carbonate (particles). If the amount of calcium carbonate is less than 30% by weight, the amount of carbon monoxide produced will not be reduced effectively. On the other hand, if the amount of calcium carbonate exceeds 55% by weight, the number of puffs of smoking articles is remarkably reduced, which is not suitable for practical use.
- the carbonaceous heat source composition of the present invention includes, in addition to calcium carbonate and carbon, carbon A binder for binding calcium acid and carbon is included.
- the amount of the binder is preferably 5 to 15% by weight. When the amount of the binder is less than 5% by weight, the binding force by the binder tends not to be fully exhibited. Also, if the amount of the binder exceeds 15% by weight, the amount of carbon decreases, and as a result, the heat source tends not to be burned sufficiently.
- alginic acid salt carboxymethylcellulose or a salt thereof, pectin or a salt thereof, carrageenan or a salt thereof, guar gum and the like can be used.
- the carbonaceous heat source composition of the present invention contains 30 to 55% by weight of calcium carbonate, and the balance is carbon, including the case of further containing a binder. Any known carbon with no particular restrictions on the origin of the carbon (particles) used can be used.
- the carbonaceous heat source composition of the present invention can reduce the amount of carbon monoxide produced by combustion of the heat source to 60% or less as compared with a general smoking article using a carbonaceous heat source.
- the combustion temperature of the carbonaceous heat source composition of the present invention is relatively low. Is considered to be a cause. That is, the combustion temperature of the carbonaceous heat source composition of the present invention is 1000 ° C or lower. In general, it is known that the higher the combustion temperature, the higher the amount of carbon monoxide produced, and the carbonaceous heat source of the present invention has a maximum temperature of 100 ° C or less, resulting in carbon monoxide It is thought that the amount can be greatly reduced.
- calcium carbonate is preferably used in an amount of 0.08 to 0.0.
- the amount of carbon monoxide produced during smoking combustion can be further reduced compared to when calcium carbonate with a particle size of more than 18 ⁇ m is used.
- the proportion of calcium carbonate in the carbonaceous heat source composition is the same, by using calcium carbonate having a particle size in the range of 0.08 to 0.15 zm, calcium carbonate having a particle size exceeding 18 xm can be obtained.
- the amount of carbon monoxide produced can be reduced to an amount equivalent to 50% to 80% of the amount of carbon monoxide produced.
- the carbonaceous heat source composition of the present invention can be shaped as a heat source by a molding means such as extrusion molding.
- the heat source obtained from the carbonaceous heat source composition of the present invention is used as a heat source for various non-combustible smoking articles in which the heat source and the aerosol generating material are physically separated.
- the non-combustion smoking article 10 shown in FIG. 1 has an aerosol generation section 11 that is heated to generate an aerosol containing a flavor component.
- the aerosol section 11 includes a first aerosol generation part 111 and a second aerosol generation part 112.
- the first aerosol generating part 111 is a cylinder formed of a thermally stable material such as an anorium or stainless steel, and is filled with, for example, a sheet tobacco and a tobacco cut
- the second aerosol generating part 112 is A similar cylinder is filled with, for example, tobacco cuts.
- the first aerosol generating portion 111 and the second aerosol generating portion 112 are positioned in the longitudinal direction of the smoking article 10 in contact with each other.
- a carbonaceous heat source 12 made of the composition of the present invention is provided so as to be physically separated from the aerosol generation section 11. ing.
- the heat source 12 is provided with a through-hole 121 for taking in external air in the axial direction.
- the outer periphery of the heat source 12 is usually surrounded by a heat-resistant member 13 made of glass wool, for example.
- a normal filter 14 can be attached to the rear end of the aerosol generation section 11 (the rear end of the second aerosol generation section 112).
- Such a non-combustible smoking article 10 may have a normal cigarette appearance.
- a carbonaceous heat source was molded from a composition containing calcium carbonate (12 to 55% by weight), binder (10% by weight), and carbon (remainder: 78 to 35% by weight).
- a smoking article with the structure shown in Fig. 1 was prepared, and under standard smoking conditions (TI ⁇ J Standard measurement method “4th edition” Appendix 1) Smoking and burning with an automatic smoking machine, and TPM (total particulate matter) and carbon monoxide production at that time were measured. The results are also shown in Table 1.
