WO2005115586A1 - Medium for mid-performance air filter, process for producing the same and mid-performance air filter - Google Patents

Medium for mid-performance air filter, process for producing the same and mid-performance air filter Download PDF

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Publication number
WO2005115586A1
WO2005115586A1 PCT/JP2005/009786 JP2005009786W WO2005115586A1 WO 2005115586 A1 WO2005115586 A1 WO 2005115586A1 JP 2005009786 W JP2005009786 W JP 2005009786W WO 2005115586 A1 WO2005115586 A1 WO 2005115586A1
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WIPO (PCT)
Prior art keywords
medium
mass
filter
fibers
fiber diameter
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Application number
PCT/JP2005/009786
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French (fr)
Japanese (ja)
Inventor
Norikazu Shinya
Yoshinobu Kakizaki
Masaaki Watanabe
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Nippon Muki Co., Ltd.
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Publication of WO2005115586A1 publication Critical patent/WO2005115586A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/20Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2003Glass or glassy material
    • B01D39/2017Glass or glassy material the material being filamentary or fibrous
    • B01D39/2024Glass or glassy material the material being filamentary or fibrous otherwise bonded, e.g. by resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin

Definitions

  • the present invention relates to a medium for a medium performance air filter, a method for producing the same, and a medium performance air filter.
  • the present invention relates to a medium-performance air filter used in the purification of clean rooms, office air conditioners, home air conditioners, and the like used in the fields of the semiconductor manufacturing industry, the pharmaceutical manufacturing industry, the food industry, and hospitals.
  • the present invention relates to a high performance air filter medium and a method for producing the same, and a medium performance air filter.
  • a large-area filter medium is folded in a zigzag shape, and the interval between the filter media is held by a corrugated separator that is an interval holding material to form a filter pack.
  • An air filter housed in a 290 mm box-shaped filter frame is used.
  • Such an air filter has an advantage that it has a long filter life because of a large filter medium area.
  • a pleated filter pack is formed in which a small space between filter media obtained by folding an electret non-woven fabric or the like in a zigzag shape is maintained by a ribbon material, and, for example, a type in which the filter media is housed in a box-shaped filter frame having a depth of 610 mm.
  • Air filters are also used.
  • This type of air filter has the advantage that dust or the like having the opposite charge is easily adsorbed because the fibers constituting the nonwoven fabric as the filter medium are charged with positive or negative charges.
  • This type of air filter uses the air filter for a long time by frequently changing the filter medium.
  • a blow-off type air filter in which a frame is attached to an opening of a bag-shaped filter medium is also used.
  • Such a streamer type air filter also has an advantage that the depth of the filter medium is large and the service life is long because the depth is as large as 610 mm.
  • a filter medium used in the air filter in addition to the electret nonwoven fabric and the like, a filter medium made of a sheet obtained by adding a binder to synthetic fibers or inorganic fibers and forming the sheet by a wet papermaking method has been used.
  • a filter medium for a medium-performance air filter a filter medium having high dust collection efficiency and high pressure loss and a low pressure loss is desired.
  • a conventional filter medium 10 made of a sheet made of glass fiber or the like by a wet papermaking method is applied to a glass fiber 9 having a relatively small average fiber diameter in a thickness direction of the filter medium.
  • a gap having a small average pore diameter is formed uniformly, so that there is a problem that a large amount of dust 8 is unevenly collected on the air inflow side, and the pressure loss increases.
  • the filter medium 10 includes a slightly larger average fiber diameter and glass fibers 16.
  • Patent Document 2 discloses that a synthetic fiber 11 having a large average fiber diameter, a glass fiber 12 having a small average fiber diameter, and foamable particles are dispersed in a dispersion medium, and the wet papermaking method is used.
  • a sheet in which a void 13 is formed by foaming expandable particles after forming a sheet-like material is used as a filter medium 15 is disclosed.
  • Patent Document 1 JP-A-7-253028
  • Patent Document 2 JP-A-9155127
  • the filter medium 15 described in Patent Document 2 has a structure in which the density of the filter medium 15 is reduced due to the voids 13 formed by the foaming of the expandable particles.
  • a large mesh structure formed by synthetic fibers 11 having a large average fiber diameter serving as fibers is filled with glass fibers 12 having a small average fiber diameter, and gaps having a small average pore diameter are also uniform in the thickness direction of the filter medium 15. Therefore, the problem that a large amount of dust 8 is trapped unevenly on the air inflow side has not been improved. For this reason, the filter medium 15 has a problem that the pressure loss is high and the life of the filter medium is short.
  • the filter medium 15 has an advantage that an air passage is secured by the voids 13 formed by the foaming of the expandable particles, but the air passage that has been secured is very large, and the skeleton fiber and the skeleton fiber. There was a problem that the synthetic fibers 11 having a large average fiber diameter hindered the pressure loss.
  • the present invention provides an air passage secured by a void portion in a sheet constituting a filter medium, and uniformly distributes air in the thickness direction of the filter medium without collecting dust in a direction toward an air inflow side. It is another object of the present invention to provide a medium-performance air filter medium, a method for manufacturing the same, and a medium-performance air filter capable of collecting dust and having a longer life.
  • a medium-performance air filter according to the present invention is a medium-performance air filter formed of a sheet in which voids are formed by bonding surrounding fibers with fragments obtained by bursting expandable particles.
  • a filter medium wherein the sheet comprises 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 m; 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m; It is characterized by comprising 5 to 15% by mass of an adhesive synthetic fiber of 35 m and 3 to 10% by mass of flakes of expandable particles.
  • the method for producing a medium-performance filter medium for a medium-performance air filter comprises, as described in claim 2, 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 ⁇ m, and an average fiber diameter of less than 2 ⁇ m. 0 to 15% by mass of glass short fibers, 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 m, and unfoamed expandable particles 3 to 3 to 20 ⁇ m in average particle size 3 to:
  • a sheet is formed using an aqueous dispersion in which LO mass% is dispersed, and the expandable particles are expanded to form a void. Then, the surrounding fibers are debris obtained by bursting the expandable particles. It is characterized in that it is bonded to form a sheet.
  • a medium-performance air filter according to the present invention uses the filter medium for a medium-performance air filter according to claim 1 as described in claim 3. The invention's effect
  • the filter material for a medium-performance air filter of the present invention is a sheet in which voids are formed by adhering surrounding fibers with fragments obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 to 8 70 to 90% by mass of glass short fibers of m, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ⁇ . And 3 to 10% by mass of flakes of expandable particles. Therefore, the air gaps in the sheet serve as air passages, so that the air can easily move from the inflow side to the outflow side of the filter medium, and the average fibers constituting the sheet throughout the thickness direction of the filter medium.
  • Dust can be evenly collected in a relatively fine mesh structure formed by short glass fibers having a diameter of 2 to 8 m, and the filter medium made of the sheet can have a long life.
  • the average fiber diameter is less than 2 m
  • the fine short glass fibers are dispersed by a relatively fine network structure formed by short glass fibers having an average fiber diameter of 2 to 8 m, and the fine glass fibers are small enough not to increase the pressure loss.
  • the sheet contains 3 to 10% by mass of fragments of the expandable particles, the fragments of the ruptured expandable particles strongly adhere to the surrounding fibers so as not to deteriorate the air permeability, and reduce the strength of the filter medium. Can be improved.
  • the method for producing a filter material for a medium-performance air filter of the present invention since the surrounding fibers are bonded by the fragments obtained by rupture of the expandable particles, compared with the case where the fibers are bonded only by the adhesive synthetic fibers. Thus, the strength of the sheet is improved, and a long-life filter medium can be manufactured.
  • the medium-performance air filter using the filter medium for a medium-performance air filter of the present invention has a high filter medium strength, so that the life of the filter medium is about twice as long as when a sheet made of conventional glass fiber is used as the filter medium.
  • the filter can be made long, and a medium-performance air filter using the filter medium can be compactly formed.
  • FIG. 1 (a) a sheet before foaming of expandable particles serving as a filter material for a medium-performance air filter of the present invention, (b) a sheet in which the expandable particles are expanded, and (c).
  • FIG. 2 is a conceptual diagram showing a state in which air is passed through a medium-performance air filter medium of the present invention.
  • FIG. 3 is a conceptual diagram showing a state in which air is passed through a conventional filter medium.
  • FIG. 4 is a conceptual diagram showing a state in which air is passed through a filter medium having a gap in a conventional sheet.
  • the filter material for a medium-performance air filter according to the present invention is a sheet that forms voids by adhering surrounding fibers with debris obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 70 to 90% by mass of glass short fibers of up to 8 ⁇ m, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ⁇ 5 to 15 % By mass, and 3 to 10% by mass of foam particles.
  • the reason why 70 to 90% by mass of short glass fibers having an average fiber diameter of 2 to 8 m is blended in the sheet is that if the blending amount is less than 70% by mass, the fragments of adhesive synthetic fibers and foamable particles are combined. However, if the average fiber diameter exceeds 8 m or the blending amount exceeds 90% by mass, the adhesive synthetic fiber and the particles of the expandable particles may be reduced. This is because there is a problem that the strength of the filter medium is reduced due to a reduced amount of the compound. In order to reduce the gap between the fibers in the sheet and to improve the dust collection efficiency in a range where the pressure loss is not increased, a part of the short glass fibers is blended in an amount of 0 to 15% by mass to obtain an average fiber.
  • Short glass fibers with a diameter of less than 2 m can also be used. In order to use stable quality glass short fibers, it is preferable to use those having an average fiber diameter of 0.3 m or more.
  • the short glass fiber those formed by a steam spraying method, a spying method, a fire insertion method, a rotary method, or the like can be used.
