WO2005024084A1 - An alloy steel composition - Google Patents

An alloy steel composition Download PDF

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Publication number
WO2005024084A1
WO2005024084A1 PCT/AU2004/000095 AU2004000095W WO2005024084A1 WO 2005024084 A1 WO2005024084 A1 WO 2005024084A1 AU 2004000095 W AU2004000095 W AU 2004000095W WO 2005024084 A1 WO2005024084 A1 WO 2005024084A1
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Prior art keywords
casting
metal casting
alloy steel
metal
steel composition
Prior art date
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PCT/AU2004/000095
Other languages
French (fr)
Inventor
Peter Laczko
Original Assignee
Roche Castings Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2003904931A external-priority patent/AU2003904931A0/en
Application filed by Roche Castings Pty Ltd filed Critical Roche Castings Pty Ltd
Priority to AU2004270752A priority Critical patent/AU2004270752A1/en
Publication of WO2005024084A1 publication Critical patent/WO2005024084A1/en

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper

Definitions

  • the present invention relates to an alloy steel composition and in particular to an alloy steel composition that is suitable for use in the production of metal castings for applications which are subject to highly abrasive wear forces.
  • Metal castings which are used in applications are subject to a large amount of abrasive wear force, which over time, gradually wears away at the metal casting until replacement is required.
  • the metal castings used in these types of applications can withstand a high degree of abrasive wear and also maintain hardness throughout the entire composition of the metal casting.
  • the present invention provides an alloy steel composition which includes the following constituents by weight: carbon 0.5 - 3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1-2.0% chromium 1.0 - 3.0% molybdenum 0.1-0.5% copper 0.1-2.0%.
  • the percentage composition of nickel is 0.10 - 0.45% by weight and the percentage composition of copper is 0.10 - 0.45% by weight.
  • the alloy steel includes the following composition be weight: carbon 0.75- - 0.90% silicon 0.35- - 0.50% manganese 0.80- -1.00% nickel 0.25- - 0.45% chromium 1.90- -2.30% molybdenum 0.25-0.45% copper 0.25 - 0.45%.
  • the alloy steel includes the following composition be weight: carbon 0.80- - 0.85% silicon 0.42- - 0.48% manganese 0.85- - 0.95 % nickel 0.32- - 0.38% chromium 2.05- -2.25% molybdenum 0.30-0.37% copper 0.32 - 0.38%.
  • the present invention provides a metal casting produced from an alloy steel composition which includes the following constituents by weight: carbon 0.5-3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1 - 2.0% chromium 1.0 - 3.0% molybdenum 0.1 - 0.5% copper 0.1 - 2.0%.
  • the metal casting has a substantially pearlitic microstructure throughout its entirety.
  • the hardness of the casting is greater than 310 HB when measured using the Brinell Hardness Test.
  • the hardness of the casting is greater than 335 HB and more preferably still greater than 350 HB
  • the metal casting may be used in applications which are subject to high abrasive wear forces.
  • the metal casting may be used as a component in autogenous grinding mills, semi-autogenous grinding mills or ball mills, and more preferably still, the components are lifter bars, liners, pulp lifters and/or grates.
  • the hardness of the casting is greater than 310 HB and preferably greater than 330 HB.
  • the present invention provides a method of producing a metal casting composed of an alloy steel composition, which includes the following constituents by weight: carbon 0.5 - 3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1 - 2.0% chromium 1.0 - 3.0% molybdenum 0.1 - 0.5% copper 0.1 - 2.0%, characterised wherein the method includes the steps of: i. pouring the molten alloy composition into a metal casting mould; ii. cooling the metal casting at ambient temperature; and iii. grind casting and gauge to profile.
  • Figure 1 is a photograph of a metal casting produced from an alloy in accordance with one aspect of the present invention
  • Figure 2 is a photograph of a commercially available metal casting used in autogenous and semi autogenous grinding mills.
  • the alloy steel composition in accordance with one aspect of the present invention includes the following alloying elements: carbon, silicon, manganese, nickel, chromium, molybdenum, copper, with the balance of the composition being principally composed of iron.
  • Other elements which may be present in trace quantities include sulphur, phosphorus, vanadium, aluminium and niobium.
  • the resulting alloy provided a surprising through hardness which made it particularly useful for applications such as autogenous and semi-autogenous grinding mills, ball mills and indeed any application that subjects metal castings to highly abrasive wear forces. Furthermore, upon structural analysis of metal castings produced from the alloy composition, it was found that they have a substantially pearlitic microstructure.
  • Metal castings in accordance with an aspect of the present invention, are produced by preparing the molten alloy composition with the correct proportions of the alloying constituents. The molten alloy is then poured into a mould conforming to the particular shape casting desired. The metal casting is then cooled to ambient air temperature after which the casting is removed from the mould and ground and gauged to the desired profile.
  • a metal casting which has a thickness of greater than 300mm it may be desirable to air blast the castings, after cooling, in order to increase their hardness. Furthermore, if the metal castings include thicker sections adjacent to thinner sections, then a further step of tempering may be introduced after the normalising heat treatment.
  • Test metal casting A was produced from an alloy according to an aspect of the present invention.
  • the two remaining metal castings B and C are commercially available products.
  • the three test metal castings A, B and C were put into service for a period of four months after which time they were removed and examined.
  • Microstructure of the specimen composed of Alloy A - consisted of a tempered pearlite with a very small amount of spheroidal carbide in some insulated areas.
  • the microscopic examination of the specimen composed of Alloy B revealed a pearlitic microstructure with a network of boundary carbide and a small amount of spheroidal carbide in some areas.
  • Microstructure of the Alloy C consists of tempered martensite with 0.5% to 1% carbide around the grain boundaries. Also very light etching revealed some micro-cracks in between the grains of the microstructure.
  • these grades are expected to achieve a fully pearlitic microstructure with a hardness range on the wear face of 320 HB to 380 HB but some lower hardness can be expected in the middle of very thick section castings as slower cooling occurs in these thick casting sections during heat treatment.
  • the metal casting produced from alloy C has the lowest performance against abrasive wear force as a result of its martensitic microstructure.
  • the casting produced from alloy B shows the presence of a carbide network around the grain boundaries, which increased the hardness but in the same time decreases the toughness of the material.
  • the metal casting produced form alloy A achieved the best performance as a result of its material properties. Through hardness was achieved with a fine pearlitic microstructure with spheroidal carbides in very small-insulated areas. The presence of spheroidal carbide improves wear resistance without decreasing the toughness of the material.

