WO2003102067A1 - Solution acceleratrice permettant de durcir des resines de polyester non saturees, dont l'utilisation dans des denrees alimentaires a ete approuvee - Google Patents

Solution acceleratrice permettant de durcir des resines de polyester non saturees, dont l'utilisation dans des denrees alimentaires a ete approuvee Download PDF

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Publication number
WO2003102067A1
WO2003102067A1 PCT/EP2003/004235 EP0304235W WO03102067A1 WO 2003102067 A1 WO2003102067 A1 WO 2003102067A1 EP 0304235 W EP0304235 W EP 0304235W WO 03102067 A1 WO03102067 A1 WO 03102067A1
Authority
WO
WIPO (PCT)
Prior art keywords
cobalt
unsaturated polyester
solution according
solvent
accelerator solution
Prior art date
Application number
PCT/EP2003/004235
Other languages
English (en)
Inventor
Anna Gerdine Van De Bovenkamp-Bouwman
Johannes Martinus Gerardus Maria Reijnders
Original Assignee
Akzo Nobel N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V. filed Critical Akzo Nobel N.V.
Priority to JP2004510315A priority Critical patent/JP2005528496A/ja
Priority to AU2003229721A priority patent/AU2003229721A1/en
Priority to EP03722536A priority patent/EP1507823A1/fr
Publication of WO2003102067A1 publication Critical patent/WO2003102067A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
    • C08F299/0442—Catalysts
    • C08F299/045—Peroxy-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators

