WO2006008336A1 - Unite et procede de couchage par voile - Google Patents
Unite et procede de couchage par voile Download PDFInfo
- Publication number
- WO2006008336A1 WO2006008336A1 PCT/FI2005/000332 FI2005000332W WO2006008336A1 WO 2006008336 A1 WO2006008336 A1 WO 2006008336A1 FI 2005000332 W FI2005000332 W FI 2005000332W WO 2006008336 A1 WO2006008336 A1 WO 2006008336A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- web
- agent
- curtain
- feed elements
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/46—Pouring or allowing the fluid to flow in a continuous stream on to the surface, the entire stream being carried away by the paper
- D21H23/48—Curtain coaters
Definitions
- the present invention relates to a curtain-coating unit, according to the preamble of Claim 1 , for coating a material web, which is arranged to move, with a coating agent.
- a curtain-coating unit is this kind, the coating agent is fed to the surface of the material web in a curtain-like flow.
- the invention also relates to a curtain-coating method for coating a moving material web.
- a curtain-coating unit includes an application beam arranged above the web, in which there is a narrow nozzle gap or a sloping feed plane fitted over the width of the web, from which the coating agent is fed to the surface of the web as a continuous curtain over the width of the web.
- the web which moves at a speed many times greater than that of the downward-flowing coating-agent curtain, sweeps the coating-agent curtain into a thin film at the point of contact. Thus the final coating-agent layer is formed on the surface of the web.
- the web can be feed simultaneously with several coating layers on top of each other, if the application beam is equipped with parallel nozzle gaps, from which the coating agent is fed to a sloping feed plane, so that the flows of coating agent fed from the different nozzle gaps come on top of each other before they flow onto the web.
- the boundary-layer air removal means are situated, in the direction of travel of the web, before the point at which the coating-agent curtain falls onto the web.
- the boundary-layer air removal means typically consist of a suction surface arranged against the web, through which the air layer on the surface of the material web is sucked off, as well as an air doctor arranged between the suction surface and the point of contact of the coating agent.
- curtain coating offers several advantages over traditional blade coating methods. In curtain coating no rapidly wearing parts, such as doctor blades or rods, are used. In addition, curtain coating places less strain on the web, thus reducing the number of web breaks occurring at the coating station. In curtain coating, the penetration of the web by the coating agent is small, which permits good coating coverage. The small coating agent penetration also reduces wetting of the base web during the coating process and thus improves the strength of the web as coating proceeds. In addition, with the aid of curtain coating it is possible to achieve a situation, in which the feed of the coating agent directly determines the amount of coating, without a return or bypass circulations, which simplifies the construction of the coating station and facilitates its operation.
- the amount of coating agent being fed from the application beam may vary greatly. Thus areas form on the web, in which there is a large amount of coating agent.
- the dryers after coating may not then be able to dry the coating layer sufficiently, in which case wet coating agent will adhere to the structures following the coater. Therefore, when coating starts, the coating agent is prevented from reaching the surface of the web, by bringing a so-called starting trough, into which the coating agent being fed from the application beam can run, between the application beam and the web.
- the coating agent is led from the application beam to the starting trough until the flow is as desired. After this, the starting trough is moved away from under the coating-agent curtain, so that the coating agent can reach the surface of the web.
- the coating can be started by moving the application beam in the direction of travel of the web away form the application point to a location over a starting trough fixed in place and the coating-agent flow is regulated as desired, after which the application beam is moved back to the coating position.
- the magnitude of this turning can vary if the properties of the coating agent and/or the amount being fed are changed. This may weaken the coating result, because the coating-agent curtain may strike the boundary-layer air remover, or the distance between the boundary-layer air remover and the point of contact of the curtain may grow too large.
- the invention is intended to create an improved curtain-coating unit.
- the invention is based on the application beam of the curtain-coating unit being able to be tilted, i.e. rotated around an axis transverse to the web, during coating. With the aid of the rotating movement, the location, in the direction of travel of the web, of the curtain of coating agent falling from the application beam can be altered during coating, for example, when coating commences.
- the curtain-coating unit according to the invention is characterized by what is stated in the characterizing portion of Claim 1.
- the curtain-coating method according to the invention is, in turn, characterized by what is stated in the characterizing portion of Claim 8.
- the position of the coating curtain in the direction of travel of the web can be altered by rotating the application beam around an axis in the cross direction of the web. Due to this, the solution according to the invention requires few moving parts and its construction is simple and reliable.
