WO2006009995A1 - Compression resistant nonwovens - Google Patents
Compression resistant nonwovens Download PDFInfo
- Publication number
- WO2006009995A1 WO2006009995A1 PCT/US2005/021751 US2005021751W WO2006009995A1 WO 2006009995 A1 WO2006009995 A1 WO 2006009995A1 US 2005021751 W US2005021751 W US 2005021751W WO 2006009995 A1 WO2006009995 A1 WO 2006009995A1
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- WO
- WIPO (PCT)
- Prior art keywords
- web
- fibers
- precursor
- tufts
- topsheet
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H11/00—Non-woven pile fabrics
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51104—Topsheet, i.e. the permeable cover or layer facing the skin the top sheet having a three-dimensional cross-section, e.g. corrugations, embossments, recesses or projections
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51121—Topsheet, i.e. the permeable cover or layer facing the skin characterised by the material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/5116—Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
- A61F13/51305—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability having areas of different permeability
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F2013/51002—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers with special fibres
- A61F2013/51007—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers with special fibres characterized by the orientation of fibres
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/5116—Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
- A61F2013/51165—Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers with the combination of films and nonwovens
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
- A61F2013/51338—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability having improved touch or feeling, e.g. smooth film
- A61F2013/51344—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability having improved touch or feeling, e.g. smooth film with pile webs or velvet-like tissues
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
- A61F2013/51355—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability for improving fluid flow
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
- A61F2013/51355—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability for improving fluid flow
- A61F2013/51372—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability for improving fluid flow with valve or valve-like upper layer; Tapered capillary structures
Definitions
- This invention relates to fibrous nonwoven webs suitable for use as a topsheet in a disposable absorbent article.
- this invention relates to fibrous webs treated by mechanical formation to have increased compression resistance.
- Disposable absorbent articles such as baby diapers, adult incontinence products, sanitary napkins, pantiliners, hemorrhoid treatment pads, bandages, and the like are well known in the art. Such articles generally have a fluid permeable topsheet, and fluid impermeable backsheet, and an absorbent core sandwiched between the topsheet and the backsheet to absorb and contain body fluid exudates.
- disposable absorbent articles such as sanitary napkins and pantiliners
- Fluid on the body can be minimized by ensuring that the fluid enters the absorbent article, and does not come back out, such as by being pressed or squeezed out. While much work has been done in to minimize rewet to the body, there remains a need for a disposable absorbent article that helps keep the users body clean and dry.
- a sanitary napkin comprising a topsheet comprising a plurality of discrete tufts of fibrous material, wherein the topsheet has a density of less than 0.027 g/cc under a load of 0.004 psi, and a density of less than 0.068 at a load of 0.23 psi.
- FIG. 1 is a perspective view of a web of the present invention.
- FIG. 2 is an enlarged view of a portion of the web shown in FIG. 1.
- FIG. 3 is a cross-sectional view of section 3-3 of FIG. 2.
- FIG. 4 is a plan view of a portion of the web as indicated by 4-4 in FIG. 3.
- FIG. 5 is a perspective view of an apparatus for forming the web of the present invention.
- FIG. 6 is a cross-sectional depiction of a portion of the apparatus shown in FIG. 5.
- FIG. 7 is a perspective view of a portion of the apparatus for forming one embodiment the web of the present invention.
- FIG. 8 is an enlarged perspective view of a portion of the apparatus for forming the web of the present invention.
- FIG. 9 is an enlarged view of a portion of another embodiment of a web of the present invention.
- FIG. 10 is a partial cut away plan view of a sanitary napkin of the present invention.
- the present invention can be utilized in any of known disposable absorbent products.
- the present invention comprises a sanitary napkin intended to be used as a menstrual pad.
- the sanitary napkin of the present invention comprises at least three components: a topsheet, a lotion applied to the topsheet, and an absorbent core in fluid communication with the topsheet. It has been unexpectedly found that, by using the web of the present invention, a sanitary napkin of the present invention can provide for a desirable clean body benefit.
- the sanitary napkin of the present invention provides for better compression resistance, comparable to that of known formed film webs, such as DRI- WEAVE® topsheet utilized on ALWAYS® sanitary napkins marketed by The Procter & Gamble Co.
- FIG. 1 shows a laminate web 1 of the present invention, suitable for use as a compression resistant topsheet in a disposable absorbent article of the present invention.
- Web 1 can comprise one layer, but in a preferred embodiment comprises at least two layers.
- the layers are referred to herein as generally planar, two-dimensional precursor webs, such as first precursor web 20 and second precursor web 21.
- both precursor webs are nonwoven webs.
- Precursor webs 20 and 21 (and any additional webs) can be joined by adhesive, thermal bonding, ultrasonic bonding and the like, but are preferably joined without the use of adhesive or other forms of bonding.
- the constituent precursor webs of web 1 can be joined by interlocking mechanical engagement resulting from the formation of tufts 6.
- Web 1 has a first side 3 and a second side 5, the term "sides" being used in the common usage of generally planar two-dimensional webs, such as paper and films that have two sides when in a generally flat condition.
- Each precursor web 20 and 21 has a first surface 12 and 13, respectively, and a second surface 14 and 15, respectively (shown in FIG. 3).
- Web 1 has a machine direction (MD) and a cross machine direction (CD) as is commonly known in the art of web manufacture.
- MD machine direction
- CD cross machine direction
- both precursor webs are nonwoven webs comprised of substantially randomly oriented fibers.
- first precursor web 20 is a relatively hydrophilic nonwoven web and second precursor web 21 is a nonwoven web is a relatively hydrophobic nonwoven web.
- the hydrophobicity or hydrophilicity can be achieved by use of fibers having the proper characteristics, or the precursor webs can be treated to have the desired characteristics.
- first side 3 of web 1 is defined by exposed portions of the first surface 13 of second precursor web 21 and at least one, but preferably a plurality of, discrete tufts 6 which are integral extensions of the fibers of at least first precursor web 20 and preferably both precursor webs.
- each tuft 6 can comprise a plurality of looped, aligned fibers 8 extending through second precursor web 21 and outwardly from the first surface 13 thereof.
- each tuft 6 can comprise a plurality of non-looped fibers 18 (as shown in FIG. 3) that extend outwardly from the first surface 13.
- tufts 6 can comprise fibers from both precursor webs.
- fibers of first precursor web 20 are formed inside the tuft, with fibers of second precursor web being substantially covering the outside of the tuft.
- nonwoven web refers to a web having a structure of individual fibers or threads which are interlaid, but not in a repeating pattern as in a woven or knitted fabric, which do not typically have randomly oriented fibers.
- Nonwoven webs or fabrics have been formed from many processes, such as, for example, meltblowing processes, spunbonding processes, hydroentangling, airlaying, and bonded carded web processes, including carded thermal bonding. Fibers can be bicomponent, multicomponent, multiconstituent, and the like, as known in the art.
- the basis weight of nonwoven fabrics is usually expressed in grams per square meter (gsm).
- the basis weight of the laminate web is the combined basis weight of the constituent layers and any other added components.
- Fiber diameters are usually expressed in microns; fiber size can also ,be expressed in denier, which is a unit of weight per length of fiber.
- the basis weight of laminate webs suitable for use in the present invention can range from 10 gsm to 500 gsm.
- the constituent fibers of nonwoven precursor web 20 or 21 can be comprised of polymers such as polyethylene, polypropylene, polyester, and blends thereof.
