WO2004007607A1 - Mit polymeren phosphorigsäureestern stabilisierte thermoplaste - Google Patents

Mit polymeren phosphorigsäureestern stabilisierte thermoplaste Download PDF

Info

Publication number
WO2004007607A1
WO2004007607A1 PCT/EP2003/007094 EP0307094W WO2004007607A1 WO 2004007607 A1 WO2004007607 A1 WO 2004007607A1 EP 0307094 W EP0307094 W EP 0307094W WO 2004007607 A1 WO2004007607 A1 WO 2004007607A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
component
compositions according
bis
group
Prior art date
Application number
PCT/EP2003/007094
Other languages
German (de)
English (en)
French (fr)
Inventor
Thomas Braig
Dietmar Bielefeldt
Urs-Peter Dorsch
Karsten-Josef Idel
Annett KÖNIG
Lars Rodefeld
Claus-Ludolf Schultz
Original Assignee
Lanxess Deutschland Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland Gmbh filed Critical Lanxess Deutschland Gmbh
Priority to DE50307251T priority Critical patent/DE50307251D1/de
Priority to AU2003249943A priority patent/AU2003249943A1/en
Priority to EP03763696A priority patent/EP1523520B1/de
Priority to US10/520,796 priority patent/US20060014864A1/en
Priority to JP2004520470A priority patent/JP2005532458A/ja
Publication of WO2004007607A1 publication Critical patent/WO2004007607A1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/529—Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients

Definitions

  • the silane compounds are generally used in amounts of 0.05 to, preferably 0.5 to 1.5 and in particular 0.8 to 1% by weight, based on the mineral filler, for surface coating.
  • thermoplastic different from the thermoplastic used as component B, can be used as component E.
  • Copolycarbonates can also be used.
  • copolycarbonates are in particular polydiorganosiloxane-polycarbonate block copolymers whose weight average molar mass (Mw) is preferably 10,000 to 200,000 g / mol, particularly preferably 20,000 to 80,000 g / mol (determined by gel chromatography after prior calibration by Light scattering measurement or ultracentrifugation).
  • Mw weight average molar mass
  • the content of aromatic carbonate structure units in the polydiorganosiloxane-polycarbonate block copolymers is preferably 75 to 97.5% by weight, particularly preferably 85 to 97% by weight.
  • the graft F.2 95 to 5, preferably 70 to 10% by weight of one or more graft bases with glass transition temperatures ⁇ 10 ° C, preferably ⁇ 0 ° C, particularly preferably ⁇ -20 ° C.
  • the graft F.2 has an average particle size (d 5 o value) microns in general from 0.05 to 10, preferably from 0.1 microns to 5, particularly preferably 0.2 to 1 micron.
  • Pure polybutadiene rubber is particularly preferred.
  • crosslinking monomers are the cyclic monomers triallyl cyanurate, trialiyl isocyanurate, triacryloylliexahydro-s-rriazine, triallylbenzenes.
  • the amount of crosslinked monomers is preferably 0.02 to 5, in particular 0.05 to 2% by weight, based on the graft base F.2.
  • Preferred "other" polymerizable, ethylenically unsaturated monomers which, in addition to the acrylic acid esters, can optionally be used to prepare the graft base F.2 are, for. B. acrylonitrile, styrene, ⁇ -methyl styrene, acrylamides, vinyl-Ci- C 6 alkyl ether, methyl methacrylate, butadiene.
  • Preferred acrylate rubbers as Graft base F.2 are emulsion polymers which have a gel content of at least 60% by weight.
  • Component AI polymeric polyphosphoric acid ester
  • GPC eluent: tetrahydrofuran, refractive index (Rl) detector, penetration according to DIN 55672-1, calibrated against polystyrene standards

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/EP2003/007094 2002-07-11 2003-07-03 Mit polymeren phosphorigsäureestern stabilisierte thermoplaste WO2004007607A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE50307251T DE50307251D1 (en) 2002-07-11 2003-07-03 Mit polymeren phosphorigsäureestern stabilisierte thermoplaste
AU2003249943A AU2003249943A1 (en) 2002-07-11 2003-07-03 Thermoplastic materials that are stabilized with polymer phosphite esters
EP03763696A EP1523520B1 (de) 2002-07-11 2003-07-03 Mit polymeren phosphorigsäureestern stabilisierte thermoplaste
US10/520,796 US20060014864A1 (en) 2002-07-11 2003-07-03 Thermoplastic materials that are stabilised with polmeric phosphite esters
JP2004520470A JP2005532458A (ja) 2002-07-11 2003-07-03 ポリマー亜リン酸エステルで安定化された熱可塑性プラスチック