Abstract

An alloy steel composition which includes the following constituents by weight: 0.5 - 3.5% carbon, 0.2 - 0.8% silicon, 0.5 - 1.5% manganese, 0.1 - 2.0% nickel, 1.0 - 3.0% chromium, 0.1 - 0.5% molybdenum and 0.1 - 2.0% copper.

Description

An Alloy Steel Composition
The present invention relates to an alloy steel composition and in particular to an alloy steel composition that is suitable for use in the production of metal castings for applications which are subject to highly abrasive wear forces.
Background of the Invention
Metal castings which are used in applications, such as for example autogenous and semi autogenous grinding mills and ball mills, are subject to a large amount of abrasive wear force, which over time, gradually wears away at the metal casting until replacement is required.
As such, it is desirable that the metal castings used in these types of applications can withstand a high degree of abrasive wear and also maintain hardness throughout the entire composition of the metal casting.
Previous attempts at producing metal castings with increased abrasive wear resistance have focused on varying the alloying components of steel alloys in order to produce the desired characteristics, hi addition, various production techniques, such as air blasting and liquid quenching the metal castings have been used to increase the hardness and thereby abrasive wear resistance of the castings.
Surprisingly, it has been found that if an alloy steel composition is produced which includes the alloying components of copper and nickel, then the resulting alloy steel composition has an increased abrasive wear resistance that provides that the composition is very suitable for producing metal castings used in the applications discussed above.
Summary of the Invention
According to one aspect, the present invention provides an alloy steel composition which includes the following constituents by weight: carbon 0.5 - 3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1-2.0% chromium 1.0 - 3.0% molybdenum 0.1-0.5% copper 0.1-2.0%.
Preferably, the percentage composition of nickel is 0.10 - 0.45% by weight and the percentage composition of copper is 0.10 - 0.45% by weight.
Preferably the alloy steel includes the following composition be weight: carbon 0.75- - 0.90% silicon 0.35- - 0.50% manganese 0.80- -1.00% nickel 0.25- - 0.45% chromium 1.90- -2.30% molybdenum 0.25-0.45% copper 0.25 - 0.45%.
More preferably the alloy steel includes the following composition be weight: carbon 0.80- - 0.85% silicon 0.42- - 0.48% manganese 0.85- - 0.95 % nickel 0.32- - 0.38% chromium 2.05- -2.25% molybdenum 0.30-0.37% copper 0.32 - 0.38%.
According to another aspect, the present invention provides a metal casting produced from an alloy steel composition which includes the following constituents by weight: carbon 0.5-3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1 - 2.0% chromium 1.0 - 3.0% molybdenum 0.1 - 0.5% copper 0.1 - 2.0%.
Preferably the metal casting has a substantially pearlitic microstructure throughout its entirety. Furthermore, the hardness of the casting is greater than 310 HB when measured using the Brinell Hardness Test. Preferably, the hardness of the casting is greater than 335 HB and more preferably still greater than 350 HB
According to another aspect, the metal casting may be used in applications which are subject to high abrasive wear forces. Preferably, the metal casting may be used as a component in autogenous grinding mills, semi-autogenous grinding mills or ball mills, and more preferably still, the components are lifter bars, liners, pulp lifters and/or grates.
Preferably after about 50 to 100 mm of wear has occurred on the metal casting, the hardness of the casting is greater than 310 HB and preferably greater than 330 HB.
According to a further aspect the present invention provides a method of producing a metal casting composed of an alloy steel composition, which includes the following constituents by weight: carbon 0.5 - 3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1 - 2.0% chromium 1.0 - 3.0% molybdenum 0.1 - 0.5% copper 0.1 - 2.0%, characterised wherein the method includes the steps of: i. pouring the molten alloy composition into a metal casting mould; ii. cooling the metal casting at ambient temperature; and iii. grind casting and gauge to profile.
Brief Description of the Figures
The present invention will become better understood from the following detailed description of a preferred but non-limiting embodiment thereof, described in connection with the accompanying drawings, where in: Figure 1 is a photograph of a metal casting produced from an alloy in accordance with one aspect of the present invention; and Figure 2 is a photograph of a commercially available metal casting used in autogenous and semi autogenous grinding mills.
Detailed Description of the Invention
The alloy steel composition in accordance with one aspect of the present invention includes the following alloying elements: carbon, silicon, manganese, nickel, chromium, molybdenum, copper, with the balance of the composition being principally composed of iron. Other elements which may be present in trace quantities include sulphur, phosphorus, vanadium, aluminium and niobium.
