WO2005115586A1 - Medium for mid-performance air filter, process for producing the same and mid-performance air filter - Google Patents
Medium for mid-performance air filter, process for producing the same and mid-performance air filter Download PDFInfo
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- WO2005115586A1 WO2005115586A1 PCT/JP2005/009786 JP2005009786W WO2005115586A1 WO 2005115586 A1 WO2005115586 A1 WO 2005115586A1 JP 2005009786 W JP2005009786 W JP 2005009786W WO 2005115586 A1 WO2005115586 A1 WO 2005115586A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2003—Glass or glassy material
- B01D39/2017—Glass or glassy material the material being filamentary or fibrous
- B01D39/2024—Glass or glassy material the material being filamentary or fibrous otherwise bonded, e.g. by resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
- B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
Definitions
- the present invention relates to a medium for a medium performance air filter, a method for producing the same, and a medium performance air filter.
- the present invention relates to a medium-performance air filter used in the purification of clean rooms, office air conditioners, home air conditioners, and the like used in the fields of the semiconductor manufacturing industry, the pharmaceutical manufacturing industry, the food industry, and hospitals.
- the present invention relates to a high performance air filter medium and a method for producing the same, and a medium performance air filter.
- a large-area filter medium is folded in a zigzag shape, and the interval between the filter media is held by a corrugated separator that is an interval holding material to form a filter pack.
- An air filter housed in a 290 mm box-shaped filter frame is used.
- Such an air filter has an advantage that it has a long filter life because of a large filter medium area.
- a pleated filter pack is formed in which a small space between filter media obtained by folding an electret non-woven fabric or the like in a zigzag shape is maintained by a ribbon material, and, for example, a type in which the filter media is housed in a box-shaped filter frame having a depth of 610 mm.
- Air filters are also used.
- This type of air filter has the advantage that dust or the like having the opposite charge is easily adsorbed because the fibers constituting the nonwoven fabric as the filter medium are charged with positive or negative charges.
- This type of air filter uses the air filter for a long time by frequently changing the filter medium.
- a blow-off type air filter in which a frame is attached to an opening of a bag-shaped filter medium is also used.
- Such a streamer type air filter also has an advantage that the depth of the filter medium is large and the service life is long because the depth is as large as 610 mm.
- a filter medium used in the air filter in addition to the electret nonwoven fabric and the like, a filter medium made of a sheet obtained by adding a binder to synthetic fibers or inorganic fibers and forming the sheet by a wet papermaking method has been used.
- a filter medium for a medium-performance air filter a filter medium having high dust collection efficiency and high pressure loss and a low pressure loss is desired.
- a conventional filter medium 10 made of a sheet made of glass fiber or the like by a wet papermaking method is applied to a glass fiber 9 having a relatively small average fiber diameter in a thickness direction of the filter medium.
- a gap having a small average pore diameter is formed uniformly, so that there is a problem that a large amount of dust 8 is unevenly collected on the air inflow side, and the pressure loss increases.
- the filter medium 10 includes a slightly larger average fiber diameter and glass fibers 16.
- Patent Document 2 discloses that a synthetic fiber 11 having a large average fiber diameter, a glass fiber 12 having a small average fiber diameter, and foamable particles are dispersed in a dispersion medium, and the wet papermaking method is used.
- a sheet in which a void 13 is formed by foaming expandable particles after forming a sheet-like material is used as a filter medium 15 is disclosed.
- Patent Document 1 JP-A-7-253028
- Patent Document 2 JP-A-9155127
- the filter medium 15 described in Patent Document 2 has a structure in which the density of the filter medium 15 is reduced due to the voids 13 formed by the foaming of the expandable particles.
- a large mesh structure formed by synthetic fibers 11 having a large average fiber diameter serving as fibers is filled with glass fibers 12 having a small average fiber diameter, and gaps having a small average pore diameter are also uniform in the thickness direction of the filter medium 15. Therefore, the problem that a large amount of dust 8 is trapped unevenly on the air inflow side has not been improved. For this reason, the filter medium 15 has a problem that the pressure loss is high and the life of the filter medium is short.
- the filter medium 15 has an advantage that an air passage is secured by the voids 13 formed by the foaming of the expandable particles, but the air passage that has been secured is very large, and the skeleton fiber and the skeleton fiber. There was a problem that the synthetic fibers 11 having a large average fiber diameter hindered the pressure loss.
