WO2004030456A1

WO2004030456A1 - Composition for controlling house pest and method of controlling

Info

Publication number: WO2004030456A1
Application number: PCT/JP2003/012730
Authority: WO
Inventors: Osamu Imai
Original assignee: Ishihara Sangyo Kaisha, Ltd.
Priority date: 2002-10-07
Filing date: 2003-10-03
Publication date: 2004-04-15
Also published as: AU2003271092A1

Abstract

A method of controlling house pests, characterized by treating house pests with a house pest control composition containing as an active ingredient a sulfosuccinic acid dialkyl ester, a salt thereof, or the like or with the active ingredient. Also provided is a composition for controlling house pests which contains as an active ingredient a sulfosuccinic acid dialkyl ester, a salt thereof, or the like.

Description

Specification

House pest control composition and control method

"Technical field"

The present invention relates to a composition for controlling house pests containing a dialkyl sulfosuccinate or a salt thereof as an active ingredient, or a method for controlling house pests by treating the active ingredient into house pests. In addition, the present invention particularly relates to a method for controlling termites and ants.

"Background technology"

Dialkyl sulfosuccinates are compounds known as surfactants and are used as pesticide emulsifiers, wetting agents, penetrants and the like. However, it is not known that dialkyl sulfosuccinates have a termite control action. Urea or uric acid is also a known compound. However, it is not known that urea or uric acid has a control activity on white stalks.

The compound of the formula (I) described below is a compound described in US Pat. No. 5,360,860, US Pat. No. 6,239,160, US Pat. No. 6,566,518, and the like. The compound of the formula (II) described later is a compound described in US Pat. No. 5,288,727. However, a composition for controlling insect pests in a house combining these compounds with a dialkyl sulfosuccinate is not known.

Conventionally known methods for controlling termites include methods using organic phosphorus compounds such as chlorpyrifos and pyrethroid compounds. Examples of the method for controlling gall include methods using hydramethylnon, lithium sulfonate, organic phosphorus compounds, carbamate compounds, pyrethroid compounds and the like. Examples of the cockroach control method include a method using hydramethylnon, a pyrethroid compound, an organic phosphorus compound, and the like. However, some of these methods have concerns about toxicity to mammals and their impact on the environment, and there is a need for new methods for controlling house pests using more safe active ingredients. In addition, even if a termite control agent useful as a bait agent is applied to house wood such as pillars and bases, the termites will not There is a problem of feeding house wood together with pesticides, and there is a need for a method to minimize termite damage.

"Disclosure of the invention"

The present inventors have conducted intensive searches for a method for controlling house pests, and as a result, have found that dialkylsulfosuccinic acid or its derivatives have termite-killing, feeding-inhibiting and repellent activities against termites. It has been found that urea also has termiticidal activity, and furthermore, that when the dialkyl sulfosuccinic acid or a salt thereof is mixed with a specific insecticidal compound having termite activity, the active ingredient exerts a synergistic effect. completed. That is, the present invention relates to a composition for controlling house pests containing a dialkyl sulfosuccinate or a salt thereof as an active ingredient or a method for controlling house pests in which an effective amount of the component is applied to house pests.

Also, the present invention provides (a) a dialkyl sulfosuccinate or a salt thereof, and (c) a (c-11) formula (I):

[Wherein, Y is a haloalkyl group, m is 0 or 1, and Q is

(X is an oxygen atom or a sulfur atom, and R ¹ and R ² are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, Alkyl group, -W ¹ )! ^ Group, -OR ⁴ group S (0> _n R ⁵ groups, One NH R ⁶ group,

, — C (R ⁸ ) NO— is a R ⁹ group or an optionally substituted aryl group, or R ¹ and R ² are taken together as = C (R ¹¹ )! ^ ¹ group, or A 5- or 6-membered heterocyclic group having 4 to 5 carbon atoms which may contain a nitrogen atom or an oxygen atom may be formed together with an adjacent nitrogen atom, and R ³ is an alkyl group which may be substituted, An optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted cycloalkyl group, an optionally substituted aryl group, an alkoxy group, an alkylthio group or a mono- or dialkylamino group, ⁴ is a hydrogen atom, an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, a cycloalkyl group which may be substituted, an aryl group which may be substituted, A heterocyclic group or a COR ³ group, R ⁵ is an alkyl group or a dialkylamino group; R ⁶ is an alkyl group or an aryl group; Z is an N or C—R ⁷ group; R ⁷ is a hydrogen atom, a halogen atom, R ⁸ and R ⁹ are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, or an optionally substituted alkyl group, an alkoxy group, an alkylthio group or a nitro group. An alkynyl group, an optionally substituted aryl group or an optionally substituted heterocyclic group, wherein R ^{1 fl} and R ¹¹ are each independently a hydrogen atom or an optionally substituted alkyl; Group, an optionally substituted alkenyl group, an optionally substituted heterocyclic group, one N- (R ⁿ ) R ¹³ group, an optionally substituted alkoxy group, an optionally substituted alkylthio group, R ¹² and R ¹³ are each independently a hydrogen atom, An alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted or a heterocyclic group which may be substituted; W ¹ represents an oxygen atom or a sulfur atom; And n is 1 or 2) or a heterocyclic group which may be substituted.] Or a salt thereof, and / or (c-12) a formula (II):

[Wherein, R ¹ ′, R ² ′ and R ⁴ ′ each independently represent a hydrogen atom, a halogen atom, an alkyl group optionally substituted with a halogen atom or an alkoxy group optionally substituted with a halogen atom. R ³ ′ is a halogen atom, an alkyl group optionally substituted with a halogen atom or an alkoxy group optionally substituted with a halogen atom, R ⁵ ′ is a hydrogen atom or an alkyl group, and R ⁶ ′ is X ⁷ 'CO- group, or X ^s' O CO- or a group, or R ^5' and R ⁶ ', such that together connexion, may form = CR ^7' R ⁸ 'group, X ^7' is hydrogen X ⁸ ′ is an alkyl group, R ⁷ ′ is a hydrogen atom or an alkyl group, and R ⁸ ′ is an amino group or an alkoxy group which may be substituted by an alkyl group. A composition for controlling house pests comprising the hydrazone compound represented by the formula (1) or a salt thereof as an active ingredient, or the composition. The present invention relates to a control method using the composition of the invention.