  • the sheet 5 to 15% by mass of the adhesive synthetic fiber having an average fiber diameter of 10 to 35 ⁇ m is blended when the amount is less than 5% by mass or the average fiber of the adhesive synthetic fiber. If the diameter is less than 10 ⁇ m, the bonding area with the short glass fiber is reduced, and the bonding strength is insufficient. If the blending amount exceeds 15% by mass or the average fiber diameter of the adhesive synthetic fiber exceeds 35 ⁇ m, a film is formed between the fibers when the resin is melted and turned into a binder, and the pressure of the filter medium is reduced. This is because the higher the loss, the shorter the filter life.
  • a core-sheath type synthetic fiber can be used as the adhesive synthetic fiber.
  • a core-sheath type synthetic fiber using polyester as the core component and a modified polyester having a low melting point as the sheath component for example, N720 manufactured by Kuraray Co., Ltd.
  • a core-sheath type using polyester as the core component and polyethylene as the sheath component Use of synthetic fibers (for example, N710 manufactured by Kuraray Co., Ltd.) is possible.
  • the adhesive synthetic fibers are not limited to core-sheath type synthetic fibers.
  • synthetic fibers made of thermoplastic resin such as acrylic resin, polyester resin and polyolefin resin, and thermosetting materials such as epoxy resin Synthetic fibers made of fats and the like can also be used.
  • the content of 3 to 10% by mass of the shards of the expandable particles in the sheet is less than 3% by mass.
  • the strength of the filter medium becomes weaker when the amount of the filter medium adhered to the fiber is small.
  • the amount exceeds 10% by mass the strength of the filter medium is increased, but the amount of fragments of the ruptured expandable particles is increased, and the glass material is reduced.
  • a large amount of explosive foamed particles adhere to the gaps between the short fibers and the adhesive synthetic fibers, resulting in poor air permeability, high pressure loss, and short filter media life.
  • a wet papermaking method using an aqueous dispersion in which unfoamed expandable particles having an average particle size of 3 to 20 ⁇ m are dispersed in the glass short fibers and the adhesive synthetic fibers of the above-mentioned composition After forming a void portion by foaming the expandable particles to form a void portion, a filter medium for a neutral air filter formed of a sheet in which surrounding fibers are adhered by fragments of the expandable particles is ruptured.
  • the use of unexpanded expandable particles having an average particle size of 3 to 20 / ⁇ ⁇ is due to the fact that the average particle size of the unexpanded expandable particles is less than 3 m.
  • the average particle size of the unexpanded expandable particles is less than 3 m.
  • the average particle size exceeds 20 m, the voids become large.
  • the trapping efficiency is improved, a large amount of ruptured expandable particles adhere to the interstices between the fibers, resulting in a problem that the pressure loss increases and the life of the filter medium is shortened.
  • the expandable particles used have a particle diameter of about 4 to 5 times and a volume of about 50 to 100 times when expanded by foaming.
  • a heat-expandable gas such as ethane, ethylene, propane, butane, or isobutane was included on the outer wall. Things can be used.
  • MMA acrylonitrile monomethyl methacrylate
  • isobutane was used as the heat-expandable gas contained in the expandable particles due to the degree of expansion of the expandable particles and the degree of adhesion between the expanded expandable particles and the short glass fibers. It is preferred to use expandable particles.
  • the expandable particles expand by heating, and the expandable particles burst, and the encapsulated heat-expandable gas is released to the outside. Fragments of the ruptured expandable particles melt and firmly adhere to the surrounding fiber surface and Z or intersection. Note that the mass of the expandable particles hardly changes before and after the gas is released to the outside.
  • filamentous fibers such as ultrafine fibrillated synthetic fibers, natural fibers, and glass long fibers are used. May be blended.
  • a surfactant it is also possible to add a surfactant to uniformly disperse the fibers and the like in the dispersion liquid and form a sheet by a wet papermaking method. It is also possible to provide a binder.
  • Example 1 C-glass short fiber with average fiber diameter of 0.8 ⁇ m 3, (MLF # 208 manufactured by Nippon Sheet Glass Co., Ltd.) 10% by mass, and C-glass short fiber with average fiber diameter of 4 ⁇ m 3 (W50 manufactured by Mag Co., Ltd.) Core-sheath type synthetic fiber 2 with an average fiber diameter of 17 m and an average fiber length of 5 mm (adhesive polyester, modified polyester sheath, 55% heat shrinkage at 140 ° C, Kuraray 7% by mass and thermally expandable microcapsules 4 having an average particle size of 10 to 20; An aqueous dispersion was prepared by dispersing and mixing 5% by mass of a polymer and Matsumoto Microsphere F-55 manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.
  • the aqueous dispersion was made into a sheet using a normal paper machine, and then subjected to a surfactant treatment.
  • the sheet was dried at 140 ° C. to bond the C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2, and to obtain an unexpanded thermal expansion.
  • Foamable microcapsules 4 are foamed about 20 times to form foamed microcapsules 5, and the short C glass fibers 3, 3 'and core-sheath type synthetic fiber 2 are pressed along the spherical surface of the microcapsules 5. Spread out. Then, as shown in FIG. 1 (c) and FIG.
  • the foamed microcapsules 5 are ruptured, and the crushed fragments 7 bond the surrounding C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2 to each other.
  • the sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g / cm 2 having a plurality of voids 6 formed therein was used as a medium-performance air filter medium.
  • 8 indicates dust.
  • C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 73% by mass, and the heat-expandable microcapsules were 10% by mass as expandable particles in the same manner as in Example 1.
  • a sheet having a thickness of 0.86 mm and a basis weight of 9 lgZcm 2 was used as a filter medium for a medium-performance air filter.
  • C-glass short fiber with an average fiber diameter of 0.8 ⁇ m (MLF # 208, manufactured by Nippon Sheet Glass Co., Ltd.) is 0% by mass
  • C-glass short fiber with an average fiber diameter of 4 ⁇ m (W50, manufactured by Mag Co., Ltd.) is 88% by mass.
  • a sheet having a thickness of 0.70 mm and a basis weight of 90 gZcm 2 was used as a medium performance air filter medium in the same manner as in Example 1 except for the above.
  • C-glass short fiber 3 with an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.)
  • C-glass short fiber with an average fiber diameter of 4 ⁇ m (NANJING AIXIN FIBREGLASS PRODUCT CO., LTD.) was used. Except that, in the same manner as in Example 1, a sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g Zcm 2 was used as a medium-performance air filter medium.
  • Example 2 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 83% by mass, and the thermally expandable microcapsules were 0% by mass as expandable particles. Then, a sheet having a thickness of 0.60 mm and a basis weight of 95 gZcm 2 was used as a medium-performance air filter medium.
  • the C glass short fiber having an average fiber diameter of 4 ⁇ m W50 manufactured by Mag Co., Ltd.
  • the thermally expandable microcapsules were 0% by mass as expandable particles.
  • a sheet having a thickness of 0.60 mm and a basis weight of 95 gZcm 2 was used as a medium-performance air filter medium.
  • Example 2 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 ⁇ m (W50 manufactured by Mag Co., Ltd.) was 68% by mass, and the thermally expandable microcapsules were 15% by mass as expandable particles. Thus, a sheet having a thickness of 0.91 mm and a basis weight of 88 gZcm 2 was used as a medium-performance air filter medium.
  • a sheet mainly made of glass fiber having an average fiber diameter of 2 ⁇ m and made by a commercially available wet papermaking method and having a thickness of 0.36 mm and a basis weight of 64 gZcm 2 was used as a filter medium for a medium-performance air filter.
  • a sheet having a thickness of 0.50 mm and a basis weight of 90 gZcm 2 mainly composed of glass fiber having an average fiber diameter of 2 ⁇ m and produced by a commercially available wet papermaking method was used as a filter medium for a medium-performance air filter.
  • Atmospheric dust having an average particle size of 0.3 m was passed through a medium-performance air filter medium at a wind speed of 0.5 mZs, and the collection efficiency in accordance with JIS B9908 was measured.
  • Evaluation criteria Collection efficiency was 50% or more, ⁇ , 40-50% was ⁇ , and less than 40% was X.
  • the service life of the filter medium was measured as follows. Using 15 kinds of powder is tested for powder specified in JIS Z8901, Shi measuring the powder dust holding amount to a final pressure loss 250Pa at wind speed 5. 3 cm / s at a dust concentration of 70 workers 30 mg / m 3 7
  • the life of the filter material for medium-performance air filters of Conventional Example 1 measured according to the above method is 100, and the filter media whose life exceeds 2 times the life of the filter
  • the filter media having a life of less than 2 times was designated as X, and the media having a service life less than 2 times was designated as X.
  • Fiber Foamable particles Thickness Per unit area Collection efficiency Outflow side dust Overall evaluation Filter media life
  • Examples 1 to 4 for medium-performance air filters had a filter life that was at least twice as long as that of the commercially available filter media of Conventional Example 1. Furthermore, it was confirmed that Examples 2 and 4 had good collection efficiency.
  • Examples 1 to 4 medium-performance filter media for air filters have foams in which foamable particles are foamed, and a fragment in which the foamable particles are ruptured has a void portion in which the surface of the surrounding fiber and the Z or intersection are bonded.
  • the voids serve as passages to facilitate the passage of air in the thickness direction of the filter medium, and the fine mesh structure of short glass fibers having an average fiber diameter of 2 to 8 m, which is the main part of the sheet that constitutes the filter medium, It was confirmed that the life of the filter medium was prolonged because dust was collected almost uniformly throughout the thickness direction of the filter medium. Further, when fine glass short fibers having an average fiber diameter of less than 2 / zm are blended as in Examples 1, 2, and 4, this fine glass short fiber force is used to reduce the glass fiber having an average fiber diameter of 2 to 8 m. Dispersed by the relatively fine mesh structure formed by the fibers, a finer mesh structure was formed, and it was confirmed that the efficiency of collecting dust over the entire thickness of the filter medium was increased and the filter medium life was prolonged. Was.
