WO2005090929A1 - Ultraschall-strömungssensor mit wandlerarray und reflextionsfläche - Google Patents
Ultraschall-strömungssensor mit wandlerarray und reflextionsfläche Download PDFInfo
- Publication number
- WO2005090929A1 WO2005090929A1 PCT/EP2005/050287 EP2005050287W WO2005090929A1 WO 2005090929 A1 WO2005090929 A1 WO 2005090929A1 EP 2005050287 W EP2005050287 W EP 2005050287W WO 2005090929 A1 WO2005090929 A1 WO 2005090929A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ultrasonic
- flow sensor
- reflection surface
- transducer array
- sensor according
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N29/00—Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
- G01N29/02—Analysing fluids
- G01N29/024—Analysing fluids by measuring propagation velocity or propagation time of acoustic waves
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/66—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by measuring frequency, phase shift or propagation time of electromagnetic or other waves, e.g. using ultrasonic flowmeters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/66—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by measuring frequency, phase shift or propagation time of electromagnetic or other waves, e.g. using ultrasonic flowmeters
- G01F1/662—Constructional details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
- G01F1/66—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by measuring frequency, phase shift or propagation time of electromagnetic or other waves, e.g. using ultrasonic flowmeters
- G01F1/665—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow by measuring frequency, phase shift or propagation time of electromagnetic or other waves, e.g. using ultrasonic flowmeters of the drag-type
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N29/00—Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
- G01N29/02—Analysing fluids
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N29/00—Investigating or analysing materials by the use of ultrasonic, sonic or infrasonic waves; Visualisation of the interior of objects by transmitting ultrasonic or sonic waves through the object
- G01N29/34—Generating the ultrasonic, sonic or infrasonic waves, e.g. electronic circuits specially adapted therefor
- G01N29/341—Generating the ultrasonic, sonic or infrasonic waves, e.g. electronic circuits specially adapted therefor with time characteristics
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01P—MEASURING LINEAR OR ANGULAR SPEED, ACCELERATION, DECELERATION, OR SHOCK; INDICATING PRESENCE, ABSENCE, OR DIRECTION, OF MOVEMENT
- G01P5/00—Measuring speed of fluids, e.g. of air stream; Measuring speed of bodies relative to fluids, e.g. of ship, of aircraft
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01P—MEASURING LINEAR OR ANGULAR SPEED, ACCELERATION, DECELERATION, OR SHOCK; INDICATING PRESENCE, ABSENCE, OR DIRECTION, OF MOVEMENT
- G01P5/00—Measuring speed of fluids, e.g. of air stream; Measuring speed of bodies relative to fluids, e.g. of ship, of aircraft
- G01P5/24—Measuring speed of fluids, e.g. of air stream; Measuring speed of bodies relative to fluids, e.g. of ship, of aircraft by measuring the direct influence of the streaming fluid on the properties of a detecting acoustical wave
- G01P5/245—Measuring speed of fluids, e.g. of air stream; Measuring speed of bodies relative to fluids, e.g. of ship, of aircraft by measuring the direct influence of the streaming fluid on the properties of a detecting acoustical wave by measuring transit time of acoustical waves
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2291/00—Indexing codes associated with group G01N29/00
- G01N2291/02—Indexing codes associated with the analysed material
- G01N2291/028—Material parameters
- G01N2291/02836—Flow rate, liquid level
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2291/00—Indexing codes associated with group G01N29/00
- G01N2291/04—Wave modes and trajectories
- G01N2291/044—Internal reflections (echoes), e.g. on walls or defects
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2291/00—Indexing codes associated with group G01N29/00
- G01N2291/10—Number of transducers
- G01N2291/106—Number of transducers one or more transducer arrays
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2291/00—Indexing codes associated with group G01N29/00
- G01N2291/26—Scanned objects
- G01N2291/263—Surfaces
- G01N2291/2634—Surfaces cylindrical from outside
Definitions
- the invention relates to an ultrasonic flow sensor, in particular for measuring the volume or mass flow of a fluid, according to the preamble of patent claim 1.
- Ultrasonic flow sensors are used in particular to measure the volume or mass flow or the flow rate of a gaseous or liquid medium flowing through a pipeline.