"Best mode for carrying out the invention"

Examples of the dialkyl sulfosuccinate include dibutyl sulfosuccinic acid, dibutyl sulfosuccinic acid, dihexyl sulfosuccinic acid, and dioctyl sulfosuccinic acid. Of these, dioctyl sulfosuccinic acid is preferred. Salts of dialkyl sulfosuccinates include sodium salt, potassium salt, calcium salt and the like. Among them, a sodium salt is desirable. The dialkyl sulfosuccinate or a salt thereof is commercially available as it is or as a liquid dissolved in a solvent. Commercially available products include, for example, trade name Perzol KMN-1 (manufactured by Miyoshi Oil & Fats Co., Ltd.), trade name Perzol KMN-3 (manufactured by Miyoshi Oil & Fats Co., Ltd.), and trade name Newkargen EP- 70G (manufactured by Takemoto Yushi Co., Ltd.), trade name Perex @ T-I-P (produced by Kao Corporation), trade name Perex TR (produced by Kao Corporation), trade name Perex CS (produced by Kao Corporation), Trade name Belex ΤΑ (manufactured by Kao Corporation), trade name Repar 870 Ρ (manufactured by Lion Corporation), trade name Newcol 290—Μ ( Nippon Emulsifier Co., Ltd.), brand name Newcol 290-K (manufactured by Nippon Emulsifier Co., Ltd.), and brand name EICOUL 291-M (manufactured by Nippon Emulsifier Co., Ltd.). it can.

Dialkyl sulfosuccinates or salts thereof have insecticidal activity, feeding inhibitory activity and repellent activity against house pests, and urea or uric acid has insecticidal activity against house pests. It is useful as an active ingredient of the composition for controlling pests.

An alkyl group which may be substituted in the formula (I); an alkenyl group which may be substituted; an alkynyl group which may be substituted and a cycloalkyl group which may be substituted; Alkylthio group; trialkylsilyl group; phenyl group; phenyl group substituted by halogen, alkyl, alkoxy, nitro or haloalkyl; phenyl group substituted by phenoxy optionally substituted by alkoxy or alkylthio; phenoxy group; two Lucio group; amino group; a morpholino group substituted with an alkyl; mol Horino group; cyclic amino group C ₂ _ _6; where alkyl is 1 pc or 2 pcs substituted amino group 1-piperazinyl group; alkyl, phenyl, 1-piperazinyl group substituted by pyridyl or trifluoromethylpyridyl Heterocyclic group which may be substituted by halogen, alkyl, alkoxy, octaalkoxy, alkylthio, phenyl, phenoxy, phenylthio, cycloalkyl or cycloalkoxy; hydroxy group; cyano group; cycloalkyl group; imino group _ C (W ² ) R ¹⁴ groups (W ² is an oxygen atom or a sulfur atom, R ¹⁴ is a hydrogen atom, an amino group, an amino group substituted with one or two alkyl groups, an alkyl group, an alkoxy group Group, an alkylthio group or an aryl group), or 〇C (W ² ) R ¹⁵ group (R ¹⁵ is an aryl group substituted with an alkyl group or a haloalkyl group) or an alkylsulfonyl group. When the above substituent is an imino group, it may form an amidino group or an imidate group together with an amino group or an alkoxy group. Examples of the secondary substituent of the aryl group which may be substituted in the formula (I) include a halogen atom, an alkyl group, a haloalkyl group, an alkoxy group, a haloalkoxy group, an alkylthio group, a cycloalkyl group and a cycloalkoxy group. , An alkoxyl ruponyl group And an alkylcarbonyl group, an alkylcarbonyloxy group, an aryl group, an aryloxy group, an arylthio group, an amino group, an amino group substituted with one or two alkyl groups, a cyano group, a nitro group, and a hydroxy group.

As the secondary substituent of the optionally substituted heterocyclic group contained in the formula (I), there may be mentioned, for example, a hydrogen atom, a hydrogen atom, an alkyl group, an alkoxy group, a haloalkoxy group, an alkylthio group, a halogen atom, an alkyl group and an alkoxy group. A phenyl group which may be substituted with a nitro group, a haloalkyl or a phenoxy group; a phenoxy group; a phenylthio group; a cycloalkyl group;

Examples of the alkyl group or alkyl moiety contained in the formula (I) include those having 1 to 6 carbon atoms, such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, and a hexyl group. The compounds having 3 or more may have linear or branched structural isomers. Examples of the alkenyl group include those having 2 to 6 carbon atoms, for example, ethenyl group, propenyl group, butenyl group, pentenyl group, and hexenyl group, and those having 3 or more carbon atoms are linear or branched. It may be of a structural isomer of the chain. Alkynyl groups include those having 2 to 6 carbon atoms, for example, ethynyl group, propynyl group, butyl group, pentynyl group, and hexynyl group. It may have a structural isomer of the chain. Examples of the cycloalkyl group include those having 3 to 8 carbon atoms, such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, and a cyclohexyl group.

As the 5-membered or 6-membered heterocyclic group having 4 to 5 carbon atoms which may contain a nitrogen atom or an oxygen atom together with an adjacent nitrogen atom together with R ¹ and R ² contained in the formula (I), Examples thereof include a morpholino group, a pyrrolidino group, a piperidino group, a 1-imidazolidinyl group, a 2-cyanoimino 3-methyl-1-imidazolidinyl group, a 1-piperazinyl group and a 4-methyl-1-piperazinyl group.

Examples of the aryl group included in the formula (I) include a phenyl group, a phenyl group, a furanyl group, a pyridyl group, a naphthyl group, a benzophenyl group, a benzofuranyl group, and a quinolinyl group.

The heterocyclic moiety of the optionally substituted heterocyclic group contained in R ¹ or R ² is Nitrogen atom and oxygen atom such as jyl group, chenyl group, furyl group, pyrazinyl group, pyrimidinyl group, tetrahydrofuranyl group, thiazolyl group, isooxazolyl group, quinolyl group, pyrazolyl group, oxazolyl group, oxaziazolyl group, thiadiazolyl group, triazolyl group, etc. Examples thereof include a 5- to 7-membered monocyclic group or a condensed phenyl group containing 1 to 3 heteroatoms selected from a sulfur atom.

The heterocyclic moiety of the optionally substituted heterocyclic group represented by Q in the formula (I) includes 5 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom. A 7-membered monocyclic group is preferable, and specifically, a 5-membered monocyclic group such as a pyrazolyl group, an oxazolyl group, a thiazolyl group, an oxdiazolyl group, a thiadiazolyl group, and a triazolyl group;

And 6-membered monocyclic groups.

