WO2004035718A2 - Composition - Google Patents

Composition Download PDF

Info

Publication number
WO2004035718A2
WO2004035718A2 PCT/EP2003/011100 EP0311100W WO2004035718A2 WO 2004035718 A2 WO2004035718 A2 WO 2004035718A2 EP 0311100 W EP0311100 W EP 0311100W WO 2004035718 A2 WO2004035718 A2 WO 2004035718A2
Authority
WO
WIPO (PCT)
Prior art keywords
acid
composition according
concentrate
weight
oxidation
Prior art date
Application number
PCT/EP2003/011100
Other languages
German (de)
English (en)
Other versions
WO2004035718A3 (fr
Inventor
Ralf M. Kern
Sven Reichwagen
Original Assignee
Arconia Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arconia Gmbh filed Critical Arconia Gmbh
Priority to DE10393374T priority Critical patent/DE10393374D2/de
Priority to AU2003285288A priority patent/AU2003285288A1/en
Publication of WO2004035718A2 publication Critical patent/WO2004035718A2/fr
Publication of WO2004035718A3 publication Critical patent/WO2004035718A3/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
    • A61L2/186—Peroxide solutions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/722—Oxidation by peroxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/06—Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Definitions

  • the present invention relates to a cleaning agent concentrate for dissolving biofouling and to a composition comprising at least one organic acid and at least one peroxide.
  • DE 43 25 312 A1 disclose disinfectants in the form of an aqueous solution of a peroxide, food preservatives and non-toxic acids or their salts, in particular sodium benzoate and sorbic acid.
  • these agents are not very stable in storage and, depending on their composition, lose their effectiveness within 1 to 3 months.
  • the object of the present invention is therefore to provide a composition of the type mentioned above which has a satisfactory sterilizing effect and improved storage stability.
  • the solution consists in a concentrate with the features of claim 1 or in a composition with the features of claim 2.
  • the concentrate according to the invention contains from 0.1 to 4% by weight, preferably from 0.3 to 2.5%. -% of at least one substance from the group
  • composition according to the invention contains 0.001 to 40% by weight of at least one oxidation-stable, at least monounsaturated, substituted or unsubstituted organic acid, 0.001 to 40% by weight of at least one oxidation-stable, saturated, substituted or unsubstituted organic acid, up to 30% by weight.
  • % Hydrogen peroxide and / or at least one inorganic and / or organic peroxidic compound and contains up to 2% by weight of an oxidation-stable complexing agent.
  • composition according to the invention or the concentrate form a synergistic, multi-secured system of active ingredients that complement, add or reinforce their effect.
  • peroxidic compound is understood to mean all inorganic and organic compounds which contain a structural element of oxygen.
  • oxygen radicals causes the peroxidic compound to rapidly oxidize the outer shell of cells, the outer shell being torn open and destroyed, so that the cell interior emerges outside.
  • enzymes that are supposed to intercept the oxygen radicals are destroyed or inhibited so quickly that they cannot fully develop their effect.
  • Other proteins and nucleic acids are also attacked and damaged by the oxygen radicals.
  • the resulting blockage of the metabolic pathways energy metabolism; protein biosynthesis leads to cell death. This effect occurs very quickly.
  • the peroxidic compound intervenes suddenly and massively in the cell structure, whereby it is broken down itself. So it is a strong but short-term effect.
  • the organic acids ensure that the cell residues created in the process just described are broken down and thus prevent the formation of biofilms and bio-aggregates and the so-called biofouling.
  • Existing biofilms and bio-aggregates are dissolved and broken down.
  • they can form peracids for a short time under the influence of the peroxidic compound and thus supplement the effect of the peroxidic compound.
  • these effects can add, supplement or intensify. In contrast to the effect of the peroxidic compound, this effect is long-lasting since the organic acids are broken down only very slowly.
  • the complexing agent damages the germs to be combated by complexing Ca 2+ and Mg 2+ ions and thus removing them from the metabolism of the germs.