- a typical ultrasound flow sensor comprises two ultrasound transducers arranged offset in the flow direction, which generate ultrasound signals and send them out to the other ultrasound transducer that they are receiving. Depending on the direction of radiation, the ultrasound signals are either accelerated or slowed down by the flow. The ultrasound signals are therefore received by the two transducers after different transit times. From the transit time difference of the ultrasonic signal in the direction of flow and the
- An ultrasound signal in the opposite direction can finally be evaluated by an electronic evaluation system the desired measured variable.
- Another type of ultrasonic flow sensor uses the effect of the jet drift.
- This type usually comprises two transducer arrays (a series arrangement of several transducers) arranged opposite one another on a pipeline, one of which works as a transmitting array and the other as a receiving array.
- the transmission array sends an ultrasound signal to the opposite reception array, where the signal is detected. If a fluid flows through the pipeline at a flow velocity v, the sound waves emitted transversely to the direction of flow are carried along by the flow and thereby deflected in the direction of flow (jet drift).
- v flow velocity
- the construction of such an ultrasonic flow sensor with two transducer arrays is relatively complex and complicated.
- An essential aspect of the invention is to realize an ultrasonic flow sensor with only a single transducer array and an opposite reflection surface, and to operate the flow sensor in such a way that the transducer array emits ultrasonic signals to the opposite reflection surface and receives the reflected signals again.
- the extent of the jet drift is a measure of the flow velocity of the flowing medium.
- transducer array is understood here in particular to mean a series arrangement of a plurality of ultrasound transducers, which are preferably arranged directly adjacent to one another.
- the individual transducers are preferably arranged in alignment and produce e.g. flat or cylindrical
- the converter array can also be used in this way be formed so that spherical, ellipsoidal or otherwise curved wave fronts are generated.
- the converter array according to the invention is preferably operated in a pulsed manner. This means that the individual ultrasound transducers of the transducer array are electrically excited in a pulsed manner and generate a corresponding ultrasound signal that is received again by the transducers after its transit time - which essentially depends on the tube diameter and the speed of sound in the fluid.
- the frequency of the suggestions per time i.e. the number of ultrasound signals that run through the measurement section at the same time is in principle freely selectable. It should only be taken into account here that conventional converters cannot send and receive at the same time, and thus transmission and reception must not coincide at one time.
- the sensor may, according to a first mode of operation, for example, similarly as in ⁇ sing-around "(Note: sing-around refers generally to the fact that transit time measurement is performed) processes are operated, wherein the reception of an ultrasound signal at the transducer array in each case the generation of a new ultrasonic signal This causes the ultrasound signals to run back and forth continuously.
- sing-around refers generally to the fact that transit time measurement is performed
- the generation of the ultrasound signals is periodically triggered by an oscillator in such a way that a new ultrasound signal is only ever sent after an ultrasound signal has been received.
- the transducer array is controlled in such a way that it sends a sequence of several ultrasound signals within one round trip time (ie the time that an ultrasound signal would need from the transducer array to the reflection surface and back).
- a sequence of several ultrasound signals within one round trip time (ie the time that an ultrasound signal would need from the transducer array to the reflection surface and back).
- the transducer array before the first of the ultrasound signals becomes the transducer array has reached again, coupled at least one further signal into the measuring section.
- the number of measurements per time can be increased significantly and thus the measurement accuracy can be increased, the measurement duration being significantly shorter compared to n individual measurements.
- the time interval between the individual ultrasound signals of a sequence is to be selected so that a transducer is ready to receive, ie does not exactly work in the transmission mode when a reflected ultrasound signal arrives at the transducer.
- the ultrasound flow sensor preferably comprises transmission electronics with which the individual ultrasound transducers can be excited individually and independently of one another. This makes it possible to set the path differences of the individual signals emitted by the ultrasound transducers in such a way that a global ultrasound wave with a definable wavefront is generated by interference. For example, an essentially cylindrical or spherical wavefront is generated, which is reflected on the opposite reflection surface and hits the transducer array in a focused manner.
- the reflecting surface can simply be part of the inner wall of the tube, without the wall having to be specially adapted.
- the individual transducers of the transducer array are excited synchronously, so that a wave with a flat wavefront is produced by interference of the individual signals.
- the reflection surface is preferably curved such that the plane wave is focused and hits the transducer array in bundles.
- the reflection surface should also be designed in such a way that it offers little resistance to the flow and does not generate any turbulence.