- the present invention provides an air passage secured by a void portion in a sheet constituting a filter medium, and uniformly distributes air in the thickness direction of the filter medium without collecting dust in a direction toward an air inflow side. It is another object of the present invention to provide a medium-performance air filter medium, a method for manufacturing the same, and a medium-performance air filter capable of collecting dust and having a longer life.
- a medium-performance air filter according to the present invention is a medium-performance air filter formed of a sheet in which voids are formed by bonding surrounding fibers with fragments obtained by bursting expandable particles.
- a filter medium wherein the sheet comprises 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 m; 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m; It is characterized by comprising 5 to 15% by mass of an adhesive synthetic fiber of 35 m and 3 to 10% by mass of flakes of expandable particles.
- the method for producing a medium-performance filter medium for a medium-performance air filter comprises, as described in claim 2, 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 ⁇ m, and an average fiber diameter of less than 2 ⁇ m. 0 to 15% by mass of glass short fibers, 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 m, and unfoamed expandable particles 3 to 3 to 20 ⁇ m in average particle size 3 to:
- a sheet is formed using an aqueous dispersion in which LO mass% is dispersed, and the expandable particles are expanded to form a void. Then, the surrounding fibers are debris obtained by bursting the expandable particles. It is characterized in that it is bonded to form a sheet.
- a medium-performance air filter according to the present invention uses the filter medium for a medium-performance air filter according to claim 1 as described in claim 3. The invention's effect
- the filter material for a medium-performance air filter of the present invention is a sheet in which voids are formed by adhering surrounding fibers with fragments obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 to 8 70 to 90% by mass of glass short fibers of m, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ⁇ . And 3 to 10% by mass of flakes of expandable particles. Therefore, the air gaps in the sheet serve as air passages, so that the air can easily move from the inflow side to the outflow side of the filter medium, and the average fibers constituting the sheet throughout the thickness direction of the filter medium.
- Dust can be evenly collected in a relatively fine mesh structure formed by short glass fibers having a diameter of 2 to 8 m, and the filter medium made of the sheet can have a long life.
- the average fiber diameter is less than 2 m
- the fine short glass fibers are dispersed by a relatively fine network structure formed by short glass fibers having an average fiber diameter of 2 to 8 m, and the fine glass fibers are small enough not to increase the pressure loss.
- the sheet contains 3 to 10% by mass of fragments of the expandable particles, the fragments of the ruptured expandable particles strongly adhere to the surrounding fibers so as not to deteriorate the air permeability, and reduce the strength of the filter medium. Can be improved.
- the method for producing a filter material for a medium-performance air filter of the present invention since the surrounding fibers are bonded by the fragments obtained by rupture of the expandable particles, compared with the case where the fibers are bonded only by the adhesive synthetic fibers. Thus, the strength of the sheet is improved, and a long-life filter medium can be manufactured.
- the medium-performance air filter using the filter medium for a medium-performance air filter of the present invention has a high filter medium strength, so that the life of the filter medium is about twice as long as when a sheet made of conventional glass fiber is used as the filter medium.
- the filter can be made long, and a medium-performance air filter using the filter medium can be compactly formed.
- FIG. 1 (a) a sheet before foaming of expandable particles serving as a filter material for a medium-performance air filter of the present invention, (b) a sheet in which the expandable particles are expanded, and (c).
- FIG. 2 is a conceptual diagram showing a state in which air is passed through a medium-performance air filter medium of the present invention.
- FIG. 3 is a conceptual diagram showing a state in which air is passed through a conventional filter medium.
- FIG. 4 is a conceptual diagram showing a state in which air is passed through a filter medium having a gap in a conventional sheet.
- the filter material for a medium-performance air filter according to the present invention is a sheet that forms voids by adhering surrounding fibers with debris obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 70 to 90% by mass of glass short fibers of up to 8 ⁇ m, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ⁇ 5 to 15 % By mass, and 3 to 10% by mass of foam particles.
- the reason why 70 to 90% by mass of short glass fibers having an average fiber diameter of 2 to 8 m is blended in the sheet is that if the blending amount is less than 70% by mass, the fragments of adhesive synthetic fibers and foamable particles are combined. However, if the average fiber diameter exceeds 8 m or the blending amount exceeds 90% by mass, the adhesive synthetic fiber and the particles of the expandable particles may be reduced. This is because there is a problem that the strength of the filter medium is reduced due to a reduced amount of the compound. In order to reduce the gap between the fibers in the sheet and to improve the dust collection efficiency in a range where the pressure loss is not increased, a part of the short glass fibers is blended in an amount of 0 to 15% by mass to obtain an average fiber.
