WO2004111293A1 - 窒化処理方法及び装置 - Google Patents
窒化処理方法及び装置 Download PDFInfo
- Publication number
- WO2004111293A1 WO2004111293A1 PCT/JP2004/008133 JP2004008133W WO2004111293A1 WO 2004111293 A1 WO2004111293 A1 WO 2004111293A1 JP 2004008133 W JP2004008133 W JP 2004008133W WO 2004111293 A1 WO2004111293 A1 WO 2004111293A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- work
- temperature
- nitriding
- heat treatment
- glow discharge
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/36—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3485—Sputtering using pulsed power to the target
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/54—Controlling or regulating the coating process
- C23C14/548—Controlling the composition
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B13/00—Adaptive control systems, i.e. systems automatically adjusting themselves to have a performance which is optimum according to some preassigned criterion
- G05B13/02—Adaptive control systems, i.e. systems automatically adjusting themselves to have a performance which is optimum according to some preassigned criterion electric
Definitions
- the present invention relates to a method and an apparatus for nitriding a workpiece in a heat treatment furnace.
- the nitriding treatment is a treatment for nitrifying a surface of a work made of a steel material to form an iron nitride layer, thereby hardening the work surface, and is widely performed.
- a plasma nitriding treatment in which plasma heating is performed by glow discharge.
- a heating means such as an infrared heater or a graphite cloth heating element is arranged around the work, 2.
- a prior art in which a workpiece is heated in combination with glow discharge (see, for example, JP-A-52-82641 and JP-A-53-23836).
- the heat generated by the glow discharge is basically generated by the collision of nitrogen ions generated by the glow discharge with the surface of the work. If heated excessively, the surrounding work is heated by the radiant heat of the work itself, so that a temperature difference occurs between a part close to the heating means and a part separated from the heating means.
- This problem can be solved by arranging a large number of heating means between the workpieces. However, for example, such as in the case of multi-product small-quantity production in which it is required to perform nitriding on workpieces having different shapes. In a production line, it is practically impossible to arrange a heating means at an appropriate position between works.
- a general object of the present invention is to provide a nitriding method capable of quickly and uniformly heating a work to a temperature at which stable nitriding can be performed, and performing a good nitriding treatment in a state where there is little temperature variation of the work. And a device.
- a main object of the present invention is to provide a nitriding method and an apparatus capable of performing extremely good nitriding on a large number of works having complicated shapes.
- Another object of the present invention is to provide a nitriding method and apparatus which can be easily applied to various kinds of works.
- Another object of the present invention is to provide a nitriding method and apparatus which can be applied to a horizontal heat treatment furnace to perform good nitriding.
- the frequency of the noise voltage for generating the glow discharge is set to 1 kHz or more, the time during which the current is continuously supplied is set to lms or less, and the error can be detected with a short detection time.
- the current is interrupted before the voltage at which the arc mark is generated is reached, preventing the arc mark from being generated, maintaining a stable glow discharge state, and damaging the work surface. It can be heated without. The shorter the detection time, the better. Therefore, for example, it is preferable to use a power supply for generating a pulse voltage of about 15 kHz.
- the horizontal heat treatment furnace which tends to vary depending on the convection, the distance from the heating element, the number of workpieces, etc. Even with such a structure, the peak temperature in the heat treatment furnace can be uniformly increased.
- the glow discharge and the heating by the heating element By using them together, the workpiece can be quickly heated while maintaining a uniform temperature distribution. As a result, the time required for all the workpieces to reach a certain temperature can be shortened, and the time required to maintain the workpieces at a certain temperature can be shortened.
- the current density of the green discharge is reduced, so that excessive heat from the workpiece itself heated by the green discharge is obtained.
- the generation of radiant heat can be avoided, the temperature distribution in the heat treatment furnace can be kept uniform, and a rapid rise in temperature can be avoided.
- the workpiece can be heated to a desired nitriding temperature with high accuracy by further heating the workpiece from this temperature using a heating element disposed around the workpiece.
