WO2004015029A1 - Method and ribbed tube for thermally cleaving hydrocarbons - Google Patents
Method and ribbed tube for thermally cleaving hydrocarbons Download PDFInfo
- Publication number
- WO2004015029A1 WO2004015029A1 PCT/EP2003/004827 EP0304827W WO2004015029A1 WO 2004015029 A1 WO2004015029 A1 WO 2004015029A1 EP 0304827 W EP0304827 W EP 0304827W WO 2004015029 A1 WO2004015029 A1 WO 2004015029A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tube
- ribs
- finned tube
- profile
- rib
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
- C10G9/18—Apparatus
- C10G9/20—Tube furnaces
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/24—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by heating with electrical means
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/40—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only inside the tubular element
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
- C10G2300/807—Steam
Definitions
- the swirl flow absorbs the vertebrae detaching at the rib flanks, so that there is no local return of the vertebrae in the manner of a self-contained circular flow into the rib valleys.
- the mean residence time is lower than in the smooth tube and moreover more homogeneous over the cross-section (see Fig. 7). This is confirmed by the higher overall speed in the profile tube with swirl (profile 3) compared to the tube with straight ribs (profile 2). This is ensured in particular when the swirl flow in the area of the fins or the fins extend at an angle of 20 ° to 40 °, for example 30 °, preferably 25 ° to 32.5 ° with respect to the tube axis.
- the heat inevitably different over the circumference of the tube between the sun and shadow side is offered balanced in the tube wall and inside the tube and the heat was quickly dissipated inwards to the core zone. This is associated with a reduction in the risk of local overheating of the process gas on the tube wall and the resulting pyrolysis coke.
- the thermal stress on the pipe material is lower due to the temperature balance between the sun and shade side, which leads to an extension of the service life.
- the temperature is also made more uniform over the pipe cross section, with the result that the olefin yield is better. The reason for this is that without the radial temperature equalization according to the invention inside the pipe inside the hot pipe wall would overcrack and in the pipe center a recombination of fission products would occur.
- the superiority of the finned tube according to the invention (profile 3) compared to a smooth tube (profile 0) and a finned tube with axially parallel fins (profile 1), in which the radial distance between the rib valleys and the fin tips is 4.8 mm, illustrate the data of the following Table.
- the finned tubes all had 8 fins and the same enveloping circle.
- the hydraulic diameter is defined as follows:
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Geometry (AREA)
- General Engineering & Computer Science (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (17)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2493463A CA2493463C (en) | 2002-07-25 | 2003-05-08 | Process and finned tube for the thermal cracking of hydrocarbons |
NZ537827A NZ537827A (en) | 2002-07-25 | 2003-05-08 | Process and finned tube for the thermal cracking of hydrocarbons |
ES03725176T ES2374568T3 (en) | 2002-07-25 | 2003-05-08 | PROCEDURE AND TUBE WITH FINS FOR THERMAL DISPOSAL OF HYDROCARBONS. |