  • Example 3 when no short glass fiber having an average fiber diameter of less than 2 / zm is blended at all as in Example 3, although the life of the filter medium is twice as long as the filter medium of Conventional Example 1, the fiber constituting the filter medium is Since the gap between the fibers became large, the dust collection efficiency was lower than in Examples 1, 2, and 4. Also, as in Comparative Example 1, the filter medium containing no expandable particles was the same as the expandable particles. Since no air gap was formed due to the foaming, no air passage was secured in the thickness direction of the filter medium, and the life of the filter medium was shortened as in Conventional Example 1. In the filter medium of Comparative Example 1, voids were formed due to the expansion of the expandable particles because the dust adhering to the air outflow side was ineffective. Therefore, it was speculated that the air passage was not secured and dust was trapped in the filter media on the air inflow side.
  • Comparative Example 2 in the filter medium containing more than 10% by mass of expandable particles, the apparent dust collection efficiency is increased because many voids are formed due to the expansion of the expandable particles.
  • the filter material per unit volume which is the part that originally collects dust, is reduced, and the dust is collected by the smaller filter medium, resulting in higher pressure loss and the same filter life as in the previous example 1. It was getting shorter.
  • the present invention relates to a medium-performance air filter medium, a method for manufacturing the medium, and a method for manufacturing a medium-performance air filter, which uniformly collects dust in a relatively fine mesh structure over the entire thickness direction of the filter medium and extends the life of the filter medium. It has industrial applicability in that a high performance air filter can be provided.

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  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

A medium for mid-performance air filter that ensures the passage of air by means of voids within a sheet constituting the filter medium, and that without trapping dust disproportionately on its air inlet side, is capable of trapping dust uniformly in the direction of thickness of the filter medium, and that accordingly is capable of prolonging its service life; a process for producing the same; and a mid-performance air filter. There is provided a medium for mid-performance air filter, comprising a sheet having voids formed by causing fragments resulting from bursting of expandable particles to bond surrounding fibers, characterized in that the sheet is composed of 70 to 90 mass% of glass staple fibers of 2 to 8 μm average fiber diameter, 0 to 15 mass% of glass staple fibers of < 2 μm average fiber diameter, 5 to 15 mass% of sticky synthetic fibers of 10 to 35 μm average fiber diameter and 3 to 10 mass% of fragments from expandable particles.

Description

明 細 書  Specification
中性能エアフィルタ用ろ材及びその製造方法並びに中性能エアフィルタ 技術分野  TECHNICAL FIELD The present invention relates to a medium for a medium performance air filter, a method for producing the same, and a medium performance air filter.
[0001] 本発明は、半導体製造工業、医薬品製造工業、食品工業及び病院などの分野で 使用されるクリーンルームの浄化、オフィスの空調、家庭用エアコン等に使用される 中性能エアフィルタに用いられる中性能エアフィルタ用ろ材及びその製造方法並び に中性能エアフィルタに関する。  [0001] The present invention relates to a medium-performance air filter used in the purification of clean rooms, office air conditioners, home air conditioners, and the like used in the fields of the semiconductor manufacturing industry, the pharmaceutical manufacturing industry, the food industry, and hospitals. The present invention relates to a high performance air filter medium and a method for producing the same, and a medium performance air filter.
背景技術  Background art
[0002] 従来、中性能エアフィルタとしては、大面積のろ材をジグザグ状に折り、前記ろ材の 間隔を間隔保持材である波形状のセパレータで保持してフィルタパックを形成し、例 えば、奥行き 290mmの箱形のフィルタ枠に収容させたエアフィルタが使用されてい る。このようなエアフィルタは、ろ材面積が大きいため長寿命であるという利点がある。 また、エレクレット不織布等をジグザグ状に折ったろ材の微小な間隔をリボン材で保 持したプリーツ型のフィルタパックを形成し、例えば、奥行き 610mmの箱形のフィル タ枠に収容させたタイプのエアフィルタも使用されている。このタイプのエアフィルタ は、ろ材である不織布を構成する繊維にプラス若しくはマイナスの電荷を帯電させて いるため、反対の電荷を有する粉塵等を吸着しやすいという利点がある。このタイプ のエアフィルタは、ろ材を頻繁に交換することで、エアフィルタを長く使用している。ま た、例えば、特許文献 1のように、袋状のろ材の開口部に枠体を取り付けた吹き流し タイプのエアフィルタも使用されている。このような吹き流しタイプのエアフィルタも奥 行きが 610mmと大きいため、ろ材面積が大きく長寿命であるという利点がある。  Conventionally, as a medium-performance air filter, a large-area filter medium is folded in a zigzag shape, and the interval between the filter media is held by a corrugated separator that is an interval holding material to form a filter pack. An air filter housed in a 290 mm box-shaped filter frame is used. Such an air filter has an advantage that it has a long filter life because of a large filter medium area. In addition, a pleated filter pack is formed in which a small space between filter media obtained by folding an electret non-woven fabric or the like in a zigzag shape is maintained by a ribbon material, and, for example, a type in which the filter media is housed in a box-shaped filter frame having a depth of 610 mm. Air filters are also used. This type of air filter has the advantage that dust or the like having the opposite charge is easily adsorbed because the fibers constituting the nonwoven fabric as the filter medium are charged with positive or negative charges. This type of air filter uses the air filter for a long time by frequently changing the filter medium. In addition, for example, as in Patent Document 1, a blow-off type air filter in which a frame is attached to an opening of a bag-shaped filter medium is also used. Such a streamer type air filter also has an advantage that the depth of the filter medium is large and the service life is long because the depth is as large as 610 mm.
[0003] 前記エアフィルタに用いられるろ材としては、前記エレクレット不織布等の他に、合 成繊維や無機繊維にバインダを添加して湿式抄紙法で抄造したシートからなるろ材 が用いられていた。このような中性能エアフィルタ用のろ材としては、強度が強ぐ粉 塵の捕集効率が高く、圧力損失が低 、ものが望まれて 、る。 [0003] As a filter medium used in the air filter, in addition to the electret nonwoven fabric and the like, a filter medium made of a sheet obtained by adding a binder to synthetic fibers or inorganic fibers and forming the sheet by a wet papermaking method has been used. As such a filter medium for a medium-performance air filter, a filter medium having high dust collection efficiency and high pressure loss and a low pressure loss is desired.
例えば、図 3に示すように、ガラス繊維等を湿式抄紙法で抄造したシートからなる従 来のろ材 10は、平均繊維径の比較的小さいガラス繊維 9によって、ろ材の厚さ方向 に平均孔径の小さな隙間が均一に形成されてしまうため、空気の流入側に多くの粉 塵 8が偏って捕集され、圧力損失が高くなるという問題があった。前記ろ材 10には平 均繊維径のやや大き 、ガラス繊維 16も含まれて 、る。 For example, as shown in FIG. 3, a conventional filter medium 10 made of a sheet made of glass fiber or the like by a wet papermaking method is applied to a glass fiber 9 having a relatively small average fiber diameter in a thickness direction of the filter medium. In this case, a gap having a small average pore diameter is formed uniformly, so that there is a problem that a large amount of dust 8 is unevenly collected on the air inflow side, and the pressure loss increases. The filter medium 10 includes a slightly larger average fiber diameter and glass fibers 16.
[0004] 圧力損失を低くするためには、平均繊維径の大きい繊維を使用してろ材の密度を 低くすることが考えられる。しかし、平均繊維径の大きな繊維のみで抄造したシートを ろ材とした場合、繊維と繊維の隙間が大きくなり、粉塵の捕集効率が低下する。この ため、特許文献 2には、図 4に示すように、平均繊維径の大きな合成繊維 11と、平均 繊維径の小さなガラス繊維 12と、発泡性粒子を分散媒に分散し、湿式抄紙法によつ てシート状物を形成した後、発泡性粒子の発泡によって空隙部 13を形成したシート をろ材 15としたものが開示されている。前記発泡性粒子は、発泡した際にシート状物 を構成する繊維を押し広げて空隙部 13を形成し、この空隙部 13を維持したまま、発 泡性粒子の外壁 14を溶融させて周囲の繊維を接着している。 [0004] In order to reduce the pressure loss, it is conceivable to reduce the density of the filter medium by using fibers having a large average fiber diameter. However, when a sheet made of only fibers having a large average fiber diameter is used as a filter medium, the gap between the fibers becomes large, and the dust collection efficiency decreases. For this reason, as shown in FIG. 4, Patent Document 2 discloses that a synthetic fiber 11 having a large average fiber diameter, a glass fiber 12 having a small average fiber diameter, and foamable particles are dispersed in a dispersion medium, and the wet papermaking method is used. Thus, a sheet in which a void 13 is formed by foaming expandable particles after forming a sheet-like material is used as a filter medium 15 is disclosed. When the foamable particles are expanded, the fibers constituting the sheet-like material are expanded to form voids 13, and while the voids 13 are maintained, the outer wall 14 of the foamable particles is melted to form a peripheral portion. The fiber is glued.