- the temperature of the workpiece exceeds the desired nitriding temperature, an abnormal structure may be generated in the workpiece, but in the present invention, the heat generated by glow discharge is adjusted with high precision. Therefore, the temperature required for the nitriding treatment can be reduced by setting the temperature to a high temperature without overshooting the work.
- the current density of the glow discharge is preferably set to 0.05 to 7 mA / cm 2 . If it is less than 0.05 mA / cm 2 , especially at low temperatures, the glow discharge is not stable and uniform heating cannot be performed. If the current density is set to a value higher than 7 mA / cm 2 , the operation shifts to arc discharge, which causes damage to the workpiece. If the current density is less than 0. ImA / cm 2 , it takes time to raise the temperature. If the current density is more than 4 mA / cm 2 , in the case of a work having a projection or the like, ion collision easily occurs on the projection or the like. Abnormal heating may occur. Therefore, the current density is preferably set in the range of 0.1 to 4 mA / cm 2 .
- a dummy work is provided in the heat treatment furnace, and the contact temperature of the dummy work and the radiation temperature are measured. And the radiation temperature of the work is detected, and the temperature of the work itself is estimated by correcting the radiation temperature of the work from the temperature difference between the contact temperature and the radiation temperature of the dummy work.
- FIG. 1 is a schematic configuration diagram of a nitriding system including a nitriding apparatus of the present embodiment.
- FIG. 2 is an explanatory view of a work to be subjected to a nitriding treatment and a magazine storing the work.
- FIG. 3 is a configuration explanatory view of a horizontal heat treatment furnace and a control circuit thereof according to the present embodiment.
- FIG. 4 is a flowchart of a nitriding treatment method of the present embodiment.
- FIG. 5 is an explanatory diagram showing a relationship among a work temperature, a current density, and a heater output in the nitriding treatment method of the present embodiment.
- FIG. 1 is a schematic configuration diagram of a nitriding system 10 including the nitriding apparatus of the present embodiment. As shown in FIG. 2, a plurality of crankshafts 12 as workpieces are supplied to the nitriding system 10 as a magazine 16 positioned on a jig 14.
- the nitriding system 10 is provided with a washing machine 20 for removing dust, oil, and the like attached to the crankshaft 12 conveyed by the conveyor 18, and receives the washed crankshaft 12 from the conveyor 18 and sends it to each work station.
- FIG. 3 is an explanatory view of the configuration of the horizontal heat treatment furnace 24 arranged in each work station and the control circuit thereof.
- the horizontal heat treatment furnace 24 is a heat treatment furnace for performing a plasma nitriding treatment on the crankshaft 12, and is configured as a horizontal type in which the magazine 16 in which the crankshaft 12 is positioned moves in and out in the horizontal direction.
- an inner partition wall 28 and an outer partition wall 30 are provided on a base 26.
- the inner partition wall 28 forms a nitriding chamber 32 made of a nitriding atmosphere for accommodating the crankshaft 12 together with the jig 14.
- the space between the inner partition wall 28 and the outer partition wall 30 is provided with a coolant passage 33 for cooling the inner partition wall 28 to eliminate the influence of heat radiation and to facilitate control when the temperature of the nitriding chamber 32 rises.
- a plurality of electric heaters 34 are arranged along the inner partition wall 28 and the base 26.
- the nitriding chamber 32 has a physical property equivalent to that of the crankshaft 12.
- One work 36 is provided. Note that the dummy work 36 may be the crankshaft 12 itself.
- a negative electrode 38 electrically connected to the magazine 16 is disposed via an insulator 40, and a negative electrode 42 electrically connected to the dummy work 36 is provided on the base 26. It is arranged via 44. Further, an electrode plate 45 is provided inside the electric heater 34 in the nitriding chamber 32. The positive electrode 46 is connected to the electrode plate 45. Between these negative electrodes 38 and 42 and the positive electrode 46, a discharge power supply unit 48 (glow discharge generating means) for applying a pulse voltage having a frequency of 1 kHz or more is connected. A heater power supply unit 50 (heating means) is connected to the electric heater 34.
