WO2004103549A3 - Oxidation process using microchannel technology and novel catalyst useful in same - Google Patents

Oxidation process using microchannel technology and novel catalyst useful in same

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Publication number
WO2004103549A3
WO2004103549A3 PCT/US2004/010611 US2004010611W WO2004103549A3 WO 2004103549 A3 WO2004103549 A3 WO 2004103549A3 US 2004010611 W US2004010611 W US 2004010611W WO 2004103549 A3 WO2004103549 A3 WO 2004103549A3
Authority
WO
WIPO (PCT)
Prior art keywords
same
oxidation process
novel catalyst
catalyst useful
microchannel technology
Prior art date
Application number
PCT/US2004/010611
Other languages
French (fr)
Other versions
WO2004103549A2 (en
Inventor
Richard Q Long
Anna Lee Tonkovich
Eric Daymo
Barry L Yang
Francis P Daly
Yong Wang
Original Assignee
Velocys Inc
Richard Q Long
Anna Lee Tonkovich
Eric Daymo
Barry L Yang
Francis P Daly
Yong Wang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/440,053 external-priority patent/US7220390B2/en
Application filed by Velocys Inc, Richard Q Long, Anna Lee Tonkovich, Eric Daymo, Barry L Yang, Francis P Daly, Yong Wang filed Critical Velocys Inc
Priority to EP04785469A priority Critical patent/EP1628755A2/en
Priority to CA2525256A priority patent/CA2525256C/en
Priority to AU2004241941A priority patent/AU2004241941B2/en
Priority to JP2006532382A priority patent/JP4768619B2/en
Publication of WO2004103549A2 publication Critical patent/WO2004103549A2/en
Publication of WO2004103549A3 publication Critical patent/WO2004103549A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • C—CHEMISTRY; METALLURGY
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00835—Comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/00862—Dimensions of the reaction cavity itself
    • C—CHEMISTRY; METALLURGY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1029—Catalysts in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1628—Controlling the pressure
    • C01B2203/1633—Measuring the pressure
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2260/00—Heat exchangers or heat exchange elements having special size, e.g. microstructures
    • F28F2260/02—Heat exchangers or heat exchange elements having special size, e.g. microstructures having microchannels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process is disclosed for converting a hydrocarbon reactant to CO and H2. The process comprises: (A) flowing a reactant composition comprising the hydrocarbon reactant (116) and oxygen or a source of oxygen (118) through a microchannel reactor (100) in contact with a catalyst under reaction conditions to form the product. The product formed in step (A) may be converted to a product comprising CO2 and H2O in a microchannel reactor. A catalyst is disclosed which comprises a composition represented by the formula M'a M2b M3C AId OX wherein: M1 is Rh, Ni, Pd, Pt, Ru, Co or a mixture of two or more thereof; M2 is Ce, Pr, Tb or a mixture of two or more thereof.
PCT/US2004/010611 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful in same WO2004103549A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP04785469A EP1628755A2 (en) 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful in same
CA2525256A CA2525256C (en) 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful in same
AU2004241941A AU2004241941B2 (en) 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful in same
JP2006532382A JP4768619B2 (en) 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful therefor

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/440,053 US7220390B2 (en) 2003-05-16 2003-05-16 Microchannel with internal fin support for catalyst or sorption medium
US10/440,053 2003-05-16
US10/449,913 US7226574B2 (en) 2003-05-16 2003-05-30 Oxidation process using microchannel technology and novel catalyst useful in same
US10/449,913 2003-05-30

Publications (2)

Publication Number Publication Date
WO2004103549A2 WO2004103549A2 (en) 2004-12-02
WO2004103549A3 true WO2004103549A3 (en) 2005-09-15

Family

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Family Applications (1)

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PCT/US2004/010611 WO2004103549A2 (en) 2003-05-16 2004-04-08 Oxidation process using microchannel technology and novel catalyst useful in same

Country Status (5)