- smoking articles made using a carbonaceous heat source containing 30% by weight or more of calcium carbonate are smoking articles made using a carbonaceous heat source containing less than 30% by weight of calcium carbonate. As compared with the above, it is possible to greatly reduce the amount of carbon monoxide produced. In addition, smoking articles made using a carbonaceous heat source containing 30% by weight or more of calcium carbonate compared to smoking articles made using a carbonaceous heat source containing less than 30% by weight of calcium carbonate. There is a tendency to decrease.
- FIG. 2 shows a temperature history inside the carbon heat source during the smoking combustion.
- curve a is the result for Comparative Example 1
- curve b is the result for Example 1
- curve c is the result for Example 2
- curve d is the result for Example 3.
- the temperature histories of each are shifted so that they can be easily divided.
- the steep peak in each curve in Fig. 2 represents a puff.
- the temperature near the 3-5 puff where the combustion temperature is highest is a carbonaceous heat source containing 30% by weight or more of calcium carbonate. If it is, it will be 1000 ° C or less. From the data shown in Table 1, it is clear that the carbon monoxide production is greatly reduced when the combustion temperature is 1000 ° C or lower.
- the component ratio of the carbonaceous heat source composition was fixed at 40% by weight of calcium carbonate, 10% by weight of binder, and 50% by weight of carbon, and the heat source was changed by changing the particle size of calcium carbonate as shown in Table 2 below.
- Produced Using the obtained carbonaceous heat source, a smoking article with the structure shown in Fig. 1 was prepared, and smoked and burned with an automatic smoking machine under the standard smoking conditions (TIOJ standard measurement method ⁇ 4th edition '' appendix 1). The amount of carbon monoxide produced was measured. The results are shown in Table 2.
- the particle size is 0.
- the amount of carbon monoxide produced when a smoking article made using a carbonaceous heat source containing calcium carbonate in the range of 15 to 0.08 / m is burnt and smoked is reduced to 70 to 57.5%.
- the amount of calcium carbonate is 30 to 55 weight 0 /. It is a simple structure to set within the range of As a result, the reliability of smoking products caused by the use of additives such as carbon monoxide oxidation catalyst, or the significant changes in product design, such as filter ventilation, have resulted in product flavor characteristics. Thus, it is possible to provide a carbonaceous heat source composition capable of reducing the amount of carbon monoxide produced while avoiding the problem of changing the temperature.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Paper (AREA)
- Carbon And Carbon Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Resistance Heating (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002594274A CA2594274C (en) | 2005-01-06 | 2005-12-22 | Carbonaceous heat source composition for non-combustion-type smoking article |
JP2006550723A JP4759523B2 (ja) | 2005-01-06 | 2005-12-22 | 非燃焼型喫煙物品用炭素質熱源組成物 |
ES05819460.6T ES2545532T3 (es) | 2005-01-06 | 2005-12-22 | Composición de fuente de calor carbonácea para un artículo para fumar de tipo no combustible |
CN200580046024XA CN101098635B (zh) | 2005-01-06 | 2005-12-22 | 非燃烧型吸烟物品用碳质热源组合物 |