  • the complexing agent complexes heavy metal ions, which catalyze the decomposition of the peroxidic compound. This protects the peroxidic compound from decomposition and thus stabilizes it.
  • composition according to the invention significantly increases the storage stability of the composition according to the invention, namely from 2 to 3 months to 1 to more than 2 years.
  • the composition according to the invention is thus the first ever to be a marketable product which can be used without special precautions and preservation measures.
  • composition of the invention is also non-toxic and biodegradable. It is brought into direct contact with the substrate to be treated. An effect occurs almost immediately and a complete cleaning effect can occur after just 10 to 20 minutes of exposure.
  • the at least one oxidation-stable, at least monounsaturated organic acid is selected from the group comprising fruit acids, sorbic acid, maleic acid, fumaric acid and their salts.
  • the at least one oxidation-stable saturated organic acid is preferably selected from the group comprising fruit acids, glycolic acid, lactic acid, succinic acid, oxalic acid, malonic acid, glutaric acid, adipic acid, pimelic acid, benzoic acid, p-hydroxybenzoic acid, straight-chain or branched alkanoic acids with 1 to 12 carbon atoms, and their salts.
  • the skillful combination of acids means that their effects are mutually reinforcing, supplementing or adding.
  • Many organic acids for example benzoic acid and sorbic acid, are metabolic poisons for many germs, so that they enhance the effect of the peroxidic compound on killing germs. Furthermore, they facilitate the membrane transfer of the peroxidic compound, damage the outer skin of the germs to be controlled and help stabilize the peroxidic compound.
  • Suitable peroxidic compounds include hydroperoxides, peroxides, e.g. urea peroxide, diacyl peroxides, peracids, peracid esters and epidioxides.
  • Suitable inorganic peroxidic compounds are, for example, peroxomonosulfates, peroxodisulfates, peroxomonophosphates,
  • Peroxodiphosphate Peroxomonocarbonate and Peroxodicarbonate.
  • the choice depends on the formulation and the intended use of the composition according to the invention in individual cases.
  • hydrogen peroxide in liquid formulations and urea peroxide in solid formulations are particularly suitable.
  • ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), phosphoric acid, (poly) phosphoric acids, oxalic acid, acetoacetic acid and its salts and succinic acid derivatives can be used as complexing agents.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • phosphoric acid phosphoric acid
  • poly phosphoric acids oxalic acid
  • acetoacetic acid and its salts and succinic acid derivatives can be used as complexing agents.
  • These complexing agents complex metal ions particularly effectively, so that not only is the peroxidic compound stabilized in
  • the composition according to the invention can contain numerous additives and auxiliaries.
  • additives and auxiliaries include, for example, one or more oxidation-resistant degreasing agents which are selected from the group comprising soaps, anionic and nonionic surfactants, alkylbenzenesulfates, alkylbenzenesulfonates, fatty acid esters, sulfated fatty acid glycerides, betaines, sulfobetaines and.
  • Saponins preferably sodium dodecyl sulfate, sodium dodecyl sulfonate and sodium lauryl sulfate.
  • oxidation-resistant permeation agents such as DMSO, straight-chain or branched, mono- or polyhydric alcohols with 1 to 12 carbon atoms and polyethylene glycols. It can also contain other auxiliaries such as defoamers, anti-corrosion agents, adhesives, wetting agents, fragrances and / or dyes.
  • insects are also directly affected by damage to their quinine shell.
  • the composition according to the invention can be formulated as a solution, as a solid or as a gel.
  • it can contain up to 99% by weight of at least one solvent such as water or one at room temperature contain liquid, branched or unbranched, mono- or polyhydric alkanol.
  • ethanol or isopropanol are suitable.
  • the water is preferably demineralized.
  • Alcohols such as ethanol or isopropanol also have the advantage that they also have a bactericidal and fungicidal effect, which also increases the germicidal action of the composition according to the invention.
  • the composition according to the invention is preferably weakly acidic to neutral, for example with a pH of 3.0 to 6.8.