- the application beam in the starting situation of the coating, is rotated to a starting position, in which the coating agent flows from the application beam to a starting trough.
- the application beam is rotated to the coating position, in which the coating-agent curtain can fall onto the web. Due to the rotating movement of the application beam, the movement between the ends of the beam is better synchronized.
- the distance of the point of contact of the coating-agent curtain from the boundary-layer air remover can be measured and adjusted while the curtain coater is running.
- the distance of the point of contact of the coating-agent curtain from the boundary-layer air remover can thus be kept as desired in the coating starting situation and during normal running when production conditions change, due to which the structures of the boundary-layer air remover remain cleaner and the operation of the boundary-layer air removal remains optimal.
- adjustment of the distance between the point of contact of the coating-agent curtain with the web and the boundary-layer air remover allows the point of contact of the coating-agent curtain of coating agent to be kept as close as possible to the doctoring point, so that a new boundary-air layer will not have time to develop before the point of contact of the coating-agent curtain.
- This is advantageous, particularly in coaters running at high speed, in which a new air layer can form on the surface of the web in a distance of as little as 20 mm.
- the distance adjustment permits control of the air flows prevailing in the vicinity of the point of contact of the coating-agent curtain, so that they disturb application as little as possible.
- Figure 1 shows a cross-section of one curtain coater according to the invention, in the starting position.
- Figure 2 shows the curtain-coating unit of Figure 1, in the coating position.
- the curtain-coating unit 1 there are elements for guiding the continuous material web 6 to be coated and for conveying it forward in the coater 1.
- a hitch roll 5 and a second hitch roll 5' which support the web 6 as it travels, act as the elements.
- the hitch rolls 5, 5' are mounted at their ends in bearings running in bearing shells, which are in turn attached to the frame elements 3 of the coating unit 1.
- An application beam 2 is fitted above the hitch roll 5, to feed the coating mixture to the web 6 as a freely falling curtain 10.
- the application beam 2 there is a nozzle or other feed component extending over the entire width of the web 6, from which the coating agent is fed to the web 6 over the entire width of the web, or extending essentially over the entire width of the web, as a freely falling curtain 10.
- the other feed component can be, for example, a sloping feed plane, from which the coating mixture falls in a curtain-like flow to the surface of the web.
- the application beam 2 is equipped with a sloping plane 13 and three parallel feed gaps 14.
- Each feed gap 14 extends over the entire width of the web 6.
- Coating agent is fed from the feed gaps 14 to the sloping feed plane 13, from which the coating agent flows on over the lip and falls in a curtain-like flow onto the web 6 at the point of contact 9.
- the coating-agent flows fed from the different feed gaps 14 are on top of each other on the feed plane 13, so that the coating agent fed from the feed gap located closest to the Hp 11 is the lowest and the coating agent fed from the feed gap farthest from the lip 11 is on top.
- the application beam 2 is attached rigidly to the frame elements 3 of the curtain coater, for example, with the aid of bearers in the frame element.
- the frame element 3 is, in turn, attached rotatably to the frame 4 of the coater by hinges, with the aid of which the frame element 3 can rotate around an axis 12 at the hinge point running in the cross direction of the web.
- Operating devices 7 are arranged between the frame element 3 and the frame 4, with the aid of which the frame element 3 can be rotated around the axis 12. For example, hydraulic cylinders, the first end of which is hinged to the frame element 3 and the second end to the frame 4, are used as the operating devices 7.
- the rotational movement of the frame element 3 is limited to the desired amount by means of stops, against which the operating devices 7 press the frame element 3 at the extreme positions of the rotational movement.
- the rotational movement is preferably limited in such a way that the frame element 3 and the application beam 2 can rotate around the axis 12 by at most 45° counterclockwise, preferably by at most 15°.
- the frame element 3 and the application beam 2 can be rotated around the axis 12 by about 15°.
- the angle of rotation can be preferably typically also 10°.
- the curtain-coating unit 1 also includes a trough-like starting trough 8, to which the coating agent fed from the application beam 2 is fed when coating starts (Fig. 1).
- the starting trough 8 is attached to the frame element 3. From the starting trough 8, the coating agent flows on to the coating mixture circulation.
