WO2005073644A1 - Procede, appareil et systeme pour transferer la chaleur - Google Patents

Procede, appareil et systeme pour transferer la chaleur Download PDF

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Publication number
WO2005073644A1
WO2005073644A1 PCT/AU2005/000083 AU2005000083W WO2005073644A1 WO 2005073644 A1 WO2005073644 A1 WO 2005073644A1 AU 2005000083 W AU2005000083 W AU 2005000083W WO 2005073644 A1 WO2005073644 A1 WO 2005073644A1
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WO
WIPO (PCT)
Prior art keywords
gas
fluid stream
cooling
heat
adsorbent
Prior art date
Application number
PCT/AU2005/000083
Other languages
English (en)
Inventor
Sunil Dutt Sharma
Original Assignee
Commonwealth Scientific And Industrial Research Organisation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2004900376A external-priority patent/AU2004900376A0/en
Application filed by Commonwealth Scientific And Industrial Research Organisation filed Critical Commonwealth Scientific And Industrial Research Organisation
Priority to JP2006549786A priority Critical patent/JP2007519881A/ja
Priority to AU2005207978A priority patent/AU2005207978B2/en
Priority to US10/587,221 priority patent/US20080229766A1/en
Priority to EP05700115A priority patent/EP1711755A4/fr
Priority to CN2005800100047A priority patent/CN1961184B/zh
Publication of WO2005073644A1 publication Critical patent/WO2005073644A1/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
    • F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
    • F25B17/086—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt with two or more boiler-sorber/evaporator units
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F5/00—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater
    • F24F5/0007—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater cooling apparatus specially adapted for use in air-conditioning
    • F24F5/0014—Air-conditioning systems or apparatus not covered by F24F1/00 or F24F3/00, e.g. using solar heat or combined with household units such as an oven or water heater cooling apparatus specially adapted for use in air-conditioning using absorption or desorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]

Definitions

  • An invention is disclosed relating to a method, apparatus and system for transferring heat.
  • the invention finds particular application as a desorption cooler, using the heat of one fluid (gas or liquid) to cool another fluid and, whilst being described in this context, is not so limited.
  • the invention can be applied in reverse, to enhance the cooling of a heated fluid.
  • the invention finds application in a broad range of industries and contexts .
  • US 5,522,228 discloses apparatus for the production of cold by the adsorption and desorption of carbon dioxide.
  • the apparatus comprises two vessels 10,11 packed with activated carbon and zeolite respectively, and connected by a conduit 12 having a valve 13.
  • a heat exchanger 14 is provided around vessel 10 and a heater 15 is provided around vessel 11.
  • vessel 10 is cooled to -50 °C, with the zeolite in vessel 11 at 190 °C.
  • the valve 13 is opened and the carbon dioxide desorbs from the activated carbon, which somehow warms the vessel 10 up to 0°C. However, as desorption would extract heat from the activated carbon, presumably a heated fluid is passed through heat exchanger 14 to warm the vessel 10 up to 0°C. The desorbed carbon dioxide passes to vessel 11 and is adsorbed by the zeolite, which cools to 45°C. Again, as adsorption would heat the zeolite, presumably some type of cooling is employed to cool the vessel 11 to 45°C. The valve is then closed, and vessel 10 is allowed to warm from 0°C to 30°C (ambient temperature) . At the same time vessel 11 is heated by heater 15 from 45°C to 70°C.
  • valve is then opened, and vessel 11 is heated from 70°C to 200°C by heater 15, which desorbs the carbon dioxide from the zeolite and causes it to pass to and adsorb on the activated carbon in vessel 10.
  • heater 15 desorbs the carbon dioxide from the zeolite and causes it to pass to and adsorb on the activated carbon in vessel 10.
  • This causes the activated carbon to cool from 30 °C to -40 °C, presumably by circulating a cooling fluid in heat exchanger 14, as adsorption would heat the activated carbon (ie. thermodynamically self cooling to -40°C is impossible due to the liberation of heat of adsorption) .
