WO2006062174A1 - Masking agent for livestock meat odor - Google Patents

Masking agent for livestock meat odor Download PDF

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Publication number
WO2006062174A1
WO2006062174A1 PCT/JP2005/022588 JP2005022588W WO2006062174A1 WO 2006062174 A1 WO2006062174 A1 WO 2006062174A1 JP 2005022588 W JP2005022588 W JP 2005022588W WO 2006062174 A1 WO2006062174 A1 WO 2006062174A1
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WO
WIPO (PCT)
Prior art keywords
masking agent
meat
odor
masking
weight
Prior art date
Application number
PCT/JP2005/022588
Other languages
French (fr)
Japanese (ja)
Inventor
Tatsuo Akai
Hajime Ohkawa
Ryoichi Harada
Original Assignee
San-Ei Gen F.F.I., Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by San-Ei Gen F.F.I., Inc. filed Critical San-Ei Gen F.F.I., Inc.
Priority to JP2006546760A priority Critical patent/JP4785750B2/en
Publication of WO2006062174A1 publication Critical patent/WO2006062174A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/428Addition of flavours, spices, colours, amino acids or their salts, peptides, vitamins, yeast extract or autolysate, nucleic acid or derivatives, organic acidifying agents or their salts or acidogens, sweeteners, e.g. sugars or sugar alcohols; Addition of alcohol-containing products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/10Natural spices, flavouring agents or condiments; Extracts thereof
    • A23L27/12Natural spices, flavouring agents or condiments; Extracts thereof from fruit, e.g. essential oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/84Flavour masking or reducing agents

Definitions

  • the present invention relates to a masking agent that effectively masks the odor of livestock meat.
  • the present invention also relates to a method for masking meat odor using the masking agent.
  • livestock meat is affected by its breeding environment, and the difference in meat quality due to the difference in feed can be a big problem for food processing.
  • the differences in meat quality, flavor, fat content, etc. are often clarified by processing.
  • livestock meat odor is a problem to be solved for food production, and various methods for improving livestock odor have been studied so far.
  • Patent Document 1 a method for reducing or removing odor by immersing meat in tea extract
  • Patent Document 2 5 'inosinic acid and 5' guaric acid are used as 5 'nucleotides. 1 to 5% per solid, 5% or more of ⁇ -glucan and mannan per solid, and peptide extract containing 20% or more of yeast per solid as an active ingredient
  • Patent Document 2 A method for reducing unpleasant odors such as seafood odors, animal meat odors and oily odors by adding animal odor improvers
  • Patent Document 4 A method for masking odors of foods by adding sake lees in the production of foods (patent document 4) and foods that are masked with odors peculiar to poultry and meat by adding sucralose
  • Patent Document 5 which contains livestock meat extract and powdered sake A seasoning that eliminates the animal's animal odor and improves the taste and flavor of the meat
  • Kneaded products that correct unpleasant odors such as livestock meat odor (Patent Document 7), extraction extras containing fats and oils, spices, and umami ingredients
  • Chicken meat odor mitigating agent (patent document 8) mixed with tart and beef fat with whipped cream or coconut butter, etc., and a method of removing meatiness by blending dartathion into the base of fish and meat paste products (patent) Reference 9), deodorizing and deodorizing agents that can be used for fish and meat masking agents, etc., containing L-ascorbic acid, benzoic acid, darconic acid, folic acid, nicotinic acid or Z and their salts as active ingredients (Patent Document 10), plum Meat extract, plum paste, plum vinegar, pickled plum, salted soup of ume, plum wine, and other flavor-improving flavor-improving agents (Patent Document 11), beef, horse meat, A method of deodorizing and improving the flavor of pork meat such as a low-quality portion of pork with a
  • Patent Document 1 JP 2003-310215 A
  • Patent Document 2 Japanese Patent Laid-Open No. 2003-284528
  • Patent Document 3 Japanese Patent Laid-Open No. 2002-191317
  • Patent Document 4 Japanese Patent Laid-Open No. 2000-157184
  • Patent Document 5 Japanese Patent Laid-Open No. 4-84867
  • Patent Document 6 Japanese Patent Laid-Open No. 4 53465
  • Patent Document 7 JP-A-2-268663
  • Patent Document 8 JP-A-1 171458
  • Patent Document 9 Japanese Patent Laid-Open No. 61-239867
  • Patent Document 10 Japanese Patent Laid-Open No. 60-136506
  • Patent Document 11 JP-A 55-48369
  • Patent Document 12 Japanese Patent Laid-Open No. 50-18658
  • livestock meat is easily affected by the breeding environment in terms of meat quality, flavor and fat content. Moreover, not only in meat, but also when it comes to the final processed food, the effects often surface. For this reason, livestock meat tends to be identified in connection with production areas such as Matsusaka beef and Kobe beef. In addition to the breeding environment, the effects of the difference in the feed that livestock directly take into the body are assumed to be non-negligible. For example, corn like corn It has been pointed out that the odor of the meat obtained is different between cattle that mainly feed on dairy and cattle that mainly feed on pasture.
  • the present inventors have also noticed that the meat obtained from cattle with grass as the main feed feels a blue-smelling glass odor more strongly than the meat obtained from cattle with cereal as the main feed, and such glasses. It was confirmed that by smelling meat with strong odor as food, the odor became even more pronounced. However, the technology for improving the blue-smelling glass odor of such livestock meat has been studied in the past.
  • the present invention has the following aspects.
  • a meat odor masking agent containing vanillin and a spice extract as active ingredients Item 1.
  • a meat odor masking agent according to item 1 containing a vanilla bean extract and a spice extract as active ingredients.
  • Item 3 The meat odor masking agent according to Item 1 or 2, wherein the spice is at least one selected from the group consisting of mace, garlic, thyme, cinnamon and peppermint.
  • Item 4 The content of vanillin is 0.04 to 0.15% by weight in 100% by weight of the masking agent, The animal meat odor masking agent according to Item 1 to 3.
  • the content of the spice extract is 0.2 to 15 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction.
  • Masking agent for livestock meat odor is 0.2 to 15 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction.
  • Item 6 Livestock meat according to Item 2, wherein the blended amount of the green beans extract is 2 to 20 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw vanilla beans before extraction. Odor masking agent.
  • Item 7 The meat odor according to Item 2, which is a compounding ratio power of the vanilla bean extract and the spice extract in terms of the dry weight of the raw material vanilla beans and the spices before extraction: 4: 3 to 10: 1 Trout King agent.
  • Item 8 The masking agent according to Items 1 to 7, wherein the livestock meat odor is a blue odor glass odor.
  • Item 9 A method for masking meat odor, comprising using the masking agent according to items 1 to 8.
  • Item 10 The method for masking meat odor according to Item 9, comprising any of the following steps:
  • Item 11 The method for masking a meat odor according to Item 9, wherein the masking agent is used as one of raw materials for foods using livestock meat.
  • Item 12 The method for masking meat odor according to claims 9 to 11, wherein the masking agent is used in a proportion of 0.05 to 0.5 parts by weight per 100 parts by weight of the meat.
  • the present invention it is possible to effectively mask the odor generated by livestock meat strength, particularly the blue odor glass odor.
  • the present invention provides a masking agent for improving livestock odor generated from livestock meat, particularly blue-smelling glass odor. Specifically, the present invention provides a masking agent for livestock meat odor containing vanillin and an extract from spices as active ingredients.
  • the vanillin contained as an active ingredient in the masking agent of the present invention may be a vanillin obtained by chemical synthesis, which may be a naturally derived vanillin obtained by extracting vanilla beans.
  • the vanillin of the present invention includes vanillin derivatives such as ethyl valine.
  • purified vanillin may be used, or an extract of vanilla bean curd or the like may be used.
  • vanilla beans used in obtaining an extract from vanilla beans are the same as Vanilla orch idaceae, a vine perennial plant belonging to the genus Vanilla, and the fruits (pods and beans) of related plants. It is a vanilla bean obtained by regular treatment (curing), and a commercially available one can be used.
  • extraction may be performed by immersing the pod and beans in a solvent as they are, or by extraction using pods and beans that have been shredded, crushed, pulverized, or the like. Good.
  • the extraction method from vanilla beans is not particularly limited as long as it is a method that can extract vanilla bean strength vanillin.
  • extraction is performed using a water-soluble solvent such as water, alcohol, or a mixture thereof. The method of doing can be mentioned.
  • the amount of the water-soluble solvent should be sufficient to soak the vanilla beans as the material to be extracted.
