WO2004081103A2 - Procede de reduction de la viscosite a l'etat fondu d'une composition polymerique sulfone aromatique, et procede de production d'un composant d'avion - Google Patents

Procede de reduction de la viscosite a l'etat fondu d'une composition polymerique sulfone aromatique, et procede de production d'un composant d'avion Download PDF

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WO2004081103A2
WO2004081103A2 PCT/US2004/005229 US2004005229W WO2004081103A2 WO 2004081103 A2 WO2004081103 A2 WO 2004081103A2 US 2004005229 W US2004005229 W US 2004005229W WO 2004081103 A2 WO2004081103 A2 WO 2004081103A2
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composition
aromatic sulfone
sulfone polymer
additive
polymer
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PCT/US2004/005229
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English (en)
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WO2004081103A3 (fr
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Shari Weinberg
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Solvay Advanced Polymers, L.L.C.
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Priority to EP04737306A priority Critical patent/EP1638840A4/fr
Priority to US10/547,744 priority patent/US20070037928A1/en
Priority to JP2006508794A priority patent/JP2006519911A/ja
Publication of WO2004081103A2 publication Critical patent/WO2004081103A2/fr
Publication of WO2004081103A3 publication Critical patent/WO2004081103A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones

Definitions

  • This invention relates to a method for lowering the melt viscosity of an aromatic sulfone polymer composition ; it relates also to a method for manufacturing an aircraft component comprising an aromatic sulfone polymer composition, which comprises applying to the aromatic sulfone polymer composition the above cited method for lowering its melt viscosity.
  • Aromatic sulfone polymers especially polybiphenylethersulfones, offer indeed an attractive combination of properties, especially high fire resistance and supertoughness. Yet, existing aromatic sulfone polymer compositions are no more fully satisfactory, and we
  • a high flow material is intended to denote a material which has a low melt viscosity. High flow materials would make it possible notably to mold thin-walled, and consequently light-weight, aircraft interior components.
  • U.S. patent No. 5,204,400 describes an aromatic sulfone polymer composition suitable for manufacturing aircraft interior components, comprising a polybiphenylethersulfone, a fluorocarbon polymer such as a polytetrafluoroethylene, and at least 2 pbw.
  • anhydrous zinc borate in this composition, the fluorocarbon polymer and the anhydrous zinc borate act synergistically to the purpose of increasing the flame retardancy of the aromatic sulfone polymer composition (see notably col. 21, 1. 50-53).
  • U.S. patent No. 5,916,958 describes an aromatic sulfone polymer composition, suitable for manufacturing aircraft interior components, comprising a polybiphenylethersulfone, a fluorocarbon polymer such as a polytetrafluoroethylene, and at least 3 pbw. of titanium dioxide ; in this other composition, the fluorocarbon polymer and the titanium dioxide act also synergistically to the purpose of increasing the flame retardancy of the aromatic sulfone polymer composition (see notably col. 13, 1. 13-17).
  • the fire resistant (in particular, flame retardant) aromatic sulfone polymer compositions found adequate in prior years for use in demanding applications such as aircraft interiors are no longer acceptable, because none of them has a sufficiently low melt viscosity so as to produce very light-weight materials.
  • the present invention is based on the surprising effect of reduction of the melt viscosity of an aromatic sulfone polymer composition obtained by using an additive which comprises a fluorocarbon polymer comprising recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylefher.
  • An aspect of the present invention is to a method for lowering the melt viscosity of an aromatic sulfone polymer composition consisting of at least one aromatic sulfone polymer and, optionally, one or more other ingredients [composition (1)], which comprises using an additive consisting of at least one fluorocarbon polymer comprising recurring units derived from at least one erfluorinated monoolefin and at least one perfluoroalkylvinylefher and, optionally, one or more other ingredients [additive (A)].
  • composition (I)
  • composition (I) - preparing an aromatic sulfone polymer composition consisting of the ingredient(s) of composition (I) and the ingredient(s) of additive (A) [composition (II)], wherein composition (II) has a melt viscosity lower than the melt viscosity composition (1).
  • composition (II) has a
  • composition (II) has a viscosity measured at 380°C under a shear rate of 498.6 s "1 of less than V 2 times the viscosity of composition (I), measured at the same temperature and under the same shear rate.