Definitions

  • the invention relates to an accelerator solution for curing an unsaturated polyester resin comprising a solvent and a cobalt-containing salt.
  • the curing process to which the present invention relates is a conventional hardening process of unsaturated polyester-based formulations, wherein the curing is effected by means of peroxides.
  • An accelerator solution is added to promote and accelerate said curing process. More particularly, it serves to specifically increase the activity of the peroxide at lower temperatures and consequently to speed up the rate of hardening of the polyester resin, resulting in a reduced hardening time.
  • Such an accelerator solution is known from JP-A-57 147509, wherein the solution contains a solvent, an organic cobalt compound, an organic copper salt, and an alkali metal carboxylate.
  • the mixture of metal salts poses a problem with respect to suitability for food-related applications.
  • aromatic compounds e.g., the aromatic solvents that are listed, are undesired.
  • the invention consists of an accelerator solution suitable for peroxide curing of an unsaturated polyester resin which consists essentially of said solvent or solvents, one or more cobalt-containing salts, and, optionally, one or more stabilizers. Addition of a stabilizer to the accelerator solution generally improves its stability.
  • Solvents used in the present invention should fulfill the requirement of being non-toxic and thus applicable in food-related applications. Furthermore, the solvent should not or should not be suspected to significantly burden the environment. Aromatic solvents generally do not meet these requirements and are less preferred.
  • the one or more accelerators present in the accelerator solution according to the invention viz. the cobalt-containing salt or salts, must further be sufficiently soluble in the solvent, for which the solvent preferably comprises one or more polar groups, for example a hydroxyl or a carboxylate group.
  • the cobalt-containing salt or salts are considered to be sufficiently soluble in the solvent if at least 1%w/w of said salt or salts can be dissolved in 99%w/w of solvent.
  • the solvent preferably does not adversely affect the accelerating properties of the cobalt-containing salt(s). It is also contemplated that the solvent is already present during the preparation of the cobalt salt(s). Accordingly, it is preferred that the solvent is inert in this reaction mixture, after which the solution is used for curing of unsaturated polyester resins (UP resins). Preferably, the solvent has a melting point below 0°C. Moreover, the solvent employed in the present invention preferably is a non-hygroscopic solvent.
  • suitable solvents are alkanes such as pentane, isopentane, and hexane; glycols such as diethyleneglycol, dipropyleneglycol, and ethyleneglycol; isobutanol; pentanol; phosphor-containing compounds such as triethylphosphate and triethylphosphite; and esters such as dibutylmaleate, dibutylsuccinate, and ethylacetate.
  • Preferred solvents are triethylphosphate, triethylphosphite, isopentane, ethyleneglycol, diethyleneglycol, and ethylacetate.
  • ethyleneglycol More preferred are ethyleneglycol, diethyleneglycol, triethylphosphate, and triethylphosphite. It is also contemplated to use a mixture of at least two of the aforementioned solvents. However, it is preferred to use only one.
  • the accelerator solution comprises at least 20 percent by weight (%w/w), preferably at least 25%w/w, and most preferably at least 30%w/w, and at most 99%w/w, preferably at most 98%w/w, and most preferably at most 95%w/w of the solvent, all based on the weight of the total accelerator solution.
  • the one or more accelerators of the present invention are chosen such that they generally are soluble in the unsaturated polyester resin.
  • Suitable accelerators are cobalt-containing salts selected from cobalt acetate, cobalt proprionate, cobalt butyrate, cobalt 2-ethylhexanoate, cobalt hexanoate, cobalt octoate, cobalt laurate, cobalt oleate, cobalt linoleate, cobalt palmitate, cobalt stearate, cobalt acetylacetonate, and cobalt naphthenate.
  • the most preferred accelerator solutions essentially contain cobalt octoate, cobalt 2- ethylhexanoate and/or cobalt naphthenate as metal salts.
  • cobalt-containing salts may be employed, it is preferred to use only one of them.
  • the cobalt-containing salt can be combined with another metal-containing accelerator.
  • a metal-containing accelerator can be selected from the group consisting of conventional salts of one or more carboxylic acids with one or more of the metals and complexes of metals selected from the group consisting of lithium, copper, potassium, manganese, magnesium, vanadium, and iron.
  • the accelerator solution can comprise at least 1%w/w, preferably at least 2%w/w, and most preferably at least 5%w/w, and at most 80%w/w, preferably at most 75%w/w, and most preferably at most 70%w/w of the accelerator or combined accelerators, all based on the weight of the total accelerator solution.
  • the accelerator solution consists essentially of accelerator and solvent.
  • one or more stabilizers may be added to improve the stability of the accelerator solution.
  • Stabilizers suitable for the present invention are compounds that typically prevent crystallization of the cobalt salt or salts in the solution, for example tertiary amines such as triethanol amine and dimethylamino ethanol, and secondary amines such as diethanol amine. These stabilizers preferably are non-toxic and suitable for food-related applications. For this reason, aromatic amines are not preferred. These stabilizers are added to the solution in at least 0.1%w/w, preferably at least 0.2%w/w, and most preferably at least 0.5%w/w, and at most 8%w/w, preferably at most 6%w/w, and most preferably at most 4%w/w of the stabilizer, all based on the weight of the total accelerator solution.
  • the curing process of the present invention comprises the addition of an accelerator solution according to the invention to one or more conventional resins and/or pre-polymers and preferably at least one peroxide, followed by mixing and dispersing.
  • the curing process is preferably carried out at ambient temperatures commonly used in applications such as hand lay-up, spray-up, filament winding, resin transfer moulding, coating (e.g. gel-coat and standard coatings), button production, centrifugal casting, corrugated sheets or flat panels, relining systems, kitchen sinks via pouring compounds, etc.
  • coating e.g. gel-coat and standard coatings
  • button production e.g. gel-coat and standard coatings
  • centrifugal casting corrugated sheets or flat panels
  • relining systems relining systems
  • kitchen sinks via pouring compounds etc.
  • it can also be used in SMC, BMC, pulltrusion techniques, and the like, for which temperatures up to 180°C, more preferably up to 150°C, most preferably up to 100°C are used.
  • the resin or pre-polymer can be selected from any conventional resin.
  • it is chosen from the group consisting of conventional unsaturated polyesters, including so-called ortho resins, iso-resins, iso-npg resins, vinyl ester resins, acrylic resins, and dicyclopentadiene resins.
  • ortho resins such resins are maleic, allylic, vinylic, and epoxy-type materials, combined with at least one ethylenically unsaturated reactive monomer.
  • Preferred ethylenically unsaturated reactive monomers include styrene and styrene derivatives such as ⁇ -methylstyrene, vinyltoluene, indene, divinyl benzene, stilbene, but also diallylphtalate, dibenzylideneacetone, allyl benzene; triallyl cyanurate, triallyl isocyanurate, and mixtures thereof.
  • the amount of ethylenically unsaturated reactive monomer is at least 0.1%w/w, based on the weight of the resin, preferably at least 1%w/w, and most preferably at least 5%w/w, and at most 50%w/w, preferably at most 40%w/w, and most preferably at most 35%w/w.
  • the accelerator solution is generally employed in a conventional amount. Amounts of at least 0.1%w/w, preferably at least 0.25%w/w, and at most 5%w/w, preferably at most 2%w/w of the accelerator solution, based on the weight of the resin, are typically used.
  • Peroxides suitable for the curing of UP resins include organic peroxides, such as conventionally used ketone peroxide, perester, and peroxydicarbonate. The skilled person will understand that these peroxides can be combined with conventional additives, for instance phlegmatizers, such as hydrophilic esters and hydrocarbon solvents.
  • the amount of peroxide formulation to be used in the curing process is at least 0.1 %w/w, preferably at least 0.5%w/w, and most preferably at least 1%w/w, and at most 8%w/w, preferably at most 5%w/w, most preferably at most 2%w/w, all based on the weight of the resin.
  • the UP resin is first mixed with the ethylenically unsaturated reactive monomer.
  • the accelerator composition can be added in several different manners and may have been pre-mixed with the monomer or resin.
  • the peroxide formulation can be added directly to the mixture. However, it can also be first mixed with the monomer or resin. Care is to be taken that the peroxide formulation and the accelerator solution are not pre-mixed, since this will be hazardous.
  • the cured UP resin may be applied in food-related applications.
  • These resins can be employed in glass reinforced and non-glass reinforced products which come into contact with potable liquids, such as wine, water, whiskey, cognac, milk etc., and food articles such as vegetables or meat.
  • the UP resin may also be used in for example pipes, boxes or truck panels. The invention is elucidated in the following examples.
  • An example of an accelerator solution according to the invention is a solution in triethylphosphate containing 35%w/w cobalt 2-ethylhexanoate. Also a composition further containing 2%w/w of triethanolamine was prepared. Both solutions show a good storage stability. The solvent triethylphosphate as well as the stabilizer triethanolamine is food-approved. The curing of a UP resin with Butanox M50 ® in which these accelerator formulations are used was identical to the curing with conventional accelerator compositions which are not food- approved. The UP resin resulting from the curing process in the presence of the accelerator solution is suitable for food-related applications.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerization Catalysts (AREA)