- Short glass fibers with a diameter of less than 2 m can also be used. In order to use stable quality glass short fibers, it is preferable to use those having an average fiber diameter of 0.3 m or more.
- the short glass fiber those formed by a steam spraying method, a spying method, a fire insertion method, a rotary method, or the like can be used.
- the sheet 5 to 15% by mass of the adhesive synthetic fiber having an average fiber diameter of 10 to 35 ⁇ m is blended when the amount is less than 5% by mass or the average fiber of the adhesive synthetic fiber. If the diameter is less than 10 ⁇ m, the bonding area with the short glass fiber is reduced, and the bonding strength is insufficient. If the blending amount exceeds 15% by mass or the average fiber diameter of the adhesive synthetic fiber exceeds 35 ⁇ m, a film is formed between the fibers when the resin is melted and turned into a binder, and the pressure of the filter medium is reduced. This is because the higher the loss, the shorter the filter life.
- a core-sheath type synthetic fiber can be used as the adhesive synthetic fiber.
- a core-sheath type synthetic fiber using polyester as the core component and a modified polyester having a low melting point as the sheath component for example, N720 manufactured by Kuraray Co., Ltd.
- a core-sheath type using polyester as the core component and polyethylene as the sheath component Use of synthetic fibers (for example, N710 manufactured by Kuraray Co., Ltd.) is possible.
- the adhesive synthetic fibers are not limited to core-sheath type synthetic fibers.
- synthetic fibers made of thermoplastic resin such as acrylic resin, polyester resin and polyolefin resin, and thermosetting materials such as epoxy resin Synthetic fibers made of fats and the like can also be used.
- the content of 3 to 10% by mass of the shards of the expandable particles in the sheet is less than 3% by mass.
- the strength of the filter medium becomes weaker when the amount of the filter medium adhered to the fiber is small.
- the amount exceeds 10% by mass the strength of the filter medium is increased, but the amount of fragments of the ruptured expandable particles is increased, and the glass material is reduced.
- a large amount of explosive foamed particles adhere to the gaps between the short fibers and the adhesive synthetic fibers, resulting in poor air permeability, high pressure loss, and short filter media life.
- a wet papermaking method using an aqueous dispersion in which unfoamed expandable particles having an average particle size of 3 to 20 ⁇ m are dispersed in the glass short fibers and the adhesive synthetic fibers of the above-mentioned composition After forming a void portion by foaming the expandable particles to form a void portion, a filter medium for a neutral air filter formed of a sheet in which surrounding fibers are adhered by fragments of the expandable particles is ruptured.
- the use of unexpanded expandable particles having an average particle size of 3 to 20 / ⁇ ⁇ is due to the fact that the average particle size of the unexpanded expandable particles is less than 3 m.
- the average particle size of the unexpanded expandable particles is less than 3 m.
- the average particle size exceeds 20 m, the voids become large.
- the trapping efficiency is improved, a large amount of ruptured expandable particles adhere to the interstices between the fibers, resulting in a problem that the pressure loss increases and the life of the filter medium is shortened.
- the expandable particles used have a particle diameter of about 4 to 5 times and a volume of about 50 to 100 times when expanded by foaming.
- a heat-expandable gas such as ethane, ethylene, propane, butane, or isobutane was included on the outer wall. Things can be used.
- MMA acrylonitrile monomethyl methacrylate
- isobutane was used as the heat-expandable gas contained in the expandable particles due to the degree of expansion of the expandable particles and the degree of adhesion between the expanded expandable particles and the short glass fibers. It is preferred to use expandable particles.
- the expandable particles expand by heating, and the expandable particles burst, and the encapsulated heat-expandable gas is released to the outside. Fragments of the ruptured expandable particles melt and firmly adhere to the surrounding fiber surface and Z or intersection. Note that the mass of the expandable particles hardly changes before and after the gas is released to the outside.
- filamentous fibers such as ultrafine fibrillated synthetic fibers, natural fibers, and glass long fibers are used. May be blended.
- a surfactant it is also possible to add a surfactant to uniformly disperse the fibers and the like in the dispersion liquid and form a sheet by a wet papermaking method. It is also possible to provide a binder.