  • a gel is used to formulate the gel
  • composition at least one gelling agent added, preferably Aerosil, alginate, agarose or at least one acrylate.
  • the resulting gel can then be applied to the surface to be treated.
  • a preferred formulation is, for example:
  • composition according to the invention also acts as a pharmaceutical in humans and animals, for example for the treatment of bacterial and viral infectious diseases, allergens, mycoses, pediculoses and other parasite infestation. It also acts as a bactericide, fungicide, insecticide and / or pesticide, preferably in agriculture, horticulture, as a tonic and / or care products for the treatment of plants and animals, as cleaning agents in the household and industry, as agents for air and water disinfection as well as for swimming pool and whirlpool disinfection and as surface disinfectants.
  • the composition contains: 50 g H 2 0 2 1 g sorbic acid 2.5 g benzoic acid 1 g EDTA 1 g H 3 P0 4 1 IH 2 0 (demin.)
  • the water is initially introduced, then the EDTA is dissolved, then the acids are added and finally the hydrogen peroxide is added.
  • aqueous 30% hydrogen peroxide solution was used to prepare the aqueous solution.
  • hydrogen peroxide urea peroxide or persulfate (as in Virkon) can also be used.
  • a powder mixture is produced which contains an equivalent to 50 g of hydrogen peroxide of the peroxide used.
  • Components, as well as the auxiliaries, if any, are supplied as a powdery mixture, as granules or in tablet form.
  • H 2 0 2 0.01% sorbic acid, 0.025% benzoic acid, 0.001% EDTA, 0.1% H 3 P0 4 , in demineralized water.
  • Spray preferably in a composition of 0.5% H 2 O 2 , 0.01% sorbic acid, 0.025% benzoic acid, 0.001% EDTA, 0.1% H 3 P0 4 , in demineralized water.
  • benzoic acid 0.025% benzoic acid, 0.001% EDTA, 0.1% H 3 PO 4 , 0.5% SDS in demineralized water.
  • composition according to the invention also has a deodorant effect by killing odor-forming germs.
  • a composition of 3.5% H 2 0 2 , 0.1% sorbic acid, 0.25% is effective, for example.
  • Algae are used. It works in the care of fur and feathers against mites and skin fungi and in the cleaning and disinfection of small wounds.
  • the composition according to the invention has a deodorizing effect by killing odor-forming germs.
  • a composition of 0.5% H 2 O 2 , 0.01% sorbic acid, for example, is effective.
  • Benzoic acid 0.1% EDTA, 0.1% H 3 PO 4 , 0.05% DMSO, 0.5% SDS in demineralized water.
  • Composition is atomized in the beehive.
  • the composition according to the invention can be used, for example, for the external treatment of fruits, but also for the disinfection of water and for the disinfection of processing machines. This is particularly unproblematic because the composition according to the invention is non-toxic and biodegradable.
  • a composition of 0.3% H 2 O 2 , 0.05% sorbic acid, 0.1% benzoic acid, 0.01% EDTA, 0.1% H 3 P0 4 in demineralized water is suitable, for example.
  • Hygienic processing of food is made possible by keeping production plants free of microorganisms and biofilm material.
  • composition according to the invention can also be contained in or mixed with the ice in a concentration suitable for the development of the effects described, so that its cleaning action occurs in the course of melting and, for example, biofilm formation from the ice-filled cold rooms on a fish trawler to serving in the Fish restaurant remains excluded and the original freshness of the fish remains guaranteed.
  • the composition according to the invention is also for leather care, for cleaning and disinfecting surfaces, pipes and hoses, in particular also for medical devices and apparatus, for cleaning and disinfecting water tanks, air conditioning systems, sanitary facilities, cooling and hot water systems, drinking water systems and waste water systems Air and water disinfection, suitable as surface disinfectant, for drinking water treatment and for swimming pool and whirlpool disinfection.
  • a composition of 5% H 2 O 2 , 0.1% sorbic acid, 0.25% benzoic acid, 0.1% EDTA, 0.1% H 3 PO in demineralized water is suitable for this.
  • a composition of 3% H 2 0 2 , 0.1% sorbic acid, 0.25% benzoic acid, 0.1% EDTA, 0.1% H 3 PO 4 can be used in demineralized water.