特許文献 1:特開平 7— 253028号公報  Patent Document 1: JP-A-7-253028
特許文献 2:特開平 9 155127号公報  Patent Document 2: JP-A-9155127
発明の開示  Disclosure of the invention
発明が解決しょうとする課題  Problems to be solved by the invention
[0005] し力しながら、図 4に示すように、特許文献 2に記載のろ材 15は、発泡性粒子の発 泡によって形成された空隙部 13によって、ろ材 15の密度は低下するものの、骨格繊 維となる平均繊維径の大きな合成繊維 11によって形成された大きな網目構造中に、 平均繊維径の小さなガラス繊維 12が充填され、やはりろ材 15の厚さ方向に平均孔 径の小さな隙間が均一に形成されてしまうため、空気の流入側に多くの粉塵 8が偏つ て捕集されるという問題は改善されていな力つた。このため、ろ材 15は、圧力損失が 高くなり、ろ材の寿命が短いという問題があった。また、ろ材 15は、発泡性粒子の発 泡により形成された空隙部 13によって空気の通路が確保されるという利点を有するも のの、せつカゝく確保された空気の通路が、骨格繊維となる平均繊維径の大きな合成 繊維 11によって邪魔され、圧力損失が高くなるという問題があった。 [0005] As shown in FIG. 4, the filter medium 15 described in Patent Document 2 has a structure in which the density of the filter medium 15 is reduced due to the voids 13 formed by the foaming of the expandable particles. A large mesh structure formed by synthetic fibers 11 having a large average fiber diameter serving as fibers is filled with glass fibers 12 having a small average fiber diameter, and gaps having a small average pore diameter are also uniform in the thickness direction of the filter medium 15. Therefore, the problem that a large amount of dust 8 is trapped unevenly on the air inflow side has not been improved. For this reason, the filter medium 15 has a problem that the pressure loss is high and the life of the filter medium is short. Further, the filter medium 15 has an advantage that an air passage is secured by the voids 13 formed by the foaming of the expandable particles, but the air passage that has been secured is very large, and the skeleton fiber and the skeleton fiber. There was a problem that the synthetic fibers 11 having a large average fiber diameter hindered the pressure loss.
そこで、本発明は、ろ材を構成するシート内の空隙部によって空気の通路が確保さ れるとともに、空気の流入側に偏って粉塵を捕集することなぐろ材の厚み方向に均 一に粉塵を捕集することができ、長寿命化することの可能な中性能エアフィルタ用ろ 材及びその製造方法並びに中性能エアフィルタを提供することを目的とする。 In view of the above, the present invention provides an air passage secured by a void portion in a sheet constituting a filter medium, and uniformly distributes air in the thickness direction of the filter medium without collecting dust in a direction toward an air inflow side. It is another object of the present invention to provide a medium-performance air filter medium, a method for manufacturing the same, and a medium-performance air filter capable of collecting dust and having a longer life.
課題を解決するための手段  Means for solving the problem
[0006] 本発明の中性能エアフィルタ用ろ材は、請求項 1に記載の通り、発泡性粒子を破裂 させた破片で周囲の繊維を接着して空隙部を形成したシートからなる中性能エアフィ ルタ用ろ材であって、前記シートは平均繊維径 2〜8 mのガラス短繊維 70〜90質 量%と、平均繊維径 2 m未満のガラス短繊維 0〜 15質量%と、平均繊維径 10〜3 5 mの接着性合成繊維 5〜15質量%と、発泡性粒子の破片 3〜10質量%からなる ことを特徴する。  [0006] A medium-performance air filter according to the present invention, as described in claim 1, is a medium-performance air filter formed of a sheet in which voids are formed by bonding surrounding fibers with fragments obtained by bursting expandable particles. A filter medium, wherein the sheet comprises 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 m; 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m; It is characterized by comprising 5 to 15% by mass of an adhesive synthetic fiber of 35 m and 3 to 10% by mass of flakes of expandable particles.
また、本発明の中性能エアフィルタ用ろ材の製造方法は、請求項 2に記載の通り、 平均繊維径 2〜8 μ mのガラス短繊維 70〜90質量%と、平均繊維径 2 μ m未満のガ ラス短繊維 0〜 15質量%と、平均繊維径 10〜35 mの接着性合成繊維 5〜15質 量%と、平均粒径 3〜20 μ mの未発泡の発泡性粒子 3〜: LO質量%を分散させた水 性分散液を用いてシート状物を抄造し、前記発泡性粒子を発泡させて空隙部を形成 した後、前記発泡性粒子を破裂させた破片で周囲の繊維を接着してシートとすること を特徴とする。  Further, the method for producing a medium-performance filter medium for a medium-performance air filter according to the present invention comprises, as described in claim 2, 70 to 90% by mass of glass short fibers having an average fiber diameter of 2 to 8 μm, and an average fiber diameter of less than 2 μm. 0 to 15% by mass of glass short fibers, 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 m, and unfoamed expandable particles 3 to 3 to 20 μm in average particle size 3 to: A sheet is formed using an aqueous dispersion in which LO mass% is dispersed, and the expandable particles are expanded to form a void. Then, the surrounding fibers are debris obtained by bursting the expandable particles. It is characterized in that it is bonded to form a sheet.
また、本発明の中性能エアフィルタは、請求項 3に記載の通り、請求項 1に記載の 中性能エアフィルタ用ろ材を用いたことを特徴とする。 発明の効果  Further, a medium-performance air filter according to the present invention uses the filter medium for a medium-performance air filter according to claim 1 as described in claim 3. The invention's effect
[0007] 本発明の中性能エアフィルタ用ろ材は、発泡性粒子を破裂させた破片で周囲の繊 維を接着して空隙部を形成したシートであって、前記シートは平均繊維径 2〜8 m のガラス短繊維 70〜90質量%と、平均繊維径 2 m未満のガラス短繊維 0〜 15質 量%と、平均繊維径 10〜35 /ζ πιの接着性合成繊維 5〜15質量%と、発泡性粒子の 破片 3〜10質量%からなるものである。従って、前記シート中の空隙部が空気の通 路となって、ろ材の流入側から流出側まで空気が移動しやすくなるとともに、ろ材の 厚さ方向全体に亘つて、前記シートを構成する平均繊維径 2〜8 mのガラス短繊維 によって形成された比較的細かい網目構造中に均等に粉塵を捕集することができ、 前記シートからなるろ材を長寿命とすることができる。また、平均繊維径 2 m未満の ガラス短繊維を混合した場合は、平均繊維径 2〜8 mのガラス短繊維によって形成 された比較的細かい網目構造によって、前記微細ガラス短繊維が分散されて、圧力 損失を上昇させない程度の微細な網目構造を形成し、ろ材の厚さ方向全体にわたつ て粉塵の捕集効率を高くすることができ、ろ材寿命をより長くすることができる。 [0007] The filter material for a medium-performance air filter of the present invention is a sheet in which voids are formed by adhering surrounding fibers with fragments obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 to 8 70 to 90% by mass of glass short fibers of m, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ζπι. And 3 to 10% by mass of flakes of expandable particles. Therefore, the air gaps in the sheet serve as air passages, so that the air can easily move from the inflow side to the outflow side of the filter medium, and the average fibers constituting the sheet throughout the thickness direction of the filter medium. Dust can be evenly collected in a relatively fine mesh structure formed by short glass fibers having a diameter of 2 to 8 m, and the filter medium made of the sheet can have a long life. In addition, the average fiber diameter is less than 2 m When short glass fibers are mixed, the fine short glass fibers are dispersed by a relatively fine network structure formed by short glass fibers having an average fiber diameter of 2 to 8 m, and the fine glass fibers are small enough not to increase the pressure loss. By forming a mesh structure, dust collection efficiency can be increased over the entire thickness of the filter medium, and the life of the filter medium can be prolonged.
また、前記シート中に発泡性粒子の破片が 3〜10質量%含まれるため、破裂した 発泡性粒子の破片が通気性を悪化させない程度に強固に周囲の繊維を接着し、ろ 材の強度を向上することができる。  Further, since the sheet contains 3 to 10% by mass of fragments of the expandable particles, the fragments of the ruptured expandable particles strongly adhere to the surrounding fibers so as not to deteriorate the air permeability, and reduce the strength of the filter medium. Can be improved.
本発明の中性能エアフィルタ用ろ材の製造方法によれば、前記発泡性粒子を破裂 させた破片で周囲の繊維を接着しているため、接着性合成繊維のみで繊維を接着 する場合と比較して、シートの強度が向上し、長寿命のろ材を製造することができる。 本発明の中性能エアフィルタ用ろ材を用いた中性能エアフィルタは、ろ材強度が高 いため、従来のガラス繊維を抄造したシートをろ材として用いた場合と比較して、ろ材 の寿命を約 2倍長くすることができ、前記ろ材を用いた中性能エアフィルタをコンパク トに形成できる。  According to the method for producing a filter material for a medium-performance air filter of the present invention, since the surrounding fibers are bonded by the fragments obtained by rupture of the expandable particles, compared with the case where the fibers are bonded only by the adhesive synthetic fibers. Thus, the strength of the sheet is improved, and a long-life filter medium can be manufactured. The medium-performance air filter using the filter medium for a medium-performance air filter of the present invention has a high filter medium strength, so that the life of the filter medium is about twice as long as when a sheet made of conventional glass fiber is used as the filter medium. The filter can be made long, and a medium-performance air filter using the filter medium can be compactly formed.
図面の簡単な説明  Brief Description of Drawings
[0008] [図 1] (a)本発明の中性能エアフィルタ用ろ材となる発泡性粒子を発泡させる前のシ ート、(b)発泡性粒子を発泡させた状態のシート、(c)発泡性粒子を破裂させた状態 のシートを示す概念図  [0008] [Fig. 1] (a) a sheet before foaming of expandable particles serving as a filter material for a medium-performance air filter of the present invention, (b) a sheet in which the expandable particles are expanded, and (c). Conceptual diagram showing a sheet in which effervescent particles have been ruptured
[図 2]本発明の中性能エアフィルタ用ろ材に空気を通過させた状態を示す概念図 [図 3]従来例のろ材に空気を通過させた状態を示す概念図  FIG. 2 is a conceptual diagram showing a state in which air is passed through a medium-performance air filter medium of the present invention. FIG. 3 is a conceptual diagram showing a state in which air is passed through a conventional filter medium.