- the starting trough 8 is located between the application beam 2 and the web 6, at a point at which the coating-agent curtain falls from the application beam 2 when coating starts, so that the coating agent cannot reach the surface of the web 6.
- the starting trough 8 extends at least over the width from which the coating agent is fed from the application beam 2 to the web, so that in the starting situation all of the coating mixture coming from the application beam 2 falls into the starting trough 8.
- the starting trough 8 is located above the hitch roll 5. When the frame element 2 is rotated around the axis 12, the starting trough 8 also rotates.
- the curtain-coating unit 1 also includes boundary-layer air removal means 15, which are used to remove the boundary-layer air on the surface of the web 6 before the point of contact 9 of the coating-agent curtain 10 with the web.
- the boundary-layer air is a layer of air that has formed on the surface of the web 6, which moves together with the advancing web 6.
- the boundary-layer air removal means 15 are attached to the frame element 3 and are located above the web 6.
- the boundary-layer air removal means 15 include a suction surface arranged facing the upper surface of the web 6, in which there is, for example, a nozzle or openings, through which the boundary-layer air is sucked off the surface of the web 6. The suction surface extends over the entire width of the web.
- the boundary-layer air removal means 15 When the frame element 3 is rotated around the axis 12, the boundary-layer air removal means 15 also rotate.
- the boundary-layer air removal means 15 include a doctor fitted against the web 6 and extending over the entire width of the web, for example, a blade or rod doctor, by means of which the boundary-layer air is also removed from the surface of the web 6.
- the doctor is located after the suction surface in the direction of travel of the web 6, but nevertheless before the point of contact 9 of the coating-agent curtain 10 with the web.
- the width d of the gap is preferably 30 - 80 mm.
- the direction of travel of the web 6 is shown in the drawings by an arrow. It is also possible to remove the boundary-layer air without contact.
- the curtain-coating unit 1 also includes guard plate 16, which is fitted between the application beam 2 and the boundary-layer air removal means 15. A closed air space is formed between the guard plate 16 and the coating-agent curtain 10, into which stabilization air can be blown during coating, if necessary. The behaviour of the curtain 10 in the area of the point of contact 9 is controlled with the aid of the stabilization air.
- the stabilization air is blown into the area of the point of contact 9 of the coating-agent curtain 10 using stabilization-air blowing means and is removed from the area of the point of contact by stabilization-air removal means, m the curtain-coating unit according to the invention the stabilization air blowing and removal means disclosed in patent application FI 20035108, for example, can be used.
- the curtain-coating unit 1 includes a measuring device 17, by means of which the distance between the point of contact 9 of the coating-mixture curtain 10 with the web and the boundary-layer air removal means 15 can be measured while the coating unit 1 is running.
- the measuring device 17 is, for example, a laser measuring device, which includes means for sending a laser pulse to the curtain 10 of coating mixture and means for receiving the reflected laser pulse.
- the distance of the coating-agent curtain 10 from the measuring device 17 can be determined on the basis of the time taken for the laser pulse to travel the distance between the transmitter and the receiver. Further, on this basis it is possible to calculate the distance between the boundary-layer air removal means 15 and the point of contact 9.
- the measuring device 17 is located, for example, beneath the starting trough 8.
- the frame element 3 and the application beam 2 attached to it are first rotated around the axis 12 by the operating devices 7 to the starting position according to Figure 1.
- the lip 11, or other component of the application beam 2, from which the coating-agent curtain 10 begins to flow freely downwards towards the web 6, is above the starting trough 8.
- the feed of the coating agent to the sloping plane 13 from the feed gaps 14 is commenced.
- the coating agent fed from the application beam 2 is allowed to flow to the starting trough 8 until the properties of the coating-agent curtain, such as the feed amount, have been adjusted as desired.
- the feed of the coating agent from the application beam 2 is continued and the frame element 3 and the application beam 2 are rotated around the axis 12 by the operating devices 7 to the coating position according to Figure 2.
- the coating-agent curtain 10 fed from the application beam 2 falls through the gap between the starting trough 8 and the boundary-layer air removal means 15 to the point of contact 9 of the surface of the moving web 6.
- the web 6, which moves at a speed many times that of the downwardly flowing coating-agent curtain 10, sweeps the coating-agent curtain at the point of contact 9 into a thin film, so that the final layer of coating agent is formed on the surface of the web 6.
- the boundary-layer air on the surface of the web 6 is removed during application by the boundary-layer air removal means 15.
