WO2005038347A2 - Appareil d'allumage de milieux combustibles - Google Patents
Appareil d'allumage de milieux combustibles Download PDFInfo
- Publication number
- WO2005038347A2 WO2005038347A2 PCT/US2004/033140 US2004033140W WO2005038347A2 WO 2005038347 A2 WO2005038347 A2 WO 2005038347A2 US 2004033140 W US2004033140 W US 2004033140W WO 2005038347 A2 WO2005038347 A2 WO 2005038347A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrogen
- containing gas
- catalytic material
- tubular housing
- source
- Prior art date
Links
- 239000001257 hydrogen Substances 0.000 claims abstract description 94
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 94
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 93
- 239000007789 gas Substances 0.000 claims abstract description 84
- 239000000463 material Substances 0.000 claims abstract description 47
- 230000003197 catalytic effect Effects 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 230000001590 oxidative effect Effects 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000003570 air Substances 0.000 claims description 73
- 230000015572 biosynthetic process Effects 0.000 claims description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000012080 ambient air Substances 0.000 claims description 4
- 230000000712 assembly Effects 0.000 claims description 4
- 238000000429 assembly Methods 0.000 claims description 4
- 239000006262 metallic foam Substances 0.000 claims 2
- 230000000977 initiatory effect Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 53
- 238000005755 formation reaction Methods 0.000 description 31
- 239000003054 catalyst Substances 0.000 description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 22
- 239000007800 oxidant agent Substances 0.000 description 20
- 239000000446 fuel Substances 0.000 description 17
- 229930195733 hydrocarbon Natural products 0.000 description 17
- 150000002430 hydrocarbons Chemical class 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 239000000567 combustion gas Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 229910052697 platinum Inorganic materials 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- -1 shale Substances 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 5
- 239000003245 coal Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003466 anti-cipated effect Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000000644 propagated effect Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010892 electric spark Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
- E21B43/243—Combustion in situ
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
- E21B36/02—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones using burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q11/00—Arrangement of catalytic igniters
Definitions
- the present invention relates to ignition systems, particularly catalytic ignition systems. More particularly, the present invention relates to apparatuses employing such ignition systems that can be used in remote environments to ignite a combustible mixture, e.g., a hydrocarbon/oxygen gas containing mixture.
- a combustible mixture e.g., a hydrocarbon/oxygen gas containing mixture.
- Ignition systems for igniting a combustible mixture at a remote location are used in a variety of applications.
- ignition systems can be used to ignite combustible mixtures issuing from flare stacks in refineries, chemical plants, etc.
- a prime example of the use of an ignition system in a remote environment is their use in igniting burners disposed in earth boreholes drilled into a subterranean formation.
- the subterranean formation is one that contains a hydrocarbonaceous material e.g., coal, shale, tar sands, oil, etc.
- one or more heat sources is installed into a subterranean, hydrocarbon (oil) containing formation to heat the formation, one of the goals being to raise the temperature in the formation above the pyrolyzation temperature of the hydrocarbons in the formation.
- the ' 081 Publication describes numerous embodiments and systems for supplying heat, preferably at pyrolysis temperatures, to the oil containing formation to vaporize and/or pyrolyze the oil and convert at least a portion of the oil to more valuable and more easily recoverable hydrocarbons, the produced more valuable hydrocarbons being recovered from the subterranean formation.
- Flameless combustors are demonstrated, for example, in U.S. Patents 5,255,742, 5,404,952, 5,862,858, 5,899,269, and 6,269,882, all of which are incorporated herein by reference. Most of these flameless combustors operate by preheating a fuel and combusting it to a temperature above an auto ignition temperature of the mixture. The fuel and combustion air are then mixed in the heating zone to combust. In the heating zone, the flameless combustor, and a catalyst surface may be provided to lower the auto ignition temperature of the fuel and air mixture. It clearly would be desirable to have an ignition source or system which could be positioned in the wellbore, e.g.
- the present invention can include an ignition system which can be positioned in a relatively small diameter tubing e.g. a 3" I.D.