[図 4]従来例のシート中に空隙部を有するろ材に空気を通過させた状態を示す概念 図  FIG. 4 is a conceptual diagram showing a state in which air is passed through a filter medium having a gap in a conventional sheet.
符号の説明  Explanation of symbols
[0009] 1 中性能エアフィルタ用ろ材としたシート [0009] 1 Sheets used as filter media for medium-performance air filters
2 接着性合成繊維である芯鞘型合成繊維  2 Core-sheath type synthetic fibers that are adhesive synthetic fibers
3 平均繊維径 4 μ mの Cガラス短繊維  3 C glass short fiber with average fiber diameter of 4 μm
3 ' 平均繊維径 0. 8 μ mの Cガラス短繊維  3 'Short C glass fiber with average fiber diameter of 0.8 μm
4 未発泡の熱膨張性マイクロカプセル 5 熱膨張により発泡したマイクロカプセル 4 Unfoamed heat-expandable microcapsules 5 Microcapsules foamed by thermal expansion
6 空隙部  6 Void
7 破裂したマイクロカプセルの破片  7 Ruptured microcapsule fragments
8 粉塵  8 dust
9 ガラス繊維  9 Glass fiber
10 ろ材  10 Filter media
11 平均繊維径の大きい合成繊維  11 Synthetic fiber with large average fiber diameter
12 平均繊維径の小さ!/、ガラス短繊維  12 Small average fiber diameter! / Short glass fiber
13 空隙部  13 Void
14 外壁  14 Exterior wall
15 ろ材  15 Filter media
16 平均繊維径のやや大き!/、ガラス繊維  16 Slightly larger average fiber diameter! / Glass fiber
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
本発明の中性能エアフィルタ用ろ材は、発泡性粒子を破裂させた破片で周囲の繊 維を接着して空隙部を形成して!/、るシートであって、前記シートは平均繊維径 2〜8 μ mのガラス短繊維 70〜90質量%と、平均繊維径 2 m未満のガラス短繊維 0〜1 5質量%と、平均繊維径 10〜35 /ζ πιの接着性合成繊維 5〜15質量%と、発泡性粒 子の破片 3〜 10質量%からなつている。  The filter material for a medium-performance air filter according to the present invention is a sheet that forms voids by adhering surrounding fibers with debris obtained by bursting foamable particles, and the sheet has an average fiber diameter of 2 70 to 90% by mass of glass short fibers of up to 8 μm, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, and adhesive synthetic fibers having an average fiber diameter of 10 to 35 / ζπι 5 to 15 % By mass, and 3 to 10% by mass of foam particles.
前記シート中に、平均繊維径 2〜8 mのガラス短繊維を 70〜90質量%配合して いるのは、配合量が 70質量%未満では接着性合成繊維、発泡性粒子の破片の配 合量が増加するため、ろ材の圧力損失が高くなる問題があり、平均繊維径が 8 mを 超えるカゝ若しくは配合量が 90質量%を超えると、接着性合成繊維、発泡性粒子の破 片の配合量も少なくなるため、ろ材の強度が低下するという問題があるからである。 前記シート中の繊維と繊維の隙間を小さくし、圧力損失を上昇させない範囲で粉塵 の捕集効率を向上させるため、前記ガラス短繊維の一部を配合量 0〜 15質量%の 範囲で平均繊維径 2 m未満のガラス短繊維を使用することもできる。尚、安定した 品質のガラス短繊維を使用するためには、平均繊維径 0. 3 m以上のものを使用す ることが好ましい。 前記ガラス短繊維は、蒸気吹付法、スピユング法、火焰挿入法、ロータリー法など で形成したものを使用することができる。 The reason why 70 to 90% by mass of short glass fibers having an average fiber diameter of 2 to 8 m is blended in the sheet is that if the blending amount is less than 70% by mass, the fragments of adhesive synthetic fibers and foamable particles are combined. However, if the average fiber diameter exceeds 8 m or the blending amount exceeds 90% by mass, the adhesive synthetic fiber and the particles of the expandable particles may be reduced. This is because there is a problem that the strength of the filter medium is reduced due to a reduced amount of the compound. In order to reduce the gap between the fibers in the sheet and to improve the dust collection efficiency in a range where the pressure loss is not increased, a part of the short glass fibers is blended in an amount of 0 to 15% by mass to obtain an average fiber. Short glass fibers with a diameter of less than 2 m can also be used. In order to use stable quality glass short fibers, it is preferable to use those having an average fiber diameter of 0.3 m or more. As the short glass fiber, those formed by a steam spraying method, a spying method, a fire insertion method, a rotary method, or the like can be used.
[0011] 前記シート中に、平均繊維径 10〜35 μ mの接着性合成繊維を 5〜 15質量%配合 して ヽるのは、配合量が 5質量%未満或いは接着性合成繊維の平均繊維径が 10 μ m未満では、ガラス短繊維との接着面積が少なくなり、接着力が不足するため、ろ材 強度が弱くなる問題があるからである。また、配合量が 15質量%を超えるか或いは接 着性合成繊維の平均繊維径が 35 μ mを超えると、榭脂が溶けてバインダ化した際に 繊維間に皮膜が形成され、ろ材の圧力損失が高くなつてフィルタ寿命が短くなる問題 があるからである。  [0011] In the sheet, 5 to 15% by mass of the adhesive synthetic fiber having an average fiber diameter of 10 to 35 µm is blended when the amount is less than 5% by mass or the average fiber of the adhesive synthetic fiber. If the diameter is less than 10 μm, the bonding area with the short glass fiber is reduced, and the bonding strength is insufficient. If the blending amount exceeds 15% by mass or the average fiber diameter of the adhesive synthetic fiber exceeds 35 μm, a film is formed between the fibers when the resin is melted and turned into a binder, and the pressure of the filter medium is reduced. This is because the higher the loss, the shorter the filter life.
[0012] 前記接着性合成繊維としては、芯鞘型合成繊維を使用することができる。例えば、 芯成分にポリエステル、鞘成分に低融点の変成ポリエステルを使用した芯鞘型合成 繊維 (例えば、株式会社クラレ製 N720)や、芯成分にポリエステル、鞘成分にポリエ チレンを使用した芯鞘型合成繊維 (例えば、株式会社クラレ製 N710)を使用すること 力 Sできる。また、前記接着性合成繊維は、芯鞘型合成繊維に限ることなぐ例えば、 アクリル榭脂、ポリエステル榭脂、ポリオレフイン榭脂等の熱可塑性榭脂からなる合成 繊維、エポキシ榭脂等の熱硬化性榭脂からなる合成繊維等を使用することもできる。  As the adhesive synthetic fiber, a core-sheath type synthetic fiber can be used. For example, a core-sheath type synthetic fiber using polyester as the core component and a modified polyester having a low melting point as the sheath component (for example, N720 manufactured by Kuraray Co., Ltd.), or a core-sheath type using polyester as the core component and polyethylene as the sheath component Use of synthetic fibers (for example, N710 manufactured by Kuraray Co., Ltd.) is possible. The adhesive synthetic fibers are not limited to core-sheath type synthetic fibers. For example, synthetic fibers made of thermoplastic resin such as acrylic resin, polyester resin and polyolefin resin, and thermosetting materials such as epoxy resin Synthetic fibers made of fats and the like can also be used.
[0013] 前記シート中に、発泡性粒子の破片を 3〜10質量%配合しているのは、 3質量% 未満であると、発泡後破裂させた発泡性粒子の破片の量が少なくなり、繊維と接着す る量が少なぐろ材強度が弱くなるという問題があり、 10質量%を超えると、ろ材強度 は高くなるものの、破裂させた発泡性粒子の破片の量が多くなつて、前記ガラス短繊 維及び接着性合成繊維の隙間に破裂した発泡性粒子が多量に付着して、通気性が 悪化し、圧力損失が高くなり、ろ材寿命が短くなるという問題がある力 である。  [0013] The content of 3 to 10% by mass of the shards of the expandable particles in the sheet is less than 3% by mass. There is a problem that the strength of the filter medium becomes weaker when the amount of the filter medium adhered to the fiber is small. When the amount exceeds 10% by mass, the strength of the filter medium is increased, but the amount of fragments of the ruptured expandable particles is increased, and the glass material is reduced. A large amount of explosive foamed particles adhere to the gaps between the short fibers and the adhesive synthetic fibers, resulting in poor air permeability, high pressure loss, and short filter media life.
[0014] 次に、本発明の中性能エアフィルタ用ろ材の製造方法について説明する。  Next, a method for producing a medium-performance air filter medium of the present invention will be described.
