WO2004009889A1 - Flat multifilament-yarn textile - Google Patents

Flat multifilament-yarn textile Download PDF

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Publication number
WO2004009889A1
WO2004009889A1 PCT/JP2003/009277 JP0309277W WO2004009889A1 WO 2004009889 A1 WO2004009889 A1 WO 2004009889A1 JP 0309277 W JP0309277 W JP 0309277W WO 2004009889 A1 WO2004009889 A1 WO 2004009889A1
Authority
WO
WIPO (PCT)
Prior art keywords
flat
woven fabric
multifilament yarn
fabric
filament
Prior art date
Application number
PCT/JP2003/009277
Other languages
French (fr)
Japanese (ja)
Inventor
Shuji Minato
Motohiro Kitagawa
Ryo Tohdo
Original Assignee
Teijin Fibers Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2002214953A external-priority patent/JP3895227B2/en
Priority claimed from JP2002216419A external-priority patent/JP2004060064A/en
Priority claimed from JP2002327949A external-priority patent/JP4065764B2/en
Application filed by Teijin Fibers Limited filed Critical Teijin Fibers Limited
Priority to CN038014491A priority Critical patent/CN1585841B/en
Priority to EP03741538.7A priority patent/EP1524343B1/en
Priority to US10/490,410 priority patent/US20050176323A1/en
Priority to CA2461551A priority patent/CA2461551C/en
Priority to KR1020047004204A priority patent/KR101017876B1/en
Publication of WO2004009889A1 publication Critical patent/WO2004009889A1/en

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/44Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
    • D03D15/46Flat yarns, e.g. tapes or films
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/28Cellulose esters or ethers, e.g. cellulose acetate
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/04Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
    • D10B2321/041Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polyvinyl chloride or polyvinylidene chloride
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/14Dyeability
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3033Including a strip or ribbon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • Y10T442/3089Cross-sectional configuration of strand material is specified
    • Y10T442/3114Cross-sectional configuration of the strand material is other than circular

Definitions

  • the present invention relates to a flat multifilament yarn woven fabric. More specifically, the present invention relates to a multifilament composed of a plurality of artificial single filaments having a flat cross-sectional shape, a force, and two or more constrictions on one side of the cross-sectional shape. Including thread
  • the present invention relates to a woven fabric having a soft feel and practically high water absorption, abrasion strength, and anti-see-through properties.
  • low-permeability textiles have been proposed in the fields of sports clothing and uniforms.
  • low-permeability fabrics include high-density fabrics using synthetic fibers such as polyester-polyamide, fabrics that have been coated with a resin or the like on the fabric surface, and fabrics that have been subjected to force rendering. It has been known.
  • Synthetic fibers such as polyester / polyamide are widely used in clothing and industrial applications due to their excellent physical and chemical properties.
  • polyester fibers have many excellent features such as strength, dimensional stability, and easy care.
  • many woven fabrics using synthetic fibers such as polyester have been proposed for a wide range of applications.
  • woven fabrics made of synthetic fibers such as polyester have the above-mentioned excellent properties, but generally have high transparency, and when they are used for clothing, clothing worn under them, such as underwear, can be seen through. The disadvantage is that it can be seen.
  • curtains and other textiles used in the interior field need to have both high anti-see-through properties (the property that no movement of objects or people in the room can be seen from the outside) and high light-transmitting and light-transmitting properties.
  • high anti-see-through properties the property that no movement of objects or people in the room can be seen from the outside
  • high light-transmitting and light-transmitting properties the property that no movement of objects or people in the room can be seen from the outside
  • the black light-shielding layer is laminated on the surface of the fabric and the above-mentioned light-shielding power is one, there is a problem that the room becomes dark and a heavy atmosphere due to poor lighting.
  • the mirror curtain has a problem that although it has high daylighting property, it has insufficient antireflection property, especially at night, and has a glittering luster due to a bright yarn.
  • the fabric made of synthetic fibers has a disadvantage that it is inferior in water absorbency, especially sweat absorbency, to fabrics made of natural fibers such as cotton.
  • a fabric is subjected to a water absorbing process using a water-repellent agent, but applications requiring even more excellent water absorbing and sweat absorbing properties, such as lining, sports clothing, and There are uniform clothing.
  • An object of the present invention is to have a feeling of high flexibility, water absorption and sweat absorption,
  • An object of the present invention is to provide a flat multifilament yarn woven fabric having a high abrasion strength, a moderate air permeability and a light transmissivity, and a high transparency preventing property.
  • the present invention is useful for the construction of a fiber material having an appropriate air permeability, a fiber material having a high anti-seepage property, a fiber material having a high water absorbing property and a sweat absorbing property, and / or a fiber material having a high abrasion strength.
  • the aim is to provide a flat multi-filament yarn fabric.
  • the above object can be achieved by the flat multifilament yarn woven fabric of the present invention.
  • the flat multifilament yarn woven fabric of the present invention contains a fiber-forming artificial polymer as a main component, and comprises a multifilament yarn composed of a plurality of artificial filaments having a flat cross-sectional shape, which is formed by warp and / or weft.
  • the formed two or more constrictions per one surface are formed substantially symmetrically with respect to the longitudinal center line, and are perpendicular to the longitudinal direction of the maximum longitudinal length (B) of the irregular cross section.
  • the cross-sectional flatness expressed by the ratio (B / C1) to the maximum width (C1) in the crossing direction is in the range of 2 to 6,
  • the fiber-forming artificial polymer is selected from polyester, polyamide, polyvinylidene chloride, polypropylene, regenerated cellulose, and cellulose acetate.
  • the ratio (C1ZC2) to (C2) is preferably 1.05 to 4.00.
  • the total fineness of the multifilament yarn is 30 to: L70dtex, and the single filament is The fineness is preferably 0.5 to 5 dtex.
  • the woven fabric preferably has a woven structure selected from a plain woven structure, a twill woven structure, and a satin woven structure.
  • the content of the multifilament yarn having the flat cross-sectional shape contained in the woven fabric is preferably 10 to: L00 mass%.
  • the force factor value is in the range of 1500 to 3500.
  • the multifilament yarn (A) has a burning number of 0 to 2500 TZm.
  • the air permeability of the woven fabric measured by JIS L 1096-1998, 6.27.1, Method A (Fragile-type testing machine method) is measured. , 5 mlZcm 2 ⁇ sec or less.
  • the air permeability is preferably in the range of 0.1 to 4. Oml / cm 2 ⁇ sec.
  • the water absorption rate of the woven fabric is measured by JIS L 1096-1998, 6.26.1, (2) B method (Piret method). However, it is preferable that it is 40 mm or more.
  • the abrasion strength of the woven fabric measured by JIS L 1096-1998, 6.17.1, (1) A_1 method (planar method) is reduced. It is preferable that the number is 50 times or more.
  • the low-permeability fiber material of the present invention includes the flat multifilament filament woven fabric according to the embodiment (1) ′ of the present invention.
  • the multifilament yarn contains 0.2% by mass or more of the matting agent, and the woven fabric has a cover factor in the range of 1300 to 3000.
  • the multifilament yarn preferably has a twist number of 0 to: LSOOTZm.
  • the water absorption rate of the woven fabric measured by the JIS L 1096-1998, 6.26.1, (2) B method (Pilet method)
  • the anti-see-through / sweat-absorbing fiber material of the present invention includes the flat multifilament yarn woven fabric according to the aspect (2) of the present invention.
  • the multifilament yarn contains 0 to 0.2% by mass of the matting agent, and the power factor of the woven fabric is in the range of 800 to 2000. .
  • the multifilament yarn has a twist number of 0 to 1000 Zm. Is preferred.
  • the see-through preventing fiber material of the present invention contains the flat multifilament yarn woven fabric of the embodiment (3) of the present invention.
  • FIG. 1 is an explanatory diagram showing an example of a cross-sectional shape of a flat multifilament yarn woven fabric used in the flat multifilament yarn woven fabric of the present invention.
  • FIG. 2 is used for the flat multifilament yarn woven fabric of the present invention.
  • FIG. 3 is an explanatory diagram showing another example of the cross-sectional shape of the flat multifilament.
  • FIG. 3 is an explanatory diagram showing another example of the cross-sectional shape of the flat multifilament used in the flat multifilament yarn fabric of the present invention. .
  • the inventors of the present invention provide a woven fabric comprising, as a warp and / or a weft, a multifilament made of a fiber-forming artificial polymer and having a plurality of filaments having a flat cross-sectional shape. 3 or more, preferably 4 or more, more preferably 4 to 6 bulges whose flat cross-sectional shape bulges out on both sides of the longitudinal center line in a direction outward from the longitudinal center line. Part, and two or more, preferably three or more, more preferably three to five, constricted parts formed between these bulging parts and facing the longitudinal center line.
  • the flat section of the birment is The cross-sectional flatness expressed by the ratio (BZ C1) of the maximum length (B) of the shape to the maximum value C1 in the direction crossing at right angles to this length direction is 2 to 6
  • BZ C1 the ratio of the maximum length (B) of the shape to the maximum value C1 in the direction crossing at right angles to this length direction
  • the inventors of the present invention believe that the plurality of constrictions formed on the flat surface of the flat multifilament develop a capillary phenomenon with respect to a liquid, and therefore the fabric of the present invention is exposed to water and sweat. On the other hand, it was found that they exhibited excellent water absorption and sweat absorption properties.
  • the inventors of the present invention have proposed that the plurality of bulges and constrictions formed on the peripheral surface of the flat multifilament reduce the frictional resistance of the peripheral surface of the flat multifilament as described above. As a result, it has been found that the woven fabric of the present invention has excellent wear strength.
  • the inventors of the present invention consider that the flat surface formed by a plurality of bulges and constrictions on the peripheral surface of the flat multifilament used in the woven fabric of the present invention has the following characteristics.
  • the transmitted light is scattered by reflection and refraction, thereby reducing the transparency without significantly reducing the light collection (transmission amount), and preventing the inside of the fabric from being seen through from the outside. I found that I could.
  • the inventor of the present invention provides the flat multifilament yarn of the present invention.
  • the flat multifilament yarn of the present invention can have air permeability, water absorption and sweat absorption, abrasion strength, see-through prevention properties, and the like. Has been found to be able to be appropriately adjusted, and thereby it is possible to provide a clothing material having these characteristics.
  • the present invention has been completed based on the above findings.
  • the flat multifilament yarn woven fabric of the present invention comprises a multifilament yarn comprising a plurality of artificial filaments having a flat cross-sectional shape, which contains a fiber-forming artificial polymer as a produced component, and comprises a warp yarn and a Z or weft yarn. It is a woven fabric to be included.
  • the shape of the cross section 1 of the single filament is perpendicular to its longitudinal center line with respect to its length. It has a relatively short width, that is, a flat shape.
  • cross section 1 shown in Fig. 1 three or more (four in Fig. 1) bulges per side protruding outward from the longitudinal center line on both sides of its longitudinal center line 2 3 and two or more (three in FIG. 1) constrictions 4 per side formed between the bulges 3 are formed symmetrically with respect to the longitudinal center line.
  • the cross-sectional flatness represented by the ratio (BZ C1) of the maximum length (B) in the longitudinal direction to the maximum width (C1) in the direction perpendicular to the longitudinal center direction is It is in the range of 2-6.
  • each flat single filament three or more bulging portions and two or more constrictions formed on one surface of the flat cross-sectional shape are opposite to the one surface of the flat cross-sectional shape.
  • the shapes and arrangement positions thereof are almost symmetrical with respect to the longitudinal center line of the flat cross-sectional shape.
  • the number of bulges is 3 or more per side as described above, preferably 4 or more, and more preferably 4 to 6 as described above. is there.
  • the number of constricted portions is two or more per side, preferably three or more, and more preferably three to five.
  • the cross-sectional flatness is 2 to 6, as described above, and preferably 3 to 5.
  • the frictional resistance on the periphery of the filament increases, and multifilament
  • the spread due to pressure welding at the intersection at the intersection of the courses is insufficient, it is difficult to control the resulting air permeability, the wear strength is insufficient, and the decrease in the constriction on the periphery of the filament is obtained.
  • the resulting fabric has insufficient water absorption and sweat absorption properties, and further has an insufficient light scattering effect on the periphery of the filament, resulting in an insufficient transparency preventing effect of the obtained fabric.
  • the cross-sectional flatness (B / C1) of the flat multifilament yarn in the cross section of a single filament is 2 to 6, as described above, and preferably 3 to 5. is there . If the cross-sectional flatness is less than 2, the filament and the bending resistance (rigidity) are increased, and the obtained woven fabric becomes insufficient in flexibility, so that a desired soft feeling cannot be obtained.
  • the cross-sectional flatness is less than 2, the spread of the multifilament in the woven fabric, particularly by press-welding at the weft intersection, becomes insufficient, and the gap between the weft yarns cannot be sufficiently reduced.
  • the size of the voids between the fibers cannot be made sufficiently small, it becomes difficult to control the air permeability of the obtained woven fabric to a desired value.
  • the ratio of the maximum width (C1) in the direction orthogonal to the longitudinal center line to the minimum value (C2) ( C1 / C2) is preferably from 1.05 to 4.00, more preferably from 1.10 to 2.50.
  • the above ratio (C1Z C2) is a parameter related to the depth of the constriction of the flat single filament.
  • FIGS. 2 and 3 each show another example of the cross-sectional shape of the flat single filament used for the flat multifilament yarn fabric of the present invention.
  • the cross section of the filament 1 shown in FIG. 2 has the same shape as the cross section shown in FIG. 1 on both sides of the longitudinal center line 2, but the cross section of the bulging portion 3 is elliptical. It is gentle like an arc along the long axis, so the constriction 4 is shallow.
  • the cross section of the filament 1 shown in FIG. 3 has four bulges and three constrictions on one side on both sides of its longitudinal center line.
  • the piece 3a is narrower in width and height than the other bulge, so the depth from the top of the bulge 3a to the valley bottom of the constriction 4a on both sides is the other constriction. It is shallower than the four parts.
  • the force factor of the flat multifilament yarn woven fabric of the present invention is as follows.
  • it is 800 to 3500, and can be appropriately set according to the characteristics and performance required of the woven fabric.
  • the force factor (CF) of a woven fabric is defined by the following equation.
  • DWp represents the total fineness (dtex) of the warp
  • MWp represents the warp weaving density (this Z2.54cm)
  • D f represents the total fineness (dtex) of the weft
  • M f represents the weaving density of the weft (this Z2.54cm).
  • the force factor (CF) of the flat multi-filament yarn fabric of the present invention is less than 800, the voids formed between the warp and the weft become large, and the air permeability of the obtained fabric is adjusted to a desired value. It becomes difficult to control and it is difficult to obtain high see-through prevention. If the force-per-factor (CF) exceeds 3500, the obtained woven fabric becomes insufficient in flexibility, and the (adopted light) transmittance becomes insufficient.
  • the fiber-forming artificial polymer used for forming the flat multifilament of the flat multifilament yarn woven fabric of the present invention is a fiber-forming synthetic polymer such as polyester, polyamide, polyvinylidene chloride, and the like. And fiber-forming semi-synthetic polymers such as cellulose acetate; and regenerated polymers such as regenerated cellulose.
  • fiber-forming thermoplastic polymers such as polyesters (eg, polyethylene terephthalate and trimethylene terephthalate), which can be produced by melt spinning, are considered. ), Polyamide (For example, nylon 6, nylon 66, etc.), polyvinylidene chloride, polypropylene and the like.
  • the fiber-forming artificial polymer may include an anti-glazing agent (for example, titanium dioxide, etc.), a fine pore-forming agent (for example, a metal salt of organic sulfonic acid, etc.), a cationic dye dyeing agent (for example, Isophthal Acid sulfonium salts, etc.), antioxidants (eg, hindered phenol compounds, etc.), heat stabilizers, flame retardants (eg, diantimony trioxide), fluorescent brighteners, coloring agents, antistatic agents (eg, sulfonic acid metal salts) Etc.), one or more of a moisture absorbent (eg, polyoxyalkylene alcohol) and an antibacterial agent may be added as additives.
  • an anti-glazing agent for example, titanium dioxide, etc.
  • a fine pore-forming agent for example, a metal salt of organic sulfonic acid, etc.
  • a cationic dye dyeing agent for example, Isophthal Acid sulfonium salts, etc.
  • the total fineness of the multifilament yarns used in the woven fabric of the present invention and the latitude of the flat single multifilament are not particularly limited as long as the target woven fabric of the present invention can be obtained. , 30 to: 170 dt ex, more preferably 50 to: LOO dt ex, and the single filament fineness is preferably 0.5 to 5 dt ex, more preferably 1 to 5 dt ex. ⁇ 4 dt ex.
  • the number of twists is not particularly limited as long as the target woven fabric is obtained, and depends on the use and required characteristics of the target woven fabric. In general, it is preferably 0 to 2500 T / m, and more preferably 0 to 600 TZm.
  • the multifilament yarn used for the woven fabric of the present invention has been subjected to air crimping such as false twist crimping, Taslan crimping, and interlacing as long as the target fabric of the present invention is obtained. May
  • the warp and / or the weft constituting the woven fabric are formed of a plurality of single filaments having the flat cross-sectional shape. It is composed of filament yarn. That is, both the warp and the weft may be constituted by the flat multifilament yarn, or only one of the warp and the weft is constituted by the flat multifilament yarn. The other one may be composed of a yarn different from the flat multifilament yarn.
  • the heterogeneous yarn may be any of a monofilament yarn, a multifilament yarn and a spun yarn, and these have a special function, for example, an antistatic property, a glittering property, and the like. Is also good.
  • the content of the flat multifilament is preferably from 10 to 100% by mass, more preferably from 20 to 100% by mass, based on the total mass of the woven fabric. 100% by mass is, preferably in the al 40-100 mass 0/0.
  • the flat multifilament for a fabric according to the present invention is a spinneret for flat filaments, for example, a plurality of dischargers having a cross-sectional shape described in JP-A-56-107044, page 5, FIG. It can be manufactured using a spinneret having an outlet.