- the fibers can comprise cellulose, rayon, cotton, or other natural materials or blends of polymer and natural materials.
- the fibers can also comprise a super absorbent material such as polyacrylate or any combination of suitable materials.
- the fibers can be monocomponent, bicomponent, and/or biconstituent, non-round (e.g., capillary channel fibers), and can have major cross-sectional dimensions (e.g., diameter for round fibers) ranging from 0.1-500 microns.
- one type of fibers suitable for the nonwoven web includes nanofibers.
- Nanofibers are described as fibers having a mean diameter of less than 1 micron. Nanofibers can comprise all of the fibers in a nonwoven web or a portion of the fibers in a nonwoven web.
- the constituent fibers of the nonwoven precursor web may also be a mixture of different fiber types, differing in such features as chemistry (e.g. PE and PP), components (mono- and bi-), denier (micro denier and >20 denier), shape (i.e. capillary and round) and the like.
- the constituent fibers can range from about 0.1 denier to about 100 denier.
- spunbond fibers refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced. Spunbond fibers are generally not tacky when they are deposited on a collecting surface. Spunbond fibers are generally continuous and have average diameters (from a sample of at least 10) larger than 7 microns, and more particularly, between about 10 and 40 microns.
- meltblowing refers to a process in which fibers are formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually heated, gas (for example air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface, often while still tacky, to form a web of randomly dispersed meltblown fibers. Meltblown fibers are microfibers which may be continuous or discontinuous and are generally smaller than 10 microns in average diameter.
- polymer generally includes, but is not limited to, homopolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, etc., and blends and modifications thereof.
- polymer includes all possible geometric configurations of the material. The configurations include, but are not limited to, isotactic, atactic, syndiotactic, and random symmetries.
- the term "monocomponent" fiber refers to a fiber formed from one or more extruders using only one polymer. This is not meant to exclude fibers formed from one polymer to which small amounts of additives have been added for coloration, antistatic properties, lubrication, hydrophilicity, etc. These additives, for example titanium dioxide for coloration, are generally present in an amount less than about 5 weight percent and more typically about 2 weight percent.
- bicomponent fibers refers to fibers which have been formed from at least two different polymers extruded from separate extruders but spun together to form one fiber. Bicomponent fibers are also sometimes referred to as conjugate fibers or multicomponent fibers. The polymers are arranged in substantially constantly positioned distinct zones across the cross-section of the bicomponent fibers and extend continuously along the length of the bicomponent fibers.
- the configuration of such a bicomponent fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another, or may be a side-by-side arrangement, a pie arrangement, or an "islands-in-the-sea" arrangement.
- biconstituent fibers refers to fibers which have been formed from at least two polymers extruded from the same extruder as a blend. Biconstituent fibers do not have the various polymer components arranged in relatively constantly positioned distinct zones across the cross-sectional area of the fiber and the various polymers are usually not continuous along the entire length of the fiber, instead usually forming fibrils which start and end at random. Biconstituent fibers are sometimes also referred to as multiconstituent fibers.
- non-round fibers describes fibers having a non-round cross- section, and includes “shaped fibers” and “capillary channel fibers.”
- Such fibers can be solid or hollow, and they can be tri-lobal, delta-shaped, and are preferably fibers having capillary channels on their outer surfaces.
- the capillary channels can be of various cross-sectional shapes such as “U-shaped”, “H-shaped”, “C-shaped” and “V-shaped”.
- One preferred capillary channel fiber is T-401, designated as 4DG fiber available from Fiber Innovation Technologies, Johnson City, TN.
- T-401 fiber is a polyethylene terephthalate (PET polyester).
- the term "integral" as in “integral extension” when used for the tufts 6 refers to fibers of the tufts 6 having originated from the fibers of the precursor webs.
- fibers in tufts 6 can be integral with, i.e., originated in, first precursor web 20. Therefore, the looped fibers 8 and non-looped fibers 18 of tufts 6, can be plastically deformed and extended fibers of the first precursor web 20, and are, therefore, integral with first precursor web 20.
- integral is to be distinguished from fibers introduced to or added to a separate precursor web for the purpose of making tufts, as is commonly done in conventional carpet making, for example.
- tufts 6 can be varied to give varying texture to first side 3 of web 1. For example, if tufts 6 are sufficiently closely spaced the first side 3 of web 1 can have a terry cloth-like feel.
- tufts 6 can be arranged in patterns such as lines or filled shapes to create portions of a laminate web having greater texture, softness, bulk, absorbency or visual design appeal. For example, when tufts 6 are arranged in a pattern of a line or lines, the tufts can have the appearance of stitching. Tufts 6 can also be arranged to form specific shapes, such as designs, words or logos.
- First precursor web 20 can be a fibrous woven or nonwoven web comprising fibers having sufficient elongation properties to have portions formed into tufts 6 as described more fully below. Tufts are formed by urging fibers out-of-plane in the Z-direction at discrete, localized, portions of precursor webs.
- the urging out-of-plane can be due to fiber displacement, i.e., the fiber is able to move relative to other fibers and be "pulled," so to speak, out-of-plane. More often, however, for most nonwoven precursor webs, the urging out-of-plane is due to the fibers of tufts 6 having been at least partially plastically stretched and permanently deformed to form tufts 6. Therefore, in one embodiment, depending on the desired height of tufts 6, the constituent fibers of nonwoven precursor webs can exhibit an elongation to break of at least about 5%, more preferably at least about 10%, more preferably at least about 25%, more preferably at least about 50%, and more preferably at least about 100%. Elongation to break can be determined by simple tensile testing, such as by use of Instron tensile testing equipment, and can generally be found on material data sheets from suppliers of such fibers or webs.
- a suitable precursor webs should comprise fibers capable of experiencing sufficient plastic deformation and tensile elongation, or are capable of sufficient fiber mobility, such that looped fibers 8 are formed.
- fibers capable of experiencing sufficient plastic deformation and tensile elongation, or are capable of sufficient fiber mobility, such that looped fibers 8 are formed.
- loose fibers or loose fiber ends 18 Such fibers are referred to herein as "loose” fibers or "loose fiber ends” 18 as shown in FIG. 3.
- Loose fiber ends 18 are not necessarily undesirable for the present invention, and in some embodiments, most or all of the fibers of tufts 6 can be loose fiber ends 18.
- Loose fiber ends 18 can also be the result of forming tufts 6 from nonwoven webs consisting of, or containing, cut staple fibers. In such a case, some number of the staple fiber ends may protrude into the tuft 6, depending upon such things as the number of staple fibers in the web, the staple fiber cut length, and the height of the tufts. In some instances, it may be desired to use a blend of fibers of different lengths in a precursor web or fibers of different lengths in different layers. This may be able to selectively separate the longer fibers from the shorter fibers. The longer fibers may predominately form the tuft 6 while the shorter fibers predominately remain in the portion of the web not forming the tuft 6.
- An exemplary mixture of fiber lengths can include fibers of approximately 2 to 8 centimeters for the longer fibers and less than about 1 centimeter for the shorter fibers.
- First precursor web 20 can be a fibrous woven or nonwoven web comprising elastic or elastomeric fibers.
- Elastic or elastomeric fibers can be stretched at least about 50% and return to within 10% of their original dimension.
- Tufts 6 can be formed from elastic fibers if the fibers are simply displaced due to the mobility of the fiber within the nonwoven, or if the fibers are stretched beyond their elastic limit and are plastically deformed.