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10231334A DE10231334A1 (de) 2002-07-11 2002-07-11 Mit polymeren Phosphorigsäureestern stabilisierte Thermoplaste
DE10231334.2 2002-07-11

Publications (1)

Publication Number Publication Date
WO2004007607A1 true WO2004007607A1 (de) 2004-01-22

Family

ID=29761883

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/007094 WO2004007607A1 (de) 2002-07-11 2003-07-03 Mit polymeren phosphorigsäureestern stabilisierte thermoplaste

Country Status (9)

Country Link
US (1) US20060014864A1 (US20050137174A1-20050623-C00027.png)
EP (1) EP1523520B1 (US20050137174A1-20050623-C00027.png)
JP (1) JP2005532458A (US20050137174A1-20050623-C00027.png)
KR (1) KR100938957B1 (US20050137174A1-20050623-C00027.png)
CN (1) CN1681879A (US20050137174A1-20050623-C00027.png)
AU (1) AU2003249943A1 (US20050137174A1-20050623-C00027.png)
DE (2) DE10231334A1 (US20050137174A1-20050623-C00027.png)
ES (1) ES2286466T3 (US20050137174A1-20050623-C00027.png)
WO (1) WO2004007607A1 (US20050137174A1-20050623-C00027.png)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008016260A1 (de) 2008-03-29 2009-10-01 Bayer Materialscience Ag Schlagzähmodifizierte Polyalkylenterephthalat/Polycarbonat-Zusammensetzungen
WO2012025481A1 (de) 2010-08-24 2012-03-01 Bayer Materialscience Ag SCHLAGZÄHMODIFIZIERTE POLYESTER/POLYCARBONAT-ZUSAMMENSETZUNGEN MIT VERBESSERTER REIßDEHNUNG

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101903659B1 (ko) 2011-09-30 2018-10-04 다우 글로벌 테크놀로지스 엘엘씨 폴리카르보네이트 및 폴리프로필렌의 난연성 열가소성 조성물
US9375968B2 (en) * 2012-01-19 2016-06-28 Covestro Deutschland Ag Plastic film for printing by dye diffusion thermal transfer printing
KR20160009715A (ko) 2014-07-15 2016-01-27 에스케이플래닛 주식회사 잔금 포인트 적립 시스템, 포인트 제공 장치 및 이를 이용한 포인트 제공 방법
EP3262123B1 (en) 2015-02-23 2019-04-17 SABIC Global Technologies B.V. Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof
EP3262117B1 (en) * 2015-02-23 2019-05-08 SABIC Global Technologies B.V. Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof
EP3660064A1 (de) * 2018-11-28 2020-06-03 LANXESS Deutschland GmbH Zubereitungen mit verbesserter wirksamkeit als flammschutzmittel
CN113227230B (zh) 2018-12-20 2023-04-04 朗盛德国有限责任公司 聚酯组合物
EP4074718A1 (de) 2021-04-15 2022-10-19 LANXESS Deutschland GmbH Stabilisatoren für polymere

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2615341A1 (de) * 1976-04-08 1977-10-27 Bayer Ag Phosphorigsaeureester enthaltende polyalkylenterephthalate
DE4244028A1 (de) * 1992-12-24 1994-06-30 Bayer Ag Thermoplastische Formmassen mit wiederaufbereiteten Formmassen entsprechender Zusammensetzung
EP0776934A1 (de) * 1995-11-30 1997-06-04 Bayer Ag Mit Phosphorigsäureestern stabilisierte Polymer-Formmassen
WO2002034833A1 (de) * 2000-10-25 2002-05-02 Bayer Aktiengesellschaft Mit phosphorigsäureestern stabilisierte polyalkylenterephthalat-zusammensetzungen