  • composition (II) is supertough.
  • composition (II) has an
  • composition (I) increased fire resistance than of composition (I).
  • composition (II) has a heat release rate under fire conditions lower than composition (I).
  • aromatic sulfone polymer comprises at least one polybiphenylethersulfone.
  • Another embodiment of the present invention is where more than 80 wt. % of the aromatic sulfone polymer consists of the polybiphenylethersulfone.
  • aromatic sulfone polymer further comprises more than 20 wt. % of at least one bisphenol A polysulfone.
  • fluorocarbon polymer comprises recurring units derived from tetrafluoroethylene and perfluoromethylvinylether.
  • composition (II) comprises less than 10 wt. %, based on the total weight of composition (II), of the fluorocarbon polymer.
  • additive (A) further comprises a polymer selected from the group consisting of polyetherimides, polycarbonates, poly(aryl ether ketones), and liquid crystalline polymers.
  • composition (II) is free of inorganic flame retardant or comprises inorganic flame retardant in an amount of less than 2 pbw. (based on the weight of the aromatic sulfone polymer).
  • Anhydrous zinc borate is an example of inorganic flame retardant.
  • composition (II) is free of titanium dioxide or comprises titanium dioxide in an amount of less than 3 pbw. (based on the weight of the aromatic sulfone polymer).
  • composition (II) comprises titanium dioxide in an amount of at least 3 pbw. (based on the weight of the aromatic sulfone polymer).
  • Another aspect of the present invention is to a method for manufacturing an aircraft component comprising an aromatic sulfone polymer composition consisting of at least one aromatic sulfone polymer and, optionally, one or more other ingredients [composition (I)], which comprises applying to the aromatic sulfone polymer composition the method for lowering its melt viscosity as above described.
  • Another aspect of the present invention is to the use of an additive consisting of at least one fluorocarbon polymer comprising recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylefher and, optionally, one or more other ingredients [additive (A)], to lower the melt viscosity of an aromatic sulfone polymer composition consisting of at least one aromatic sulfone polymer and, optionally, one or more other ingredients [composition (1)].
  • Another aspect of the present invention is to a method for preparing an aromatic sulfone polymer composition in the need of lowering its melt viscosity, which comprises :
  • an additive consisting of at least one fluorocarbon polymer comprising recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylefher, and optionally, one or more other ingredients [additive (A)], in an effective amount to lower the melt viscosity of the aromatic sulfone polymer composition,
  • composition (II) Another aspect of the present invention is to an aromatic sulfone polymer composition [composition (II)] comprising :
  • composition (II) has a melt viscosity lower than the melt viscosity of the same composition without additive (A) [composition (I)].
  • composition (II) Another aspect of the present invention is to an aircraft component comprising composition (II).
  • the aircraft component is selected from the group consisting of an overhead passenger service unit, a window reveal, an air return grill, an aircraft wall panel, an aircraft overhead storage locker, an aircraft serving tray, an aircraft seat back, an aircraft cabin partition, and an aircraft duct.
  • an aspect of the present invention is to an aircraft comprising the aircraft component as above described.
  • This invention pertains to the use of an additive of a specific type to lower the melt viscosity of an aromatic sulfone polymer composition.
  • the use of the additive offers increased fire resistance in addition to lower melt viscosity.
  • the use of the additive offers supertough behaviour in addition to lower melt viscosity.
  • a very preferred aspect of the invention is where the use of the additive offers lower melt viscosity, increased fire resistance and supertough behaviour.
  • Criteria to determine these properties include, for example:
  • Melt viscosity Melt viscosity measurements can be made using a Kayeness LCR series capillary rheometer in accordance with ASTM D3835. High flow at high shear rate (above 100 s "1 ) is of particular interest since high shear rates achieved during thin-wall injection molding ; injection molding is a technique which is commonly used for manufacturing aromatic sulfone polymer compositions.
  • the viscosity of the composition (II) measured at 380°C under a shear rate of 3513.5 s "1 is advantageously lower than 200 Pa.s, and preferably lower than about 175 Pa.s.
  • the viscosity of the composition (IT) measured at 380°C under a shear rate of 498.6 s "1 is advantageously lower than 600 Pa.s, preferably lower than 450 Pa.s, and very preferably lower than 300 Pa.s.