  • Examples of the alcohol used in the water-soluble solvent include a lower alcohol having 1 to 6 carbon atoms or a polyhydric alcohol.
  • Specific examples of the alcohol include lower alcohols such as methanol, ethanol, propanol and isopropanol, and polyhydric alcohols such as propylene glycol and glycerin, and ethanol is preferred. These may be used singly or in combination of two or more, and may be used in combination with water.
  • the concentration of the solvent is not particularly limited, but hydrous alcohol having an alcohol content of 15 to 20% by volume is preferable.
  • the masking agent of the present invention can also be prepared using a commercially available vanilla flavor.
  • vanilla flavor products manufactured by San-Ei Gen F.F.I. Co., Ltd. can be exemplified, and these can be used as a raw material for the masking agent of the present invention.
  • the vanilla flavor can be used regardless of whether it is derived from a natural product or a chemically synthesized product as long as it contains vanillin, or synthetic vanillin itself can be used.
  • the content of vanillin in the masking agent is from 0.04 to 0 to 100 parts by weight of the masking agent.
  • the masking effect becomes insufficient, and a feeling of spice is strongly felt. Further, when the content of vanillin is increased, the balance with the spices is deteriorated, and the vanilla aroma is strongly felt, so that a sufficient masking effect cannot be obtained.
  • the spices used in the present invention include plant seeds, fruits, rhizomes, flower buds, leaves, crusts, and the like.
  • spices specifically, cardamom, cloves, nutmeg, fenugreek, fenugreek, laurel, coriander, cumin, fennel, thyme, sage, pepper, chili, mustard, ginger, onion, garlic, turmeric, paprika, juniper Examples include berries, honore spice, cinnamon, mace, salamander, perilla, basil, spearmint, peppermint, heart force, lemongrass, and rosemary, and combinations of one or more of these.
  • a combination of at least one of mace, garlic, thyme, cinnamon and peppermint is preferred.
  • These spices may be subjected to the extraction process in the form in which these spices are usually used, and may be subjected to the extraction process after being dried, crushed, pulverized or the like, if necessary. Also good.
  • the method for extracting spice power is not particularly limited, and the same method as described above for obtaining an extract from vanilla beans can be used.
  • the amount of the spice extract in the masking agent is 0.2 to 15 parts by weight, preferably 0.4 to 10 parts per 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction. Part by weight can be exemplified.
  • the masking agent of the present invention can also be prepared using a commercially available spice extract.
  • a commercially available spice extract Specifically, the San-Like Spice Mitstus series manufactured by San-Ei Gen F.F.I. Co., Ltd. can be exemplified, and these can be appropriately mixed to be used as a raw material for the masking agent of the present invention.
  • the extract from vanilla beans and spices may be obtained by premixing the vanilla beans and spices and extracting the force, or after obtaining the extract separately from the vanilla beans and spices. It can be obtained by mixing the extracts.
  • a weight ratio of vanilla beans and spices to a water-soluble solvent is 1: 1-1: Mix in a ratio of 100, 20-95. C for 1-60 minutes, preferably 85-90. A method of extracting with C for 40 to 60 minutes can be mentioned.
  • the extract obtained from vanilla beans and spices is used as it is as a masking agent according to the present invention.
  • it may be diluted or concentrated as necessary, or lyophilized, or powdered by a known method such as spray drying after adding an appropriate base.
  • spray drying after adding an appropriate base.
  • it can be further dissolved in water and used as a liquid.
  • the masking agent of the present invention is obtained by extraction from vanilla beans and spices
  • the content of the extract of vanilla beans is converted to the dry weight of the raw material vanilla beans before extraction.
  • Examples are 2 to 20 parts by weight, preferably 4 to 15 parts by weight, based on parts by weight.
  • the amount of the masking agent of the present invention added to livestock meat or foods using livestock meat is 0.05.
  • Examples are 5 parts by weight, preferably 0.08-0.2 parts by weight.
  • the addition amount of the masking agent is small, the blue odor! /, The glass odor cannot be sufficiently masked, and if the addition amount is large, the flavor of vanillin or spice contained in the masking agent may affect the food. ⁇ which is preferable.
  • a method for adding the masking agent of the present invention to food for example, a method of spraying various kinds of meat or immersing various kinds of meat in the masking agent of the present invention, and using meat
  • a method of adding and mixing as one of the raw materials when manufacturing and processing the processed food is a method of adding and mixing as one of the raw materials when manufacturing and processing the processed food. Since the masking agent of the present invention does not require special equipment or production conditions when used, it can be easily used industrially.
  • Other food additives may be added to the masking agent of the present invention within a range not impairing the effects of the present invention.
  • food additives include amino acids such as sodium L-glutamate and sodium L-aspartate or salts thereof, nucleic acids such as 5'-inosinoic acid or salts thereof, organic acids such as monopotassium citrate or Seasonings such as salts thereof and inorganic salts such as potassium chloride; power-raising extract, rust extract, and kojic acid; shelf life improvers such as shirako protein extract, polylysine, and sorbic acid preservatives; alpha, j8-amylase, a, j8 Darukoshidaze, enzymes papain; Kuen acid, fumaric acid, P H adjusting agent and succinic acids; sucrose fatty acid esters, glycerin fatty acid esters, organic Emulsifiers such as acid monoglycerides and lecithins; fragrances; ⁇ -
  • Examples of foods that can mask the blue odor and glass odor of livestock meat using the masking agent of the present invention include, without limitation, foods using livestock meat.
  • foods using livestock meat are not limited to foods containing livestock meat itself, but include livestock extract obtained using livestock meat and foods containing livestock-derived ingredients. Specifically, cattle, pigs, chickens, goats, sheep, horses, deer, wild boars, rabbits, pheasants, duck and other livestock, preferably cattle bred using pasture as the main feed, and sheep meat Examples of foods that have been registered.
  • the types of food include steak, grilled meat, ham, sausage, grilled pork, tonkatsu, croquette, bacon, corned beef, hamburger, gyoza, shiyumai, nugget, meatball, pickled meat, dried meat, boiled meat, yakitori,
  • Examples include liver pate, meat pie, and soup based on livestock meat, and preferred are stick, grilled meat, and hamburger.
  • the masking method for livestock meat odor of the present invention is characterized by using the masking agent of the present invention.
  • Examples of the method for masking meat odor according to the present invention include spraying the masking agent of the present invention on various types of meat, or immersing various types of meat in the masking agent of the present invention, and injecting them into the inside of the meat (injection).
  • the masking agent of the present invention is added and mixed as one of the raw materials.
  • the method of combining and using is mentioned.
  • the method for masking meat odor according to the present invention does not require any special equipment or manufacturing conditions for use, and therefore can be easily carried out industrially.
  • the amount of the masking agent of the present invention added to the animal meat or the food using the meat in the method for masking the meat odor of the present invention depends on the degree of the meat odor emitted from the meat, especially the blue odor glass odor.
  • 0.05 to 0.5 parts by weight, preferably 0.08 to 0.2 parts by weight can be exemplified for 100 parts by weight of livestock meat used for food.
  • the masking agent raw materials (dried product) described in the following formulation examples and comparative examples 1 and 2 and make 15 parts of 95% ethanol aqueous solution and 100 parts of water in total, and perform reflux extraction at 90 ° C for 2 hours.
  • the extract was cooled to room temperature, solids were removed with a 200 mesh wire net, and left in a refrigerator for 24 hours.
  • the masking agent which concerns on this invention was obtained by filtering the filter aid (The product made from a JOHNS MANVILLE, the muffler mouth) into the supernatant part of this extract using the cake Nol8 filter paper.
  • the spices were broken down to 3 parts of garlic, 40 parts of black pepper, 100% of all spices 25 ⁇ ⁇ coriander 1 mace 7 ⁇ ⁇ cinnamon 2 ⁇ ⁇ time 2 ⁇ and lorenore 2 ⁇ .
  • Beef hamburger was obtained by steaming to reach ° C.
  • Trehalose (Trehach made by Hayashibara) part 5735321 Seasoning (Sunlike * beef flavor 4309 P *)
  • the degree of masking of the meat odor varied depending on the mixing ratio of vanilla beans and spices contained in the masking agent.
  • the generation of the glass odor could be suppressed particularly effectively.
  • the masking agents obtained in the examples were used for A and C beef, generation of livestock odor could be effectively suppressed.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
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  • Proteomics, Peptides & Aminoacids (AREA)
  • Meat, Egg Or Seafood Products (AREA)
  • General Preparation And Processing Of Foods (AREA)

Abstract

It is intended to provide a masking agent for the livestock meat odor which comprises an extract from vanillin and a spice as the active ingredient; and a method of masking the livestock meat odor by using this masking agent.