- tubing which is disposable in an earth borehole and which will ignite a combustible fuel e.g. a mixture of a hydrocarbon and an oxidizing gas, e.g., air, without the use of electrical heaters, preheating of gases, etc.
- a combustible fuel e.g. a mixture of a hydrocarbon and an oxidizing gas, e.g., air
- the present invention can employ a composition of matter which, when exposed to a first gas/oxygen containing gas (oxidizer) mixture, results in an exothermic reaction causing the temperature of the composition of the matter to be elevated above the auto ignition temperature of the first gas with consequent ignition of the first gas/oxidizer mixture to produce a pilot flame.
- the resulting pilot flame can be propagated into (1 ) a burner ignition zone to ignite a fuel mixture supplied to suitable bumer(s), or (2) or near the opening in a flare stack from which is issuing a combustible medium to ignite the combustible mediums.
- a series of ignition systems as described above in conjunction with a series of burners which can be spaced axially along the inside of a burner tubing positioned in an earth borehole so as to provide a multiplicity of heat generating sources along the length of the tubing.
- the hot combustion gases flowing towards the bottom of the tubing disposed in the wellbore can then exit the bottom of the tubing and flow up the annulus between the burner tubing and a second concentrically disposed tubular, e.g., casing, surrounding the burner tubing.
- the hot combustion gases can flow into the annulus between the burner tubing and the formation in the case of an open, uncased borehole.
- air from the surface can be pumped down through the burner tubing, the air being heated by the combustion gases and/or the flame from the burners.
- Yet another preferred aspect of the present invention can include an igniter/burner module wherein an igniter system, as described above, is mounted, on, in or in sufficiently close proximity to a burner that is supplied with a combustible fuel.
- the burner may take the form of one or more nozzles, jets or openings in a burner block or housing, the burner being supplied with a combustible fuel mixture, the igniter system being positioned sufficiently close to at least one nozzle so that it will ignite the combustible fuel mixture issuing from the nozzle and subsequently all other nozzles.
- Still a further preferred aspect of the present invention can include an apparatus for igniting a combustible medium issuing from an opening in a flare stack, the apparatus including an igniter assembly having a support, a catalytic material carried by the support, the catalytic material comprising a substance which reacts with a hydrogen containing gas in the presence of an oxidizing gas to produce an exothermic reaction and preferably a temperature sufficient to cause auto ignition of the hydrogen, a source of the hydrogen-containing gas and a source of the oxidizing gas.
- FIG. 1 is an elevational, sectional view of one embodiment of an igniter assembly used in the apparatus of the present invention.
- Fig. 2 is an elevational, sectional view of another embodiment of the igniter assembly used in the apparatus of the present invention.
- Fig. 3 is an elevational, sectional view of another embodiment of the igniter assembly used in the apparatus of the present invention.
- Fig. 4 is an elevational view, partly in section of another embodiment of the igniter assembly used in the apparatus of the present invention.
- Fig. 5 is an elevational view of an igniter assembly in accordance with one embodiment of the present invention used with a flare stack.
- Fig. 6 is an elevational view of another embodiment of the igniter assembly of the present invention used with a flare stack.
- Fig. 1 is an elevational, sectional view of one embodiment of an igniter assembly used in the apparatus of the present invention.
- Fig. 2 is an elevational, sectional view of another embodiment of the igniter assembly used in the apparatus of the present invention.
- Fig. 3 is
- FIG. 7 is an elevational view of another embodiment of the igniter assembly of the present invention used with a flare stack.
- Fig. 8 is an elevational view, partly in section of a portion of an igniter wand employing an igniter assembly in accordance with the present invention.
- Fig. 9 is an elevational view showing the igniter wand as connected to the source of a hydrogen-containing gas.
- Fig. 10 is an elevational view, partly in section, showing a plurality of igniter assembly/burner modules in a tubing in a earth borehole which is in a subterranean formation containing hydrocarbonaceous materials.
- Fig. 11 is an elevational view, partly in section, showing in greater detail the igniter assembly/burner module shown in Fig. 10.
