WO2005121297A1

WO2005121297A1 - Cleaning composition

Info

Publication number: WO2005121297A1
Application number: PCT/NZ2005/000106
Authority: WO
Inventors: Judith Helen Blyth; Fadil Al-Alawi
Original assignee: Brilliance Intellectual Property Limited
Priority date: 2004-06-10
Filing date: 2005-05-30
Publication date: 2005-12-22
Also published as: NZ533453A; HK1101190A1; ES2371259T3; AU2005252597A1; CN1993455A; MXPA06014392A; EP1756255B1; JP2008502784A; CN1993455B; CA2570044C; ATE521693T1; US20070179081A1; DK1756255T3; EP1756255A1; EP1756255A4; AU2005252597B2; USRE42136E1; US7533677B2; JP5295563B2; ZA200700234B

Abstract

A cleaning composition which may be a stainless steel cleaning composition comprising a branched ester and an organic solute. The use and a method of using the cleaning composition is also included within the scope of the present invention.

Description

Cleaning Composition

FIELD OF THE INVENTION

This invention relates to a cleaning composition, in particular, but not exclusively to a cleaning composition for use on stainless steel, in addition, the invention also relates to various methods of applying the cleaning composition to the surface of a material.

BACKGROUND OF THE INVENTION

There is a domestic and industrial need to be able to clean or remove grease, stains or dirt from materials such as a ceramics and metals, and thus restore the lustre of these materials.

Although the present invention is embodied in several different aspects, it is clear from this extremely broad background review, that each of these aspects are so linked as to form part of the same inventive concept.

OBJECT

It is therefore an object of the present invention to go at least some way towards providing a solution to the aforementioned need in a simple yet effective manner or to at least provide the public with a useful choice.

STATEMENTS OF THE INVENTION

According to one aspect of the present invention, there is provided a cleaning composition comprising a branched ester and an organic solute.

Accordingly in a second aspect of the present invention there is provided a stainless steel cleaning composition comprising an ester of a branched fatty acid with a fatty alcohol. Preferably, the stainless steel cleaning composition further comprises a solute. Although the branched ester may be derived from a branched alcohol and a linear fatty acid, preferably the branched ester is derived from a branched fatty acid and a number of fatty alcohols.

For the avoidance of doubt, the term "derived from" in this context is intended to include readily available or made precursors to the branched ester for example, the acid may be the acid halide.

Preferably the or each fatty alcohol is a linear chain alcohol having a carbon chain length in the range of 5-25. This is particularly advantageous as the lypophiUic chain will associate itself with grease and many other types of organic material on the surface to be cleaned, making it easier to clean.

More preferably the or each fatty alcohol has a carbon chain length selected from or in the range of 15-19.

Even more preferably, the fatty alcohol is derived from the group comprising coconut oil, palm kernel oil and whale oil.

Preferably, the branched fatty acid contains carbon containing branches in the range of 1-5.

More preferably, there are three carbon contarning branches.

More preferably, the branches contain the same number of carbon atoms.

Preferably, the total number of carbon atoms in any molecule of the branched fatty acid is in the range of 6-12.

More preferably, the range is 7-9.

Preferably the branched ester is cetearyl (or cetostearyl) isonanoate.

Preferably the composition comprises cetearyl isononanoate in the range of 90-99% w/w.

More preferably the composition comprises cetearyl isononanoate in the range of 98% w/w. Even more preferably the cleaning composition comprises cetearyl isononanoate in the range of 97.8% w/w.

Preferably the cleaning composition comprises an organic solute in the range of 1-10%) w/w.

More preferably the cleaning composition comprises an organic solute that is substantially 2% w/w.

Preferably the organic solute comprises an oil expressed from lemon peel.

Preferably the organic solute is D-Limonene.

Preferably the cleaning composition further comprises an additional organic preservative.

More preferably the preservative comprises 0.2% w/w of glydant dissolved in solvent mixture.