Description

畜肉臭のマスキング剤  Meat odor masking agent
技術分野  Technical field
[0001] 本発明は畜肉が有する臭気を効果的にマスキングするマスキング剤に関する。また 本発明は、該マスキング剤を用いた畜肉臭のマスキング方法に関する。  [0001] The present invention relates to a masking agent that effectively masks the odor of livestock meat. The present invention also relates to a method for masking meat odor using the masking agent.
背景技術  Background art
[0002] 近年、 BSE問題や鳥インフルエンザ等畜肉に関する様々な問題が生じている。そ のため汚染地域や汚染のおそれのある畜肉が使用できなくなるなど、食品製造にと つて大きな問題が生じている。このような状況に食品製造業界では、代替となる畜肉 原料を入手するため、汚染のない地域や原料の確保が急務とされている。  [0002] In recent years, various problems related to livestock meat such as the BSE problem and avian influenza have occurred. As a result, there are major problems in food production, such as the use of contaminated areas and potentially contaminated livestock meat. Under such circumstances, the food manufacturing industry is urgently required to secure a clean area and raw materials in order to obtain alternative livestock raw materials.
[0003] し力しながら畜肉は、その飼育環境に影響を受けやすぐ特に飼料の差による肉質 の差は、食品加工にとって大きな問題となることがある。肉質、風味、脂肪含量など、 加工することによりその差がより明確になることが少なくない。特に畜肉臭は、食品製 造にとって解決すべき課題であり、現在に至るまでに様々な畜肉臭の改善方法が検 討されている。  [0003] However, livestock meat is affected by its breeding environment, and the difference in meat quality due to the difference in feed can be a big problem for food processing. The differences in meat quality, flavor, fat content, etc. are often clarified by processing. In particular, livestock meat odor is a problem to be solved for food production, and various methods for improving livestock odor have been studied so far.
[0004] 具体的には、茶抽出液に食肉を浸すことにより臭みを低減ないし除去する方法 (特 許文献 1)、 5' ヌクレオチド類として、 5' イノシン酸、 5' グァ-ル酸を対固形分 当たり各々 1〜5%、 β—グルカン及びマンナンを対固形分当たり 5%以上含有し、 かつペプチド含量が対固形分当たり 20%以上である酵母エキスを有効成分とする畜 肉食品の肉食獣臭改善剤 (特許文献 2)、キノコ類抽出物を食品に対して特定の割 合で添加することにより、魚介類臭や畜肉臭や油臭等の不快臭を軽減する方法 (特 許文献 3)、スクラロースを含有させることにより、鳥獣肉特有の臭みを有意にマスキン グした食品 (特許文献 4)、食品類の製造に際し、酒粕を含有させることにより食品類 の臭いのマスキングを行う方法 (特許文献 5)、畜肉エキスと粉末酒を含有してなる、 肉の獣臭さが消され、肉の味、風味を向上させる調味料 (特許文献 6)、醤油を油脂 に加えて乳化し、油中水型乳化工マルジヨンとし、これを添加して畜肉臭等の不快臭 を矯正した練り製品 (特許文献 7)、油脂類、香辛料、旨味成分を含む抽出エキストラ タト及び牛脂肪にホイップクリームまたはココナッツバター等を混和した鶏肉臭緩和 剤(特許文献 8)、魚肉、肉類練製品のベースにダルタチオンを配合し加工することに より肉類のくさみをとる方法 (特許文献 9)、 Lーァスコルビン酸、安息香酸、ダルコン 酸、葉酸、ニコチン酸または Z及びこれらの塩を有効成分とする、魚畜肉マスキング 剤等に使用できる脱臭,消臭剤 (特許文献 10)、梅肉エキス、梅肉ペースト、梅酢、梅 干、青梅の塩漬汁及び梅酒などの 1種を有効成分とする肉類の臭味を消す効果の 著しい風味改良剤 (特許文献 11)、牛肉、馬肉、豚肉の低肉質部等の肉類を麹菌、 紅麹菌由来壌素群によって脱臭、風味改善を行う方法 (特許文献 12)等が開示され ている。 [0004] Specifically, a method for reducing or removing odor by immersing meat in tea extract (Patent Document 1), 5 'inosinic acid and 5' guaric acid are used as 5 'nucleotides. 1 to 5% per solid, 5% or more of β-glucan and mannan per solid, and peptide extract containing 20% or more of yeast per solid as an active ingredient A method for reducing unpleasant odors such as seafood odors, animal meat odors and oily odors by adding animal odor improvers (Patent Document 2) and mushroom extracts at a specific ratio to food (patent literature) 3) A method for masking odors of foods by adding sake lees in the production of foods (patent document 4) and foods that are masked with odors peculiar to poultry and meat by adding sucralose ( Patent Document 5), which contains livestock meat extract and powdered sake A seasoning that eliminates the animal's animal odor and improves the taste and flavor of the meat (Patent Document 6), soy sauce is added to the fats and oils to emulsify, and a water-in-oil emulsifier is added. Kneaded products that correct unpleasant odors such as livestock meat odor (Patent Document 7), extraction extras containing fats and oils, spices, and umami ingredients Chicken meat odor mitigating agent (patent document 8) mixed with tart and beef fat with whipped cream or coconut butter, etc., and a method of removing meatiness by blending dartathion into the base of fish and meat paste products (patent) Reference 9), deodorizing and deodorizing agents that can be used for fish and meat masking agents, etc., containing L-ascorbic acid, benzoic acid, darconic acid, folic acid, nicotinic acid or Z and their salts as active ingredients (Patent Document 10), plum Meat extract, plum paste, plum vinegar, pickled plum, salted soup of ume, plum wine, and other flavor-improving flavor-improving agents (Patent Document 11), beef, horse meat, A method of deodorizing and improving the flavor of pork meat such as a low-quality portion of pork with a koji mold or a koji mold derived from koji mold (patent document 12) is disclosed.
特許文献 1 :特開 2003— 310215号公報 Patent Document 1: JP 2003-310215 A
特許文献 2:特開 2003 - 284528号公報 Patent Document 2: Japanese Patent Laid-Open No. 2003-284528
特許文献 3:特開 2002— 191317号公報 Patent Document 3: Japanese Patent Laid-Open No. 2002-191317
特許文献 4:特開 2000— 157184号公報 Patent Document 4: Japanese Patent Laid-Open No. 2000-157184
特許文献 5 :特開平 4— 84867号公報 Patent Document 5: Japanese Patent Laid-Open No. 4-84867
特許文献 6:特開平 4 53465号公報 Patent Document 6: Japanese Patent Laid-Open No. 4 53465
特許文献 7:特開平 2— 268663号公報 Patent Document 7: JP-A-2-268663
特許文献 8:特開平 1 171458号公報 Patent Document 8: JP-A-1 171458
特許文献 9:特開昭 61— 239867号公報 Patent Document 9: Japanese Patent Laid-Open No. 61-239867
特許文献 10:特開昭 60— 136506号公報 Patent Document 10: Japanese Patent Laid-Open No. 60-136506
特許文献 11 :特開昭 55— 48369号公報 Patent Document 11: JP-A 55-48369
特許文献 12 :特開昭 50— 18658号公報 Patent Document 12: Japanese Patent Laid-Open No. 50-18658
発明の開示 Disclosure of the invention
発明が解決しょうとする課題 Problems to be solved by the invention
上述の通り畜肉は、肉質、風味、脂肪含量などについて、飼育環境の影響を受け やすい。また、精肉においてのみならず、最終的な加工食品となったときにその影響 が表面化することも少なくない。そのため、畜肉は、松阪牛、神戸牛というように産地 と結びつけて識別される傾向にある。飼育環境の他、家畜が直接体内に取り入れる 飼料の違いによる影響も、無視できないと推測される。例えば、トウモロコシのような穀 類を主な飼料とする牛と、牧草を主な飼料とする牛とでは、得られる肉の臭気が異な ることが指摘されている。本発明者らも、牧草を主たる飼料とする牛から得られる肉で は、穀類を主たる飼料とする牛から得られる肉よりも、青臭いグラス臭が強く感じられ ること、及び、その様なグラス臭の強い肉を食品としてカ卩ェすることにより、更にその 臭気が顕著になることを確認した。し力しながら、従来このような畜肉が有する青臭い グラス臭の改善を目的とする技術は検討されて 、な 、のが実情である。 As mentioned above, livestock meat is easily affected by the breeding environment in terms of meat quality, flavor and fat content. Moreover, not only in meat, but also when it comes to the final processed food, the effects often surface. For this reason, livestock meat tends to be identified in connection with production areas such as Matsusaka beef and Kobe beef. In addition to the breeding environment, the effects of the difference in the feed that livestock directly take into the body are assumed to be non-negligible. For example, corn like corn It has been pointed out that the odor of the meat obtained is different between cattle that mainly feed on dairy and cattle that mainly feed on pasture. The present inventors have also noticed that the meat obtained from cattle with grass as the main feed feels a blue-smelling glass odor more strongly than the meat obtained from cattle with cereal as the main feed, and such glasses. It was confirmed that by smelling meat with strong odor as food, the odor became even more pronounced. However, the technology for improving the blue-smelling glass odor of such livestock meat has been studied in the past.