EP05819460.6A EP1847189B1 (en) | 2005-01-06 | 2005-12-22 | Carbonaceous heat source composition for non-combustion smoking article |
US11/819,292 US7775216B2 (en) | 2005-01-06 | 2007-06-26 | Carbonaceous heat source composition for non-combustion-type smoking article |
HK08101395.1A HK1107747A1 (en) | 2005-01-06 | 2008-02-05 | Carbonaceous heat source composition for non-combustion smoking article |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005-001598 | 2005-01-06 | ||
JP2005001598 | 2005-01-06 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/819,292 Continuation US7775216B2 (en) | 2005-01-06 | 2007-06-26 | Carbonaceous heat source composition for non-combustion-type smoking article |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006073065A1 true WO2006073065A1 (ja) | 2006-07-13 |
Family
ID=36647547
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/023592 WO2006073065A1 (ja) | 2005-01-06 | 2005-12-22 | 非燃焼型喫煙物品用炭素質熱源組成物 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7775216B2 (ja) |
EP (1) | EP1847189B1 (ja) |
JP (1) | JP4759523B2 (ja) |
KR (2) | KR20080072967A (ja) |
CN (1) | CN101098635B (ja) |
CA (1) | CA2594274C (ja) |
ES (1) | ES2545532T3 (ja) |
HK (1) | HK1107747A1 (ja) |
RU (1) | RU2357623C2 (ja) |
UA (1) | UA89803C2 (ja) |
WO (1) | WO2006073065A1 (ja) |
Cited By (21)
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WO2007119678A1 (ja) * | 2006-04-11 | 2007-10-25 | Japan Tobacco Inc. | 非燃焼型喫煙物品用炭素質熱源組成物及び非燃焼型喫煙物品 |
WO2011118043A1 (ja) * | 2010-03-26 | 2011-09-29 | 日本たばこ産業株式会社 | 非燃焼型喫煙物品の燃料要素およびその製造方法 |
US20120080042A1 (en) * | 2009-06-18 | 2012-04-05 | Manabu Nishimura | Non-combustion smoking article having carbonaceous heat source |
WO2014016961A1 (ja) * | 2012-07-27 | 2014-01-30 | 日本たばこ産業株式会社 | 喫煙物品 |
WO2018100688A1 (ja) | 2016-11-30 | 2018-06-07 | 日本たばこ産業株式会社 | 喫煙物品用香料含有シートおよびそれを含む喫煙物品 |
WO2018139068A1 (ja) | 2017-01-30 | 2018-08-02 | 日本たばこ産業株式会社 | たばこ原料の製造方法及びたばこ原料 |
WO2018235761A1 (ja) | 2017-06-19 | 2018-12-27 | 日本たばこ産業株式会社 | 喫煙物品用フィルタおよびその製造方法 |
WO2019026201A1 (ja) | 2017-08-02 | 2019-02-07 | 日本たばこ産業株式会社 | たばこ香味液の製造方法およびたばこ香味液 |
WO2019097641A1 (ja) | 2017-11-16 | 2019-05-23 | 日本たばこ産業株式会社 | 香料担持たばこ充填材の製造方法、香料担持たばこ充填材、および加熱型香味吸引器 |
WO2020021599A1 (ja) | 2018-07-23 | 2020-01-30 | 日本たばこ産業株式会社 | たばこ材料の製造方法、たばこ材料、たばこ香味液の製造方法、たばこ香味液、および加熱型香味吸引器 |
WO2020153491A1 (ja) | 2019-01-25 | 2020-07-30 | 日本たばこ産業株式会社 | 喫煙物品用フィルター |
WO2020153490A1 (ja) | 2019-01-25 | 2020-07-30 | 日本たばこ産業株式会社 | 喫煙物品用フィルター |
WO2020202528A1 (ja) | 2019-04-04 | 2020-10-08 | 日本たばこ産業株式会社 | 香味吸引器用炭素熱源の製造方法、複合粒子、香味吸引器用炭素熱源、および香味吸引器 |
WO2020235007A1 (ja) | 2019-05-21 | 2020-11-26 | 日本たばこ産業株式会社 | 加熱型香味吸引器用香料含有シートおよび加熱型香味吸引器 |
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WO2022049703A1 (ja) | 2020-09-03 | 2022-03-10 | 日本たばこ産業株式会社 | たばこ充填材、非燃焼加熱型香味吸引器、およびたばこ充填材の製造方法 |
WO2022149220A1 (ja) | 2021-01-06 | 2022-07-14 | 日本たばこ産業株式会社 | たばこ香味液の製造方法、たばこ香味液、たばこ添加物、および香味吸引器 |
RU2783207C1 (ru) * | 2019-04-04 | 2022-11-10 | Джапан Тобакко Инк. | Способ изготовления угольного источника тепла для устройства для ингаляции ароматизатора, композитные частицы, угольный источник тепла для устройства для ингаляции ароматизатора и устройство для ингаляции ароматизатора |
WO2022249242A1 (ja) | 2021-05-24 | 2022-12-01 | 日本たばこ産業株式会社 | たばこ香味液の製造方法、たばこ香味液、および香味吸引器 |
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US12029234B2 (en) | 2016-02-18 | 2024-07-09 | Japan Tobacco Inc. | Non-combustion type inhalation article |