Even more preferably the glydant may be selected from the group comprising 1,3-

Dihydroxymethyl 5,5-dimethylhydantoin; l-Hydroxymethyl-5,5-dimethylhydantoin; 5,5- Dimethylhydantoin; 3-Iodo-2-propynl butyl carbamate and 1,3 -butylene glycol.

Preferably, the organic solvent is formaldehyde and water.

Accordingly in a third aspect the present invention there is provided a use of a branched ester and organic solvent for the manufacture of a cleaning composition for cleaning stainless steel. Preferably the branched ester is derived from a branched fatty acid and a number of fatty alcohols.

Preferably the or each fatty alcohol is a linear chain alcohol having a carbon chain length in the range of 5-25.

Preferably, the branched fatty acid contains carbon containing branches in the range of 1-5. More preferably, there are three carbon containing branches.

More preferably, the branches contain the same number of carbon atoms.

More preferably, the range is 7-9.

Preferably the branched ester is cetearyl (or cetostearyi) isonanoate.

Even more preferably, the cetearyl (or cetostearyi) isonanoate is in the form of a product known commercially by the Trade Mark Cetiol SN.

More preferably the composition comprises cetearyl isononanoate in the range of 98% w/w.

Even more preferably the cleaning composition comprises cetearyl isononanoate in the range of 97.8% w/w.

Preferably the cleaning composition comprises an organic solute in the range of 1-10% w/w.

Preferably, the organic solute comprises an oil expressed from a citrus fruit.

Preferably the organic solute comprises an oil expressed from lemon peel.

Preferably the organic solute is D-Lirnonene.

More preferably the preservative comprises 0.2% w/w of glydant dissolved in solvent mixture. Even more preferably the glydant may be selected from the group comprising 1,3- Dihydroxymethyl 5,5-diimethylhydantoin; 1-Hydroxymethyl 5,5-dimethylhydantoin; 5,5- Dimethylhydantoin; 3-Iodo-2-propynl butyl carbamate and 1,3 -butylene glycol.

Preferably, the organic solvent is formaldehyde and water.

The amount w/w of the or each glydant may be selected from the range 1-70% of the glydant and solvent mixture combination.

Preferably, 3-Iodo-2-propynl butyl carbamate is used in the range of 1.8-2.7%w/w.

Preferably, 1,3-butylene glycol is used in the range 3.3-4.9%w/w.

Preferably, the formaldehyde is used in the range of 0.15 -0.25% w/w.

Preferably, the water is used in the range 20-25%w/w.

Accordingly in a further aspect of the present invention there is provided a stainless steel wipe comprising a flexible substrate impregnated with the composition according to the first statement of the invention.

Preferably, in the range of 5-60% of the surface area of one or both of the substrate surfaces is impacted with the composition,

More preferably, this range is 30-50%.

Accordingly in a still further aspect the invention consists in a method of cleaning a surface of a material employing a composition as described herein comprising the steps of:

applying the composition to the surface,

applying pressure and friction substantially firmly to the cleaning composition against the surface,

and removing the cleaning composition from the surface.

Preferably, the cleaning composition is contained within a compressed gas container and applied to the surface by actuating a nozzle on the container. Preferably, the cleaning composition is impregnated onto a cloth or wipe, thus allowing the first two steps of the method as outlined above to be combined.

The invention may also broadly be said to consist in the parts, elements and features referred to or indicated in the specification of the application, individually or collectively, and any or all combinations of any two or more of the parts, elements or features and where specific integers are mentioned herein which have known equivalents such equivalents are deemed to be incorporated herein as if individually set forth.

The invention consists of the foregoing an also envisages constructions of which the following gives examples.

DESCRIPTION OF THE PREFFERED EMBODIMENTS

The present invention comprises a cleaning composition suitable for cleaning a stainless steel surface.

The first cleaning composition comprises cetearyl isononanoate in the form of Cetiol SN mixed together with an organic solvent in the form of a range of some of the natural oils of lemon peel. The cleaning composition thus formed is especially effective in removing stains and/or grease and/or smears and/or any contaminants on the surface, particularly when the surface is a metallic shiny one.