課題を解決するための手段  Means for solving the problem
[0006] 本発明者らは、上記のような畜肉臭、特に青臭いグラス臭を改善するために鋭意検 討を重ねた結果、香辛料力 の抽出物とバニリンを有効成分とするマスキング剤を調 製し、これを添加することで畜肉臭、特に青臭いグラス臭を効果的にマスキングでき るとの知見を得、本発明を完成するに至った。  [0006] As a result of intensive investigations to improve the above-mentioned animal meat odor, particularly the blue odor glass odor, the present inventors have prepared a masking agent containing a spice power extract and vanillin as active ingredients. In addition, the inventors have obtained knowledge that the addition of this can effectively mask livestock meat odor, particularly blue odor glass odor, and the present invention has been completed.
[0007] 本発明は以下の態様を有する。  [0007] The present invention has the following aspects.
項 1.バニリン及び香辛料抽出物を有効成分として含有する、畜肉臭のマスキング剤 項 2.バニラ豆抽出物及び香辛料抽出物を有効成分として含有する、項 1に記載の 畜肉臭のマスキング剤。  Item 1. A meat odor masking agent containing vanillin and a spice extract as active ingredients Item 2. A meat odor masking agent according to item 1 containing a vanilla bean extract and a spice extract as active ingredients.
項 3.香辛料が、メース、ガーリック、タイム、シナモン及びペパーミントからなる群より 選ばれる 1種以上である、項 1または 2に記載の畜肉臭のマスキング剤。  Item 3. The meat odor masking agent according to Item 1 or 2, wherein the spice is at least one selected from the group consisting of mace, garlic, thyme, cinnamon and peppermint.
項 4.バニリンの含有量が、マスキング剤 100重量%中、 0. 04〜0. 15重量%である 項 1〜3に記載の畜肉臭のマスキング剤。  Item 4. The content of vanillin is 0.04 to 0.15% by weight in 100% by weight of the masking agent, The animal meat odor masking agent according to Item 1 to 3.
項 5.香辛料抽出物の含有量が、抽出前の原料香辛料の乾燥重量に換算して、マス キング剤 100重量部に対して 0. 2〜15重量部である、請求項 1〜4に記載の畜肉臭 のマスキング剤。  Item 5. The content of the spice extract is 0.2 to 15 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction. Masking agent for livestock meat odor.
項 6ノ -ラ豆抽出物の配合量が、抽出前の原料バニラ豆の乾燥重量に換算して、マ スキング剤 100重量部に対して 2〜20重量部である、項 2に記載の畜肉臭のマスキ ング剤。  Item 6. Livestock meat according to Item 2, wherein the blended amount of the green beans extract is 2 to 20 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw vanilla beans before extraction. Odor masking agent.
項 7.抽出前の原料バニラ豆及び原料香辛料の乾燥重量に換算して、バニラ豆抽出 物と香辛料抽出物との配合割合力 4 : 3〜10 : 1である、項 2に記載の畜肉臭のマス キング剤。 Item 7. The meat odor according to Item 2, which is a compounding ratio power of the vanilla bean extract and the spice extract in terms of the dry weight of the raw material vanilla beans and the spices before extraction: 4: 3 to 10: 1 Trout King agent.
項 8.畜肉臭が青臭いグラス臭である項 1〜7に記載のマスキング剤。  Item 8. The masking agent according to Items 1 to 7, wherein the livestock meat odor is a blue odor glass odor.
項 9.項 1〜8に記載のマスキング剤を使用することを特徴とする畜肉臭のマスキング 方法。  Item 9. A method for masking meat odor, comprising using the masking agent according to items 1 to 8.
項 10.下記の工程のいずれかを含む、項 9に記載の畜肉臭のマスキング方法: Item 10. The method for masking meat odor according to Item 9, comprising any of the following steps:
(1)マスキング剤を畜肉に噴霧する工程、 (1) A process of spraying a masking agent on livestock meat,
(2)マスキング剤に浸漬する工程、  (2) a step of immersing in a masking agent,
(3)マスキング剤を畜肉に注入する工程。  (3) A process of injecting a masking agent into meat.
項 11.マスキング剤を、畜肉を利用した食品の原料の 1つとして使用する、項 9に記 載の畜肉臭のマスキング方法。  Item 11. The method for masking a meat odor according to Item 9, wherein the masking agent is used as one of raw materials for foods using livestock meat.
項 12.マスキング剤を、畜肉 100重量部に対して 0. 05〜0. 5重量部の割合で用い ることを特徴とする、請求項 9〜11に記載の畜肉臭のマスキング方法。  Item 12. The method for masking meat odor according to claims 9 to 11, wherein the masking agent is used in a proportion of 0.05 to 0.5 parts by weight per 100 parts by weight of the meat.
発明の効果  The invention's effect
[0008] 本発明によれば、畜肉力 生じる臭気、特に青臭いグラス臭を効果的にマスキング することが可能となる。また、本発明によれば、家畜の飼育環境の違いによる風味の 差を生じな 、加工食品を製造することが可能となる。  [0008] According to the present invention, it is possible to effectively mask the odor generated by livestock meat strength, particularly the blue odor glass odor. In addition, according to the present invention, it is possible to produce processed foods without causing a difference in flavor due to differences in livestock breeding environments.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
[0009] (1)本発明の畜肉阜のマスキング剤 [0009] (1) The masking agent for livestock meat fu of the present invention
本発明は、畜肉から生じる畜肉臭、特に青臭いグラス臭を改善するためのマスキン グ剤を提供する。詳しくは、バニリンと、香辛料からの抽出物とを有効成分として含有 する畜肉臭のマスキング剤を提供する。  The present invention provides a masking agent for improving livestock odor generated from livestock meat, particularly blue-smelling glass odor. Specifically, the present invention provides a masking agent for livestock meat odor containing vanillin and an extract from spices as active ingredients.
[0010] 本発明のマスキング剤に有効成分として含有されるバニリンは、バニラ豆力 抽出 して得られる天然由来のバニリンでもよぐ化学合成により得られるバニリンであっても よい。また、本発明のバニリンには、ェチルバ-リン等のバニリン誘導体も含む。 [0010] The vanillin contained as an active ingredient in the masking agent of the present invention may be a vanillin obtained by chemical synthesis, which may be a naturally derived vanillin obtained by extracting vanilla beans. The vanillin of the present invention includes vanillin derivatives such as ethyl valine.
[0011] 本発明のマスキング剤のバニリン成分の原料としては、バニラ豆力ゝらの抽出物を用 いてもよぐ精製したバニリンを用いてもよい。 [0011] As a raw material for the vanillin component of the masking agent of the present invention, purified vanillin may be used, or an extract of vanilla bean curd or the like may be used.
[0012] バニラ豆からの抽出物を得る際に使用するバニラ豆は、ラン科バニラ属の蔓性多年 生の植物である Vanilla orch idaceaeおよびその類縁植物の果実(さや及び豆)を一 定の処理 (キュアリング)して得られるバニラビーンズであり、一般に市販されているも のを利用することができる。 [0012] Vanilla beans used in obtaining an extract from vanilla beans are the same as Vanilla orch idaceae, a vine perennial plant belonging to the genus Vanilla, and the fruits (pods and beans) of related plants. It is a vanilla bean obtained by regular treatment (curing), and a commercially available one can be used.
[0013] バニラ豆力 抽出物を得る際には、さや及び豆をそのまま溶媒に浸漬して抽出を行 つてもよく、細断、破砕、粉砕等したさや及び豆を用いて抽出を行ってもよい。  [0013] When obtaining an extract of vanilla bean, extraction may be performed by immersing the pod and beans in a solvent as they are, or by extraction using pods and beans that have been shredded, crushed, pulverized, or the like. Good.