- a radiation thermometer for work 52 for detecting the radiation temperature of the crankshaft 12
- a radiation thermometer for dummy work 54 for detecting the radiation temperature of the dummy work 36
- a dummy work contact thermometer 56 composed of a thermocouple for detecting the contact temperature of the dummy work 36.
- the radiation thermometer for work 52, the radiation thermometer for dummy work 54, and the contact thermometer for dummy work 56 are connected to a temperature detection unit 58 (temperature detection means, temperature calculation means).
- the temperature detection unit 58 estimates the temperature of the crankshaft 12 from each detected temperature data.
- a vacuum suction pump 60 is connected to the nitridation chamber 32 via a valve 62 for sucking gas inside the nitridation chamber 32 to obtain a desired degree of vacuum.
- a gas for performing a plasma nitriding process for example, a nitriding gas which is a mixed gas of a nitrogen gas, a hydrogen gas, an ammonia gas, an argon gas, etc., is supplied to the inside of the nitriding process chamber 32.
- the nitriding gas supply unit 64 is connected via a valve 66.
- a coolant supply unit 68 for supplying coolant is connected to the coolant passage 33 via a valve 70.
- the coolant supplied to the coolant passage 33 is configured to be able to be discharged to the outside via the valve 72.
- the discharge power supply unit 48, the heater power supply unit 50, the temperature detection unit 58, the vacuum suction pump 60, the nitriding gas supply unit 64, and the coolant supply unit 68 are controlled by a control unit 74 (control means). You.
- the nitriding system 10 of the present embodiment is basically configured as described above. Yes, and its operation and effect will be described with reference to the flowchart shown in FIG.
- a magazine 16 in which a plurality of crankshafts 12 are positioned on a jig 14 is prepared, and the magazine 16 is carried into a washing machine 20 by a conveyor 18, and Remove adhering dust and oil (Step Sl).
- Step S2 the magazine 16 whose crankshaft 12 has been cleaned is transported by the conveyor 22 and is loaded into the nitriding chamber 32 of each horizontal heat treatment furnace 24 (Step S2).
- the horizontal heat treatment furnace 24 is a horizontal type
- a plurality of magazines 16 holding the crankshaft 12 can be easily moved in and out of the nitriding chamber 32 as compared with a vertical type.
- the layout of the processing system 10 can be simplified.
- the number of processes of the crankshaft 12 that can be processed at one time can be easily increased.
- the heat treatment chamber must be configured to be large at the top.
- the bottom of the jig 14 is connected to the negative electrode 38 provided on the base 26.
- a dummy work 36 having the same physical properties as the crankshaft 12 is provided in the nitriding chamber 32 in advance.
- the magazine 16 is put into the nitriding chamber 32, and after closing the horizontal heat treatment furnace 24, the nitriding chamber 32 is set to a nitriding atmosphere (step S3).
- the control unit 74 drives the vacuum suction pump 60 to suck the air inside the nitriding chamber 32 to a predetermined degree of vacuum, and then drives the nitriding gas supply unit 64 to switch the nitrogen gas, hydrogen gas, A nitriding gas composed of a mixed gas such as ammonia gas and argon gas is introduced into the nitriding chamber 32.
- the coolant supply unit 68 is driven to introduce coolant into the coolant passage 33 between the inner partition wall 28 and the outer partition wall 30 to start cooling the wall surface of the inner partition wall 28 (step S4).
- the control unit 74 sets a pulse voltage having a frequency of 15 kHz and a current density p of 2.5 mAZcm 2 to the discharge power supply unit 48 (step S5).
- the control unit 74 sets the output H of the heater power supply unit 50 to 40% (step S6).
- the output of the heater power supply unit 50 is 100% when the electric power (heat) per lkg of the crankshaft 12 to be supplied to the nitriding chamber 32 is 160 W. Therefore, the output H of 40% is 64 W / kg.