  • the viscosity of the composition (II) measured at 380°C under a shear rate of 23.2 s "1 is advantageously lower than 800 Pa.s, and preferably lower than 700 Pa.s.
  • the viscosity of the composition (H) measured at 380°C under a shear rate of 3513.5 s " is advantageously less than 9 / 10 times the viscosity of composition (I), and preferably less than 4 / 5 times the viscosity of composition (I), the viscosity of composition (I) being measured at the same temperature and under the same shear rate.
  • the viscosity of the composition (II) measured at 380°C under a shear rate of 498.6 s "1 is advantageously less than 9 / ⁇ 0 times the viscosity of composition (I), preferably less than 4 / 5 times the viscosity of composition (I), more preferably less than 3 / 5 times the viscosity of composition (1), and still more preferably less than V 2 times the viscosity of composition (I), the viscosity of composition (I) being measured at the same temperature and
  • the viscosity of the composition (II) measured at 380°C under a shear rate of 23.2 s "1 is advantageously less than 9 / 10 times the viscosity of composition (I), preferably less than 4 / 5 times the viscosity of composition (I), and more preferably less than 7 / ⁇ 0 times the viscosity of composition (I), the viscosity of composition (I) being measured at the same temperature and under the same shear rate.
  • the toughness can be measured by the Notched Izod impact testing per ASTM D-256.
  • Composition (II) has a Notched Izod value, measured by the above test, of advantageously at least V 3 of the Notched Izod value, preferably at least 2 / 3 of the Notched Izod value, and still more preferably 4 / 5 of the Notched Izod value of composition (1), measured in the same conditions.
  • Supertough behaviour or supertoughness is usually illustrated by a Notched Izod value greater than 10 ft-lb/in and by a ductile failure mode on Notched Izod impact testing per ASTM D-256.
  • Composition (II) is advantageously supertough.
  • Fire resistance can be measured according to one criterion or a combination of criteria such as low heat release rate, high self-extinguishing properties and low smoke generation, as described herein.
  • Composition (II) has advantageously an increased fire resistance relative to composition (I). 4. Heat release rate.
  • Heat release characteristics can be determined by the procedures of Part 25 of Title 14 of the Code of Federal Regulations.
  • composition (II) has advantageously a decreased heat release rate under fire conditions relative to composition (I).
  • composition (II) meets advantageously the 65/65 1990 compliance levels in these standards for the two minutes total heat release and the maximum heat release rate and preferably show superior heat release performance and vastly exceed the 1990 standards. To this point, the heat release properties of composition (II) were evaluated in accordance with FAR 25. 853 Amendment 25-83, Appendix F, Part IV. Ohio State University (OSU) heat release performance levels of ⁇ 5kW/(min.m 2 ) at 2 minutes and a maximum heat release rate of 30-40 kW/m 2 could be achieved.
  • FAR 25. 853 Amendment 25-83 Appendix F, Part IV. Ohio State University (OSU) heat release performance levels of ⁇ 5kW/(min.m 2 ) at 2 minutes and a maximum heat release rate of 30-40 kW/m 2 could be achieved.
  • An increase in self-extinguishing properties can correlate with a decreased burn length and/or a decreased burn time.
  • Composition (II) has advantageously self-extinguishing properties greater than or equal to the self-extinguishing properties of composition (I).
  • Smoke generation can be measured by the smoke density test in accordance with FAR 25.853 (a-l)/ASTM F814/E662.
  • a decrease of smoke generation is intended to denote a decrease of at least one of the followings, as measured in accordance with the above test : (i) the smoke density ; (ii) the overall toxic gas emission ; (iii) the carbon monoxide emission.
  • the smoke generation under fire conditions of composition (II) is advantageously lower than or equal to the smoke generation under the same fire conditions of composition (I).
  • composition (II) measured at 4 min according to FAR 25.853 (a-l)/ASTM F814/E662 is advantageously at most 2, and preferably at most 1.
  • composition (II) The overall toxic gas emission of composition (II), measured according to BSS 7239
  • - ATS 1000/ABD0031 is advantageously lower than 200 ppm, and preferably lower than 20 ppm.
  • composition (II) The carbon monoxide emission of composition (II), measured according to BSS 7239
  • - ATS 1000/ABD0031 is advantageously lower than 100 ppm, and preferably lower than 10 ppm.