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3022272A (en) * 1962-02-20 Process for the production of high
DE1007996B (de) * 1955-03-26 1957-05-09 Bayer Ag Verfahren zur Herstellung thermoplastischer Kunststoffe
US2991273A (en) * 1956-07-07 1961-07-04 Bayer Ag Process for manufacture of vacuum moulded parts of high molecular weight thermoplastic polycarbonates
US3148172A (en) * 1956-07-19 1964-09-08 Gen Electric Polycarbonates of dihydroxyaryl ethers
US2999846A (en) * 1956-11-30 1961-09-12 Schnell Hermann High molecular weight thermoplastic aromatic sulfoxy polycarbonates
US3062781A (en) * 1958-07-02 1962-11-06 Bayer Ag Process for the production of polycarbonates
US2999835A (en) * 1959-01-02 1961-09-12 Gen Electric Resinous mixture comprising organo-polysiloxane and polymer of a carbonate of a dihydric phenol, and products containing same
US3028635A (en) * 1959-04-17 1962-04-10 Schlumberger Cie N Advancing screw for gill box
US3189662A (en) * 1961-01-23 1965-06-15 Gen Electric Organopolysiloxane-polycarbonate block copolymers
US3288864A (en) * 1962-05-11 1966-11-29 Union Carbide Corp Reaction products of isopropenyl phenols and of linear dimers thereof
US3378524A (en) * 1964-05-12 1968-04-16 First Nat Bank Of Morgantown Tetrachloro bisphenol a phosphite resins
US3442864A (en) * 1965-06-30 1969-05-06 Diamond Alkali Co Formals of norbornane-2,7-diols and copolymers thereof with trioxane
US3419634A (en) * 1966-01-03 1968-12-31 Gen Electric Organopolysiloxane polycarbonate block copolymers
FR1580834A (US20050137174A1-20050623-C00027.png) * 1968-01-04 1969-09-12
US3644574A (en) * 1969-07-17 1972-02-22 Eastman Kodak Co Shaped articles of blends of polyesters and polyvinyls
US3879348A (en) * 1970-12-22 1975-04-22 Bayer Ag Saponification-resistant polycarbonates
DE2255639C3 (de) * 1972-11-14 1981-11-19 Bayer Ag, 5090 Leverkusen Ester der phosphorigen Säure
US4073769A (en) * 1971-08-11 1978-02-14 Bayer Aktiengesellschaft Esters of phosphorous acid
US4323501A (en) * 1971-08-11 1982-04-06 Bayer Aktiengesellschaft Esters of phosphorous acid
US4013613A (en) * 1971-10-01 1977-03-22 General Electric Company Reinforced intercrystalline thermoplastic polyester compositions
US3821325A (en) * 1973-03-23 1974-06-28 Gen Electric Organopolysiloxane-polycarbonate block copolymers
US3832419A (en) * 1973-03-23 1974-08-27 Gen Electric Organopolysiloxane-polycarbonate block copolymers
US4035958A (en) * 1973-03-30 1977-07-19 Tokyo Kosei Kaken Co. Ltd. Mobile floor cleaning and polishing device
US3956229A (en) * 1974-07-16 1976-05-11 Allied Chemical Corporation Films and sheets of polyester-polycarbonate blends
US4066617A (en) * 1975-12-22 1978-01-03 Mobay Chemical Corporation Stabilized poly(alkylene terephthalates)
DE2715932A1 (de) * 1977-04-09 1978-10-19 Bayer Ag Schnellkristallisierende poly(aethylen/alkylen)-terephthalate
US4334106A (en) * 1981-02-05 1982-06-08 The Upjohn Company Process for the preparation of hydroxyphenyl-indanols
DE3631539A1 (de) * 1986-09-17 1988-03-24 Bayer Ag Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit
DE3631540A1 (de) * 1986-09-17 1988-03-24 Bayer Ag Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit
DE3704655A1 (de) * 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
DE3704657A1 (de) * 1987-02-14 1988-08-25 Bayer Ag Teilchenfoermige mehrphasenpolymerisate
DE3738143A1 (de) * 1987-11-10 1989-05-18 Bayer Ag Verwendung von redoxpfropfpolymerisaten zur verbesserung der benzinbestaendigkeit von thermoplastischen, aromatischen polycarbonat- und/oder polyestercarbonat-formmassen
US5227458A (en) * 1988-08-12 1993-07-13 Bayer Aktiengesellschaft Polycarbonate from dihydroxydiphenyl cycloalkane
NO170326C (no) * 1988-08-12 1992-10-07 Bayer Ag Dihydroksydifenylcykloalkaner
DE3842219A1 (de) * 1988-12-15 1990-06-21 Bayer Ag Stabilisierte thermoplastische formmassen
US5231124A (en) * 1988-12-15 1993-07-27 Bayer Aktiengesellschaft Stabilized thermoplastic molding compositions
DE4238123C2 (de) * 1992-11-12 2000-03-09 Bayer Ag Verfahren zur Herstellung von thermoplastischen Polycarbonaten
DE4312390A1 (de) * 1993-04-16 1994-10-20 Bayer Ag Zweistufen-Verfahren zur Herstellung von thermoplastischem Polycarbonat
DE19539290A1 (de) * 1995-10-23 1997-04-24 Bayer Ag Verfahren zur Herstellung von Poly-(diorganosiloxan)-Polycarbonat-Blockcopolymeren
DE19643280A1 (de) * 1996-10-21 1998-04-23 Basf Ag Flammgeschützte Formmassen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2615341A1 (de) * 1976-04-08 1977-10-27 Bayer Ag Phosphorigsaeureester enthaltende polyalkylenterephthalate
DE4244028A1 (de) * 1992-12-24 1994-06-30 Bayer Ag Thermoplastische Formmassen mit wiederaufbereiteten Formmassen entsprechender Zusammensetzung
EP0776934A1 (de) * 1995-11-30 1997-06-04 Bayer Ag Mit Phosphorigsäureestern stabilisierte Polymer-Formmassen
WO2002034833A1 (de) * 2000-10-25 2002-05-02 Bayer Aktiengesellschaft Mit phosphorigsäureestern stabilisierte polyalkylenterephthalat-zusammensetzungen