Abstract

L'invention se rapporte à une solution accélératrice permettant de durcir une résine de polyester non saturée qui est constituée sensiblement d'un ou de plusieurs solvants, d'un ou de plusieurs sels contenant du cobalt, et éventuellement d'un ou de plusieurs stabilisateurs. Le solvant, le sel et le stabilisateur sont des composés dont l'utilisation dans des denrées alimentaires a été approuvée. Ladite solution est utilisée pour durcir des résines de polyester non saturées qui sont appropriées pour des utilisations associées aux denrées alimentaires.
PCT/EP2003/004235 2002-05-30 2003-04-22 Solution acceleratrice permettant de durcir des resines de polyester non saturees, dont l'utilisation dans des denrees alimentaires a ete approuvee WO2003102067A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2004510315A JP2005528496A (ja) 2002-05-30 2003-04-22 不飽和ポリエステル樹脂硬化用の、食品用に認可された促進剤溶液
AU2003229721A AU2003229721A1 (en) 2002-05-30 2003-04-22 A food approved accelerator solution for curing unsaturated polyester resins
EP03722536A EP1507823A1 (fr) 2002-05-30 2003-04-22 Solution acceleratrice permettant de durcir des resines de polyester non saturees, dont l'utilisation dans des denrees alimentaires a ete approuvee

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02077125.9 2002-05-30
EP02077125 2002-05-30

Publications (1)

Publication Number Publication Date
WO2003102067A1 true WO2003102067A1 (fr) 2003-12-11

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PCT/EP2003/004235 WO2003102067A1 (fr) 2002-05-30 2003-04-22 Solution acceleratrice permettant de durcir des resines de polyester non saturees, dont l'utilisation dans des denrees alimentaires a ete approuvee