Examples of the secondary substituent of the optionally substituted heterocyclic group represented by Q in the formula (I) include a halogen atom, a nitro group, an optionally substituted alkyl group, and an optionally substituted alkyl group. An optionally substituted alkynyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, an optionally substituted cycloalkyl group, a hydroxyl group, an optionally substituted alkoxy group, and an optionally substituted Good alkenyloxy group, optionally substituted alkynyloxy group, optionally substituted aryloxy group, optionally substituted heterocyclic oxy group, optionally substituted cycloalkoxy group, mercapto group, substituted Alkylthio group, alkenylthio group which may be substituted, alkynylthio group which may be substituted, arylthio group which may be substituted, heterocyclic group which may be substituted Thio group, optionally substituted cycloalkylthio group, optionally substituted carboxy group, optionally substituted alkoxycarbonyl group, optionally substituted aryl group, luponyl group, optionally substituted carbonyloxy group , Formyl group, optionally substituted ester group, optionally substituted acyl group, optionally substituted sulfonyl group, optionally substituted sulfyl group, optionally substituted sulfonyloxy group, substituted Optionally substituted alkylsulfyl group, optionally substituted sulfonylalkyl group, optionally substituted amino group, optionally substituted isocyanato group, optionally substituted arylalkyl group, optionally substituted And a good heterocyclic alkyl group. Of these secondary substituents, those that may be substituted are halogen atoms; cyano groups; halogen groups that can be substituted with halogen, haloalkyl, cyano, alkoxy, aryl, and alkoxy groups that can be substituted with halogen, aryl. An amino group which may be substituted with an alkylsulfonyl, arylalkyl, heterocyclic alkyl, alkyl, aryl, arylalkyl, alkylhydroxy, cyanoalkyl, alkynyl, alkenyl, cycloalkyl; alkoxy, alkylamino or alkyl An alkylthio group; an aryloxy group; an arylthio group; an aryl group optionally substituted with halogen, haloalkoxy, alkyl or aryl; a nitro group; Arylalkyl group; cycloalkyl group; alkylsulfonyloxy group; alkylalkyl group; alkyl, haloalkyl, alkenyl, alkynyl, heterocyclic alkyl, aryloxy, aryloxyalkyl, alkoxy, alkoxycarbonylalkyl, Hydroxyalkyl, cyanoalkyl, alkoxyalkyl, alkenyl, arylalkoxy, alkoxylability isocyanato group optionally substituted with luponylalkyl; arylalkylisocyanana optionally substituted with arylalkyl, halogen, alkyl, alkoxy A cycloalkyl group; a cycloalkyl group; a cycloalkyl group; an alkyl isocyanate group which may be substituted with a haloalkyl group; an alkynylalkyl isocyanate group; Xy, alkylthio, halogen, hydroxy, haloalkoxy, nitro, halogen substituted aryloxy or aryloxy isocyanato group; heterocyclic ring optionally substituted with alkyl, alkoxy, aryl or ester Group: it can be further substituted by a tertiary substituent such as an alkoxyisocyano group.

The compound of formula (I) may form a salt with an acidic substance or a basic substance, and the salt with the acidic substance may be a hydrochloride, a hydrobromide, a phosphate, a sulfate, or a nitrate. Such an inorganic acid salt may be used, and the salt with a basic substance may be an inorganic or organic base salt such as a sodium salt, a potassium salt, a calcium salt, an ammonium salt or a dimethylamine salt.

The compound of the formula (I) or a salt thereof is disclosed in the aforementioned U.S. Pat. No. 5,360,860, U.S. Pat. No. 6,239,160, U.S. Pat. No. 6,566,518, U.S. Pat. It can be manufactured by the method described.

Examples of the alkyl group or alkyl moiety contained in the formula (II) include those having 1 to 6 carbon atoms, such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, and a hexyl group. Or, it includes those having structural isomers of branched fatty chains. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom.

The compound of the formula (II) may form a salt with an acidic substance or a basic substance. Salts with acidic substances include, for example, inorganic acid salts such as hydrochlorides and sulfates. Salts with basic substances include sodium salts, potassium salts, calcium salts, ammonium salts, dimethylamine salts And salts with inorganic bases or organic bases.

The compound of the formula (II) or a salt thereof can be produced by the method described in the aforementioned US Pat. No. 5,288,727.

The house pests referred to in the present invention are pests that live in or around a house, and specifically include termites, ari, cockroaches, and the like. The composition for controlling house pests of the present invention is particularly effective in controlling termites among these house pests.

Examples of termites include: Mastotermit idae Pteroterminidae, Termopsidaeo spp. genus mes, Cryptotemes, Incisitemes, GlyptotermesM], Hodotermit idae, Pterodactylidae [Hodotermes, Microhodotermes, Anacanthotermes], Rhmotermit idae, Rhizophyllid termites [Genus Ret icul itermes, Heterotermes, Heterotermotes] Genus], Serritemit idae sawtooth termite, Termite tidae termite [Amiteraes genus, Drepanotermes genus, Hopitalitermes genus, Trin genus ervitermes, Macrote genus, Odontotermes, Microtemes, Nasut itermes, Pericapritermes, Anoplotermes].

Specific examples of termites to be controlled include: japonicus termites (Ret icul itermes speratus), common termites (Coptotermes formosanus), American kansaiishiari (Incisitermes minor), terrestrial termites (Cryptotermes domes t icus), formosanus), Japanese termite (Neoterme skoshunensis), Japanese termite (Glyptotermes satsumensis), Nakamushi mouth (Gly totermes nakaj imai), Power tangiary (Gly totermes fuscus), Kodama li The termites (Hodotermopsis j aponica) and the termites

(Coptotermes guangzhoensis), amami termite (Reticul itermes miyatakei), termite (Ret icul itermes f laviceps amamianus), termite

(Reticul itermes sp.), Evening larvae (Nasut itermes takasagoensis), two-sided termites (Pericapriterme nitobei), and musciate termites (Sinocapritermes mushae).

Examples of squirrels include the octopus ant (Bracliyponera chinensis), the squirrel (Pheidole nodus), the key-mouthed seriary squirrel (Crematogaster osakensis), the squirrel squirrel (Crematogaster laboriosa), and the sculptures of jellyfish (Polyergus samurai), Himeari (Monomorium intrudens), Iehimeri (Monomorium pharaonis), Tobiiroshiari (Tetramorium caespitum), Iriant (iire ant) and the like.