- Fig. 12 is a cross-sectional view taken along the lines 12-12 of Fig. 11.
- the present invention comprises a self-igniting system which includes a chamber or support, a source of a first gas and an oxygen containing gas (oxidizer) to the chamber or the support, and a composition of matter disposed in the chamber or supported on the support that reacts with the first gas/oxidizer to preferably cause auto ignition of the first gas and oxidizer mixture to produce a flame or at least increases the temperature of the composition of matter to a point which could result in ignition of a combustible mixture e.g. a hydrocarbon such as methane, the system being positioned in tubing or other such earth bore hole tubulars, e.g., tubing, casing, etc.
- a combustible mixture e.g. a hydrocarbon such as methane
- the self-igniting system can be used to ignite a combustible mixture issuing from an opening in a flare stack, the self-igniting system being supported sufficiently close to, or in the opening in the flare stack to effect ignition of the issuing combustible mixture.
- the oxidizer is an oxidizing gas of the type that will support combustion. Typically, the oxidizer will be an oxygen containing gas, e.g., air, O 2 , etc.
- the interaction or reaction between the first gas (hydrogen-containing gas) and the composition of matter produces an exothermic reaction, which can raise the temperature of the composition of matter to above the auto ignition temperature of the first gas.
- the first gas is hydrogen
- the oxidizer is air
- the composition of matter is a platinum group metal, e.g., palladium, in any form, which when contacted with the hydrogen/oxidizer mixture results in the catalyzed reaction of hydrogen and the oxygen in the air.
- the hydrogen/air mixture contacts the catalytic material, the temperature of the platinum/palladium, etc., is elevated well above
- the auto ignition temperature of hydrogen i.e., greater than about 1 ,080°F.
- hydrogen/air mixture ignites and results in a flame that can be propagated to a burner ignition zone to ignite a combustible mixture issuing from a suitable burner assembly into the burner igniter zone.
- a burner ignition zone to ignite a combustible mixture issuing from a suitable burner assembly into the burner igniter zone.
- hydrogen and oxygen will not react automatically when mixed together because of the large activation energy needed to initiate the reaction.
- the mechanism of the reaction is extremely complex and that one of the initiation steps is breaking of the bond between the two hydrogen atoms of the hydrogen molecule which requires 432kJ/mole. This energy is typically initially provided by " a spark or flame. After the reaction begins, the energy produced from it will provide the necessary energy to continue breaking apart the hydrogen molecules.
- a catalyst provides an alternative mechanism that has a lower activation energy that allows the reaction to proceed without the requirement of the initial addition of energy via a flame or spark.
- Hydrogen molecules will adsorb to the platinum or palladium surface.
- the energy of the interaction between the hydrogen atoms and the platinum or palladium surface contributes to the breaking of the bond between the hydrogen atoms in the hydrogen molecule.
- the separate hydrogen atoms are then free to react at the surface or leave the surface and participate in the water forming steps.
- the invention also contemplates that other gases or mixtures thereof can be brought into contact with other compositions of matter, also presently unknown to the inventor, which will result in a catalyzed auto ignition of such other gases in the presence of a suitable oxidizer such as air, oxygen or the like.
- a suitable oxidizer such as air, oxygen or the like.
- the particular form of the composition of matter, e.g., the platinum or palladium-containing material will vary depending upon the end-use, the specific design of the support or housing for the catalyst and other factors.
- the platinum can be disposed or carried on an inert refractory-type carrier such as alumina, silica, titanic, etc., which can be in the form of pellets, granules or formed bodies, e.g., a compacted mass of the platinum group metal/carrier mixture.
- the platinum group containing material can also take the form of a sponge.
- applicant has found that platinum supported on a foam-like structure made of a material known as Fecralloy and marketed by CRI Catalyst Company can be used to form an excellent catalytic material for use in the present invention.
- the Fecralloy which is in the form of a hard foam pad or sponge normally contains 22 percent chromium, 5.3 percent aluminum, a small amount of yithrium in addition to iron.
- the Fecralloy material can withstand temperatures in excess of 2000°F.