- Example 1 C-glass short fiber with average fiber diameter of 0.8 ⁇ m 3, (MLF # 208 manufactured by Nippon Sheet Glass Co., Ltd.) 10% by mass, and C-glass short fiber with average fiber diameter of 4 ⁇ m 3 (W50 manufactured by Mag Co., Ltd.) Core-sheath type synthetic fiber 2 with an average fiber diameter of 17 m and an average fiber length of 5 mm (adhesive polyester, modified polyester sheath, 55% heat shrinkage at 140 ° C, Kuraray 7% by mass and thermally expandable microcapsules 4 having an average particle size of 10 to 20; An aqueous dispersion was prepared by dispersing and mixing 5% by mass of a polymer and Matsumoto Microsphere F-55 manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.
- the aqueous dispersion was made into a sheet using a normal paper machine, and then subjected to a surfactant treatment.
- the sheet was dried at 140 ° C. to bond the C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2, and to obtain an unexpanded thermal expansion.
- Foamable microcapsules 4 are foamed about 20 times to form foamed microcapsules 5, and the short C glass fibers 3, 3 'and core-sheath type synthetic fiber 2 are pressed along the spherical surface of the microcapsules 5. Spread out. Then, as shown in FIG. 1 (c) and FIG.
- the foamed microcapsules 5 are ruptured, and the crushed fragments 7 bond the surrounding C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2 to each other.
- the sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g / cm 2 having a plurality of voids 6 formed therein was used as a medium-performance air filter medium.
- 8 indicates dust.
- C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 73% by mass, and the heat-expandable microcapsules were 10% by mass as expandable particles in the same manner as in Example 1.
- a sheet having a thickness of 0.86 mm and a basis weight of 9 lgZcm 2 was used as a filter medium for a medium-performance air filter.
- C-glass short fiber with an average fiber diameter of 0.8 ⁇ m (MLF # 208, manufactured by Nippon Sheet Glass Co., Ltd.) is 0% by mass
- C-glass short fiber with an average fiber diameter of 4 ⁇ m (W50, manufactured by Mag Co., Ltd.) is 88% by mass.
- a sheet having a thickness of 0.70 mm and a basis weight of 90 gZcm 2 was used as a medium performance air filter medium in the same manner as in Example 1 except for the above.
- C-glass short fiber 3 with an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.)
- C-glass short fiber with an average fiber diameter of 4 ⁇ m (NANJING AIXIN FIBREGLASS PRODUCT CO., LTD.) was used. Except that, in the same manner as in Example 1, a sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g Zcm 2 was used as a medium-performance air filter medium.
- Example 2 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 83% by mass, and the thermally expandable microcapsules were 0% by mass as expandable particles. Then, a sheet having a thickness of 0.60 mm and a basis weight of 95 gZcm 2 was used as a medium-performance air filter medium.
- the C glass short fiber having an average fiber diameter of 4 ⁇ m W50 manufactured by Mag Co., Ltd.
- the thermally expandable microcapsules were 0% by mass as expandable particles.
- a sheet having a thickness of 0.60 mm and a basis weight of 95 gZcm 2 was used as a medium-performance air filter medium.
- Example 2 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 68% by mass, and the thermally expandable microcapsules were 15% by mass as expandable particles. Thus, a sheet having a thickness of 0.91 mm and a basis weight of 88 gZcm 2 was used as a medium-performance air filter medium.
- a sheet mainly made of glass fiber having an average fiber diameter of 2 ⁇ m and made by a commercially available wet papermaking method and having a thickness of 0.36 mm and a basis weight of 64 gZcm 2 was used as a filter medium for a medium-performance air filter.
- a sheet having a thickness of 0.50 mm and a basis weight of 90 gZcm 2 mainly composed of glass fiber having an average fiber diameter of 2 ⁇ m and produced by a commercially available wet papermaking method was used as a filter medium for a medium-performance air filter.
- Atmospheric dust having an average particle size of 0.3 m was passed through a medium-performance air filter medium at a wind speed of 0.5 mZs, and the collection efficiency in accordance with JIS B9908 was measured.
- Evaluation criteria Collection efficiency was 50% or more, ⁇ , 40-50% was ⁇ , and less than 40% was X.