[0014] バニラ豆からの抽出方法としては、バニラ豆力 バニリンを抽出することのできる方 法であれば特に制限されないが、例えば、水、アルコールまたはこれらの混合物等の 水溶性溶媒を用いて抽出する方法を挙げることができる。水溶性溶媒の量は、抽出 する素材であるバニラ豆が十分に浸る程度の量があればよい。  [0014] The extraction method from vanilla beans is not particularly limited as long as it is a method that can extract vanilla bean strength vanillin. For example, extraction is performed using a water-soluble solvent such as water, alcohol, or a mixture thereof. The method of doing can be mentioned. The amount of the water-soluble solvent should be sufficient to soak the vanilla beans as the material to be extracted.
[0015] 水溶性溶媒に用いられるアルコールとしては、例えば、炭素数 1〜6の低級アルコ ールまたは多価アルコールが挙げられる。アルコールとしてより具体的には、メタノー ル、エタノール、プロパノール及びイソプロパノール等の低級アルコール、またはプロ ピレンダリコール及びグリセリン等の多価アルコールが例示され、好ましくはエタノー ルである。これらは 1種単独で用いても、 2種以上を組み合わせて用いてもよぐさら に水と混合して用いてもよい。水溶性溶媒として含水アルコールを用いる場合、溶媒 の濃度は、特に制限されないが、アルコール含有量が 15〜20容量%である含水ァ ルコールが好ましい。  [0015] Examples of the alcohol used in the water-soluble solvent include a lower alcohol having 1 to 6 carbon atoms or a polyhydric alcohol. Specific examples of the alcohol include lower alcohols such as methanol, ethanol, propanol and isopropanol, and polyhydric alcohols such as propylene glycol and glycerin, and ethanol is preferred. These may be used singly or in combination of two or more, and may be used in combination with water. When hydrous alcohol is used as the water-soluble solvent, the concentration of the solvent is not particularly limited, but hydrous alcohol having an alcohol content of 15 to 20% by volume is preferable.
[0016] また、本発明のマスキング剤は、市販されているバニラ系フレーバーを利用して調 製することもできる。具体的には三栄源エフ ·エフ ·アイ株式会社製のバニラ系フレー バー製品を例示することができ、これらを本発明のマスキング剤の原料とする事もで きる。バニラ系フレーバーとしては、バニリンを含むものであれば、天然物由来のもの 、化学合成品に拘わらず使用でき、また、合成バニリンそのものを用いることもできる  [0016] The masking agent of the present invention can also be prepared using a commercially available vanilla flavor. Specifically, vanilla flavor products manufactured by San-Ei Gen F.F.I. Co., Ltd. can be exemplified, and these can be used as a raw material for the masking agent of the present invention. The vanilla flavor can be used regardless of whether it is derived from a natural product or a chemically synthesized product as long as it contains vanillin, or synthetic vanillin itself can be used.
[0017] マスキング剤中のバニリンの含有量は、マスキング剤 100重量部に対して 0. 04〜0[0017] The content of vanillin in the masking agent is from 0.04 to 0 to 100 parts by weight of the masking agent.
. 15重量部が例示できる。 15 parts by weight can be exemplified.
[0018] マスキング剤中のバニリンの含有量が少なくなるとマスキング効果が不十分となり、 スパイス感が強く感じられるようになる。また、バニリンの含有量が多くなると香辛料と のバランスが悪くなり、バニラ香が強く感じられるようになり充分なマスキング効果が得 られない。 [0019] 本発明で使用する香辛料としては、植物の種子、果実、根茎、花蕾、葉、榭皮等が 挙げられる。香辛料として、具体的には、カルダモン、クローブ、ナツメグ、フエヌグリ ーク、コロハ、ローレル、コリアンダー、クミン、フェンネル、タイム、セージ、コショウ、唐 辛子、マスタード、ショウガ、オニオン、ガーリック、ターメリック、パプリカ、ジュニパー ベリー、ォーノレスパイス、シナモン、メース、サンショウ、シソ、バジル、スペアミント、ぺ パーミント、ハツ力、レモングラス、及び、ローズマリー等が挙げられ、これらの 1種以 上を組み合わせたものも挙げられる。香辛料としては、メース、ガーリック、タイム、シ ナモン、ペパーミントの 1種以上を組み合わせたものが好まし 、。 [0018] When the content of vanillin in the masking agent is reduced, the masking effect becomes insufficient, and a feeling of spice is strongly felt. Further, when the content of vanillin is increased, the balance with the spices is deteriorated, and the vanilla aroma is strongly felt, so that a sufficient masking effect cannot be obtained. [0019] Examples of the spices used in the present invention include plant seeds, fruits, rhizomes, flower buds, leaves, crusts, and the like. As spices, specifically, cardamom, cloves, nutmeg, fenugreek, fenugreek, laurel, coriander, cumin, fennel, thyme, sage, pepper, chili, mustard, ginger, onion, garlic, turmeric, paprika, juniper Examples include berries, honore spice, cinnamon, mace, salamander, perilla, basil, spearmint, peppermint, heart force, lemongrass, and rosemary, and combinations of one or more of these. As a spice, a combination of at least one of mace, garlic, thyme, cinnamon and peppermint is preferred.
[0020] これらの香辛料は、これらの香辛料が通常使用される形態のまま抽出工程に供して もよぐまた、必要に応じて、乾燥、破砕、粉砕処理等を行った後に抽出工程に供し てもよい。  [0020] These spices may be subjected to the extraction process in the form in which these spices are usually used, and may be subjected to the extraction process after being dried, crushed, pulverized or the like, if necessary. Also good.
[0021] 香辛料力 の抽出方法としては、特に制限されないが、上記に記載の、バニラ豆か ら抽出物を得るのと同様の方法を用いることができる。  [0021] The method for extracting spice power is not particularly limited, and the same method as described above for obtaining an extract from vanilla beans can be used.
[0022] マスキング剤中の香辛料抽出物の量は、抽出前の原料香辛料の乾燥重量に換算 して、マスキング剤 100重量部に対して 0. 2〜15重量部、好ましくは 0. 4〜10重量 部が例示できる。 [0022] The amount of the spice extract in the masking agent is 0.2 to 15 parts by weight, preferably 0.4 to 10 parts per 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction. Part by weight can be exemplified.
[0023] また、本発明のマスキング剤は、市販されている香辛料抽出物を利用して調製する こともできる。具体的には三栄源エフ ·エフ ·アイ株式会社製のサンライクスパイスミツ タスシリーズを例示することができ、これらを適宜混合して本発明のマスキング剤の原 料とする事ちできる。  [0023] The masking agent of the present invention can also be prepared using a commercially available spice extract. Specifically, the San-Like Spice Mitstus series manufactured by San-Ei Gen F.F.I. Co., Ltd. can be exemplified, and these can be appropriately mixed to be used as a raw material for the masking agent of the present invention.
[0024] バニラ豆及び香辛料からの抽出物は、バニラ豆及び香辛料を予め混合して力 抽 出して得てもよぐまた、バニラ豆及び香辛料から別々に抽出物を得た後に、得られ た抽出物を混合して得てもょ ヽ。  [0024] The extract from vanilla beans and spices may be obtained by premixing the vanilla beans and spices and extracting the force, or after obtaining the extract separately from the vanilla beans and spices. It can be obtained by mixing the extracts.
[0025] バニラ豆及び香辛料を予め混合して力 抽出物を得る場合、特に限定するもので はないが、具体的な抽出方法として、バニラ豆及び香辛料と、水溶性溶媒とを重量比 1: 1〜1: 100の割合で混合し、 20〜95。Cで 1〜60分間、好ましくは 85〜90。Cで 40 〜60分間抽出する方法が挙げられる。  [0025] When a power extract is obtained by previously mixing vanilla beans and spices, there is no particular limitation, but as a specific extraction method, a weight ratio of vanilla beans and spices to a water-soluble solvent is 1: 1-1: Mix in a ratio of 100, 20-95. C for 1-60 minutes, preferably 85-90. A method of extracting with C for 40 to 60 minutes can be mentioned.
[0026] バニラ豆及び香辛料カゝら得られた抽出物をそのまま本発明に係るマスキング剤とし てもよいし、必要に応じて希釈または濃縮したり、凍結乾燥や、適当な基剤を加えた 後に噴霧乾燥する等の公知の方法により粉末ィ匕してもよい。実際に食品に添加する 際には、粉末ィ匕したものをさらに水に溶 、て液状として使用してもょ 、。 [0026] The extract obtained from vanilla beans and spices is used as it is as a masking agent according to the present invention. Alternatively, it may be diluted or concentrated as necessary, or lyophilized, or powdered by a known method such as spray drying after adding an appropriate base. When it is actually added to food, it can be further dissolved in water and used as a liquid.