Examples of cockroaches include the cockroaches Blattella germanica, the cockroaches Moritzia (Blattella nipponica), the cockroaches (Periplaneta ful iginosa), the cockroaches (Periplaneta americana), the cockroaches (Periplaneta australasiae), and the cockroaches (Periplaneta australasiae b)

(Blatta oriental is), black cockroach (Periplaneta j aponica), red cockroach (Periplaneta j apanna), house cockroach (Neostylopyga rhombi folia), ma The cockroach (Hebardina yayeyamana), the cockroach (Rhabdoblatta fo rmosana), the brown cockroach (Trichoblatta pygmaea), and the cockroach (Panest hia angustipennis spadica) are exemplified.

(a) Dialkyl sulfosuccinate or a salt thereof is effective alone, but (b) It can be used in combination with urea or uric acid. When mixed and used, the mixing ratio of the component (a) and the component (b) is 1: 200 to 200: 1, preferably 1: 100 to 100: 1, and more preferably 1:50 to 1. 50: 1, most preferably 1: 5 to 5: 1. It should be noted that urea or uric acid alone can be used as an active ingredient of a house pest control agent.

In addition to the component (a), the component (c) can be further mixed and used. The mixing ratio of the component (a) and the component (c) is 1: 200 to 200: 1, preferably 1: 100 to 100: 1, more preferably 1:50 to 50: 1, and most preferably. 1: 5 to 5: 1. The component (c) is an active ingredient that is consumed by house pests. However, when a composition for controlling house pests containing the component (a) and the component (c) as active ingredients, the composition of (a) Since the ingredient provides an antifeeding activity and a repellent activity, it can be used as a house insect pest control agent for wood application. In addition to this, synergistically enhances the termiticidal activity by contact that the component (a) and the component (c) previously had. When this composition is applied to wood and used, it can control house pests while minimizing damage to the wood. When the active ingredient (b) is further added to this composition, the effect of controlling house pests is further enhanced.

(a) The dialkyl sulfosuccinate or a salt thereof may be used in place of the component (b) and the component Z or (c), or in combination with the component (b) and the component Z or (c), It can be used by mixing with compounds such as benzoyl perylene compounds; organophosphorus insecticides; carbamate insecticides; pyrethroid insecticides; and other insecticides. In addition, acaricides (fungicides); preservatives and the like can be further mixed and used. Representative examples are shown below.

Benzoylpereas: Diflubenzuron, Chloriluazuron, Teflubenzuron, Flufeno Cuxuron (Flufenoxuron), Trifluumuron (Triilumuron), Hexaflumuron (Hexaf lumuron), Lufenuron (Lufenuron), Novaluron (Novaluron), Novifflumuron (Novif lumuron).

Organophosphorus insecticides: phoxime, probe phos, fenthion, phennitrothion, diazinon, chlorpyrifos, ESP, bamidion, fentoate, dimethoate, formotion, marathon, trichlorfon, thiomethone, phosmet, dichlorvos, acephate, EP Methyl parathion, oxydimethyl methyl, ethion, salicion, cyanophos, isoxathion, pyridafen. Thion, hosalon, methidathion, sulprophos, pyraclophos, monocrotophos, fenamiphos.

Carbamate pesticides: fenovcalp, proboxil, aldicarb, provoquisul, mesomil, BPMC, MTM C, levulinyl, cartap, thiocyclam, carbosulfan, benfracarb, pirimicarp, ethiofencarb, phenoxycarp, thiodicarp.

Pyrethroid insecticides: silafluofen, permethrin, dipermethrin, decamestrin, fenvalerate, fenpropatrin, pyrethrin, allesulin, tetramethrin, resmethrin, dimethrin, propasulin, bifentrin, prothrin, fulvalinate, cyfluthrin, cyhalothrin, cyhalothrin, cyhalothrin Etofenprox, cycloprothrin, tralomethrin, silaneofane.

Neonicotinoid insecticide: imidacloprid.

Nereistoxin insecticide: bensultap.

Other insecticides: chlorfenapyr, sulfuramide, hydramethylnon, bupu mouth fuezin, pyriproxyfen, diafenthiuron, machine oil, nicotine sulfate, BT, fipronil, clotianidin, a; — (, α, 1-trifluoro-m 1-trioyl) 1-p-tolunitrile 4 (p-trifluoromethoxyphenyl) semicarbazone.

Preservatives: Pennyl chlorophenyl laurate, P-promo 2,6-dichlorf Enol, 3-Feodo-2-propynylbutyl carbamate, 3-ethoxyponyloxy-1-bromo-1,2, -Jodopropene, Benzalconium chloride, Dialkyldimethylammonium chloride, Bis (n-triptyltin) oxide, Triptyltin Terephthalate, zinc aphthenate, xyligen aluminum salt, cyproconazole, azaconazole, tebuconazole.

(a) The dialkylsulfosuccinate or a salt thereof can be used alone or as it is in the form of a mixture with or combined with the component (b) and / or the component (c) described above. It can be used in the form that the medicine can take, that is, wettable powder, water solvent, powder, emulsion, liquid, granule, flowable oil, paste, aerosol, fumigant, smoker and the like. When the solid additive is used as the additive and carrier, plant powder such as soybean powder and flour, diatomaceous earth, apatite, gypsum, talc, bentonite, clay, and other mineral powder, and sodium benzoate If organic and inorganic compounds such as urea, urea, and sodium sulfate are used, and liquid liquids are used, vegetable oils, mineral oils, kerosene, petroleum fractions such as xylene and solvent naphtha, and cyclohexane Xane, cyclohexanone, dimethylformamide, N, N-dimethylacetamide, dimethyl sulfoxide, trichloroethylene, methyl isobutyl ketone, water, etc. are used. In these formulations, a surfactant can be added if necessary to obtain a uniform and stable form. The wettable powders, emulsions, aqueous solutions and flowables thus obtained are diluted to a predetermined concentration with water to form suspensions, solutions or emulsions, and powders and granules are sprayed as they are Used in the method. The concentration of the components in the formulation may be selected according to the dosage form, treatment method, type of house pest, etc., but the active components (a) to (c) containing dialkyl sulfosuccinate or its salt as an essential component The total content is usually from 0.1 to 90% by weight, preferably from 1 to 60% by weight, and more preferably from 10 to 40% by weight.

In the present invention, the dialkyl sulfosuccinate ester or a salt thereof or a preparation thereof is applied to a place where house pests inhabit or to be protected from house pests. Specifically, for example, it is applied to termites and nests; house timber; buildings and surrounding soil; concrete blocks, floor slabs, electric wires, and coatings of various cables. It is applied by using cloth, spraying, spraying, dipping, pressure injection, kneading, mixing, etc.