  • the flat multifilament yarn woven fabric of the present invention can be manufactured by a normal weaving method using the flat multifilament yarn manufactured as described above as a warp and / or a weft. It can be dyed and finished in the usual way.
  • the flat multifilament yarn is a polyester yarn
  • the woven fabric can be subjected to a weight reduction treatment.
  • a water-absorbing enhancement treatment for example, a treatment for applying or impregnating a water-absorbing agent such as an anion-based hydrophilic polymer compound
  • a water-repelling treatment for example, a water-repelling agent such as a fluorine compound
  • At least one of the following treatments: coating or impregnating), ultraviolet shielding treatment (for example, dispersion method of metal oxide ultrafine particles), antistatic treatment, deodorant treatment, insect repellent treatment, and phosphorescent treatment. May be applied sequentially
  • the fineness of the warp and the warp / weft density are controlled such that the force factor (CF) of the woven fabric is in the range of 1500 to 3500.
  • the preferable force factor (CF) of the woven fabric is 1500 3000, and more preferably 1500 2500.
  • the number of twists of the flat multifilament yarn is preferably 02,500 TZm, more preferably 0 600 TZm, and further preferably 0 TZm. That is, it is untwisted.
  • the flat multifilament yarn woven fabric of the embodiment (1) of the present invention preferably has a low air permeability of 5 ml / cm 2 , sec or less, more preferably 4 ml / cm 2 ⁇ sec or less. More preferably, it is 0.13 ml / cm 2 .sec.
  • This air permeability is measured by the JIS L 1096-1998 6.27.1 A method (Fragile type testing machine method).
  • the flat multifilament yarn woven fabric has a water absorption rate measured by JIS L 1096-1998 6.26.1 (2) B method (Pireck method), It is preferably 40 or more, more preferably 50 70 mm, and the wear strength measured by the JIS L 1096-1998 6.17.1 (1) A- It is preferably at least 50 times, more preferably at least 80 times, even more preferably at least 100 times.
  • the cover factor (CF) of the woven fabric is less than 1500, the area of the gap formed by the warp and the weft yarns And the resulting fabric may have excessively high air permeability (for example, more than 5 ml / cm 2 -sec), and may have insufficient water absorption / perspiration and abrasion strength. If the force factor (CF) exceeds 3500, the warp and the weft are in close contact with each other, resulting in insufficient flexibility of the obtained woven fabric and increased bending resistance, resulting in a poor feeling of the woven fabric. In addition, the wear strength may be insufficient.
  • the flat multifilament yarn woven fabric according to the aspect (1) of the present invention which has a force par factor (CF) of 1500 to 3500
  • the flat multifilament yarn constituting the warp and the knit or the weft is formed by a weft Due to the contact pressure at the intersection, the single filaments that are in contact with each other slide on each other at their contact surfaces, and the yarn is flattened and spreads laterally, reducing the area of the yarn gap and reducing the woven fabric.
  • the air permeability decreases.
  • the flat multifilament yarn woven fabric of the embodiment (1) of the present invention preferably has a low air permeability of 5 ml / cm 2 .sec or less.
  • the flattening of the yarn lowers the bending resistance of the obtained woven fabric, improves its flexibility, and shows a soft feeling.
  • the single filament peripheral surface of the flat multifilament yarn of the present invention three or more bulges per one surface extending along the longitudinal direction and two or more constrictions formed between the bulges are provided.
  • the peripheral surface of the filament is roughened, and even if the single filaments are in contact with each other, especially when they are pressed against each other at the intersection of the warp and weft, the contact area between the single filaments is increased. It is small, so the surface frictional resistance is small, which contributes to the improvement of the flexibility of the fabric.
  • the flat multifilament yarn woven fabric according to the above aspect (1) of the present invention has a feeling excellent in flexibility, high water absorption / perspiration, and abrasion strength. It is useful as a low-breathable fiber material for sports clothing for boys and girls, folk costumes such as uniforms and toves, underwear, lining, hats and umbrellas.
  • the multifilament yarn is 0.2% by mass or more, preferably 0.4 to 3.5% by mass. /. And more preferably 1.0 to 2.5 mass 0 /.
  • the cover factor (CF) of the fabric is in the range of 1300 to 3000, preferably 1400 to 2500.
  • composition and type of the matting agent contained in the multifilament of the flat multifilament yarn woven fabric of the embodiment (2) of the present invention are not particularly limited as long as the desired woven fabric can be obtained.
  • Inorganic fine particles composed of one or more kinds such as parium sulfate can be used. If the content of the anti-glare agent is less than 0.2 mass relative to the mass of the multifilament, the light reflectance of the obtained multifilament yarn becomes insufficient, and the obtained woven fabric has a sufficient In some cases, it may not be possible to exhibit a high degree of fluoroscopy prevention. However, if the content of the antiglare agent exceeds 7% by mass, the systemability of the obtained polymer composition may be unstable.
  • cover factor (CF) of the woven fabric of the embodiment (2) of the present invention is less than 1300, the gap formed between the warp and the weft becomes large, and the see-through preventing property of the obtained woven fabric becomes insufficient. If the cover factor (CF) exceeds 3,000, the woven fabric obtained may have insufficient flexibility and the texture may be unsatisfactory.
  • the force factor (CF) of the woven fabric when the woven structure has a plain woven structure, is preferably in the range of 1400 to 1800, and more preferably 1500 to 1700. It is. , Further, when the woven structure of the woven fabric of the embodiment (2) of the present invention has a twill woven structure, the force factor (CF) of the woven fabric is preferably in the range of 1900 to 2400, and more preferably. 2000-2300.
  • the number of twists of the multifilament yarn used for the fabric of the embodiment (2) of the present invention is preferably 0 to 1500 TZm. And more preferably 0 to 600 T / m. More preferably, the number of twists is OT / m, that is, no twist.
  • the degree of see-through prevention is determined according to JIS Z 8729-1994, L * a * b * color system, and the test sample is placed on a white plate.
  • the degree of prevention of fluoroscopy is preferably A L15 or less, more preferably 13.5 or less, and further preferably 10 to 13.
  • the degree of see-through prevention ⁇ L is higher than 15, the see-through preventing property of the woven fabric may be insufficient for practical use.
  • the water absorption of this woven fabric measured by the JIS L 1096-1998, 6.26.1, (2) B method (Pilet method)
  • the speed is preferably 40 mm or more, preferably 45 mm or more, and more preferably 50 to 70 mm.
  • the water absorption speed is less than 40 mm, the water absorption and sweat absorption of the fabric may be insufficient for practical use.
  • the cross-sectional shape of a single filament constituting the multifilament yarn is as follows. Since it is flat and has three or more bulges on one side and two or more constrictions formed between them, the mutual friction resistance of the single filaments that are in contact with each other is small. Because of the slipperiness, when pressure is applied to the multifilament yarn, the single filament is easily displaced at the contact surface, the yarn spreads flatly, and the single filament spreads that flat. In a plane, they can be in close contact with each other and have a small gap between the yarns, so that the amount of light transmission can be reduced.
  • this single filament contains 0.2% by mass or more of the matting agent, it is possible to reduce the light transmittance of the obtained woven fabric and diffusely reflect the light beam projected toward the woven fabric.
  • the plurality of bulges and constrictions formed on the flat peripheral surface of the single filament can roughen the flat peripheral surface, scatter light, and prevent see-through.
  • the flattening and spreading of the flat multifilament yarn at the intersection of the warp and weft of the woven fabric can soften the intersection and soften the texture of the woven fabric.
  • the constriction extending in the longitudinal axis direction of the peripheral surface of the single filament can exhibit a high water absorption rate and a high water absorption rate by exhibiting a capillary phenomenon against water or sweat. .
  • the flat multifilament yarn woven fabric according to the aspect (2) of the present invention is a fiber material used for applications requiring high antireflection property and sweat-absorbing property, for example, a fiber for lining, sports clothing, uniform clothing and the like. It is useful as a material.
  • the artificial filament of the multifilament yarn contains 0 to 0.2% by mass of the matting agent, and the cover factor (CF ) Is in the range of 800 to 2000.
  • the content of the anti-glare agent contained in the artificial filament is as described above.
  • the antiglare agent can be selected from conventional antiglare agents such as titanium dioxide and barium sulfate. If the content of the anti-glare agent exceeds 0.2% by mass, in the preferred use of the fabric of the embodiment (3) of the present invention, for example, in a curtain, the light transmittance becomes insufficient, and therefore, the lighting property is unsatisfactory. It may be something like that.
  • the number of twists of the flat multifilament yarn is preferably from 0 to 1000 T / m, more preferably from 0 to 200 TZm and no twist. (0T / m) is more preferable.
  • the force factor (CF) of the flat multifilament yarn woven fabric of the embodiment (3) of the present invention is 800 to 2000, preferably 900 to 1800, and more preferably 1000 to 1800. Is more preferred.
  • the force factor (CF) is less than 800, the gap between the warp and the weft becomes large in a preferable use of the flat multifilament yarn woven fabric of the embodiment (3) of the present invention, for example, in a curtain, and the obtained woven fabric
  • the method for preventing see-through is insufficient. If it exceeds 2000, the lighting may be insufficient.
  • the light transmittance (%) can be calculated by subtracting the light blocking ratio (%) of the woven fabric from 100 (%). When the light transmittance is less than 10%, the preferred use of the obtained fabric is
  • lighting may be insufficient. If the light transmittance exceeds 70%, the resulting fabric may not be sufficiently transparent.
  • the flat multifilament yarn woven fabric of the embodiment (3) of the present invention is preferably dyed and finished to be colorless (white) or light to medium color.
  • the type and amount of dye used for dyeing may be appropriately selected according to the use of the obtained fabric and the required performance.
  • the flat multifilament yarn woven fabric in the flat multifilament yarn woven fabric, the flat multifilament yarn is flattened by the contact pressure at the intersection of the warp and the weft, and the single filament is woven.
  • the laminations are close to each other on the deviated plane, forming a dense structure. Therefore, the gap between the warp and the weft is reduced, and the amount of light transmitted through the gap is reduced. In addition, a small amount of light transmitted through the gap causes diffraction in the gap, and adjacent transmitted lights interfere with each other to improve the effect of preventing see-through.
  • the filament circumference Irregular reflection of light and refraction of light transmitted through the filament increase, and thus the obtained woven fabric can exhibit an excellent effect of preventing see-through without reducing the amount of collected light.
  • the flat multifilament yarn woven fabric of the embodiment (3) of the present invention also has a soft feeling, low bending resistance and air permeability, as well as high abrasion strength and water absorption / perspiration, similarly to the other embodiments. It shows the nature.
  • the flat multifilament yarn woven fabric of the embodiment (3) of the present invention is useful as an anti-transparent fiber material for intellectuals such as curtains, roll blinds, and partitions. is there.
  • Example The present invention is further described by the following examples. However, these examples do not limit the scope of the present invention.
  • Polyethylene terephthalate resin was pierced into a spinneret and 30 melt spinning holes with a shape corresponding to the filament cross-sectional shape shown in Fig. 1 (4 circles per side on both sides of the longitudinal center line) (With an arc-shaped bulge and three constrictions formed between them) at a spinning temperature of 300 ° C.
  • the extruded filamentary melt stream is taken off at a take-off speed of 4000 mZ while cooling and solidifying, and the obtained unstretched multifilament is immediately taken up at a temperature of 97 ° C without winding up.
  • the film was drawn at a draw ratio of 1.3 to prepare a drawn multifilament yarn having a yarn count force S of 84 dtex / 30 filaments.
  • This stretched multifilament has a cross-sectional shape as shown in Fig. 1, its cross-sectional flatness is 3.2, and the value of the ratio C1 / C2 in the filament cross-sectional width is 1.
  • the flat multifilament yarn is used as a warp and a weft while being untwisted.
  • Warp density 101 yarns / 2.54 cm
  • the finished flat woven fabric was subjected to the following test.
  • the air permeability of the test fabric was measured according to JISL 1096-1998, 6.27.1, Method A (Frazil-type testing machine method).
  • the wear strength of the test fabric was measured by the JIS L 1096-1998, 6.17.1, (1) A-1 method (plane method).
  • the water absorption rate of the test fabric was measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrek method).
  • Table 1 shows the evaluation results.
  • Example 1 In the same manner as in Example 1, a flat multifilament yarn flat woven fabric was manufactured and tested. However, in the cross-sectional shape of the flat filament, the number of arc-shaped bulges per side was set to three, the number of constrictions was set to two, and the flatness of the cross-section (BZC1) was 3.2 with respect to the longitudinal center line. / C2 is set to 1.2. The force per factor (CF) of the obtained plain fabric was 1782. Table 1 shows the test results. Comparative Example 1
  • a multifilament yarn flat woven fabric was manufactured and tested in the same manner as in Example 1. However, the cross-sectional shape of the filament was changed to a circle.
  • the strength factor (CF) of the obtained plain fabric was 1782. Table 1 shows the test results.
  • a polyethylene terephthalate resin containing 2.5% by mass of titanium dioxide was used as an anti-glare agent. 30 pieces of this resin were punched into the spinneret and had a shape corresponding to the filament cross-sectional shape shown in Fig. 1.
  • a spinning temperature of 300 ° C. through a melt spinning hole (having four arc-shaped bulges on each side and three constrictions formed therebetween) on both sides of the longitudinal center line. Do not cool and solidify the extruded
  • the undrawn multifilament was drawn at a drawing speed of 97 m / min and immediately stretched at a temperature of 97 ° C at a draw ratio of 1.3 without winding, and the yarn count was 84 dtex / 30 filament.
  • the drawn multifilament yarn of the fiber was prepared.
  • This drawn multifilament had a cross-sectional shape as shown in FIG. 1, the cross-sectional flatness was 3.2, and the value of the ratio C1 / C2 in the cross-sectional width of the filament was 1.2.
  • the multifilament yarn is used as a warp and a weft while being untwisted.
  • the above woven fabric was subjected to the following test.
  • Example 1 the water absorption rate of the test fabric was measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrex method).
  • Table 2 shows the evaluation results.
  • Example 3 In the same manner as in Example 3, a flat multifilament yarn flat woven fabric was manufactured and tested. However, in the cross-sectional shape of the flat filament, the number of liquid swelling portions per side was set to 3 and the number of constrictions was set to 2 per side, and the cross-sectional flatness (BZC1) was 3.2, and the ratio was C1ZC2. Was changed to 1.2. The force per factor (CF) of the obtained plain fabric was 1,700. Table 2 shows the test results.
  • a multi-filament yarn flat woven fabric was manufactured in the same manner as in Example 3. The test was performed. However, the cross-sectional shape of the filament was changed to a circle.
  • the cover factor (CF) of the obtained plain fabric was 1,700.
  • Table 2 shows the test results.
  • the drawn multifilament yarn having a yarn count of 84 dt exZ 30 filament was drawn at a magnification of 1.3.
  • This drawn multifilament has a cross-sectional shape as shown in Fig. 1, its cross-sectional flatness is 3.2, and the value of the ratio C1Z C2 in the filament cross-sectional width is 1.2.
  • Fig. 1 The drawn multifilament yarn having a yarn count of 84 dt exZ 30 filament was drawn at a magnification of 1.3.
  • This drawn multifilament has a cross-sectional shape as shown in Fig. 1, its cross-sectional flatness is 3.2, and the value of the ratio C1Z C2 in the filament cross-sectional width is 1.2.
  • the multifilament yarn is used as warp and weft without twisting.
  • Warp density 63 yarns / 2.54cm
  • the flat multifilament plain woven fabric was subjected to the following test.
  • the test fabric was subjected to the light-shielding rate (%) measurement according to JI SL 1055-1987, 6.1, Method A (I, illuminance: 100, 0OOlx), and from the obtained light-shielding rate (%), the following formula was used.
  • the light transmittance (%) was calculated from the equation.
  • An object to be seen through (color: red, shape: rectangular parallelepiped, dimensions: 15cm x 7cm x 7cm) is placed 20cm away from one surface of the test sample in a room with an illuminance of 700 lx using an 80W fluorescent lamp for indoor use. Position, and place the eye of the article observer in an outdoor location (daylight, illuminance 100,000 lx) 30 cm away from the other surface of the fabric to be tested. The following four levels were used to evaluate the degree of daytime visibility of the article when the article was seen through a woven fabric.
  • Night fluoroscopy prevention The nighttime perspective prevention was tested in the same manner as the daytime perspective prevention test method. However, the article viewer was located outside the room at night (illuminance: 0.2 lx).
  • Table 3 shows the results of a test in which the degree of nighttime fluoroscopy prevention was evaluated in four stages, as in the case of daytime.
  • Example 5 In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
  • Example 5 In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
  • the weaving structure of the plain woven fabric was changed to a warp density: 112 / 2.54 cm, a weft density: 74 / 2.54 cm, and the force factor (CF) was changed to 1800.
  • Example 5 In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
  • Example 5 In the same manner as in Example 5, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The resulting fabric had a power factor of 1,000. Table 3 shows the test results.
  • a multifilament yarn flat woven fabric was manufactured and tested in the same manner as in Example 5. However, the cross-sectional shape of the filament was changed to a circle.
  • the cover factor (CF) of the obtained plain fabric was 1,000. Table 3 shows the test results.
  • Example 6 In the same manner as in Example 6, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The resulting plain weave had a power factor (CF) of 880. Table 3 shows the test results.
  • Example 7 In the same manner as in Example 7, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The cover factor (CF) of the obtained plain fabric was 1,800. Table 3 shows the test results.
  • the slippage between the single filaments is good due to the special cross-sectional shape of the single filament, and the contact pressure at the intersection between the warp and the weft is good. Since the multifilament yarns are flattened and spread, and the gaps between the yarns are reduced, the air permeability can be appropriately controlled, and the obtained fabric has high abrasion strength, and water absorption and sweat absorption. It is excellent in light transmittance, and can diffract and diffuse the incident light without remarkably lowering the light transmittance, thereby lowering the transparency.
  • the flat multifilament yarn woven fabric of the present invention is useful as a low-permeability fiber material, a see-through preventing fiber material, a water-absorbing / sweat-absorbing fiber material, and a light-collecting / see-through preventing fiber material. .