- FIG. 1 there is shown one embodiment of the igniter assembly used in the apparatus of the present invention.
- the igniter assembly shown generally as 10, comprises a tubular housing 12 which is attached at one end to an air intake, manifold 14 and at the opposite end to a flame propagation tube 16. Received in manifold 14 is a conduit 18 through which a hydrogen- containing gas flows from a source not shown. Manifold 14 is provided with a series of openings 20 which can be in generally surrounding relationship to conduit 18.
- conduit 18 faces the throat portion of a Venturi-type tube 24 attached to tubular housing 12.
- Venturi tube 24 also forms a retainer for a hollow cylindrical section 26 of a suitable catalytic material as described above.
- Tube 16 also serves as a retainer to hold section 26 in position in tubular housing 12.
- a hydrogen-containing gas passing through conduit 18 under pressure passes into the throat of Venturi tube 24 and then into the hollow core 27 of catalyst section 26.
- the flow of the hydrogen- containing gas through conduit 18 toward the throat of tube 24 results in an aspirating effect whereby air from an ambient source is drawn in through holes 20 of manifold 14.
- This flame front propagates out tube 16 at a high velocity and can ignite a combustible mixture that it contacts such as a combustible mixture from a burner or other suitable piece of equipment, e.g., a flare stack, it being understood that the combustible mixture include an oxygen- containing gas from a suitable source.
- a combustible mixture that it contacts such as a combustible mixture from a burner or other suitable piece of equipment, e.g., a flare stack, it being understood that the combustible mixture include an oxygen- containing gas from a suitable source.
- the burning velocity of hydrogen in air is between about 2.7 to about 3.5 m/sec.
- the flame temperature is extremely hot, the flame temperature for a 19.6 percent by
- a modified tubular housing 26A is secured to a tubular extension 30 in which is disposed a conduit 32 through which a hydrogen-containing gas from a source (not shown) flows.
- Tubular extension 32 extends through a manifold block 34 which has an annulus 36 in surrounding relationship to tubular extension 32 and which is in open communication with an L-shaped port 38 which in turn is in open communication with a conduit 40 through which an oxygen-containing gas, e.g., air, or other types of oxidizer flows under pressure from a source, e.g., a compressor (not shown).
- an oxygen-containing gas e.g., air
- a source e.g., a compressor
- the hydrogen issuing from the end 42 of tubular extension 32 mixes with the air passing through conduit 40, port 38, annulus 36 and annulus 31 and passes into the throat of tube 24 resulting in an exothermic reaction and a burst of flame as described above with respect to the embodiment of Fig. 1.
- Fig. 3 there is shown yet another embodiment of the igniter assembly for use in the apparatus of the present invention.
- a tubular housing shown generally as 50 has an upset portion 52 which forms an annular recess 54 in which is disposed a tubular catalyst section 56 as described above with respect to catalyst section 26.
- Tubular housing 50 also has an extended flame front propagation tube 58.
- Secured to tubular housing 50 is an annular flange 60 forming an annular air intake 62 in surrounding relationship to an extension 64 of tubular housing 50, extension 64 being secured to upset portion 52.
- Extension 64 is also provided with a series of openings or apertures 66 which communicate with air intake 62.
- a hydrogen feed tube 68 having a tapered tip 70 forming a nozzle. The end of extension 64 threadedly receives a gland 72 which in turn threadedly receives a fitting 74.
- Fitting 74 is threadedly engaged by a nut 76, a ferrule 78 being disposed between nut 76 and fitting 74. It will be understood, in the well known manner, that when nut 76 is tightened onto fitting 74, ferrule 78 will form a fluid-tight seal around hydrogen feed tube 68.
- hydrogen from a source not shown flows under pressure through feed tube 68 and aspirates air through openings 66, the mixture of the hydrogen-containing gas and the air flowing into the portion of housing 52 forming recess 54 where it contacts catalyst section 56.
- catalyst section 56 is of a generally hollow cylindrical configuration and is conveniently made of a material as described above with respect to the embodiments discussed above.