- the distance of the coating-agent curtain 10 from the boundary-layer air removal means 15 is measured using the measuring device 17 during the operation of the coating unit 1. If the distance measured deviates from the desired distance, the application beam 2 and the frame element 3 are rotated around the axis 12 by the operating devices 7, to bring the distance back to that desired.
- the distance between the point of contact 9 of the coating-agent curtain 10 and the boundary-layer air removal devices 15 is held during operation of the curtain coater typically to 5 - 75 mm, and preferably to 15 - 20 mm.
- both the frame element 3 and the application beam 2 attached rigidly to it are rotated around an axis 2 running in the cross direction of the web, in order to move the point of contact of the coating-agent curtain 10 with the web 6 and in the starting situation.
- the rotational movement of the application beam 2 can alternatively be implemented by using hinges to attach the application beam 2 to the frame element 3. In that case, only the application beam 2 can be rotated at the hinge points around an axis in the cross direction of the web, while the frame element 3 remains stationary.
Landscapes
- Coating Apparatus (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007521966A JP4477063B2 (ja) | 2004-07-20 | 2005-07-18 | カーテンコータユニット及びカーテンコーティング方法 |
EP05771631A EP1769121A4 (fr) | 2004-07-20 | 2005-07-18 | Unite de couchage par voile et procede de couchage par voile |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI20041003A FI116738B (fi) | 2004-07-20 | 2004-07-20 | Verhopäällystysyksikkö ja verhopäällystysmenetelmä |
FI20041003 | 2004-07-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006008336A1 true WO2006008336A1 (fr) | 2006-01-26 |
Family
ID=32749220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI2005/000332 WO2006008336A1 (fr) | 2004-07-20 | 2005-07-18 | Unite et procede de couchage par voile |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1769121A4 (fr) |
JP (1) | JP4477063B2 (fr) |
FI (1) | FI116738B (fr) |
WO (1) | WO2006008336A1 (fr) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1818450A1 (fr) * | 2006-02-10 | 2007-08-15 | Voith Patent GmbH | Dispositif de revêtement par rideau |
DE102008000349A1 (de) | 2008-02-19 | 2009-08-20 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008040414A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008040402A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008040404A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008054901A1 (de) | 2008-12-18 | 2010-06-24 | Voith Patent Gmbh | Vorhangauftragswerk |
DE102010044030A1 (de) | 2010-11-17 | 2012-05-24 | Voith Patent Gmbh | Vorhangauftragswerk |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI35108A (fi) | 1960-08-09 | 1965-05-13 | Fritz Homann Ag | Menetelmä ja laite kevyiden rakennuslevyjen valmistamiseksi |
DE10012345A1 (de) | 2000-03-14 | 2001-09-20 | Voith Paper Patent Gmbh | Vorhang-Auftragsvorrichtung |
WO2001068982A1 (fr) * | 2000-03-14 | 2001-09-20 | Voith Paper Patent Gmbh | Dispositif d'application |
EP1319747A2 (fr) * | 2001-12-13 | 2003-06-18 | Dow Global Technologies Inc. | Procédé et dispositif de revêtement au rideau |
EP1541765A1 (fr) * | 2003-12-13 | 2005-06-15 | Voith Paper Patent GmbH | Dispositif de revêtement |
EP1555345A2 (fr) * | 2003-12-17 | 2005-07-20 | Voith Paper Patent GmbH | Dispositif d'enduction |
-
2004
- 2004-07-20 FI FI20041003A patent/FI116738B/fi not_active IP Right Cessation
-
2005
- 2005-07-18 JP JP2007521966A patent/JP4477063B2/ja not_active Expired - Fee Related
- 2005-07-18 WO PCT/FI2005/000332 patent/WO2006008336A1/fr active Application Filing
- 2005-07-18 EP EP05771631A patent/EP1769121A4/fr not_active Ceased
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI35108A (fi) | 1960-08-09 | 1965-05-13 | Fritz Homann Ag | Menetelmä ja laite kevyiden rakennuslevyjen valmistamiseksi |
