WO2005061417A3 - Procede de fluorodesazotation - Google Patents

Procede de fluorodesazotation Download PDF

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Publication number
WO2005061417A3
WO2005061417A3 PCT/FR2004/003241 FR2004003241W WO2005061417A3 WO 2005061417 A3 WO2005061417 A3 WO 2005061417A3 FR 2004003241 W FR2004003241 W FR 2004003241W WO 2005061417 A3 WO2005061417 A3 WO 2005061417A3
Authority
WO
WIPO (PCT)
Prior art keywords
fluorodenitrogenation
nitrogen
carbon
relates
nitrosonium
Prior art date
Application number
PCT/FR2004/003241
Other languages
English (en)
Other versions
WO2005061417A2 (fr
Inventor
Laurent Saint-Jalmes
Thierry Vidal
Original Assignee
Rhodia Chimie Sa
Laurent Saint-Jalmes
Thierry Vidal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa, Laurent Saint-Jalmes, Thierry Vidal filed Critical Rhodia Chimie Sa
Priority to EP04805714A priority Critical patent/EP1694616A2/fr
Publication of WO2005061417A2 publication Critical patent/WO2005061417A2/fr
Publication of WO2005061417A3 publication Critical patent/WO2005061417A3/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00Halogenation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06Preparation of nitro compounds
    • C07C201/12Preparation of nitro compounds by reactions not involving the formation of nitro groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention a pour objet un procédé de fluorodésazotation. Ce procédé de fluorodésazotation vise à désazoter les liaisons multiples carbone-azote et consiste à soumettre un substrat porteur de ladite liaison multiple carbone-azote à l'action d'un réactif comportant un composé susceptible de constituer un précurseur de nitrosonium (NO+), et comportant de l'acide fluorhydrique ou l'un de ses complexes acides. Applications à la fonctionnalisation en regroupements fluorométhylés ou difluorométhylés.
PCT/FR2004/003241 2003-12-18 2004-12-15 Procede de fluorodesazotation WO2005061417A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP04805714A EP1694616A2 (fr) 2003-12-18 2004-12-15 Procede de fluorodesazotation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0314881A FR2864076B1 (fr) 2003-12-18 2003-12-18 Procede de fluorodesazotation
FR0314881 2003-12-18

Publications (2)

Publication Number Publication Date
WO2005061417A2 WO2005061417A2 (fr) 2005-07-07
WO2005061417A3 true WO2005061417A3 (fr) 2005-11-17

Family

ID=34630283

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2004/003241 WO2005061417A2 (fr) 2003-12-18 2004-12-15 Procede de fluorodesazotation

Country Status (4)

Country Link
EP (1) EP1694616A2 (fr)
CN (1) CN1910123A (fr)
FR (1) FR2864076B1 (fr)
WO (1) WO2005061417A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967389A (zh) * 2010-10-27 2011-02-09 大庆油田有限责任公司 一种直接从页岩油中脱除碱性氮化合物的脱氮剂

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2972639A (en) * 1959-08-24 1961-02-21 Rohm & Haas Process for the preparation of fluorohydrocarbons
DD276689A1 (de) * 1988-11-01 1990-03-07 Univ Leipzig Verfahren zur darstellung fluorierter oxaheterocyclen
FR2672284A1 (fr) * 1991-02-04 1992-08-07 Rhone Poulenc Chimie Procede et reactif pour la synthese de composes halogenes.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2972639A (en) * 1959-08-24 1961-02-21 Rohm & Haas Process for the preparation of fluorohydrocarbons
DD276689A1 (de) * 1988-11-01 1990-03-07 Univ Leipzig Verfahren zur darstellung fluorierter oxaheterocyclen
FR2672284A1 (fr) * 1991-02-04 1992-08-07 Rhone Poulenc Chimie Procede et reactif pour la synthese de composes halogenes.

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
ADAMS D J ET AL: "Aromatic trifluoromethyldenitration and trifluoromethyldecyanation using trifluoromethyltrimethylsilane", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1, CHEMICAL SOCIETY. LETCHWORTH, GB, no. 18, 1998, pages 3081 - 3085, XP002252893, ISSN: 0300-922X *
G.A.OLAH ET AL: "Synthetic methods and reactions. 63. Pyridinium poly(hydrogen fluoride) (30% pyridine-70% hydrogen fluoride): A convenient reagent for organic fluorination reactions", J.ORG.CHEM., vol. 44, no. 22, 1979, pages 3872 - 3881, XP002252892 *
J.A. ATTAWAY ET AL: "The action of elementary fluorine upon organic compounds. XXII. The fluorination of some amides, nitriles and of methyl thiocyanate", J.AM.CHEM.SOC., vol. 81, 1959, pages 3599 - 3603, XP002294729 *

Also Published As

Publication number Publication date
FR2864076B1 (fr) 2006-02-10
WO2005061417A2 (fr) 2005-07-07
EP1694616A2 (fr) 2006-08-30
FR2864076A1 (fr) 2005-06-24
CN1910123A (zh) 2007-02-07

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