  • the heating of vessel 11 is then stopped and it is allowed to cool from 200°C to 190 D C.
  • valve 13 is essential because it is required to maintain the carbon dioxide pressure in vessel 10 during regeneration of the zeolite. If the valve is not closed carbon dioxide will simply desorb from the carbon and pass to the zeolite at the time of pre-cooling of vessel 10, so that little cooling would be observed during the cooling phase. Contrary to the teaching of US 5,522,228, the present invention provides a method, apparatus and system which does not require the complexities of periodic valve closure/opening between two vessels, nor start temperatures in the vicinity of -50 °C.
  • the present invention provides a method for transferring heat using first and second gas adsorbent materials.
  • the second material is relatively thermally isolated from but in continuous gas communication with the first material. The method comprises the steps of:
  • a hot fluid stream eg. a waste gas or process liquid
  • the hot fluid stream can be used to heat the first material so as to desorb the gas adsorbed onto the first material and, at the same time, the hot fluid stream can be cooled.
  • another fluid stream that requires cooling can be brought into thermal communication with the second material so that, when the second material is cooled by desorption therefrom of the gas, the other fluid stream can be cooled.
  • the heat of one stream can be used to cool another.
  • the method can be commenced at ambient temperatures and does not require an external cooling source.
  • pressure changes during operation are immediately translated and accommodated, and do not require additional arrangements such as valving, external heaters etc to compensate therefore.
  • the expression "relatively thermally isolated” is intended to mean that the first and second adsorbent materials are sufficiently thermally isolated such that one can be heated or cooled without affecting the other to an extent that prevents a required/desired cooling desorption (or the reverse) from being attained.
  • thermal isolation can be enhanced by spacing and/or insulating the first and second adsorbent materials from each other.
  • the first material is heated by heat transfer from a relatively hotter fluid stream (eg. via a heat exchange configuration) .
  • the hotter fluid stream can be a process waste gas or liquid.
  • step (i) whilst the first material is being heated, the second material is cooled relative to the first material by heat transfer with a cooling fluid stream.
  • the cooling fluid stream can be eg. a stream of ambient air.
  • the first material is cooled relative to the second material by heat transfer to ambient or by heat transfer with a cooling fluid stream.
  • the cooling fluid stream can be a stream of ambient air.
  • step (ii) whilst the second material is being cooled by desorption therefrom of the gas, it is used to cool another fluid (gas or liquid) stream (eg. via a heat exchange configuration) .
  • the other fluid is a process gas or liquid requiring or benefiting from cooling, and may be eg. ambient air to be cooled and used in the process .
  • the fluids in each of the streams can be gas or liquid.
  • the hot fluid stream can be a process waste or exhaust gas, the heat of which is usually otherwise wasted.
  • heat transfer with a cooling fluid stream is usually achieved by selectively bringing the first and second materials into thermal communication with eg. a stream of ambient air (eg. via the same or a different heat exchange configuration as used for the fluid hot or cooled fluid stream respectively) .
  • the second material is allowed to be slightly heated by heat transfer from the other fluid stream, and so that the second material is heated just enough to restore its temperature to a level which corresponds with its temperature in step (i) prior to gas adsorption thereon, thereby completing a cycle.
  • the first gas adsorbent material has a different adsorptivity to the second gas adsorbent material. In use, this helps provide a driving force for gas movement between the materials.
  • the first gas adsorbent material is a different material to the second gas adsorbent material.
  • the first adsorbent material can comprise a molecular sieve and the second adsorbent material can comprise an activated powder.
  • the first and second adsorbent materials can each comprise a molecular sieve, or each comprise an activated powder, but of different adsorptivities .
  • the or each molecular sieve can be a zeolite
  • the or each activated powder can be an activated carbon
  • the gas employed with the first and second adsorbent materials can be carbon dioxide.
  • this gas is pressurised relative to ambient pressure.