  • the aromatic sulfone polymer The aromatic sulfone polymer.
  • RI recurring units
  • the aromatic sulfone polymer comprises preferably at least 80 mole %, and very preferably at least 95 mole %, of recurring units (RI). More preferably, it consists of recurring units (RI).
  • Suitable aromatic dihalocompounds to the purpose of the present invention are notably dihalobenzene disulfone compounds of the general formula
  • X is a halogen, especially CI
  • Q is a divalent radical susceptible of being obtained by removing two replaceable hydrogens from a molecule of formula QH 2 , such as
  • R is an aliphatic divalent group of up to 6 carbon atoms such as a methylene, ethylene or isopropylene and the like.
  • Other suitable aromatic dihalocompounds are the 4,4'- dihalodiphenylsulfones .
  • the aromatic dihalocompound comprises preferably at most six, preferably at most four aromatic rings, and still more preferably at most two aromatic rings.
  • dihalocompounds are the 4,4'-dihalodiphenylsulfones.
  • aromatic diol which is able to polymerize with the aromatic dihalocompound is suitable.
  • aromatic diols are 4,4'-biphenol (i.e. 4,4'- dihydroxybiphenyl), bisphenol A, 4,4'-dihydroxy-diphenylsulfone (also known as bisphenol S), hydroquinone, and 4,4'-dihydroxy-diphenylether.
  • the aromatic diol is advantageously free from functional groups other than the -OH groups.
  • the aromatic diol comprises advantageously at most two aromatic rings. It is preferably chosen from 4,4'-biphenol, bisphenol A, 4,4'-dihydroxy-diphenylsulfone and 4,4'- dihydroxy-diphenylether.
  • Non limitative examples of aromatic sulfone polymers suitable to the purpose of the present invention are the polyethersulfone consisting of recurring units,
  • copolymers consisting of the above two recurring units, the polybiphenylethersulfones and the bisphenol A polysulfones.
  • the aromatic sulfone polymer comprises advantageously at least one polybiphenylethersulfone, i.e. a polymer comprising at least 50 mole % of recurring units formed by the polycondensation reaction between at least one 4,4'-dihalodiphenylsulfone and 4,4'-biphenol.
  • Polybiphenylethersulfones consist preferably of recurring units formed by the polycondensation reaction between at least one 4,4'-dihalodiphenylsulfone and 4,4'-biphenol :
  • more than 80 wt. % of the aromatic sulfone polymer consist of the polybiphenylethersulfone.
  • the aromatic sulfone polymer consists more preferably of the polybiphenylethersulfone.
  • the aromatic sulfone polymer comprises, in addition to the polybiphenylethersulfone, more than 10 wt. % of at least one bisphenol A polysulfone, i.e. a polymer comprising at least 50 mole % of recurring units formed by the polycondensation reaction between at least one 4,4'-dihalodiphenyl- sulfone and bisphenol A.
  • Bisphenol A polysulfones consist preferably of recurring units formed by the polycondensation reaction between at least one 4,4'-dihalodiphenylsulfone and bisphenol A :
  • the aromatic sulfone polymer comprises more preferably more than 20 wt. % of at least one bisphenol A polysulfone ; still more preferably, it comprises more than 20 wt. % of at least one bisphenol A polysulfone and more than 70 wt. % of polybiphenylethersulfone.
  • Composition (II) comprises advantageously at least 65 %, preferably at least 75% and more preferably at least 85 % by weight (based on the total weight of the composition) of the
  • aromatic sulfone polymer
  • the aromatic sulfone polymer may be produced by any suitable method such as those well known in the art and described in U.S. Pat. Nos. 3,634,355; 4,008,203; 4,108,837; and 4,175,175; all of which are incorporated herein by reference.
  • the molecular weight of the aromatic sulfone polymer is advantageously such that its melt index (measured using ASTM D-1238 at 380C under a 2.16 kg load be in the range of from about 4 to about 28 g /10 min.
  • Use of an aromatic sulfone polymer, such as a polybiphenyethersulfone, having a melt index lower than 2 g/10 min results usually in materials of lessened melt-fabricability ; use of an aromatic sulfone polymer, such as a polybiphenyethersulfone, with a melt index above 28 g /10 min, on the other hand, may result in materials with marginal or unsatisfactory chemical resistance.