The treatment amount of the dialkyl sulfosuccinate or its salt may be selected according to the dosage form, treatment method, type of house pest, etc. In general, in the case of soil treatment, 0.1 to 0.1 g; ² , preferably 1 to: L 0 g / m ² ; for wood treatment, 0.01 to 50 g Zm ² , preferably 0.1 to 5 g / m ² .

The composition of the present invention may contain an emulsion, a suspending agent, a wettable powder, a water solvent, a liquid, a flowable, a granule wettable powder, a granule, a dust, an air-soluble agent together with auxiliary agents as in the case of conventional insecticide preparations. Formulations, pastes, gels, sheet preparations, microcapsules, microemulsions, emulsions, oils, micro-sprays, etc., and can be used as a composition for controlling house pests. it can. The mixing ratio of these auxiliaries is usually from 0.001 to 99 parts by weight, preferably from 0.01 to 95 parts by weight, more preferably from 0.01 to 80 parts by weight, and 99.999 parts by weight, preferably 5 to 99.99 parts by weight, and more preferably 20 to 99.99 parts by weight. In the actual use of these preparations, they can be used as they are, or can be used after diluting to a predetermined concentration with a diluent such as water.

Examples of the adjuvant include a carrier, an emulsifier, a suspending agent, a dispersing agent, a spreading agent, a penetrating agent, a wetting agent, a thickening agent, a stabilizer and the like, and these may be added as needed. Carriers are divided into solid carriers and liquid carriers. Solid carriers include animal and plant powders such as starch, activated carbon, soy flour, flour, wood flour, fish meal, milk powder; talc, kaolin, bentonite, calcium carbonate, zeolite And mineral powders such as diatomaceous earth, white carbon, clay and alumina. Liquid carriers include alcohols such as water, isopropyl alcohol and ethylene glycol; ketones such as cyclohexanone and methyl ethyl ketone; dioxane and tetrahydrofuran. Ethers such as kerosene and light oil; aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, methylnaphthalene and sorbent naphtha; halogenated hydrocarbons such as black benzene; Acids such as dimethylformamide Esters such as glycerin esters of fatty acids; bromide such nitriles such as Asetonitoriru; And sulfur-containing compounds such as dimethylsulfoxide.

When the composition of the present invention is used for controlling house pests, the total amount of the active ingredient to be treated varies depending on the treatment method of the composition of the present invention, the form of preparation, and other various conditions. 100 g Zm ² , preferably 1 to: L 0 g / m ² ; in the case of wood treatment, 0.01 to 50 g Zm ² , preferably 0.1 to 5 g / m ² .

The composition of the present invention can be applied to habitats of house pests. Examples of habitats for house pests include wood, soil, and trails for house pests such as ant roads. This includes places where house pests may live in the future, such as wood for home use such as pillars and foundations. If the active ingredient is formulated in water solvents, liquids, dusts, pastes, gels, etc., and applied to the habitat of house pests, it can be eaten or brought into contact with house pests, thus controlling house pests be able to . Above all, in the control of termites and ants, methods such as directly applying the above-mentioned water solvents, liquids, dusts, pastes, microcapsules, microemulsions, emulsifiers, gels, etc. to the affected area are used. desirable.

When the composition of the present invention is applied to a habitat of wood or house pests, it may be sprayed or applied. When applying the composition of the present invention formulated in a dust agent, paste agent, gel agent, or the like to wood, it is preferable to perform perforation injection with holes as necessary.

The composition of the present invention can be subjected to soil treatment by a method of forming a drug layer on the soil surface. More specifically, for example, when a liquid material is to be applied to the underfloor soil of a wooden building that can be invaded by humans, it is sprayed using a power sprayer, and the emphasis is on building foundations where ant passages are easily formed. It is better to process. When treating underfloor soil such as bathrooms and entrances where humans cannot enter, a method is used in which a drill is used and a chemical is injected into the soil from there.

The composition of the present invention may be in the form of an aerosol containing the above-mentioned dust. The aerosol usually contains the above-mentioned powder and propellant, and if necessary, a solvent. The aerosol usually contains 0.1 to 10% by weight of the powder and usually 20 to 90% of the propellant. % By weight. As the solvent, for example, Esters such as isopropyl myristate, isopropyl palmitate, isopropyl decanoate and isopropyl laurate; and alcohols such as ethanol and isopropyl alcohol.

When the composition of the present invention is in the form of a sheet preparation, the active ingredient compound can be usually contained in the sheet preparation at a concentration of 0.01 to 20% by weight. The sheet preparation can be produced by holding the active ingredient compound on a sheet-like carrier such as cellulose paper according to a usual method. For example, a sheet preparation can be prepared by applying a solution or dispersion containing the active ingredient compound to cellulose paper and drying. The solution or dispersion can be obtained by dissolving the active ingredient compound in a suitable solvent, but may be diluted with water containing a surfactant or a dispersant, if necessary.

Next, preferred embodiments of the present invention will be described, but the present invention is not limited thereto.

Among the “control methods for house pests” of the present invention, some preferred embodiments will be exemplified.

(1) A method for controlling house pests, which comprises treating an effective amount of a dialkyl sulfosuccinate or a salt thereof to house pests.

(2) A method for controlling house pests, which comprises treating an effective amount of (a) a dialkyl sulfosuccinate or a salt thereof and (b) urea or uric acid with house pests.

(3) The method according to the above (1) or (2), wherein the salt of the dialkylsulfosuccinic acid is a sodium salt.

(4) The method according to the above (1) to (3), wherein the house pest is a termite or an ant.

(5) The method according to the above (1) to (3), wherein the dialkyl sulfosuccinate or a salt thereof is applied to a habitat of house pests.

(6) The method according to (1) to (3), wherein the dialkyl sulfosuccinate or a salt thereof is applied to a place to be protected from house pests.

(7) Apply dialkyl sulfosuccinate or its salt to the place to be protected. (6) the method of repelling house pests by using

(8) The method according to the above (1) to (3), wherein the dialkyl sulfosuccinate or its salt is applied to an ant road or directly to wood or a damaged part.

(9) The method according to (5), wherein the habitat of the house pest is soil.

(10) The method of (5) above, wherein the habitat of the house pest is an ant path.

(11) The method of the above (5), wherein the habitat of the house pest is wood.

Some preferred embodiments of the “composition for controlling house pests” of the present invention will be described.

(1) (a) a dialkyl sulfosuccinate or a salt thereof, and (c) (c-1) a pyridine compound of the formula (I) or a salt thereof, and / or (c-12) a hydrazone of the formula (II) A composition for controlling house pests, comprising a system compound or a salt thereof as an active ingredient.