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

Flat multifilament-yarn textile having excellent characteristics of low air permeability, show-through prevention capability and/or water/sweat-absorbing capability is textile including multifilament yarns each of which is formed of plural artificial filaments as the warp and weft and has a flat cross-sectional shape. On both sides of the longitudinal centerline in the flat cross section, at least more than three swollen portions per one side, outwardly swollen from the longitudinal centerline, and more than two constricted portions per one side, formed between the swollen portions, are formed substantially symmetrical with respect to the longitudinal centerline. A cross-sectional flatness expressed by a ratio (B/C1) of a length (B) in the longitudinal centerline to a maximum width (C1) in the direction perpendicular to the centerline direction is within a range from 2 to 6 and has a cover factor of 800 to 3,500 as the textile as a whole.

Description

明 細 書 . 偏平マルチフィラメ ント糸条織物  Description: Flat multifilament yarn fabric
技術分野 Technical field
本発明は、 偏平マルチフィラメ ント糸条織物に関するものである 。 更に詳しく述べるならば、 本発明は、 偏平な断面形状を有し、 力、 つ前記断面形状の片面当り 2個以上のくびれ部を有する、 複数本の 人造単フィ ラメ ントから構成されたマルチフィ ラメ ント糸条を含み The present invention relates to a flat multifilament yarn woven fabric. More specifically, the present invention relates to a multifilament composed of a plurality of artificial single filaments having a flat cross-sectional shape, a force, and two or more constrictions on one side of the cross-sectional shape. Including thread
、 柔軟な風合と、 実用上高い吸水性、 摩耗強さ及び透視防止性とを 有する織物に関するものである。 背景技術 The present invention relates to a woven fabric having a soft feel and practically high water absorption, abrasion strength, and anti-see-through properties. Background art
従来より、 スポーツ衣料やユニフォームなどの分野で低通気度織 物が多数提案されている。 そして、 かかる低通気度織物としては、 ポリエステルゃポリ アミ ドなどの合成繊維を用いた高密度織物や、 織物表面に樹脂などのコーティング加工を施したもの、 さらには力 レンダー加工を施したものなどが知られている。  Many low-permeability textiles have been proposed in the fields of sports clothing and uniforms. Examples of such low-permeability fabrics include high-density fabrics using synthetic fibers such as polyester-polyamide, fabrics that have been coated with a resin or the like on the fabric surface, and fabrics that have been subjected to force rendering. It has been known.
しかしながら、 これら高密度織物や、 織物表面にコーティ ング加 ェゃカレンダー加工を施したものは、 通常風合いが硬く、 また、 織 物表面の摩耗に対する強度 (耐摩耗性) が低く、 その改善が求めら れていた。  However, these high-density woven fabrics and woven fabrics that have been subjected to coating and calendering usually have a hard texture and low strength (abrasion resistance) against abrasion of the woven fabric surface. Had been taken.
またポリエステルゃポリアミ ドなどの合成繊維は、 その優れた物 理的及び化学的特性によ り衣料用から産業用へと広い範囲に用いら れている。 特に、 ポリ エステル繊維は強度、 寸法安定性、 イージー ケア一性等多くの優れた特徴を備えている。 このため、 ポリエステ ルなどの合成繊維を用いた織物が、 広い用途に多数提案されている しかしながら、 ポリ エステルなどの合成繊維からなる織物は、 前 記の優れた性質を有する反面、 一般に透明度が高く、 これを衣料に 用いた場合、 その下に着用されている衣料、 例えば下着が透けて見 えるという欠点がある。 Synthetic fibers such as polyester / polyamide are widely used in clothing and industrial applications due to their excellent physical and chemical properties. In particular, polyester fibers have many excellent features such as strength, dimensional stability, and easy care. For this reason, many woven fabrics using synthetic fibers such as polyester have been proposed for a wide range of applications. However, woven fabrics made of synthetic fibers such as polyester have the above-mentioned excellent properties, but generally have high transparency, and when they are used for clothing, clothing worn under them, such as underwear, can be seen through. The disadvantage is that it can be seen.
合成繊維織物の上記問題点を解決する手段と しては、 合成繊維中 に、 酸化チタンなどの無機微粒子を練り込むことが知られている。 この手段によ り、 繊維自身の不透明性、 又は透視防止性は向上する けれども、 経糸と緯糸との間に形成される空隙を通る光の透過を防 止するためには、 織物密度を密にする必要があり、 このよ う にする と得られる織物の柔軟性が低下するという問題を生ずる。  As a means for solving the above-mentioned problems of the synthetic fiber fabric, kneading inorganic fine particles such as titanium oxide into synthetic fibers is known. By this means, the opacity or the see-through prevention of the fiber itself is improved, but in order to prevent the transmission of light through the gap formed between the warp and the weft, the density of the fabric is increased. In such a case, there is a problem that the flexibility of the obtained fabric is reduced.
さらに、 カーテンなどのインテリア分野に用いられる織物におい て、 透視防止性 (外部から室内の物品や人の動きがみえないという 性質) と、 採光性光透過性とが、 ともに高いことが要求されるが、 この二つの特性を、 一般的には、 両立させることがきわめて困難で める。  In addition, curtains and other textiles used in the interior field need to have both high anti-see-through properties (the property that no movement of objects or people in the room can be seen from the outside) and high light-transmitting and light-transmitting properties. However, it is generally very difficult to reconcile these two characteristics.
このため、 通常、 室内側には厚手のドレープカーテン、 窓側には 薄手のレースカーテンを配し、 夜間は厚手の ドレープカーテンを閉 め、 昼間は透視防止性と採光性との両方を得るために薄手のレース カーテンを閉めておく ことが一般的に行われている。 しかし、 一般 に厚手の ドレープカーテンは透視防止性は優れているが採光性が乏 しく、 他方、 薄手のレースカーテンでは、 夜間はもとよ り、 昼間に おいても透視防止性が十分でなく、 その改善が望まれていた。  For this reason, usually thick drape curtains are placed on the indoor side, thin lace curtains are placed on the window side, and the thick drape curtains are closed at night, and in order to obtain both anti-transparency and daylighting during the day. It is common practice to keep light lace curtains closed. However, in general, thick drape curtains have good see-through prevention but poor lighting, while thin race curtains do not have sufficient see-through prevention not only at night but also during the day. The improvement was desired.
この問題を解決するために、 例えば、 酸化チタンなどの艷消し剤 を含んだポリエステル繊維と、 黒原着ポリエステル繊維とを交織す ることによ り得られ、 光を反射 · 吸収するこ とのできる遮光カーテ ン (例えば、 特許第 3167586号公報) 、 又は生地の片面又は両面に 、 光輝を有する糸条が配置されるように編織成し、 光沢のある面に 光があたると、 その散乱光によ り外部から内側への透視をさまたげ るが、 採光性及び通気性を損う ことのないミラーカーテン (例えば 特開 2000— 237035号公報) 、 並びに布帛表面に黒色の遮光層を積層 することによ り遮光すること (例えば、 実開昭 62— 113787号公報) などが提案されている。 In order to solve this problem, for example, it is obtained by interweaving a polyester fiber containing an anti-glazing agent such as titanium oxide and a black-dyed polyester fiber so that light can be reflected and absorbed. Shading curtain (for example, Japanese Patent No. 3167586), or on one or both sides of the fabric When the shiny surface is illuminated by light, the scattered light hinders the see-through from outside to inside, but impairs lighting and ventilation. There are proposals for mirror curtains (for example, Japanese Patent Application Laid-Open No. 2000-237035) that do not produce noise, and for shielding light by laminating a black light-shielding layer on the surface of the fabric (for example, Japanese Utility Model Application Laid-Open No. 62-113787). Have been.
しかし、 布帛表面に黒色遮光層を積層したもの、 及び前記遮光力 一テンにおいては、 採光性が悪いために、 室内が暗く、 重苦しい雰 囲気になるという問題があっ 。 また前記ミラーカーテンにおいて は、 採光性は高いけれども、 特に夜間において、 透視防止性が十分 でなく、 さらには光輝光糸条によるぎらついた光沢があるという問 題があった。  However, in the case where the black light-shielding layer is laminated on the surface of the fabric and the above-mentioned light-shielding power is one, there is a problem that the room becomes dark and a heavy atmosphere due to poor lighting. In addition, the mirror curtain has a problem that although it has high daylighting property, it has insufficient antireflection property, especially at night, and has a glittering luster due to a bright yarn.
従って、 採光性を損う ことなく優れた透視防止性の高い実用的織 物は未だ提供されていない。  Therefore, there has not yet been provided a practical woven material that has excellent anti-reflective properties without impairing the lighting property.
さらに、 合成繊維からなる織物には、 綿などの天然繊維からなる 織物に比較して、 吸水性、 特に、 吸汗性に劣るという欠点があった 合成繊維織物の吸水性、 特に吸汗性を増進する手段としては、 親 水化剤を用いて、 織物に吸水加工を施すことが知られているが、 さ らに優れた吸水性及び吸汗性が求められる用途、 例えば裏地、 スポ 一ッ衣料、 及びユニホーム衣料などがある。  In addition, the fabric made of synthetic fibers has a disadvantage that it is inferior in water absorbency, especially sweat absorbency, to fabrics made of natural fibers such as cotton. As a means, it is known that a fabric is subjected to a water absorbing process using a water-repellent agent, but applications requiring even more excellent water absorbing and sweat absorbing properties, such as lining, sports clothing, and There are uniform clothing.
そこで、 柔軟な風合と、 高い透視防止性と、 優れた吸水性及び吸 汗性を有する人造繊維織物、 特に合成繊維織物の提供が、 強く望ま れている。 発明の開示  Therefore, there is a strong demand for artificial fiber woven fabrics, particularly synthetic fiber woven fabrics, which have a soft feeling, high anti-transparency properties, and excellent water and sweat absorption properties. Disclosure of the invention
本発明の目的は、 柔軟性の高い風合を有し、 吸水性及び吸汗性、 摩耗強さが高く適度の通気性、 及び透光性と、 高い透視防止性を有 する偏平マルチフィ ラメント糸条織物を提供することにある。 An object of the present invention is to have a feeling of high flexibility, water absorption and sweat absorption, An object of the present invention is to provide a flat multifilament yarn woven fabric having a high abrasion strength, a moderate air permeability and a light transmissivity, and a high transparency preventing property.
さらに本発明は、 適度の通気度を有する繊維材料、 高い透視防止 性を有する繊維材料、 高い吸水性及び吸汗性を有する繊維材料、 及 び/又は高い摩耗強さを有する繊維材料の構成に有用な偏平マルチ フィ ラメ ン ト糸条織物を提供しょう とするものである。  Furthermore, the present invention is useful for the construction of a fiber material having an appropriate air permeability, a fiber material having a high anti-seepage property, a fiber material having a high water absorbing property and a sweat absorbing property, and / or a fiber material having a high abrasion strength. The aim is to provide a flat multi-filament yarn fabric.
上記目的は、 本発明の偏平マルチフィラメ ン ト糸条織物によって 達成することができる。  The above object can be achieved by the flat multifilament yarn woven fabric of the present invention.
本発明の偏平マルチフィラメント糸条織物は、 繊維形成性人造重 合体を主成分と して含み、 偏平な断面形状を有する複数本の人造フ イラメントからなるマルチフィラメント糸条を、 経糸及び/又は緯 糸として含む織物であって、  The flat multifilament yarn woven fabric of the present invention contains a fiber-forming artificial polymer as a main component, and comprises a multifilament yarn composed of a plurality of artificial filaments having a flat cross-sectional shape, which is formed by warp and / or weft. A woven fabric containing as a yarn,
前記人造フィラメ ントの偏平断面において、 その長手中心線の両 側に、 前記長手中心線の外側に向って膨出している片面当り 3個以 上の膨出部と、 これら膨出部の間に形成された片面当り 2個以上の くびれ部とが、 前記長手中心線に関してほぼ対称に形成されており 、 前記異形断面の、 長手最大長さ (B ) の、 この長さ方向に直角を なして交差する方向における最大幅 (C1) に対する比 (B / C1) に よ り表される断面偏平度が 2〜 6の範囲内にあり、  In the flat cross section of the artificial filament, on each side of the longitudinal center line, at least three bulging portions per side bulging outward from the longitudinal center line, and between these bulging portions The formed two or more constrictions per one surface are formed substantially symmetrically with respect to the longitudinal center line, and are perpendicular to the longitudinal direction of the maximum longitudinal length (B) of the irregular cross section. The cross-sectional flatness expressed by the ratio (B / C1) to the maximum width (C1) in the crossing direction is in the range of 2 to 6,
織物全体と して、 800〜3500 の力パーファクターを有することを 特徴とするものである。  It is characterized by having a force par factor of 800-3500 as the whole woven fabric.
本発明の偏平マルチフィ ラメント糸条織物において、 前記繊維形 成性人造重合体が、 ポリ エステル、 ポリアミ ド、 ポリ塩化ビニリデ ン、 ポリ プロ ピレン、 再生セルロース、 及び酢酸セルロースから選 ばれることが好ましい。  In the flat multifilament yarn woven fabric of the present invention, it is preferable that the fiber-forming artificial polymer is selected from polyester, polyamide, polyvinylidene chloride, polypropylene, regenerated cellulose, and cellulose acetate.
本発明の偏平マルチフィ ラメ ント糸条織物において、 前記人造フ イ ラメントの偏平断面において、 その幅の最大値 (C1) の、 最小値 (C2) に対する比 (C1ZC2) 、 1.05〜4.00であることが好ましい 本発明の偏平マルチフィ ラメ ント糸条織物において、 前記マルチ フィラメ ント糸条の合計繊度は、 30〜: L70dtex であり、 単フィラメ ント繊度は、 0.5〜 5 dtex であることが好ましい。 In the flat multifilament yarn woven fabric according to the present invention, the minimum value of the maximum value (C1) of the width in the flat cross section of the artificial filament. The ratio (C1ZC2) to (C2) is preferably 1.05 to 4.00. In the flat multifilament yarn woven fabric of the present invention, the total fineness of the multifilament yarn is 30 to: L70dtex, and the single filament is The fineness is preferably 0.5 to 5 dtex.
本発明の偏平マルチフィラメント糸条織物において、 前記織物が 、 平織組織、 綾織組織、 サテン織組織から選ばれる織物組織を有す ることが好ましい。  In the flat multifilament yarn woven fabric of the present invention, the woven fabric preferably has a woven structure selected from a plain woven structure, a twill woven structure, and a satin woven structure.
本発明の偏平マルチフィラメント糸条織物において、 前記織物に 含まれる前記偏平断面形状を有するマルチフィラメ ン ト糸条の含有 率は、 10〜: L00質量% であることが好ましい。  In the flat multifilament yarn woven fabric of the present invention, the content of the multifilament yarn having the flat cross-sectional shape contained in the woven fabric is preferably 10 to: L00 mass%.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 1 ) において 、 前記力パーファクター値が、 1500〜3500の範囲内にある。  In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the force factor value is in the range of 1500 to 3500.
本発明の偏平マルチフィラメント糸条織物の態様 ( 1 ) において 、 前記マルチフィ ラメ ント糸条 ( A) が、 0〜2500TZmの燃り数 を有することが好ましい。  In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, it is preferable that the multifilament yarn (A) has a burning number of 0 to 2500 TZm.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 1 ) において 、 前記織物の、 JIS L 1096-1998、 6.27.1 、 A法 (フラジール形試 験機法) によ り測定された通気度が、 5 mlZcm2 · sec以下であるこ とが好ましい。 In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the air permeability of the woven fabric measured by JIS L 1096-1998, 6.27.1, Method A (Fragile-type testing machine method) is measured. , 5 mlZcm 2 · sec or less.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 1 ) において 、 前記通気度が 0.1〜4. Oml/cm2 · secの範囲内にあることが好まし レ、。 In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the air permeability is preferably in the range of 0.1 to 4. Oml / cm 2 · sec.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 1 ) において ' 、 前記織物の、 JIS L 1096 - 1998、 6.26.1 、 ( 2 ) B法 (パイレツ ク法) によ り測定された吸水速度が、 40mm以上であることが好まし い。 本発明の偏平マルチフィラメ ント糸条織物の態様 ( 1 ) において 、 前記織物の JIS L 1096-1998、 6.17.1 , ( 1 ) A_ 1法 (平面法 ) によ り測定された摩耗強さが、 50回以上であることが好ましい。 本発明の低通気度繊維材料は、 前記本発明の態様 ( 1 ) 'の偏平マ ルチフイ ラメ ント糸条織物を含むものである。 In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the water absorption rate of the woven fabric is measured by JIS L 1096-1998, 6.26.1, (2) B method (Piret method). However, it is preferable that it is 40 mm or more. In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the abrasion strength of the woven fabric measured by JIS L 1096-1998, 6.17.1, (1) A_1 method (planar method) is reduced. It is preferable that the number is 50 times or more. The low-permeability fiber material of the present invention includes the flat multifilament filament woven fabric according to the embodiment (1) ′ of the present invention.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 2) において 、 前記マルチフィ ラメ ント糸条が 0.2質量%以上の艷消し剤を含み 、 かつ前記織物のカバーファクターが 1300〜3000の範囲内にある。 本発明の偏平マルチフィ ラメ ン ト糸条織物の態様 ( 2 ) において 、 前記マルチフィ ラメ ン ト糸条が 0〜: LSOOTZmの撚り数を有する ことが好ましい。  In the aspect (2) of the flat multifilament yarn woven fabric of the present invention, the multifilament yarn contains 0.2% by mass or more of the matting agent, and the woven fabric has a cover factor in the range of 1300 to 3000. . In the aspect (2) of the flat multifilament yarn woven fabric of the present invention, the multifilament yarn preferably has a twist number of 0 to: LSOOTZm.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 2 ) において 、 前記織物が、 JIS Z 8729 - 1994、 L * a * b *表色系において、 白色 板上に置かれたときの L* 値 (L ) と、 黒色板上に置かれたとき の L* 値 (L*b) との差厶 L (= L*ff — L*b) により表される透視 防止度が、 15以下であることが好ましい。 In the aspect (2) of the flat multifilament yarn woven fabric of the present invention, in the JIS Z 8729-1994, the L * value when placed on a white plate in the L * a * b * color system. The difference between (L) and the L * value (L * b ) when placed on a black plate is less than or equal to 15 as shown by L (= L * ff — L * b ). Is preferred.
本発明の偏平マルチフィラメ ント糸条織物の態様 ( 2 ) において 、 前記織物の、 JIS L 1096-1998、 6.26.1 , ( 2 ) B法 (パイ レツ ク法) によ り測定された吸水速度が、 40mm以上であることが好まし い。  In the aspect (2) of the flat multifilament yarn woven fabric of the present invention, the water absorption rate of the woven fabric measured by the JIS L 1096-1998, 6.26.1, (2) B method (Pilet method) However, it is preferable that it is 40 mm or more.