- Second precursor web 21 can be virtually any web material, the only requirement being that it have sufficient integrity to be formed into the laminate by the process described below. In one embodiment, it can have sufficiently less elongation properties relative to first precursor web
- second precursor web 21 will rupture, e.g., by tearing due to extensional failure, such that portions of first precursor web 20 can extend through, (i.e., "punch through” so to speak), second precursor web 21 to form tufts 6 on first side
- second precursor web 21 is a polymer film. Second precursor web 21 can also have sufficient elongation properties to be formed into looped fibers, as described above with respect to first precursor web 20.
- FIG. 2 A representative tuft 6 for the embodiment of web 1 shown in FIG. 1 (where the second precursor web 21 is "punched through” by first precursor web) is shown in a further enlarged view in FIG. 2.
- tuft 6 comprises a plurality of looped fibers 8 that are substantially aligned such that tuft 6 has a distinct linear orientation and a longitudinal axis L.
- Tuft 6 also have a transverse axis T generally orthogonal to longitudinal axis L in the MD-CD plane.
- longitudinal axis L is parallel to the MD.
- all the spaced apart tufts 6 have generally parallel longitudinal axes L.
- the number of tufts 6 per unit area of web 1, i.e., the area density of tuft 6, can be varied from 1 tuft per unit area, e.g., square centimeter to as high as 100 tufts per square centimeter. There can be at least 10, or at least 20 tufts 6 per square centimeter, depending on the end use. In general, the area density need not be uniform across the entire area of web 1 , but tufts 6 can be only in certain regions of web 1, such as in regions having predetermined shapes, such as lines, stripes, bands, circles, and the like.
- openings 4 of second precursor web 21 will have a distinct linear orientation and a longitudinal axis, which is oriented parallel to the longitudinal axis L of its corresponding tuft 6. Likewise, openings 4 will also have a transverse axis generally orthogonal to longitudinal axis in the MD-CD plane.
- tufts 6 can extend through openings 4 in second precursor web
- Openings 4 are formed by locally rupturing second precursor web 21 by the process described in detail below. Rupture may involve a simple splitting open of second precursor web 21, such that opening 4 remains a simple two-dimensional aperture. However, for some materials, such as polymer films, portions of second precursor web 21 can be deflected or urged out-of-plane (i.e., the plane of second precursor web 21) to form flap-like structures, referred to herein as flap, or flaps, 7. The form and structure of flaps 7 is highly dependent upon the material properties of second precursor web 21. Flaps 7 can have the general structure of one or more flaps, as shown in FIGS. 1 and 2. In other embodiments, flap 7 can have a more volcano-like structure, as if the tuft 6 is erupting from the flap 7. In other embodiments, flaps 7 can virtually completely cover tufts 6, such that they form a "cap" over tufts 6.
- flaps 7 may extend out of plane significantly, even being as high, so to speak, as the tufts 6 themselves. In this embodiment flaps 7 can cause the tufts 6 to be more resilient and less susceptible to flattening due to compressive or bending forces.
- the laminate web 1 comprises at least two layers (i.e., precursor webs 20 and 21), and both layers affect the tactile qualities and compression resistance of tufts 6.
- Tufts 6 preferably comprise looped fibers from both precursor webs. Therefore, tufts 6 can be, in a sense, either "punched through” second precursor web 21 or “pushed into” the tufts of second precursor web 21. In either case, it can be said that first and second precursor webs can be “locked” in place by frictional engagement with openings 4.
- the lateral width of opening 4 i.e., the dimension measured parallel to its transverse axis
- the frictional engagement of the tufts and openings provides for a laminate web structure having permanent tufting on one side that can be formed without adhesives or thermal bonding.
- a web 1 comprising a nonwoven first precursor web 20 can be characterized as being predominantly fibrous on both sides of web 1 with the fibers being contributed only by nonwoven first precursor web 20. Therefore, tufts 6 can be spaced sufficiently closely so as to effectively cover first side 3 of web 1. In such an embodiment, both sides of web 1 appear to be nonwoven, with a difference between the two sides 3 and 5 being a difference in surface texture.
- the invention can be described as a laminate material of two or more precursor webs, wherein both sides of the laminate web are substantially covered by fibers from only one of the precursor webs.
- one characteristic of tufts 6 can be the predominant directional alignment of the fibers 8 or 18.
- looped, aligned fibers 8 can be described as having a significant or major vector component parallel to the Z-CD plane and the looped fibers 8 have a substantially uniform alignment with respect to transverse axis T when viewed in plan view, such as in FIG. 4.
- looped fibers 8 fibers 8 that are integral with and begin and end in first precursor web 20 but extend outwardly in the Z-direction from first surface 13 of second precursor web 21.
- aligned with respect to looped fibers 8 of tufts 6 is meant that looped fibers 8 are all generally oriented such that, if viewed in plan view as in FIG. 4, each of the looped fibers 8 has a significant vector component parallel to the transverse axis T, and preferably a major vector component parallel to the transverse axis T.
- non-looped fibers 18 are integral with, but only begin in first precursor web 20 and have a free end extending outwardly in the Z-direction from first surface 13 of second precursor web 21.
- Loose fibers 18 can also have a generally uniform alignment described as having a significant or major vector component parallel to the Z-CD plane.
- the alignment is a characteristic of tufts 6 prior to any post-manufacture deformation due to winding onto a roll, or compression in use in an article of manufacture.
- a looped fiber 8 oriented at an angle of greater than 45 degrees from the longitudinal axis L when viewed in plan view, as in FIG. 4 has a significant vector component parallel to the transverse axis T.
- a looped fiber 8 oriented at an angle of greater than 60 degrees from longitudinal axis L when viewed in plan view, as in FIG. 4 has a major vector component parallel to the transverse axis T.
- at least 50%, more preferably at least 70%, and more preferably at least 90% of fibers 8 of tuft 6 have a significant, and more preferably, a major vector component parallel to transverse axis T.
- Fiber orientation can be determined by use of magnifying means if necessary, such as a microscope fitted with a suitable measurement scale.
- a straight-line approximation for both longitudinal axis L and the looped fibers 8 can be used for determining the angle of looped fibers 8 from longitudinal axis L.
- one fiber 8a is shown emphasized by a heavy line, and its linear approximation 8b is shown as a dashed line. This fiber makes an angle of approximately 80 degrees with the longitudinal axis (measured counterclockwise from L).
- the orientation of looped fibers 8 in the tufts 6 is to be contrasted with the fiber composition and orientation for first precursor web 20, which, for nonwoven webs is best described as having a substantially randomly-oriented fiber alignment.
- the orientation of the looped fibers 8 in tufts 6 could be the same as described above, but the fibers of first precursor web 20 would have the orientation associated with the particular weaving process used to make the web, e.g., a square weave pattern.
- the longitudinal axes L of tufts 6 are generally aligned in the MD. Tufts 6 and, therefore, longitudinal axes L, can, in principle, be aligned in any orientation with respect to the MD or CD. Therefore, in general, it can be said that for each tuft 6, the looped aligned fibers 8 are aligned generally orthogonal to the longitudinal axis L such that they have a significant vector component parallel to transverse axis T, and more preferably a major vector component parallel to transverse axis T.