The organic solute, D-Limonene is a yellow oil with a characteristic lemon taste and odour and even though it is present in a small amount, it serves as a cleaning agent in its own right, and it ■ also acts as an anti smearing agent. It also provides the composition with a fragrance.

Even though this cleaning composition comprises substantially the solute in the range of 1 and 10% w/w, it was found that substantially 2% w/w of the organic solute tends to give the most satisfactory results. The formulation is given in Example 1.

The formulation of the second preferred embodiment is given in Example 2 and the reader will see that it includes a glydant composition formed from multiple components in equal weight for weight. The details of the preservative can be found in Table 3.

Example 1

A preferred formulation for the cleaning composition of the present invention is as follows: substantially 98% w/w of Cetiol SN and substantially 2% w/w of D-Limonene.

Example 2

Another preferred formulation for the cleaning composition of the present invention is as follows: substantially 97.8% w/w of Cetiol SN; substantially 2% w/w of D-Limonene and 70% total w/w (for the glydant and solvent mixture) in any combination of 1,3-Dihydroxymethyl 5,5- dimethylhydantoin; l-Hydroxymethyl-X,X-dimethylhydantoin and 5,5-Dimethylhydantoin; whilst 3-Iodo-2-propynl butyl carbamate is 2.5%w/w (of the glydant solvent mixture) and 1,3- butylene glycol is 4.5%w/w (of the glydant solvent mixture), and the formaldehyde is 0.19%w/w (of the glydant solvent mixture) and the water is makes up the remainder of the w/w%.

Example 3

Another preferred formulation for the cleaning composition of the present invention is as follows: substantially 98.5% w/w Cetiol SN and 1.5% w/w perfume in the form of grean lemon

4852.

Other examples employed during the research stages included

Example 4

Mineral oil (Finavestan A80B) as substantially 98.5% w/w and 1.5% w/w perfume in the form of grean lemon 4852 &

Example 5

Mineral oil (Finavestan A80B) as substantially 98% w/w and 2% w/w D-Limonene.

The cleaning composition is best prepared by a method which includes the steps of mixing and dissolving the organic solute D Limonene in Cetiol SN. This is performed by placing the Cetiol SN into a clean dry mixing vessel, and adding the D- Limonene drop wise followed by the glydant dissolved in the glydant solvent mixture in a similar manner.

Once the D-limonene and the glydant dissolved in the glydant solvent mixture has been dissolved, the mixture is ready for bottling.

The method of restoring the lustre to a metal surface that has been contaminated comprises the steps of applying the cleaning composition to the surface, applying pressure and friction with a rag, tissue or cloth firmly over the surface containing the cleaning composition and subsequently removing the cleaning composition from the surface.

The preferred cleaning composition of the present invention works particularly well in restoring the lustre of metallic surfaces such as stainless steels and chrome, however either embodiment of the cleaning composition may also clean other smooth surfaces like porcelain copper, other metals, metal alloys and even fluorinated objects having surfaces that are known commercially by the Registered Trade Mark "Teflon".

Users will also find the cleaning composition effective when applied on the surface of cutlery, sinks, wash hand basins and bathtubs. It should be noted that the cleaning composition is biodegradable.

Either of the embodiments of the cleaning composition of the present invention may be contained in a compressed gas container thus allowing the cleaning composition to be sprayed onto a surface to achieve an even distribution.

Alternatively, the cleaning composition can be impregnated onto a cloth or wipe, the cloth or wipe possibly containing a removable surface sheet to expose a "ready to use" cloth or wipe.

Advantages

It can be seen that at least in the preferred form of the invention a cleaning composition is provided which offers the following advantages: 1. efficient removal of grease, stains or marks, notably soap scum and marks from showers and shower heads, ceramics, and glass although in the latter case the amount of composition applied to a wipe or substrate is in the range of 5-15%.

2. effective restoration of the lustre or shininess of a surface

3. simple and easy to use and manufacture

4. giving a pleasant smell of a citrus fruit, preferably lemon.

