Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
  • C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
  • C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K7/00—Use of ingredients characterised by shape
  • C08K7/22—Expanded, porous or hollow particles
  • C08K7/24—Expanded, porous or hollow particles inorganic
  • C08K7/28—Glass
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K9/00—Use of pretreated ingredients
  • C08K9/04—Ingredients treated with organic substances

Definitions

• the present invention relates to a filled resin composite.
• fillers into resin compositions to adjust the physical properties of the resultant compositions (often referred to as "composites” or “filled composites”) such as reduce the density thereof, or reduce cost by reducing the proportion of relatively expensive resin with cheaper materials.
• fillers include solid particulates such as titanium dioxide, glass, etc.
• hollow particles such as hollow glass bubbles.
• glass bubbles have often been used to successfully reduce density of the final composite, in many cases the glass bubbles are crushed during manipulation of the composite, thereby impairing the desired reduction in density.
• resin composites containing glass bubbles have often exhibited undesirable loss of desired physical properties such as tensile strength.
• Non-reinforcing fillers can be defined as any particle with an aspect ratio (length over diameter) less than 2. It is assumed that the loss in mechanical strength is due primarily to the filler causing a disruption of the polymer chains and also due to the inefficient bonding between the polymer and the filler; where the bond strength is assumed to be less than the tensile strength of the polymer chains themselves.
• Illustrative examples of filled resin composites are disclosed in U.S. Patent No.
• a composite of the invention comprises apolyamide such as nylon, e.g., nylon-6,6 (e.g., (Zytel 101L from Dupont)) and blends of nylon (e.g., NORYL GTX a blend of nylon and polyphenylene ether available from GE), and glass bubbles .
• apolyamide such as nylon, e.g., nylon-6,6 (e.g., (Zytel 101L from Dupont)) and blends of nylon (e.g., NORYL GTX a blend of nylon and polyphenylene ether available from GE), and glass bubbles .
• the glass bubbles have been treated with aminopropyltriethoxysilane ("APS") prior to incorporation into the composite.
• APS aminopropyltriethoxysilane
• the glass bubbles should exhibit a crush strength of at least 10,000 PSI to withstand many extrusion operations. In some embodiments, they will preferably exhibit a crush strength of at least 18,000 PSI to withstand injection molding as well as extrusion operations.
• the strength of the glass bubbles is typically measured using ASTM D3102- 72; "Hydrostatic Collapse Strength of Hollow Glass Microspheres".
• the invention provides filled nylon-6,6 composites that can be used to create lightweight parts which require the tensile properties of standard, i.e., unfilled nylon-6,6. Furthermore, molded parts made from filled nylon-6,6 will also have reduced shrinkage after molding (due to displaced polymer) and other benefits over standard nylon-6,6.
• lightweight parts with good tensile properties will include sporting goods for reduced user fatigue and/or increases in performance, transportation (automotive, aerospace, etc.) parts for fuel savings, improved acceleration or higher top speed, and reduced fuel emissions.
• parts made for "structural" applications are not suitable candidates for nylon-6,6 with non-reinforcing fillers.
• lightweight structural parts can now be made with filled nylon-6,6.
• the present invention may be used with commercially available glass bubble fillers for use in resin composites.
• the bubbles are of the high strength variety such as
• ScotchliteTM Glass Bubbles S60HS which are soda-lime-borosilicate glass. These bubbles exhibit an isostatic crush strength of 18,000 psi, density of 0.60 g/cc, and average diameter of about 30 microns .
• Tensile Modulus was determined following ASTM Test Method D-638 and is reported in
• Elongation at Break was determined following ASTM Test Method D-638 and is reported as %.
• Density A fully automated gas displacement pycnometer obtained under the trade designation "ACCUPYC 1330 PYCNOMETER” from Micromeritics, Norcross, Georgia, was used to determine the density of the injection molded composite material according to ASTM D-2840-69, "Average True Particle Density of Hollow Microspheres".

Landscapes

• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Priority Applications (3)

Applications Claiming Priority (2)

Publications (1)

Family

ID=34748885

Family Applications (1)

Country Status (5)

Cited By (6)

Families Citing this family (13)

Citations (3)

Family Cites Families (4)

• 2004
  • 2004-12-30 WO PCT/US2004/043826 patent/WO2005066251A1/en not_active Ceased
  • 2004-12-30 US US10/585,023 patent/US20070155858A1/en not_active Abandoned
  • 2004-12-30 CN CNA2004800396639A patent/CN1902270A/zh active Pending
  • 2004-12-30 JP JP2006547534A patent/JP2007517127A/ja not_active Withdrawn
  • 2004-12-30 EP EP04815824A patent/EP1699856A1/en not_active Withdrawn

Patent Citations (3)

Also Published As

Similar Documents

Legal Events