  • a specific example of the mode of action of the composition according to the invention is the cleaning of old, moldy leather harnesses for horses, for example riding horses. After spraying with the composition specified above and an exposure time of 10 to 15 minutes, not only can the mildew covering be easily wiped off, but the old, hard leather also becomes supple and soft again and remains permanently supple after oil treatment. Through long years of contamination, a solid biofouling structure had formed in the pores of the leather, which had hardened the leather considerably. The treatment by the composition according to the invention frees the pores from the biofilm material and makes them supple again, so that the agent could penetrate the pores. Leather shoes can also be treated in the same way.
  • Another example is clean room air treatment. By adding to the air, the microorganisms are killed directly.
  • the biofilm material that surrounds agglomerations of microorganisms and ensures cohesion in the air is dissolved and any agglomeration of microorganisms that make up about 1/10 of the residual dust falls apart.
  • the microorganisms also perish here.
  • Indoor air can be enriched with the composition according to the invention.
  • This ensures that the air is enriched with a fine mist of aerosol particles of ⁇ 3 ⁇ if possible, so that the composition is distributed throughout the room and unfolds its effect.
  • the aerosol particles get into the ventilated rooms and in them on all furnishings and materials (e.g. fabrics, clothing, food supplies etc.).
  • the air supply devices for example air conditioning systems, are cleaned of any biofilm deposits, so that no more microorganisms are spread, but also the biofilm clusters of microorganisms within the ventilated room are removed.
  • Such air cleaning can also be used for transport containers of all kinds (in addition to wiping the surfaces themselves), so that the transported goods (for example fruit) are kept clean and preserved.
  • air and water filters work noticeably more effectively if they are kept free of biofilm material.
  • the composition according to the invention is, inter alia, against SARS coronavirus, Bacillus anthracis, Escherichia coli, Klebsiella pneumoniae, Staphylococcus aureus, Pseudomonas aeruginosa, Streptococcus faecalis, Proteus mirabilis, Mycobacterium tuberculosis, Clostridium sporogens, Candida albicans, dust mites, varroa mites and many other pathogens and parasites are effective.
  • SARS coronavirus Bacillus anthracis, Escherichia coli, Klebsiella pneumoniae, Staphylococcus aureus, Pseudomonas aeruginosa, Streptococcus faecalis, Proteus mirabilis, Mycobacterium tuberculosis, Clostridium sporogens, Candida albicans, dust mites, varroa
  • inhaled or applied to infested areas for example in a composition of 3% H 2 O 2 , 0.1% sorbic acid, 0.25% benzoic acid, 0.1% EDTA, 0.1% H 3 P0 4 , in demineralized water (preferably for inhalation) or in a composition of 1.5% H 2 O 2 , 0.1% sorbic acid, 0.15% benzoic acid, 0.1% EDTA, 0.1% H 3 PO 4 , 0.05% DMSO in demineralized water (preferably for application).
  • any germs such as bacteria, viruses, fungi, protozoa etc. are deprived of the possibility of spreading.
  • germs or biofilms for multicellular animals such as mites, mosquitoes, flies, worms, but also
  • mice and rats are not necessary for existence, it has been observed that the environment cleaned with the composition according to the invention is at least avoided by these animals, so that, for example, the number of flies and mosquitoes is at least reduced in animal stalls.
  • composition according to the invention thus represents an effective biological disinfectant and disinfectant as well as pesticide. Since biofilm or biofouling can occur in all areas in which an infestation of microorganisms is possible, the composition according to the invention is economical everywhere and in particular in a biologically relevant temperature range can be used up to approx. 70 ° C.
  • composition according to the invention is user-friendly and environmentally friendly, non-toxic and completely biodegradable. It shows a very large one Range of effects and enables safe and effective infection control for a variety of applications, e.g.
  • Agriculture, horticulture and forestry plant strengthening / plant protection through plant and tree treatment, e.g. mildew, aphids, mites, bacteria, post harvest treatment
  • Germicidal drugs e.g. wound disinfectants, inhalation drugs (SARS, TBC, influenza etc.), athlete's foot and nail fungus, warts.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