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FI121361B (fi) * | 2008-01-22 | 2010-10-29 | Stagemode Oy | Tupakkatuote ja menetelmä sen valmistamiseksi |
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DE102012104773A1 (de) * | 2012-06-01 | 2013-12-05 | Delfortgroup Ag | Zigarettenpapier mit plättchenförmigem Füllstoff |
MY171475A (en) | 2012-07-04 | 2019-10-15 | Philip Morris Products Sa | Combustible heat source with improved binding agent |
TWI674850B (zh) * | 2012-09-04 | 2019-10-21 | 瑞士商菲利浦莫里斯製品股份有限公司 | 吸煙製品 |
JP6469024B2 (ja) * | 2013-03-15 | 2019-02-13 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | エアロゾル修飾剤を含む気流を方向付ける要素を伴う喫煙物品 |
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MX2016011033A (es) | 2014-02-27 | 2016-11-29 | Philip Morris Products Sa | Fuente de calor combustible con una barrera fijada a esta y su metodo de fabricacion. |
US10314334B2 (en) * | 2015-12-10 | 2019-06-11 | R.J. Reynolds Tobacco Company | Smoking article |
CN105768208B (zh) * | 2016-03-18 | 2019-10-25 | 江苏金恒新型包装材料有限公司 | 一种加热非燃烧型烟草包装纸 |
CN107149167A (zh) * | 2017-04-28 | 2017-09-12 | 南京理工大学 | 卷烟用中低温含能热源及其制备方法 |
CN108041687B (zh) | 2017-12-22 | 2020-11-27 | 安徽中烟工业有限责任公司 | 具有低温燃烧热源的气雾产生物品 |
CN108451027B (zh) * | 2018-01-22 | 2023-05-26 | 云南中烟工业有限责任公司 | 一种复合炭质热源及其制备方法 |
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2005
- 2005-12-22 ES ES05819460.6T patent/ES2545532T3/es active Active
- 2005-12-22 UA UAA200707578A patent/UA89803C2/ru unknown
- 2005-12-22 CN CN200580046024XA patent/CN101098635B/zh not_active Expired - Fee Related
- 2005-12-22 EP EP05819460.6A patent/EP1847189B1/en not_active Not-in-force
- 2005-12-22 WO PCT/JP2005/023592 patent/WO2006073065A1/ja active Application Filing
- 2005-12-22 JP JP2006550723A patent/JP4759523B2/ja not_active Expired - Fee Related
- 2005-12-22 KR KR1020087017630A patent/KR20080072967A/ko not_active Application Discontinuation
- 2005-12-22 KR KR1020077013471A patent/KR100868590B1/ko active IP Right Grant
- 2005-12-22 RU RU2007125475/12A patent/RU2357623C2/ru active
- 2005-12-22 CA CA002594274A patent/CA2594274C/en active Active
-
2007
- 2007-06-26 US US11/819,292 patent/US7775216B2/en active Active
-
2008
- 2008-02-05 HK HK08101395.1A patent/HK1107747A1/xx not_active IP Right Cessation
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JP5227793B2 (ja) * | 2006-04-11 | 2013-07-03 | 日本たばこ産業株式会社 | 非燃焼型喫煙物品 |
US20120080042A1 (en) * | 2009-06-18 | 2012-04-05 | Manabu Nishimura | Non-combustion smoking article having carbonaceous heat source |
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Also Published As
Publication number | Publication date |
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UA89803C2 (ru) | 2010-03-10 |
EP1847189B1 (en) | 2015-07-29 |
RU2357623C2 (ru) | 2009-06-10 |
ES2545532T3 (es) | 2015-09-11 |
CN101098635A (zh) | 2008-01-02 |
US7775216B2 (en) | 2010-08-17 |
KR20070086212A (ko) | 2007-08-27 |
CN101098635B (zh) | 2010-12-15 |
HK1107747A1 (en) | 2008-04-18 |
KR100868590B1 (ko) | 2008-11-12 |
EP1847189A4 (en) | 2011-05-18 |
KR20080072967A (ko) | 2008-08-07 |
JP4759523B2 (ja) | 2011-08-31 |
RU2007125475A (ru) | 2009-01-10 |
CA2594274A1 (en) | 2006-07-13 |
CA2594274C (en) | 2009-12-15 |
JPWO2006073065A1 (ja) | 2008-06-12 |
US20070245623A1 (en) | 2007-10-25 |
EP1847189A1 (en) | 2007-10-24 |
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