(2) (a) dialkyl sulfosuccinate or a salt thereof, (b) urea or uric acid, and (c) (c-11) a pyridine compound of the formula (I) or a salt thereof, and Z or (c 1) A composition for controlling house pests, comprising a hydrazone compound of the formula (II) or a salt thereof as an active ingredient.

(3) The composition according to the above (1) to (2), wherein the salt of the dialkylsulfosuccinic acid is a sodium salt.

(4) (b) urea or uric acid, and (c) (c-1) a pyridine compound of the formula (I) or a salt thereof, and / or (c-12) a hydrazone compound of the formula (II) or a hydrazone compound thereof. A composition for controlling house pests containing a salt as an active ingredient.

(5) The composition according to any one of the above (1) to (3), wherein (c) is (c-1) a pyridine compound of the formula (I) or a salt thereof.

(6) A pyridine compound of the formula (I) or a salt thereof, wherein Q is

[X is an oxygen atom or a sulfur atom, and R ¹ and R ² are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, cycloalkyl group which may be, - C CW R ³ _{groups, -! S (0) n} R 5 groups, one NHR ⁶ group, or R ¹ and R ² together ^{= C (R 1 ") ^} 11 Or a 5- or 6-membered heterocyclic group having 4 to 5 carbon atoms which may contain a nitrogen atom or an oxygen atom together with an adjacent nitrogen atom].

(7) X is an oxygen atom, R ¹ and R ² are each independently a hydrogen atom, an alkyl group, alkoxyalkyl group, alkylaminoalkyl group, C _2. ₆ cyclic aminoalkyl group, a hydroxyalkyl group, Shianoarukiru group, A thiocarbamoylalkyl group, an alkylcarbonyloxyalkyl group, an alkylcarbonyl group, an arylcarbonyl group, a trifluoromethyl-substituted arylcarbonyl group, an alkoxythiocarbonyl group or an alkoxycarbonyl group, or R ¹ and becomes R ² gar緖= C to form a (R ^1Q) R ¹¹ groups, the composition of the ⁽⁵⁾ R ^{1 (1} and R ¹¹ are each alkoxy and alkyl Chio group.

(8) The pyridine compound is N-cyanomethyl-14-trifluoromethyl-3-pyridinepyridine (compound A), N-ethyl-4-1-trifluoromethyl-3-pyridinepyridine, 4-trifluoromethyl Cyl-3-pyridinecarboxamide, N_thiocarbamoylmethyl-4-trifluoromethyl-3-pyridine power Lupoxamide, N-ethoxymethyl-14-trifluoromethyl-3-pyridine power Lupoxamide, N-isopropylaminomethyl-4 —Trifluoromethyl-3-pyridinepyridinecarboxamide, N-cyanomethyl_N, N—bis (4-trifluoromethylnicotinyl) amine, N-acetyl-N-cyanomethyl-14-trifluoromethyl-3-pyridinepyridinecarboxamide, N-cyanomethyl-N— Methyl-4 monotrifluoromethylpyridine—3-capillary Samido, 〇 one methyl N-(4 one triflate Ruo Russia methyl nicotinate Noi Le) Chiokarubamato, N- methyl-4 Ichiboku riff Ruo b methylpyridine _ 3 forces Rupokisamido, N- (Ν ', N' - dimethylaminopyridine 4-methyltrifluoro-1-pyridine-3-N- (4-piperidylmethyl) -4-4-trifluoromethylpyridine-13-nitrolipoxamide, N-cyanomethyl N— (4-trifluoromethyl) Methylnicotinoyl) Aminomethylpiparatate, O, S-Dimethyl N- (4-Trifluoromethylnicotinoyl) 'Iminoformate, N-Hydroxymethyl-4-1, Trifluoromethyl-3-pyridinyl lipoxamide, N At least one compound selected from the group consisting of —acetyl-14-trifluoromethyl-13-pyridinecarboxamide and methyl N— (4-drifluoromethylnicotinol) carbamate or their 1-oxides. Certain compositions according to (5) above.

(9) The composition according to the above (5), wherein the pyridine compound is N-cyanomethyl-141-trifluoromethyl-3-pyridine lipoxamide or 4-trifluoromethyl-3-pyridine lipoxamide.

(10) A pyridine compound of the formula (I) or a salt thereof, wherein Q is

[Wherein X is an oxygen atom or a sulfur atom, and R ¹ is a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, or an optionally substituted A good cycloalkyl group, an optionally substituted aryl group or a C (W ¹ ) R ³ group, wherein R ⁴ is a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, A alkynyl group, a cycloalkyl group which may be substituted, an aryl group which may be substituted, a heterocyclic group which may be substituted, or a COR ³ group].

(11) The composition according to the above (5), which is a pyridine compound of the formula (I) or a salt thereof, wherein Q is an optionally substituted heterocyclic group.

(12) The composition according to the above (11), wherein the heterocyclic group is a 5- to 7-membered monocyclic group containing 2 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom.

(13) The composition according to the above (11), wherein the heterocyclic group is a 5-membered monocyclic group containing 2 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom. (14) The composition according to the above (11), wherein the 5-membered monocyclic group is a pyrazolyl group, an oxazolyl group, a thiazolyl group, an oxadiazolyl group, a thiadiazolyl group or a triazolyl group.

(15) The composition according to the above (11), wherein the heterocyclic group is a 6-membered monocyclic group containing 2 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom.

(16) a 6-membered monocyclic group

(Wherein R is an alkyl group).

(17) The composition according to the above (16), wherein R ¹⁶ is a methyl group or an isopropyl group.

(18) The composition according to any one of the above (1) to (3), wherein (c) is (c-2) a hydrazone compound of the formula (II) or a salt thereof.

(19) The hydrazone-based compound is [4, -chloro-2-(4-trifluoromethylphenyl) acetophenone] N '— C1-(dimethylamino) ethylidene] hydrazone (compound No.1), [4' — Fluoro-2_ (4-trifluoromethylphenyl) acetophenone] N '-[1- (Dimethylamino) ethylidene] hydrazone (Compound No.2), ethyl 3- (1- (4- (4-methylphenyl))-2 — (4—Trifluoromethylphenyl) ethylidene] Carbazate (Compound No. 3), [4′-one-mouthed 2- (4-Yuichi-shary-butylphenyl) acetophenone] N, — [1-1 ( [Dimethylamino] ethylidene] hydrazone (Compound No.4), [4'-Fluoro-2- (4-butyl phenylphenyl) acetophenone] N '_ [1-1 (Dimethylamino) ethylidene] hydrazone Things No.5), [4 'single-methyl-2 one ₍₄ Isseki one shari - Puchirufueniru) Asetofuenon] N, one [1- (dimethylcarbamoyl Ruamino) Echiriden] hydrazone (Compound No.6), [4' single black Mouth 2— (4—Trifluoromethylphenyl) acetophenone] N, 1- [1-aminoethylidene] hydrazone (Compound No.7) or [4′-Fluoro-2- (4-trifluoromethylphenyl) acetophenone] N ′ -[1-Aminoethylidene] hydrazone (18) The composition according to the above (18), which is (Compound No. 8).