本発明の透視防止性 · 吸汗性繊維材料は、 前記本発明の態様 ( 2 ) の偏平マルチフィ ラメ ント糸条織物を含むものである。  The anti-see-through / sweat-absorbing fiber material of the present invention includes the flat multifilament yarn woven fabric according to the aspect (2) of the present invention.
本発明の偏平マルチフィラメント糸条織物の態様 ( 3 ) において 、 前記マルチフィ ラメ ント糸条が 0〜0.2質量% の艷消し剤を含み 、 前記織物の力パーファクターが 800〜2000の範囲内にある。  In the aspect (3) of the flat multifilament yarn woven fabric of the present invention, the multifilament yarn contains 0 to 0.2% by mass of the matting agent, and the power factor of the woven fabric is in the range of 800 to 2000. .
本発明の偏平マルチフィラメント糸条織物の態様'( 3 ) において 、 前記マルチフィ ラメ ン ト糸条が 0〜1000Zmの撚り数を有するこ とが好ましい。 In the aspect (3) of the flat multifilament yarn woven fabric of the present invention, the multifilament yarn has a twist number of 0 to 1000 Zm. Is preferred.
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 3 ) において 、 前記織物の、 J I S L 1055-1987、 6. 1、 A法 (伹し、 照度は 10万 lx ) によ り測定された光透過率が 10〜 70 %であることが好ましい。 本発明の透視防止性繊維材料は、 本発明の態様 ( 3 ) の偏平マル チフィ ラメ ント糸条織物を含むものである。 図面の簡単な説明  In the aspect (3) of the flat multifilament yarn woven fabric of the present invention, the light transmission of the woven fabric measured by the JISL 1055-1987, 6.1, A method (where illuminance is 100,000 lx). Preferably the rate is between 10 and 70%. The see-through preventing fiber material of the present invention contains the flat multifilament yarn woven fabric of the embodiment (3) of the present invention. BRIEF DESCRIPTION OF THE FIGURES
図 1 は、 本発明の偏平マルチフィラメ ント糸条織物に用いられる 偏平マルチフィ ラメ ントの断面形状の一例を示す説明図であり、 図 2は、 本発明の偏平マルチフィ ラメ ント糸条織物に用いられる 偏平マルチフィラメントの断面形状の他の一例を示す説明図であり 図 3は、 本発明の偏平マルチフィ ラメ ント糸条織物に用いられる 偏平マルチフィラメントの断面形状の更に他の一例を示す説明図で ある。 発明を実施するための最良の形態  FIG. 1 is an explanatory diagram showing an example of a cross-sectional shape of a flat multifilament yarn woven fabric used in the flat multifilament yarn woven fabric of the present invention. FIG. 2 is used for the flat multifilament yarn woven fabric of the present invention. FIG. 3 is an explanatory diagram showing another example of the cross-sectional shape of the flat multifilament. FIG. 3 is an explanatory diagram showing another example of the cross-sectional shape of the flat multifilament used in the flat multifilament yarn fabric of the present invention. . BEST MODE FOR CARRYING OUT THE INVENTION
本発明の発明者らは、 繊維形成性人造重合体からなり、 かつ偏平 な断面形状を有する複数本のフィラメントからなるマルチフィラメ ントを、 経糸及び 又は緯糸と して含む織物において、 前記フイラ メントの偏平断面形状が、 その長手中心線の両側に、 前記長手中心 線から外側に向う方向に膨出している 3個以上の、 好ましく は 4個 以上の、 よ り好ましく は 4〜 6個の膨出部と、 これら膨出部の間に 形成され、 前記長手中心線に向う 2個以上の、 好ましく は 3個以上 の、 よ り好ましく は 3〜 5個の、 くびれ部とが、 前記長手中心線に 関してほ 対称に形成されていて、 前記ブイラメントの偏平断面形 状の、 最大長さ (B ) の、 この長さ方向に直角をなして交差する方 向の最大値 C1に対する比 (B Z C1) によ り表される断面偏平度が 2 〜 6であるようにコントロールすると、 得られる織物において、 ( 1 ) 偏平マルチフィラメ ント糸条中の単フィ ラメ ン トは、 経 · 緯糸 の交差点においてその組織接圧によ り、 互に偏平な表面におい,て密 着しながら、 滑動して拡がり、 幅広で緻密な糸条部を形成し、 この 部分においては、 偏平単フィラメ ン ト間に形成される空隙が少なく なり、 ( 2 ) また、 互に重なり合つている偏平フィラメ ントの表面 は、 複数個の膨出部と、 複数個のくびれ部により粗面化しているた めフィラメ ント間の摩擦抵抗が低くなり、 従って、 偏平マルチフィ ラメ ント経 · 緯糸の交差点は、 高い柔軟性 (屈曲性) を有し、 しか も低い通気度を有することを見出した。 The inventors of the present invention provide a woven fabric comprising, as a warp and / or a weft, a multifilament made of a fiber-forming artificial polymer and having a plurality of filaments having a flat cross-sectional shape. 3 or more, preferably 4 or more, more preferably 4 to 6 bulges whose flat cross-sectional shape bulges out on both sides of the longitudinal center line in a direction outward from the longitudinal center line. Part, and two or more, preferably three or more, more preferably three to five, constricted parts formed between these bulging parts and facing the longitudinal center line. And the flat section of the birment is The cross-sectional flatness expressed by the ratio (BZ C1) of the maximum length (B) of the shape to the maximum value C1 in the direction crossing at right angles to this length direction is 2 to 6 In the obtained woven fabric, (1) the single filaments in the flat multifilament yarn are densely arranged on mutually flat surfaces due to the tissue contact pressure at the intersection of the warp and weft. While wearing, it slides and spreads to form a wide and dense thread portion, and in this portion, the voids formed between the flat single filaments are reduced, and (2) The surface of the flat filament is roughened by a plurality of bulges and a plurality of constrictions, so the frictional resistance between the filaments is low, and therefore, the intersection of the flat multifilament warp and weft Has high flexibility (bending ) Has been found to have even lower air permeability deer.
さらに、 本発明の発明者らは、 偏平マルチフィラメントの偏平表 面に形成されている複数個のくびれ部は、 液体に対して毛管現象を 発現し、 このため本発明の織物は水及び汗に対し、 優れた吸水及び 吸汗性を示すことを見出した。  Further, the inventors of the present invention believe that the plurality of constrictions formed on the flat surface of the flat multifilament develop a capillary phenomenon with respect to a liquid, and therefore the fabric of the present invention is exposed to water and sweat. On the other hand, it was found that they exhibited excellent water absorption and sweat absorption properties.
さらに、 本発明の発明者らは、 偏平マルチフィラメ ン トの周面に 形成された複数個の膨出部及びくびれ部は、 前述のように偏平マル チフイラメ ント周面の摩擦抵抗を低下させその結果、 本発明の織物 は、 優れた摩耗強さを有することを見出した。  Further, the inventors of the present invention have proposed that the plurality of bulges and constrictions formed on the peripheral surface of the flat multifilament reduce the frictional resistance of the peripheral surface of the flat multifilament as described above. As a result, it has been found that the woven fabric of the present invention has excellent wear strength.
さ らに、 本発明の発明者らは、 本発明の織物に用いられる偏平マ ルチフィラメントの周面上の複数個の膨出部及びくびれ部によ り形 成される粗面は、 それを透過する光を反射及び屈折によ り散乱させ 、 それにより採光性 (透光量) を著しく低下させることなく透視性 を低下させ、 織物の外側から、 その内側の透視を防止するこ とがで きることを見出した。  Furthermore, the inventors of the present invention consider that the flat surface formed by a plurality of bulges and constrictions on the peripheral surface of the flat multifilament used in the woven fabric of the present invention has the following characteristics. The transmitted light is scattered by reflection and refraction, thereby reducing the transparency without significantly reducing the light collection (transmission amount), and preventing the inside of the fabric from being seen through from the outside. I found that I could.
さ らに、 本発明の発明者は、 本発明の偏平マルチフィ ラメ ン ト糸 条織物のカバーファクターを、 800〜3500 の範囲内において、 適宜 に設定することによって、 本発明の偏平マルチフィラメント糸条織 物の、 通気性、 吸水 · 吸汗性、 摩耗強さ、 透視防止性などを適宜に 調整し得ること、 及びそれにより これらの特性を有する衣料材料を 提供し得ることを見出した。 Further, the inventor of the present invention provides the flat multifilament yarn of the present invention. By appropriately setting the cover factor of the strip fabric within the range of 800 to 3500, the flat multifilament yarn of the present invention can have air permeability, water absorption and sweat absorption, abrasion strength, see-through prevention properties, and the like. Has been found to be able to be appropriately adjusted, and thereby it is possible to provide a clothing material having these characteristics.
本発明は、 上記知見に基いて完成されたものである。  The present invention has been completed based on the above findings.
本発明の偏平マルチフイラメント糸条織物は、 繊維形成性人造重 合体を生成分として含み、 偏平な断面形状を有する複数本の人造フ イラメ ントからなるマルチフィ ラメント糸条を、 経糸及び Z又は緯 糸と して含む織物である。  The flat multifilament yarn woven fabric of the present invention comprises a multifilament yarn comprising a plurality of artificial filaments having a flat cross-sectional shape, which contains a fiber-forming artificial polymer as a produced component, and comprises a warp yarn and a Z or weft yarn. It is a woven fabric to be included.
上記偏平マルチフィラメ ント糸条において、 例えば、 図 1に示さ れているように、 単フィ ラメ ン トの断面 1の形状は、 その長さに対 して、 その長手中心線に対し垂直方向の幅が比較的短い形状、 すな わち偏平形状をなすものである。 図 1 に示されている断面 1 におい て、 その長手中心線 2の両側に、 長手中心線から外側に向って膨出 ている片面当り 3個以上 (図 1 においては 4個) の膨出部 3 と、 こ の膨出部 3の間に形成されている片面当り 2個以上 (図 1 において は 3個) のくびれ部 4 とが長手中心線に関して対称に形成されてい る。 図 1の断面において、 その長手方向の最大長さ (B ) の、 前記 長手中心的方向に直角をなす方向の最大幅 (C1) に対する比 (B Z C1) によ り表される断面偏平度は 2〜 6の範囲内にある。  In the above-mentioned flat multifilament yarn, for example, as shown in FIG. 1, the shape of the cross section 1 of the single filament is perpendicular to its longitudinal center line with respect to its length. It has a relatively short width, that is, a flat shape. In cross section 1 shown in Fig. 1, three or more (four in Fig. 1) bulges per side protruding outward from the longitudinal center line on both sides of its longitudinal center line 2 3 and two or more (three in FIG. 1) constrictions 4 per side formed between the bulges 3 are formed symmetrically with respect to the longitudinal center line. In the cross section of FIG. 1, the cross-sectional flatness represented by the ratio (BZ C1) of the maximum length (B) in the longitudinal direction to the maximum width (C1) in the direction perpendicular to the longitudinal center direction is It is in the range of 2-6.
各偏平単フィラメントの断面形状において、 前記偏平断面形状の 片面上に形成されている、 3個以上の膨出部と 2個以上のくびれ部 は、 前記偏平断面形状の、 前記片面に対し反対の面上に形成されて いる 3個以上の膨出部と 2個以上のくびれ部とに対し、 その形状及 び配置位置において、 前記偏平断面形状の長手'中心線に関して、 ほ ぼ対称をなしている。 前述マルチフィ ラメ ントの偏平単フィラメ ントの断面において、 膨出部の数は、 前述のよ うに片面当り 3個以上であり、 好ましくは 4個以上であり、 さ らに好ましくは 4〜 6個にある。 またくびれ部 の数は前述のように片面当り 2個以上であり、 好ましく は 3個以上 であり、 さ らに好ましくは 3〜 5個である。 さらに、 断面偏平度は 、 前述のように 2〜 6であり、 好ましくは 3〜 5である。 In the cross-sectional shape of each flat single filament, three or more bulging portions and two or more constrictions formed on one surface of the flat cross-sectional shape are opposite to the one surface of the flat cross-sectional shape. With respect to three or more bulging portions and two or more constricting portions formed on the surface, the shapes and arrangement positions thereof are almost symmetrical with respect to the longitudinal center line of the flat cross-sectional shape. I have. In the cross section of the flat single filament of the multifilament, the number of bulges is 3 or more per side as described above, preferably 4 or more, and more preferably 4 to 6 as described above. is there. As described above, the number of constricted portions is two or more per side, preferably three or more, and more preferably three to five. Further, the cross-sectional flatness is 2 to 6, as described above, and preferably 3 to 5.
膨出部の数が片面当 り 2個以下であり、 従ってくびれ部の数が片 面当 り 1個以下であると、 フィ ラメ ン ト周面の摩擦抵抗が大きくな り、 マルチフィラメ ントの、 経緯交差点における圧接による拡がり が不十分になり、 得られる通気度のコン ト ロールが困難になり摩耗 強さが不十分になり、 また、 フィ ラメ ン ト周面のくびれ部の減少に より得られる織物の吸水 · 吸汗性が不十分になり、 さらにフィラメ ント周面における光散乱効果が不十分になって、 得られる織物の透 視防止効果が不十分になる。  If the number of bulges is 2 or less per side, and if the number of constrictions is 1 or less per side, the frictional resistance on the periphery of the filament increases, and multifilament However, the spread due to pressure welding at the intersection at the intersection of the courses is insufficient, it is difficult to control the resulting air permeability, the wear strength is insufficient, and the decrease in the constriction on the periphery of the filament is obtained. The resulting fabric has insufficient water absorption and sweat absorption properties, and further has an insufficient light scattering effect on the periphery of the filament, resulting in an insufficient transparency preventing effect of the obtained fabric.
本発明の偏平マルチフィラメ ント糸条織物において、 その偏平マ ルチフィラメント糸条の単フィラメントの断面における断面偏平度 ( B / C1 ) は前述のように 2〜 6であり、 好ましくは 3〜 5である 。 この断面偏平度が 2未満であると、 フィラメント と曲げ抵抗 (剛 性) が高くなり、 得られる織物の柔軟性が不十分になり、 このため 所望のソフ トな風合が得られない。  In the flat multifilament yarn woven fabric of the present invention, the cross-sectional flatness (B / C1) of the flat multifilament yarn in the cross section of a single filament is 2 to 6, as described above, and preferably 3 to 5. is there . If the cross-sectional flatness is less than 2, the filament and the bending resistance (rigidity) are increased, and the obtained woven fabric becomes insufficient in flexibility, so that a desired soft feeling cannot be obtained.
さ らに断面偏平度が 2未満であると、 織物中、 特に経緯交差点に おける圧接によるマルチフィラメントの拡がりが不十分になって、 経緯糸条間の間隙を十分小さくすることができず、 また、 繊維間の 空隙のサイズを十分に小さくすることができないため、 得られる織 物の通気度を所望値にコント ロールすることが困難になる。  Further, if the cross-sectional flatness is less than 2, the spread of the multifilament in the woven fabric, particularly by press-welding at the weft intersection, becomes insufficient, and the gap between the weft yarns cannot be sufficiently reduced. However, since the size of the voids between the fibers cannot be made sufficiently small, it becomes difficult to control the air permeability of the obtained woven fabric to a desired value.
また、 断面偏平度 (B _/ C1 ) が、 6を超えるマルチフィ ラメ ント の製造は困難である。 本発明の織物に用いられる偏平マルチフィラメ ント糸条の偏平単 フィ ラメ ントの断面形状において、 その長手中心線に、 直交する方 向の最大幅 (C1 ) の、 最小値 (C2) に対する比 (C1/ C2) は、 1. 05 〜4. 00であるこ とが好ましく、 1. 10〜2. 50であることが好ましい。 上記比 (C1Z C2) は、 偏平単フィ ラメ ン トのくびれ部の深さに関係 するパラメータであって、 比 (C1/ C2) が、 1. 05未満であるとき、 すなわち、 くびれ部の深さが浅いときは、 偏平単フィ ラメ ントの周 面の摩擦抵抗が高く、 従って得られる織物の通気性が高く、 かつ摩 耗強さ及び透視防止性が不十分になることがあり、 また吸水、 吸汗 性が不十分になることがある。 まだ、 比 (C1Z C2) が、 4. 0 をこえ ると、 偏平単フィ ラメ ン トのくびれ部の深さが過大になり、 その作 用効果が飽和し、 しかも、 得られる織物には、 その紡糸工程が不安 定であり、 得られた単フィラメントが、 そのくびれ部に沿って裂け 易く、 かつ、 単フィラメ ントの断面形状の均一性が低下するという 不都合が生ずることがある。 ' 図 2及び 3の各々には、 本発明の偏平マルチフイラメ ント糸条織 物に用いられる偏平単フィ ラメ ントの断面形状の他の一例が示され ている。 In addition, it is difficult to manufacture a multifilament having a cross-sectional flatness (B_ / C1) of more than 6. In the cross-sectional shape of the flat single filament of the flat multifilament yarn used in the woven fabric of the present invention, the ratio of the maximum width (C1) in the direction orthogonal to the longitudinal center line to the minimum value (C2) ( C1 / C2) is preferably from 1.05 to 4.00, more preferably from 1.10 to 2.50. The above ratio (C1Z C2) is a parameter related to the depth of the constriction of the flat single filament. When the ratio (C1 / C2) is less than 1.05, that is, the depth of the constriction When the depth is shallow, the frictional resistance of the flat single filament surface is high, so that the resulting fabric may have high air permeability, and may have insufficient abrasion strength and insufficient see-through prevention. However, sweat absorption may be insufficient. If the ratio (C1Z C2) exceeds 4.0, the depth of the narrow portion of the flat single filament becomes too large, and the effect of the flatness is saturated. The spinning process is unstable, and the obtained single filament may be easily torn along the constricted portion, and the uniformity of the cross-sectional shape of the single filament may be reduced. FIGS. 2 and 3 each show another example of the cross-sectional shape of the flat single filament used for the flat multifilament yarn fabric of the present invention.
図 2に示されているフィラメ ント 1の断面は、 その長手中心線 2 の両側に図 1 に記載の断面と同様の形状を有しているが、 膨出部 3 の断面形状は、 楕円形の長軸に沿う孤形のようになだらかであって 、 従って、 くびれ部 4の深さが浅い。  The cross section of the filament 1 shown in FIG. 2 has the same shape as the cross section shown in FIG. 1 on both sides of the longitudinal center line 2, but the cross section of the bulging portion 3 is elliptical. It is gentle like an arc along the long axis, so the constriction 4 is shallow.
図 3に示されているフィラメ ント 1の断面は、 その長手中心線の 両側に、 片側当 り 4個の膨出部と 3個のくびれ部とを有するもので あるが、 膨出部の 1個 3aが他の膨出部にく らベて、 幅及び高さにお いて小さく、 従って膨出部 3aの頂点から、 その両側のくびれ部 4aの 谷底までの深さは、 他のくびれ部 4部のそれよ り も浅い。 本発明の偏平マルチフィラメ ント糸条織物の力パーファクタ一はThe cross section of the filament 1 shown in FIG. 3 has four bulges and three constrictions on one side on both sides of its longitudinal center line. The piece 3a is narrower in width and height than the other bulge, so the depth from the top of the bulge 3a to the valley bottom of the constriction 4a on both sides is the other constriction. It is shallower than the four parts. The force factor of the flat multifilament yarn woven fabric of the present invention is as follows.
、 前述のとおり 800〜3500であり、 織物に求められる特性、 性能に 応じて、 適宜に設定することができる。 As described above, it is 800 to 3500, and can be appropriately set according to the characteristics and performance required of the woven fabric.
織物の力パーファクター (CF) は、 下記式によ り定義されるもの である。  The force factor (CF) of a woven fabric is defined by the following equation.
CF= (DWp/1.1)1/2 XMWp+ (DWf/1.1)1/2 XMWf CF = (DWp / 1.1) 1/2 XMWp + (DWf / 1.1) 1/2 XMWf