With the addition of copper and nickel, in combination with the specific ratios of the other principal alloying constituents, it was found that the resulting alloy provided a surprising through hardness which made it particularly useful for applications such as autogenous and semi-autogenous grinding mills, ball mills and indeed any application that subjects metal castings to highly abrasive wear forces. Furthermore, upon structural analysis of metal castings produced from the alloy composition, it was found that they have a substantially pearlitic microstructure.
Metal castings, in accordance with an aspect of the present invention, are produced by preparing the molten alloy composition with the correct proportions of the alloying constituents. The molten alloy is then poured into a mould conforming to the particular shape casting desired. The metal casting is then cooled to ambient air temperature after which the casting is removed from the mould and ground and gauged to the desired profile.
If a metal casting is desired which has a thickness of greater than 300mm it may be desirable to air blast the castings, after cooling, in order to increase their hardness. Furthermore, if the metal castings include thicker sections adjacent to thinner sections, then a further step of tempering may be introduced after the normalising heat treatment.
The present invention will become better understood from the following example of a preferred but non-limiting embodiment thereof.
Example
A trial was conducted to analyse the effect of abrasive wear force upon various metal castings used in autogenous grinding mills. Three different metal castings made of different alloy steels were tested. Test metal casting A was produced from an alloy according to an aspect of the present invention. The two remaining metal castings B and C are commercially available products. The three test metal castings A, B and C were put into service for a period of four months after which time they were removed and examined.
Composition Analysis
Samples of the three test metal castings A, B and C were abrasively cut and constantly cooled with water to avoid overheating so they can be used for chemical and metallographic analysis. Chemical analysis results are given in the following table which were provided using an ARL 3460 Optical Emission Spectrometer. Table: 1
Figure imgf000008_0001
Hardness
Each of the worn test metal castings was surface ground to a dept of 3 - 4 mm on the wear face and hardness tested using an Equotip instrument. Hardness results with specification and testing position are given in the following table:
Table: 2
Figure imgf000008_0002
Metallography
A small section was cut from the wear face of each of the three test metal castings. All specimens were wet ground on silicon carbide paper, polished with 6 & 1 μm diamond and etched using 2% Nital. Examination was performed using a metallurgical microscope at x50 to xlOOO magnifications. This revealed a slightly different microstructure for each specification.
Microstructure of the specimen composed of Alloy A - consisted of a tempered pearlite with a very small amount of spheroidal carbide in some insulated areas. The microscopic examination of the specimen composed of Alloy B revealed a pearlitic microstructure with a network of boundary carbide and a small amount of spheroidal carbide in some areas.
Microstructure of the Alloy C consists of tempered martensite with 0.5% to 1% carbide around the grain boundaries. Also very light etching revealed some micro-cracks in between the grains of the microstructure.
Visual examination
As it can be seen from the photographs in figures 1 and 2, all pieces are heavily worn with no metal flow on the edges. Some pieces of the castings made from Alloys B and C have been worn to very thin sections of only 40 mm around bolt holes while the most warn part of the casting made from alloy A liner is 80 mm in thickness (See the table below).
It has been noticed that areas around boltholes are most affected, so the thickness has been checked and presented in the following table. The thickness results are a good indication of the wear resistance of different metal compositions.
Table: 3
Figure imgf000009_0001
Conclusion
After heat treatment, these grades are expected to achieve a fully pearlitic microstructure with a hardness range on the wear face of 320 HB to 380 HB but some lower hardness can be expected in the middle of very thick section castings as slower cooling occurs in these thick casting sections during heat treatment.
The metal casting produced from alloy C has the lowest performance against abrasive wear force as a result of its martensitic microstructure.
The casting produced from alloy B shows the presence of a carbide network around the grain boundaries, which increased the hardness but in the same time decreases the toughness of the material.
The metal casting produced form alloy A achieved the best performance as a result of its material properties. Through hardness was achieved with a fine pearlitic microstructure with spheroidal carbides in very small-insulated areas. The presence of spheroidal carbide improves wear resistance without decreasing the toughness of the material.
Although several preferred embodiments have been described in detail, it should also be understood that various changes, substitutions, and alterations can be made herein by one ordinarily skilled in the art without departing from the spirit or scope of the present invention.

