WO2006016079A3 - Procede perfectionne de fabrication d'acide phosphorique - Google Patents

Procede perfectionne de fabrication d'acide phosphorique Download PDF

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Publication number
WO2006016079A3
WO2006016079A3 PCT/FR2005/050451 FR2005050451W WO2006016079A3 WO 2006016079 A3 WO2006016079 A3 WO 2006016079A3 FR 2005050451 W FR2005050451 W FR 2005050451W WO 2006016079 A3 WO2006016079 A3 WO 2006016079A3
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
liquid
phosphoric acid
solid
slurry
Prior art date
Application number
PCT/FR2005/050451
Other languages
English (en)
Other versions
WO2006016079A2 (fr
Inventor
Guy Nineuil
Thierry Sirba
Original Assignee
Vichem
Guy Nineuil
Thierry Sirba
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vichem, Guy Nineuil, Thierry Sirba filed Critical Vichem
Priority to DE602005011013T priority Critical patent/DE602005011013D1/de
Priority to EP05778171A priority patent/EP1773851B1/fr
Publication of WO2006016079A2 publication Critical patent/WO2006016079A2/fr
Publication of WO2006016079A3 publication Critical patent/WO2006016079A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/18—Phosphoric acid
    • C01B25/22—Preparation by reacting phosphate-containing material with an acid, e.g. wet process
    • C01B25/222—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen
    • C01B25/223—Preparation by reacting phosphate-containing material with an acid, e.g. wet process with sulfuric acid, a mixture of acids mainly consisting of sulfuric acid or a mixture of compounds forming it in situ, e.g. a mixture of sulfur dioxide, water and oxygen only one form of calcium sulfate being formed
    • C01B25/225—Dihydrate process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Removal Of Specific Substances (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Saccharide Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

Procédé de fabrication d'acide phosphorique consistant, dans au moins deux couples réacteur-séparateur solide/liquide successifs, : - dans le premier réacteur, à attaquer entre 60 et 80 % du débit de phosphate tricalcique avec de l'acide sulfurique dans un milieu réactionnel, dont l'eau est fournie par la totalité de l'eau de lavage du mélange de la bouillie provenant de ce premier réacteur et du gâteau extrait du second séparateur liquide/solide, - à faire réagir dans le second réacteur, le complément à 100 % du débit de phosphate tricalcique et la quantité d'acide sulfurique nécessaire à l'attaque, en présence de tout ou partie de l'acide phosphorique intermédiaire produit et recueilli par séparation liquide solide de la bouillie provenant du premier réacteur, - enfin, par séparation solide/liquide de la bouillie issue du second réacteur, à recueillir l'acide phosphorique final produit, - parallèlement, à extraire le gâteau formé sur le second séparateur et le disperser dans la bouillie issue du premier réacteur avant séparation liquide/solide.
PCT/FR2005/050451 2004-07-13 2005-06-16 Procede perfectionne de fabrication d'acide phosphorique WO2006016079A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE602005011013T DE602005011013D1 (de) 2004-07-13 2005-06-16 Verbessertes verfahren zur herstellung von phosphorsäure
EP05778171A EP1773851B1 (fr) 2004-07-13 2005-06-16 Procede perfectionne de fabrication d'acide phosphorique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0451524A FR2873119B1 (fr) 2004-07-13 2004-07-13 Procede perfectionne de fabrication d'acide phosphorique
FR0451524 2004-07-13

Publications (2)

Publication Number Publication Date
WO2006016079A2 WO2006016079A2 (fr) 2006-02-16
WO2006016079A3 true WO2006016079A3 (fr) 2006-08-10

Family

ID=34947558

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2005/050451 WO2006016079A2 (fr) 2004-07-13 2005-06-16 Procede perfectionne de fabrication d'acide phosphorique

Country Status (5)

Country Link
EP (1) EP1773851B1 (fr)
AT (1) ATE414091T1 (fr)
DE (1) DE602005011013D1 (fr)
FR (1) FR2873119B1 (fr)
WO (1) WO2006016079A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5188583B2 (ja) 2008-01-04 2013-04-24 エルジー・ライフ・サイエンシーズ・リミテッド 細胞、組織及び臓器保存効果を有するインドール及びインダゾール誘導体

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1212825A (fr) * 1958-08-25 1960-03-25 Ets Kuhlmann Procédé continu de fabrication d'acide phosphorique et appareillage pour sa mise en oeuvre
FR2130847A5 (en) * 1971-03-23 1972-11-10 Pechiney Saint Gobain Wet process phosphoric acid prodn - high phosphorus pentoxide concn
US4220630A (en) * 1978-01-04 1980-09-02 Occidental Petroleum Corporation Hemihydrate type process for phosphoric acid manufacture using additive to improve filterability
FR2468548A1 (fr) * 1979-10-31 1981-05-08 Rhone Poulenc Ind Perfectionnements au procede de preparation d'acide phosphorique de voie humide
EP0181029A2 (fr) * 1984-11-05 1986-05-14 Prayon Développement Société anonyme Procédé continu de préparation d'acide phosphorique et de sulfate de calcium

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1212825A (fr) * 1958-08-25 1960-03-25 Ets Kuhlmann Procédé continu de fabrication d'acide phosphorique et appareillage pour sa mise en oeuvre
FR2130847A5 (en) * 1971-03-23 1972-11-10 Pechiney Saint Gobain Wet process phosphoric acid prodn - high phosphorus pentoxide concn
US4220630A (en) * 1978-01-04 1980-09-02 Occidental Petroleum Corporation Hemihydrate type process for phosphoric acid manufacture using additive to improve filterability
FR2468548A1 (fr) * 1979-10-31 1981-05-08 Rhone Poulenc Ind Perfectionnements au procede de preparation d'acide phosphorique de voie humide
EP0181029A2 (fr) * 1984-11-05 1986-05-14 Prayon Développement Société anonyme Procédé continu de préparation d'acide phosphorique et de sulfate de calcium

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; BESPALOV, A. V. ET AL: "Manufacture of wet - process phosphoric acid by dihydrate process with separate feed of apatite concentrate", XP002320022, retrieved from STN Database accession no. 133:254491 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; YAKUBOV, R. YA. ET AL: "Effect of seed crystals on the decomposition and crystallization of calcium sulfate dihydrate in production of wet - process phosphoric acid from the phosphorites of Karatau", XP002320023, retrieved from STN Database accession no. 101:57165 *
KHIMICHESKAYA PROMYSHLENNOST (MOSCOW) , (10), 625-628 CODEN: KPRMAW; ISSN: 0023-110X, 1999 *
UZBEKSKII KHIMICHESKII ZHURNAL , (3), 43-6 CODEN: UZKZAC; ISSN: 0042-1707, 1984 *

Also Published As

Publication number Publication date
EP1773851A2 (fr) 2007-04-18
WO2006016079A2 (fr) 2006-02-16
ATE414091T1 (de) 2008-11-15
DE602005011013D1 (de) 2008-12-24
FR2873119A1 (fr) 2006-01-20
EP1773851B1 (fr) 2008-11-12
FR2873119B1 (fr) 2008-02-01

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