Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
  • C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
  • C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
  • C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
• • A—HUMAN NECESSITIES
  • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
  • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
  • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
  • A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
  • A23L29/35—Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
• • A—HUMAN NECESSITIES
  • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
  • A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
  • A23P10/00—Shaping or working of foodstuffs characterised by the products
  • A23P10/20—Agglomerating; Granulating; Tabletting
  • A23P10/22—Agglomeration or granulation with pulverisation of solid particles, e.g. in a free-falling curtain
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
  • C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
  • C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch

Definitions

• the invention relates on the one hand to a spray-dried starch hydrolysate agglomerate product.
• the invention relates to a method for preparing a spray-dried starch hydrolysate agglomerate product in a spray-drying tower, comprising spraying a liquid material onto a solid powder material, whereby the liquid material is atomised by means of one or more two-fluid nozzles using a fluid for heating and conveying this material, and whereby the agglomerated spray- dried starch hydrolysate is produced by injecting the solid powder material in the top of the drying tower in such a way that the trajectory of the powder crosses the spray pattern of the atomised liquid material.
• Starch hydrolysate products are obtained by the partial hydrolysis of cereal, root or tuber starches. Depending on the degree of hydrolysis, as expressed by the dextrose equivalent (DE), one speaks about maltodextrins (DE ⁇ 20) or glucose (corn) syrups (DE > 20). These starch hydrolysates can be obtained via different manufacturing processes, including a one step enzymatic hydrolysis, a two-step enzyme-enzyme process or a two-step acid-enzyme process.
• DE dextrose equivalent
• Maltodextrins are mainly available commercially in a spray-dried, particulate form. Some of the glucose syrups having a DE between 20 and 30 are also available in a spray-dried particulate form and are known as "corn syrup solids".
• powder products are used as dispersing aids, flavour carriers, bulking agents, humectants, viscosifiers and other functional ingredients. They can work in a wide variety of applications - from dry mixes to fillings and from sauces to beverages.
• the physical characteristics of the powder products are of great importance for their use in this wide range of applications. Important physical properties related to these powders are: bulk density (loose and tapped) and related to these, compressibility; average particle size; - particle size distribution; mechanical stability; flowability; dispersability and related to that, dissolution speed.
• a first type are the standard spray-dried powders which have a relatively high bulk density varying between 0,45 - 0,65 g/cm 3 , an average low particle size and a broad particle size distribution.
• the relatively high bulk density makes these spray-dried powders suitable in the preparation of dry mixes, because phase de-mixing of the different components in these compositions is thereby limited or even prevented.
• the relatively high bulk density further results in less voluminous packaging sizes thereby influencing positively transportation costs per weight unit.
• a major disadvantage however is the relatively high amount of fines (with particle size ⁇ 100 micron), resulting in dusting problems and therefore safety risks, limited or bad flowability and increased compressibility.
• the compacted powders and the glass-like products obtained by these processes do show one or more shortcomings which are related to their physical properties (density, mechanical stability, particle size and/or moisture content) and to the processes used for their manufacture.
• agglomerated spray-dried starch based products and dry-mixes based on these agglomerated spray-dried starch based products are described.
• the agglomerated starch-based product is a homogeneous powder wherein each powder particle is an agglomeration of randomly distributed fine grains.
• these spray-dried agglomerated starch-based products can be prepared by spray-cooking of unmodified (native) or modified starch and maltodextrin in an apparatus such as is described in US 4,280,851.
• the maltodextrin is injected in the top of the spraying tower in such a way that the trajectory of the dry powder crosses the spray pattern of the spray-cooked starch in order to produce spray-dried agglomerated particles.
• the purpose of the invention is therefore to provide a spray-dried starch hydrolysate agglomerate product which combines the advantageous properties of standard spray- dried starch hydrolysates and known spray-dried starch hydrolysate agglomerate products.
• This purpose of the invention is obtained by providing a spray-dried starch hydrolysate agglomerate product, in which the starch hydrolysate has the following properties: - a dextrose equivalent (DE) between 5 and 35; a moisture content of ⁇ 6% by weight; an unpacked bulk density between 0,4 and 0,6 g/cm 3 ; a compressibility of less than 10%; a particle size distribution whereby less than 5% by weight is bigger than 500 micron and less than 5% by weight is smaller than 53 micron; an average particle size of between 150 - 250 micron; a mechanical stability of > 95%; a static angle of repose (SAOR) of less than 45°, as a measure for flowability; and - a dissolution speed of ⁇ 180 seconds.
• DE dextrose equivalent
• SAOR static angle of repose
• a spray-dried starch hydrolysate agglomerate product which has a high bulk density, reduced volume, a high mechanical stability, low dusting, high dissolution speed, higher mean particle size and better particle size distribution.
• the starch hydrolysate has the following properties: a DE between 5 and 35; a moisture content of ⁇ 6% by weight; - an unpacked bulk density between 0,45 and 0,55 g/cm 3 ; a compressibility of less than 5%; a particle size distribution whereby less than 3% by weight is bigger than 500 micron and less than 3% by weight is smaller than 53 micron; an average particle size of between 175 - 230 micron; a mechanical stability of > 97%; - a SAOR of less than 40 °; and a dissolution speed of ⁇ 120 seconds.