但し、 上式において、  However, in the above formula,
DWp は経糸の総繊度 (dtex) を表し、  DWp represents the total fineness (dtex) of the warp,
MWp は経糸の織密度 (本 Z2.54cm) を表し、  MWp represents the warp weaving density (this Z2.54cm),
D f は緯糸の総繊度 (dtex) を表し、  D f represents the total fineness (dtex) of the weft,
M f は緯糸の織密度 (本 Z2.54cm) を表す。  M f represents the weaving density of the weft (this Z2.54cm).
本発明の偏平マルチブイラメ ント糸条織物において、 その力パー ファクター (CF) が、 800未満 であると、 経糸と緯糸の間に形成さ れる空隙が大きく なり、 得られる織物の通気度を所望値にコントロ ールするこ とが困難になり、 かつ高い透視防止性を得ることが困難 になる。 また力パーファクタ一 (CF) が 3500を超えると、 得られる 織物の柔軟性が不十分になり、 かつ (採用光) 透光性も不十分にな る。  When the force factor (CF) of the flat multi-filament yarn fabric of the present invention is less than 800, the voids formed between the warp and the weft become large, and the air permeability of the obtained fabric is adjusted to a desired value. It becomes difficult to control and it is difficult to obtain high see-through prevention. If the force-per-factor (CF) exceeds 3500, the obtained woven fabric becomes insufficient in flexibility, and the (adopted light) transmittance becomes insufficient.
本発明の偏平マルチフィラメ ント糸条織物の偏平マルチフィ ラメ ントを形成するために用いられる繊維形成性人造重合体は、 繊維形 成性合成重合体、 例えばポリエステル、 ポリアミ ド、 ポリ塩化ビ- リデン、 及びポリ プロ ピレンなど ; 繊維形成性半合成重合体、 例え ば酢酸セルロースなど ; 並びに再成重合体、 例えば再生セルロース 、 など、 から選ぶことができる。 偏平マルチフィ ラメ ン トの製造ェ 程の難易を配慮すると、 溶融紡糸法によ り繊維製造可能な繊維形成 性熱可塑性重合体、 例えばポリエステル (例えばポリエチレンテレ フタ レー ト、 及び ト リ メチレンテレフタ レー トなど) 、 ポリ アミ ド (例えばナイ ロ ン 6、 ナイロン 66など) 、 ポリ塩化ビニリデン及び ポリ プロ ピレンなどから選ばれることが好ましい。 The fiber-forming artificial polymer used for forming the flat multifilament of the flat multifilament yarn woven fabric of the present invention is a fiber-forming synthetic polymer such as polyester, polyamide, polyvinylidene chloride, and the like. And fiber-forming semi-synthetic polymers such as cellulose acetate; and regenerated polymers such as regenerated cellulose. Considering the difficulty of flat multifilament manufacturing processes, fiber-forming thermoplastic polymers, such as polyesters (eg, polyethylene terephthalate and trimethylene terephthalate), which can be produced by melt spinning, are considered. ), Polyamide (For example, nylon 6, nylon 66, etc.), polyvinylidene chloride, polypropylene and the like.
前記繊維形成性人工重合体には、 必要に応じて、 艷消し剤 (例え ば二酸化チタンなど) 、 微細孔形成剤 (例えば有機スルホン酸金属 塩など) 、 カチオン染料可染化剤 (例えばイ ソフタル酸スルホニゥ ム塩など) 、 酸化防止剤 (例えばヒ ンダー ドフエノール化合物など ) 、 熱安定剤、 難燃剤 (例えば三酸化二アンチモン) 、 蛍光増白剤 、 着色剤、 帯電防止剤 (例えばスルホン酸金属塩など) 、 吸湿剤 ( 例えばポリォキシアルキレンダルコールなど) 及び抗菌剤の 1種以 上を添加剤と して添加してもよい。  If necessary, the fiber-forming artificial polymer may include an anti-glazing agent (for example, titanium dioxide, etc.), a fine pore-forming agent (for example, a metal salt of organic sulfonic acid, etc.), a cationic dye dyeing agent (for example, Isophthal Acid sulfonium salts, etc.), antioxidants (eg, hindered phenol compounds, etc.), heat stabilizers, flame retardants (eg, diantimony trioxide), fluorescent brighteners, coloring agents, antistatic agents (eg, sulfonic acid metal salts) Etc.), one or more of a moisture absorbent (eg, polyoxyalkylene alcohol) and an antibacterial agent may be added as additives.
本発明の織物に用いられるマルチフィラメ ント糸条の合計繊度及 び偏平単マルチフィ ラメ ン トの緯度には、 本発明の目的織物が得ら れる限り格別の制限はないが、 一般に、 総繊度は、 30〜: 170dt ex で あることが好ましく、 より好ましく は 50〜: LOOdt ex であり、 単フィ ラメン ト繊度は、 0. 5〜 5 dt ex であることが好ましく、 よ り好まし くは 1 〜 4 dt exである。  The total fineness of the multifilament yarns used in the woven fabric of the present invention and the latitude of the flat single multifilament are not particularly limited as long as the target woven fabric of the present invention can be obtained. , 30 to: 170 dt ex, more preferably 50 to: LOO dt ex, and the single filament fineness is preferably 0.5 to 5 dt ex, more preferably 1 to 5 dt ex. ~ 4 dt ex.
本発明の偏平マルチフィラメ ント糸条織物に用いられる偏平マル チフィ ラメ ン ト糸条において、 その撚り数については目的織物が得 られる限り格別の制限はなく、 目的織物の用途及び必要特性に応じ て、 適宜に設定することができるが、 一般に 0〜2500 T / mである ことが好ましく、 0〜 600 T Z mであることがよ り好ましい。  In the flat multifilament yarn used in the flat multifilament yarn woven fabric of the present invention, the number of twists is not particularly limited as long as the target woven fabric is obtained, and depends on the use and required characteristics of the target woven fabric. In general, it is preferably 0 to 2500 T / m, and more preferably 0 to 600 TZm.
本発明の織物に用いられるマルチフィラメント糸条は、 本発明の 目的織物が得られる限り仮撚捲縮加工、 タスラン捲縮加工及びィン ターレース加工などの空気捲縮加工が施されたものであってもよい  The multifilament yarn used for the woven fabric of the present invention has been subjected to air crimping such as false twist crimping, Taslan crimping, and interlacing as long as the target fabric of the present invention is obtained. May
本発明の織物において、 それを構成する経糸及び/又は緯糸が、 前記偏平断面形状を有する複数本の単フイ ラメ ン トからなるマルチ フィ ラメ ン ト糸条により構成される。 すなわち、 経糸及び緯糸の両 方が、 前記偏平マルチフィ ラメ ント糸条によ り構成されていてもよ いし、 経糸及び緯糸のいずれか一方のみが、 前記偏平マルチフイラ メ ント糸条によ り構成され、 他の一方が前記偏平マルチフィ ラメ ン ト糸条とは異種の糸条により構成されていてもよい。 前記異種糸条 は、 モノ フィ ラメ ント糸条、 マルチフィ ラメ ント糸条及び紡績糸条 のいずれであってもよく、 これらは、 特殊機能、 例えば帯電防止性 、 光輝性、 などを有していてもよい。 また、 本発明の織物に用いら れる経糸及び/又は緯糸において、 前記偏平マルチフイラメ ント糸 条と ともに、 本発明の目的織物が得られる限り、 前記偏平マルチフ イ ラメント とは異る少量の異種繊維が、 混用されていてもよい。 本発明の偏平マルチフィラメ ント糸条織物において、 前記偏平マ ルチフィ ラメ ン トの含有率は、 織物の全質量に対して、 10~ 100質 量% であることが好ましく、 よ り好ましく は 20〜 100質量% であ り、 さ らに好ましくは 40〜100質量0 /0 である。 In the woven fabric of the present invention, the warp and / or the weft constituting the woven fabric are formed of a plurality of single filaments having the flat cross-sectional shape. It is composed of filament yarn. That is, both the warp and the weft may be constituted by the flat multifilament yarn, or only one of the warp and the weft is constituted by the flat multifilament yarn. The other one may be composed of a yarn different from the flat multifilament yarn. The heterogeneous yarn may be any of a monofilament yarn, a multifilament yarn and a spun yarn, and these have a special function, for example, an antistatic property, a glittering property, and the like. Is also good. Further, in the warp and / or weft used for the woven fabric of the present invention, a small amount of different kinds of fibers different from the flat multifilament are used together with the flat multifilament yarn as long as the target woven fabric of the present invention is obtained. , May be mixed. In the flat multifilament yarn fabric of the present invention, the content of the flat multifilament is preferably from 10 to 100% by mass, more preferably from 20 to 100% by mass, based on the total mass of the woven fabric. 100% by mass is, preferably in the al 40-100 mass 0/0.
本発明の織物用偏平マルチフィ ラメ ン トは、 偏平フィ ラメ ン ト用 紡糸口金、 例えば、 特開昭 56— 107044号公報、 第 5頁、 第 2図 Cに 記載の断面形状の複数個の吐出口を有する紡糸口金を用いて、 製造 することができる。  The flat multifilament for a fabric according to the present invention is a spinneret for flat filaments, for example, a plurality of dischargers having a cross-sectional shape described in JP-A-56-107044, page 5, FIG. It can be manufactured using a spinneret having an outlet.
本発明の偏平マルチフィラメ ント糸条織物は、 前述のようにして 製造された偏平マルチフィラメ ント糸条を、 経糸及び/又は緯糸と して用いて、 通常の製織方法によ り製造することができ、 通常の方 法によ り染色 ' 仕上加工を施すことができる。 偏平マルチフィラメ ント糸条が、 ポリエステル糸条である場合には、 当該織物にアル力 リ減量処理を施すことができる。 また、 仕上加工において吸水性増 進処理 (例えばァニオン系親水性高分子化合物などの吸水剤を塗布 又は含浸する処理) 、 撥水処理 (例えばフッ素化合物などの撥水剤 を塗布又は含浸する処理) 、 紫外線遮蔽処理 (例えば金属酸化物超 微粒子の分散液方法) 、 帯電防止処理、 消臭剤付与処理、 防虫剤付 与処理、 蓄光剤処理の一種以上を同時に、 又は、 順次に施してもよ レヽ The flat multifilament yarn woven fabric of the present invention can be manufactured by a normal weaving method using the flat multifilament yarn manufactured as described above as a warp and / or a weft. It can be dyed and finished in the usual way. When the flat multifilament yarn is a polyester yarn, the woven fabric can be subjected to a weight reduction treatment. Further, in the finishing process, a water-absorbing enhancement treatment (for example, a treatment for applying or impregnating a water-absorbing agent such as an anion-based hydrophilic polymer compound), a water-repelling treatment (for example, a water-repelling agent such as a fluorine compound) At least one of the following treatments: coating or impregnating), ultraviolet shielding treatment (for example, dispersion method of metal oxide ultrafine particles), antistatic treatment, deodorant treatment, insect repellent treatment, and phosphorescent treatment. , May be applied sequentially
本発明の偏平マルチフィ ラメ ント糸条織物の態様 ( 1 ) において 、 織物の力パーファクター (CF) が、 1500 3500の範囲内にあるよ うに、 経 ' 緯糸の繊度及び経 · 緯糸密度がコン ト ロールされる。 本発明の態様 ( 1 ) において、 織物の好ましい力パーファクター (CF) は 1500 3000であり、 さらに好ましくは 1500 2500である。 また、 本発明の態様 ( 1 ) において、 偏平マルチフィ ラメ ント糸条 の撚り数は、 0 2500 TZmであることが好ましく よ り好ましくは 0 600TZmであり、 さ らに好ましく は撚り数 0 TZm、 すなわ ち無撚りである。  In the aspect (1) of the flat multifilament yarn woven fabric of the present invention, the fineness of the warp and the warp / weft density are controlled such that the force factor (CF) of the woven fabric is in the range of 1500 to 3500. Rolled. In the embodiment (1) of the present invention, the preferable force factor (CF) of the woven fabric is 1500 3000, and more preferably 1500 2500. In the aspect (1) of the present invention, the number of twists of the flat multifilament yarn is preferably 02,500 TZm, more preferably 0 600 TZm, and further preferably 0 TZm. That is, it is untwisted.
本発明の態様 ( 1 ) の偏平マルチフィ ラメ ン ト糸条織物は、 5ml /cm2, sec以下の低い通気度を有することが好ましく、 よ り好まし くは 4 ml/cm2 · sec以下、 さ らに好ましくは 0.1 3 ml/cm2 . sec であることが好ましい。 この通気度は、 JIS L 1096 - 1998 6.27.1 A法 (フラジール形試験機法) により測定される。 The flat multifilament yarn woven fabric of the embodiment (1) of the present invention preferably has a low air permeability of 5 ml / cm 2 , sec or less, more preferably 4 ml / cm 2 · sec or less. More preferably, it is 0.13 ml / cm 2 .sec. This air permeability is measured by the JIS L 1096-1998 6.27.1 A method (Fragile type testing machine method).
また、 本発明の態様 ( 1 ) において、 その偏平マルチフィラメン ト糸条織物の、 JIS L 1096-1998 6.26.1 ( 2 ) B法 (パイ レツ ク法) によ り測定された吸水速度が、 40 以上であることが好まし く、 50 70mmであることがよ り好ましく、 また、 JIS L 1096-1998 6.17.1 ( 1 ) A—法 (平面法) によ り測定された摩耗強さが 5 0回以上であることが好ましく、 80回以上であることがよ り好まし く、 100回以上 であることがさらに好ましい。  In the aspect (1) of the present invention, the flat multifilament yarn woven fabric has a water absorption rate measured by JIS L 1096-1998 6.26.1 (2) B method (Pireck method), It is preferably 40 or more, more preferably 50 70 mm, and the wear strength measured by the JIS L 1096-1998 6.17.1 (1) A- It is preferably at least 50 times, more preferably at least 80 times, even more preferably at least 100 times.
本発明の態様 ( 1 ) において、 その織物のカバーファクター (CF ) が 1500未満であると、 経糸と緯糸とによ り形成される間隙の面積 が大きくなり、 得られる織物の通気性が過大 (例えば 5 ml / cm2 - s ecを超える) になり、 吸水 · 吸汗性及び摩耗強さが不十分になるこ とがある。 またその力パーファクター (CF) が 3500を超えると、 経 糸及び緯糸が密接して、 得られる織物の柔軟性が不十分になりかつ 屈曲抵抗が大きくなって織物の風合が不良になり、 かつ摩耗強さが 不十分になることがある。 In the embodiment (1) of the present invention, if the cover factor (CF) of the woven fabric is less than 1500, the area of the gap formed by the warp and the weft yarns And the resulting fabric may have excessively high air permeability (for example, more than 5 ml / cm 2 -sec), and may have insufficient water absorption / perspiration and abrasion strength. If the force factor (CF) exceeds 3500, the warp and the weft are in close contact with each other, resulting in insufficient flexibility of the obtained woven fabric and increased bending resistance, resulting in a poor feeling of the woven fabric. In addition, the wear strength may be insufficient.
本発明の態様 ( 1 ) の前記 1500〜3500の力パーファクタ一 (CF) を有する偏平マルチフィ ラメ ン ト糸条織物において、 その経糸及び ノ又は緯糸を構成する偏平マルチブイラメ ン ト糸条が、 経緯交差点 における接圧によ り、 互に接触している単フィ ラメントが互にその 接触面で滑って糸条は偏平になって横方向に拡がり、 糸条間隙の面 積が小さくなり、 織物の通気度が低下する。 このため、 本発明の態 様 ( 1 ) の偏平マルチフィ ラメ ン ト糸条織物は、 好ましくは 5 ml // cm2 . s e c以下の低い通気度を示す。 In the flat multifilament yarn woven fabric according to the aspect (1) of the present invention, which has a force par factor (CF) of 1500 to 3500, the flat multifilament yarn constituting the warp and the knit or the weft is formed by a weft Due to the contact pressure at the intersection, the single filaments that are in contact with each other slide on each other at their contact surfaces, and the yarn is flattened and spreads laterally, reducing the area of the yarn gap and reducing the woven fabric. The air permeability decreases. For this reason, the flat multifilament yarn woven fabric of the embodiment (1) of the present invention preferably has a low air permeability of 5 ml / cm 2 .sec or less.
さらに、 本発明の態様 ( 1 ) において、 糸条の前記偏平化により 、 得られる織物の屈曲抵抗が低下し、 その柔軟度が向上し、 ソフ ト な風合を示す。 また、 本発明の偏平マルチフィ ラメ ン ト糸条の単フ イラメ ント周面において、 その長手方向に沿って伸びる片面当り 3 以上の膨出部と、 その間に形成される 2以上のくびれ部により単フ イラメ ント周面は粗面化されていて、 単フィ ラメ ントが、 互に接触 しても、 特に経 ' 緯糸の交差点において、 互に圧接されても、 単フ イラメ ント相互の接触面積が小さく、 従って、 表面摩擦抵抗が小さ くなり、 織物の柔軟性向上に寄与する。 さ らに、 単フィ ラメ ン ト周 面において、 その長手方向に沿って伸'びるくびれ部は、 単フィラメ ントが互に接触しても閉塞されることがない、 又は少ないから、 水 分又は汗はこのくびれ部の毛管現象によ り容易に拡散するため、 得 られる織物は、 優れた吸水性、 吸汗性を示す。 本発明の前記態様 ( 1 ) の偏平マルチフィ ラメ ン ト糸条織物は、 柔軟性に優れた風合と、 高い吸水 · 吸汗性、 及び摩耗強さを有して いるため、 各種衣料材料、 例えば男子及び女子用のスポーツ衣料、 ユニフォーム、 トーブなどの民族衣装、 下着類、 裏地、 帽子類並び に傘地などの低通気性繊維材料と して有用である。 Further, in the aspect (1) of the present invention, the flattening of the yarn lowers the bending resistance of the obtained woven fabric, improves its flexibility, and shows a soft feeling. In addition, on the single filament peripheral surface of the flat multifilament yarn of the present invention, three or more bulges per one surface extending along the longitudinal direction and two or more constrictions formed between the bulges are provided. The peripheral surface of the filament is roughened, and even if the single filaments are in contact with each other, especially when they are pressed against each other at the intersection of the warp and weft, the contact area between the single filaments is increased. It is small, so the surface frictional resistance is small, which contributes to the improvement of the flexibility of the fabric. Furthermore, on the periphery of the single filament, the constricted portion extending along the longitudinal direction of the single filament does not become blocked even if the single filaments are in contact with each other. Since the sweat is easily diffused by the capillary action of the constriction, the obtained woven fabric exhibits excellent water absorption and sweat absorption. The flat multifilament yarn woven fabric according to the above aspect (1) of the present invention has a feeling excellent in flexibility, high water absorption / perspiration, and abrasion strength. It is useful as a low-breathable fiber material for sports clothing for boys and girls, folk costumes such as uniforms and toves, underwear, lining, hats and umbrellas.
本発明の偏平マルチフィ ラメ ン ト糸条織物の態様 ( 2 ) において 、 前記マルチフィ ラメ ン ト糸条が、 0. 2質量%以上 、 好ましく は 0. 4〜3. 5質量。/。、 より好ましく は 1. 0〜2. 5質量0/。、 の艷消し剤を含み 、 前記織物のカバーファクター (CF) が 1300〜3000、 好ましく は 14 00- 2500, の範囲内にある。 In the aspect (2) of the flat multifilament yarn woven fabric of the present invention, the multifilament yarn is 0.2% by mass or more, preferably 0.4 to 3.5% by mass. /. And more preferably 1.0 to 2.5 mass 0 /. And the cover factor (CF) of the fabric is in the range of 1300 to 3000, preferably 1400 to 2500.
本発明の態様 ( 2 ) の偏平マルチフィラメ ント糸条織物のマルチ フィ ラメ ントに含まれる艷消し剤の組成及び種類には、 目的織物が 得られる限り格別の制限はないが、 例えば二酸化チタン、 硫酸パリ ゥムなどの 1種以上からなる無機微粒子を用いることができる。 艷 消し剤の含有量が、 マルチフィ ラメ ントの質量に対し、 0. 2 質量未 満であると、 得られるマルチフィ ラメ ン ト糸条の光反射率が不十分 になり、 得られる織物が、 十分な透視防止性を示すことができない ことがある。 但し、 艷消し剤の含有量が 7質量%を超えると、 得ら れる重合体組成物の製系性が不安定になるこ とがある。  The composition and type of the matting agent contained in the multifilament of the flat multifilament yarn woven fabric of the embodiment (2) of the present invention are not particularly limited as long as the desired woven fabric can be obtained. Inorganic fine particles composed of one or more kinds such as parium sulfate can be used. If the content of the anti-glare agent is less than 0.2 mass relative to the mass of the multifilament, the light reflectance of the obtained multifilament yarn becomes insufficient, and the obtained woven fabric has a sufficient In some cases, it may not be possible to exhibit a high degree of fluoroscopy prevention. However, if the content of the antiglare agent exceeds 7% by mass, the systemability of the obtained polymer composition may be unstable.