Country Link
EP (1) EP1628755A2 (en)
AU (1) AU2004241941B2 (en)
CA (1) CA2525256C (en)
RU (1) RU2005139412A (en)
WO (1) WO2004103549A2 (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1755777B1 (en) * 2004-03-23 2012-05-23 Velocys, Inc. Micro-channel reactor with catalyst applied to thermally-grown alumina, methods of using same, catalyst and its making
US7820445B2 (en) * 2004-04-22 2010-10-26 Velocys Fluidization and solids processing in microchannel devices
US7442360B2 (en) 2004-04-27 2008-10-28 Velocys, Inc. Hydrogen peroxide production in microchannel reactors
JP4991102B2 (en) * 2004-12-22 2012-08-01 パナソニック株式会社 Microreactor
EP1679115A1 (en) * 2005-01-07 2006-07-12 Corning Incorporated High performance microreactor
CN104525072A (en) * 2005-03-23 2015-04-22 维罗西股份有限公司 Surface features in microprocess technology
EP2543434B1 (en) * 2005-07-08 2022-06-15 Velocys Inc. Catalytic reaction process using microchannel technology
WO2007071741A1 (en) * 2005-12-22 2007-06-28 Shell Internationale Research Maatschappij B.V. Microchannel apparatus for removal of combustible , volatile contaminants
CN101426752B (en) * 2006-03-23 2014-08-13 万罗赛斯公司 Process for making styrene using microchannel process technology
EP1854536A1 (en) * 2006-05-11 2007-11-14 Corning Incorporated High throughput thermally tempered microreactor devices and methods
JP5278641B2 (en) * 2006-06-23 2013-09-04 日産自動車株式会社 Metal substrate manufacturing method
EP1932821A1 (en) * 2006-12-12 2008-06-18 Basf Se Method for manufacturing oxidation products from Cyclohexan
WO2008089376A2 (en) * 2007-01-19 2008-07-24 Velocys Inc. Process and apparatus for converting natural gas to higher molecular weight hydrocarbons using microchannel process technology
EP2313385A2 (en) * 2008-07-14 2011-04-27 Velocys Inc. Process for making ethylene oxide using microchannel process technology
EP2300447A1 (en) 2008-07-14 2011-03-30 Basf Se Process for making ethylene oxide
EP2216093A1 (en) * 2009-01-30 2010-08-11 Corning Incorporated In situ formation and deposition of palladium Pd(0) in reactors
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
CN109745933B (en) * 2019-02-28 2023-08-15 山东理工大学 Oxygen-permeable hydrogen-permeable integrated catalytic membrane microreactor for benzene-based phenol production
CN114920279B (en) * 2022-05-09 2023-10-24 西南石油大学 Preparation method and application of oxygen carrier for low-temperature oxidation of methane to prepare hydrogen
CN118491440B (en) * 2024-07-17 2024-10-01 西南石油大学 Microreaction channel and microreactor

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001060742A1 (en) * 2000-02-18 2001-08-23 Conoco Inc. Chromium-rare earth based catalysts and process for converting hydrocarbons to synthesis gas
US20010018140A1 (en) * 2000-02-20 2001-08-30 Ingo Hermann Catalytic burner element inside a fuel cell with structured catalytic coated surfaces
WO2002014854A1 (en) * 2000-08-14 2002-02-21 Chevron U.S.A. Inc. Use of microchannel reactors in combinatorial chemistry
EP1232790A1 (en) * 1999-11-25 2002-08-21 Kawasaki Jukogyo Kabushiki Kaisha Catalyst for exothermic or endothermic reaction, catalyst for water-gas-shift reaction and catalyst for selective oxidation of carbon monoxide, and plate-fin heat exchange type reformer
WO2002064248A2 (en) * 2001-02-16 2002-08-22 Battelle Memorial Institute Integrated reactors, methods of making same, and methods of conducting simultaneous exothermic and endothermic reactions
FR2826293A1 (en) * 2001-06-21 2002-12-27 Elf Antar France PROCESS FOR OBTAINING SYNTHESIS GAS BY PARTIAL CATALYTIC OXIDATION

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1232790A1 (en) * 1999-11-25 2002-08-21 Kawasaki Jukogyo Kabushiki Kaisha Catalyst for exothermic or endothermic reaction, catalyst for water-gas-shift reaction and catalyst for selective oxidation of carbon monoxide, and plate-fin heat exchange type reformer
WO2001060742A1 (en) * 2000-02-18 2001-08-23 Conoco Inc. Chromium-rare earth based catalysts and process for converting hydrocarbons to synthesis gas
US20010018140A1 (en) * 2000-02-20 2001-08-30 Ingo Hermann Catalytic burner element inside a fuel cell with structured catalytic coated surfaces
WO2002014854A1 (en) * 2000-08-14 2002-02-21 Chevron U.S.A. Inc. Use of microchannel reactors in combinatorial chemistry
WO2002064248A2 (en) * 2001-02-16 2002-08-22 Battelle Memorial Institute Integrated reactors, methods of making same, and methods of conducting simultaneous exothermic and endothermic reactions
FR2826293A1 (en) * 2001-06-21 2002-12-27 Elf Antar France PROCESS FOR OBTAINING SYNTHESIS GAS BY PARTIAL CATALYTIC OXIDATION

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