本発明の製造方法によれば、前記配合のガラス短繊維及び接着性合成繊維に、 平均粒径 3〜20 μ mの未発泡の発泡性粒子を分散させた水性分散液を用いて湿式 抄紙法によりシート状物を抄造し、前記発泡性粒子を発泡させて空隙部を形成した 後、前記発泡性粒子を破裂させた破片で周囲の繊維を接着したシートからなる中性 能エアフィルタ用ろ材を製造して 、る。 また、平均粒径が 3〜20 /ζ πιの未発泡の発泡性粒子を使用しているのは、未発泡 の発泡性粒子の平均粒径が 3 m未満であると、発泡した発泡性粒子の膨張率が低 いため、ろ材中に空気の通路となる充分な大きさの空隙部を形成することができない という問題があり、平均粒径が 20 mを超えると、空隙が大きくなるため、ろ材の捕集 効率は向上するものの、破裂した発泡性粒子が前記繊維の隙間に多量に接着して しまうため、圧力損失が高くなり、ろ材寿命が短くなるという問題があるからである。 According to the production method of the present invention, a wet papermaking method using an aqueous dispersion in which unfoamed expandable particles having an average particle size of 3 to 20 μm are dispersed in the glass short fibers and the adhesive synthetic fibers of the above-mentioned composition. After forming a void portion by foaming the expandable particles to form a void portion, a filter medium for a neutral air filter formed of a sheet in which surrounding fibers are adhered by fragments of the expandable particles is ruptured. Manufacture. In addition, the use of unexpanded expandable particles having an average particle size of 3 to 20 / 、 πι is due to the fact that the average particle size of the unexpanded expandable particles is less than 3 m. However, there is a problem that it is not possible to form a sufficiently large void in the filter medium because the coefficient of expansion of the filter medium is low.If the average particle size exceeds 20 m, the voids become large. Although the trapping efficiency is improved, a large amount of ruptured expandable particles adhere to the interstices between the fibers, resulting in a problem that the pressure loss increases and the life of the filter medium is shortened.
[0015] 前記発泡性粒子は、発泡により粒径が約 4〜5倍、体積が約 50〜100倍に膨張す るものを使用している。 [0015] The expandable particles used have a particle diameter of about 4 to 5 times and a volume of about 50 to 100 times when expanded by foaming.
前記発泡性粒子としては、ポリスチレン、ポリ塩化ビニル、ポリ塩ィ匕ビ二リデン及び z又はこれらの共重合体力 なる外壁に、ェタン、エチレン、プロパン、ブタン、イソブ タン等の熱膨脹性ガスを内包したものを使用することができる。特に、発泡性粒子の 膨張度、発泡した発泡性粒子とガラス短繊維の接着具合等から発泡性粒子の外壁 にアクリロニトリル一メチルメタアタリレート (MMA)、内包する熱膨脹性ガスにイソブ タンを使用した発泡性粒子を使用することが好ましい。前記熱膨脹性の発泡性粒子 を使用した場合、加熱による膨張によって、前記発泡性粒子が発泡し、更に、前記発 泡性粒子が破裂して内包された熱膨脹性ガスが外部に放出されるとともに、破裂した 発泡性粒子の破片が溶融して、周囲にある繊維の表面及び Z又は交点を強固に接 着する。尚、前記ガスが外部に放出された前後で発泡性粒子の質量はほとんど変化 しない。  As the expandable particles, polystyrene, polyvinyl chloride, polyvinyl chloride, zirride, or a copolymer of these, a heat-expandable gas such as ethane, ethylene, propane, butane, or isobutane was included on the outer wall. Things can be used. In particular, acrylonitrile monomethyl methacrylate (MMA) was used on the outer wall of the expandable particles, and isobutane was used as the heat-expandable gas contained in the expandable particles due to the degree of expansion of the expandable particles and the degree of adhesion between the expanded expandable particles and the short glass fibers. It is preferred to use expandable particles. When the heat-expandable expandable particles are used, the expandable particles expand by heating, and the expandable particles burst, and the encapsulated heat-expandable gas is released to the outside. Fragments of the ruptured expandable particles melt and firmly adhere to the surrounding fiber surface and Z or intersection. Note that the mass of the expandable particles hardly changes before and after the gas is released to the outside.
[0016] 尚、前記シート中には、捕集効率を低下させず、圧力損失を上昇させない範囲であ れば、極細のフィブリル化合成繊維や天然繊維、ガラス長繊維等のフィラメント状繊 維等の繊維を配合してもよい。その他、前記繊維等を分散液に均一に分散させるた めの界面活性剤を添加して湿式抄紙法によりシートを抄造することも可能であり、シ 一トを抄造した後、強度向上のためにバインダを付与することも可能である。  [0016] In the sheet, as long as the collection efficiency is not lowered and the pressure loss is not increased, filamentous fibers such as ultrafine fibrillated synthetic fibers, natural fibers, and glass long fibers are used. May be blended. In addition, it is also possible to add a surfactant to uniformly disperse the fibers and the like in the dispersion liquid and form a sheet by a wet papermaking method. It is also possible to provide a binder.
実施例  Example
[0017] 次に、本発明の中性能エアフィルタ用ろ材及びそのろ材の製造方法の実施例を図 面に基づき説明し、併せてろ材の比較例及び従来例を説明する。  Next, an embodiment of the filter medium for a medium-performance air filter of the present invention and a method for manufacturing the filter medium will be described with reference to the drawings, and a comparative example and a conventional example of the filter medium will be described.
[0018] 実施例 1 : 平均繊維径 0. 8 μ mの Cガラス短繊維 3, (日本板硝子株式会社製 MLF # 208) 1 0質量%と、平均繊維径 4 μ mの Cガラス短繊維 3 (株式会社マグ製 W50) 78質量% と、接着性合成繊維として、平均繊維径 17 m、平均繊維長 5mmの芯鞘型合成繊 維 2 (芯成分ポリエステル、鞘成分変成ポリエステル、 140°Cの熱収縮率 55%、クラレ 株式会社製 N720) 7質量%と、発泡性粒子として、平均粒径 10〜20 ;ζ ΐηの熱膨脹 性マイクロカプセル 4 (発泡開始温度 100〜105°C、外壁にアクリロニトリル—メチルメ タアタリレート (MMA)共重合体、熱膨張性ガスにイソブタンを内包した松本油脂製 薬株式会社製マツモトマイクロスフェアー F— 55) 5質量%とを水中に分散、混合して 水性分散液とした。この水性分散液に対して、分子量 150万のカチオン性アクリルァ ミド吸着剤を添加して前記熱膨脹性マイクロカプセル 4を前記 Cガラス短繊維 3, 3, 及び芯鞘型合成繊維 2の表面に吸着 ·担持させた。 Example 1: C-glass short fiber with average fiber diameter of 0.8 μm 3, (MLF # 208 manufactured by Nippon Sheet Glass Co., Ltd.) 10% by mass, and C-glass short fiber with average fiber diameter of 4 μm 3 (W50 manufactured by Mag Co., Ltd.) Core-sheath type synthetic fiber 2 with an average fiber diameter of 17 m and an average fiber length of 5 mm (adhesive polyester, modified polyester sheath, 55% heat shrinkage at 140 ° C, Kuraray 7% by mass and thermally expandable microcapsules 4 having an average particle size of 10 to 20; An aqueous dispersion was prepared by dispersing and mixing 5% by mass of a polymer and Matsumoto Microsphere F-55 manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd. in which isobutane was encapsulated in a heat-expandable gas in water. To this aqueous dispersion, a cationic acrylamide adsorbent having a molecular weight of 1.5 million was added to adsorb the heat-expandable microcapsules 4 on the surfaces of the C glass short fibers 3, 3 and the core-sheath type synthetic fibers 2. Supported.
図 1 (a)に示すように、通常の抄紙機を用いて前記水性分散液をシート状物とした 後、界面活性剤処理を行った。図 1 (b)に示すように、前記シート状物を 140°Cで乾 燥して、 Cガラス短繊維 3, 3'と芯鞘型合成繊維 2を接着するとともに、未発泡の熱膨 張性マイクロカプセル 4を約 20倍に発泡させて、発泡したマイクロカプセル 5とし、こ のマイクロカプセル 5の球面に沿って周囲の Cガラス短繊維 3、 3'及び芯鞘型合成繊 維 2を押し広げた。そして、図 1 (c)と図 2に示すように、発泡したマイクロカプセル 5を 破裂させ、破裂させた破片 7で周囲の Cガラス短繊維 3, 3'と芯鞘型合成繊維 2を接 着し、内部に複数の空隙部 6を形成した厚さ 0. 71mm, 目付 92g/cm2のシート 1を 中性能エアフィルタ用ろ材とした。尚、図 2中、 8は粉塵を示す。 As shown in FIG. 1 (a), the aqueous dispersion was made into a sheet using a normal paper machine, and then subjected to a surfactant treatment. As shown in FIG. 1 (b), the sheet was dried at 140 ° C. to bond the C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2, and to obtain an unexpanded thermal expansion. Foamable microcapsules 4 are foamed about 20 times to form foamed microcapsules 5, and the short C glass fibers 3, 3 'and core-sheath type synthetic fiber 2 are pressed along the spherical surface of the microcapsules 5. Spread out. Then, as shown in FIG. 1 (c) and FIG. 2, the foamed microcapsules 5 are ruptured, and the crushed fragments 7 bond the surrounding C glass short fibers 3, 3 ′ and the core-sheath type synthetic fiber 2 to each other. The sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g / cm 2 having a plurality of voids 6 formed therein was used as a medium-performance air filter medium. In addition, in FIG. 2, 8 indicates dust.
[0019] 実施例 2 : Example 2:
平均繊維径 4 μ mの Cガラス短繊維 (株式会社マグ製 W50) 73質量%とし、発泡性 粒子として、前記熱膨脹性マイクロカプセルを 10質量%としたこと以外は、実施例 1と 同様にして、厚さ 0. 86mm, 目付 9 lgZcm2のシートを中性能エアフィルタ用ろ材と した。 C glass short fiber having an average fiber diameter of 4 μm (W50 manufactured by Mag Co., Ltd.) was 73% by mass, and the heat-expandable microcapsules were 10% by mass as expandable particles in the same manner as in Example 1. A sheet having a thickness of 0.86 mm and a basis weight of 9 lgZcm 2 was used as a filter medium for a medium-performance air filter.