  • the melt flow range will preferably be 8-20 g/10 minutes for optimal performance.
  • Examples of commercial aromatic sulfone polymers useful in the compositions according to the present invention include notably UDEL ® bisphenol A polysulfones, RADEL R polybiphenylethersulfones and RADEL ® A sulfone polymers ; these are available from Solvay Advanced Polymers, L.L.C.
  • Composition (II) also can have a slightly lower specific gravity.
  • composition (II) allows advantageously composition (II) to be used in thin-wall parts for weight reduction.
  • the fluorocarbon polymer comprising recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylether is advantageously one which, when used alone as additive (A), results in lowering the melt viscosity of sulfone polymer composition (I).
  • the fluorocarbon polymer has an essentially crystalline structure and has a melting point in excess of about 120° C.
  • Suitable perfluorinated monoolefins include notably octafluorobutenes, hexafluoropropylene and tetrafluoroefhylene.
  • the perfluorinated monolefin comprises preferably tetrafluoroethylene.
  • the perfluorinated monolefin is tetrafluoroethylene.
  • a "perfluoroalkylvinylether” is intended to denote any ethylenically unsatured compound which is perfluorinated (i.e. in which all the hydrogen atoms have been substituted by fluorine atoms) and which comprises at least one group (G) chosen from - O - (ether group) and - NH - (amino group).
  • the perfluoralkylvinylether comprises preferably one and only one group (G).
  • Group (G) is preferably an ether group.
  • Group (G) is preferably linked to a vinyl or to an allyl group on one hand, and to a C 2 - C 20 hydrocarbyl group on the other hand.
  • Group (G) is very preferably linked to a vinyl group on one hand, and to a C 2 -C 20 alkyl group on the other hand.
  • the alkyl group of the perfluoroalkylvinylether contains preferably up to six carbon atoms, very preferably up to three carbon atoms, and still more preferably one carbon atom. Good results were obtained when using perfluoromefhylvinylether, perfluoroethylvinylether or the perfluoropropylvinylethers as the perfluoralkylvinylefher. Excellent results were obtained when using perfluoromethylvinylefher as the perfluoralkylvinylefher.
  • the fluorocarbon polymer consists essentially of recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylether. Still more preferably, the fluorocarbon polymer consists of recurring units derived from at least one perfluorinated monoolefin and at least one perfluoroalkylvinylether.
  • HYFLON ® from SOLVAY SOLEXIS S.p.A.
  • Composition (II) comprises advantageously less than 20 wt. %, preferably less than 10 wt. % and more preferably less than 6 wt. %, based on the total weight of composition (II), of the fluorocarbon polymer.
  • composition (II) comprises advantageously more than 0.1 wt. %, preferably more than 0.5 % and more preferably more than 1 wt. %, based on the total weight of composition (II), of the fluorocarbon polymer.
  • composition (II) comprises 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18 and 19 weight % as well as all values
  • composition (II) comprises a polybiphenylethersulfone polymer, 1-15 wt. %, based on the total weight of composition (II), of MFA, and optionally 0-10% of a liquid crystal polymer (LCP).
  • LCP liquid crystal polymer
  • Additive (A) can further comprise, in addition to the fluorocarbon polymer, any ingredient which, when used alone as additive of composition (I), lowers the melt viscosity of composition (I).
  • additive (A) consists of the fluorocarbon polymer.
  • additive (A) further comprises a polymer (P) selected from the group consisting of polyetherimides, polycarbonates, poly(aryl ether ketones) and liquid crystalline polymers.
  • P a polymer selected from the group consisting of polyetherimides, polycarbonates, poly(aryl ether ketones) and liquid crystalline polymers.
  • additive (A) in addition to the fluorocarbon polymer, and their levels, depends possibly upon the end use envisioned for the material.
  • a composition comprising a high amount of a polybiphenylethersulfone in combination with an additive (A) comprising a poly(aryl ether ketone) in addition to the fluorocarbon polymer, may be preferred ; here, a high amount of polybiphenylethersulfone means usually more than 70 weight %, or more than about 75 weight % of the polybiphenylethersulfone based on combined weight of polyphenylsulfone and poly(aryl ether ketone).