本発明の態様 ( 2 ) の織物のカバーファクター (CF) が 1300未満 であると、 経糸及び緯糸の間に形成される間隙が大きくなり、 得ら れる織物の透視防止性が不十分になることがあり、 また、 そのカバ 一ファクター (CF) が、 3000を超えると得られる織物の柔軟性が不 十分になり、 その風合が不満足になることがある。  When the cover factor (CF) of the woven fabric of the embodiment (2) of the present invention is less than 1300, the gap formed between the warp and the weft becomes large, and the see-through preventing property of the obtained woven fabric becomes insufficient. If the cover factor (CF) exceeds 3,000, the woven fabric obtained may have insufficient flexibility and the texture may be unsatisfactory.
本発明の態様 ( 2 ) の織物において、 その織組織が平織組織を有 する場合、 当該織物の力パーファクター (CF) は 1400〜1800の範囲 内にあることが好ましく、 さらに好ましくは 1500〜1700である。 , また、 本発明の態様 ( 2 ) の織物の織組織が、 綾織組織を有する 場合、 当該織物の力パーファクター (CF) は、 1900〜2400の範囲内 にあることが好ましく、 さ らに好ましく は 2000〜2300である。 In the woven fabric according to the embodiment (2) of the present invention, when the woven structure has a plain woven structure, the force factor (CF) of the woven fabric is preferably in the range of 1400 to 1800, and more preferably 1500 to 1700. It is. , Further, when the woven structure of the woven fabric of the embodiment (2) of the present invention has a twill woven structure, the force factor (CF) of the woven fabric is preferably in the range of 1900 to 2400, and more preferably. 2000-2300.
本発明の態様 ( 2 ) の織物に用いられるマルチフィ ラメ ン ト糸条 の撚り数には、 目的織物が得られる限り、 格別の制限はない。 しか し、 糸条内の単フィ ラメ ン ト相互の相対的変位について、 十分な自 由度を確保するためには、 偏平マルチフィ ラメ ント糸条の撚り数は 、 0〜1500TZmであることが好ましく、 よ り好ましくは 0〜 600 T/mである。 さらに好ましくは、 撚り数は O T/m、 すなわち無 撚りである。  There is no particular limitation on the number of twists of the multifilament yarn used for the fabric of the embodiment (2) of the present invention as long as the desired fabric is obtained. However, in order to ensure a sufficient degree of freedom with respect to the relative displacement between the single filaments in the yarn, the number of twists of the flat multifilament yarn is preferably 0 to 1500 TZm. And more preferably 0 to 600 T / m. More preferably, the number of twists is OT / m, that is, no twist.
本発明の態様 ( 2 ) の偏平マルチフィ ラメ ン ト糸条織物について 、 その透視防止度を、 JIS Z 8729- 1994、 L * a * b *表色系において 、 供試試料を、 白色板上に载置したとき、 その L* 値 (L と記す ) と、 黒色板上に載置したとき、 その L* 値 (L、と記す) との差 Δ L (= L% - L \) をもって表すとき、 その透視防止度は A L15 以下であることが好ましく、 より好ましくは 13.5以下であり、 さら に好ましく は 10〜: 13である。 透視防止度 Δ Lが 15よ り高いときは、 当該織物の透視防止性は、 実用上不十分であることがある。  Regarding the flat multifilament yarn woven fabric of the embodiment (2) of the present invention, the degree of see-through prevention is determined according to JIS Z 8729-1994, L * a * b * color system, and the test sample is placed on a white plate. When placed on a black plate, the difference between its L * value (denoted by L) and its L * value (denoted by L) is represented by ΔL (= L%-L \) In this case, the degree of prevention of fluoroscopy is preferably A L15 or less, more preferably 13.5 or less, and further preferably 10 to 13. When the degree of see-through prevention ΔL is higher than 15, the see-through preventing property of the woven fabric may be insufficient for practical use.
本発明の態様 ( 2 ) の偏平マルチフィ ラメ ン ト糸条織物において 、 この織物の、 JIS L 1096-1998、 6.26.1 、 ( 2 ) B法 (パイ レツ ク法) によ り測定された吸水速度は、 40mm以上であることが好まし く、 45mm以上であることが好ましく、 さ らに好ましくは 50〜 70mmで める。  In the flat multifilament yarn woven fabric according to the embodiment (2) of the present invention, the water absorption of this woven fabric measured by the JIS L 1096-1998, 6.26.1, (2) B method (Pilet method) The speed is preferably 40 mm or more, preferably 45 mm or more, and more preferably 50 to 70 mm.
上記吸水速度が 40mm未満であると、 当該織物の吸水性及び吸汗性 は、 実用上不十分なことがある。  If the water absorption speed is less than 40 mm, the water absorption and sweat absorption of the fabric may be insufficient for practical use.
本発明の態様 ( 2 ) の偏平マルチフィ ラメ ン ト糸条織物は、 その マルチフィ ラメ ント糸条を構成する単フィ ラメントの断面形状が、 偏平であり、 かつ、 片面当り 3個以上の膨出部と、 その間に形成さ れた 2個以上のくびれ部とを有するため、 互に周面を接する単フィ ラメントの相互摩擦抵抗が小さく、 滑り易いため、 マルチフィラメ ント糸条に押圧が付荷されると、 単フィ ラメ ン トは、 その接触面で 容易に変位して、 糸条は、 偏平に拡がり、 かつ単フィラメントはそ の偏平面において、 互に密接し、 かつ糸条間の間隙を小さく して、 光の透過量を少くすることができる。 In the flat multifilament yarn woven fabric of the embodiment (2) of the present invention, the cross-sectional shape of a single filament constituting the multifilament yarn is as follows. Since it is flat and has three or more bulges on one side and two or more constrictions formed between them, the mutual friction resistance of the single filaments that are in contact with each other is small. Because of the slipperiness, when pressure is applied to the multifilament yarn, the single filament is easily displaced at the contact surface, the yarn spreads flatly, and the single filament spreads that flat. In a plane, they can be in close contact with each other and have a small gap between the yarns, so that the amount of light transmission can be reduced.
また、 この単フィラメントは、 0. 2質量%以上 の艷消し剤を含む から、 得られる織物の光の透過率を低く し、 かつ織物に向って投射 された光線を乱反射することができる。  In addition, since this single filament contains 0.2% by mass or more of the matting agent, it is possible to reduce the light transmittance of the obtained woven fabric and diffusely reflect the light beam projected toward the woven fabric.
さらに、 単フイラメ ントの偏平周面に形成された複数個の膨出部 及びくびれ部は、 前記偏平周面を粗面化して、 光を散乱して透視を 防止することができる。 また、 織物の経 · 緯糸の交差点における偏 平マルチフィラメ ント糸条の偏平化及び拡がりは、 前記交差点を柔 軟にし、 織物の風合を柔かにすることができる。 さ らに、 単フイ ラ メ ン ト周面の、 その長手軸方向に伸びるくびれ.部は、 水又は汗に対 し、 毛細管現象を発現して、 高い吸水速度及び吸汗速度を示すこと ができる。  Furthermore, the plurality of bulges and constrictions formed on the flat peripheral surface of the single filament can roughen the flat peripheral surface, scatter light, and prevent see-through. The flattening and spreading of the flat multifilament yarn at the intersection of the warp and weft of the woven fabric can soften the intersection and soften the texture of the woven fabric. In addition, the constriction extending in the longitudinal axis direction of the peripheral surface of the single filament can exhibit a high water absorption rate and a high water absorption rate by exhibiting a capillary phenomenon against water or sweat. .
従って、 本発明の態様 ( 2 ) の偏平マルチフィ ラメ ン ト糸条織物 は、 高い透視防止性と吸汗性とが要求される用途に用いられる繊維 材料、 例えば裏地、 スポーツ衣料、 ユニホーム衣料など用繊維材料 として有用なものである。  Therefore, the flat multifilament yarn woven fabric according to the aspect (2) of the present invention is a fiber material used for applications requiring high antireflection property and sweat-absorbing property, for example, a fiber for lining, sports clothing, uniform clothing and the like. It is useful as a material.
本発明の偏平マルチフィラメ ント糸条織物の態様 ( 3 ) において 、 前述マルチフイラメ ント糸条の人造フィラメ ントが、 0〜0· 2 質 量%の艷消し剤を含み、 前記織物のカバーファクター (CF) が 800 〜 2000の範囲内にある。  In the aspect (3) of the flat multifilament yarn woven fabric of the present invention, the artificial filament of the multifilament yarn contains 0 to 0.2% by mass of the matting agent, and the cover factor (CF ) Is in the range of 800 to 2000.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ン ト糸条織物において 、 人造フィ ラメ ン トに含まれる艷消し剤の含有量は、 前述のようにIn the flat multifilament yarn woven fabric according to the embodiment (3) of the present invention, However, the content of the anti-glare agent contained in the artificial filament is as described above.
0〜0.2質量%でぁり、 好ましく は、 0〜0.1質量%でぁり、 艷消し 剤が含まれていないこと ( 0質量%) がよ り好ましい。 艷消し剤は 、 従来の艷消し剤、 例えば二酸化チタン、 硫酸バリ ウムなどから選 ぶことができる。 艷消し剤の含有量が 0.2質量%を超えると、 本発 明の態様 ( 3 ) の織物の好ましい用途、 例えば、 カーテンにおいて は、 その光透過率が不十分になり、 従って、 採光性が不満足なもの になることがある。 It is preferably from 0 to 0.2% by mass, more preferably from 0 to 0.1% by mass, and even more preferably not containing an antiglare agent (0% by mass). The antiglare agent can be selected from conventional antiglare agents such as titanium dioxide and barium sulfate. If the content of the anti-glare agent exceeds 0.2% by mass, in the preferred use of the fabric of the embodiment (3) of the present invention, for example, in a curtain, the light transmittance becomes insufficient, and therefore, the lighting property is unsatisfactory. It may be something like that.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ント糸条織物において 、 その偏平マルチフィラメ ント糸条の撚り数は、 0〜1000T/mで あることが好ましく、 より好ましく は 0〜200TZm であり無撚り ( 0 T / m ) であることがさ らに好ましい。  In the flat multifilament yarn woven fabric according to the embodiment (3), the number of twists of the flat multifilament yarn is preferably from 0 to 1000 T / m, more preferably from 0 to 200 TZm and no twist. (0T / m) is more preferable.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ン ト糸条織物の力パー ファクター (CF) は、 前述のように 800〜2000であり、 900〜1800 であることが好ましく、 1000〜 1800であることがさらに好ましい。  As described above, the force factor (CF) of the flat multifilament yarn woven fabric of the embodiment (3) of the present invention is 800 to 2000, preferably 900 to 1800, and more preferably 1000 to 1800. Is more preferred.
力パーファクター (CF) が 800未満であると、 本発明の態様 ( 3 ) の偏平マルチフィ ラメ ント糸条織物の好ましい用途、 例えばカー テンなどにおいて、 経糸 · 緯糸の間隙が大きくなり、 得られる織物 の透視防止法が不十分になる。 またそれが 2000を超えると、 採光性 が不十分となることがある。  When the force factor (CF) is less than 800, the gap between the warp and the weft becomes large in a preferable use of the flat multifilament yarn woven fabric of the embodiment (3) of the present invention, for example, in a curtain, and the obtained woven fabric The method for preventing see-through is insufficient. If it exceeds 2000, the lighting may be insufficient.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ント糸条織物の、 JIS L 1055-1987、 6.1 、 A法 (但し、 照度は 100, OOOlx) によ り測定さ れた光透過率が、 10〜70%であることが好ましく、 20〜50%である ことがよ り好ましい。 前記光透過率 (%) は、 当該織物の遮光率 ( %) を 100 (%) から減算することによ り算出することができる。 この光透過率が、 10%未満であると、 得られた織物の好ましい用途 The light transmittance of the flat multifilament yarn woven fabric of the embodiment (3) of the present invention measured by JIS L 1055-1987, 6.1, A method (illuminance is 100, OOOlx) is 10 to It is preferably 70%, more preferably 20 to 50%. The light transmittance (%) can be calculated by subtracting the light blocking ratio (%) of the woven fabric from 100 (%). When the light transmittance is less than 10%, the preferred use of the obtained fabric is
、 例えばカーテンにおいて、 採光性が不十分になることがあり、 ま た光透過率が 70%を超える と、 得られる織物の透視防止性が、 不十 分になるこ とがある。 For example, in curtains, lighting may be insufficient. If the light transmittance exceeds 70%, the resulting fabric may not be sufficiently transparent.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ント糸条織物は、 無色 (白色) 又は、 淡色乃至中色程度に染色仕上げされることが好まし い。 染色に用いられる染料の種類及び染着量は、 得られる織物の用 途及び所要性能に応じて、 適宜に選択すればよい。  The flat multifilament yarn woven fabric of the embodiment (3) of the present invention is preferably dyed and finished to be colorless (white) or light to medium color. The type and amount of dye used for dyeing may be appropriately selected according to the use of the obtained fabric and the required performance.
本発明の態様 ( 3 ) において、 偏平マルチフィ ラメ ント糸条織物 は、 その経糸と緯糸との交差部において、 偏平マルチフィ ラメ ン ト 糸条は、 その接圧によ り、 偏平に拡がり、 単フィ ラメ ントは、 その 偏平面において、 互に密接して緻密な構造を構成する。 そのため、 経糸及び緯糸の間隙が小さくなり この間隙を透過する光の量が低減 する。 またこの間隙を透過する少量の光は、 この間隙において回折 を生じ、 隣り合った透過光が互に干渉して、 透視防止効果を向上さ せる。 また偏平単フィ ラメ ン トの特殊断面形状によ り、 同一繊度を 有する平滑な周面を有する偏平断面フィラメント、 円形断面フィラ メ ント、 及び三角断面フィ ラメントに対比して、 フィ ラメント周面 における光の乱反射及びフィラメント透過光の屈折が増大し、 この ため、 得られる織物は採光量を低減させることなく優れた透視防止 効果を発現することができる。  In the aspect (3) of the present invention, in the flat multifilament yarn woven fabric, the flat multifilament yarn is flattened by the contact pressure at the intersection of the warp and the weft, and the single filament is woven. The laminations are close to each other on the deviated plane, forming a dense structure. Therefore, the gap between the warp and the weft is reduced, and the amount of light transmitted through the gap is reduced. In addition, a small amount of light transmitted through the gap causes diffraction in the gap, and adjacent transmitted lights interfere with each other to improve the effect of preventing see-through. Also, due to the special cross-sectional shape of the flat single filament, compared to the flat cross-section filament, the circular cross-section filament, and the triangular cross-section filament having the same fineness, the filament circumference Irregular reflection of light and refraction of light transmitted through the filament increase, and thus the obtained woven fabric can exhibit an excellent effect of preventing see-through without reducing the amount of collected light.
また本発明の態様 ( 3 ) の偏平マルチフィ ラメ ン ト糸条織物も、 他の態様と同様に、 柔軟な風合、 低い屈曲抵抗性及び通気性、 並び に,高い摩耗強さ及び吸水 · 吸汗性を示すものである。  Further, the flat multifilament yarn woven fabric of the embodiment (3) of the present invention also has a soft feeling, low bending resistance and air permeability, as well as high abrasion strength and water absorption / perspiration, similarly to the other embodiments. It shows the nature.
本発明の態様 ( 3 ) の偏平マルチフィ ラメ ン ト糸条織物は上記特 性に基づき、 カーテン、 ロールブライ ン ド、 パ一テイ シヨ ンなどの イ ンテリャ用透視防止性繊維材料に有用なものである。 実施例 本発明を、 下記実施例により更に説明する。 伹し、 これら実施例 は、 本願発明の範囲を限定するものではない。 Based on the above characteristics, the flat multifilament yarn woven fabric of the embodiment (3) of the present invention is useful as an anti-transparent fiber material for intellectuals such as curtains, roll blinds, and partitions. is there. Example The present invention is further described by the following examples. However, these examples do not limit the scope of the present invention.
実施例 1 Example 1
ポリ エチレンテレフタレート樹脂を、 紡糸口金に穿孔され、 かつ 図 1 に示されているフィ ラメント断面形状に対応する形状を有する 30個の溶融紡糸孔 (長手中心線の両側に、 片側当り 4個の円弧状膨 出部と、 その間に形成された 3個のくびれ部を有する) を通して、 紡糸温度 300°Cで押出した。 押し出されたフィ ラメ ン ト状溶融体流 を冷却固化しながら、 4000 m Z分の引取り速度で引き取り、 得られ た未延伸マルチフィラメ ントを卷き取ることなく直ちに、 97°Cの温 度において延伸倍率 1. 3で延伸して、 ヤーンカウント力 S、 84dtex/ 30フィ ラメ ントの延伸マルチフィラメ ント糸条を作製した。 この延 伸マルチフィラメントは、 図 1に示されているような断面形状を有 し、 その断面偏平度は 3. 2であり、 フィ ラメ ン ト断面幅における比 C1/ C2の値は、 1. 2 であった。  Polyethylene terephthalate resin was pierced into a spinneret and 30 melt spinning holes with a shape corresponding to the filament cross-sectional shape shown in Fig. 1 (4 circles per side on both sides of the longitudinal center line) (With an arc-shaped bulge and three constrictions formed between them) at a spinning temperature of 300 ° C. The extruded filamentary melt stream is taken off at a take-off speed of 4000 mZ while cooling and solidifying, and the obtained unstretched multifilament is immediately taken up at a temperature of 97 ° C without winding up. In this example, the film was drawn at a draw ratio of 1.3 to prepare a drawn multifilament yarn having a yarn count force S of 84 dtex / 30 filaments. This stretched multifilament has a cross-sectional shape as shown in Fig. 1, its cross-sectional flatness is 3.2, and the value of the ratio C1 / C2 in the filament cross-sectional width is 1. Was 2.
前記偏平マルチフィラメ ント糸条を無撚り のまま、 経糸及び緯糸 として用いて、  The flat multifilament yarn is used as a warp and a weft while being untwisted.
経糸密度 : 101本 / 2. 54cm  Warp density: 101 yarns / 2.54 cm
緯糸密度 : 90本 / 2. 54cm  Weft density: 90 yarns / 2.54cm
の平織物を製造した。 この平織物の偏平マルチフィラメ ント糸条の 含有率は 100%であった。 この平織物に精練、 染色仕上加工を施し た。 仕上げられた平織物の力パーフアクター ( CF) は、 1782であつ た。 Was manufactured. The content of the flat multifilament yarn of this plain fabric was 100%. This plain fabric was scoured and dyed. The finished plain weave had a force perforator (CF) of 1782.
上記仕上平織物を下記試験に供した。  The finished flat woven fabric was subjected to the following test.
( 1 ) 通気度  (1) Air permeability
供試織物の通気度は、 J I S L 1096-1998、 6. 27. 1 、 A法 (フラジ ール形試験機法) に従って測定された。 ( 2 ) 摩耗強さ The air permeability of the test fabric was measured according to JISL 1096-1998, 6.27.1, Method A (Frazil-type testing machine method). (2) Wear strength
供試織物の摩耗強さは、 JIS L 1096-1998、 6.17.1 、 ( 1 ) A— 1法 (平面法) によ り測定された。  The wear strength of the test fabric was measured by the JIS L 1096-1998, 6.17.1, (1) A-1 method (plane method).
( 3 ) 吸水性  (3) Water absorption
供試織物の吸水速度は、 JIS L 1096-1998、 6.26.1 , ( 2 ) B法 (パイ レック法) によ り測定された。  The water absorption rate of the test fabric was measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrek method).
( 4 ) 風合い  (4) Texture
手の触感によ り、 下記 5段階に分類し評価した。  Based on the tactile sensation of the hand, the following five levels were used for evaluation.
5級 きわめて柔軟性が高く、 風合はきわめて優れている。  Class 5 Extremely high flexibility and excellent texture.
4級 柔軟性が高く、 風合が優れている。  Class 4 High flexibility and excellent texture.
3級 柔軟性は良好であり、 風合も良好である。  Class 3 The flexibility is good and the feeling is good.