- FIG. 4 wherein the air or oxygen supply is from a forced air source through a tube 80 into an annular plenum 82 formed by an annular housing 84 which is attached to extension 64 of housing 58.
- the operation of the embodiment shown in Fig. 4 is substantially the same as that described above with respect to Fig. 3. It is to be noted that the use of forced air from a bottle source or other clean air source provides an advantage in that contamination of the catalyst is minimized. In this regard, air from some ambient sources can contain soot and other particulates which, over time, can effect the efficiency of the catalyst.
- a flare stack 90 has an opening 92 through which waste gases containing combustible gases would ordinarily escape to atmosphere if not burnt.
- an igniter assembly shown generally as 96, which is substantially the igniter assembly shown in Fig. 3, and includes a flame propagation tube 100 terminating in a nozzle or burner tip 102.
- Hydrogen is supplied, under pressure, via hydrogen feed line 104 from a flow meter 106 connected to a line 108 which in turn is connected to a hydrogen source (not shown).
- a flame is intermittently supplied to burner 102 as needed.
- the system of Fig. 5 can be automated by the use of solenoid control systems or other logic control systems to provide hydrogen to the igniter assembly when ignition is required.
- Fig. 6 there is shown another embodiment of the present invention involving a flare stack. As in the case of the embodiment shown in Fig. 5, the ignition assembly shown generally as 96 is attached to a flame propagation tube 112. It will be noted that with respect to the embodiments shown in Figs.
- Air to be mixed with the hydrogen is by means of aspiration of ambient air as shown in Fig. 3 rather than by forced air being introduced as shown in Fig. 4.
- a system such as shown in Fig. 4 could be employed in either of the embodiments of Figs. 5 or 6.
- Flame propagation tube 112 is attached to a pilot burner 114. Pilot burner 114 is in turn attached to a tube 115 to which is connected to an air aspirator 116 into which the end of a flow line 118 terminates Methane, propane, or some light hydrocarbon gas from a source not shown flows through flow line 118 into aspirator 116 where it mixes with air and then flows through tube 115 to pilot burner 114.
- Fig. 7 shows yet another embodiment of the invention for use with a flare stack.
- the embodiment shown in Fig. 7 differs from that shown in Fig. 6 in that the igniter assembly, shown generally as 120 is substantially the same as described with respect to the embodiment shown in Fig. 4, i.e., instead of being an air aspiration system, the embodiment shown in Fig. 7, like the embodiment shown in Fig.
- a forced air system wherein air via a line 124 is supplied through a flowline126 from a line 128 from a source such as an air compressor or the like, not shown.
- hydrogen supplied to igniter assembly 120 is connected to a solenoid valve 130 forming part of an automatic flare pilot ignition system which typically incorporate thermocouples, optical flame monitors or the like which detect the absence of any flame, i.e., no pilot flame.
- solenoid valve 130 would open such that hydrogen would be supplied to igniter assembly 120 ultimately resulting, as described above, in the ignition of a pilot flame from pilot burner 114 via methane or the like being supplied via line 118.
- Figs. 8 and 9 show a simplified hand-held wand employing an igniter assembly of the present invention.
- the igniter assembly shown in Fig. 8 is of a self-aspirating type substantially like that shown in Fig. 1.
- a wand 140 has disposed therein, a catalyst section carrier 142, catalyst section 144, being in the form of a hollow cylinder with a central opening 146.
- a retainer 148 together with Venturi tube 150 hold catalyst section 144 in place.
- a hydrogen feed line 152 running through wand 140 supplies hydrogen which aspirates air through holes 154 in wand 140, holes 154 being located just upstream of tube 150.
- a hydrogen supply line 154 connected to a source of hydrogen such as a tank 156 is connected by a coupling 158 to wand 140.
- FIG. 10 there is shown a typical subterranean usage of the apparatus of the present invention.
- An earth formation 200 has drilled therein a borehole 204, borehole 204, as seen, having a vertical section 206 which extends to the surface and a generally horizontal section 208 running generally parallel to the surface.