  • polybiphenylethersulfone In injection molding applications, for example, less than 70 weight % or less than about 65 weight % of the polybiphenylethersulfone may be used. Such compositions having more than 70 wt % polybiphenylethersulfone may display poor processing in many injection molding applications, whereas such high levels will provide better processing for
  • Poly(aryl ether ketones) encompass the generic description of a class of crystalline aromatic polymers. These resins are readily available from a variety of commercial sources, and methods for their preparation are well known, including the processes described for example in U.S. Pat. Nos. 3,441,538, 3,442,857, 3,516,966, 4,396,755 and 4,816,556; all of which are incorporated herein by reference in their entireties. Commercially available resins include the VICTREX ® PEEK poly(aryl ether) ketones, available from Victrex, LTD.
  • Polymer (P) is preferably a liquid crystalline polymer (LCP).
  • the liquid crystal polymer can be in an amount of 10, 20, 30, 40, 50, 70, 80 or 90 weight %, based on the total weight of additive (A), or any other value or subrange there between.
  • the amount of the liquid crystal polymer ranges preferably from 1 to 6 wt. %, based on the total weight of the composition.
  • the liquid crystalline polymer is advantageously a wholly aromatic polyester.
  • composition (I) is advantageously chosen from ingredients which, when used alone as additives of an aromatic sulfone polymer, do not result in lowering the melt viscosity of the aromatic sulfone polymer.
  • composition (I) consists of the aromatic sulfone polymer.
  • composition (I) contains one or more ingredients in addition to the aromatic sulfone polymer.
  • additional components and the levels, depend possibly upon the end use envisioned for the material.
  • composition (I) also contains titanium dioxide.
  • composition (I) is substantially free of titanium dioxide and, in some cases, free of titanium dioxide, which means no detectable levels of titanium dioxide as measured according to procedures commonly employed in the field.
  • titanium dioxides suitable for use in the present invention include any commercially available TiO 2 .
  • the particle size of the TiO is preferably below about 2 microns because higher particle sizes can deleteriously affect the physical properties of the polymer. Any of the available crystalline forms of the titanium dioxide may be used, with the rutile form preferred due to its superior pigment properties.
  • the total amount of TiO 2 will preferably be below about 12 weight % based on the total weight of composition (I), inclusive of below 11, 10, 9, 8, 7, 6, 5, 4, 3, 2, and 1 weight % as well as all values and subranges there between, to avoid compounding and processing difficulties. Certain embodiments of the present invention employ about 1 to about 10 weight % TiO 2 since these materials have better processability. In certain other embodiments of the present invention the amount of TiO 2 in the polymer composition ranges from about 7-10 weight %.
  • composition (1) comprises a solid filler or reinforcing agent in amounts from about 1 to 50 percent by weight, based on the total weight of composition (I), inclusive of all values and subranges there between. In certain other compositions of the present invention the amount of solid filler or reinforcing is from about 10 to 30 percent, based on the total weight of composition (I).
  • Fibers which may serve as reinforcing media include, but are not limited to, glass fibers, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of metals such as aluminum fibers, titanium fibers, magnesium fibers, wollastonite, rock wool fibers, steel fibers, tungsten fibers, etc.
  • Representative filler and other materials include glass, calcium silicate, silica, clays, talc, mica; pigments such as carbon black, iron oxide, cadmium red, iron blue, and other additives such as, wollastonite, graphite, aluminum trihydrate, sodium aluminum carbonate, barium ferrite, etc.
  • Composition (I) may further include additional additives commonly employed in the resin art such as thermal stabilizers, ultraviolet light stabilizers, plasticizers, and the like.
  • Composition (II) may be prepared by the compounding processes commonly employed in the resin compounding field.
  • the individual components commonly provided in the form of chips, pellets or powders
  • the composition of solid polymer particles which may also including reinforcing filler, fiber pigments, additives, and the like, may then be pelletized, for example by melt extrusion to form a strand which, upon solidification, can be broken up into chips or pellets. It is not necessary to combine all components in a single operation.
  • a composition containing fluorocarbon polymer can be compounded first, and melt blended with the desired amounts of TiO 2 in a later operation.
  • Composition (II) may be further fabricated by melt processing to form a variety of relatively stiff, shaped articles and molded goods, including molded three-dimensional articles, fibers, films, tapes, and the like, as well as used in forming sheet goods for use in laminating and for coating applications.