Throughout the description and claims of this specification the word "comprise" and variations of that word, such as "comprises" and "comprising", are not intended to exclude other additives, components, integers or steps.

Claims

1. A cleaning composition comprising a branched ester and an organic solute.

2. A stainless steel cleaning composition comprising an ester of a branched fatty acid with a fatty alcohol.

3. A stainless steel cleaning composition as claimed in claim 2, wherein the stainless steel cleaning composition further comprises a solute.

4. A composition as claimed in any preceding claim, wherein the branched ester is derived from a branched fatty acid and a number of fatty alcohols.

5. A stainless steel cleaning composition as claimed in any one of claims 2-4, wherein the or each fatty alcohol is a linear chain alcohol having a carbon chain length in the range of 5-25.

6. A stainless steel cleaning composition as claimed in any one of claims 2-5, wherein the or each fatty alcohol has a carbon chain length selected from or in the range of 15-19.

7. A stainless steel cleaning composition as claimed in any one of claims 2-6, wherein the fatty alcohol is derived from the group comprising coconut oil, palm kernel oil and whale oil.

8. A stainless steel cleaning composition as claimed in any one of claims 2-7, wherein the branched fatty acid contains carbon containing branches in the range of 1-5.

9. A stainless steel cleaning composition as claimed in claim 8, wherein there are three carbon containing branches.

10. A stainless steel cleaning composition as claimed in claim 9, wherein the branches contain the same number of carbon atoms.

11. A stainless steel cleaning composition as claimed in any one of claims 2-10, wherein the total number of carbon atoms in any molecule of the branched fatty acid is in the range of 6- 12.

12. A stainless steel cleaning composition as claimed in claim 11, wherein the range is 7-9.

13. A cleaning composition as claimed in any preceding claim, wherein the branched ester is cetearyl (or cetostearyi) isonanoate.

14. A cleaning composition as claimed in claim 13, wherein the composition comprises cetearyl isononanoate in the range of 90-99% w/w.

15. A cleaning composition as claimed in claim 14, wherein the composition comprises cetearyl isononanoate in the range of 98% w/w.

16. A cleaning composition as claimed in claim 13 or 14, wherein cleaning composition comprises cetearyl isononanoate in the range of 97.8% w/w.

17. A cleaning composition as claimed in claim 1 or claim 3, wherein the organic solute in the range of 1-10% w/w.

18. A cleaning composition as claimed in claim 17, wherein the organic solute is substantially 2% w/w.

19. A cleaning composition as claimed in claim 17 or 18, wherein the organic solute comprises an oil expressed from lemon peel.

20. A cleaning composition as claimed in any one of claims 17 - 19, wherein the organic solute is D-Limonene.

21. A cleaning composition as claimed in any preceding claim, wherein the cleaning composition further comprises an additional organic preservative.

22. A cleaning composition as claimed in claim 21, wherein the preservative comprises 0.2% w/w of glydant dissolved in solvent mixture.

23. A cleaning composition as claimed in claim 22, wherein the glydant may be selected from the group comprising 1,3-Dihydroxymethyl 5,5-dimethylhydantoin; l-Hydroxymethyl-5,5- dimethylhydantoin; 5,5-Dimethylhydantoin; 3-Iodo-2-propynl butyl carbamate and 1,3- butylene glycol.

24. A cleaning composition as claimed in any preceding claim, wherein the composition contains an organic solvent.

25. A cleaning composition as claimed in claim 24, wherein the organic solvent is formaldehyde and water.

26. A use of a branched ester and organic solvent for the manufacture of a cleaning composition for cleaning stainless steel.

27. A use as claimed in claim 26, wherein the branched ester is derived from a branched fatty acid and a number of fatty alcohols.

28. A use as claimed in claim 26 or 27, wherein the or each fatty alcohol is a linear chain alcohol having a carbon chain length in the range of 5-25.

29. A use as claimed in claim 28, wherein the or each fatty alcohol has a carbon chain length selected from or in the range of 15-19.

30. A use as claimed in any one of claims 27 - 29, wherein the fatty alcohol is derived from the group comprising coconut oil, palm kernel oil and whale oil.