JP2004526658A JP4536512B2 (en) | 2002-07-25 | 2003-05-08 | Method for pyrolyzing hydrocarbons and ribbed tubes |
AU2003227737A AU2003227737A1 (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons |
EP03725176A EP1525289B9 (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons |
MXPA05001070A MXPA05001070A (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons. |
EA200500258A EA010936B1 (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons |
YUP-2005/0060A RS20050060A (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons |
AT03725176T ATE526385T1 (en) | 2002-07-25 | 2003-05-08 | METHOD AND FINNED TUBE FOR THERMAL CRACKING OF HYDROCARBONS |
BRPI0312919-5A BR0312919B1 (en) | 2002-07-25 | 2003-05-08 | Finned tube for thermal cracking of hydrocarbons in the presence of steam |
US10/945,860 US20050131263A1 (en) | 2002-07-25 | 2004-09-21 | Process and finned tube for the thermal cracking of hydrocarbons |
IL166229A IL166229A (en) | 2002-07-25 | 2005-01-11 | Process and ribbed tube for thermally cleaving hydrocarbons |
ZA2005/00456A ZA200500456B (en) | 2002-07-25 | 2005-01-18 | Method and ribbed tube for thermally cleaving hydrocarbons |
HR20050072A HRP20050072A2 (en) | 2002-07-25 | 2005-01-24 | Method and ribbed tube for thermally cleaving hydrocarbons |
NO20050493A NO337398B1 (en) | 2002-07-25 | 2005-01-28 | Ribbed tubes for thermal splitting of hydrocarbons |
US12/025,398 US7963318B2 (en) | 2002-07-25 | 2008-02-04 | Finned tube for the thermal cracking of hydrocarbons, and process for producing a finned tube |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10233961A DE10233961A1 (en) | 2002-07-25 | 2002-07-25 | Cracking hydrocarbon materials in presence of steam heated with pipes having helical inner ribs promoting uniform temperature in pipe wall |
DE10233961.9 | 2002-07-25 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/945,860 Continuation US20050131263A1 (en) | 2002-07-25 | 2004-09-21 | Process and finned tube for the thermal cracking of hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004015029A1 true WO2004015029A1 (en) | 2004-02-19 |
Family
ID=30128404
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/004827 WO2004015029A1 (en) | 2002-07-25 | 2003-05-08 | Method and ribbed tube for thermally cleaving hydrocarbons |
Country Status (22)
Country | Link |
---|---|
EP (2) | EP1525289B9 (en) |
JP (2) | JP4536512B2 (en) |
KR (1) | KR101023668B1 (en) |
CN (1) | CN100523133C (en) |
AT (1) | ATE526385T1 (en) |
AU (1) | AU2003227737A1 (en) |
BR (1) | BR0312919B1 (en) |
CA (1) | CA2493463C (en) |
DE (1) | DE10233961A1 (en) |
EA (1) | EA010936B1 (en) |
ES (1) | ES2374568T3 (en) |
HR (1) | HRP20050072A2 (en) |
IL (1) | IL166229A (en) |
MA (1) | MA27325A1 (en) |
MX (1) | MXPA05001070A (en) |
NO (1) | NO337398B1 (en) |
NZ (1) | NZ537827A (en) |
PL (1) | PL204769B1 (en) |
PT (1) | PT1525289E (en) |
RS (1) | RS20050060A (en) |
UA (1) | UA85044C2 (en) |
WO (1) | WO2004015029A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10611968B2 (en) | 2015-07-09 | 2020-04-07 | Sabic Global Technologies B.V. | Minimizing coke formation in a hydrocarbon cracker system |
GB2590363A (en) * | 2019-12-09 | 2021-06-30 | Paralloy Ltd | Internally profiled tubes |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PL2037202T3 (en) | 2006-07-05 | 2019-03-29 | Nippon Steel & Sumitomo Metal Corporation | Metal tube for thermal cracking reaction |