- casing 210 Disposed in the borehole 204 is casing 210, casing 210 being cemented via cement 212 in the vertical section 206.
- the horizontal section 208 of borehole 204 forms an annulus around casing 210 but it will be recognized that it could be filled with substances which aid heat conductivity or transfer, if desired.
- casing 210 extends into a formation 214 containing hydrocarbonaceous materials such as coal, oil, heavy oils, tar sands, shale oil or the like.
- tubing 216 Disposed generally concentrically in casing 210 is tubing 216 which like casing 210 has a vertical section and a generally horizontal section.
- tubing 216 Disposed in tubing 216 are a series of igniter assembly/burner modules shown generally as 218 and described more fully hereafter. As can be seen, modules 218 are staggered along the length of tubing 216.
- the burners B of modules 218 are ignited by means of the ignition assemblies C, air being forced down tubing 216 from a compressor or other source of forced air.
- the air moving down tubing 216 is heated by combustion gases and the flames issuing from the burner of modules 218.
- the mixture of hot air and combustion gases exits the end 220 of tubing 216 and passes upward in the annulus 222 between tubing 216 and casing 210.
- the heated air combustion gases moving through the annulus 222 heats casing 210 and ultimately the air or other material in borehole 204 surrounding casing 210 eventually heating the hydrocarbonaceous-containing formation 214.
- hydrocarbons in the formation 214 are vaporized and/or pyrolyzed to smaller more valuable and more easily recoverable molecules which can then be recovered by a production well shown generally as 230 which extends down into formation 214.
- Modules 218 comprise a burner B have a housing forming a chamber 246A, chamber 246A being also defined by a front wall 242 in which are positioned a series of holes 244 (see Fig. 12) and a back wall 243.
- Chamber 246A essentially forms an annular plenum inside housing 240.
- a main methane supply line 246 which as seen in Fig. 10 extends through wall 242 and passes through each of the igniter assembly/burner modules 218.
- a slip stream of methane is removed from supply line 246 via a conduit 248 and introduced via a fitting assemblage 250 into an aspirator housing 280.
- Aspirator housing 280 as seen, is a tubular member having a series of holes 282 and is attached to wall 243.
- Conduit 248 extends into aspirator housing 280 and terminates in a tapered tip or nozzle 284.
- a manifold 252 is connected to a main air supply line 254 by means of a conduit 256.
- Air supply line 254 runs from the surface along the full length of the tubing to feed successive igniter assembly/burner modules 218.
- Manifold 252 is also connected via a conduit 258 to a hydrogen supply line 260 which as in the case of the methane line 246 and air line 254 extends to the surface and feeds all of the igniter assembly/burner modules 218 staggered along the length of tubing 216.
- air and hydrogen are admixed and contact the catalyst segment such as shown in Fig.
- the apparatus of the present invention utilizes, as can be seen from the above, a tubular housing in which is disposed the catalytic material.
- the catalytic material is in the form of a tube disposed in the tubular housing as seen, for example, in Fig. 1.
- the catalytic material need not be in the form of a tube as noted above.
- the catalyst material could be in the form of pellets, granules or the like, held in a perforate housing disposed in the tubular housing.
- the geometry of the igniter assembly is such that the tubular housing in which the catalytic material is positioned has a flame front propagation tube attached to the tubular housing at one end.
- the flame front propagation tube can vary in length from about 2 inches up to about 15 feet depending upon the particular application.
- a Venturi- type arrangement is preferably employed. In this regard and again as noted in Fig.
- Venturi tube at the mouth of which the hydrogen-containing gas and the oxidizing gas mix and then flow at a higher velocity through the tubular housing containing the catalytic material.
- the presence of the Venturi tube increases the velocity of flow of the hydrogen-containing gas and the oxidizer through the tubular housing and hence through the bore through the cylinder of catalytic material.
- auto ignition of the hydrogen occurs with a flame front which moves in both directions along the tubular member, i.e., toward the end to which the flame propagation tube is attached and toward the end through which the Venturi tube is attached.
- the flame propagation travels through the flame propagation tube and essentially acts as a spark at the source of a combustible fuel which can be issuing from a pilot burner, a burner, a flare stack or the like.