- tufts 6 comprising predominantly looped, aligned fibers 8
- another characteristic of tufts 6 comprising predominantly looped, aligned fibers 8 can be their generally open structure characterized by open void area 10 defined interiorly of tufts 6, as shown in FIGS. 2 and 3.
- the void area 10 may have a shape that is wider or larger at the distal end 31 of the tuft 6 and narrower at the base 17 of the tuft 6. This is opposite to the shape of the tooth which is used to form the tuft 6.
- void area is not meant an area completely free of any fibers; the term is meant as a general description of the general appearance of tufts 6.
- a loose fiber 18 or a plurality of loose fibers 18 may be present in the void area 10.
- open void area is meant that the two longitudinal ends of tuft 6 are generally open and free of fibers, such that tuft 6 can form something like a "tunnel" structure in an uncompressed state, as shown in FIG. 3.
- the second side 5 of web 1 exhibits discontinuities 16 characterized by a generally linear indentation defined by formerly random fibers of the second surface 14 of first precursor web 20 having been urged directionally (i.e., in the "Z -direction" generally orthogonal to the MD-CD plane as shown in FIGS. 1 and 3) into tufts 6 by the teeth of the forming structure, described in detail below.
- the abrupt change of orientation exhibited by the previously randomly-oriented fibers of first precursor web 20 defines the discontinuity 16, which exhibits a linearity such that it can be described as having a longitudinal axis generally parallel to longitudinal axis L of the tuft 6.
- discontinuity 16 may not be as distinctly noticeable as tufts 6. For this reason, the discontinuities 16 on the second side 5 of web 1 can go unnoticed and may be generally undetected unless web 1 is closely inspected. As such, the second side 5 of web 1 can have the look and feel of an un-tufted first precursor web 20.
- web 1 can have the textured look and feel of terry cloth on first side 3, and a relatively smooth, soft look and feel on second side 5, both sides being comprised of fibers from the same nonwoven web, i.e., the first precursor web 20.
- discontinuities 16 can appear as apertures, and may be apertures through web 1 via the ends of the tunnel-like tufts 6.
- the fibers 8 or 18 of tuft 6 can originate and extend from either the first surface 12 or the second surface 14 of first precursor web 20.
- the fibers 8 or 18 of tuft 6 can also extend from the interior 28 of first precursor web 20.
- the fibers 8 or 18 of tufts 6 extend due to having been urged out of the generally two-dimensional plane of first precursor web 20 (i.e., urged in the "Z -direction" as shown in FIG. 3).
- the fibers 8 or 18 of the tufts 6 comprise fibers that are integral with and extend from the fibers of the first precursor web 20.
- web 1 can be described as being a laminate web formed by selective mechanical deformation of at least a first and second precursor webs, at least the first precursor web being a nonwoven web, the laminate web having a first side, the first side comprising the second precursor web and a plurality of discrete tufts, each of the discrete tufts comprising a plurality of tufted fibers being integral extensions of the first precursor web and extending through the second precursor web; and a second side, the second side comprising the first precursor web.
- the extension of fibers 8 or 18 can be accompanied by a general reduction in fiber cross sectional dimension (e.g., diameter for round fibers) due to plastic deformation of the fibers and Poisson's ratio effects. Therefore, the aligned looped fibers 8 of tuft 6 can have an average fiber diameter less than the average fiber diameter of the fibers of first precursor web 20. It is believed that this reduction in fiber diameter contributes to the perceived softness of the first side 3 of web 1, a softness that can be comparable to cotton terry cloth, depending on the material properties of the first precursor web 20. It has been found that the reduction in fiber cross-sectional dimension is greatest intermediate the base 17 and the distal portion 31 of tuft 6. This is believed to be due to the preferred method of making, as disclosed more fully below.
- portions of fibers at the base 17 and distal portion 31 of tufts 6 are adjacent the tip of teeth 110 of roll 104, described more fully below, and are frictionally locked and immobile during processing.
- the intermediate portions of tufts 6 are more free to stretch, or elongate, and accordingly, can experience a corresponding fiber cross sectional dimension reduction.
- Some fibers of first precursor web 20 may laterally squeeze the base 17 of the tuft 6.
- the base 17 of the tuft 6 may even be closed (if the fibers from the tuft 6 are close enough together to touch) or may remain open. Generally, any opening at the base 17 is narrow. The closing or narrowing or squeezing of other fibers at the base 17 can help to stabilize the tufts 6 and second precursor web 21.
- the apparatus 100 comprises a pair of intermeshing rolls 102 and 104, each rotating about an axis A, the axes A being parallel in the same plane.
- Roll 102 comprises a plurality of ridges 106 and corresponding grooves 108 which extend unbroken about the entire circumference of roll 102.
- Roll 104 is similar to roll 102, but rather than having ridges that extend unbroken about the entire circumference, roll 104 comprises a plurality of rows of circumferentially-extending ridges that have been modified to be rows of circumferentially- spaced teeth 110 that extend in spaced relationship about at least a portion of roll 104.
- rolls 102 and 104 intermesh such that the ridges 106 of roll 102 extend into the grooves 112 of roll 104 and the teeth 110 of roll 104 extend into the grooves 108 of roll 102.
- the intermeshing is shown in greater detail in the cross sectional representation of FIG. 6, discussed below.
- Both or either of rolls 102 and 104 can be heated by means known in the art such as by using hot oil filled rollers or electrically-heated rollers.
- the apparatus 100 is shown in a preferred configuration having one patterned roll, e.g., roll 104, and one non-patterned grooved roll 102.
- Such an apparatus can produce webs with tufts 6 protruding from both sides of the web 1.
- An apparatus could also be designed to have teeth that pointing in opposite directions on the same roll. This would result in a web with tufts 6 being produced on both sides of the web.
- FIG. 5 The method of making a web 1 of the present invention in a commercially viable continuous process is depicted in FIG. 5.
- Web 1 is made by mechanically deforming precursor webs, such as first and second precursor webs, 20 and 21 that can each be described as generally planar and two dimensional prior to processing by the apparatus shown in FIG. 5.
- precursor webs such as first and second precursor webs, 20 and 21 that can each be described as generally planar and two dimensional prior to processing by the apparatus shown in FIG. 5.
- planar and two dimensional is meant simply that the webs start the process in a generally flat condition relative to the finished web 1 that has distinct, out-of-plane, Z-direction three-dimensionality due to the formation of tufts 6.
- “Planar” and “two-dimensional” are not meant to imply any particular flatness, smoothness or dimensionality.
- the process and apparatus of the present invention is similar in many respects to a process described in U.S. Pat.
- a web 1 of the present invention can have tufts 6 of loose fiber ends 18 and/or "tunnel-like" tufts 6 of looped, aligned fibers 8 extending through and away from the surface 13 of a first side 3, unlike the "tent-like" rib-like elements of SELF webs which each have continuous side walls associated therewith, i.e., a continuous "transition zone,” and which do not exhibit interpenetration of one layer through another layer.
- Precursor webs 20 and 21 are provided either directly from their respective web making processes or indirectly from supply rolls (neither shown) and moved in the machine direction to the nip 116 of counter-rotating intermeshing rolls 102 and 104.
- the precursor webs are preferably held in a sufficient web tension so as to enter the nip 16 in a generally flattened condition by means well known in the art of web handling.
- teeth 110 "push" or "punch” fibers of first precursor web 20 through second precursor web 21.
- first and second precursor webs 20, 21 the portions of the fibers of the precursor webs that are oriented predominantly in the CD across teeth 110 are urged by the teeth 110 out of the plane of first precursor web 20.