- Step S7 After setting the processing conditions as described above, the heating of the nitriding atmosphere in the nitriding chamber 32 and the nitriding process are started (Step S7).
- the crankshaft 12 when the crankshaft 12 is turned on, the setting of each processing condition is completed, and the discharge power supply unit 48 and the heater power supply unit 50 are driven (processing time tO), the negative electrode is turned on.
- a glow discharge is generated by a panel voltage applied between the positive electrode 46 and the positive electrode 46, and the nitriding gas in the nitriding chamber 32 is ionized by the green discharge and collides with the surface of the crankshaft 12. As a result, the crankshaft 12 is heated.
- the electric heater 34 disposed on the outer periphery of the magazine 16 holding the crankshaft 12 generates heat, and the nitriding atmosphere in the nitriding chamber 32 is heated by the radiant heat generated by the generated heat. Since the glow discharge also occurs on the surface of the dummy work 36, the dummy work 36 is similarly heated.
- the nitriding atmosphere is sufficiently heated to a temperature at which stable nitriding treatment can be started. Even in a non-heated state, a stable glow discharge state without arc discharge is maintained. In other words, by preventing the continuation of arc discharge in the detection time, the current is interrupted before reaching the voltage at which the arc marks are generated, and the arc marks are not generated. And maintain a stable glow discharge state. Therefore, the situation where the surface of the crankshaft 12 is damaged by the arc discharge does not occur.
- Heating by glow discharge is not due to radiant heat, but is caused by collision of nitrogen ions or nitrogen radicals generated by glow discharge with the crankshaft 12.
- the influence of the radiant heat is small, and the position of the adjacent crankshaft 12 and the shape of the crankshaft 12 are not affected. Therefore, the crankshaft 12 is uniformly heated by the glow discharge.
- the nitriding atmosphere in the nitriding chamber 32 is heated by the radiant heat from the electric heater 34 arranged along the inner partition wall 28 and having a low output, the crankshaft 12 has a uniform temperature distribution. It is quickly heated to the desired stable nitriding temperature while maintaining it.
- the coolant is supplied to the coolant passage 33.
- the coolant is supplied from the electric heater 34. It is possible to avoid a situation in which radiant heat is reflected by the inner partition wall 28 and the crankshaft 12 disposed inside is heated more than necessary. Therefore, the temperature of the crankshaft 12 can be raised more uniformly.
- the temperature of the crankshaft 12 is estimated with high accuracy using the temperature of the dummy work 36 provided in the nitriding chamber 32 and the radiation temperature of the crankshaft 12 (steps S8 and S9).
- the work radiation thermometer 52 disposed close to the crankshaft 12 detects the radiation temperature Trw, which is the temperature of the radiation heat radiated from the crankshaft 12.
- the radiation thermometer 54 for the dummy work disposed close to the dummy work 36 detects the radiation temperature Trd, which is the temperature of the radiation heat radiated from the dummy work 36.
- the contact thermometer 56 for the dummy work fixed to the dummy work 36 detects an accurate contact temperature Ted of the dummy work 36.
- the temperature detection unit 58 calculates the radiation temperature Trd of the dummy work 36 detected by the radiation thermometer 54 for the dummy work and the contact temperature Ted of the dummy work 36 detected by the contact thermometer 56 for the dummy work. Is obtained as a temperature correction value ⁇ , and the temperature Tw of the crankshaft 12 is calculated using the temperature correction value ⁇ .
- Tw Trw + ⁇
- control unit 74 determines whether or not the temperature Tw force S400 ° C of the crankshaft 12 estimated by the temperature detection unit 58 is higher than or equal to the temperature during the heating of the nitriding atmosphere in the nitriding chamber 32. Is performed (step S10). In this case, when the temperature Tw force of the crankshaft 12 becomes 400 ° C or more, the influence of the heat radiation of the crankshaft 12 cannot be neglected. Temperature unevenness may occur.