[0027] 本発明のマスキング剤を、バニラ豆及び香辛料カゝら抽出して得る場合、バニラ豆抽 出物の含有量は、抽出前の原料バニラ豆の乾燥重量に換算して、マスキング剤 100 重量部に対して 2〜20重量部、好ましくは 4〜 15重量部が例示できる。香辛料の配 合量は、抽出前の原料バニラ豆及び原料香辛料の乾燥重量に換算して、バニラ豆 抽出物と香辛料抽出物との配合割合力 バニラ豆:香辛料 =4 : 3〜10 : 1となる範囲 が例示できる。  [0027] When the masking agent of the present invention is obtained by extraction from vanilla beans and spices, the content of the extract of vanilla beans is converted to the dry weight of the raw material vanilla beans before extraction. Examples are 2 to 20 parts by weight, preferably 4 to 15 parts by weight, based on parts by weight. The amount of spice is calculated by converting the dry weight of the raw material vanilla beans and raw material spices before extraction, and the mixing ratio of vanilla bean extract and spice extract vanilla beans: spices = 4: 3 to 10: 1 This range can be illustrated.
[0028] 本発明のマスキング剤の畜肉または畜肉を利用した食品への添加量は、畜肉より 発する畜肉臭、特に青臭いグラス臭の程度にもよるが、畜肉 100重量部に対し 0. 05 〜0. 5重量部、好ましくは 0. 08-0. 2重量部が例示できる。  [0028] The amount of the masking agent of the present invention added to livestock meat or foods using livestock meat is 0.05. Examples are 5 parts by weight, preferably 0.08-0.2 parts by weight.
[0029] マスキング剤の添加量が少な 、と青臭!/、グラス臭を充分にマスキングすることがで きず、添加量が多くなるとマスキング剤に含まれるバニリンや香辛料の風味が食品に 影響を及ぼすようになり好ましくな ヽ。  [0029] If the addition amount of the masking agent is small, the blue odor! /, The glass odor cannot be sufficiently masked, and if the addition amount is large, the flavor of vanillin or spice contained in the masking agent may affect the food.ヽ which is preferable.
[0030] 本発明のマスキング剤の食品への添加方法としては、例えば、各種畜肉に噴霧す る、または各種畜肉を本発明のマスキング剤に浸漬する等して使用する方法、及び、 畜肉を使用した食品を製造加工する際に、その原料の 1つとして添加混合する等し て使用する方法が挙げられる。本発明のマスキング剤は、使用に際して特別な装置 や製造条件を必要としないので、工業的にも簡便に使用することができる。  [0030] As a method for adding the masking agent of the present invention to food, for example, a method of spraying various kinds of meat or immersing various kinds of meat in the masking agent of the present invention, and using meat One example is a method of adding and mixing as one of the raw materials when manufacturing and processing the processed food. Since the masking agent of the present invention does not require special equipment or production conditions when used, it can be easily used industrially.
[0031] 本発明のマスキング剤には、本発明の効果を損なわない範囲において他の食品添 加物を添加することもできる。食品添加物としては、例えば、 L—グルタミン酸ナトリウ ム、 L—ァスパラギン酸ナトリウム等のアミノ酸またはその塩、 5 '—イノシン酸ニナトリ ゥム等の核酸またはその塩、クェン酸一カリウム等の有機酸またはその塩、および塩 化カリウム等の無機塩類に代表される調味料;力ラシ抽出物、ヮサビ抽出物、および コウジ酸等の日持向上剤;しらこ蛋白抽出物、ポリリジン、およびソルビン酸等の保存 料; α、 j8アミラーゼ、 a、 j8ダルコシダーゼ、パパイン等の酵素;クェン酸、フマル酸 、コハク酸等の PH調整剤;ショ糖脂肪酸エステル、グリセリン脂肪酸エステル、有機 酸モノグリセリド、レシチン等の乳化剤;香料; β一力ロチン、アナトー色素、紫トウモロ コシ色素等の着色料;カラギナン、アルギン酸及びアルギン酸塩、ぺクチン、タマリン ドシードガム、ダルコマンナン、生澱粉、化工澱粉、加工澱粉、微結晶セルロース、発 酵セルロース、微小繊維状セルロース、カルボキシメチルセルロース塩、メチルセル ロース、ェチノレメチノレセノレロース、ヒドロキシプロピルセルロース、脱アシノレ型ジエラン ガム、ネイティブ型ジエランガム、アラビアガム、タラガム、ダルコマンナン、サイリウム シードガム、マクロホモプシスガム等の増粘剤'ゲル化剤;ショ糖、果糖、ブドウ糖、麦 芽糖、澱粉糖化物、還元澱粉水飴、デキストリン、トレハロース、黒糖、はちみつ等の 糖類;ソルビトール、エリスリトール、キシリトール、マン-トール等の糖アルコール類; スクラロース、アスパルテーム、ステビア、アセスルファムカリウム、ソーマチン、サッカ リン等の高甘味度甘味料;ビタミン Α、ビタミン C等のビタミン類;鉄、カルシウム等のミ ネラル類等が例示でき、これらの 1種以上を組み合わせて添加することができる。 [0031] Other food additives may be added to the masking agent of the present invention within a range not impairing the effects of the present invention. Examples of food additives include amino acids such as sodium L-glutamate and sodium L-aspartate or salts thereof, nucleic acids such as 5'-inosinoic acid or salts thereof, organic acids such as monopotassium citrate or Seasonings such as salts thereof and inorganic salts such as potassium chloride; power-raising extract, rust extract, and kojic acid; shelf life improvers such as shirako protein extract, polylysine, and sorbic acid preservatives; alpha, j8-amylase, a, j8 Darukoshidaze, enzymes papain; Kuen acid, fumaric acid, P H adjusting agent and succinic acids; sucrose fatty acid esters, glycerin fatty acid esters, organic Emulsifiers such as acid monoglycerides and lecithins; fragrances; β-strength rotins, anato dyes, purple corn dyes and other colorants; carrageenan, alginic acid and alginates, pectin, tamarind seed gum, darcomannan, raw starch, modified starch Starch, microcrystalline cellulose, fermented cellulose, microfibrous cellulose, carboxymethylcellulose salt, methylcellulose, ethinolemethinorescenellose, hydroxypropylcellulose, de-asinole type dielan gum, native dielan gum, gum arabic, tara gum, darco Thickeners such as mannan, psyllium seed gum, macrohomopsis gum and gelling agents; sugars such as sucrose, fructose, glucose, maltose, starch saccharified, reduced starch syrup, dextrin, trehalose, brown sugar, honey; sorbitol, D Sugar alcohols such as sitolol, xylitol, mannitol; high-intensity sweeteners such as sucralose, aspartame, stevia, acesulfame potassium, thaumatin, saccharin; vitamins such as vitamin Α and vitamin C; Nerals can be exemplified, and one or more of these can be added in combination.
[0032] 本発明のマスキング剤を用いて畜肉の青臭 、グラス臭をマスキングできる食品とし ては、畜肉を利用した食品を制限無く挙げることができる。ここで、畜肉を利用した食 品とは、畜肉そのものを含む食品に限られず、畜肉を用いて得られる畜肉エキスや、 畜肉由来の成分を含有する食品を含む。具体的には、牛、豚、鶏、山羊、羊、馬、鹿 、イノシシ、ゥサギ、キジ、鴨等の畜肉、好ましくは牧草を主飼料として飼育された牛、 羊の畜肉を原料としてカ卩ェされた食品が例示できる。食品の種類としては、ステーキ 、焼き肉、ハム、ソーセージ、焼き豚、トンカツ、コロッケ、ベーコン、コンビーフ、ハン バーグ、ギヨゥザ、シユウマイ、ナゲット、ミートボール、かす漬け肉、乾燥肉、肉の佃 煮、焼き鳥、レバーパテ、ミートパイ、畜肉をベースにしたスープ等が例示され、ステ ーキ、焼き肉、及びハンバーグが好ましい。  [0032] Examples of foods that can mask the blue odor and glass odor of livestock meat using the masking agent of the present invention include, without limitation, foods using livestock meat. Here, foods using livestock meat are not limited to foods containing livestock meat itself, but include livestock extract obtained using livestock meat and foods containing livestock-derived ingredients. Specifically, cattle, pigs, chickens, goats, sheep, horses, deer, wild boars, rabbits, pheasants, duck and other livestock, preferably cattle bred using pasture as the main feed, and sheep meat Examples of foods that have been registered. The types of food include steak, grilled meat, ham, sausage, grilled pork, tonkatsu, croquette, bacon, corned beef, hamburger, gyoza, shiyumai, nugget, meatball, pickled meat, dried meat, boiled meat, yakitori, Examples include liver pate, meat pie, and soup based on livestock meat, and preferred are stick, grilled meat, and hamburger.