- Fibers can be urged out of plane due to fiber mobility, or they can be urged out of plane by being stretched and/or plastically deformed in the Z-direction.
- Portions of first precursor web 20 urged out of plane by teeth 110 can also push fibers of second precursor web 21 of the plane, or they can push through second precursor web 21, (if it has relatively lower extensibility), thereby resulting in formation of tufts 6 on first side 3 of web 1.
- Fibers of precursor webs 20 and/or 21 that are predominantly oriented generally parallel to the longitudinal axis L, i.e., in the MD of precursor web 20 as shown in FIG. 1, are simply spread apart by teeth 110 and remain substantially in their original, randomly- oriented condition. This is why the looped fibers 8 can exhibit the unique fiber orientation in embodiments such as the one shown in FIGS. 1-4, which is a high percentage of fibers of each tuft 6 having a significant or major vector component parallel to the transverse axis T of tuft 6.
- the precursor webs 20, 21 can possess differing material properties with respect to the ability of the precursor webs to elongate before failure, e.g., failure due to tensile stresses.
- a nonwoven first precursor web 20 can have greater fiber mobility and/or greater fiber elongation characteristics relative to second precursor web 21, such that the fibers thereof can move or stretch sufficiently to form tufts 6 while the second precursor web 21 ruptures, i.e., does not stretch to the extent necessary to form tufts.
- both precursor webs have sufficient elongation such that fibers thereof can move or stretch sufficiently to form tufts 6.
- the degree to which the fibers of nonwoven precursor webs are able to extend out of plane without plastic deformation can depend upon the degree of inter-fiber bonding of the precursor web. For example, if the fibers of a nonwoven precursor web are only very loosely entangled to each other, they will be more able to slip by each other (i.e., to move relative to adjacent fibers by reptation) and therefore be more easily extended out of plane to form tufts. On the other hand, fibers of a nonwoven precursor web that are more strongly bonded, for example by high levels of thermal point bonding, hydroentanglement, or the like, will more likely require greater degrees of plastic deformation in extended out-of-plane tufts.
- first precursor web 20 can be a nonwoven web having relatively low inter-fiber bonding
- second precursor web 21 can be a nonwoven web having relatively high inter-fiber bonding, such that the fibers of first precursor web can extend out of plane, while the fibers of second precursor web 21 cannot.
- first precursor web 20 can be a nonwoven web having relatively low inter-fiber bonding
- second precursor web 21 can be a nonwoven web having relatively high inter-fiber bonding, such that the fibers of first precursor web can extend out of plane, while the fibers of second precursor web 21 cannot.
- the fibers therein tend to extend, while the fibers of second precursor web, unable to extend, tend to break.
- the number, spacing, and size of tufts 6 can be varied by changing the number, spacing, and size of teeth 110 and making corresponding dimensional changes as necessary to roll 104 and/or roll 102.
- This variation, together with the variation possible in precursor webs 20, 21 permits many varied webs 1 to be made for many purposes.
- web 1 made from a first precursor web 20 comprising a relatively high basis weight woven fabric having MD and CD woven plastically-extensible threads and a second precursor web 21 comprising relatively high basis weight, relatively low-extensible synthetic polymer nonwoven material could be made into a strong, porous ground covering, such as an erosion control device useful for reducing sloping path deterioration and enabling growth of indigenous vegetation in unstable soil.
- FIG. 6 shows in cross section a portion of the intermeshing rolls 102 and 104 and ridges 106 and teeth 110.
- teeth 110 have a tooth height TH (note that TH can also be applied to ridge height; in a preferred embodiment tooth height and ridge height are equal), and a tooth-to- tooth spacing (or ridge-to-ridge spacing) referred to as the pitch P.
- depth of engagement E is a measure of the level of intermeshing of rolls 102 and 104 and is measured from tip of ridge 106 to tip of tooth 110.
- the depth of engagement E, tooth height TH, and pitch P can be varied as desired depending on the properties of precursor webs 20, 21 and the desired characteristics of web 1.
- FIG. 7 shows one embodiment of a roll 104 having a plurality of teeth 110 useful for making a terry cloth-like web 1 from a nonwoven first precursor web 20 having a basis weight of between about 60 gsm and 100 gsm, preferably about 80 gsm and a polyolefinic film (e.g., polyethylene or polypropylene) second precursor web 21 having a density of about 0.91-0.94 and a basis weight of about 20 gsm.
- a polyolefinic film e.g., polyethylene or polypropylene
- teeth 110 have a uniform circumferential length dimension TL measured generally from the leading edge LE to the trailing edge TE at the tooth tip 111 of about 1.25 mm and are uniformly spaced from one another circumferentially by a distance TD of about 1.5 mm.
- teeth 110 of roll 104 can have a length TL ranging from about 0.5 mm to about 3 mm and a spacing TD from about 0.5 mm to about 3 mm, a tooth height TH ranging from about 0.5 mm to about 5 mm, and a pitch P between about 1 mm (0.040 inches) and about 5 mm (0.200 inches).
- Depth of engagement E can be from about 0.5 mm to about 5 mm (up to a maximum equal to tooth height TH).
- each tooth 110 has a tip 111, a leading edge LE and a trailing edge TE.
- the tooth tip 111 is elongated and has a generally longitudinal orientation, corresponding to the longitudinal axes L of tufts 6 and discontinuities 16. It is believed that to get the tufted, looped tufts 6 of the web 1 that can be described as being terry cloth-like, the LE and TE should be very nearly orthogonal to the local peripheral surface 120 of roll 104.
- the transition from the tip 111 and LE or TE should be a sharp angle, such as a right angle, having a sufficiently small radius of curvature such that teeth 110 push through second precursor web 21 at the LE and TE.
- a sharp angle such as a right angle
- having relatively sharply angled tip transitions between the tip of tooth 110 and the LE and TE permits the teeth 110 to punch through precursor webs 20, 21 "cleanly", that is, locally and distinctly, so that the first side 3 of the resulting web 1 can be described as "tufted” rather than “deformed.”
- the web 1 is not imparted with any particular elasticity, beyond what the precursor webs 20 and 21 may have possessed originally.
- the fibers of the precursor webs have a highly curvilinear shape, e.g., curled fibers
- the resultant tufts 6 will have more looped fibers 8 and less broken fibers 18 as compared to more linear fiber conformations. It is believed that such fiber conformations have a lesser chance of bridging between two adjacent teeth, and, as a result they are less prone to be stretched beyond their breaking point, and thus have a greater chance of forming complete loop structures.
- curvilinear-shaped fibers can be made by using eccentric bicomponent fibers, or side-by-side bicomponent fibers, such as bicomponent fibers consisting of polyethylene and nylon.
- first and second precursor webs are nonwoven webs in which there are minimal fiber-to-fiber bonds.
- the precursor web can be a nonwoven web having a pattern of discrete thermal point bonds, as is commonly known in the art for nonwoven webs.
- utilizing fibers having relatively high diameters, and/or relatively high extension to break, and/or relatively high fiber mobility results in better and more distinctly formed tufts 6.
- web 1 is disclosed in preferred embodiments as a two layer web made from two precursor webs, it is not necessary that it be limited to two layers.
- a three-layer or more laminate can be made from three precursor webs, as long as one of the precursor webs can extend and push through openings in another layer to form tufts.