DE10012345A1 (de) | 2000-03-14 | 2001-09-20 | Voith Paper Patent Gmbh | Vorhang-Auftragsvorrichtung |
WO2001068982A1 (fr) * | 2000-03-14 | 2001-09-20 | Voith Paper Patent Gmbh | Dispositif d'application |
EP1319747A2 (fr) * | 2001-12-13 | 2003-06-18 | Dow Global Technologies Inc. | Procédé et dispositif de revêtement au rideau |
EP1541765A1 (fr) * | 2003-12-13 | 2005-06-15 | Voith Paper Patent GmbH | Dispositif de revêtement |
EP1555345A2 (fr) * | 2003-12-17 | 2005-07-20 | Voith Paper Patent GmbH | Dispositif d'enduction |
Non-Patent Citations (1)
Title |
---|
See also references of EP1769121A4 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1818450A1 (fr) * | 2006-02-10 | 2007-08-15 | Voith Patent GmbH | Dispositif de revêtement par rideau |
DE102008000349A1 (de) | 2008-02-19 | 2009-08-20 | Voith Patent Gmbh | Vorhang-Auftragswerk |
EP2093325A2 (fr) | 2008-02-19 | 2009-08-26 | Voith Patent GmbH | Unité d'application de rideau |
EP2093325A3 (fr) * | 2008-02-19 | 2010-01-20 | Voith Patent GmbH | Unité d'application de rideau |
DE102008040414A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008040402A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008040404A1 (de) | 2008-07-15 | 2010-01-21 | Voith Patent Gmbh | Vorhang-Auftragswerk |
DE102008054901A1 (de) | 2008-12-18 | 2010-06-24 | Voith Patent Gmbh | Vorhangauftragswerk |
WO2010069776A1 (fr) * | 2008-12-18 | 2010-06-24 | Voith Patent Gmbh | Unité d’application de rideau |
DE102010044030A1 (de) | 2010-11-17 | 2012-05-24 | Voith Patent Gmbh | Vorhangauftragswerk |
Also Published As
Publication number | Publication date |
---|---|
EP1769121A4 (fr) | 2011-03-23 |
JP4477063B2 (ja) | 2010-06-09 |
EP1769121A1 (fr) | 2007-04-04 |
FI116738B (fi) | 2006-02-15 |
JP2008506525A (ja) | 2008-03-06 |
FI20041003A0 (fi) | 2004-07-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1769121A1 (fr) | Unite de couchage par voile et procede de couchage par voile | |
KR100426387B1 (ko) | 이동중인종이또는카드보드웹을피복시키는방법및장치 | |
CA2383862C (fr) | Encolleuse a rideau et procede d'encollage par rideau | |
US20030044525A1 (en) | Shingle granule valve and method of depositing granules onto a moving substrate | |
EP0651095B1 (fr) | Procédé et dispositif pour enduire une bande en mouvement | |
FI90634B (fi) | Sivelylaite ja menetelmä materiaalirainan sivelemiseksi | |
JP2001503482A (ja) | 移動する厚紙ウエブを被覆する方法及び配置 | |
JP2002513105A (ja) | 移動するウェブへのコーティング方法およびコーティングのための配置 | |
US6086954A (en) | Method and apparatus for application of coating medium onto a traveling material web having a splice | |
US20050120893A1 (en) | Inking device for gravure printing cylinder | |
US5330797A (en) | Curtain coater with displaceable edge guides and method | |
CA1180547A (fr) | Dispositif d'enduction a lame d'air et levre orientable | |
CA2219249C (fr) | Methode et installation pour le couchage d'une bande de papier ou de carton en defilement | |
US20040086638A1 (en) | Method of depositing granules onto a moving substrate | |
FI92021C (fi) | Päällystyslaite | |
CA2229118C (fr) | Appareil pour et procede de formage d'une bande de papier couche | |
JPH07289962A (ja) | 移動材料ウェブに少なくとも一の液体材料を塗布する塗布装置 | |
EP0770730B1 (fr) | Méthode et assemblage pour le revêtement d'une feuille de papier | |
US2981224A (en) | Adjustable mounting for air doctor | |
JPH11179259A (ja) | 塗工装置 | |
JPH11207233A (ja) | 塗工方法及び装置 | |
US6066208A (en) | Apparatus for coating a continuously moving web | |
FI95946C (fi) | Laitteisto ja menetelmä päällystää paperia | |
FI110956B (fi) | JET-applikointiasema ja päällystysmenetelmä | |
AU2002323267A1 (en) | Shingle granule valve and method of depositing granules onto a moving substrate |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2007521966 Country of ref document: JP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005771631 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 2005771631 Country of ref document: EP |