WO2004078765A3 - Catalyseurs pour la polymerisation du styrene - Google Patents

Catalyseurs pour la polymerisation du styrene Download PDF

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Publication number
WO2004078765A3
WO2004078765A3 PCT/EP2004/002179 EP2004002179W WO2004078765A3 WO 2004078765 A3 WO2004078765 A3 WO 2004078765A3 EP 2004002179 W EP2004002179 W EP 2004002179W WO 2004078765 A3 WO2004078765 A3 WO 2004078765A3
Authority
WO
WIPO (PCT)
Prior art keywords
inventive
polymerization
transition metal
catalyst system
catalysts
Prior art date
Application number
PCT/EP2004/002179
Other languages
German (de)
English (en)
Other versions
WO2004078765A2 (fr
Inventor
Jun Okuda
Klaus Moeller
Valentine Reimer
Original Assignee
Basf Ag
Jun Okuda
Klaus Moeller
Valentine Reimer
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Jun Okuda, Klaus Moeller, Valentine Reimer filed Critical Basf Ag
Publication of WO2004078765A2 publication Critical patent/WO2004078765A2/fr
Publication of WO2004078765A3 publication Critical patent/WO2004078765A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/18—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C07C323/20—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton with singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Systèmes de ligands bisphénolate et composés apparentés, composés de métaux de transition qui possèdent les systèmes de ligands selon la présente invention, système catalyseur pour la polymérisation de composés non saturés contenant au moins un composé de métaux de transition selon la présente invention et au moins un cocatalyseur, procédé de production de polymères par polymérisation ou copolymérisation d'au moins un composé non saturé en présence d'un système catalyseur selon la présente invention et utilisation d'un composé de métaux de transition selon la présente invention ou d'un système catalyseur selon la présente invention pour la production de polystyrène isotactique.
PCT/EP2004/002179 2003-03-05 2004-03-04 Catalyseurs pour la polymerisation du styrene WO2004078765A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10309837A DE10309837A1 (de) 2003-03-05 2003-03-05 Katalysatoren für die Polymerisation von Styrol
DE10309837.2 2003-03-05

Publications (2)

Publication Number Publication Date
WO2004078765A2 WO2004078765A2 (fr) 2004-09-16
WO2004078765A3 true WO2004078765A3 (fr) 2004-11-04

Family

ID=32864216

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/002179 WO2004078765A2 (fr) 2003-03-05 2004-03-04 Catalyseurs pour la polymerisation du styrene

Country Status (2)

Country Link
DE (1) DE10309837A1 (fr)
WO (1) WO2004078765A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006066126A2 (fr) 2004-12-16 2006-06-22 Symyx Technologies, Inc. Ligands heterocycliques de phenol, complexes metalliques et leurs utilisations en tant que catalyseurs
EP2359930A1 (fr) 2005-12-16 2011-08-24 Dow Global Technologies LLC Polymers préparé en presence des complexes metalliques avec des ligandes polydentates heteroatomiques
CN107980026B (zh) 2015-04-24 2020-11-10 倍耐力轮胎股份公司 高性能轮胎
WO2016170522A1 (fr) 2015-04-24 2016-10-27 Pirelli Tyre S.P.A. Pneu à haute performance
CN106317282B (zh) * 2016-08-19 2018-10-23 东华大学 超高分子量乙烯/苯乙烯类共聚物的制备方法
CN115697722A (zh) * 2020-06-09 2023-02-03 倍耐力轮胎股份公司 高性能轮胎

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149933A (en) * 1960-08-25 1964-09-22 Bayer Ag Process for stabilizing liquid fuels
US3161612A (en) * 1959-04-15 1964-12-15 Bayer Ag Alkylated amino phenols protecting rubber goods against ozone
US6333423B1 (en) * 1999-09-10 2001-12-25 Ramot University Authority For Applied Research And Industrial Development Ltd. Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3161612A (en) * 1959-04-15 1964-12-15 Bayer Ag Alkylated amino phenols protecting rubber goods against ozone
US3149933A (en) * 1960-08-25 1964-09-22 Bayer Ag Process for stabilizing liquid fuels
US6333423B1 (en) * 1999-09-10 2001-12-25 Ramot University Authority For Applied Research And Industrial Development Ltd. Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HINSHAW C J ET AL: "MOLYBDENUM(VI)-DIOXO COMPLEXES WITH LINEAR AND TRIPODAL TETRADENTATE LIGANDS: MODELS FOR THE MOLYBDENUM(VI/V) CENTERS OF THE MOLYBDENUM HYDROXYLASES AND RELATED ENZYMES 1. SYNTHESES AND STRUCTURES", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY, EASTON, US, vol. 28, no. 25, 1989, pages 4483 - 4496, XP002935342, ISSN: 0020-1669 *
KOMISSAROV, V. N. ET AL: "Synthesis of amino derivatives of sterically hindered phenols from quinones", ZHURNAL ORGANICHESKOI KHIMII , 26(10), 2188-91 CODEN: ZORKAE; ISSN: 0514-7492, 1990, XP009032847 *
OKUDA J ET AL: "SYNTHESIS AND CHARACTERIZATION OF MONONUCLEAR TITANIUM COMPLEXES CONTAINING A BIS(PHENOXY) LIGAND DERIVED FROM 2,2'-METHYLENE-BIS(6-TERT-BUTYL-4-METHYLPHENOL)", CHEMISCHE BERICHTE, XX, XX, vol. 128, no. 3, 1995, pages 221 - 227, XP009012454, ISSN: 0009-2940 *

Also Published As

Publication number Publication date
WO2004078765A2 (fr) 2004-09-16
DE10309837A1 (de) 2004-09-16

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