- the reflection surface can be used, for example, as a bulge located in the inner tube wall can be realized.
- a shielding device is provided on the side of the reflection surface, which causes that part of the
- Ultrasonic signal that strikes the dimming device is not reflected or only reflected back onto the transducer array.
- the dimming device can e.g. be realized in such a way that the incident ultrasound signal is absorbed, scattered or reflected out of the sound path of the useful signal. As a result, an intensity pattern is mapped on the transducer array, the limits of which are relatively sharp and can therefore be detected well.
- the dimming device can e.g. an area of
- Inner wall surface which e.g. is roughened or provided with fine grooves in order to diffusely scatter the ultrasonic signal.
- the grooves are preferably aligned in the direction of flow.
- the transducer array is preferably mounted flush with the inner wall of the pipeline. As a result, the flow of the fluid is not disturbed and, in particular, there is no turbulence.
- the transducer array according to the invention is moreover preferably mounted in the upper half of a pipeline. This has the advantage that only a little dust or suspended matter can collect on the transducer array. If the transducer array and the reflection surface are arranged laterally opposite on the pipeline, both elements are contaminated relatively little.
- the ultrasound flow sensor preferably includes a transmitter and receiver electronics that the transducer array in stimulates as desired and the reflected ultrasound signal is detected and evaluated.
- FIG. 1 shows a schematic view of an ultrasonic flow sensor according to a first embodiment of the invention
- FIG. 2 is a schematic view of an ultrasound
- Fig. 3 is a schematic view of an ultrasonic flow sensor according to a third embodiment of the invention.
- the flow sensor essentially comprises an ultrasound transducer array 2 comprising a plurality of individual, strip-shaped ultrasound transducers 2a-2n arranged in parallel, each of which generates ultrasound signals and emits them to an opposite reflection surface 4. Interference of the individual signals creates a global wavefront 7, which propagates through the flowing fluid 1 transversely to the direction of flow, is reflected on the reflection surface 4 and then hits the transducer array 2 again.
- the position of the pixel P is a measure of the flow velocity v of the fluid 1.
- the individual ultrasound transducers 2a-2n of the transducer array 2 are controlled separately, so that, due to the path differences of the individual signals, an approximately cylindrical wavefront 7 is formed which is concavely curved in the radiation direction Edge areas 8 first meet the reflection surface 4.
- the shaft 7 is thereby focused and strikes the transducer array 2 essentially at a point P, depending on the flow velocity v, the image point P moves more or less strongly in the direction of flow 12 (effect of the jet drift).
- Flow velocity v is indicated by dashed lines and a pixel P '.
- a reception electronics 6 evaluates the ultrasound signal detected at the ultrasound transducers 2a-2n and calculates the desired measurement variable therefrom.
- the reflection surface 4 is merely a section of the inner tube wall opposite the transducer array 2.
- the inner tube wall in the area of the reflection surface 4 could e.g. polished or provided with a special reflective layer.
- the transducer array 2 is mounted here on the pipe 3 to prevent dust or
- Fig. 2 shows a schematic representation of another
- the transmission and evaluation circuits 5 and _ 6 are omitted for reasons of clarity.
- the same components are identified by the same reference symbols.
- the individual ultrasonic transducers 2a-2n of the transducer array 2 are controlled in such a way that a plane wavefront 7, which runs in the direction of the reflection surface 4, is produced by interference of the individual signals.
- the reflection surface 4 is curved in such a way that the ultrasound signal 7 is focused and strikes the transducer array 2 approximately in the form of a line or point. Precise pinpoint focusing is not absolutely necessary.
- the reflection surface 4 is formed as a bulge in the tube wall of the tube 3 in order not to hinder the flow of the fluid 1 and, in particular, to cause turbulence that is as small as possible.
- FIG. 3 shows a further embodiment of an ultrasonic flow sensor with a small transducer array 2 and an opposite reflection surface 4.
- the extension of the reflection surface 4 is in this. Embodiment less than the length of the transducer array 2. Adjacent to
- a reflecting device 11 is provided on the reflection surface 4, which attenuates or filters the incident sound signal. That that part of an ultrasonic signal 7 which strikes the anti-dazzle device 11 is not reflected back or only reflected back onto the transducer array 2.
- the dimming device 11 can e.g. as a wall area with a particularly rough surface or e.g. be realized as a grooved area of the inner tube wall.