  • composition (IT) can be used to manufacture various articles commonly made with aromatic sulfone polymers. Methods of fabricating such articles can be performed according to the known methods in the field, for example, forming the article using injection molding or extrusion. For example, aircraft components, and particularly, interior components of aircrafts can be made with composition (II).
  • composition (II) could be used anywhere where shear thinning flow behavior for thin-wall parts, good toughness, and fire resistance (notably, flame resistance) are important.
  • Such applications include, but are not limited to, overhead passenger service units, window reveals, air return grills, wall panels, overhead storage lockers, serving trays, seat backs, cabin partitions, and ducts.
  • another embodiment of the present invention is an aircraft comprising one or more of these aircraft components.
  • All the polymer resins present in the exemplified compositions were dried in a dehumidifying oven at 150°C overnight for approximately 16 hours.
  • the compositions were prepared by tumble blending all the ingredients of the aromatic sulfone polymer compositions for approximately 30 minutes.
  • the aromatic sulfone polymer compositions were then extruded using a 25mm twin screw double vented Berstorff extruder having an L/D ratio of 33:1 at a rate of approximately 25 lb/hr at a screw speed of 200 rpm.
  • the aromatic sulfone polymer compositions were extruded at a melt temperature of 350°C.
  • the first vent port was open to the atmosphere while the second vent port was connected to a vacuum pump.
  • the strands were then passed through a water trough for cooling and then pelletized.
  • Smoke Density The smoke density testing was performed in accordance with FAR 25.853 (a-l)/ASTM F814/E662. In this test a 3"x3"x-.80" specimen was exposed to multiple flamelets in combination with a 2.5 W/cm 2 radiant heat source in an enclosed National Bureau of Standards smoke density chamber. The smoke density was determined by light attenuation of light intensity of a 2200K light source shown vertically up through the test chamber. A microphotometer was used to measure the light intensity. The optical density yielded a measure of the amount of smoke produced when burned. This value was captured after combustion for four minutes.
  • Tables 3 to 6 show that all the examplified compositions exhibit, in addition to an extremely low viscosity (as illustrated in table 2), a very high level of fire resistance properties, which far exceeds the requirements. With this regard, they perform at least in a comparable fashion and, for some properties like the heat release, better than control composition CE.
  • Table 7 shows that all the examplified compositions exhibit, in addition to an extremely low melt viscosity (as illustrated in table 2), an extremely high level of toughness, commonly referred to as “supertoughness” or “supertough behaviour” (notched Izod impact strength above 10 ft-lb/in and ductile fracture at the notched Izod impact test).

Abstract

L'invention concerne un procédé de réduction de la viscosité à l'état fondu d'une composition polymérique sulfone aromatique constituée d'au moins un polymère sulfone aromatique et, éventuellement, d'au moins un autre constituant [composition (I)]. Ce procédé consiste à utiliser un additif consistant en au moins un polymère de fluorocarbone comportant des unités périodiques dérivées d'au moins une mono-oléfine perfluorée et d'au moins un perfluoroalkylvinyléther et, éventuellement, d'au moins un autre constituant [additif (A)]. L'invention concerne également un procédé de production d'un composant d'avion contenant une composition polymérique sulfone aromatique constituée d'au moins un polymère sulfone aromatique et, éventuellement, d'au moins un autre constituant qui comporte l'application du procédé susmentionné de réduction de sa viscosité à l'état fondu à cette composition polymérique sulfone aromatique.