  • a typical operating pressure in the method for the gas is around 0.5 MPa.
  • the gas and first and second materials are generally at ambient temperature.
  • the present invention provides heat transfer apparatus comprising a chamber having a first portion which contains a first adsorbent material and a second portion which contains a second adsorbent material, the apparatus characterised in that the portions are connected so as to always allow continuous gaseous communication therebetween and are relatively thermally isolated from each other.
  • the inventor has observed that an apparatus having thermally isolated portions can advantageously achieve desorption cooling (and the reverse) whilst the first and second adsorbent materials are always maintained in continuous gaseous communication (ie. without requiring a valve or stop therebetween to achieve a desorption cooling cycle) .
  • This provides, for example, a simplification over the apparatus of US 5,522,228, which requires a valve.
  • first and second chamber portions are joined by a section which is adapted to minimise conductive heat transfer between the first and second portions whilst allowing the continuous gaseous communication between the portions.
  • the section is usually a conduit having a relatively smaller width (eg. smaller diameter, or smaller effective diameter) than the width (eg. diameter or effective diameter) of the first and second chamber portions adjacent thereto. Because the conduit has a smaller width it has less surface area/dimension for heat transfer, and yet still provides for continuous gas communication between the portions.
  • first and second chamber portions and the conduit are each tubular, whilst typically the first and second chamber portions are approximately the same size.
  • each heat transfer element comprises a metal wire mesh that enhances thermal communication between an exterior of the chamber portion (via a wall of the chamber portion) and the adsorbent material therein.
  • the heat transfer elements have also been found to enhance the mass transfer rate of the gas (eg. carbon dioxide) through each of the first and second adsorbent materials.
  • the first and second materials are each packed into a respective portion of the chamber.
  • the first and second materials are as defined in the first aspect of the invention.
  • first and second chamber portions are each adapted to be positioned midstream of a respective flow of fluid, to more effectively transfer heat between the respective fluid and portion.
  • the present invention provides a system for continuously transferring heat from a first fluid stream and for continuously cooling a second fluid stream.
  • the system comprises first and second apparatus each able to be brought into thermal communication with the first and second fluid streams .
  • Each apparatus comprises a chamber having separated first and second adsorbent materials, and each apparatus is operable in the following stages whereby: (1) the first material is heated by thermal communication with the first fluid stream so as to desorb a gas adsorbed onto the first material whereby the gas passes to and is adsorbed onto the second material; and (2) the first material is cooled so that the gas is desorbed from the second material and passes therefrom to be re-adsorbed onto the first material, with the second material being cooled by desorption therefrom of the gas, and the second fluid stream being cooled by thermal communication with the second material .
  • the system is characterised in that:
  • the system advantageously provides for continuous transfer of heat from the first fluid stream and continuous cooling of the second fluid stream.
  • the system comprises a plurality of first apparatus and a plurality of second apparatus, and typically the first and second apparatus are operated in parallel.
  • the system further comprises valving for selectively switching the flow of the first and second fluid streams respectively between the first and second apparatus and the second and first apparatus, to maintain a continuous transfer of heat from the first fluid stream and a continuous cooling of the second fluid stream.
  • the valving can also be used to switch a cooling fluid stream between the first and second apparatus, such as a stream of ambient air.
  • each of the first and second apparatus is as defined in the second aspect and typically each apparatus is operated using the method of the first aspect.
  • FIG. 2 shows a schematic view of a desorption cooling system according to the invention and employing a plurality of the desorption chiller modules of Figure 1;
  • FIGS. 3a and 3b show schematic side and plan views of a demonstration unit for use in desorption cooling of a gas
  • FIG. 4 is a graph plotting temperature against time for the temperature locations T8, T4 and T6 for the regenerator of the unit of Figure 3 ;
  • - Figure 5 is a graph plotting temperature against time for the temperature locations T5 and T3 for the desorption cooler of the unit of Figure 3 ; and - Figure 6 is a graph plotting temperature against time for the temperature locations Tl, T6, T4, T3 and T5 for the demonstration unit of Figure 3.
