WO2005056566A3 - Verfahren zur herstellung von orthometallierten und orthosubstituierten aromatischen verbindungen - Google Patents
Verfahren zur herstellung von orthometallierten und orthosubstituierten aromatischen verbindungen Download PDFInfo
- Publication number
- WO2005056566A3 WO2005056566A3 PCT/EP2004/053388 EP2004053388W WO2005056566A3 WO 2005056566 A3 WO2005056566 A3 WO 2005056566A3 EP 2004053388 W EP2004053388 W EP 2004053388W WO 2005056566 A3 WO2005056566 A3 WO 2005056566A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- atoms
- group
- alkyl
- bound
- orthometalated
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- -1 hydrocarbon aromatic compound Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000006263 metalation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/6584—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having one phosphorus atom as ring hetero atom
- C07F9/65848—Cyclic amide derivatives of acids of phosphorus, in which two nitrogen atoms belong to the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002548925A CA2548925A1 (en) | 2003-12-12 | 2004-12-10 | Method for producing orthometalated and orthosubstituted metallocences |
JP2006543551A JP2007513923A (ja) | 2003-12-12 | 2004-12-10 | オルトメタレート及びオルト置換された芳香族化合物の製造方法 |
DE502004009799T DE502004009799D1 (de) | 2003-12-12 | 2004-12-10 | Verfahren zur herstellung von orthometallierten und orthosubstituierten aromatischen verbindungen |
EP04820077A EP1692149B1 (de) | 2003-12-12 | 2004-12-10 | Verfahren zur herstellung von orthometallierten und orthosubstituierten aromatischen verbindungen |
US10/582,404 US7435840B2 (en) | 2003-12-12 | 2004-12-10 | Method for producing orthometalated and orthosubstituted metallocenes |
IL175994A IL175994A0 (en) | 2003-12-12 | 2006-05-29 | Method for producing orthometalated and orthosubstituted metallocenes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH02134/03 | 2003-12-12 | ||
CH21342003 | 2003-12-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2005056566A2 WO2005056566A2 (de) | 2005-06-23 |
WO2005056566A3 true WO2005056566A3 (de) | 2005-12-01 |
Family
ID=34658635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/053388 WO2005056566A2 (de) | 2003-12-12 | 2004-12-10 | Verfahren zur herstellung von orthometallierten und orthosubstituierten aromatischen verbindungen |
Country Status (8)
Country | Link |
---|---|
US (1) | US7435840B2 (de) |
EP (1) | EP1692149B1 (de) |
JP (1) | JP2007513923A (de) |
CN (1) | CN1890253A (de) |
CA (1) | CA2548925A1 (de) |
DE (1) | DE502004009799D1 (de) |
IL (1) | IL175994A0 (de) |
WO (1) | WO2005056566A2 (de) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE602005003572T2 (de) * | 2004-05-07 | 2008-04-17 | Umicore Ag & Co. Kg | Ferrocenylliganden für homogene, enantioselektive hydrierungskatalysatoren |
EP2256229A1 (de) * | 2005-11-04 | 2010-12-01 | Sulzer Metaplas GmbH | Schichtsystem zur Bildung einer Oberflächenschicht auf einer Oberfläche eines Substrats, Beschichtungsverfahren und Substrat mit einem Schichtsystem |
CN113845545A (zh) * | 2015-07-23 | 2021-12-28 | 赢创运营有限公司 | 用于烷氧基羰基化的丁基-桥连的二膦配体 |
EP3666782A1 (de) * | 2018-12-11 | 2020-06-17 | Umicore Ag & Co. Kg | Lithiumalkylaluminate, verwendung eines lithiumalkylaluminats als transferreagenz, verfahren zur übertragung wenigstens eines restes r, verbindungen e(x)q-prp und deren verwendung, substrat und verfahren zur herstellung von lithiumalkylaluminaten |
CN116178455B (zh) * | 2023-04-26 | 2023-08-18 | 江苏欣诺科催化剂股份有限公司 | 一种二茂铁类手性膦配体的制备方法 |
Citations (8)