2級 柔軟性がやや不十分であり、 風合もやや不満足である。 Level 2 The flexibility is somewhat insufficient, and the feeling is somewhat unsatisfactory.
1級 柔軟性が不良であり、 風合も不良である。 Class 1 Poor flexibility and poor feeling.
( 5 ) 総合評価  (5) Overall evaluation
下記 4段階に評価した。  The following four levels were evaluated.
4級 きわめて優れている。  Grade 4 Excellent.
3級 優れている。  Class 3 Excellent.
2級 やや不満足  Level 2 Somewhat unsatisfactory
1級 不良  Grade 1 bad
評価結果を表 1 に示す。  Table 1 shows the evaluation results.
実施例 2 Example 2
実施例 1 と同様にして偏平マルチフィラメ ント糸条平織物を製造 し、 試験を行った。 但し、 偏平フィ ラメ ン トの断面形状において、 長手中心線に関し、 片面当り 円弧状膨出部の数を 3個、 くびれ部の 数を 2個とし、 断面偏平度 (BZC1) を 3.2、 比 C1/C2を 1.2とし た。 得られた平織物の力パーファクター (CF) は、 1782であった。 試験成績を表 1 に示す。 比較例 1 In the same manner as in Example 1, a flat multifilament yarn flat woven fabric was manufactured and tested. However, in the cross-sectional shape of the flat filament, the number of arc-shaped bulges per side was set to three, the number of constrictions was set to two, and the flatness of the cross-section (BZC1) was 3.2 with respect to the longitudinal center line. / C2 is set to 1.2. The force per factor (CF) of the obtained plain fabric was 1782. Table 1 shows the test results. Comparative Example 1
実施例 1 と同様にして偏平マルチフィラメ ント糸条平織物を製造 し、 試験を行った。 但し、 偏平フィラメ ントの断面形状を、 くびれ 部のないものと した。 (断面偏平度 = 3. 2、 比 Cl / C2 = 1. 0) 。 得ら れた平織物の力パーファクターは 1782であった。  In the same manner as in Example 1, a flat multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the flat filament has no constriction. (Section flatness = 3.2, ratio Cl / C2 = 1.0). The resulting strength factor of the plain weave was 1782.
比較例 2 Comparative Example 2
実施例 1 と同様にしてマルチフィラメ ント糸条平織物を製造し、 試験を行った。 但し、 フィ ラメ ントの断面形状を、 円形に変更した 。 得られた平織物の力パーファクター (CF) は 1782であった。 試験 成績を表 1 に示す。  A multifilament yarn flat woven fabric was manufactured and tested in the same manner as in Example 1. However, the cross-sectional shape of the filament was changed to a circle. The strength factor (CF) of the obtained plain fabric was 1782. Table 1 shows the test results.
表 1  table 1
Figure imgf000025_0001
実施例 3
Figure imgf000025_0001
Example 3
艷消し剤と して、 2. 5質量% の二酸化チタンを含むポリエチレン テレフタレー ト樹脂を、 紡糸口金に穿孔され、 かつ図 1 に示されて いるフィラメ ン ト断面形状に対応する形状を有する 30個の溶融紡糸 孔 (長手中心線の両側に、 片側当り 4個の円弧状膨出部と、 その間 に形成された 3個のくびれ部を有する) を通して、 紡糸温度 300°C で押出した。 押し出されたフイラメ ント状溶融'体流を冷却固化しな がら、 4000m/分の引取り速度で引き取り、 得られた未延伸マルチ フィラメ ントを卷き取ることなく直ちに、 97°Cの温度において延伸 倍率 1.3で延伸して、 ヤーンカウントが、 84dtex/30フィラメ ント の延伸マルチフィ ラメ ント糸条を作製した。 この延伸マルチフィ ラ メントは、 図 1に示されているような断面形状を有し、 その断面偏 平度は 3.2であり、 フィラメント断面幅における比 C1/C2の値は、 1.2 であった。 A polyethylene terephthalate resin containing 2.5% by mass of titanium dioxide was used as an anti-glare agent. 30 pieces of this resin were punched into the spinneret and had a shape corresponding to the filament cross-sectional shape shown in Fig. 1. At a spinning temperature of 300 ° C. through a melt spinning hole (having four arc-shaped bulges on each side and three constrictions formed therebetween) on both sides of the longitudinal center line. Do not cool and solidify the extruded The undrawn multifilament was drawn at a drawing speed of 97 m / min and immediately stretched at a temperature of 97 ° C at a draw ratio of 1.3 without winding, and the yarn count was 84 dtex / 30 filament. The drawn multifilament yarn of the fiber was prepared. This drawn multifilament had a cross-sectional shape as shown in FIG. 1, the cross-sectional flatness was 3.2, and the value of the ratio C1 / C2 in the cross-sectional width of the filament was 1.2.
前記マルチフイラメ ント糸条を無撚りのまま、 経糸及び緯糸と し て用いて、  The multifilament yarn is used as a warp and a weft while being untwisted.
経糸密度 : 101本 2.54cm  Warp density: 101 2.54cm
緯糸密度 : 84本 /2.54cm  Weft density: 84 yarns / 2.54cm
の平織物を製造した。 この平織物の偏平マルチフィラメント糸条の 含有率は 100%であった。 この平織物に精練、 染色仕上加工を施し た。 仕上げられた平織物の力パーファクター (CF) は、 1700であつ た。 ' Was manufactured. The content of the flat multifilament yarn of this plain fabric was 100%. This plain fabric was scoured and dyed. The finished plain weave had a force factor (CF) of 1700. '
上記織物を下記試験に供した。  The above woven fabric was subjected to the following test.
( 1 ) 透視防止度  (1) Degree of fluoroscopy prevention
JIS Z 8729- 1994、 L * a * b *表色系において、 供試織物を白色板 上に載置したときの L* 値 (L*wと記す) と、 それと黒色板上に载 置したときの L* 値 (L*bと記す) との差 (= L% - L*b) を 求め、 この をもって、 供試織物の透視防止度を表した。 JIS Z 8729-1994, L * a * b * color system, L * value when the test sample was placed on a white plate (L * w ) and it was placed on a black plate L * value (L * b hereinafter) the difference between the time (= L% - L * b ) the determined, with this, showing the perspective prevention of the test test weaving thereof.
( 2 ) 吸水性  (2) Water absorption
実施例 1 と同様に、 供試織物の吸水速度は、 JIS L 1096-1998、 6 .26.1 、 ( 2 ) B法 (パイレック法) によ り測定された。  As in Example 1, the water absorption rate of the test fabric was measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrex method).
( 3 ) 風合い  (3) Texture
実施例 1 と同様に、 手の触感によ り、 下記 5段階に分類し評価し た。 5級 きわめて柔軟性が高く、 風合はきわめて優れている。 In the same manner as in Example 1, evaluation was made based on the tactile sensation of the hands in the following five categories. Class 5 Extremely high flexibility and excellent texture.
4級 柔軟性が高く、 風合が優れている。  Class 4 High flexibility and excellent texture.
3級 柔軟性は良好であり、 風合も良好である。  Class 3 The flexibility is good and the feeling is good.
2級 柔軟性がやや不十分であり、 風合もやや不満足である。 1級 柔軟性が不良であり、 風合も不良である。  Level 2 The flexibility is somewhat insufficient, and the feeling is somewhat unsatisfactory. Class 1 Poor flexibility and poor feeling.
( 4 ) 総合評価  (4) Overall evaluation
実施例 1 と同様に、 下記のように 4段階に評価した。  As in Example 1, evaluation was made in four steps as follows.
4級 きわめて優れている。  Grade 4 Excellent.
3級 優れている。  Class 3 Excellent.
2級 やや不満足  Level 2 Somewhat unsatisfactory
1級 不良  Grade 1 bad
評価結果を表 2に示す。  Table 2 shows the evaluation results.
実施例 4 Example 4
実施例 .3 と同様にして偏平マルチフィラメ ント糸条平織物を製造 し、 試験を行った。 但し、 偏平フィ ラメ ン トの断面形状において、 長手中心線に関し、 片面当り液状膨出部の数を 3個、 くびれ部の数 を 2個と し、 断面偏平度 (BZC1) を 3.2、 比 C1ZC2を 1.2と した 。 得られた平織物の力パーファクター (CF) は、 1700であった。 試 験成績を表 2に示す。  In the same manner as in Example 3, a flat multifilament yarn flat woven fabric was manufactured and tested. However, in the cross-sectional shape of the flat filament, the number of liquid swelling portions per side was set to 3 and the number of constrictions was set to 2 per side, and the cross-sectional flatness (BZC1) was 3.2, and the ratio was C1ZC2. Was changed to 1.2. The force per factor (CF) of the obtained plain fabric was 1,700. Table 2 shows the test results.
比較例 3 Comparative Example 3
実施例 3 と同様にして偏平マルチフィラメント糸条平織物を製造 し、 試験を行った。 伹し、 偏平フィ ラメ ン トの断面形状を、 くびれ 部のないものと した。 (断面偏平度 =3.2、 比 C1ZC2 1.0) 。 得ら れた平織物のカバーファクターは 1700であった。 試験成績を表 2に 示す。  In the same manner as in Example 3, a flat multifilament yarn flat woven fabric was manufactured and tested. On the other hand, the cross-sectional shape of the flat filament has no constriction. (Section flatness = 3.2, ratio C1ZC2 1.0). The cover factor of the obtained plain fabric was 1,700. Table 2 shows the test results.
比較例 4 Comparative Example 4
実施例 3 と同様にしてマルチブイラメ ント糸条平織物を製造し、 試験を行った。 但し、 フィ ラメ ン トの断面形状を、 円形に変更したA multi-filament yarn flat woven fabric was manufactured in the same manner as in Example 3. The test was performed. However, the cross-sectional shape of the filament was changed to a circle.
。 得られた平織物のカバ一ファクター (CF) は 1700であった。 試験 成績を表 2に示す。 . The cover factor (CF) of the obtained plain fabric was 1,700. Table 2 shows the test results.
表 2  Table 2
Figure imgf000028_0001
実施例 5
Figure imgf000028_0001
Example 5
ポリ エチレンテレフタ レート樹脂 (艷消剤を含まない) を、 紡糸 口金に穿孔され、 かつ図 1に示されているフィ ラメ ン ト断面形状に 対応する形状を有する 30個の溶融紡糸孔 (長手中心線の両側に、 片 側当 り 4個の円弧状膨出部と、 その間に形成された 3個のくびれ部 を有する) を通して、 紡糸温度 300°Cで押出した。 押し出されたフ イラメ ント状溶融体流を冷却固化しながら、 4000m /分の引取り速 度で引き取り、 得られた未延伸マルチフィ ラメ ントを卷き取ること なく直ちに、 97°Cの温度において延伸倍率 1. 3で延伸して、 ヤーン カウントが、 84dt exZ 30フイ ラメ ントの延伸マルチフィラメント糸 条を作製した。 この延伸マルチフィラメントは、 図 1 に示されてい るよ うな断面形状を有し、 その断面偏平度は 3. 2であり、 フィ ラメ ント断面幅における比 C1Z C2の値は、 1. 2 であった。  Thirty melt spinning holes (longitudinal) made of a polyethylene terephthalate resin (not containing an anti-glare agent) were punched into the spinneret and had a shape corresponding to the filament cross-sectional shape shown in Fig. 1. (Four arc-shaped bulges per side, and three constrictions formed between them) on both sides of the center line) at a spinning temperature of 300 ° C. While cooling and solidifying the extruded filamentary melt stream, it is drawn at a take-up speed of 4000 m / min, and the obtained undrawn multifilament is drawn immediately at a temperature of 97 ° C without winding up. The drawn multifilament yarn having a yarn count of 84 dt exZ 30 filament was drawn at a magnification of 1.3. This drawn multifilament has a cross-sectional shape as shown in Fig. 1, its cross-sectional flatness is 3.2, and the value of the ratio C1Z C2 in the filament cross-sectional width is 1.2. Was.
前記マルチフィ ラメ ン ト糸条を無撚りのまま、 経糸及び緯糸と し て用いて、 The multifilament yarn is used as warp and weft without twisting. Using
経糸密度 : 63本 / 2. 54cm  Warp density: 63 yarns / 2.54cm
緯糸密度 : 52本/ 2. 54cm  Weft density: 52 yarns / 2.54 cm
の平織物を製造した。 この平織物の偏平マルチフィラメ ント糸条の 含有率は 100 %であった。 この平織物に精練、 染色仕上加工を施し た。 仕上げられた平織物の力パーファクター (CF) は、 1000であつ た。 Was manufactured. The content of the flat multifilament yarn of this plain fabric was 100%. This plain fabric was scoured and dyed. The finished plain weave had a force factor (CF) of 1,000.
上記偏平マルチフィラメ ント平織物を下記試験に供した。  The flat multifilament plain woven fabric was subjected to the following test.
( 1 ) 光透過率  (1) Light transmittance
供試織物を、 JI S L 1055-1987、 6. 1 、 A法 (伹し、 照度を 100 , 0 OOlx) による遮光率 (%) 測定に供し、 得られた遮光率 (%) から 、 下記式によ り光透過率 (%) を算出した。  The test fabric was subjected to the light-shielding rate (%) measurement according to JI SL 1055-1987, 6.1, Method A (I, illuminance: 100, 0OOlx), and from the obtained light-shielding rate (%), the following formula was used. The light transmittance (%) was calculated from the equation.
光透過率 (%) = 100 —遮光率 (%)  Light transmittance (%) = 100 — Light blocking rate (%)
( 2 ) 透視防止性  (2) Anti-transparency
昼間透視防止性  Daytime perspective prevention
室内用 80W蛍光灯による、 照度 700 lxの室内に、 透視すべき物 品 (色 : 赤、 形状 : 直方体、 寸法 : 15cm X 7 cm X 7 cm) を、 供試織 物の 1表面から 20cm離れた位置に置き、 供試織物の他の表面から 30 cm離れた室外の位置 (昼間太陽光、 照度 100 , 000 lx) に、 物品視 認者の眼を位置させ、 物品視認者が、 供試織物を介して、 物品を透 視したときの、 その物品の昼間透視防止性の程度を下記 4段階に評 価した。  An object to be seen through (color: red, shape: rectangular parallelepiped, dimensions: 15cm x 7cm x 7cm) is placed 20cm away from one surface of the test sample in a room with an illuminance of 700 lx using an 80W fluorescent lamp for indoor use. Position, and place the eye of the article observer in an outdoor location (daylight, illuminance 100,000 lx) 30 cm away from the other surface of the fabric to be tested. The following four levels were used to evaluate the degree of daytime visibility of the article when the article was seen through a woven fabric.
4級 物品を全く認識できない。  Class 4 The product cannot be recognized at all.
3級 物品をわずかに認識できる。  Class 3 Goods can be recognized slightly.
2級 物品の輪郭がほぼ認識できる。  Class 2 The outline of the article can be almost recognized.
1級 物品を明確に認識できる。  First-class goods can be clearly recognized.
夜間透視防止性 昼間透視防止性試験方法と同様にして、 夜間透視防止性を試験し た。 但し、 物品視認者は、 夜間室外 (照度 : 0. 2 lx) に位置させ た。 Night fluoroscopy prevention The nighttime perspective prevention was tested in the same manner as the daytime perspective prevention test method. However, the article viewer was located outside the room at night (illuminance: 0.2 lx).
夜間透視防止性の程度を、 昼間の場合と同様に 4段階に評価した 試験結果を表 3に示す。  Table 3 shows the results of a test in which the degree of nighttime fluoroscopy prevention was evaluated in four stages, as in the case of daytime.
実施例 6 Example 6
実施例 5 と同様にして、 偏平マルチフィラメ ント糸条平織物を製 造し、 試験を行った。  In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
但し、 平織物の織組織を、 経密度 : 55本 Z2. 54cm、 緯密度 : 36本 Z2. 54cmに変更し、 従ってそのカバーファクタ一 ( CF) を 880に変 更した。  However, the weaving structure of the plain woven fabric was changed to a warp density: 55 strands Z2.54 cm and a weft density: 36 strands Z2.54 cm. Therefore, its cover factor (CF) was changed to 880.
試験成績を表 3に示す。  Table 3 shows the test results.
実施例 7 Example 7
実施例 5 と同様にして、 偏平マルチフィ ラ メ ン ト糸条平織物を製 造し、 試験を行った。  In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
伹し、 平織物の織組織を、 経密度 : 112本/ 2. 54cm、 緯密度 : 74 本 / 2. 54cmに変更し、 その力パーファクター (CF) を、 1800に変更 した。  The weaving structure of the plain woven fabric was changed to a warp density: 112 / 2.54 cm, a weft density: 74 / 2.54 cm, and the force factor (CF) was changed to 1800.
試験成績を表 3に示す。  Table 3 shows the test results.
実施例 8 Example 8
実施例 5 と同様にして偏平マルチフィラメ ント糸条平織物を製造 し、 試験を行った。  In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested.
但し、 偏平マルチフィ ラメ ン ト糸条に、 撚り数 : 200 T Z mの撚 りを施した。 得られた平織物の力パーファクターは 1000であった。 試験成績を表 3に示す。  However, the flat multifilament yarn was twisted at a twist of 200 TZm. The power factor of the obtained plain fabric was 1000. Table 3 shows the test results.
比較例 5 実施例 5 と同様にして偏平マルチフィラメ ント糸条平織物を製造 し、 試験を行った。 伹し、 偏平フィ ラメ ントの断面形状を、 くびれ 部のないものとした。 (断面偏平度 = 3. 2、 比 C1Z C2 = 1. 0) 。 得ら れた平織物の力パーフ了クターは 1000であった。 試験成績を表 3に 示す。 Comparative Example 5 In the same manner as in Example 5, a flat multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the flat filament has no constriction. (Section flatness = 3.2, ratio C1Z C2 = 1.0). The obtained plain fabric had a power perfume doctor of 1,000. Table 3 shows the test results.
比較例 6 Comparative Example 6
実施例 5 と同様にしてマルチフィラメ ント糸条平織物を製造し、 試験を行った。 伹し、 マルチフィ ラメ ン トの断面形状を三角形に変 更した。 得られた織物の力パーファクタ一は 1000であった。 試験成 績を表 3に示す。  In the same manner as in Example 5, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The resulting fabric had a power factor of 1,000. Table 3 shows the test results.
比較例 7 Comparative Example 7
実施例 5 と同様にしてマルチフィラメント糸条平織物を製造し、 試験を行った。 但し、 フィ ラメ ン トの断面形状を、 円形に変更した 。 得られた平織物のカバーファクター (CF) は 1000であった。 試験 成績を表 3に示す。  A multifilament yarn flat woven fabric was manufactured and tested in the same manner as in Example 5. However, the cross-sectional shape of the filament was changed to a circle. The cover factor (CF) of the obtained plain fabric was 1,000. Table 3 shows the test results.
比較例 8 Comparative Example 8
実施例 6 と同様にして、 マルチフィ ラメント糸条平織物を製造し 、 試験を行った。 但し、 マルチフィ ラメ ン トの断面形状を三角形に 変更した。 得られた平織物の力パーファクター (CF) は 880であつ た。 試験成績を表 3に示す。  In the same manner as in Example 6, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The resulting plain weave had a power factor (CF) of 880. Table 3 shows the test results.
比較例 9 Comparative Example 9
実施例 7 と同様にして、 マルチフィ ラメント糸条平織物を製造し 、 試験を行った。 但し、 マルチフィ ラメ ントの断面形状を三角形に 変更した。 得られた平織物のカバーファクター (CF) は 1800であつ た。 試験成績を表 3に示す。 In the same manner as in Example 7, a multifilament yarn flat woven fabric was manufactured and tested. However, the cross-sectional shape of the multifilament was changed to a triangle. The cover factor (CF) of the obtained plain fabric was 1,800. Table 3 shows the test results.
Figure imgf000032_0001
産業上の利用可能性
Figure imgf000032_0001
Industrial applicability
本発明の偏平マルチフィラメ ン ト糸条織物は、 その単フイ ラメ ン トの特殊断面形状によ り単フィ ラメ ン ト間の滑りがよく、 経糸と緯 糸との交差点における接触圧力によ り、 マルチフィ ラメ ント糸条が 偏平化して拡がり、 糸条間の空隙を小さくなるから、 通気度を適宜 にコン ト口ールすることができ、 得られる織物の摩耗強さが高く、 吸水 · 吸汗性に優れ、 光透過性を、 著しく低下させることなく、 入 射された光を回折及び乱反射して散乱させ、 透視性を低下させるこ とができる。 従って、 本発明の偏平マルチフィラメ ント糸条織物は 、 低通気度繊維材料、 透視防止性繊維材料、 吸水 · 吸汗性繊維材料 及び採光性 · 透視防止性繊維材料などと して有用なものである。  In the flat multifilament yarn woven fabric of the present invention, the slippage between the single filaments is good due to the special cross-sectional shape of the single filament, and the contact pressure at the intersection between the warp and the weft is good. Since the multifilament yarns are flattened and spread, and the gaps between the yarns are reduced, the air permeability can be appropriately controlled, and the obtained fabric has high abrasion strength, and water absorption and sweat absorption. It is excellent in light transmittance, and can diffract and diffuse the incident light without remarkably lowering the light transmittance, thereby lowering the transparency. Therefore, the flat multifilament yarn woven fabric of the present invention is useful as a low-permeability fiber material, a see-through preventing fiber material, a water-absorbing / sweat-absorbing fiber material, and a light-collecting / see-through preventing fiber material. .