• the starch hydrolysate has a dissolution speed of ⁇ 90 seconds.
• a spray-dried starch hydrolysate agglomerate product according to the invention preferably has a DE between of 10 to 22.
• Another purpose of the invention is to provide a method for preparing a spray-dried starch hydrolysate agglomerate product in a spray-drying tower according to the preamble of claim 1, whereby the thus obtained spray-dried starch hydrolysate agglomerate products do show the combined properties of standard spray-dried starch hydrolysates and known spray-dried starch hydrolysate agglomerate products, i.e. a high bulk density, reduced volume, a high mechanical stability, low dusting, high dissolution speed, higher mean particle size and better particle size distribution.
• This purpose is realised by providing a method for preparing a spray-dried starch hydrolysate agglomerate product in a spray-drying tower, comprising spraying a liquid material onto a solid powder material, whereby the liquid material is atomised by means of one or more two-fluid nozzles using a fluid for heating and conveying this material, and whereby the agglomerated spray-dried starch hydrolysate is produced by injecting the solid powder material in the top of the drying tower in such a way that the trajectory of the powder crosses the spray pattern of the atomised liquid material, and wherein the liquid material which is atomised by one or more two-fluid nozzles is a starch hydrolysate solution, whereby this starch hydrolysate solution is atomised using steam as said fluid.
• the starch hydrolysate solution has a concentration of 50 - 75% dry matter, and more preferably, of 65 - 75% dry matter.
• the steam has a pressure between 7 and 15 bar.
• the weight ratio of steam versus starch hydrolysate solution is within the range of 0,05 and 0,4, and preferably between 0,1 and 0,3.
• the heating air which is introduced in the spraying tower has preferably a temperature between 160 and 300 °C, and more preferably between 180 and 250 °C.
• the exiting air has a temperature between 90 and 120 °C.
• the ratio between the solid powder and the starch hydrolysate solution, on a dry weight basis, is preferably between 0,6 and 1,1, and more preferably between 0,8 and 1.
• the dry powder is a starch hydrolysate powder.
• the starch hydrolysate powder is a spray-dried form of the starch hydrolysate solution.
• the agglomerated spray-dried starch hydrolysate particles is brought into a fluidised bed.
• the spray-dried starch hydrolysate agglomerate product according to the invention having the properties as described in the product claims, can be used at the same time for preparing dry mixes, as well as for preparing thickening solutions such as for meat, dairy, baby food or convenience food applications. In these applications, dissolution speed is very important. Improved handling properties with regard to bulk density, mechanical stability, dusting properties (safety) and flowability are of importance in the preparation of dry mixes, but also with regard to storage, dosing and mechanical transportation. As a consequence, such a product will simplify storage installations and transportation means at the costumer, because only one type of product will need to be stored and transported. In order to stabilise the above cited starch hydrolysates, they may be submitted to a state of the art hydrogenation process prior to the spray-drying step, thereby providing hydrogenated starch hydrolysates.
• DE glucose equivalent
• the bulk density of the spray-dried starch hydrolysate agglomerate product is expressed as the unpacked bulk density.
• the unpacked bulk density is determined by weighing a quantity of spray-dried starch hydrolysate agglomerate product of the invention in a glass graduated cylinder of 250 ml. The unpacked density then corresponds to the ratio of the mass of the product and the volume of the product.
• Particle size distribution is determined by sieving 50 g of powder in a Retsch NE1000 shaking device containing sieves of 53, 100, 200, 300 and 500 micron, during 10 minutes using an amplitude of 1,5.
• Average particle size is expressed as the mathematical mean particle size on weight basis of the different fractions obtained from the particle size distribution.
• SAOR static angle of repose
• Dissolution speed corresponds with the time needed to dissolve 20 g of product in 200 ml water at 5 °C in a beaker of 400 ml, whereby the mixture is continuously stirred with a magnetic stirrer at 300 rpm.
• the method according to the invention for preparing a spray-dried starch hydrolysate agglomerate product may be performed in a spray-drying tower as disclosed in EP 1 166 645.
• a spray-drying tower as disclosed in EP 1 166 645.
• other types of spray-drying towers can be used to perform the method.
• the tower which is used in EP 1 166 645 comprises one or more two- fluid spraying nozzles as described in US 4,280,851.
• a starch hydrolysate is injected in the top of the tower in such a way that the trajectory of a solid powder, preferably a dry starch hydrolysate powder, crosses the spray pattern of a starch hydrolysate solution which is atomised by one or more two-fluid nozzles.
• the atomising process of the starch hydrolysate solution in the one or more two-fluid nozzles is performed by first atomising the starch hydrolysate solution into an enclosed chamber, then interjecting steam into the atomised starch hydrolysate solution in the enclosed chamber and finally enabling the atomised starch hydrolysate solution to exit the chamber through a vent aperture into the spraying tower.
• the stream of fines of the starch hydrolysate powder which is injected in the top of the spraying tower is contacted with the sprays from the two- fluid nozzles, using conditions allowing the formation of the spray-dried starch hydrolysate agglomerate product of the invention.
