WO2004036210A1 - Method for on-line monitoring of quality and condition of non-aqueous fluids - Google Patents

Method for on-line monitoring of quality and condition of non-aqueous fluids Download PDF

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Publication number
WO2004036210A1
WO2004036210A1 PCT/US2003/032235 US0332235W WO2004036210A1 WO 2004036210 A1 WO2004036210 A1 WO 2004036210A1 US 0332235 W US0332235 W US 0332235W WO 2004036210 A1 WO2004036210 A1 WO 2004036210A1
Authority
WO
WIPO (PCT)
Prior art keywords
fluid
frequency
temperature
low
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/032235
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English (en)
French (fr)
Inventor
Vadim F. Lvovich
David B. Skursha
Frederick P. Boyle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Priority to CA002502283A priority Critical patent/CA2502283A1/en
Priority to AU2003284079A priority patent/AU2003284079B2/en
Priority to DE60323656T priority patent/DE60323656D1/de
Priority to JP2004544845A priority patent/JP4309350B2/ja
Priority to EP03776310A priority patent/EP1552292B1/en
Priority to BR0315423-8A priority patent/BR0315423A/pt
Publication of WO2004036210A1 publication Critical patent/WO2004036210A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/26Oils; Viscous liquids; Paints; Inks
    • G01N33/28Oils, i.e. hydrocarbon liquids
    • G01N33/2888Lubricating oil characteristics, e.g. deterioration

Definitions

  • FIG. 2 is a schematic representation of an apparatus, wherein the fluid temperature is monitored but not controlled.
  • FIG. 1 is a schematic illustration of an apparatus 1 that can be used to collect appropriate data required for the monitoring and detecting of on-line the characterization of a fluid.
  • Apparatus 1 includes three pairs of essentially parallel electrodes 3 immersed in highly resistive fluid 5, in conduit 7. The pairs of electrodes 3 are fixedly held in and electrically isolated from conduit 7, by mounts 9.
  • Apparatus 1 also includes three signal generators 11a, lib, lie that supply sinusoidal signals of fixed amplitude, frequency and offset voltage through electrical conduits 13, to an associated pair of electrodes 3.
  • a signals offset voltage is defined as the time averaged voltage of the signal.
  • apparatus 43 of FIG. 2 can be mounted in locations other than conduit 7 as long as fluid 5 flows between electrode pairs 3 in a manner that allows the fluid between the electrode pairs to be at the temperature measured by thermocouple 31 and representative of the current quality/condition of the fluid in the equipment being monitored.
  • a fewer number of signal generators 11a, lib, lie and pairs of electrodes 3 can be used if a signal genera- tor can be controlled to apply multiple desired frequencies and/or off set- voltages.
  • the electrodes 3 need not be flat plates with only one surface of each electrode op- posed to the other electrode.
  • An apparatus embodiment can have electrodes geometries with greater than one surface of each electrode opposed to the other electrode.
  • Apparatus 43 can be individual components, as shown in FIG. 2, or can be integrated components, which, for example, reduce cost, size and/or power requirements of the apparatus.
  • a fluid's real-impedance response 65, 67 rises relatively quickly, as a function of equipment use, to a maximum value (M M ) 69.
  • the value of the peak 69 is not as critical to the useful life of the fluid as is the percent decrease from this peak value during fluid life.
  • Curves 65 and 67 are scaled to have the same peak value 69.
  • the real-impedance of both the premium and standard quality fluids decrease as a function of time, with the standard fluid decreasing more rapidly.
  • the method in block 117 determines if the medium-frequency response S M is greater than a stored maximum medium-frequency response MM- If the answer is "yes”, which means that the medium-frequency response has not reached its maximum value, than MM is replaced by S M in block 119 and no further analysis of the medium-frequency response is done with the method advancing to block 121 where variable "M" is set equal to zero to indicate that the fluid condition determined by the fluid's medium- frequency response is acceptable. If the block 117 determination is "no", i.e.
  • FIG. 9 uses low-, medium- and high frequency responses to determine fluid quality and conditions
  • a similar embodiment could be shown where the high-frequency response S H in not used in the determination for fluids in applications where the change in the fluid's high-frequency response is substantially less significant than the fluid's medium- and low-frequency response changes.
  • the dielectric/impedance analyzer sequentially applied about 3 V peak-to-peak electrical signals to the electrodes immersed in the oil at about 1 Hz with an about 3 V offset such that the signal oscillated from about +1.5 V to about +4.5 V relative to ground, and at about 100 Hz and about 1 MHz with about zero volt offset set such that the signals oscillate from about -1.5 to about +1.5 V relative to ground.
  • the dielectric/impedance analyzer determined the test oil's imaginary impedance (Zj m ) at about 1 Hz, the test oil's real impedance (Z rea i) at about 100 Hz and the test oil's dielectric ( ⁇ ) at about 1 MHz.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Testing And Monitoring For Control Systems (AREA)
PCT/US2003/032235 2002-10-16 2003-10-14 Method for on-line monitoring of quality and condition of non-aqueous fluids Ceased WO2004036210A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA002502283A CA2502283A1 (en) 2002-10-16 2003-10-14 Method for on-line monitoring of quality and condition of non-aqueous fluids
AU2003284079A AU2003284079B2 (en) 2002-10-16 2003-10-14 Method for on-line monitoring of quality and condition of non-aqueous fluids
DE60323656T DE60323656D1 (de) 2002-10-16 2003-10-14 Verfahren zur online- überwachung von qualität und zustand von nichtwässrigen fluiden
JP2004544845A JP4309350B2 (ja) 2002-10-16 2003-10-14 非水性流体の品質および状態をオンライン監視するための方法
EP03776310A EP1552292B1 (en) 2002-10-16 2003-10-14 Method for on-line monitoring of quality and condition of non-aqueous fluids
BR0315423-8A BR0315423A (pt) 2002-10-16 2003-10-14 Método para determinar a condição de um fluido não-aquoso