- web 1 could comprise the top sheet, secondary topsheet, and core of a feminine hygiene product.
- adhesive or other bonding means be utilized to make laminate web 1.
- the constituent layers of web 1 can be held in a face-to-face laminated relationship by virtue of the "locking" effect of the tufts 6 that extend through openings 4 in second precursor web 21.
- adhesives or thermal bonding or other bonding means it may be desirable to use adhesives or thermal bonding or other bonding means, depending on the end use application of web 1.
- a web 1 comprising bicomponent fiber nonwoven webs can be through-air bonded after formation of tufts 6 to provide for layer-to-layer adhesion for greater peel strength.
- adhesive for example, in some embodiments adhesive, chemical bonding, resin or powder bonding, or thermal bonding between layers can be selectively applied to certain regions or all of the precursor webs.
- adhesive can be applied in a continuous manner, such as by slot coating, or in a discontinuous manner, such as by spraying, extruding, and the like.
- Discontinuous application of adhesive can be in the form of stripes, bands, droplets, and the like.
- each precursor web can have different material properties, thereby providing web 1 with beneficial properties when used as a topsheet in a disposable absorbent article such as a sanitary napkin.
- web 1 comprising two (or more) precursor webs, e.g., first and second precursor webs, can have beneficial fluid handling properties.
- first precursor web 20 can be comprised of relatively hydrophilic fibers.
- Second precursor web 21 can be comprised of relatively hydrophobic fibers. The tufts 6 of such a web could form a topsheet having a relatively hydrophobic body-facing surface, with hydrophilic tufts to pull fluid away from the body and through the topsheet.
- Fluid deposited upon the upper, relatively hydrophilic tufts can be quickly transported away from the relatively hydrophobic layer to the portion of the article underlying the second precursor web layer (e.g., the absorbent core).
- the second precursor web layer e.g., the absorbent core.
- FIG. 10 shows in partial cut away plan view a sanitary napkin having as one of its components a web 1 of the present invention.
- sanitary napkin 200 comprises a backsheet 202, a topsheet 206 and an absorbent core 204 disposed between the topsheet 206 and backsheet 202 which can be joined about a the periphery 210.
- Sanitary napkin 1 can have side extensions, commonly referred to as "wings" 208 designed to wrap the sides of the crotch region of the panties of the user of sanitary napkin 1.
- wings commonly referred to as "wings" 208 designed to wrap the sides of the crotch region of the panties of the user of sanitary napkin 1.
- Sanitary napkins, including topsheets for use as the body facing surface thereof, are well known in the art and need no detailed description of various alternative and optional designs.
- web 1 can also be used in a diaper or adult incontinence product or other disposable hygiene products. However, it is noted that web 1 can be used as, or as a component of, one or more of a backsheet, core material, topsheet, secondary topsheet, or wing material. Web 1 can also have multiple layers and comprise a topsheet, secondary topsheet, core, backsheet, or any number of layers.
- Web 1 is especially useful as a topsheet 206 of sanitary napkin 200.
- Web 1 is particularly beneficial as a topsheet 206 for sanitary napkins due to the combination of excellent fluid acquisition and compression resistance for the prevention of rewet to the body-facing surface of topsheet 206 when in use.
- Rewet can be a result of at least two causes: (1) squeezing out of the absorbed fluid due to pressure on the sanitary napkin 200; and/or (2) wetness entrapped within or on the topsheet 206.
- both properties, fluid acquisition and compression resistance, are maximized and rewet is minimized.
- a topsheet will exhibit high rates of fluid acquisition, and low levels of rewet.
- topsheet 206 can have applied thereto a lotion composition.
- the lotion composition can be any of known lotions, such as lotions comprising petrolatum, which can provide a skin benefit to the user.
- the lotion also provides a clean body benefit to the user. That is, the lotion preferably renders menses less susceptible to sticking to the body, including hair and skin.
- the lotion is hydrophobic, and renders hair and skin hydrophobic.
- Lotion can be applied in any manner known in the art for applying lotions to nonwoven webs. Lotion can be applied to the tips (i.e., the distal ends) of tufts 6. It has been found that applying lotion to the tips enables efficient transfer to the skin of the wearer. Without being bound by theory, it is believed that the tufts act as little brushes to wipe the lotion onto the body during motion, such as walking.
- the lotion of the present invention can include those disclosed in US 5,968,025; US 6,627,787; US 6,498,284; US 6,426,444; US 6,586,652; US 3,489,148; US 6,503,526; 6,287,581; US 6,475,197; US 6,506,394; US 6,503,524; US 6,626,961; WO 2000038747; or EP-A 927,050.
- the topsheet 206 (or portions thereof) can be treated with other materials or compositions to render it sufficiently hydrophobic.
- the topsheet can be treated with silicone treatments, low surface energy treatments, fluorinated hydrocarbon treatments.
- relatively hydrophobic means a material or composition having a contact angle with water of at least about 70 degrees, preferably at least about 90 degrees.
- low surface energy means less than about 55 dynes per square centimeter, preferably less than about 26 dynes per square centimeter, and more preferably from about 30 to about 50 dynes per square centimeter.
- web 1 is used as a topsheet 206 in conjunction with a high capacity and highly absorbent core 204.
- a preferred absorbent core is an airlaid core of the type disclosed in US 5,445,777; or US 5,607,414.
- absorbent core 204 is the type generally referred to as HIPE foams, such as those disclosed in US 5,550,167; US, 5,387,207; US 5,352,711; and 5,331,015.
- absorbent core 204 has a capacity after desorption at 30 cm of less than about 10% of its free absorbent capacity; a capillary absorption pressure of from about 3 to about 20 cm; a capillary desorption pressure of from about 8 to about 25 cm; a resistance to compression deflection of from about 5 to about 85% when measured under a confining pressure of 0.74 psi; and a free absorbent capacity of from about 4 to 125 grams/gram.
- Each of these parameters can be determined as set forth in US 5,550,167. issued August 27, 1996 to DesMarais.
- One advantage of utilizing the airlaid or HIPE foam cores as disclosed is that the absorbent core can be made very thin.
- an absorbent core of the present invention can have an average caliper (thickness) of less than about 20 mm, preferably less than about 10 mm, and the thickness can be less than about 5 mm.
- Table 1 shown below shows compression data for webs of the present invention, as well as comparison webs.
- Sample Nos. 1-3, 5 and 7 are comparison samples and Sample Nos. 4, 6, and 8-13 are webs of the present invention.
- Sample 1 is a formed polyethylene film comparable to DRI-WEAVE® topsheets used on ALWAYS® sanitary napkins, available from Tredegar Film Products, Terre Haute, IN.
- Sample 2 is a formed polyethylene film made by Tredegar Film Products, Terre Haute, IN, according to the teachings of US 4,629,643 issued to Curro et al. on Dec. 16, 1986.
- Sample 3 is a 30 gsm spunbond web of 50/50 PE/PP bicomponent fibers available from BBA, Simpsonville, SC.
- Sample 4 is a web of the present invention made from the web of Sample 3 processed according to the process described herein.
- Sample 5 is a carded nonwoven web comprising 50% 6 denier (dpf) PE/PP bicomponent fibers and 50% 6 denier PET fibers, available from BBA, Simpsonville, SC. Sample 6 is made by the process as described herein from the web of Sample 5.
- dpf 6 denier PE/PP bicomponent fibers
- 6 denier PET fibers available from BBA, Simpsonville, SC.