- sicfi thus produces a pattern with high sound intensity due to that on reflection surface 4 reflected part of signal 7 and lower
- the limits of this pattern in turn shift depending on the flow velocity v of the fluid 1.
- the desired measured variable can again be determined from the position of the pattern.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05701594A EP1728054A1 (de) | 2004-03-18 | 2005-01-24 | Ultraschall-str mungssensor mit wandlerarray und reflextionsfläche |
JP2007503316A JP2007529725A (ja) | 2004-03-18 | 2005-01-24 | 変換器アレイおよび反射面を伴う超音波流速流量センサ |
US10/593,143 US7503225B2 (en) | 2004-03-18 | 2005-01-24 | Ultrasonic flow sensor having a transducer array and reflective surface |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004013251A DE102004013251A1 (de) | 2004-03-18 | 2004-03-18 | Ultraschall-Strömungssensor mit Wandlerarray und Reflexionsfläche |
DE102004013251.8 | 2004-03-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005090929A1 true WO2005090929A1 (de) | 2005-09-29 |
Family
ID=34960123
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/050287 WO2005090929A1 (de) | 2004-03-18 | 2005-01-24 | Ultraschall-strömungssensor mit wandlerarray und reflextionsfläche |
Country Status (6)
Country | Link |
---|---|
US (1) | US7503225B2 (de) |
EP (1) | EP1728054A1 (de) |
JP (1) | JP2007529725A (de) |
KR (1) | KR20070004723A (de) |
DE (1) | DE102004013251A1 (de) |
WO (1) | WO2005090929A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008000577A1 (de) * | 2006-06-26 | 2008-01-03 | Continental Automotive Gmbh | Verfahren und vorrichtung zum messen eines luftmassenstroms mittels ultraschall |
EP2154491A1 (de) * | 2008-08-07 | 2010-02-17 | UAB Minatech | Ultraschallflussmesser, Wandlerbaugruppe und entsprechendes Verfahren |
DE102013101950A1 (de) | 2012-05-03 | 2013-11-07 | Technische Universität Dresden | Anordnung und Verfahren zur Messung einer Strömungsgeschwindigkeit fluider Medien |
WO2019206507A1 (de) * | 2018-04-24 | 2019-10-31 | Endress+Hauser Flowtec Ag | Ultraschallwandler und durchflussmessgerät |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100765383B1 (ko) * | 2007-03-16 | 2007-10-10 | (주)제노정보시스템 | 수막 갈라짐 검출장치 |
GB0722256D0 (en) * | 2007-11-13 | 2007-12-27 | Johnson Matthey Plc | Level measurement system |
WO2010015073A1 (en) * | 2008-08-04 | 2010-02-11 | Mcgill University | Ultrasonic measurement of ph in fluids |
DE102008058376A1 (de) * | 2008-11-20 | 2010-06-02 | Nivus Gmbh | Verfahren und Vorrichtung zur Fluidströmungsmessung |
DE102009046468A1 (de) * | 2009-11-06 | 2011-05-12 | Robert Bosch Gmbh | Ultraschallströmungssensor zum Einsatz in einem fluiden Medium |
DE102012101098A1 (de) * | 2012-02-10 | 2013-08-14 | Endress + Hauser Flowtec Ag | Ultraschall-Durchflussmessgerät und Verfahren zur Ermittlung der Fließgeschwindigkeit bzw. des Volumendurchflusses eines Fluids |
WO2014029404A1 (en) * | 2012-08-22 | 2014-02-27 | Miitors Aps | A compact ultrasonic flow meter |
DE102013105922A1 (de) * | 2013-06-07 | 2014-12-11 | Endress + Hauser Flowtec Ag | Ultraschall-Durchflussmessgerät |
DE102014106429A1 (de) | 2013-07-10 | 2015-01-15 | Sick Ag | Durchflussmessvorrichtung und Verfahren zum Messen der Strömungsgeschwindigkeit eines Fluids |
US9343898B2 (en) * | 2013-07-19 | 2016-05-17 | Texas Instruments Incorporated | Driver current control apparatus and methods |
USD845804S1 (en) | 2017-10-13 | 2019-04-16 | Great Plains Industries, Inc. | Insertion ultrasonic flow meter |
USD845805S1 (en) | 2017-10-13 | 2019-04-16 | Great Plains Industries, Inc. | Tee housing for ultrasonic sensor module |