- a combustible fuel which can be issuing from a pilot burner, a burner, a flare stack or the like.
- only a small flame of hydrogen will remain lit at the outlet of the hydrogen feed tube.
- the tip of the hydrogen tube nozzle or the like through which the hydrogen under pressure is flowing is displaced somewhat axially from the start of the catalyst section.
- the tip of the hydrogen tube, nozzle, etc. could be positioned so as to be in the hollow core in the catalyst section.
- the hydrogen- containing gas be introduced into the tubular housing in the form of a stream as opposed to simply being diffused into the tubular housing. It is believed that by introducing a stream of the hydrogen-containing gas into the tubular housing containing the catalyst section, there results in a more uniform self-ignition of the hydrogen in the catalyst section thereby providing better flame propagation and enhancing the "spark-like" igniting capability of the igniter assembly used in the present invention.
- the ignition system of the present invention provides a virtually foolproof method to ignite a combustible gas or other combustible mixture in a remote environment such as in a tubular member disposed in an earth borehole or in connection with a flare stack.
- the unique igniter assembly of the present invention can be designed for multiple burners, e.g., 15 to 40, which can be spaced along a length of tubing disposed in a borehole. It is also anticipated that the burner output from each burner will be 50,000 to 125,000 BTU/hr.
- the igniter assembly of the present invention will be capable of handling inlet combustion
- the igniter assembly/burner module will fit inside a 3" I.D. burner tube. It is anticipated that the service life of the igniter assemblies will be 3-5 years with little to no maintenance.
- the marked novelty of the igniter system of the present invention is best demonstrated by the fact that under the parameters set out above, e.g., having to dispose the burners in a 3" I.D. tube, in downhole conditions at elevated temperatures, in the presence of moisture and with a repetitive and long lifetime, it accomplishes what electric igniters or any other heretofore known ignition systems cannot accomplish. It overcomes the difficulty of having to protect ignition wires in a hard wired system using an electric igniter from prolonged
- the igniter assembly used in the apparatus of the present invention generally falls into two categories.
- the combustion air required for auto ignition of the hydrogen-containing gas is supplied to the igniter assembly from the surrounding ambient air by introducing hydrogen into a Venturi at a sufficient velocity.
- the Venturi effect causes the required amount of oxidizer gas to be drawn into the Venturi tube where it is mixed with the hydrogen-containing gas and then introduced to the catalyst section.
- the second basic type of igniter assembly is of the forced air type wherein the oxidizer required for auto ignition of the hydrogen-containing gas supplies to the igniter assembly by an air compressor or any other controlled air source, e.g., pressurized bottled air.
- an air compressor or any other controlled air source e.g., pressurized bottled air.
- a flow meter, regulator, orifice plate or any other means of accurately controlling airflow can provide the desired specific amounts of combustion air into the igniter assembly.
- This type of igniter assembly is particularly suited for applications where purity of the ambient or surrounding outside air is in question.
- the hydrogen is introduced into the tubular housing which holds the catalyst under a pressure to ensure flow of the hydrogen-containing gas/oxidizer through the tubular housing and into contact with the catalyst contained therein.
- the hydrogen pressure will range from about 0.1 to about 3 psi with flow rates from about 50 to about 1400 cc/sec.
- the method can include simply heating the formation to make the oil less viscous whereby it can be pumped more efficiently, i.e., without the necessity for vaporizing and/or pyrolyzing any of the oil.
- the igniter assembly in combination with the flare stack provides an easy and efficient method of igniting combustible mixtures issuing from a flare stack and eliminates the need for spark igniters, continual pilot flames, etc.