[0033] (2)本発明の畜肉阜のマスキング方法  [0033] (2) Masking method for livestock meat fu of the present invention
本発明の畜肉臭のマスキング方法は、上記本発明のマスキング剤を使用することを 特徴とする。本発明の畜肉臭のマスキング方法としては、例えば、本発明のマスキン グ剤を各種畜肉に噴霧する、または各種畜肉を本発明のマスキング剤に浸漬する、 畜肉の内部へ注入する (インジェクション)等して使用する方法、及び、畜肉を使用し た食品を製造加工する際に、その原料の 1つとして本発明のマスキング剤を添加混 合する等して使用する方法が挙げられる。本発明の畜肉臭のマスキング方法は、使 用に際して特別な装置や製造条件を必要としないので、工業的にも簡便に実施する ことができる。 The masking method for livestock meat odor of the present invention is characterized by using the masking agent of the present invention. Examples of the method for masking meat odor according to the present invention include spraying the masking agent of the present invention on various types of meat, or immersing various types of meat in the masking agent of the present invention, and injecting them into the inside of the meat (injection). When manufacturing and processing foods using livestock meat, the masking agent of the present invention is added and mixed as one of the raw materials. The method of combining and using is mentioned. The method for masking meat odor according to the present invention does not require any special equipment or manufacturing conditions for use, and therefore can be easily carried out industrially.
[0034] 本発明の畜肉臭のマスキング方法における本発明のマスキング剤の畜肉または畜 肉を利用した食品への添加量は、畜肉より発する畜肉臭、特に青臭いグラス臭の程 度にもよる力 食品に使用される畜肉 100重量部に対して 0. 05-0. 5重量部、好ま しくは 0. 08〜0. 2重量部が例示できる。  [0034] The amount of the masking agent of the present invention added to the animal meat or the food using the meat in the method for masking the meat odor of the present invention depends on the degree of the meat odor emitted from the meat, especially the blue odor glass odor. For example, 0.05 to 0.5 parts by weight, preferably 0.08 to 0.2 parts by weight, can be exemplified for 100 parts by weight of livestock meat used for food.
実施例  Example
[0035] 以下、本発明の内容を以下の試験例を用いて具体的に説明する。但し、本発明は これらに限定されるものではない。尚、実施例中の「部」「%」はそれぞれ「重量部」「 重量%」を、文中「*」は三栄源エフ 'エフ'アイ株式会社の製品、厂※」は三栄源エフ •エフ ·アイ株式会社の登録商標であることを示す。  [0035] The contents of the present invention will be specifically described below using the following test examples. However, the present invention is not limited to these. In the examples, “parts” and “%” are “parts by weight” and “% by weight”, respectively, “*” in the text is a product of San-Eigen F.F. · Indicates a registered trademark of i Corporation.
[0036] 実施例 1  [0036] Example 1
<マスキング剤の調製 >  <Preparation of masking agent>
下記処方実施例、比較例 1及び 2に記載のマスキング剤原料 (乾燥物)を混合し、 9 5%エタノール水溶液 15部、水をカ卩ぇ全量 100部とし、 90°C2時間還流抽出を行つ た。該抽出物を室温まで冷却後、 200メッシュ金網で固形物を除去し、冷蔵庫にて 2 4時間静置した。その後、該抽出物の上澄み部分にろ過助剤 (JOHNS MANVILLE社 製 ノ、ィフ口)をカ卩ぇ Nol8ろ紙を用いてろ過することにより、本発明に係るマスキング 剤を得た。尚、香辛料の内訳は、ガーリック 3部、ブラックペパー 40部、オールスパイ ス 25咅^コリアンダー 1 メース 7咅^シナモン 2咅^タイム 2咅及びローレノレ 2咅の 全量 100部とした。  Mix the masking agent raw materials (dried product) described in the following formulation examples and comparative examples 1 and 2 and make 15 parts of 95% ethanol aqueous solution and 100 parts of water in total, and perform reflux extraction at 90 ° C for 2 hours. The The extract was cooled to room temperature, solids were removed with a 200 mesh wire net, and left in a refrigerator for 24 hours. Then, the masking agent which concerns on this invention was obtained by filtering the filter aid (The product made from a JOHNS MANVILLE, the muffler mouth) into the supernatant part of this extract using the cake Nol8 filter paper. The spices were broken down to 3 parts of garlic, 40 parts of black pepper, 100% of all spices 25 咅 ^ coriander 1 mace 7 咅 ^ cinnamon 2 咅 ^ time 2 咅 and lorenore 2 咅.
[0037] [表 1]  [0037] [Table 1]
Figure imgf000010_0001
Figure imgf000010_0001
<ビーフハンバーグの調製、評価 >  <Preparation and evaluation of beef hamburger>
表 2の原料部及び調味部(実施例、比較例 1及び 2)全てをよく混合し、こぶし大に 成型後、表面を鉄板上 200°Cで表裏各 1分ずつ焼成した。その後、中心温度が 75Mix all ingredients and seasonings in Table 2 (Examples, Comparative Examples 1 and 2) After molding, the surface was baked on an iron plate at 200 ° C for 1 minute each on the front and back. After that, the center temperature is 75
°C達温になるようスチームにかけることにより、ビーフハンバーグを得た。 Beef hamburger was obtained by steaming to reach ° C.
[0039] 原料部 (A〜C)と調味部(実施例、比較例 1及び 2)をそれぞれ組み合わせたビー フハンバーグと、マスキング剤を含まない調味部によるブランク品を調製し、調製後の 風味の評価を行った。その結果を表 3に示す。 [0039] A beef hamburger in which the raw material part (A to C) and the seasoning part (Examples, Comparative Examples 1 and 2) are combined and a blank product containing the seasoning part not containing the masking agent are prepared, and the flavor after the preparation Was evaluated. The results are shown in Table 3.
[0040] [表 2] [0040] [Table 2]
Figure imgf000011_0001
Figure imgf000011_0001
<調味部 処方 > <Seasoning part prescription>
食塩  Salt
乳清たんばく (ミルプロ※ No. 142 *)  Whey Tank (Mirpro * No. 142 *)
乳清たんぱく (ミルプロ※ LG*) o oooolll  Whey protein (Mirpro * LG *) o oooolll
畜肉用品質改良剤 (エスプロ一ゲン※ M— 5 OR*)  Quality improvement agent for livestock meat (Esprogen * M—5 OR *)
トレハロース (林原社製 トレハ) 部 5735321 調味料 (サンライク※ビーフ風味 4309 P *)  Trehalose (Trehach made by Hayashibara) part 5735321 Seasoning (Sunlike * beef flavor 4309 P *)
調味料 (サンライク※コゥボ 0409 P*)  Seasoning (Sunlike * Koubo 0409 P *)
マスキング剤 (実施例、 比較例 1及び 2)  Masking agent (Example, Comparative Examples 1 and 2)
[表 3] [Table 3]
Figure imgf000011_0002
Figure imgf000011_0002
X 畜肉臭 (グラス臭) が強く感じられた X Livestock odor (glass odor) was strongly felt
X 畜肉臭 (グラス臭) が感じられた  X Livestock odor (glass odor) was felt
△ バニラ臭が強く出ていた  △ Vanilla smell was strong
▲ スパイス感が強く出ていた  ▲ The spice was strong
〇 畜肉臭が抑制され、 肉の旨味が感じられた  〇 Livestock odor was suppressed and the taste of meat was felt
◎ 畜肉臭の特にグラス臭が抑制されていた  ◎ Livestock meat odor, especially glass odor, was suppressed
[0044] <結果 > マスキング剤を使用しな力つたビーフハンバーグからは、使用した牛肉に由来する と思われるグラス臭が顕著に感じられた。即ち、牧草を主飼料としていた牛由来の牛 ミンチを使用したビーフハンバーグ (B)からは、強く青臭いグラス臭が感じられたが、 穀物を主飼料としていた牛由来の牛ミンチ (A)ではグラス臭はあまり感じられなかつ た。また、牧草を主飼料としていた牛由来の牛ミンチであっても、子牛由来の牛ミンチ の場合 (C)には、(B)程のグラス臭は感じられな力つた。 [0044] <Result> From the beef hamburger, which did not use a masking agent, the glassy odor, which seems to be derived from the beef used, was noticeable. In other words, the beef hamburger (B), which uses cattle minced from cattle that used pasture as the main feed, felt a strong blue-smelling glass odor, but the cattle derived from cattle minced (A), which used cereal as the main feed, had a glass. The odor was not felt so much. In addition, even in the case of cattle mince derived from cattle that used pasture as the main diet, in the case of calf-derived cattle mince (C), the glass odor of (B) was strong.