L'invention concerne une composition contenant: 0,1 à 40 % en poids d'au moins un acide organique, substitué ou non substitué, au moins mono-insaturé, stable à l'oxydation ; 0,1 à 40 % en poids d'au moins un acide organique, substitué ou non substitué, saturé, stable à l'oxydation ; jusqu'à 30 % en poids de peroxyde d'hydrogène et/ou d'au moins un composé peroxydique inorganique et/ou organique ; jusqu'à 2 % en poids d'un agent complexant stable à l'oxydation. La composition selon l'invention constitue un médicament, un agent désinfectant, un agent germicide, efficace et polyvalent, qui se distingue par une grande stabilité au stockage.
PCT/EP2003/011100 2002-10-14 2003-10-08 Composition WO2004035718A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE10393374T DE10393374D2 (de) 2002-10-14 2003-10-08 Zusammensetzung
AU2003285288A AU2003285288A1 (en) 2002-10-14 2003-10-08 Composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10247872.4 2002-10-14
DE10247872 2002-10-14

Publications (2)

Publication Number Publication Date
WO2004035718A2 true WO2004035718A2 (fr) 2004-04-29
WO2004035718A3 WO2004035718A3 (fr) 2004-08-26

Family

ID=32102755

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/011100 WO2004035718A2 (fr) 2002-10-14 2003-10-08 Composition

Country Status (4)

Country Link
CN (1) CN100384971C (fr)
AU (1) AU2003285288A1 (fr)
DE (1) DE10393374D2 (fr)
WO (1) WO2004035718A2 (fr)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004045281A3 (fr) * 2002-11-15 2004-09-30 Virox Technologies Inc Desinfectant a base de peroxyde d'hydrogene contenant un acide carboxylique cyclique et/ou un alcool aromatique
WO2006135620A1 (fr) * 2005-06-10 2006-12-21 S. C. Johnson & Son, Inc. Desodorisant a base de peroxyde d'hydrogene en phase vapeur
WO2007014606A2 (fr) * 2005-08-02 2007-02-08 Thomas Besendorfer Composition a effet bactericide, fongicide, virocide et insecticide et composition a action repulsive
WO2007068938A2 (fr) * 2005-12-14 2007-06-21 Bristol-Myers Squibb Company Préparation antimicrobienne
WO2008137632A1 (fr) * 2007-05-04 2008-11-13 The Procter & Gamble Company Compositions antimicrobiennes, produits et procédés d'utilisation
EP2022332A1 (fr) * 2007-08-02 2009-02-11 Wesso Ag Produit de désinfection aqueux destiné à réduire le nombre de germes dans l'air
EP2182811A1 (fr) * 2007-08-15 2010-05-12 Virox Technologies Inc. Compostions antimicrobiennes
AU2008201748B2 (en) * 2007-12-03 2011-06-02 Kemira Oyj Composition and method for treating wood
US8298482B2 (en) 2005-06-10 2012-10-30 S.C. Johnson & Son, Inc. Vapor phase hydrogen peroxide deodorizer
WO2013096814A1 (fr) * 2011-12-22 2013-06-27 Bui Huyen Phuong Solution de concentré d'acide peracétique stable non corrosive
US8637085B2 (en) 2002-02-12 2014-01-28 Virox Technologies Inc. Enhanced activity hydrogen peroxide disinfectant
US8808755B2 (en) 2004-05-14 2014-08-19 Virox Technologies Inc. Hydrogen peroxide-based skin disinfectant
AU2013206810B2 (en) * 2005-12-14 2016-04-21 Convatec Technologies Inc. Antimicrobial composition
US10450535B2 (en) 2017-10-18 2019-10-22 Virox Technologies Inc. Shelf-stable hydrogen peroxide antimicrobial compositions
US10651491B2 (en) 2015-08-24 2020-05-12 Kemira Oyj Method for reducing fouling of a microbial fuel cell, cleaning agent composition and its use
US11135315B2 (en) 2010-11-30 2021-10-05 Convatec Technologies Inc. Composition for detecting biofilms on viable tissues
US11286601B2 (en) 2012-12-20 2022-03-29 Convatec Technologies, Inc. Processing of chemically modified cellulosic fibres
EP3967144A4 (fr) * 2019-05-10 2023-01-25 Kao Corporation Composition de retrait de biofilm pour système aquatique
DE102021129678A1 (de) 2021-11-15 2023-05-17 Knieler & Team Gmbh Gebrauchsfertige Wässrige Desinfektionsmittelzusammensetzung
EP3967664A4 (fr) * 2019-05-10 2023-05-31 Kao Corporation Procédé de retrait de biofilm