- Samples 4 and 6 are made with one precursor web by the process described herein.
- Samples 8-13 are made according to the present invention using two precursor webs as described herein, and where both precursor webs contribute fibers to the tufts, in a nested configuration, so to speak.
- the fibers of the second precursor web are not "punched through” but rather are formed into a tuft along with fibers of the first precursor web, the two webs contributing fibers to the tufts.
- Sample 8 is made by the process as described herein from the two layer laminate of fibrous nonwoven web of Sample 7.
- the first layer of Sample 7 comprises a 30 gsm web of 50/50 PE/PP bicomponent fibers and the second layer is a 45 gsm web comprising 50% 6 denier 50/50 PE/PP bicomponent fibers and 50% 9 denier PP fibers. Both webs are available from BBA, Simpsonville, SC.
- Sample 9 is made by the process as described herein from a two layer laminate wherein the first and second layers comprise a 30 gsm web of PE/PP bicomponent fibers and the second layer is also surfactant treated to impart a relatively higher level of hydrophilicity, as is known in the art.
- the 30 gsm webs are available from BBA, Simpsonville, SC.
- Sample 10 is made by the process as described herein from a two layer laminate of fibrous nonwoven webs wherein the first layer comprises a 30 gsm web of PE/PP bicomponent fibers and the second layer is a 45 gsm web comprising 50% 6 denier PE/PP bicomponent fibers and 50% 6 denier PET fibers. Both webs are available from BBA, Simpsonville, SC.
- Sample 11 is made by the process as described herein from a two layer laminate of fibrous nonwoven webs wherein the first layer comprises a 30 gsm web of PE/PP bicomponent fibers from Pegas, Czech Republic, and the second layer is a 45 gsm web comprising 50% 6 denier PE/PP bicomponent fibers and 50% 6 denier PET fibers, available from BBA, Simpsonville, SC.
- Samples 12 and 13 are each made by the process as described herein from a two layer laminate of fibrous nonwoven webs wherein the first layer comprises a 30 gsm web of 50/50 PE/PP bicomponent fibers and the second layer is a 45 gsm web comprising 50% 6 denier 50/50 PE/PP bicomponent fibers and 50% 6 denier PET fibers. Both precursor webs are available from BBA, Simpsonville, SC.
- Each of the Samples of the present invention shown in Table 1 were processed according to the present invention through the nip of intermeshing rolls as described above, with a pitch P of 1.5 mm (about 0.060 inch), a tooth height TH of about 3.7 mm (about 0.145 inch), a tooth distance TD of 1.6 mm (about 0.063 inches) and a tooth length TL of 1.25 mm (about 0.050 inch).
- the depth of engagement DOE and line speed are shown in Table 1 for each sample of the present invention.
- webs of the present invention have excellent density and specific volume properties under loads simulating loads experienced in the wearing of a sanitary napkin.
- 0.004 psi can correspond to a pressure experienced while standing
- 0.23 psi can correspond to a pressure when sitting on a soft surface
- 0.75 se can correspond to sitting on a hard surface.
- Void volume and specific volume can be determined by the following methods: VOID VOLUME
- Void volume under compression was calculated at 0.004, 0.23, and 0.75 pounds per square inch pressure using an MTS tensile tester.
- the tensile tester measured the resisting force as a material was compressed between a movable platen and a fixed base. The material was compressed at a constant rate to a force of 1000 g. Force and platen position were recorded.
- Void volume for a given platen position is calculated using the equation:
- VV void volume of material in cubic centimeters per gram
- x o initial platen position from the base in millimeters
- x platen position from initial position in millimeters
- a 171 area of material in square centimeters
- M mass of material in grams
- p fiber fiber density in grams per cubic centimeter
- the web fiber density is the weight average of each individual fiber density:
- Pfiber, total ( w t% fiberl) (Pfiberl) + (wt% fibert) (Pfibert) +
- wt% weight percent of the fiber type in the web or:
- Suitable equipment for this test could include a tensile tester (MTS model Alliance RT/ 1 with Test Works software and 50 N load cell).
- the tester must have a fixed base larger in size than the platen.
- the zero height between the platen and base is set by bringing the platen down until the first substantial force is measured, the platen is then backed up one increment, and the cross head position is zeroed.
- the sample gage length for each sample is set by raising the platen above the fixed base to a distance greater than the initial thickness of the material. From this position the platen is lowered until a force of 1 gf is applied to the sample. This position from the zero height is recorded as the initial platen position (x 0 ) and the cross head position is re-zeroed.
- P web density in grams per cubic centimeter of the nonwoven web
- Xo initial platen position from the base in millimeters
- x platen position from initial position in millimeters
- BW mass of the material in grams per square meter
- Suitable equipment for this test could include a tensile tester (MTS model Alliance RT/1 with Test Works software and 50 N load cell).
- the tester must have a fixed base larger in size than the platen.
- the zero height between the platen and base is set by bringing the platen down until the first substantial force is measured, the platen is then backed up one increment, and the cross head position is zeroed.
- the sample gage length for each sample is set by raising the platen above the fixed base to a distance greater than the initial thickness of the material. From this position the platen is lowered until a force of 1 gf is applied to the sample. This position from the zero height is recorded as the initial platen position (x 0 ) and the cross head position is re-zeroed.
- topsheet 206 can additionally be coated or treated with medicaments, cleaning fluids, anti-bacterial solutions, emulsions, fragrances, or surfactants.
- apparatus 100 can be configured to only form tufts 6 on a portion of the web 1, or to form varying sizes or area densities of tufts 6.
- Another advantage of the process described to produce the webs of the present invention is that the webs can be produced in-line with other web production equipment or in-line with disposable absorbent article production equipment. Additionally, there may be other solid state formation processes that can be used either prior to or after the process of the present invention.
- a web could be processed according to the present invention and then apertured with a stretching process, such as one described in US Patent No. 5,658,639 to Curro et al.
- a material could be made into a composite through a variety of processes, such as one described in US Publication No. 2003/028,165Al to Curro et al. or ring rolled, for example as in US Patent No. 5,167,897 to Weber et al. and then processed according to the present invention.
- the resulting webs can thus exhibit the combined benefits of these multiple material modifications.