31. A use as claimed in any one of claims 27 30, wherein the branched fatty acid contains carbon containing branches in the range of 1-5.

32. A use as claimed in claim 31, wherein there are three carbon containing branches.

33. A use as claimed in claim 32, wherein the branches contain the same number of carbon atoms.

34. A use as claimed in any one of claims 27 - 33 , wherein the total number of carbon atoms in any molecule of the branched fatty acid is in the range of 6-12.

35. A use as claimed in claim 34, wherein the range is 7-9.

36. A use as claimed in any one of claims 26 - 35, wherein the branched ester is cetearyl (or cetostearyi) isonanoate.

37. A use as claimed in claim 36, wherein the cetearyl (or cetostearyi) isonanoate is in the form of a product known commercially by the Trade Mark Cetiol SN.

38. A use as claimed in claim 36 or 37, wherein the composition comprises cetearyl isononanoate in the range of 90-99% w/w.

39. A use as claimed in any one of claims 36 -38, wherein the composition comprises cetearyl isononanoate in the range of 98% w/w.

40. A use as claimed in claim 39, wherein the cleaning composition comprises cetearyl isononanoate in the range of 97.8% w/w.

41. A use as claimed in any one of claims 26 - 40, wherein the cleaning composition comprises an organic solute in the range of 1-10% w/w.

42. A use as claimed in claim 41, wherein the cleaning composition comprises an organic solute that is substantially 2% w/w.

43. A use as claimed in claim 41 or claim 42, wherein the organic solute comprises an oil expressed from a citrus fruit.

44. A use as claimed in claim 43, wherein the citrus fruit is a lemon.

45. A use as claimed in any one of claims 41 - 44, wherein the organic solute is D-Limonene.

46. A use as claimed in any one of claims 26 - 45, wherein the cleaning composition further comprises an additional organic preservative.

47. A use as claimed in claim 46, wherein the preservative comprises 0.2% w/w of glydant dissolved in solvent mixture.

48. A use as claimed in claim 47, wherein the glydant may be selected from the group comprising 1,3-Dihydroxymethyl 5,5-diimethylhydantoin; 1-Hydroxymethyl 5,5- dimethylhydantoin; 5,5-Dimethylhydantoin; 3-Iodo-2-propynl butyl carbamate and 1,3- butylene glycol.

49. A use as claimed in any one of claims 26 - 48, wherein an organic solvent is present.

50. A use as claimed in claim 49, wherein the organic solvent is formaldehyde and water.

51. A use as claimed in any one of claims 47 - 50, wherein the amount w/w of the or each glydant may be selected from the range 1-70% of the glydant and solvent mixture combination.

52. A use as claimed in claim 48, wherein 3-Iodo-2-propynl butyl carbamate is used in the range of l.8-2.7%w/w.

53. A use as claimed in claim 48, wherein 1,3-butylene glycol is used in the range 3.3- 4.9%w/w.

54. A use as claimed in claim 50, wherein the formaldehyde is used in the range of 0.15- 0.25%w/w.

55. A stainless steel wipe comprising a flexible substrate impregnated with the composition according to claim 1 or claim 2.

56. A use as claimed in claim 50, wherein the water is used in the range 20-25%w/w.

57. A wipe as claimed in claim 56, wherein the wipe has two surfaces and the range of 5-60% of the surface area of one or both of the substrate surfaces is impacted with the composition.

58. A wipe as claimed in claim 57, wherein the range is 30-50%.

59. A method of cleaning a surface of a material employing a composition as described herein comprising the steps of: applying the composition to the surface, applying pressure and friction substantially firmly to the cleaning composition against the surface, and removing the cleaning composition from the surface.

60. A method as claimed in claim 59, wherein the cleaning composition is contained within a compressed gas container and applied to the surface by actuating a nozzle on the container.

61. A method as claimed in claim 59 or 60, wherein the cleaning composition is impregnated onto a cloth or wipe, thus allowing the first two steps of the method as outlined above to be combined.