In order to describe the present invention in more detail, examples will be described below, but these do not limit the present invention.

Formulation example

(1) Brand name New Calgen EP-70G (manufactured by Takemoto Yushi Co., Ltd.) 17.2 parts by weight

(2) Urea 0 parts by weight

(3) 5 parts by weight of compound A

(4) Water 0 parts by weight

(5) N, N-dimethylformamide 3 parts by weight or more of the components are mixed uniformly to obtain a liquid. The brand name Newcalgen EP-70G contains 70% by weight of sodium dioctyl sulfosuccinate. Test example 1

A filter paper with a diameter of 80 thighs stained with an oil red was spread on a plastic petri dish, and 1 ml of a chemical solution having a predetermined concentration was dropped on the filter paper. After that, 10 termite (Reticulitermes speratus) ants were released and covered. This plastic petri dish was placed in a container covered with wet cotton at the bottom and maintained in a breeding constant temperature room at 25 ° C. Ten days and seventeen days after the treatment, the number of termites killed in the shears and the presence or absence of termite abdominal staining with an oil red were examined, and the mortality and feeding inhibition were calculated by the following formulas. The results are shown in Table 1. Mortality (%) = (Number of dead insects Z termites 10 ants) X100

Feeding inhibition rate (%) = (number of abdominal unstained insects / termite termites 10) X100 Table 1

Chemical concentration Insect mortality rate (%) Feeding inhibition rate (%)

(pm) 10 days after treatment 17 days after treatment 10 days after treatment 17 days after treatment Dioctylsul 4000 100 100 100 100 Nasuccinic acid 2000 80 90 100 90 Thorium salt aqueous solution 1000 30 50 90 90 He 500 0 50 60 60

0 0 0 30 30 Test example 2

A filter paper having a diameter of 80 mm was placed on a plastic petri dish, and 1 ml of a drug solution having a predetermined concentration was dropped on the filter, and ten termites (Coptotermes formosanus) were released and covered. This plastic petri dish was placed in a container lined with wet cotton at the bottom and maintained in a breeding constant temperature room at 25 ° C. Fourteen days after the treatment, the number of termites in the petri dish was examined, and the mortality was calculated by the following equation. The results are shown in Table 2.

Mortality (%) = (Number of dead Z termite termites 10) X 100 Table 2

Test example 3

A filter paper having a diameter of 80 watts was placed in a plastic chalet, and 1 ml of a predetermined concentration of a drug solution diluted with acetone was added dropwise thereto. After the treatment, the solvent was sufficiently volatilized, and the treated filter paper was filled with 1 ml of distilled water, and ten termites (Reticul i termes speratus) were released and capped. The plastic petri dish was placed in a container lined with wet cotton on the bottom and maintained in a breeding constant temperature room at 25 ° C. Seven days after the treatment, the number of dead insects in the petri dish was examined, and the mortality was calculated by the following formula. The results are shown in Table 3. Mortality () = (number of dead Z termite termites 10) X 100

In addition, the theoretical value () of the mortality can be calculated by Colby's formula. When the mortality (%) is higher than the theoretical value (%) according to Colby's formula, the composition for controlling house pests of the present invention has a synergistic effect on controlling house pests.

Test example 4

A filter paper having a diameter of 80 im was placed on a plastic petri dish, and 1 ml of a predetermined concentration of a drug solution diluted with acetone was added dropwise thereto. After the treatment, the solvent was sufficiently volatilized, and the treated filter paper was filled with 1 ml of distilled water, and ten termites (Reticul i termes speratus) were released and capped. This plastic petri dish was placed in a container covered with wet cotton at the bottom and maintained in a breeding constant temperature room at 25 ° C. Eight days after the treatment, the number of dead insects in the petri dish was examined, and the mortality was calculated by the following equation. The results are shown in Table 4, Table 5, Table 6, and Table 7.

Mortality (%) = (Number of dead insects 10 termites) X 100

It is also possible to calculate the theoretical value (%) of mortality based on Colby's formula. When the mortality (%) is higher than the theoretical value (%) according to Colby's formula, the composition for controlling house pests of the present invention has a synergistic effect on controlling house pests. Table 4

Compound No. 1 Mortality [Theoretical value] (%) lOppm 5ppm Oppm Dioctyl sulfo

Sodium salt of succinic acid

ΙΟΟΟρρι 100 删 70 [60] 60

50 Oppm 100 [30] 30 [30] 30

Oppm 0 0 0

Test example 5

A filter and paper having a diameter of 80 m were put on a plastic chalet, and 1 ml of a predetermined concentration of a drug solution diluted with acetone was added dropwise thereto. After evaporating the solvent sufficiently after the treatment, add l ml of distilled water to the treated filter paper and release 10 termites (Coptotemes fomosanus). Covered. This plastic petri dish was placed in a container covered with wet cotton at the bottom and maintained in a breeding constant temperature room at 25 ° C. Fourteen days after the treatment, the number of termites in the petri dish was examined, and the mortality was calculated by the following formula. The results are shown in Tables 8 and 9.

Mortality (%) = (Number of dead insects Z termites 10 ants) X 100

It is also possible to calculate the theoretical value (%) of mortality based on Colby's formula. When the mortality (%) is higher than the theoretical value (%) according to Colby's formula, the composition for controlling house pests of the present invention has a synergistic effect on controlling house pests. Table 8

Test example 6

A chemical solution of 110 ± 10 mg was applied to a test cuboid akamatsu wood piece (20 thigh X 10 cruise X 10 marauder) using a brush. The treated wood pieces were naturally dried in a room at 25 ° C for 7 days, and then the treated and untreated wood pieces were dried at a temperature of 60 ° C for 48 hours, and the mass (M ¹ ) was measured. A test specimen was used. The specimen was placed in an acrylic resin cylindrical cup (a cup with a hole of 10 holes in the bottom and hard plaster hardened to a thickness of lOnrn at the bottom), and 70 ants of Coptotennes formosanus Fired seven soldier ants. Place the cup in a container covered with wet cotton in the lower part, and keep the container at room temperature 25 ° C for 13 days. Was taken out of the cup, the deposits on the surface of the test piece were removed, dried at a temperature of 60 ° C. for 48 hours, weighed, its mass (M ² ) was obtained, and the mass reduction rate was calculated. The results are summarized in Table 10.