Claims

求 の 範 囲 Range of request
1 . 繊維形成性人造重合体を主成分として含み、 偏平な断面形状 を有する複数本の人造フィラメントからなるマルチフィ ラメ ン ト糸 条を、 経糸及びノ又は緯糸と して含む織物であって、 1. A woven fabric comprising a multifilament yarn comprising a plurality of artificial filaments having a flat cross-sectional shape as a warp and a knot or a weft, containing a fiber-forming artificial polymer as a main component,
前記人造フィ ラメ ントの偏平断面において、 その長手中心線の両 き青  In the flat cross section of the artificial filament, both blue lines of the longitudinal center line
側に、 前記長手中心線の外側に向って膨出している片面当り 3個以 上の膨出部と、 これら膨出部の間に形成された片面当り 2個以上の くびれ部とが、 前記長手中心線に関してほぼ対称に形成されており 、 前記異形断面の、 長手中心線方向の長さ (B ) の、 この長手中心 線方向に直角をなす方向における最大幅 (C1) に対する比 (B Z C1 ) によ り表される断面偏平度が 2〜 6の範囲内にあり、 On the side, there are three or more bulges per side bulging outwardly of the longitudinal center line, and two or more constrictions per side formed between these bulges, It is formed substantially symmetrically with respect to the longitudinal center line, and the ratio (BZ C1) of the length (B) of the irregular cross section to the maximum width (C1) in the direction perpendicular to the longitudinal center line direction ) Is in the range of 2 to 6,
織物全体と して、 800〜3500 の力パーファクターを有することを 特徴とする偏平マルチフィ ラメ ン ト糸条織物。  A flat multi-filament yarn woven fabric having a force par factor of 800 to 3500 as the whole woven fabric.
2 . 前記繊維形成性人造重合体が、 ポリエステル、 ポリアミ ド、 ポリ塩化ビニリデン、 ポリ プロ ピレン、 再生セルロース、 及び酢酸 セルロースから選ばれる、 請求の範囲第 1項に記載の偏平マルチフ イ ラメ ント糸条織物。  2. The flat multi-filament yarn according to claim 1, wherein the fiber-forming artificial polymer is selected from polyester, polyamide, polyvinylidene chloride, polypropylene, regenerated cellulose, and cellulose acetate. fabric.
3 . 前記人造フィ ラメ ン トの偏平断面において、 その幅の最大値 ( C1) の、 最小値 (C2) に対する比 (C1/ C2) 、 1. 05〜4. 00であ る、 請求の範囲第 1項に記載の偏平マルチフィラメ ント糸条織物。  3. The ratio (C1 / C2) of the maximum value (C1) of the width of the artificial filament to the minimum value (C2) in the flat section of the artificial filament is 1.05 to 4.00. 2. The flat multifilament yarn woven fabric according to item 1.
4 . 前記マルチフィ ラメ ン ト糸条の合計繊度は、 30〜: L70dtex で あり、 その単フイラメ ント繊度は、 0. 5〜 5 dtex である、 請求の範 囲第 1項に記載の偏平マルチフィラメ ント糸条織物。  4. The flat multifilament according to claim 1, wherein the total fineness of the multifilament yarn is 30 to: L70 dtex, and the single filament fineness is 0.5 to 5 dtex. Thread fabric.
5 . 前記織物が、 平織組織、 綾織組織、 サテン織組織から選ばれ る織組織を有する、 請求の範囲第 1項に記載の偏平マルチフィラメ ント糸条織物。 5. The flat multifilament yarn woven fabric according to claim 1, wherein the woven fabric has a woven structure selected from a plain woven structure, a twill woven structure, and a satin woven structure.
6. 前記織物に含まれる前記偏平断面形状を有する人造フィラメ ントからなるマルチフィ ラメ ント糸条の含有率は、 10〜; 100質量0 /0 である、 請求の範囲第 1項に記載の偏平マルチフィ ラメ ント糸条織 物。 6. The content of the consisting artificial Firame cement having a flat sectional shape Maruchifi lame cement yarns included in the fabric, 10; 100 mass 0/0, flat according to claim 1 Maruchifi Laminate yarn fabric.
7. 前記力パーファクター値が、 1500〜3500の範囲内にある、 請 求の範囲第 1項に記載の偏平マルチフィラメ ント糸条織物。  7. The flat multifilament yarn fabric of claim 1, wherein said force per factor value is in the range of 1500-3500.
8. 前記マルチフィ ラメ ン ト糸条が、 0〜2500T//mの撚り数を 有する、 請求の範囲第 7項に記載の偏平マルチフィ ラメント糸条織 物。 8. The Maruchifi lame down bets yarn has a twist number 0~2500T / / m, flat Maruchifi Lament yarn woven product according to claim 7.
9. 前記織物の、 JIS L 1096-1998、 6.27.1 、 A法 (フラジール 形試験機法) によ り測定された通気度が、 5 mlZcm2 · sec以下であ る、 請求の範囲第 7項に記載の偏平マルチフィ ラメ ント糸条織物。 9. The air permeability of the woven fabric measured by JIS L 1096-1998, 6.27.1, Method A (Fragile type testing machine method) is 5 mlZcm 2 · sec or less. 9. The flat multifilament yarn woven fabric according to the above item.
10. 前記通気度が 0.1~4.0mlZcm2 · secの範囲内にある、 請求の 範囲第 9項に記載の偏平マルチフィラメント糸条織物。 10. The flat multifilament yarn woven fabric according to claim 9, wherein the air permeability is in a range of 0.1 to 4.0 mlZcm 2 · sec.
11. 前記織物の、 JIS L 1096-1998、 6.26· 1 、 ( 2 ) B法 (パイ レック法) により測定された吸水速度が、 40mm以上である、 請求の 範囲第 7項に記載の偏平マルチフィラメ ント糸条織物。  11. The flat mulch according to claim 7, wherein the woven fabric has a water absorption rate measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrec method) of 40 mm or more. Filament yarn fabric.
12. 前記織物の JIS L 1096-1998、 6.17.1 、 ( 1 ) A— 1法 (平 面法) によ り測定された摩耗強さが、 50回以上である、 請求の範囲 第 7項に記載の偏平マルチフィ ラメ ン ト糸条織物。  12. The woven fabric according to claim 7, wherein the abrasion strength of the woven fabric measured by JIS L 1096-1998, 6.17.1, (1) A-1 method (flat surface method) is 50 times or more. 2. The flat multifilament yarn woven fabric according to claim 1.
13. 請求の範囲第 7〜: 12項のいずれか 1項に記載の偏平マルチフ イ ラメ ント糸条織物を含む、 低通気度繊維材料。  13. A low-permeability fiber material comprising the flat multi-filament yarn woven fabric according to any one of claims 7 to 12.
14. 前記マルチフィ ラメ ン ト糸条の人造フィ ラメ ントが 0.2質量 %以上の艷消し剤を含み、 かつ前記織物の力パーファタターが 1300 〜 3000の範囲内にある、 請求の範囲第 1項に記載の偏平マルチフィ ラメ ント糸条織物。  14. The artificial filament of the multifilament yarn contains 0.2% by mass or more of a matting agent, and the woven fabric has a force perfatator in a range of 1300 to 3000. Flat filament yarn fabric.
15. 前記マルチフィ ラメ ン ト糸条が 0〜: 1500TZmの撚り数を有 する、 請求の範囲第 14項に記載の偏平マルチフィラメ ント糸条織物 15. The multifilament yarn has a twist of 0 ~: 1500TZm. 15. The flat multifilament yarn woven fabric according to claim 14,
16. 前記織物が、 JIS Z 8729-1994、 L * a * b *表色系において、 白色板上に置かれたときの L * 値 (L ) と、 黒色板上に置かれた ときの L* 値 (L *b) との差 (= L % - L \) によ り表される 透視防止度が、 15以下である、 請求の範囲第 14項に記載の偏平マル チフイ ラメ ント糸条織物。 16. In the JIS Z 8729-1994, L * a * b * color system, the L * value (L) when the fabric is placed on a white plate and the L when the fabric is placed on a black plate 15. The flat multi-filament yarn according to claim 14, wherein the degree of prevention of see-through represented by a difference (= L%-L \) from the value (L * b ) is 15 or less. fabric.
17. 前記織物の、 JIS L 1096-1998、 6.26.1 , ( 2 ) B法 (パイ レック法) によ り測定された吸水速度が、 40mm以上である、 請求の 範囲第 14項に記載の偏平マルチフィラメ ント糸条織物。  17. The woven fabric according to claim 14, wherein a water absorption rate of the woven fabric measured by JIS L 1096-1998, 6.26.1, (2) B method (Pyrec method) is 40 mm or more. Flat multifilament yarn fabric.
18. 請求の範囲第 14〜: 17項のいずれか 1項に記載の偏平マルチフ イラメ ント糸条織物を含む、 透視防止性 · 吸汗性繊維材料。  18. A see-through preventing / sweat-absorbing fiber material, comprising the flat multifilament yarn woven fabric according to any one of claims 17 to 17.
19. 前記マルチフィ ラメ ント糸条の人造フィ ラメ ン トが 0〜0.2 質量%の艷消し剤を含み、 前記織物の力パーファクターが 800〜20 00の範囲内にある、 請求の範囲第 1項に記載の偏平マルチフィラメ ント糸条織物。  19. The multifilament yarn of claim 1 wherein the artificial filament comprises 0-0.2% by weight of the matting agent and the woven fabric has a force factor in the range of 800-200000. 2. The flat multifilament yarn woven fabric according to claim 1.
20. 前記マルチフィラメ ント糸条が 0〜1000T/mの燃り数を有 する、 請求の範囲第 19項に記載の偏平マルチフィラメ ント糸条織物  20. The flat multifilament yarn woven fabric according to claim 19, wherein the multifilament yarn has a burning number of 0 to 1000 T / m.
21. 前記織物の、 JIS L 1055-1987、 6.1、 A法 (伹し、 照度は 10 万 lx) により測定された光透過率が 10~70%である、 請求の範囲第 19項に記載の偏平マルチフィラメ ント糸条織物。 21. The fabric according to claim 19, wherein the woven fabric has a light transmittance of 10 to 70% as measured by JIS L 1055-1987, 6.1, Method A (伹, illuminance is 100,000 lx). Flat multifilament yarn fabric.
22. 請求の範囲第 19〜21項のいずれか 1項に記載の偏平マルチフ イ ラメ ント糸条織物を含む、 透視防止性繊維材料。  22. A see-through preventing fiber material, comprising the flat multifilament yarn woven fabric according to any one of claims 19 to 21.
PCT/JP2003/009277 2002-07-24 2003-07-22 Flat multifilament-yarn textile WO2004009889A1 (en)

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Application Number Priority Date Filing Date Title
CN038014491A CN1585841B (en) 2002-07-24 2003-07-22 Flat multifilament-yarn textile and textile material
EP03741538.7A EP1524343B1 (en) 2002-07-24 2003-07-22 Flat multifilament-yarn textile
US10/490,410 US20050176323A1 (en) 2002-07-24 2003-07-22 Flat multifilament-yarn textile
CA2461551A CA2461551C (en) 2002-07-24 2003-07-22 Flat multifilament yarn woven fabric
KR1020047004204A KR101017876B1 (en) 2002-07-24 2003-07-22 Flat multifilament-yarn textile

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JP2002214953A JP3895227B2 (en) 2002-07-24 2002-07-24 Apparel-related products
JP2002-214953 2002-07-24
JP2002216419A JP2004060064A (en) 2002-07-25 2002-07-25 Transparency preventing woven fabric having perspiration absorbing property
JP2002-216419 2002-07-25
JP2002-327949 2002-11-12
JP2002327949A JP4065764B2 (en) 2002-11-12 2002-11-12 Interior goods using anti-visibility textiles

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008035443A1 (en) 2006-09-20 2008-03-27 Teijin Fibers Limited Filter for extracting luxury drink and bag for extracting luxury drink
US11197386B2 (en) 2019-12-11 2021-12-07 Phoenix Contact Development and Manufacturing, Inc. Removable I/O module with diagnostics for a field device I/O connector

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005095690A1 (en) 2004-03-31 2005-10-13 Kb Seiren, Ltd. Polyester woven fabric
JP4007994B2 (en) * 2005-03-10 2007-11-14 ジャパンゴアテックス株式会社 Fiber products
JP4837346B2 (en) * 2005-09-20 2011-12-14 日本ゴア株式会社 Seal tape and textiles using the same
US8236714B2 (en) * 2005-12-13 2012-08-07 INVISTA North America S.à.r.l. Dyed fabric with visible and near infrared differential yarn fiber signature
ES2427982B1 (en) * 2012-03-29 2014-09-10 Jordi Galan Llongueras Ultralight flat weave from 2 weft directions
CN102677272A (en) * 2012-05-29 2012-09-19 蔡紫林 Curtain fabric
CN102677340A (en) * 2012-05-29 2012-09-19 蔡紫林 Window curtain fabric
CN102677281A (en) * 2012-05-29 2012-09-19 蔡紫林 Fabric
TWI613338B (en) * 2012-08-02 2018-02-01 東麗股份有限公司 Fabrics using a flat multi-lobar cross-section fiber and sewn product using the same
CN102936774A (en) * 2012-11-23 2013-02-20 苏州巨源纤维科技有限公司 Fiber
US20160076173A1 (en) * 2013-03-27 2016-03-17 Toray Industries, Inc. Spun yarn and woven or knitted fabric
CN105209674A (en) 2013-05-14 2015-12-30 旭化成纤维株式会社 Abrasion-resistant fabric
US9693409B1 (en) * 2016-05-24 2017-06-27 Richard Deniken Textile with integrated illumination feature
JP6346363B1 (en) 2017-08-16 2018-06-20 東洋紡Stc株式会社 fabric
CN108977952A (en) * 2018-08-01 2018-12-11 浙江竟成特种单丝有限公司 A kind of six disjunctor flat filaments
JP6627011B1 (en) * 2018-08-06 2019-12-25 花王株式会社 Stretchable sheet for absorbent article and method for producing the same
GB2580490B (en) * 2018-08-06 2021-02-24 Kao Corp Stretch sheet for absorbent article and method for producing the same
IT201900000496A1 (en) * 2019-01-11 2020-07-11 Chiorino Spa Ribbon comprising a fabric with bilateral satin weave
US11702772B2 (en) * 2020-05-21 2023-07-18 Burlington Industries Llc Wool fabric with stretch properties and garments made therefrom

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS626983A (en) * 1985-06-28 1987-01-13 ユニチカ株式会社 Water absorbable cloth
JPH02221411A (en) * 1989-02-16 1990-09-04 Toray Ind Inc Polyester multifilament yarn having flat cross section and woven or knit fabric using the same yarn
JPH02234915A (en) * 1989-03-08 1990-09-18 Kuraray Co Ltd Polyester fiber having excellent water absorptivity and hand
JPH0424214A (en) * 1990-05-21 1992-01-28 Toray Ind Inc Modified-cross-section polyester fiber
JPH05195367A (en) * 1992-01-16 1993-08-03 Teijin Ltd Ultraviolet ray-screening woven fabric
JPH07145575A (en) * 1993-11-17 1995-06-06 Toray Ind Inc Anti-see-through fabric tape for print and its production
JPH0860425A (en) * 1994-08-23 1996-03-05 Unitika Ltd Fiber for air bag
JPH11222721A (en) * 1998-02-09 1999-08-17 Asahi Chem Ind Co Ltd Profile shaped polyester multifilament and production of the same and knit fabric
JPH11286848A (en) * 1998-02-09 1999-10-19 Asahi Chem Ind Co Ltd High-density polyester woven fabric
WO2002014590A1 (en) 2000-08-17 2002-02-21 Toray Industries, Inc. Air-bag-use non-coat base cloth and air-bag-use fiber

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4634625A (en) * 1984-10-25 1987-01-06 E. I. Du Pont De Nemours And Company New fabrics, yarns and process
US4643119A (en) * 1985-07-12 1987-02-17 Exxon Chemical Patents Inc. Industrial textile fabric
US5236775A (en) * 1990-02-12 1993-08-17 Hoechst Aktiengesellschaft Fabric for airbag
US5626961A (en) * 1995-06-30 1997-05-06 E. I. Du Pont De Nemours And Company Polyester filaments and tows
US5704402A (en) * 1996-04-01 1998-01-06 Milliken Research Corporation Air bag fabric
US5834119A (en) * 1997-01-03 1998-11-10 E. I. Du Pont De Nemours And Company Filament cross-sections
JP2004052167A (en) * 2002-07-22 2004-02-19 Teijin Fibers Ltd Bulky knit having sweat-absorbing property and drape

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS626983A (en) * 1985-06-28 1987-01-13 ユニチカ株式会社 Water absorbable cloth
JPH02221411A (en) * 1989-02-16 1990-09-04 Toray Ind Inc Polyester multifilament yarn having flat cross section and woven or knit fabric using the same yarn
JPH02234915A (en) * 1989-03-08 1990-09-18 Kuraray Co Ltd Polyester fiber having excellent water absorptivity and hand
JPH0424214A (en) * 1990-05-21 1992-01-28 Toray Ind Inc Modified-cross-section polyester fiber
JPH05195367A (en) * 1992-01-16 1993-08-03 Teijin Ltd Ultraviolet ray-screening woven fabric
JPH07145575A (en) * 1993-11-17 1995-06-06 Toray Ind Inc Anti-see-through fabric tape for print and its production
JPH0860425A (en) * 1994-08-23 1996-03-05 Unitika Ltd Fiber for air bag
JPH11222721A (en) * 1998-02-09 1999-08-17 Asahi Chem Ind Co Ltd Profile shaped polyester multifilament and production of the same and knit fabric
JPH11286848A (en) * 1998-02-09 1999-10-19 Asahi Chem Ind Co Ltd High-density polyester woven fabric
WO2002014590A1 (en) 2000-08-17 2002-02-21 Toray Industries, Inc. Air-bag-use non-coat base cloth and air-bag-use fiber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1524343A4

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008035443A1 (en) 2006-09-20 2008-03-27 Teijin Fibers Limited Filter for extracting luxury drink and bag for extracting luxury drink
US11197386B2 (en) 2019-12-11 2021-12-07 Phoenix Contact Development and Manufacturing, Inc. Removable I/O module with diagnostics for a field device I/O connector

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CA2461551A1 (en) 2004-01-29
CN1585841B (en) 2011-03-16
TW200402488A (en) 2004-02-16
TWI329147B (en) 2010-08-21
CA2461551C (en) 2011-12-06
US20050176323A1 (en) 2005-08-11
EP1524343B1 (en) 2013-05-15
EP1524343A1 (en) 2005-04-20
CN1585841A (en) 2005-02-23

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