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Sanitary Thin Papers (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005265257A AU2005265257B2 (en) | 2004-06-21 | 2005-06-21 | Compression resistant nonwovens |
KR1020067026862A KR100801775B1 (ko) | 2004-06-21 | 2005-06-21 | 내압축성 부직포 |
EP05760396A EP1765240A1 (en) | 2004-06-21 | 2005-06-21 | Compression resistant nonwovens |
CA2570480A CA2570480C (en) | 2004-06-21 | 2005-06-21 | Compression resistant nonwovens |
BRPI0512053-5A BRPI0512053B1 (pt) | 2004-06-21 | 2005-06-21 | Hygienic absorbent of non-fabrics resistant to compression |
JP2007518173A JP4949236B2 (ja) | 2004-06-21 | 2005-06-21 | 圧縮抵抗不織布 |
CN2005800200859A CN1968664B (zh) | 2004-06-21 | 2005-06-21 | 抗压非织造材料 |
IL179861A IL179861A (en) | 2004-06-21 | 2006-12-05 | Compression-resistant nonwoven fabrics |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US58154304P | 2004-06-21 | 2004-06-21 | |
US60/581,543 | 2004-06-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006009995A1 true WO2006009995A1 (en) | 2006-01-26 |
Family
ID=34972449
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/021751 WO2006009995A1 (en) | 2004-06-21 | 2005-06-21 | Compression resistant nonwovens |
Country Status (12)
Country | Link |
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EP (1) | EP1765240A1 (zh) |
JP (1) | JP4949236B2 (zh) |
KR (1) | KR100801775B1 (zh) |
CN (1) | CN1968664B (zh) |
AR (1) | AR050671A1 (zh) |
AU (1) | AU2005265257B2 (zh) |
BR (1) | BRPI0512053B1 (zh) |
CA (1) | CA2570480C (zh) |
IL (1) | IL179861A (zh) |
SG (1) | SG153839A1 (zh) |
WO (1) | WO2006009995A1 (zh) |
ZA (1) | ZA200610175B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010517709A (ja) * | 2007-02-23 | 2010-05-27 | ザ プロクター アンド ギャンブル カンパニー | 印刷されたウェブ及び製造方法 |
CN102665633A (zh) * | 2009-11-24 | 2012-09-12 | 花王株式会社 | 吸收性物品 |
CN107106381A (zh) * | 2015-01-14 | 2017-08-29 | Sca卫生用品公司 | 包括非织造材料的吸收制品 |
US9872801B2 (en) | 2008-08-08 | 2018-01-23 | The Procter & Gamble Company | Zoned topsheet |
US11857397B2 (en) | 2017-11-06 | 2024-01-02 | The Procter And Gamble Company | Absorbent article with conforming features |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2617855T3 (es) * | 2004-06-21 | 2017-06-20 | The Procter & Gamble Company | Articulo absorbente con lámina superior que contiene loción |
US7993317B2 (en) * | 2008-08-08 | 2011-08-09 | The Procter & Gamble Company | Zoned topsheet |
JP5909349B2 (ja) * | 2010-12-20 | 2016-04-26 | 花王株式会社 | 吸収性物品 |
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US4433018A (en) * | 1980-12-23 | 1984-02-21 | Breveteam S.A. | Method of manufacturing of textile flat structure and textile web manufactured thereby |
WO2004058117A1 (en) * | 2002-12-20 | 2004-07-15 | The Procter & Gamble Company | Tufted fibrous web |
WO2004058118A1 (en) * | 2002-12-20 | 2004-07-15 | The Procter & Gamble Company | Tufted laminate web |
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EP0409535B1 (en) * | 1989-07-18 | 1994-03-23 | Mitsui Petrochemical Industries, Ltd. | A nonwoven fabric and a method of manufacturing the same |
FR2713083B1 (fr) * | 1993-12-03 | 1996-01-19 | Kaysersberg Sa | Article d'hygiène féminine muni de capteurs du flux menstruel. |
US6486379B1 (en) * | 1999-10-01 | 2002-11-26 | Kimberly-Clark Worldwide, Inc. | Absorbent article with central pledget and deformation control |
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JP2002200112A (ja) * | 2000-12-28 | 2002-07-16 | Kao Corp | 吸収性物品 |
JP3877682B2 (ja) * | 2002-03-22 | 2007-02-07 | 花王株式会社 | 吸収性物品用の表面シート |
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BR0317609B1 (pt) * | 2002-12-20 | 2013-10-08 | Textura laminada com tufos |
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2005
- 2005-06-21 CN CN2005800200859A patent/CN1968664B/zh not_active Expired - Fee Related
- 2005-06-21 WO PCT/US2005/021751 patent/WO2006009995A1/en not_active Application Discontinuation
- 2005-06-21 BR BRPI0512053-5A patent/BRPI0512053B1/pt not_active IP Right Cessation
- 2005-06-21 JP JP2007518173A patent/JP4949236B2/ja not_active Expired - Fee Related
- 2005-06-21 KR KR1020067026862A patent/KR100801775B1/ko not_active IP Right Cessation
- 2005-06-21 CA CA2570480A patent/CA2570480C/en not_active Expired - Fee Related
- 2005-06-21 SG SG200904204-5A patent/SG153839A1/en unknown
- 2005-06-21 AR ARP050102557A patent/AR050671A1/es unknown
- 2005-06-21 AU AU2005265257A patent/AU2005265257B2/en not_active Ceased
- 2005-06-21 EP EP05760396A patent/EP1765240A1/en not_active Withdrawn
-
2006
- 2006-12-05 IL IL179861A patent/IL179861A/en not_active IP Right Cessation
- 2006-12-05 ZA ZA200610175A patent/ZA200610175B/xx unknown
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US4035881A (en) * | 1974-03-12 | 1977-07-19 | Josef Zocher | Method and apparatus for producing non-woven textile product |
US4433018A (en) * | 1980-12-23 | 1984-02-21 | Breveteam S.A. | Method of manufacturing of textile flat structure and textile web manufactured thereby |
WO2004058117A1 (en) * | 2002-12-20 | 2004-07-15 | The Procter & Gamble Company | Tufted fibrous web |
WO2004058118A1 (en) * | 2002-12-20 | 2004-07-15 | The Procter & Gamble Company | Tufted laminate web |
Cited By (11)
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JP2010517709A (ja) * | 2007-02-23 | 2010-05-27 | ザ プロクター アンド ギャンブル カンパニー | 印刷されたウェブ及び製造方法 |
US9872801B2 (en) | 2008-08-08 | 2018-01-23 | The Procter & Gamble Company | Zoned topsheet |
US10729598B2 (en) | 2008-08-08 | 2020-08-04 | The Procter & Gamble Company | Zoned topsheet |
CN102665633A (zh) * | 2009-11-24 | 2012-09-12 | 花王株式会社 | 吸收性物品 |
EP2505173A1 (en) * | 2009-11-24 | 2012-10-03 | Kao Corporation | Absorbent article |
EP2505173A4 (en) * | 2009-11-24 | 2014-01-08 | Kao Corp | ABSORBENT ARTICLE |
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CN107106381A (zh) * | 2015-01-14 | 2017-08-29 | Sca卫生用品公司 | 包括非织造材料的吸收制品 |
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US11672709B2 (en) | 2015-01-14 | 2023-06-13 | Essity Hygiene And Health Aktiebolag | Absorbent product comprising a nonwoven material |
US11857397B2 (en) | 2017-11-06 | 2024-01-02 | The Procter And Gamble Company | Absorbent article with conforming features |
Also Published As
Publication number | Publication date |
---|---|
JP4949236B2 (ja) | 2012-06-06 |
IL179861A (en) | 2013-09-30 |
CA2570480C (en) | 2011-08-02 |
IL179861A0 (en) | 2007-05-15 |
AU2005265257B2 (en) | 2009-07-16 |
CN1968664B (zh) | 2010-09-29 |
KR20070032703A (ko) | 2007-03-22 |
CN1968664A (zh) | 2007-05-23 |
BRPI0512053B1 (pt) | 2017-12-05 |
EP1765240A1 (en) | 2007-03-28 |
CA2570480A1 (en) | 2006-01-26 |
JP2008503322A (ja) | 2008-02-07 |
AR050671A1 (es) | 2006-11-15 |
SG153839A1 (en) | 2009-07-29 |
KR100801775B1 (ko) | 2008-02-05 |
AU2005265257A1 (en) | 2006-01-26 |
BRPI0512053A (pt) | 2008-02-06 |
ZA200610175B (en) | 2008-08-27 |
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