  • a method, apparatus and system according to the invention is used to transfer heat energy (eg. waste heat) from a gas or liquid stream to achieve a separate cooling purpose (eg. the cooling of another separate fluid stream) .
  • a simple apparatus according to the invention is shown in the form of a desorption chiller module.
  • the module comprises a sealed vessel 10 having two cylindrical chambers (eg. tubes, such as stainless steel tubes) , being a regenerator chamber 12 and a desorption cooler chamber 14.
  • the chambers are connected by a joining section in the form of a narrower (eg. smaller diameter) conduit or neck 16 (such as a smaller diameter tube) .
  • the conduit 16 can be formed from a material having lesser thermal conductivity than the chamber walls (eg. a less thermally conductive stainless steel) and is typically welded to the chamber walls to seal the vessel 10.
  • Regenerator chamber 12 is packed with a first adsorbent material, typically in the form of a molecular sieve (eg. a zeolite such as a 13X zeolite) and the desorption cooler chamber 14 is packed with either a different second adsorbent material (eg. a surface activated powder such as activated carbon) or the same material but having a different adsorptivity (eg. another type of zeolite but having, for example, a lesser adsorptivity eg.
  • a molecular sieve eg. a zeolite such as a 13X zeolite
  • second adsorbent material eg. a surface activated powder such as activated carbon
  • adsorptivity eg. another type of zeolite but having,
  • One or more heat transfer elements in the form of a plurality of discrete metal wire mesh panels are preferably arranged in each of the chambers 12&14, together with the first and second adsorbent materials (ie. the panels are dispersed through the adsorbent material) .
  • the panels are typically formed from a material not reactive to the gas and materials in vessel 10, such as stainless steel, brass, aluminium or copper, and of a material having sufficient thermal conductivity. The panels function to enhance thermal conductivity between the adsorbent material and the wall and thus exterior of each chamber.
  • the sealed vessel 10 further comprises a suitable pressurised gas, typically carbon dioxide because of its abundance and ease of use; but other gases can be used such as refrigerants, ammonia, alcohol, water (steam) , nitrogen etc in combination with adsorbents suitable to the gas .
  • a suitable pressurised gas typically carbon dioxide because of its abundance and ease of use; but other gases can be used such as refrigerants, ammonia, alcohol, water (steam) , nitrogen etc in combination with adsorbents suitable to the gas .
  • the sealed vessel 10 is configured such that the gas can pass continuously and unhinderedly between each of the chambers 12,14 via the conduit 16.
  • no valving or additional flow control is provided or required and, as a further advantage, the sealed vessel has no moving parts.
  • the sealed vessel 10 is typically configured so that the desorption cooler chamber 14 (housing the second adsorbent material) is, at least to an operable extent, thermally isolated from the regenerator chamber 12 (housing the first adsorbent material) .
  • This is optimally achieved by employing the narrower conduit 16 to connect but space apart the chambers.
  • thermal isolation can be further enhanced by employing appropriately positioned insulation, including insulation barriers and baffles in, around and/or between the chambers (see eg. the system of Figure 2 described below) .
  • the first adsorbent material is selected to have a higher adsorptivity for the vessel gas then the second adsorbent material.
  • the regenerator chamber 12 is contacted with a relatively hot gas stream (eg. a process waste gas) by arranging the regenerator chamber in the centre or midpoint of the hot gas stream and so that the first adsorbent material is heated.
  • the hot gas stream can be passed over, around or even through chamber 12 (eg. via one or more pipes/tubes extending through chamber 12) .
  • adsorbed gas eg. carbon dioxide
  • the gas pressure in the vessel increases e.
  • the relatively cooler second material eg. activated carbon
  • the second material becomes slightly heated.