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008016260A1 (de) 2008-03-29 2009-10-01 Bayer Materialscience Ag Schlagzähmodifizierte Polyalkylenterephthalat/Polycarbonat-Zusammensetzungen
WO2012025481A1 (de) 2010-08-24 2012-03-01 Bayer Materialscience Ag SCHLAGZÄHMODIFIZIERTE POLYESTER/POLYCARBONAT-ZUSAMMENSETZUNGEN MIT VERBESSERTER REIßDEHNUNG
DE102010039712A1 (de) 2010-08-24 2012-03-01 Bayer Materialscience Aktiengesellschaft Schlagzähmodifizierte Polyester/Polycarbonat-Zusammensetzungen mit verbesserter Reißdehnung

Also Published As

Publication number Publication date
ES2286466T3 (es) 2007-12-01
DE10231334A1 (de) 2004-01-22
CN1681879A (zh) 2005-10-12
KR100938957B1 (ko) 2010-01-26
KR20060066664A (ko) 2006-06-16
AU2003249943A1 (en) 2004-02-02
JP2005532458A (ja) 2005-10-27
DE50307251D1 (en) 2007-06-21
EP1523520B1 (de) 2007-05-09
EP1523520A1 (de) 2005-04-20
US20060014864A1 (en) 2006-01-19

Similar Documents

Publication Publication Date Title
EP1355987B1 (de) Flammwidrige; mineralverstärkte polycarbonatzusammensetzungen mit hoher bindenahtfestigkeit
EP1756223B1 (de) Formmassen auf basis eines thermoplastischen polyesters mit verbesserter fliessfähigkeit
WO2009080244A1 (de) Flammgeschützte schlagzähmodifizierte polyalkylenterephthalat/polycarbonat-zusammensetzungen
EP2841501B1 (de) Pc/abs-zusammensetzungen mit guter thermischer und chemischer beständigkeit
EP1570002B1 (de) Flammwidrige polycarbonat-zusammensetzungen mit phosphor-silizium-verbindungen
EP1790692A2 (de) Formmassen auf Basis eines thermoplastischen Polyesters mit verbesserter Fliessfähigkeit
DE10128174A1 (de) Schlagzähmodifizierte Polymer-Zusammensetzung
EP1523520B1 (de) Mit polymeren phosphorigsäureestern stabilisierte thermoplaste
EP1373408B1 (de) Flammwidrige polycarbonat-zusammensetzungen mit erhöhter chemikalienbeständigkeit
EP0783019A1 (de) Thermoplastische Massen mit verbessertem Röntgenkontrast
EP2262853B1 (de) Schlagzählmodifizierte polyalkylenterephthalat/polycarbonat-zusammensetzungen
WO2007147490A1 (de) Verfahren zur herstellung schlagzähmodifizierter polyalkylenterephthalat/polycarbonat-zusammensetzungen
EP1339795B1 (de) Mit phosphorigsäureestern stabilisierte polyalkylenterephthalat-zusammensetzungen
EP0456030A2 (de) Polycarbonat-ABS-Formmassen
WO2022218593A1 (de) Stabilisatoren für polymere
EP4288490A1 (de) Polycarbonat-polyester zusammensetzung, formmasse und formkörper mit guter schlagzähigkeit und hoher thermischer belastbarkeit
EP1583799A1 (de) Homogen durchgefärbte zusammensetzungen auf basis schlagzähmodifizierten polyalkylenterephthalat/polycarbonat blends
DE102005009201A1 (de) Formmassen auf Basis eines thermoplastischen Polyesters mit verbesserter Fließfähigkeit

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2003763696

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 57/DELNP/2005

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 1020057000459

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2004520470

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 20038216353

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2003763696

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2006014864

Country of ref document: US

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 10520796

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 10520796

Country of ref document: US

WWG Wipo information: grant in national office

Ref document number: 2003763696

Country of ref document: EP