- step SI 1 the control unit 74 controls the discharge power supply unit 48, and the negative electrode 38 and the positive electrode Four 6 and the current density p of the glow discharge applied to the heater is reduced to 0.5 mA / cm 2 (step SI 1), and the output of the heater power supply unit 50 is reduced to 90% (144 kW / kg). Raise it (step S12).
- the current density p is determined by the processing time according to the temperature Tw of the crankshaft 12 estimated by the temperature detection unit 58. It is preferable that the output of the heater power supply unit 50 is controlled to be gradually increased from the processing time tl to a desired nitriding temperature of the crankshaft 12 while the output is gradually decreased from tl to t2.
- Step S13 the control unit 74 controls the heater power supply unit 50 to perform the nitriding process on the temperature Tw of the crankshaft 12. Maintain the temperature at 570 ° C (step S14). During this time, on the surface of the crankshaft 12, the nitriding treatment proceeds due to the reaction between nitrogen ions and iron ions.
- step S15 When the nitriding treatment is completed after a predetermined time has elapsed (step S15, treatment time t3), the crankshaft 12 is discharged from the horizontal heat treatment furnace 24 together with the magazine 16 (step S16).
- the magazine 16 discharged from the horizontal heat treatment furnace 24 is conveyed by the conveyor 22, carried into the cooling tank 25 and subjected to the cooling process (step S 17), and then discharged to the outside via the conveyor 27.
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- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
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- Software Systems (AREA)
- Physics & Mathematics (AREA)
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- Automation & Control Theory (AREA)
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Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04745763A EP1640470B1 (en) | 2003-06-13 | 2004-06-10 | Nitriding method and device |
US10/559,531 US20060124202A1 (en) | 2003-06-13 | 2004-06-10 | Nitriding method and device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003-169012 | 2003-06-13 | ||
JP2003169012A JP4257157B2 (ja) | 2003-06-13 | 2003-06-13 | 窒化処理方法及び装置 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004111293A1 true WO2004111293A1 (ja) | 2004-12-23 |
Family
ID=33549350
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/008133 WO2004111293A1 (ja) | 2003-06-13 | 2004-06-10 | 窒化処理方法及び装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060124202A1 (ja) |
EP (1) | EP1640470B1 (ja) |
JP (1) | JP4257157B2 (ja) |
KR (1) | KR100726821B1 (ja) |
CN (2) | CN100513628C (ja) |
WO (1) | WO2004111293A1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101812661B (zh) * | 2010-03-29 | 2012-04-25 | 中北大学 | 一种压电式超声波盐浴加热渗氮装置 |
DE102010052894A1 (de) * | 2010-12-01 | 2012-06-06 | Oerlikon Trading Ag | Kunststoffverarbeitungskomponente mit modifizierter Stahloberfläche |
CN103981480B (zh) * | 2014-04-28 | 2017-03-15 | 浙江省舟山中学 | 一种快速渗氮工艺 |
EP3177752A1 (en) * | 2014-08-08 | 2017-06-14 | Regents of the University of Minnesota | Forming iron nitride hard magnetic materials using chemical vapor deposition or liquid phase epitaxy |
CN106282909B (zh) * | 2015-05-29 | 2018-12-21 | 比亚迪股份有限公司 | 基板渗金属设备 |
JP6990162B2 (ja) | 2018-10-15 | 2022-01-12 | 株式会社神戸製鋼所 | 窒化処理装置および窒化処理方法 |