EP2408551A1 (en) * | 2009-03-17 | 2012-01-25 | Total Petrochemicals Research Feluy | Process for quenching the effluent gas of a furnace |
EP2813286A1 (en) * | 2013-06-11 | 2014-12-17 | Evonik Industries AG | Reaction tube and method for the production of hydrogen cyanide |
FR3033266B1 (en) * | 2015-03-05 | 2017-03-03 | Ifp Energies Now | COLLECTION ASSEMBLY OF A GASEOUS FLUID FOR RADIAL REACTOR |
JP6107905B2 (en) * | 2015-09-09 | 2017-04-05 | 株式会社富士通ゼネラル | Heat exchanger |
CN109072090B (en) * | 2016-04-12 | 2021-03-16 | 巴斯夫安特卫普股份有限公司 | Reactor for cracking furnace |
DE102016012907A1 (en) | 2016-10-26 | 2018-04-26 | Schmidt + Clemens Gmbh + Co. Kg | Deep hole drilling method and tool for a deep hole drilling machine and deep hole drilling machine |
DE102017003409B4 (en) | 2017-04-07 | 2023-08-10 | Schmidt + Clemens Gmbh + Co. Kg | Pipe and device for the thermal cracking of hydrocarbons |
EP3384981B1 (en) * | 2017-04-07 | 2024-03-06 | Schmidt + Clemens GmbH + Co. KG | Tube and device for the thermal splitting of hydrocarbons |
WO2018185167A1 (en) * | 2017-04-07 | 2018-10-11 | Schmidt + Clemens Gmbh + Co. Kg | Pipe and device for thermally cleaving hydrocarbons |
CA3062425C (en) * | 2017-05-05 | 2022-05-31 | Exxonmobil Chemical Patents Inc. | Heat transfer tube for hydrocarbon processing |
CA3079647A1 (en) * | 2017-10-27 | 2019-05-02 | China Petroleum & Chemical Corporation | Heat transfer enhancement pipe as well as cracking furnace and atmospheric and vacuum heating furnace including the same |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB969796A (en) | 1961-03-01 | 1964-09-16 | Exxon Research Engineering Co | Apparatus for heating fluids and tubes for disposal therein |
US4876065A (en) * | 1987-05-19 | 1989-10-24 | Vdm Nickel-Technologie Aktiengesellschaft | Corrosion-resisting Fe-Ni-Cr alloy |
DE4427859A1 (en) * | 1994-08-05 | 1995-10-26 | Siemens Ag | Tube with inner ribbing forming multi-hand thread |
DE19523280A1 (en) * | 1995-06-27 | 1997-01-02 | Gfm Gmbh | Forging machine for internal shaping of tubular workpieces |
US5950718A (en) | 1994-07-11 | 1999-09-14 | Kubota Corporation | Heat exchange tubes |
US20010001399A1 (en) * | 1996-07-25 | 2001-05-24 | Willi Kleemann | Austenitic nickel-chromium steel alloys |
EP1136541A1 (en) | 1997-06-10 | 2001-09-26 | ExxonMobil Chemical Patents Inc. | Pyrolysis furnace with an internally finned u-shaped radiant coil |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58132081A (en) * | 1982-01-08 | 1983-08-06 | Idemitsu Petrochem Co Ltd | Thermal cracking of hydrocarbon |
JPH11199876A (en) * | 1998-01-16 | 1999-07-27 | Kubota Corp | Thermal cracking pipe used for producing ethylene having coking-reducing performance |
-
2002
- 2002-07-25 DE DE10233961A patent/DE10233961A1/en not_active Withdrawn
-
2003
- 2003-05-08 AT AT03725176T patent/ATE526385T1/en active
- 2003-05-08 PL PL373967A patent/PL204769B1/en unknown
- 2003-05-08 CN CNB038178850A patent/CN100523133C/en not_active Expired - Lifetime
- 2003-05-08 RS YUP-2005/0060A patent/RS20050060A/en unknown
- 2003-05-08 EA EA200500258A patent/EA010936B1/en not_active IP Right Cessation
- 2003-05-08 CA CA2493463A patent/CA2493463C/en not_active Expired - Lifetime
- 2003-05-08 ES ES03725176T patent/ES2374568T3/en not_active Expired - Lifetime
- 2003-05-08 MX MXPA05001070A patent/MXPA05001070A/en active IP Right Grant
- 2003-05-08 WO PCT/EP2003/004827 patent/WO2004015029A1/en active Application Filing