[0020] 実施例 3 : Example 3:
平均繊維径 0. 8 μ mの Cガラス短繊維 (日本板硝子株式会社製 MLF # 208)を 0 質量%とし、平均繊維径 4 μ mの Cガラス短繊維 (株式会社マグ製 W50) 88質量%と したこと以外は、実施例 1と同様にして、厚さ 0. 70mm, 目付 90gZcm2のシートを中 性能エアフィルタ用ろ材とした。 C-glass short fiber with an average fiber diameter of 0.8 μm (MLF # 208, manufactured by Nippon Sheet Glass Co., Ltd.) is 0% by mass, and C-glass short fiber with an average fiber diameter of 4 μm (W50, manufactured by Mag Co., Ltd.) is 88% by mass. When A sheet having a thickness of 0.70 mm and a basis weight of 90 gZcm 2 was used as a medium performance air filter medium in the same manner as in Example 1 except for the above.
[0021] 実施例 4 :  Example 4:
平均繊維径 4 μ mの Cガラス短繊維 3 (株式会社マグ製 W50)の代わりに、平均繊 維径 4 μ mの Cガラス短繊維(NANJING AIXIN FIBREGLASS PRODUCT C O. , LTD製)を用いたこと以外は、実施例 1と同様にして、厚さ 0. 71mm, 目付 92g Zcm2のシート 1を中性能エアフィルタ用ろ材とした。 Instead of C-glass short fiber 3 with an average fiber diameter of 4 μm (W50 manufactured by Mag Co., Ltd.), C-glass short fiber with an average fiber diameter of 4 μm (NANJING AIXIN FIBREGLASS PRODUCT CO., LTD.) Was used. Except that, in the same manner as in Example 1, a sheet 1 having a thickness of 0.71 mm and a basis weight of 92 g Zcm 2 was used as a medium-performance air filter medium.
[0022] 比較例 1 : Comparative Example 1:
平均繊維径 4 μ mの Cガラス短繊維 (株式会社マグ製 W50)を 83質量%とし、発泡 性粒子として、前記熱膨脹性マイクロカプセルを 0質量%としたこと以外は、実施例 1 と同様にして、厚さ 0. 60mm、 目付 95gZcm2のシートを中性能エアフィルタ用ろ材 とした。 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 μm (W50 manufactured by Mag Co., Ltd.) was 83% by mass, and the thermally expandable microcapsules were 0% by mass as expandable particles. Then, a sheet having a thickness of 0.60 mm and a basis weight of 95 gZcm 2 was used as a medium-performance air filter medium.
[0023] 比較例 2 : Comparative Example 2:
平均繊維径 4 μ mの Cガラス短繊維 (株式会社マグ製 W50)を 68質量%とし、発泡 性粒子として、前記熱膨脹性マイクロカプセルを 15質量%としたこと以外は、実施例 1と同様にして、厚さ 0. 91mm、 目付 88gZcm2のシートを中性能エアフィルタ用ろ 材とした。 The same procedure as in Example 1 was carried out except that the C glass short fiber having an average fiber diameter of 4 μm (W50 manufactured by Mag Co., Ltd.) was 68% by mass, and the thermally expandable microcapsules were 15% by mass as expandable particles. Thus, a sheet having a thickness of 0.91 mm and a basis weight of 88 gZcm 2 was used as a medium-performance air filter medium.
[0024] 従来例 1 : Conventional example 1:
市販の湿式抄紙法により抄造した平均繊維径 2 μ mガラス繊維を主体とする厚さ 0 . 36mm, 目付 64gZcm2のシートを中性能エアフィルタ用ろ材とした。 A sheet mainly made of glass fiber having an average fiber diameter of 2 μm and made by a commercially available wet papermaking method and having a thickness of 0.36 mm and a basis weight of 64 gZcm 2 was used as a filter medium for a medium-performance air filter.
[0025] 従来例 2 : Conventional example 2:
市販の湿式抄紙法により抄造した平均繊維径 2 μ mガラス繊維を主体とする厚さ 0 . 50mm, 目付 90gZcm2のシートを中性能エアフィルタ用ろ材とした。 A sheet having a thickness of 0.50 mm and a basis weight of 90 gZcm 2 mainly composed of glass fiber having an average fiber diameter of 2 μm and produced by a commercially available wet papermaking method was used as a filter medium for a medium-performance air filter.
[0026] 次に、このようにして得られた実施例 1〜4、比較例 1〜2及び従来例 1〜2の各中 性能エアフィルタ用ろ材について、以下の方法によりろ材の捕集効率、ろ材の寿命を 測定し、測定結果を評価した。また、ろ材の流出側の粉塵付着の有無を評価した。更 に、これらの評価結果に基づいて、以下のように総合評価を行った。結果を表 1に示 す。 [0027] 捕集効率: Next, for each of the thus obtained medium-performance air filter media of Examples 1-4, Comparative Examples 1-2 and Conventional Examples 1-2, the collection efficiency of the filter media was determined by the following method. The service life of the filter medium was measured, and the measurement results were evaluated. The presence or absence of dust on the outflow side of the filter medium was evaluated. Furthermore, based on these evaluation results, a comprehensive evaluation was made as follows. The results are shown in Table 1. [0027] Collection efficiency:
平均粒径 0. 3 mの大気塵を 0. 5mZsの風速で中性能エアフィルタ用ろ材に通 過させ、 JIS B9908に準拠した捕集効率を測定した。  Atmospheric dust having an average particle size of 0.3 m was passed through a medium-performance air filter medium at a wind speed of 0.5 mZs, and the collection efficiency in accordance with JIS B9908 was measured.
捕集効率 (%) = (1 下流側粒子個数 Z上流側粒子個数) X 100  Collection efficiency (%) = (1 downstream particle number Z upstream particle number) X 100
評価基準:捕集効率 50%以上を◎、 40〜50%を〇、 40%未満を Xとした。  Evaluation criteria: Collection efficiency was 50% or more, ◎, 40-50% was Δ, and less than 40% was X.
[0028] ろ材の寿命: [0028] Service life of filter medium:
JIS B9908に規定された方法に基づいて、以下のようにろ材の寿命を測定した。 JIS Z8901に規定する試験用粉体である 15種類の粉体を用いて、粉塵濃度 70 士 30mg/m3で風速 5. 3cm/sで最終圧力損失 250Paになる粉体塵保持量を測 し 7こ。 Based on the method specified in JIS B9908, the service life of the filter medium was measured as follows. Using 15 kinds of powder is tested for powder specified in JIS Z8901, Shi measuring the powder dust holding amount to a final pressure loss 250Pa at wind speed 5. 3 cm / s at a dust concentration of 70 workers 30 mg / m 3 7
w=w 2 -w 1 (gZフィルタユニット)  w = w 2 -w 1 (gZ filter unit)
w :粉塵保持量  w: Dust retention amount
W:試験開始時のフィルタユニット重量 (g)  W: Weight of filter unit at the start of test (g)
W:試験終了時のフィルタユニット重量(g)  W: Filter unit weight at the end of test (g)
2  2
評価基準:前記方法に基づいて測定した従来例 1の中性能エアフィルタ用ろ材の寿 命を 100とし、前記従来例 1のろ材の寿命よりも寿命が 2倍を超えるろ材を◎とし、 2 倍のろ材を〇とし、 2倍未満の寿命のろ材を Xとした。  Evaluation criteria: The life of the filter material for medium-performance air filters of Conventional Example 1 measured according to the above method is 100, and the filter media whose life exceeds 2 times the life of the filter The filter media having a life of less than 2 times was designated as X, and the media having a service life less than 2 times was designated as X.
[0029] 流出側粉塵付着の有無: [0029] Existence of dust on the outflow side:
前記寿命試験をしたろ材を使って、流出側の各ろ材に粉塵が付着して 、るか否か を評価した。粉塵が付着している場合は、〇(有り)とし、粉塵が付着していない場合 は、 X (無し)とした。  Using the filter medium subjected to the life test, it was evaluated whether dust adhered to each filter medium on the outflow side. When dust was attached, it was rated as 〇 (presence), and when no dust was attached, it was rated as X (absent).
[0030] 総合評価: [0030] Overall rating:
捕集効率及び寿命が全てが〇か©の場合は◎とし、捕集効率が Xでろ材の寿命 が〇の場合は〇とし、ろ材の寿命が Xの場合は Xとした。  When the collection efficiency and life were all 〇 or ©, ◎ was given. When the collection efficiency was X and the life of the filter was 〇, 〇 was given. When the life of the filter was X, X was given.
[0031] [表 1] ろ材配合 ろ材特性 ろ材効果 [0031] [Table 1] Filter media composition Filter media characteristics Filter media effect
芯鞘型合成  Core-sheath type synthesis
がラス短繊維力'ラス短繊維  Is the short staple fiber power
繊維 発泡性粒子 厚さ 目付 捕集効率 流出側粉塵 総合評価 ろ材寿命  Fiber Foamable particles Thickness Per unit area Collection efficiency Outflow side dust Overall evaluation Filter media life
(質量 %) 付着の有無  (Mass%)
(質量 ¾) (質量 ¾)  (Mass ¾) (mass ¾)
(質量 ¾)  (Mass ¾)
実施例 フ フ 〇  Example
実施例 〇  Example 〇
実施例 〇 〇 〇 実施例 〇 © 比較例 フ 〇  Example 〇 〇 例 Example 〇 © Comparative Example
比較例 フ 〇  Comparative example
従来例 市販品 (湿式抄造したガラス繊維からなるシート) 〇  Conventional example Commercial product (sheet made of wet-processed glass fiber) 〇
従来例 市販品 (湿式抄造したガラス繊維からなるシート) 〇 表 1に示す結果から以下のことが分かった。  Conventional example Commercial product (sheet made of wet-processed glass fiber) か ら The results shown in Table 1 revealed the following.