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080305182A1 (en) 2002-11-15 2008-12-11 Ramirez Jose A Hydrogen peroxide disinfectant containing a cyclic carboxylic acid and/or aromatic alcohol
CN102002451B (zh) * 2010-12-14 2013-12-18 天津市华阳新兴科技有限公司 空调专用除垢灭菌清洗剂及其制备方法
CN102273488B (zh) * 2011-06-22 2012-08-22 李翰实 新生态氧高速特效杀菌消毒剂
CN103081945B (zh) * 2013-02-01 2015-10-07 中山大学 一种除霉防霉剂及相应的除霉防霉方法
EP2999777B1 (fr) 2013-05-23 2018-01-31 Nature Seal Inc. Lavage antimicrobien
CN104031771A (zh) * 2014-06-17 2014-09-10 滁州斯迈特复合材料有限公司 胃镜清洁剂
CN104031779A (zh) * 2014-06-17 2014-09-10 滁州斯迈特复合材料有限公司 直肠镜洗涤剂
CN104782671A (zh) * 2015-03-25 2015-07-22 彭新国 检验科用的抑菌消毒的消毒液及其制备方法
CN106689198A (zh) * 2017-01-03 2017-05-24 中国人民解放军北京军区疾病预防控制中心 一种复方过氧化氢消毒剂及其制备方法和应用
CN107281173A (zh) * 2017-07-24 2017-10-24 宁夏智弘生物科技有限公司 一种兽用有机酸药浴液及其制备方法
CN112593223A (zh) * 2020-12-17 2021-04-02 南京南炼宏泰技术开发有限公司 一种复合型钝化除臭清洗剂及其制备方法

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477438A (en) * 1982-11-12 1984-10-16 Surgikos, Inc. Hydrogen peroxide composition
DE4325312A1 (de) * 1993-05-17 1994-11-24 Heimo Wessollek Mittel zur Stabilisierung von Wasser, das mit menschlicher oder tierischer Haut in Kontakt kommt
US5731275A (en) * 1994-04-05 1998-03-24 Universite De Montreal Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces
WO2000027438A1 (fr) * 1998-11-06 2000-05-18 Universite De Montreal Solutions bactericides et non bactericides servant a eliminer des films biologiques
DE29904319U1 (de) * 1999-03-09 2000-08-17 Wessollek Heimo Mund- und Zahnpflegemittel, insbesondere Zahncreme
DE19910356A1 (de) * 1999-02-18 2000-08-24 Wessollek Heimo Mittel, Verfahren, Vorrichtung sowie Verwendungen zum biologischen Entkeimen von Luft und Räumen mit Luft
DE19915028A1 (de) * 1999-04-01 2000-10-05 Wessollek Heimo Mittel und Verfahren zur Erzeugung keimfreier Geflügeleier
EP1057407A1 (fr) * 1999-06-02 2000-12-06 Arconia GmbH Agent de désinfection pour des articles susceptibles d'être contaminés
US6284144B1 (en) * 1998-07-30 2001-09-04 Argad-Eyal Water Treatment Industries Inc. Water treatment
WO2002064718A1 (fr) * 2001-02-14 2002-08-22 Henning Möller Detergent permettant d'eliminer le bio-encrassement

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477438A (en) * 1982-11-12 1984-10-16 Surgikos, Inc. Hydrogen peroxide composition
DE4325312A1 (de) * 1993-05-17 1994-11-24 Heimo Wessollek Mittel zur Stabilisierung von Wasser, das mit menschlicher oder tierischer Haut in Kontakt kommt
US5731275A (en) * 1994-04-05 1998-03-24 Universite De Montreal Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces
US6284144B1 (en) * 1998-07-30 2001-09-04 Argad-Eyal Water Treatment Industries Inc. Water treatment
WO2000027438A1 (fr) * 1998-11-06 2000-05-18 Universite De Montreal Solutions bactericides et non bactericides servant a eliminer des films biologiques
DE19910356A1 (de) * 1999-02-18 2000-08-24 Wessollek Heimo Mittel, Verfahren, Vorrichtung sowie Verwendungen zum biologischen Entkeimen von Luft und Räumen mit Luft
DE29904319U1 (de) * 1999-03-09 2000-08-17 Wessollek Heimo Mund- und Zahnpflegemittel, insbesondere Zahncreme
DE19915028A1 (de) * 1999-04-01 2000-10-05 Wessollek Heimo Mittel und Verfahren zur Erzeugung keimfreier Geflügeleier
EP1057407A1 (fr) * 1999-06-02 2000-12-06 Arconia GmbH Agent de désinfection pour des articles susceptibles d'être contaminés
WO2002064718A1 (fr) * 2001-02-14 2002-08-22 Henning Möller Detergent permettant d'eliminer le bio-encrassement