  • the tendency of the gas to adsorb onto the second material can be enhanced by arranging the chamber 14 in the centre or midpoint of a cooling gas stream (eg. a stream of ambient air) such that the second material is further cooled relative to the first material.
  • the first material eg. zeolite molecular sieve
  • the regenerator chamber 12 is then cooled (eg. by stopping or redirecting the flow of hot gas and, more typically, by contacting the chamber 12 with a cooling gas stream (eg. ambient air) .
  • a cooling gas stream eg. ambient air
  • the first material cools and the pressure of carbon dioxide in the vessel is reduced.
  • the gas is desorbed from the second material and passes from chamber 14 via conduit 16 into chamber 12 and re-adsorbs onto the first material.
  • the desorption of the carbon dioxide from the second material in chamber 14 cools the second adsorbent material (ie.
  • the gas needs to extract heat from the material during its desorption) and thus cools the chamber 14 and the walls thereof.
  • the second chamber can be cooled by greater than 10 °C below ambient temperature as gas desorption progresses.
  • the same or another fluid stream can be passed over, around or even through chamber 14 (eg. through one or more heat exchange pipes/tubes arranged therethrough) , so that the other fluid stream is cooled.
  • cooled chamber 14 can be used, for example, to pre-cool a stream for eg. an engine or gas turbine, or to provide cooling air for air conditioning etc.
  • a hot process fluid eg. waste gas
  • FIG. 2 where like reference numerals are used to denote similar or like parts, a desorption cooling system 20 according to the invention is depicted.
  • the system can provide for continuous desorption cooling in accordance with the invention.
  • the system 20 employs a plurality of the sealed desorption chiller vessels 10 of Figure 1, the vessels arranged in parallel, in each of parallel module banks A and B. Each module bank is in turn arranged in a respective bank vessel 22.
  • each bank vessel 22 comprises a thermal barrier wall 24 positioned to divide each regenerator chamber 12 from its respective desorption cooler chamber 14 (except for conduit 16, which extends through wall 24) .
  • Barrier wall 24 thus further enhances the thermal isolation of chambers 12 and 14.
  • Barrier wall 24 can also be formed from and/or lined with an insulating material.
  • barrier wall 24 now defines a regenerator chamber 26 and a desorption cooler chamber 28 in each bank vessel 22.
  • four-way valves 30,30' are arranged for selectively directing fluids (eg. gases) into the bank vessels 22 of the module banks A and B.
  • four-way valve 30 can selectively direct a hot process gas 32 (eg.
  • four-way valve 30' can selectively direct a process gas requiring cooling (eg. an air stream) into one of the desorption cooler chambers 28, whilst simultaneously directing a cooling gas 36 (eg. an ambient air stream) into the other of the desorption cooler chambers 28.
  • the stream of cooling gas 36 is split and directed into both desorption cooler chambers 28, one stream for a cooling purpose (ie. in one of the chambers 28) and the other stream to be cooled to produce a chilled air stream 38 (ie.
  • the four-way valves 30,30' are controlled such that eg. whilst the regenerator chamber 26 of module A is receiving hot process gas 32 therein to facilitate gas desorption from each of the first adsorbent materials, the regenerator chamber 26 of module B is receiving cooling gas 34 therein to facilitate gas adsorption on each of the first adsorbent materials (ie. as controlled by four-way valve 30) .
  • the desorption cooler 28 of module A is receiving cooling gas 36 therein to facilitate gas adsorption on each of the second adsorbent materials
  • the desorption cooler 28 of module B is receiving to- be-chilled gas 36 therein as gas desorption from each of the second adsorbent materials takes place (ie. as controlled by four-way valve 30')
  • the gas flows for each of the four-way valves 30,30' are switched, so that the subsequent process stage can take place in each of the modules A & B.
  • the system 20 advantageously provides for the continuous transfer of heat from the hot process gas 32 and for the continuous chilling of the gas 36. Further, by switching the gas streams, the system allows for continuous as opposed to interrupted desorption cooling. Alternatively, the system can facilitate a process that is the reverse of desorption cooling.