PCT/US2004/005229 2003-03-10 2004-03-10 Procede de reduction de la viscosite a l'etat fondu d'une composition polymerique sulfone aromatique, et procede de production d'un composant d'avion WO2004081103A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP04737306A EP1638840A4 (fr) 2003-03-10 2004-03-10 Procede de reduction de la viscosite a l'etat fondu d'une composition polymerique sulfone aromatique, et procede de production d'un composant d'avion
US10/547,744 US20070037928A1 (en) 2004-03-10 2004-03-10 Method for lowering the melt viscosity of an aromatic sulfone polymer composition, and method for manufacturing an aircraft component
JP2006508794A JP2006519911A (ja) 2003-03-10 2004-03-10 芳香族スルホンポリマー組成物の溶融粘度を低下させる方法及び航空機構成部品の製造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US45296003P 2003-03-10 2003-03-10
US60/452,960 2003-03-10
US51740603P 2003-11-06 2003-11-06
US60/517,406 2003-11-06

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WO2004081103A2 true WO2004081103A2 (fr) 2004-09-23
WO2004081103A3 WO2004081103A3 (fr) 2005-01-20

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EP (1) EP1638840A4 (fr)
JP (1) JP2006519911A (fr)
IN (1) IN2007DE03642A (fr)
WO (1) WO2004081103A2 (fr)

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JP2007221754A (ja) * 2006-01-23 2007-08-30 Mitsubishi Plastics Ind Ltd スピーカー用振動板
WO2008090235A2 (fr) * 2007-02-28 2008-07-31 Solvay Advanced Polymers, L.L.C. Compositions thermoplastiques contenant des microsphères
JP2008530330A (ja) * 2005-02-16 2008-08-07 ソルヴェイ アドバンスド ポリマーズ リミテッド ライアビリティ カンパニー ポリ（アリールエーテルスルホン）材料及びその使用
WO2009135893A1 (fr) * 2008-05-09 2009-11-12 Solvay Advanced Polymers, L.L.C. Composition poly(aryle éther sulfone) haute fluidité résistante au feu
US8389672B2 (en) 2006-01-23 2013-03-05 Mitsubishi Plastics, Inc. Diaphragm for electro-accoustic transducer
WO2013049620A3 (fr) * 2011-09-30 2013-05-23 Saint-Gobain Performance Plastics Corporation Article de fluoropolymère traité à l'état fondu et procédé pour le traitement à l'état fondu de fluoropolymère
US9878770B2 (en) 2008-03-28 2018-01-30 Airbus Operations Gmbh Aircraft fuselage having burnthrough resistant components

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008530330A (ja) * 2005-02-16 2008-08-07 ソルヴェイ アドバンスド ポリマーズ リミテッド ライアビリティ カンパニー ポリ（アリールエーテルスルホン）材料及びその使用
US8623970B2 (en) 2006-01-23 2014-01-07 Mitsubishi Plastics, Inc. Diaphragm for electro-acoustic transducer
US8389672B2 (en) 2006-01-23 2013-03-05 Mitsubishi Plastics, Inc. Diaphragm for electro-accoustic transducer
JP2007221754A (ja) * 2006-01-23 2007-08-30 Mitsubishi Plastics Ind Ltd スピーカー用振動板
WO2008090235A2 (fr) * 2007-02-28 2008-07-31 Solvay Advanced Polymers, L.L.C. Compositions thermoplastiques contenant des microsphères
WO2008090235A3 (fr) * 2007-02-28 2008-09-25 Solvay Advanced Polymers Llc Compositions thermoplastiques contenant des microsphères
US8362114B2 (en) 2007-02-28 2013-01-29 Solvay Advanced Polymers, L.L.C. Thermoplastic compositions containing microspheres
US9878770B2 (en) 2008-03-28 2018-01-30 Airbus Operations Gmbh Aircraft fuselage having burnthrough resistant components
WO2009135893A1 (fr) * 2008-05-09 2009-11-12 Solvay Advanced Polymers, L.L.C. Composition poly(aryle éther sulfone) haute fluidité résistante au feu
US8586673B2 (en) 2008-05-09 2013-11-19 Solvay Advanced Polymers, L.L.C. Fire resistant, high flow poly(aryl ether sulfone) composition
US9441110B2 (en) 2008-05-09 2016-09-13 Solvay Specialty Polymers Usa, L.L.C. Fire resistant, high flow poly(aryl ether sulfone) composition
WO2013049620A3 (fr) * 2011-09-30 2013-05-23 Saint-Gobain Performance Plastics Corporation Article de fluoropolymère traité à l'état fondu et procédé pour le traitement à l'état fondu de fluoropolymère
US9156973B2 (en) 2011-09-30 2015-10-13 Saint-Gobain Performance Plastics Corporation Meltprocessed fluoropolymer article and method for melt-processing fluoropolymers

Also Published As

Publication number Publication date
EP1638840A4 (fr) 2006-09-06
EP1638840A2 (fr) 2006-03-29
WO2004081103A3 (fr) 2005-01-20
JP2006519911A (ja) 2006-08-31
IN2007DE03642A (fr) 2007-08-24

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