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1473998B1 (fr) * 2002-02-12 2016-12-07 Virox Technologies Inc. Desinfectant au peroxyde d'hydrogene a activite amelioree
US8999400B2 (en) 2002-02-12 2015-04-07 Virox Technologies Inc. Enhanced activity hydrogen peroxide disinfectant
US8637085B2 (en) 2002-02-12 2014-01-28 Virox Technologies Inc. Enhanced activity hydrogen peroxide disinfectant
WO2004045281A3 (fr) * 2002-11-15 2004-09-30 Virox Technologies Inc Desinfectant a base de peroxyde d'hydrogene contenant un acide carboxylique cyclique et/ou un alcool aromatique
US9198935B2 (en) 2004-05-14 2015-12-01 Virox Technologies Inc. Hydrogen peroxide-based skin disinfectant
US8808755B2 (en) 2004-05-14 2014-08-19 Virox Technologies Inc. Hydrogen peroxide-based skin disinfectant
US8298482B2 (en) 2005-06-10 2012-10-30 S.C. Johnson & Son, Inc. Vapor phase hydrogen peroxide deodorizer
WO2006135620A1 (fr) * 2005-06-10 2006-12-21 S. C. Johnson & Son, Inc. Desodorisant a base de peroxyde d'hydrogene en phase vapeur
AU2006258117B2 (en) * 2005-06-10 2010-08-26 S. C. Johnson & Son, Inc. Vapor phase hydrogen peroxide deodorizer
WO2007014606A2 (fr) * 2005-08-02 2007-02-08 Thomas Besendorfer Composition a effet bactericide, fongicide, virocide et insecticide et composition a action repulsive
WO2007014575A1 (fr) * 2005-08-02 2007-02-08 Thomas Besendorfer Composition a effet bactericide, fongicide, virocide et insecticide
WO2007014606A3 (fr) * 2005-08-02 2007-08-23 Thomas Besendorfer Composition a effet bactericide, fongicide, virocide et insecticide et composition a action repulsive
US10493101B2 (en) 2005-12-14 2019-12-03 Convatec Technologies Inc. Antimicrobial composition
US9149035B2 (en) 2005-12-14 2015-10-06 Convatec Technologies, Inc. Antimicrobial composition
WO2007068938A2 (fr) * 2005-12-14 2007-06-21 Bristol-Myers Squibb Company Préparation antimicrobienne
US9545390B2 (en) 2005-12-14 2017-01-17 Convatec Technologies Inc. Antimicrobial composition
JP2013209385A (ja) * 2005-12-14 2013-10-10 Convatec Technologies Inc 抗菌組成物
WO2007068938A3 (fr) * 2005-12-14 2008-09-18 Bristol Myers Squibb Co Préparation antimicrobienne
AU2013206810B2 (en) * 2005-12-14 2016-04-21 Convatec Technologies Inc. Antimicrobial composition
WO2008137632A1 (fr) * 2007-05-04 2008-11-13 The Procter & Gamble Company Compositions antimicrobiennes, produits et procédés d'utilisation
EP2022332A1 (fr) * 2007-08-02 2009-02-11 Wesso Ag Produit de désinfection aqueux destiné à réduire le nombre de germes dans l'air
EP2182811A1 (fr) * 2007-08-15 2010-05-12 Virox Technologies Inc. Compostions antimicrobiennes
EP2182811A4 (fr) * 2007-08-15 2012-11-28 Virox Technologies Inc Compostions antimicrobiennes
US8865196B2 (en) 2007-08-15 2014-10-21 Virox Technologies Inc. Antimicrobial compositions
AU2008201748B2 (en) * 2007-12-03 2011-06-02 Kemira Oyj Composition and method for treating wood
US8399106B2 (en) 2007-12-03 2013-03-19 Kemira Oyj Composition and method for treating wood
US11135315B2 (en) 2010-11-30 2021-10-05 Convatec Technologies Inc. Composition for detecting biofilms on viable tissues
WO2013096814A1 (fr) * 2011-12-22 2013-06-27 Bui Huyen Phuong Solution de concentré d'acide peracétique stable non corrosive
US11286601B2 (en) 2012-12-20 2022-03-29 Convatec Technologies, Inc. Processing of chemically modified cellulosic fibres
US10651491B2 (en) 2015-08-24 2020-05-12 Kemira Oyj Method for reducing fouling of a microbial fuel cell, cleaning agent composition and its use
US10968417B2 (en) 2017-10-18 2021-04-06 Diversey, Inc. Shelf-stable hydrogen peroxide antimicrobial compositions
US10450535B2 (en) 2017-10-18 2019-10-22 Virox Technologies Inc. Shelf-stable hydrogen peroxide antimicrobial compositions
EP3967144A4 (fr) * 2019-05-10 2023-01-25 Kao Corporation Composition de retrait de biofilm pour système aquatique
EP3967664A4 (fr) * 2019-05-10 2023-05-31 Kao Corporation Procédé de retrait de biofilm
DE102021129678A1 (de) 2021-11-15 2023-05-17 Knieler & Team Gmbh Gebrauchsfertige Wässrige Desinfektionsmittelzusammensetzung
EP4179873A1 (fr) 2021-11-15 2023-05-17 Knieler & Team GmbH Composition désinfectante aqueuse, lingettes ou serpillières imprégnée avec la composition désinfectante, procédé de désinfection de surfaces dures et utilisation