  • Non-limiting Examples of the method, apparatus and system will now be described. EXAMPLE 1 .
  • the desorption chiller module of Figure 1 was tested and then calculated to have a coefficient of performance (COP) of 0.22 (cf a theoretical COP of less than 0.054 for the system of US5, 522, 228) . This calculation was made using the system of US 5,522,228 as a basis as follows.
  • the module of Figure 1 was calculated to have a COP of 0.22.
  • the desorption cooling system of Figure 2 was then calculated to have a COP much higher than 0.22, attributed to the much greater homogeneous heating achieved in each of modules A and B, together with less heat loss therefrom because of module containment within bank vessels 22.
  • FIG. 3a&b A schematic diagram of the demonstration unit is shown in Figures 3a&b, where like reference numerals are used to denote similar or like parts to those of Figures 1&2.
  • the demonstration unit 40 comprised one of the two modules A and B as shown and described in Figure 2. Experiments were performed to study and optimize one of the modules to collect relevant performance and design data, and thereby enable scale up and scale down in the design of commercial modules .
  • the demonstration unit comprised 102 identical chiller modules 10 (as shown in Figure 1) .
  • the chiller modules were stacked in insulated regenerator and desorption cooler chambers 26,28, with each chiller module conduit 16 extending through wall 24.
  • insulated inlet 41,42,44 and outlet 46 ducts were provided to/from the chambers 26,28 to maximize heat transfer efficiencies and minimize heat losses.
  • the regenerator chamber inlet was connected to a hot air source and an ambient air source .
  • the hot air source comprised an electrical heater 48 in airflow communication with a coaxial fan 50 (Fan 2) to produce hot air at various desired flow rates and temperatures.
  • the ambient air source comprised another coaxial fan 52 (Fan 3) .
  • a manually operated damper 54 was employed between the hot air source and the ambient air source to selectively switch between hot and ambient air.
  • the desorption cooler chamber 28 was also connected to an ambient air source which comprised a third coaxial fan 56 (Fan 1) .
  • Thermocouples were placed appropriately at regenerator inlet (T1,T8), regenerator outlet (T4) , regenerator (T6) , desorption cooler inlet (T3) , regenerator outlet (T4) , and desorption cooler outlet (T5) , to sense and continuously record temperature changes during operation.
  • a data logging computer connected to the thermocouples was used to record the temperatures during test runs .
  • the data logging computer was switched on to record the temperature T at various locations as indicated on the unit 40 in Figure 3a. 2.
  • the damper 54 was manually switched to allow hot air flowing via the heater 48 into the regenerator 26, and then the fan 50 (Fan 2) and heater 48 were switched on.
  • the fan 56 (Fan 1) was switched on to remove any heat generated due to adsorption in the desorption cooler chamber 28.
  • regeneration fan 52 (Fan 3) was switched off.
  • the inlet air temperature slightly increased during each run. This was partially due to heat released from the fan motor but was also due to a change in room temperature resulting from minor losses from the insulated surface of the heater, regenerator and associated ducts.
  • the flow rates used for the trial runs were based on a heat transfer model. Air flow was estimated from the air velocity in a meter long 310mm internal diameter duct fitted at the inlet of each fan. A digital anemometer (manufacturer Lutron, Model YK-2001AL) was used for velocity measurements. Relative humidity and temperature in the vicinity of the demonstration unit were measured using an electronic hygrometer (manufacturer Erler & Weinkauff) with +10% accuracy.