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EP0803510A1 (de) * | 1996-04-25 | 1997-10-29 | Hoechst Aktiengesellschaft | 2,2'-Disubstituierte 1,1'-Diphosphino-ferrocene und 1',2-disubstiuierte 1-Phoshino-ferrocene, Verfahren zu ihrer Herstellung, ihre Verwendung sowie sie enthaltende Übergangsmetallkomplexe |
EP0842140B1 (de) * | 1995-07-27 | 2000-04-05 | Novartis AG | Verfahren zur hydrierung von iminen |
DE10052391A1 (de) * | 2000-10-20 | 2002-05-02 | Aventis Res & Tech Gmbh & Co | Bidentate Organophosphorliganden |
WO2002083695A1 (de) * | 2001-03-29 | 2002-10-24 | Basf Aktiengesellschaft | Liganden für pnicogenchelatkomplexe mit einem metall der viii. nebengruppe und verwendung der komplexe als katalysatoren für hydroformylierung, carbnonylierung, hydrocyanierung oder hydrierung |
WO2003031456A2 (en) * | 2001-10-05 | 2003-04-17 | Solvias Ag | Ligands for asymmetric reactions |
WO2003048107A1 (de) * | 2001-12-03 | 2003-06-12 | Bayer Chemicals Ag | Arylierung von olefinen |
WO2003076451A1 (de) * | 2002-03-13 | 2003-09-18 | Degussa Ag | Ferrocenylliganden und ihre verwendung in der katalyse |
WO2003093285A1 (de) * | 2002-04-30 | 2003-11-13 | Degussa Ag | Ferrocenylliganden und ein verfahren zur herstellung solcher liganden |
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US4221744A (en) * | 1978-12-01 | 1980-09-09 | Celanese Corporation | Hydroformylation process employing rhodium-based catalysts comprising ligands having electronegative substituents |
PL320698A1 (en) * | 1994-11-29 | 1997-10-27 | Lonza Ag | Method of obtaining optically active metalocenylophosphines |
EP0729969B1 (de) * | 1995-02-24 | 2000-08-16 | Novartis AG | Silylierte Ferrocenyldiphosphine, an anorganische oder polymere organische Träger gebundene silylierte Ferrocenyldiphosphine sowie Metallkomplexe davon, ihre Herstellung und Verwendung |
ATE212032T1 (de) * | 1996-07-10 | 2002-02-15 | Syngenta Participations Ag | Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendung |
US5817850A (en) * | 1997-10-30 | 1998-10-06 | Ciba Specialty Chemicals Corporation | Ferrocene bis(phosphonite) ligands and complexes for transition-metal-catalyzed reactions |
US6034240A (en) * | 1998-03-09 | 2000-03-07 | Symyx Technologies, Inc. | Substituted aminomethylphosphines, coordination complexes of aminomethylphosphines and their synthesis |
DE19952348A1 (de) * | 1998-12-19 | 2000-06-21 | Degussa | Liganden und Komplexe zur enantioselektiven Hydrierung |
AU2001236912A1 (en) * | 2000-02-10 | 2001-08-20 | The Penn State Research Foundation | Chiral ferrocene phosphines and their use in asymmetric catalytic reactions |
MXPA02012519A (es) * | 2000-07-03 | 2003-10-14 | Solvias Ag | Ferrocenil-difosfinas y su uso. |
US6590115B2 (en) * | 2000-09-29 | 2003-07-08 | Eastman Chemical Company | Phosphino-aminophosphines |
US6362354B1 (en) * | 2000-11-17 | 2002-03-26 | E. I. Du Pont De Nemours And Company | Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same |
US6620954B1 (en) * | 2002-03-25 | 2003-09-16 | Eastman Chemical Company | Phosphinometallocenylamides as novel ligands for asymmetric catalysis |
JP4633047B2 (ja) * | 2003-05-09 | 2011-02-16 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | 均一系水素化触媒のための配位子としての置換フェロセニルジホスフィン |
US7375241B2 (en) * | 2003-12-12 | 2008-05-20 | Solvias A.G. | Ferrocenyl-1,2-diphosphines, the production thereof and their use |
-
2004
- 2004-12-10 WO PCT/EP2004/053388 patent/WO2005056566A2/de active Application Filing
- 2004-12-10 US US10/582,404 patent/US7435840B2/en not_active Expired - Fee Related
- 2004-12-10 JP JP2006543551A patent/JP2007513923A/ja not_active Withdrawn
- 2004-12-10 CN CNA2004800366756A patent/CN1890253A/zh active Pending
- 2004-12-10 CA CA002548925A patent/CA2548925A1/en not_active Abandoned