Also Published As

Publication number Publication date
WO2004035718A3 (fr) 2004-08-26
DE10393374D2 (de) 2005-09-01
CN100384971C (zh) 2008-04-30
CN1705735A (zh) 2005-12-07
AU2003285288A1 (en) 2004-05-04

Similar Documents

Publication Publication Date Title
WO2004035718A2 (fr) Composition
EP1901606B1 (fr) Produits de desinfection et de sterilisation
US20100003341A1 (en) Composition with a bactericidal, fungicidal, viricidal and insecticidal action and composition acting as a repellent
US8062676B2 (en) Pesticide composition
DE3229097A1 (de) Mikrobizide mittel
US9288980B2 (en) Low environmental impact pesticide made from “GRAS” ingredients for use against Coqui frogs and other species
EP1125497B1 (fr) Produit pour la désinfection virucide des mains
DE202012006847U1 (de) Alkohol enthaltende Zusammensetzung
JP2023516778A (ja) 作物の管理と保護のための駆除剤組成物
US9161534B2 (en) Methods for cleaning a surface
JP2008519072A (ja) 除草剤、農薬、殺虫剤、殺卵剤、および殺真菌剤と共に使用するためのアジュバント組成物ならびに適用方法。
US20040253287A1 (en) Environmentally safe insecticides
US20050020678A1 (en) Environmentally safe fungicides
US20020114730A1 (en) Lemon extract and treatment methods
KR102050708B1 (ko) 소독 및 살비용 조성물, 및 이를 이용한 닭 진드기 방제 방법
WO2004000372A2 (fr) Composition desinfectante, comprimes de nettoyage produits a partir de cette composition et leur utilisation
CN105251030A (zh) 一种用于宠物生活环境的可食用的祛味消毒剂及其制备方法
DE202015001904U1 (de) Alkohol enthaltende Zusammensetzung mit Langzeiteffekt
DE19915028A1 (de) Mittel und Verfahren zur Erzeugung keimfreier Geflügeleier
EP1057407A1 (fr) Agent de désinfection pour des articles susceptibles d'être contaminés
DE60032705T2 (de) Potenziertes und stabilisiertes Desinfektionsmittel mit bakterizider und viruzider Wirkung
EP1036511A2 (fr) Procédé pour conserver et composition à cet effet
KR101535215B1 (ko) 소독 및 해충 퇴치용 연막 조성물
US20160044917A1 (en) Low environmental impact pesticide made from "gras" ingredients for use against coqui frogs and other species
DE112006003055B4 (de) Verwendung eines Mittels zur Bekämpfung von schädlichen Arthropoden

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 20038A13719

Country of ref document: CN

REF Corresponds to

Ref document number: 10393374

Country of ref document: DE

Date of ref document: 20050901

Kind code of ref document: P

WWE Wipo information: entry into national phase

Ref document number: 10393374

Country of ref document: DE

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Ref document number: JP