• Important parameters hereby are the concentration and composition of the starch hydrolysate to be agglomerated, the weight ratio of steam to hydrolysate solution, the steam pressure used in the nozzles, the temperature of the heating air in the spraying tower in which the particles are sprayed, the ratio between the starch hydrolysate powder injected in the top of the drying tower and the starch hydrolysate solution fed via the two-fluid nozzles, the feeding rate and the angle under which the spray patterns intersect.
• the starch hydrolysate solution is thereby introduced in the two-fluid nozzles at a concentration of 50 - 75%, preferably 65 - 75% dry matter, while the weight ratio of steam to starch hydrolysate solution may vary between 0,05 and 0,4, preferably between 0,1 and 0,3.
• Steam pressure used may vary between 7 and 15 bar, while the temperature of the heating air which is introduced in the spraying tower is situated between 160 and 300 °C, more preferably between 180 and 250 °C.
• the temperature of the exiting air at the bottom of the spraying tower is between 80 and 125 °C, more preferably between 90 and 120 °C.
• the angle under which the spray patterns intersect will be such that contact of the particles occurs at a location where the particle surface is tacky enough to promote adherence of the particles, but not so close to the nozzle vent apertures that lumping of the spray-dried starch hydrolysate agglomerate product occurs. A.o. this angle will depend on the concentration and composition (DE) of the starch hydrolysate solution, on the circulating air temperature, on feed rate through the nozzles and on the ratio between the starch hydrolysate powder which is injected in the top of the spraying tower and the starch hydrolysate solution that is fed through the two-fluid nozzles.
• An advantageous ratio on dry weight basis is between 0,6 and 1,1, preferably between 0,8 and 1.
• the spray- dried starch hydrolysate agglomerate product can then be brought in a fluidised bed, where the powder is further dried and/or cooled and fines present removed via the air stream.
• the advantageous properties of the product of the invention are illustrated by comparing a number of its properties with spray-dried starch hydrolysate agglomerate products currently commercialised.
• Glucidex 21IT from Roquette Freres, C*Sperse 01321 from Cerestar Holding BV and Granadex SPG20 from ANEBE.
• PSD particle size distribution SAOR: static angle of repose
• Example 2 In this example, dissolution speed at two different temperatures (5 °C and 22 °C) was compared of products of this invention versus state of the art products (see table 3). Non-agglomerated maltodextrins (18DE and 2 IDE), as well as agglomerated counterparts (C*Sperse 01318, C*Sperse 01321, Glucidex IT21) are compared with products of the invention.
• Example 3 Dissolution properties of the spray-dried starch hydrolysate agglomerated products of the invention and other spray-dried starch hydrolysate agglomerated products were compared to the values disclosed in US 4,810,307 (see table 4).
• This patent application describes a process for improving solubility of maltodextrins while retaining relatively high densities. Solubility was expressed as the time needed to dissolve 1 g of product in 240 ml water, without stirring. Nalues disclosed in US 4,810,307 varied between 5,5 minutes and 9 minutes. In table 4, these results are compared with a product of the invention and with commercially available products.

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• Engineering & Computer Science (AREA)
• Polymers & Plastics (AREA)
• Food Science & Technology (AREA)
• Medicinal Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Materials Engineering (AREA)
• Biochemistry (AREA)
• Organic Chemistry (AREA)
• Crystallography & Structural Chemistry (AREA)
• Molecular Biology (AREA)
• Nutrition Science (AREA)
• Polysaccharides And Polysaccharide Derivatives (AREA)
• Processes Of Treating Macromolecular Substances (AREA)
• Jellies, Jams, And Syrups (AREA)
• Medicinal Preparation (AREA)
• Grain Derivatives (AREA)

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• 2004
  • 2004-02-19 ES ES04712562T patent/ES2286608T3/es not_active Expired - Lifetime
  • 2004-02-19 UA UAA200609989A patent/UA81574C2/xx unknown
  • 2004-02-19 CA CA2550533A patent/CA2550533C/en not_active Expired - Fee Related
  • 2004-02-19 AU AU2004315845A patent/AU2004315845B2/en not_active Ceased
  • 2004-02-19 DE DE602004006317T patent/DE602004006317T2/de not_active Expired - Lifetime
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  • 2004-02-19 KR KR1020067016322A patent/KR101319125B1/ko active IP Right Grant
  • 2004-02-19 CN CNB2004800419217A patent/CN100508780C/zh not_active Expired - Fee Related
  • 2004-02-19 NZ NZ548622A patent/NZ548622A/en not_active IP Right Cessation
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  • 2004-02-19 BR BRPI0418555-2A patent/BRPI0418555B1/pt not_active IP Right Cessation
  • 2004-02-19 DK DK04712562T patent/DK1715758T3/da active
  • 2004-02-19 EP EP04712562A patent/EP1715758B1/en not_active Expired - Lifetime
  • 2004-02-19 US US10/590,019 patent/US7819977B2/en not_active Expired - Fee Related
  • 2004-02-19 WO PCT/EP2004/001744 patent/WO2005079595A1/en active IP Right Grant
• 2007
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