  • thermocouples were also tested on a regular basis. Temperatures were recorded up to the second place after the decimal and they had a maximum 10% error. Based on the temperature and flow rates measured for more than 50 trial runs, the cooling capacity of the desorption cooler was estimated to be around 900-1200 kJ, with the Coefficient of Performance (COP) varying between 0.07 to 0.12, depending on heat losses, humidity, efficiency of regeneration and measurement error. This indicated that favourable performance could be achieved in a commercial scale-up. Tests were also conducted to optimize the operating conditions to achieve maximum cooling capacity and COP. The performance of a single module was tested for about 1 year and the demonstration unit was tested for more than six months, and no deterioration in performance in either case was observed. Table 1 Operating conditions during run #76:

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Abstract

L'invention concerne un procédé, un appareil et un système pour transférer la chaleur à l'aide d'un premier matériau adsorbant un gaz et d'un second matériau adsorbant un gaz, qui est relativement isolé thermiquement du premier matériau mais en communication gazeuse continue avec ce dernier. Une première étape consiste à chauffer le premier matériau, de façon à désorber un gaz adsorbé sur le premier matériau, le gaz passant au second matériau et étant adsorbé sur ce dernier. Dans une seconde étape, le premier matériau est refroidi, de sorte que le gaz est désorbé du second matériau et retourne au premier matériau adsorbant pour être réabsorbé sur ce dernier. Lorsque le gaz est désorbé du second matériau, ce dernier est alors refroidi. Ainsi, un flux de gaz chaud peut être utilisé pour refroidir un autre flux de gaz.
PCT/AU2005/000083 2004-01-28 2005-01-25 Procede, appareil et systeme pour transferer la chaleur WO2005073644A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2006549786A JP2007519881A (ja) 2004-01-28 2005-01-25 熱転送方法と、熱転送装置およびシステム
AU2005207978A AU2005207978B2 (en) 2004-01-28 2005-01-25 Method, apparatus and system for transferring heat
US10/587,221 US20080229766A1 (en) 2004-01-28 2005-01-25 Method, Apparatus and System for Transferring Heat
EP05700115A EP1711755A4 (fr) 2004-01-28 2005-01-25 Procede, appareil et systeme pour transferer la chaleur
CN2005800100047A CN1961184B (zh) 2004-01-28 2005-01-25 用于传热的方法、装置和系统

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AU2004900376 2004-01-28
AU2004900376A AU2004900376A0 (en) 2004-01-28 Method, apparatus and system for transferring heat

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WO2005073644A1 true WO2005073644A1 (fr) 2005-08-11

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US (1) US20080229766A1 (fr)
EP (1) EP1711755A4 (fr)
JP (1) JP2007519881A (fr)
CN (1) CN1961184B (fr)
AU (1) AU2005207978B2 (fr)
WO (1) WO2005073644A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008109937A1 (fr) * 2007-03-09 2008-09-18 Commonwealth Scientific And Industrial Research Organisation Appareil et procédé de transfert thermique
WO2010047820A3 (fr) * 2008-10-24 2010-06-17 Exxonmobil Research And Engineering Company Système utilisant de la chaleur inutilisée pour refroidir et/ou générer du courant
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US8425674B2 (en) 2008-10-24 2013-04-23 Exxonmobil Research And Engineering Company System using unutilized heat for cooling and/or power generation
US9097445B2 (en) 2008-10-24 2015-08-04 Exxonmobil Research And Engineering Company System using unutilized heat for cooling and/or power generation
WO2011119808A1 (fr) * 2010-03-25 2011-09-29 Exxonmobil Research And Engineering Company Procédé de protection d'un adsorbant solide et adsorbant solide protégé
US8500887B2 (en) 2010-03-25 2013-08-06 Exxonmobil Research And Engineering Company Method of protecting a solid adsorbent and a protected solid adsorbent
US8814986B2 (en) 2010-03-25 2014-08-26 ExxonMobil Research and Egineering Company Method of protecting a solid adsorbent and a protected solid adsorbent

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AU2005207978B2 (en) 2009-07-30
CN1961184B (zh) 2010-06-23
AU2005207978A1 (en) 2005-08-11
US20080229766A1 (en) 2008-09-25
EP1711755A4 (fr) 2011-03-09
EP1711755A1 (fr) 2006-10-18
JP2007519881A (ja) 2007-07-19

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