Country Status (4)

Country Link
EP (1) EP1507823A1 (fr)
JP (1) JP2005528496A (fr)
AU (1) AU2003229721A1 (fr)
WO (1) WO2003102067A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1342739A1 (fr) * 2002-03-06 2003-09-10 Atofina Chemicals, Inc. Systèm de accelerateur à base de alcanolamines pour la durcissement de resine polyester insaturée
WO2006034981A1 (fr) * 2004-09-28 2006-04-06 Akzo Nobel N.V. Polymerisation de resine de polyester aqueuse insaturee impliquant un accelerateur au cobalt et un compose de complexation
WO2006128816A1 (fr) * 2005-05-31 2006-12-07 Akzo Nobel N.V. Solution d'accelerateur stable au stockage

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2132234T3 (pl) * 2007-04-02 2013-09-30 Akzo Nobel Chemicals Int Bv Roztwór przyspieszacza
TWI439451B (zh) * 2011-03-24 2014-06-01 Hoffmann La Roche 雜環胺衍生物
AR099141A1 (es) * 2014-02-11 2016-06-29 Akzo Nobel Chemicals Int Bv Proceso para el curado de una resina de poliéster insaturado o resina de éster de vinilo que contiene (met)acrilato y composición de resina curable radicalmente resultante

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2930089A (en) * 1955-12-16 1960-03-29 Rolls Royce Precision casting
GB860701A (en) * 1958-02-24 1961-02-08 Konink Ind Mij Voorheen Noury An improved catalyst for the copolymerisation of unsaturated polyester resins
US3555117A (en) * 1968-12-10 1971-01-12 Grace W R & Co Product and a method of improving the shelf life of uncured polyesters
US3645908A (en) * 1966-09-23 1972-02-29 Elektrochem Werke Muenchen Ag Ketone peroxide composition stabilized with an amine
US3668139A (en) * 1968-12-10 1972-06-06 Grace W R & Co Catalyst and method of polyester polymerization
US4175064A (en) * 1978-09-28 1979-11-20 Tenneco Chemicals, Inc. Accelerator systems for the peroxide-catalyzed curing of unsaturated polyester resin compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2930089A (en) * 1955-12-16 1960-03-29 Rolls Royce Precision casting
GB860701A (en) * 1958-02-24 1961-02-08 Konink Ind Mij Voorheen Noury An improved catalyst for the copolymerisation of unsaturated polyester resins
US3645908A (en) * 1966-09-23 1972-02-29 Elektrochem Werke Muenchen Ag Ketone peroxide composition stabilized with an amine
US3555117A (en) * 1968-12-10 1971-01-12 Grace W R & Co Product and a method of improving the shelf life of uncured polyesters
US3668139A (en) * 1968-12-10 1972-06-06 Grace W R & Co Catalyst and method of polyester polymerization
US4175064A (en) * 1978-09-28 1979-11-20 Tenneco Chemicals, Inc. Accelerator systems for the peroxide-catalyzed curing of unsaturated polyester resin compositions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1342739A1 (fr) * 2002-03-06 2003-09-10 Atofina Chemicals, Inc. Systèm de accelerateur à base de alcanolamines pour la durcissement de resine polyester insaturée
WO2006034981A1 (fr) * 2004-09-28 2006-04-06 Akzo Nobel N.V. Polymerisation de resine de polyester aqueuse insaturee impliquant un accelerateur au cobalt et un compose de complexation
WO2006128816A1 (fr) * 2005-05-31 2006-12-07 Akzo Nobel N.V. Solution d'accelerateur stable au stockage
CN101184781B (zh) * 2005-05-31 2010-10-13 阿克佐诺贝尔股份有限公司 储存稳定的促进剂溶液
US8268189B2 (en) 2005-05-31 2012-09-18 Akzo Nobel N.V. Storage-stable accelerator solution

Also Published As

Publication number Publication date
JP2005528496A (ja) 2005-09-22
AU2003229721A1 (en) 2003-12-19
EP1507823A1 (fr) 2005-02-23

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