CN109321869B (zh) * | 2018-11-21 | 2021-11-09 | 中国航发哈尔滨东安发动机有限公司 | 一种钛合金零件离子氮化工装 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5282641A (en) | 1975-12-29 | 1977-07-11 | Kawasaki Heavy Ind Ltd | Ionitriding |
JPS5323836A (en) | 1976-08-19 | 1978-03-04 | Kawasaki Heavy Ind Ltd | Ionitriding |
JPS5425274A (en) * | 1977-07-27 | 1979-02-26 | Chugai Ro Kogyo Kaisha Ltd | Ion nitrogenation treatment apparatus |
JPS5514839A (en) * | 1978-07-14 | 1980-02-01 | Kawasaki Heavy Ind Ltd | Treating method for ion nitriding |
JP2000045061A (ja) * | 1998-07-27 | 2000-02-15 | Pascal Kk | グロー放電処理に供するパルスモードでの狭グロー放電制御方法及び処理温度制御方法及びその狭グロー放電処理装置 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2501727A1 (fr) * | 1981-03-13 | 1982-09-17 | Vide Traitement | Procede de traitements thermochimiques de metaux par bombardement ionique |
GB2100023B (en) * | 1981-06-05 | 1985-01-09 | Aizenshtein Anatoly Gdalievich | Method of control of chemico-thermal treatment of workpieces in glow discharge and a device for carrying out the same |
US4859247A (en) * | 1987-11-02 | 1989-08-22 | Basf Corporation | Low viscosity, highly concentrated pigment dispersions and method of making same |
US5859404A (en) * | 1995-10-12 | 1999-01-12 | Hughes Electronics Corporation | Method and apparatus for plasma processing a workpiece in an enveloping plasma |
DE19815019B4 (de) * | 1998-04-03 | 2007-08-16 | HQM Härterei und Qualitätsmanagement GmbH | Verfahren zur Herstellung von Aluminiumnitridschichten auf Bauteilen aus Aluminiumwerkstoffen auf der Grundlage des Plasmanitrierens |
-
2003
- 2003-06-13 JP JP2003169012A patent/JP4257157B2/ja not_active Expired - Fee Related
-
2004
- 2004-06-10 US US10/559,531 patent/US20060124202A1/en not_active Abandoned
- 2004-06-10 EP EP04745763A patent/EP1640470B1/en not_active Expired - Lifetime
- 2004-06-10 KR KR1020057023745A patent/KR100726821B1/ko not_active IP Right Cessation
- 2004-06-10 CN CNB2004800162814A patent/CN100513628C/zh not_active Expired - Fee Related
- 2004-06-10 CN CN2009101415754A patent/CN101570847B/zh not_active Expired - Fee Related
- 2004-06-10 WO PCT/JP2004/008133 patent/WO2004111293A1/ja active Search and Examination
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5282641A (en) | 1975-12-29 | 1977-07-11 | Kawasaki Heavy Ind Ltd | Ionitriding |
JPS5323836A (en) | 1976-08-19 | 1978-03-04 | Kawasaki Heavy Ind Ltd | Ionitriding |
JPS5425274A (en) * | 1977-07-27 | 1979-02-26 | Chugai Ro Kogyo Kaisha Ltd | Ion nitrogenation treatment apparatus |
JPS5514839A (en) * | 1978-07-14 | 1980-02-01 | Kawasaki Heavy Ind Ltd | Treating method for ion nitriding |
US4309227A (en) | 1978-07-14 | 1982-01-05 | Kawasaki Jukogyo Kabushiki Kaisha | Ion-nitriding process |
JP2000045061A (ja) * | 1998-07-27 | 2000-02-15 | Pascal Kk | グロー放電処理に供するパルスモードでの狭グロー放電制御方法及び処理温度制御方法及びその狭グロー放電処理装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1640470A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP1640470B1 (en) | 2011-09-28 |
EP1640470A4 (en) | 2009-07-15 |
EP1640470A1 (en) | 2006-03-29 |
CN1826422A (zh) | 2006-08-30 |
CN100513628C (zh) | 2009-07-15 |
KR20060018886A (ko) | 2006-03-02 |
JP2005002444A (ja) | 2005-01-06 |
JP4257157B2 (ja) | 2009-04-22 |
CN101570847A (zh) | 2009-11-04 |
CN101570847B (zh) | 2011-05-25 |
KR100726821B1 (ko) | 2007-06-12 |
US20060124202A1 (en) | 2006-06-15 |
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