Claims

The Claims:
1. An alloy steel composition which includes the following constituents by weight: carbon 0.5 - 3.5% silicon 0.2 - 0.8% manganese 0.5 - 1.5% nickel 0.1 - 2.0% chromium 1.0 - 3.0% molybdenum 0.1 - 0.5% copper 0.1 - 2.0%.
2. An alloy steel composition according to claim 1 wherein the percentage composition of nickel is 0.10 - 0.45% by weight.
3. An alloy steel composition according to claim 1 or 2 wherein the percentage composition of copper is 0.10 - 0.45% by weight.
4. A metal casting produced from the alloy steel composition according to any one of claims 1 to 3.
5. A metal casting according to claim 4 which has a substantially pearlitic microstructure throughout its entirety.
6. A metal casting according to claim 4 or 5 wherein the hardness of the casting is greater than 310 HB.
7. A metal casting according to claim 6 wherein the hardness of the casting is greater than 335 HB.
8. A metal casting according to any one of claims 4 to 7 for use in applications which result in high wear upon the casting.
9. A metal casting according to any one of claims 4 to 7 for use as components in autogenous grinding mills, semi-autogenous grinding mills or ball mills.
10. A metal casting according to claim 9 wherein the component is any component subject to wear.
11. A metal casting according to claim 9 or 10 wherein the components are lifter bars, liners, pulp lifters and/or grates.
12. A metal casting according to any one of claims 8 to 10 wherein, after about 50 to 100 mm of wear has occurred on the casting, the hardness of the casting is greater than 310 HB and preferably greater than 330 HB.
13. A method of producing a metal casting composed of the alloy steel composition according to any one of claims 1 to 3 characterised by the steps of: i. pouring the molten alloy composition into a metal casting mould; ii. cooling the metal casting at ambient temperature; and iii. grind casting and gauge to profile.
14. A method according to claim 13 which includes the step of air blasting when the metal casting is greater than 300 mm in thickness.
15. A method according to claim 13 and 14 which includes the step of tempering at about 580°C.
PCT/AU2004/000095 2003-09-09 2004-01-27 An alloy steel composition WO2005024084A1 (en)

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CN103255355A (en) * 2013-05-28 2013-08-21 肖振桥 Infinite chilled straightening roll for rolling steel
CN105506442A (en) * 2016-01-14 2016-04-20 北京工业大学 Si-Mn alloying grinding ball iron grinding balls and preparation method thereof
CN106636906A (en) * 2016-12-28 2017-05-10 芜湖市永帆精密模具科技有限公司 Low-carbon, corrosion-resisting, high-strength and wear-resisting steel ball and preparation method thereof

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CN112239834B (en) * 2020-09-02 2021-12-21 包头钢铁（集团）有限责任公司 Steel for high-strength and high-wear-resistance rare earth ball mill hot-rolled steel balls and rolling method thereof
CN112342460A (en) * 2020-09-03 2021-02-09 包头钢铁（集团）有限责任公司 Steel for B2 high-end steel ball of ball mill and rolling method thereof

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Publication number Priority date Publication date Assignee Title
CN103255355A (en) * 2013-05-28 2013-08-21 肖振桥 Infinite chilled straightening roll for rolling steel
CN105506442A (en) * 2016-01-14 2016-04-20 北京工业大学 Si-Mn alloying grinding ball iron grinding balls and preparation method thereof
CN105506442B (en) * 2016-01-14 2017-05-31 北京工业大学 A kind of Si Mn alloyings wear-resisting ductile iron abrading-ball and preparation method thereof
CN106636906A (en) * 2016-12-28 2017-05-10 芜湖市永帆精密模具科技有限公司 Low-carbon, corrosion-resisting, high-strength and wear-resisting steel ball and preparation method thereof

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