Mass loss rate of wood pieces (%) = (M ¹ — M ² / Ψ) X100 Table 10

In addition, in the specification of the present invention, the entire contents of the specification of Japanese Patent Application No. 2002-294074, which is the basis of the priority claim of the present application, are incorporated herein by reference.

Claims

The scope of the claims

1. A composition for controlling house pests, comprising a dialkyl sulfosuccinate or a salt thereof as an active ingredient.

2. A method for controlling house pests, which comprises treating an effective amount of a dialkyl sulfosuccinate or a salt thereof to house pests.

3. The method according to claim 2, wherein the house pest is a termite or an ant.

4. The method according to claim 2, wherein the dialkyl sulfosuccinate or a salt thereof is applied to a house pest habitat.

5. The method according to claim 2, wherein the dialkyl sulfosuccinate or a salt thereof is applied to a place to be protected from house pests.

6. The method according to claim 5, wherein the dialkyl sulfosuccinate or its salt is applied to wood.

7. The method according to claim 5, wherein a dialkyl sulfosuccinate or a salt thereof is applied to wood.

8. The method according to claim 2, wherein (a) dialkyl sulfosuccinate or a salt thereof and (b) urea or uric acid are applied to house pests.

9. (a) Dialkyl sulfosuccinate or a salt thereof, and (c) (c-1) Formula (I):

[Wherein, Y is a haloalkyl group, m is 0 or 1, and Q is

(X is an oxygen atom or a sulfur atom, and R ¹ and R ² are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group, cycloalkyl group which may be, - CW ^ R ³ group, -OR ⁴ group, -S (0) _n R ⁵ group, -NHR ⁶ group,

一 C (R ⁸ ) = N〇R ⁹ or an aryl group which may be substituted, or R ¹ and R ² together form = C (R ^ R ¹¹ , or A 5- or 6-membered heterocyclic group having 4 to 5 carbon atoms which may contain a nitrogen atom or an oxygen atom may be formed together with an adjacent nitrogen atom, and R ³ is an alkyl group which may be substituted, An optionally substituted alkenyl group, an optionally substituted alkynyl group, an optionally substituted cycloalkyl group, an optionally substituted aryl group, an alkoxy group, an alkylthio group or a mono- or dialkylamino group, ⁴ is a hydrogen atom, an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, a cycloalkyl group which may be substituted, an aryl group which may be substituted Is an optionally substituted heterocyclic group or COR ³ group, R ⁵ is an alkyl group or a dialkylamino group; R ⁶ is an alkyl group or an aryl group; Z is an N or C-R ⁷ group; R ⁷ is a hydrogen atom, a halogen atom, or may be substituted R ⁸ and R ⁹ are each independently a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl R ^{1 D} and R ¹¹ are each independently a hydrogen atom, an alkyl group which may be substituted, or a substituted or unsubstituted aryl group or an optionally substituted heterocyclic group. An optionally substituted alkenyl group, an optionally substituted heterocyclic group, one N_ (R ¹² ) R ¹³ group, an optionally substituted alkoxy group, an optionally substituted alkylthio group, and R ¹² and R ¹³ is each independently a hydrogen atom, An alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted or a heterocyclic group which may be substituted, and W ¹ is an oxygen atom or a sulfur atom. , N is 1 or 2 Or a heterocyclic group which may be substituted.] Or a salt thereof, and / or (c-12) a formula (II):

[Wherein, R ¹ ′, R ² ′ and R ⁴ ′ each independently represent a hydrogen atom, a halogen atom, an alkyl group optionally substituted with a halogen atom or an alkoxy group optionally substituted with a halogen atom. R ³ ′ is a halogen atom, an alkyl group optionally substituted with a halogen atom or an alkoxy group optionally substituted with a halogen atom, R ⁵ ′ is a hydrogen atom or an alkyl group, and R ⁶ ′ is X ⁷ 'CO- group, or X ^8' OCO- groups as or R ⁵ 'and R ^6', such that together connexion, may form a -CR ⁷ 'R ^8' group, X ⁷ 'is a hydrogen atom or X ⁸ ′ is an alkyl group, R ⁷ ′ is a hydrogen atom or an alkyl group, and R ⁸ ′ is an amino group or an alkoxy group which may be substituted with an alkyl group. A composition for controlling house pests, comprising a hydrazone compound or a salt thereof as an active ingredient.

10. The composition according to claim 9, further comprising (b) urea and Z or uric acid as active ingredients.

11. The composition according to claim 9, wherein (c-11) is N-cyanomethyl-4-1-trifluoromethyl-3-pyridine lipoxamide and / or 4-trifluoromethyl-3-pyridinecarboxamide.

12. (c-2) is [4,1-methyl-2- (4-trifluoromethylphenyl) acetophenone] N '-[11- (dimethylamino) ethylidene] hydrazone, [4'-fluoro-2-- ( 4-Trifluoromethylphenyl) acetophenone] N '1 [11- (Dimethylamino) ethylidene] Hydrazone, ethyl 3-[1_ (4-chloromethylphenyl) 1 2_ (4-Trifluoromethylphenyl) ethylidene] Power basate, [4,1-Chloro-2- (4-overnight-butylbutylphenyl) acetophenone] N, 1- [11- (dimethylamino) ethylidene] hydrazone, [4,- Fluoro-2- (4-tert-butylphenyl) acetophenone] N, 1 [11 (dimethylamino) ethylidene] hydrazone, [4,1-methyl-2- (4-tert-butylphenyl) acetophenone] N, 1 [ 11- (Dimethylamino) ethylidene] hydrazone, [4,1-chloro-2- (4-trifluoromethylphenyl) acetophenone] N, 1- [1-aminoethylidene] hydrazone and [4'-fluoro-2-(4 10. The composition according to claim 9, which is at least one compound selected from the group consisting of -trifluoromethylphenyl) acetophenone] N '-[1-aminoethylidene] hydrazone.

13. A method for controlling house pests, which comprises treating the composition according to claim 9 into house pests.

1 4. The method according to claim 13, wherein the house pest is a termite or an ant.

15. The method of claim 14, wherein the house pest is a termite.