- 2004-12-10 EP EP04820077A patent/EP1692149B1/de not_active Not-in-force
- 2004-12-10 DE DE502004009799T patent/DE502004009799D1/de not_active Expired - Fee Related
-
2006
- 2006-05-29 IL IL175994A patent/IL175994A0/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0842140B1 (de) * | 1995-07-27 | 2000-04-05 | Novartis AG | Verfahren zur hydrierung von iminen |
EP0803510A1 (de) * | 1996-04-25 | 1997-10-29 | Hoechst Aktiengesellschaft | 2,2'-Disubstituierte 1,1'-Diphosphino-ferrocene und 1',2-disubstiuierte 1-Phoshino-ferrocene, Verfahren zu ihrer Herstellung, ihre Verwendung sowie sie enthaltende Übergangsmetallkomplexe |
DE10052391A1 (de) * | 2000-10-20 | 2002-05-02 | Aventis Res & Tech Gmbh & Co | Bidentate Organophosphorliganden |
WO2002083695A1 (de) * | 2001-03-29 | 2002-10-24 | Basf Aktiengesellschaft | Liganden für pnicogenchelatkomplexe mit einem metall der viii. nebengruppe und verwendung der komplexe als katalysatoren für hydroformylierung, carbnonylierung, hydrocyanierung oder hydrierung |
WO2003031456A2 (en) * | 2001-10-05 | 2003-04-17 | Solvias Ag | Ligands for asymmetric reactions |
WO2003048107A1 (de) * | 2001-12-03 | 2003-06-12 | Bayer Chemicals Ag | Arylierung von olefinen |
WO2003076451A1 (de) * | 2002-03-13 | 2003-09-18 | Degussa Ag | Ferrocenylliganden und ihre verwendung in der katalyse |
WO2003093285A1 (de) * | 2002-04-30 | 2003-11-13 | Degussa Ag | Ferrocenylliganden und ein verfahren zur herstellung solcher liganden |
Non-Patent Citations (6)
Title |
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ALMENA PEREA J J ET AL: "Synthesis and application of C2-symmetric diamino FERRIPHOS as ligands for enantioselective Rh-catalyzed preparation of chiral alpha-amino acids", TETRAHEDRON: ASYMMETRY, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 10, no. 2, 29 January 1999 (1999-01-29), pages 375 - 384, XP004158858, ISSN: 0957-4166 * |
DAVIS M ET AL: "The synthesis of certain chelating ditertiary phosphines", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL SOCIETY. LETCHWORTH, GB, 1964, pages 3786 - 3790, XP002160687, ISSN: 0368-1769 * |
DREWELIES K ET AL: "o- and m- Phenylene- bis(dichlorophosphane)-versatile, useful synthetic building blocks", ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, VERLAG CHEMIE. WEINHEIM, DE, vol. 21, no. 8, 1982, pages 638 - 639, XP002192246, ISSN: 0570-0833 * |
KOTTSIEPER K W ET AL: "Synthesis of enantiopure C1 symmetric diphosphines and phosphino-phosphonites with ortho-phenylene backbones", TETRAHEDRON: ASYMMETRY, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 12, no. 8, 21 May 2001 (2001-05-21), pages 1159 - 1169, XP004245864, ISSN: 0957-4166 * |
MEHRING, MICHAEL ET AL: "The First Rigid O,C,O-Pincer Ligand and Its Application for the Synthesis of Penta- and Hexacoordinate Organotin(IV) Compounds", ORGANOMETALLICS , 17(6), 1227-1236 CODEN: ORGND7; ISSN: 0276-7333, 1998, XP002323768 * |
REETZ M T ET AL: "New non-C2-symmetric phosphine-phosphonites as ligands in asymmetric metal catalysis", TETRAHEDRON: ASYMMETRY, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 10, no. 11, 4 June 1999 (1999-06-04), pages 2129 - 2137, XP004174097, ISSN: 0957-4166 * |
Also Published As
Publication number | Publication date |
---|---|
CN1890253A (zh) | 2007-01-03 |
EP1692149B1 (de) | 2009-07-22 |
JP2007513923A (ja) | 2007-05-31 |
EP1692149A2 (de) | 2006-08-23 |
IL175994A0 (en) | 2006-10-05 |
US20070149796A1 (en) | 2007-06-28 |
DE502004009799D1 (de) | 2009-09-03 |
US7435840B2 (en) | 2008-10-14 |
WO2005056566A2 (de) | 2005-06-23 |
CA2548925A1 (en) | 2005-06-23 |
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