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/271,885 2002-10-16
US10/271,885 US6861851B2 (en) 2002-10-16 2002-10-16 Method for on-line monitoring of quality and condition of non-aqueous fluids

Publications (1)

Publication Number Publication Date
WO2004036210A1 true WO2004036210A1 (en) 2004-04-29

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PCT/US2003/032235 Ceased WO2004036210A1 (en) 2002-10-16 2003-10-14 Method for on-line monitoring of quality and condition of non-aqueous fluids

Country Status (10)

Country Link
US (1) US6861851B2 (enExample)
EP (1) EP1552292B1 (enExample)
JP (1) JP4309350B2 (enExample)
KR (1) KR101072208B1 (enExample)
AT (1) ATE408821T1 (enExample)
AU (1) AU2003284079B2 (enExample)
BR (1) BR0315423A (enExample)
CA (1) CA2502283A1 (enExample)
DE (1) DE60323656D1 (enExample)
WO (1) WO2004036210A1 (enExample)

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US6989680B2 (en) * 2004-02-24 2006-01-24 Eaton Corporation Detection of coolant contamination in lubricating fluids
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US7355415B2 (en) * 2004-05-07 2008-04-08 The Lubrizol Corporation Method for on-line monitoring of condition of non-aqueous fluids
US20050248358A1 (en) * 2004-05-07 2005-11-10 The Lubrizol Corporation, A Corporation Of The State Of Ohio Method for on-line monitoring of condition of non-aqueous fluids
IL166760A0 (en) * 2004-05-13 2006-01-15 Nexense Ltd Method and apparatus for non-invasively monitoringconcentrations of glucose or other target substan ces
JP5158780B2 (ja) * 2004-10-06 2013-03-06 ザ ルブリゾル コーポレイション スルホネートを含有する潤滑組成物
US7362110B2 (en) * 2005-04-06 2008-04-22 Gm Global Technology Operations, Inc. Measurement cell for liquids
US7259575B2 (en) * 2005-04-08 2007-08-21 The Lubrizol Corporation Method for on-line fuel-dilution monitoring of engine lubricant
US20070202603A1 (en) * 2006-02-27 2007-08-30 Steven Wayne Counts Apparatus and method for sampling and correcting fluids
DE102006027436A1 (de) * 2006-06-12 2007-12-13 Conti Temic Microelectronic Gmbh Steuerung oder Regelung eines automatischen oder automatisierten Getriebes
US7739968B2 (en) * 2006-07-25 2010-06-22 General Vortex Energy, Inc. System, apparatus and method for combustion of metals and other fuels
KR101730679B1 (ko) 2009-11-25 2017-04-26 이데미쓰 고산 가부시키가이샤 윤활유의 열화·변질도 측정 방법 및 그의 측정 장치
CN103954656A (zh) * 2009-11-25 2014-07-30 出光兴产株式会社 润滑油的劣化度测定装置、以及机械、装置的润滑油监视系统
KR101951399B1 (ko) * 2010-11-22 2019-02-22 더루우브리졸코오포레이션 유체 상태를 모니터하는 방법
JP6313908B2 (ja) 2014-09-03 2018-04-18 ゼブラ スキマーズ コーポレイションZebra Skimmers Corp. 液体供給方法および液体供給システム
JP6174545B2 (ja) * 2014-10-17 2017-08-02 ファナック株式会社 臭気センサを用いた切削液の状態監視装置
WO2016122667A1 (en) 2015-01-30 2016-08-04 Hewlett Packard Enterprise Development Lp Sensors for cooling system fluid attributes
ES2530691B1 (es) * 2015-02-02 2015-11-03 Zertan, S.A. Método de medida de la presencia de agua en filtros de gasóleo y sensor de agua para efectuar dicho método
JP6739223B2 (ja) * 2016-04-27 2020-08-12 Kyb株式会社 センサ
US11016075B2 (en) * 2017-07-20 2021-05-25 Saudi Arabian Oil Company Methods and systems for characterization of geochemical properties of hydrocarbons using microwaves
US11099168B2 (en) * 2018-07-23 2021-08-24 Schlumberger Technology Corporation Methods and apparatus for water detection in multiphase flows
US11555813B2 (en) * 2019-03-14 2023-01-17 Bvba Dierickx-Tools Apparatus and method for monitoring a condition of metalworking fluid of a metalworking fluid circuit of a metalworking machine
US11668668B2 (en) * 2020-10-05 2023-06-06 Pryor Knowledge Systems, Inc. Mechanism for the real-time prediction of incipient failure in working fluids
US20250180514A1 (en) * 2023-11-30 2025-06-05 Wisconsin Alumni Research Foundation Non-Invasive Multiparameter Sensor

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Also Published As

Publication number Publication date
AU2003284079A1 (en) 2004-05-04
KR101072208B1 (ko) 2011-10-10
KR20050056249A (ko) 2005-06-14
ATE408821T1 (de) 2008-10-15
US6861851B2 (en) 2005-03-01
AU2003284079B2 (en) 2008-11-20
EP1552292A1 (en) 2005-07-13
EP1552292B1 (en) 2008-09-17
CA2502283A1 (en) 2004-04-29
US20040075448A1 (en) 2004-04-22
DE60323656D1 (de) 2008-10-30
BR0315423A (pt) 2005-08-23
JP2006503289A (ja) 2006-01-26
JP4309350B2 (ja) 2009-08-05

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