[0045] マスキング剤を添加した場合、マスキング剤に含まれるバニラ豆と香辛料との混合 割合により、畜肉臭(グラス臭)のマスキングの程度は異なっていた。実施例に基づい たマスキング剤を (B)の牛肉に用いたビーフハンバーグでは、特に効果的にグラス臭 の発生を抑制することができた。また、同様に実施例で得られたマスキング剤を A及 び Cの牛肉に用いた場合でも、効果的に畜肉臭の発生を抑制することができた。  [0045] When the masking agent was added, the degree of masking of the meat odor (glass odor) varied depending on the mixing ratio of vanilla beans and spices contained in the masking agent. In the beef hamburger using the masking agent based on the example for the beef (B), the generation of the glass odor could be suppressed particularly effectively. Similarly, even when the masking agents obtained in the examples were used for A and C beef, generation of livestock odor could be effectively suppressed.
[0046] 実飾 12  [0046] Jewelery 12
実施例 1で得た比較例 1に該当する香辛料のみの抽出物に、バニラエッセンス (ヮ ユラエッセンス (N) * ) 10部を添加し、以下同様の手順でビーフハンバーグを調製し たところ、本発明に係るマスキング剤である実施例品によるものと同等の効果が得ら れた。  When 10 parts of vanilla essence (ヮ Yura Essence (N) *) was added to the spice-only extract corresponding to Comparative Example 1 obtained in Example 1, beef hamburger was prepared in the same procedure. The same effect as that obtained by the example product which is the masking agent according to the invention was obtained.
[0047] 実飾 13 [0047] Decoration 13
実施例 1で得た比較例 1に該当する香辛料のみの抽出物に、合成バニリン 0. 1部 を添加し、以下同様の手順でビーフハンバーグを調製したところ、本発明に係るマス キング剤である実施例品によるものと同等の効果が得られた。  When 0.1 part of synthetic vanillin was added to the spice-only extract corresponding to Comparative Example 1 obtained in Example 1, beef hamburger was prepared in the same procedure, and it was a masking agent according to the present invention. The same effect as that of the example product was obtained.

Claims

請求の範囲 The scope of the claims
[I] バニリン及び香辛料抽出物を有効成分として含有する、畜肉臭のマスキング剤。  [I] A meat odor masking agent containing vanillin and a spice extract as active ingredients.
[2] バニラ豆抽出物及び香辛料抽出物を有効成分として含有する、請求項 1に記載の畜 肉臭のマスキング剤。  [2] The meat odor masking agent according to claim 1, comprising a vanilla bean extract and a spice extract as active ingredients.
[3] 香辛料が、メース、ガーリック、タイム、シナモン及びペパーミントからなる群より選ば れる 1種以上である、請求項 1に記載の畜肉臭のマスキング剤。  [3] The meat odor masking agent according to claim 1, wherein the spice is at least one selected from the group consisting of mace, garlic, thyme, cinnamon and peppermint.
[4] バニリンの含有量力 マスキング剤 100重量%中、 0. 04〜0. 15重量%である請求 項 1に記載の畜肉臭のマスキング剤。 [4] The content power of vanillin The masking agent for livestock meat odor according to claim 1, which is 0.04 to 0.15% by weight in 100% by weight of the masking agent.
[5] 香辛料抽出物の含有量が、抽出前の原料香辛料の乾燥重量に換算して、マスキン グ剤 100重量部に対して 0. 2〜 15重量部である、請求項 1に記載の畜肉臭のマスキ ング剤。 [5] The livestock meat according to claim 1, wherein the content of the spice extract is 0.2 to 15 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw spices before extraction. Odor masking agent.
[6] バニラ豆抽出物の配合量が、抽出前の原料バニラ豆の乾燥重量に換算して、マスキ ング剤 100重量部に対して 2〜20重量部である、請求項 2に記載の畜肉臭のマスキ ング剤。  [6] The livestock meat according to claim 2, wherein the amount of the vanilla bean extract is 2 to 20 parts by weight with respect to 100 parts by weight of the masking agent in terms of the dry weight of the raw vanilla beans before extraction. Odor masking agent.
[7] 抽出前の原料バニラ豆及び原料香辛料の乾燥重量に換算して、バニラ豆抽出物と 香辛料抽出物との配合割合力 4 : 3〜10 : 1である、請求項 2に記載の畜肉臭のマス キング剤。  [7] The livestock meat according to claim 2, wherein the ratio of the ratio of the vanilla bean extract and the spice extract to the dry weight of the raw vanilla beans and the spices before extraction is 4: 3 to 10: 1. Odor masking agent.
[8] 畜肉臭が青臭 、グラス臭である請求項 1に記載のマスキング剤。  8. The masking agent according to claim 1, wherein the meat odor is a blue odor or a glass odor.
[9] 請求項 1に記載のマスキング剤を使用することを特徴とする畜肉臭のマスキング方法  [9] A method for masking meat odor, comprising using the masking agent according to claim 1.
[10] 下記の工程のいずれかを含む、畜肉臭のマスキング方法: [10] Method for masking meat odor, including any of the following steps:
(1)請求項 1に記載のマスキング剤を畜肉に噴霧する工程、  (1) A step of spraying the masking agent according to claim 1 on livestock meat,
(2)畜肉を請求項 1に記載のマスキング剤に浸漬する工程、  (2) a step of immersing livestock meat in the masking agent according to claim 1,
(3)請求項 1に記載のマスキング剤を畜肉に注入する工程。  (3) A step of injecting the masking agent according to claim 1 into livestock meat.
[II] 請求項 1に記載のマスキング剤を、畜肉を利用した食品の原料の 1つとして使用する 、畜肉臭のマスキング方法。  [II] A method for masking meat odor, wherein the masking agent according to claim 1 is used as one of raw materials for food using livestock meat.
[12] 請求項 1に記載のマスキング剤を、畜肉 100重量部に対して 0. 05〜0. 5重量部の 割合で用いることを特徴とする、畜肉臭のマスキング方法。  [12] A method for masking meat odor, comprising using the masking agent according to claim 1 in a ratio of 0.05 to 0.5 parts by weight per 100 parts by weight of livestock meat.
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Cited By (6)

* Cited by examiner, † Cited by third party
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JP2009256646A (en) * 2008-03-26 2009-11-05 Teijin Ltd Polyester containing vegetable-originated component and method for producing the same
CN104664416A (en) * 2015-03-25 2015-06-03 西南大学 Rabbit meat product and preparation method thereof
FR3016522A1 (en) * 2014-01-23 2015-07-24 Clean Farm Internat
WO2018211690A1 (en) * 2017-05-19 2018-11-22 花王株式会社 Tea beverage
WO2019048564A1 (en) * 2017-09-08 2019-03-14 Rhodia Operations Use of vanillin and/or ethylvanillin as a bitterness-masking agent
WO2021172401A1 (en) * 2020-02-25 2021-09-02 ハウス食品株式会社 Mixed spice and mixing composition that contains same

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Publication number Priority date Publication date Assignee Title
JP2009256646A (en) * 2008-03-26 2009-11-05 Teijin Ltd Polyester containing vegetable-originated component and method for producing the same
FR3016522A1 (en) * 2014-01-23 2015-07-24 Clean Farm Internat
CN104664416A (en) * 2015-03-25 2015-06-03 西南大学 Rabbit meat product and preparation method thereof
WO2018211690A1 (en) * 2017-05-19 2018-11-22 花王株式会社 Tea beverage
WO2019048564A1 (en) * 2017-09-08 2019-03-14 Rhodia Operations Use of vanillin and/or ethylvanillin as a bitterness-masking agent
FR3073368A1 (en) * 2017-09-08 2019-05-17 Rhodia Operations USE OF VANILLIN AND / OR ETHYLVANILLIN AS AMINISHING MASKING AGENT
WO2021172401A1 (en) * 2020-02-25 2021-09-02 ハウス食品株式会社 Mixed spice and mixing composition that contains same

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