実施例 1〜4の中性能エアフィルタ用ろ材は、ろ材の寿命が従来例 1の市販品のろ 材に比較して 2倍以上も長くなつていることが確認できた。更に、実施例 2、 4は捕 集効率もよいことが確認できた。実施例 1〜4の中性能エアフィルタ用ろ材は、発泡 性粒子を発泡させ、前記発泡性粒子を破裂させた破片で周囲の繊維表面及び Z又 は交点を接着した空隙部を有しており、この空隙部が通路となって、ろ材の厚さ方向 に空気が通過しやすくなり、ろ材を構成するシートの主体となる平均繊維径 2〜8 mのガラス短繊維による細かい網目構造よつて、ろ材の厚さ方向全体にわたって略 均等に粉塵が捕集されるため、ろ材寿命が長くなることが確認できた。また、実施例 1 、 2、 4のように、平均繊維径 2 /z m未満の微細なガラス短繊維を配合した場合は、こ の微細なガラス短繊維力 平均繊維径 2〜8 mのガラス短繊維によって形成された 比較的細かい網目構造によって分散されて、更に細かい網目構造が形成され、ろ材 の厚さ方向全体にわたって粉塵を捕集する効率が高くなり、ろ材寿命がより長くなる ことが確認できた。  It was confirmed that the filter media of Examples 1 to 4 for medium-performance air filters had a filter life that was at least twice as long as that of the commercially available filter media of Conventional Example 1. Furthermore, it was confirmed that Examples 2 and 4 had good collection efficiency. Examples 1 to 4 medium-performance filter media for air filters have foams in which foamable particles are foamed, and a fragment in which the foamable particles are ruptured has a void portion in which the surface of the surrounding fiber and the Z or intersection are bonded. The voids serve as passages to facilitate the passage of air in the thickness direction of the filter medium, and the fine mesh structure of short glass fibers having an average fiber diameter of 2 to 8 m, which is the main part of the sheet that constitutes the filter medium, It was confirmed that the life of the filter medium was prolonged because dust was collected almost uniformly throughout the thickness direction of the filter medium. Further, when fine glass short fibers having an average fiber diameter of less than 2 / zm are blended as in Examples 1, 2, and 4, this fine glass short fiber force is used to reduce the glass fiber having an average fiber diameter of 2 to 8 m. Dispersed by the relatively fine mesh structure formed by the fibers, a finer mesh structure was formed, and it was confirmed that the efficiency of collecting dust over the entire thickness of the filter medium was increased and the filter medium life was prolonged. Was.
また、実施例 3のように、平均繊維径が 2 /z m未満のガラス短繊維を全く配合しない 場合は、従来例 1のろ材よりもろ材寿命が 2倍長くなるものの、ろ材を構成する繊維と 繊維の隙間が大きくなるため、粉塵の捕集効率が実施例 1、 2、 4よりも低下していた また、比較例 1のように、発泡性粒子を全く配合しないろ材は、前記発泡性粒子の 発泡による空隙部が形成されないため、ろ材の厚さ方向に空気の通路が確保されず 、ろ材寿命が従来例 1と同様に短くなつていた。また、比較例 1のろ材は、空気の流 出側に付着している粉塵が無力 たため、発泡性粒子の発泡による空隙部が形成さ れていないことから、空気の通路が確保されておらず、空気の流入側となるろ材に偏 つて粉塵が捕集されて ヽるものと推測された。 Further, when no short glass fiber having an average fiber diameter of less than 2 / zm is blended at all as in Example 3, although the life of the filter medium is twice as long as the filter medium of Conventional Example 1, the fiber constituting the filter medium is Since the gap between the fibers became large, the dust collection efficiency was lower than in Examples 1, 2, and 4. Also, as in Comparative Example 1, the filter medium containing no expandable particles was the same as the expandable particles. Since no air gap was formed due to the foaming, no air passage was secured in the thickness direction of the filter medium, and the life of the filter medium was shortened as in Conventional Example 1. In the filter medium of Comparative Example 1, voids were formed due to the expansion of the expandable particles because the dust adhering to the air outflow side was ineffective. Therefore, it was speculated that the air passage was not secured and dust was trapped in the filter media on the air inflow side.
また、比較例 2のように、 10質量%を超える発泡性粒子を配合したろ材は、発泡性 粒子の発泡による空隙が多く形成されるため見掛け上の粉塵の捕集効率は上がるも のの、本来粉塵を捕集する部分である単位体積当たりのろ材の部分が少なくなり、こ の少ないろ材部分に粉塵が捕集されるため、圧力損失が高くなり、ろ材の寿命が従 来例 1と同様に短くなつていた。  Also, as in Comparative Example 2, in the filter medium containing more than 10% by mass of expandable particles, the apparent dust collection efficiency is increased because many voids are formed due to the expansion of the expandable particles. The filter material per unit volume, which is the part that originally collects dust, is reduced, and the dust is collected by the smaller filter medium, resulting in higher pressure loss and the same filter life as in the previous example 1. It was getting shorter.
また、従来例 2のように市販品のろ材の目付を実施例 1〜4と同様にした場合であつ ても、実施例 1〜4のようにろ材が長寿命化しな力つた。  In addition, even when the basis weight of a commercially available filter medium was the same as in Examples 1 to 4 as in Conventional Example 2, the filter medium had a prolonged service life as in Examples 1 to 4.
産業上の利用可能性 Industrial applicability
本発明は、ろ材の厚さ方向全体に亘つて、比較的細かい網目構造中に均等に粉 塵を捕集し、ろ材を長寿命とする、中性能エアフィルタ用ろ材及びその製造方法並 びに中性能エアフィルタを提供することができる点において、産業上の利用可能性を 有する。  The present invention relates to a medium-performance air filter medium, a method for manufacturing the medium, and a method for manufacturing a medium-performance air filter, which uniformly collects dust in a relatively fine mesh structure over the entire thickness direction of the filter medium and extends the life of the filter medium. It has industrial applicability in that a high performance air filter can be provided.

Claims

請求の範囲 The scope of the claims
[1] 発泡性粒子を破裂させた破片で周囲の繊維を接着して空隙部を形成したシートか らなる中性能エアフィルタ用ろ材であって、前記シートは平均繊維径 2〜8 mのガラ ス短繊維 70〜90質量%と、平均繊維径 2 m未満のガラス短繊維 0〜 15質量%と、 平均繊維径 10〜35 /z mの接着性合成繊維 5〜15質量%と、発泡性粒子の破片 3 〜: LO質量%からなることを特徴する中性能エアフィルタ用ろ材。  [1] A medium-performance air filter medium comprising a sheet in which voids are formed by bonding surrounding fibers with fragments obtained by bursting effervescent particles, wherein the sheet has a mean fiber diameter of 2 to 8 m. 70 to 90% by mass of short fibers, 0 to 15% by mass of glass short fibers having an average fiber diameter of less than 2 m, 5 to 15% by mass of adhesive synthetic fibers having an average fiber diameter of 10 to 35 / zm, and expandable particles Fragment 3 of: A medium-performance air filter medium characterized by comprising LO% by mass.
[2] 平均繊維径 2〜8 μ mのガラス短繊維 70〜90質量%と、平均繊維径 2 μ m未満の ガラス短繊維 0〜 15質量%と、平均繊維径 10〜35 mの接着性合成繊維 5〜15質 量%と、平均粒径 3〜20 μ mの未発泡の発泡性粒子 3〜: LO質量%を分散させた水 性分散液を用いてシート状物を抄造し、前記発泡性粒子を発泡させて空隙部を形成 した後、前記発泡性粒子を破裂させた破片で周囲の繊維を接着してシートとすること を特徴とする中性能エアフィルタ用ろ材の製造方法。  [2] Adhesion of 70-90% by mass of glass short fibers having an average fiber diameter of 2-8 μm, 0-15% by mass of glass short fibers having an average fiber diameter of less than 2 μm, and 10-35 m of average fiber diameter Unexpanded expandable particles having a synthetic fiber content of 5 to 15% by mass and an average particle size of 3 to 20 μm 3 to: A sheet-like material is formed using an aqueous dispersion in which LO mass% is dispersed, A method for producing a filter material for a medium-performance air filter, comprising: forming a void portion by foaming expandable particles; and bonding a surrounding fiber with a fragment obtained by bursting the expandable particles to form a sheet.
[3] 請求項 1に記載の中性能エアフィルタ用ろ材を用いたことを特徴とする中性能エア フイノレタ。  [3] A medium-performance air finoleta, wherein the medium for a medium-performance air filter according to claim 1 is used.
PCT/JP2005/009786 2004-05-28 2005-05-27 Medium for mid-performance air filter, process for producing the same and mid-performance air filter WO2005115586A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6335863A (en) * 1986-07-24 1988-02-16 積水化学工業株式会社 Fiber sheet molded body
JPH01135513A (en) * 1987-11-19 1989-05-29 Japan Vilene Co Ltd Air filter material
JPH05261224A (en) * 1992-03-23 1993-10-12 Hokuetsu Paper Mills Ltd Filter material for air filter
JPH09155127A (en) * 1995-12-12 1997-06-17 Mitsubishi Paper Mills Ltd Filter medium

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6335863A (en) * 1986-07-24 1988-02-16 積水化学工業株式会社 Fiber sheet molded body
JPH01135513A (en) * 1987-11-19 1989-05-29 Japan Vilene Co Ltd Air filter material
JPH05261224A (en) * 1992-03-23 1993-10-12 Hokuetsu Paper Mills Ltd Filter material for air filter
JPH09155127A (en) * 1995-12-12 1997-06-17 Mitsubishi Paper Mills Ltd Filter medium

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