- the service life of the filter medium was measured as follows. Using 15 kinds of powder is tested for powder specified in JIS Z8901, Shi measuring the powder dust holding amount to a final pressure loss 250Pa at wind speed 5. 3 cm / s at a dust concentration of 70 workers 30 mg / m 3 7
- the life of the filter material for medium-performance air filters of Conventional Example 1 measured according to the above method is 100, and the filter media whose life exceeds 2 times the life of the filter
- the filter media having a life of less than 2 times was designated as X, and the media having a service life less than 2 times was designated as X.
- Fiber Foamable particles Thickness Per unit area Collection efficiency Outflow side dust Overall evaluation Filter media life
- Examples 1 to 4 for medium-performance air filters had a filter life that was at least twice as long as that of the commercially available filter media of Conventional Example 1. Furthermore, it was confirmed that Examples 2 and 4 had good collection efficiency.
- Examples 1 to 4 medium-performance filter media for air filters have foams in which foamable particles are foamed, and a fragment in which the foamable particles are ruptured has a void portion in which the surface of the surrounding fiber and the Z or intersection are bonded.
- the voids serve as passages to facilitate the passage of air in the thickness direction of the filter medium, and the fine mesh structure of short glass fibers having an average fiber diameter of 2 to 8 m, which is the main part of the sheet that constitutes the filter medium, It was confirmed that the life of the filter medium was prolonged because dust was collected almost uniformly throughout the thickness direction of the filter medium. Further, when fine glass short fibers having an average fiber diameter of less than 2 / zm are blended as in Examples 1, 2, and 4, this fine glass short fiber force is used to reduce the glass fiber having an average fiber diameter of 2 to 8 m. Dispersed by the relatively fine mesh structure formed by the fibers, a finer mesh structure was formed, and it was confirmed that the efficiency of collecting dust over the entire thickness of the filter medium was increased and the filter medium life was prolonged. Was.
- Example 3 when no short glass fiber having an average fiber diameter of less than 2 / zm is blended at all as in Example 3, although the life of the filter medium is twice as long as the filter medium of Conventional Example 1, the fiber constituting the filter medium is Since the gap between the fibers became large, the dust collection efficiency was lower than in Examples 1, 2, and 4. Also, as in Comparative Example 1, the filter medium containing no expandable particles was the same as the expandable particles. Since no air gap was formed due to the foaming, no air passage was secured in the thickness direction of the filter medium, and the life of the filter medium was shortened as in Conventional Example 1. In the filter medium of Comparative Example 1, voids were formed due to the expansion of the expandable particles because the dust adhering to the air outflow side was ineffective. Therefore, it was speculated that the air passage was not secured and dust was trapped in the filter media on the air inflow side.
- Comparative Example 2 in the filter medium containing more than 10% by mass of expandable particles, the apparent dust collection efficiency is increased because many voids are formed due to the expansion of the expandable particles.
- the filter material per unit volume which is the part that originally collects dust, is reduced, and the dust is collected by the smaller filter medium, resulting in higher pressure loss and the same filter life as in the previous example 1. It was getting shorter.
- the present invention relates to a medium-performance air filter medium, a method for manufacturing the medium, and a method for manufacturing a medium-performance air filter, which uniformly collects dust in a relatively fine mesh structure over the entire thickness direction of the filter medium and extends the life of the filter medium. It has industrial applicability in that a high performance air filter can be provided.
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JP2004-160360 | 2004-05-28 | ||
JP2004160360 | 2004-05-28 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6335863A (en) * | 1986-07-24 | 1988-02-16 | 積水化学工業株式会社 | Fiber sheet molded body |
JPH01135513A (en) * | 1987-11-19 | 1989-05-29 | Japan Vilene Co Ltd | Air filter material |
JPH05261224A (en) * | 1992-03-23 | 1993-10-12 | Hokuetsu Paper Mills Ltd | Filter material for air filter |
JPH09155127A (en) * | 1995-12-12 | 1997-06-17 | Mitsubishi Paper Mills Ltd | Filter medium |
-
2005
- 2005-05-27 WO PCT/JP2005/009786 patent/WO2005115586A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6335863A (en) * | 1986-07-24 | 1988-02-16 | 積水化学工業株式会社 | Fiber sheet molded body |
JPH01135513A (en) * | 1987-11-19 | 1989-05-29 | Japan Vilene Co Ltd | Air filter material |
JPH05261224A (en) * | 1992-03-23 | 1993-10-12 | Hokuetsu Paper Mills Ltd | Filter material for air filter |
JPH09155127A (en) * | 1995-12-12 | 1997-06-17 | Mitsubishi Paper Mills Ltd | Filter medium |
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