USD845806S1 (en) | 2017-10-14 | 2019-04-16 | Great Plains Industries, Inc. | Saddle fitting for ultrasonic sensor module |
Citations (4)
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US4484478A (en) * | 1981-10-19 | 1984-11-27 | Haerkoenen Eino | Procedure and means for measuring the flow velocity of a suspension flow, utilizing ultrasonics |
US20020083771A1 (en) * | 2000-07-14 | 2002-07-04 | Khuri-Yakub Butrus T. | Fluidic device with integrated capacitive micromachined ultrasonic transducers |
EP1348954A1 (de) * | 2002-03-28 | 2003-10-01 | Services Petroliers Schlumberger | Vorrichtung und Verfahren zur akustischen Untersuchung eines Bohrlochs mit Hilfe eines phasengesteuerten Ultraschall-Gruppenwandlers |
WO2003091671A1 (en) * | 2002-04-24 | 2003-11-06 | Cidra Corporation | Apparatus and method for measuring parameters of a mixture having solid particles suspended in a fluid flowing in a pipe |
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US4281550A (en) * | 1979-12-17 | 1981-08-04 | North American Philips Corporation | Curved array of sequenced ultrasound transducers |
US4532812A (en) * | 1983-06-30 | 1985-08-06 | Nl Industries, Inc. | Parametric acoustic flow meter |
US4747411A (en) * | 1984-03-28 | 1988-05-31 | National Biochemical Research Foundation | Three-dimensional imaging system |
US5440937A (en) * | 1993-04-30 | 1995-08-15 | Panametrics, Inc. | Process and apparatus for ultrasonic measurement of volumeric flow through large-diameter stack |
US5426678A (en) * | 1993-07-16 | 1995-06-20 | General Electric Company | Method for ultrasonic inspection of a closely packed array of fuel rods surrounded by a thin-walled metallic channel |
US5540230A (en) * | 1994-04-15 | 1996-07-30 | Echocath, Inc. | Diffracting doppler-transducer |
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DE19924319C2 (de) | 1999-05-27 | 2001-05-17 | Bosch Gmbh Robert | Gasmeßfühler |
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2004
- 2004-03-18 DE DE102004013251A patent/DE102004013251A1/de not_active Withdrawn
-
2005
- 2005-01-24 WO PCT/EP2005/050287 patent/WO2005090929A1/de active Application Filing
- 2005-01-24 JP JP2007503316A patent/JP2007529725A/ja active Pending
- 2005-01-24 KR KR1020067018909A patent/KR20070004723A/ko not_active Application Discontinuation
- 2005-01-24 EP EP05701594A patent/EP1728054A1/de not_active Withdrawn
- 2005-01-24 US US10/593,143 patent/US7503225B2/en not_active Expired - Fee Related
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EP1348954A1 (de) * | 2002-03-28 | 2003-10-01 | Services Petroliers Schlumberger | Vorrichtung und Verfahren zur akustischen Untersuchung eines Bohrlochs mit Hilfe eines phasengesteuerten Ultraschall-Gruppenwandlers |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008000577A1 (de) * | 2006-06-26 | 2008-01-03 | Continental Automotive Gmbh | Verfahren und vorrichtung zum messen eines luftmassenstroms mittels ultraschall |
EP2154491A1 (de) * | 2008-08-07 | 2010-02-17 | UAB Minatech | Ultraschallflussmesser, Wandlerbaugruppe und entsprechendes Verfahren |
DE102013101950A1 (de) | 2012-05-03 | 2013-11-07 | Technische Universität Dresden | Anordnung und Verfahren zur Messung einer Strömungsgeschwindigkeit fluider Medien |
WO2019206507A1 (de) * | 2018-04-24 | 2019-10-31 | Endress+Hauser Flowtec Ag | Ultraschallwandler und durchflussmessgerät |
Also Published As
Publication number | Publication date |
---|---|
EP1728054A1 (de) | 2006-12-06 |
DE102004013251A1 (de) | 2005-10-06 |
JP2007529725A (ja) | 2007-10-25 |
US20070261501A1 (en) | 2007-11-15 |
US7503225B2 (en) | 2009-03-17 |
KR20070004723A (ko) | 2007-01-09 |
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