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Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/574,611 US20070042306A1 (en) | 2003-10-10 | 2004-10-07 | Apparatus for igniting combustible mediums |
CA002541169A CA2541169A1 (fr) | 2003-10-10 | 2004-10-07 | Appareil d'allumage de milieux combustibles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50981303P | 2003-10-10 | 2003-10-10 | |
US60/509,813 | 2003-10-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2005038347A2 true WO2005038347A2 (fr) | 2005-04-28 |
WO2005038347A3 WO2005038347A3 (fr) | 2005-08-18 |
Family
ID=34465115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2004/033140 WO2005038347A2 (fr) | 2003-10-10 | 2004-10-07 | Appareil d'allumage de milieux combustibles |
Country Status (3)
Country | Link |
---|---|
US (1) | US20070042306A1 (fr) |
CA (1) | CA2541169A1 (fr) |
WO (1) | WO2005038347A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107795309A (zh) * | 2017-11-10 | 2018-03-13 | 中国石油天然气股份有限公司 | 重油采油管柱及其采油方法 |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070059653A1 (en) * | 2005-09-09 | 2007-03-15 | Purdy John C | Flare stack |
EP2090825A1 (fr) * | 2008-02-14 | 2009-08-19 | Siemens Aktiengesellschaft | Elément de brûleur et brûleur doté d'une garniture résistant à la corrosion |
BR112013010455A2 (pt) * | 2010-10-28 | 2016-08-02 | Flare Ind Inc | conjunto de ignição para superfície quente para uso em pilotos para queima, incineração e queimadores |
RU2582694C2 (ru) * | 2011-02-18 | 2016-04-27 | Линк Энерджи Лтд | Розжиг подземного угольного пласта в способе подземной газификации угля, пгу |
US9062808B2 (en) * | 2012-11-20 | 2015-06-23 | Elwha Llc | Underwater oil pipeline heating systems |
US9945560B1 (en) * | 2015-03-29 | 2018-04-17 | Paul Michael Rzonca | Fire starter apparatus |
US10161626B2 (en) | 2015-07-01 | 2018-12-25 | National Technology & Engineering Solutions Of Sandia, Llc | Ducted fuel injection |
US10138855B2 (en) * | 2015-07-01 | 2018-11-27 | National Technology & Engineering Solutions Of Sandia, Llc | Ducted fuel injection with ignition assist |
US11690471B2 (en) | 2015-12-28 | 2023-07-04 | Souhel Khanania | Cooking system with burner assembly and heat exchanger |
US11346549B2 (en) | 2015-12-28 | 2022-05-31 | Souhel Khanania | Burner assembly and systems incorporating a burner assembly |
MX2018007952A (es) * | 2015-12-28 | 2018-11-09 | Khanania Souhel | Ensamble de quemador e intercambiador de calor. |
US11346548B2 (en) * | 2015-12-28 | 2022-05-31 | Souhel Khanania | Burner assembly and heat exchanger |
US11391458B2 (en) | 2016-06-27 | 2022-07-19 | Combustion Systems Company, Inc. | Thermal oxidization systems and methods |
US10801395B1 (en) | 2016-11-29 | 2020-10-13 | National Technology & Engineering Solutions Of Sandia, Llc | Ducted fuel injection |
US10514166B2 (en) * | 2017-08-29 | 2019-12-24 | Saudi Arabian Oil Company | Pyrophoric liquid ignition system for pilot burners and flare tips |
CN109237513B (zh) * | 2018-08-29 | 2024-01-26 | 西安石油大学 | 一种深井用多级固体燃料点火器 |
US11885490B2 (en) * | 2021-06-08 | 2024-01-30 | Hydrogen Technologies LLC | Burner assemblies and methods |
CN113404475B (zh) * | 2021-07-15 | 2022-03-04 | 吉林大学 | 一种用于地下矿产资源原位加热的井下燃烧加热器 |
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- 2004-10-07 US US10/574,611 patent/US20070042306A1/en not_active Abandoned
- 2004-10-07 WO PCT/US2004/033140 patent/WO2005038347A2/fr active Application Filing
- 2004-10-07 CA CA002541169A patent/CA2541169A1/fr not_active Abandoned
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Also Published As
Publication number | Publication date |
---|---|
WO2005038347A3 (fr) | 2005-08-18 |
CA2541169A1 (fr) | 2005-04-28 |
US20070042306A1 (en) | 2007-02-22 |
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