- 2003-05-08 KR KR1020057001384A patent/KR101023668B1/en active IP Right Grant
- 2003-05-08 EP EP03725176A patent/EP1525289B9/en not_active Expired - Lifetime
- 2003-05-08 UA UAA200501718A patent/UA85044C2/en unknown
- 2003-05-08 PT PT03725176T patent/PT1525289E/en unknown
- 2003-05-08 NZ NZ537827A patent/NZ537827A/en not_active IP Right Cessation
- 2003-05-08 AU AU2003227737A patent/AU2003227737A1/en not_active Abandoned
- 2003-05-08 JP JP2004526658A patent/JP4536512B2/en not_active Expired - Lifetime
- 2003-05-08 EP EP10012045A patent/EP2298850A1/en not_active Withdrawn
- 2003-05-08 BR BRPI0312919-5A patent/BR0312919B1/en active IP Right Grant
-
2005
- 2005-01-11 IL IL166229A patent/IL166229A/en active IP Right Grant
- 2005-01-18 MA MA28048A patent/MA27325A1/en unknown
- 2005-01-24 HR HR20050072A patent/HRP20050072A2/en not_active Application Discontinuation
- 2005-01-28 NO NO20050493A patent/NO337398B1/en not_active IP Right Cessation
-
2010
- 2010-02-18 JP JP2010034129A patent/JP2010150553A/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB969796A (en) | 1961-03-01 | 1964-09-16 | Exxon Research Engineering Co | Apparatus for heating fluids and tubes for disposal therein |
US4876065A (en) * | 1987-05-19 | 1989-10-24 | Vdm Nickel-Technologie Aktiengesellschaft | Corrosion-resisting Fe-Ni-Cr alloy |
US5950718A (en) | 1994-07-11 | 1999-09-14 | Kubota Corporation | Heat exchange tubes |
DE4427859A1 (en) * | 1994-08-05 | 1995-10-26 | Siemens Ag | Tube with inner ribbing forming multi-hand thread |
DE19523280A1 (en) * | 1995-06-27 | 1997-01-02 | Gfm Gmbh | Forging machine for internal shaping of tubular workpieces |
US20010001399A1 (en) * | 1996-07-25 | 2001-05-24 | Willi Kleemann | Austenitic nickel-chromium steel alloys |
EP1136541A1 (en) | 1997-06-10 | 2001-09-26 | ExxonMobil Chemical Patents Inc. | Pyrolysis furnace with an internally finned u-shaped radiant coil |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10611968B2 (en) | 2015-07-09 | 2020-04-07 | Sabic Global Technologies B.V. | Minimizing coke formation in a hydrocarbon cracker system |
GB2590363A (en) * | 2019-12-09 | 2021-06-30 | Paralloy Ltd | Internally profiled tubes |
GB2590363B (en) * | 2019-12-09 | 2023-06-28 | Paralloy Ltd | Internally profiled tubes |
Also Published As
Publication number | Publication date |
---|---|
PT1525289E (en) | 2012-01-04 |
BR0312919B1 (en) | 2014-06-24 |
RS20050060A (en) | 2007-09-21 |
PL373967A1 (en) | 2005-09-19 |
DE10233961A1 (en) | 2004-02-12 |
MXPA05001070A (en) | 2005-10-05 |
EP2298850A1 (en) | 2011-03-23 |
NZ537827A (en) | 2007-04-27 |
IL166229A (en) | 2008-11-26 |
NO337398B1 (en) | 2016-04-04 |
KR20050052457A (en) | 2005-06-02 |
MA27325A1 (en) | 2005-05-02 |
JP2010150553A (en) | 2010-07-08 |
JP4536512B2 (en) | 2010-09-01 |
ATE526385T1 (en) | 2011-10-15 |
BR0312919A (en) | 2005-07-05 |
JP2005533917A (en) | 2005-11-10 |
EA200500258A1 (en) | 2005-08-25 |
PL204769B1 (en) | 2010-02-26 |
AU2003227737A1 (en) | 2004-02-25 |
KR101023668B1 (en) | 2011-03-25 |
UA85044C2 (en) | 2008-12-25 |
ES2374568T3 (en) | 2012-02-17 |
NO20050493L (en) | 2005-03-17 |
CA2493463A1 (en) | 2004-02-19 |
EA010936B1 (en) | 2008-12-30 |
IL166229A0 (en) | 2006-01-15 |
EP1525289B9 (en) | 2012-02-29 |
EP1525289B1 (en) | 2011-09-28 |
EP1525289A1 (en) | 2005-04-27 |
HRP20050072A2 (en) | 2005-08-31 |
CA2493463C (en) | 2013-01-15 |
CN1671824A (en) | 2005-09-21 |
CN100523133C (en) | 2009-08-05 |
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