Classifications

• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B1/00—Electrolytic production of inorganic compounds or non-metals
  • C25B1/01—Products
  • C25B1/02—Hydrogen or oxygen
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B15/00—Operating or servicing cells
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B15/00—Operating or servicing cells
  • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
  • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
  • C25B9/70—Assemblies comprising two or more cells

Definitions

• the present invention relates to a Brown gas generator, and more particularly, to a Brown gas generator with a structure in which Brown gas is independently generated therewithin, thereby improving generation efficiency of
• Brown gas is a gas obtained by electrolysis of water and a mixed gas of hydrogen and oxygen in the ratio of 2:1.
• Brown gas can be obtained by simultaneously collecting the two gases, not by separately collecting them.
• Brown gas Unlike general gases, Brown gas has a peculiar property that causes an implosion phenomenon during the combustion thereof. In other words, an explosion phenomenon does not occur during the combustion of Brown gas. Instead, flames are inwardly gathered to thereby form a focus and make surroundings vacuous .
• Brown gas generator has been incessantly improved in its performance and safety and is widely used.
• FIG. 1 is a view schematically showing an electrolytic cell of a conventional Brown gas generator.
• the electrolytic cell of the conventional Brown generator will be described with reference to FIG. 1.
• Sept. 8, 2000 discloses the electrolytic cell of the Brown gas generator, in which a plurality of inner tubs 330a are fixed within an outer tub 320 by upper and lower fixing plates 310a and 310b formed of an insulator.
• the inner tubs 330a function as electrodes and are preferably manufactured by plating a surface of mild steel with nickel in an electroless method.
• the inner tubs 330 can be variously formed in a cylinder shape, a rectangular shape or a polygonal cylinder shape.
• the electrolytic cell is filled with an electrolyte in which water and electrolyte (KOH) are mixed with each other.
• a central rod 330, the inner tubs 330a standing upright, and the outer tub 320 disposed at the outermost position are coupled to the upper and lower fixing plates 310a and 310b formed of insulating materials, thus maintaining an insulated state each other.
• the inner tubs 330a are alternately set to a positive pole (+) and a negative pole (-) if a current is applied to both the central rod 330 and the outer tub 320.
• fins which are in contact with an outer periphery of the outer tub and has a wide heat radiation area, as shown in FIG. 1.
• the outer tub contacted with the fin is primarily refrigerated due to the cool air, and the electrolyte is cooled by its interfacial contact with an inner periphery of the refrigerated outer tub. Consequently, the cooling performance is degraded due to the delay of the cooling time. Therefore, the productivity of Brown gas is degraded because it is difficult to maintain the electrolytic cell at the optimal temperature (50° to 60°) when generating Brown gas.
• the electrolytic cell (an electrolytic plate) has been formed in a cylinder shape, a flat -panel shape or a polygonal shape so as to widen the electrolytic area, there is still a limitation on the widening of the electrolytic area.
• the electrolyte is electrolyzed only between the respective inner tubs 330a facing each other, thus generating Brown gas.
• the electrolyte exists independently between the respective inner tubs 330a and it is also replete enough to make all the inner tubs 330a electrified. Therefore, a voltage is also applied between the inner tubs 330a having no relation to the generation of Brown gas so that a current flows through them. As a result, an electric loss is incurred.
• the conventional Brown gas generator has a disadvantage that degrades the efficiency of gas generation considering the voltage applied from an exterior.
• the present invention is directed to a Brown gas generator that substantially obviates one or more of the problems due to limitations and disadvantages of the related art.
• An object of the present invention is to provide a Brown gas generator, in which predetermined portions where an electrolysis of an electrolyte is performed are independently provided within an electrolytic cell and water supply and water cooling are individually carried out to the independent portions, thereby maintaining the temperature in the electrolytic cell at an optimal condition and maximizing an generation efficiency of Brown gas.
• a Brown gas generator which comprises: an electrolytic cell having a structure in which flat-type pole plates/insulating plates are coupled in pair with another flat-type pole plates/insulating plates, which are in interfacial contact with the flat-type pole plates/insulating plates, to thereby independently generate Brown gas, the flat-type pole plates and the insulating plates being fixed at the same positions upward and downward around a middle fixing plate, the flat- type pole plates and the insulating plates being coupled at a regular interval by the middle fixing plate; an electrolyte adjustment means for circulating an electrolyte contained in the electrolytic cell to exchange heat of the electrolyte, and for replenishing a lack of the electrolyte; a refrigerating means for adjusting a temperature of the electrolyte by refrigerating a heat exchanger of the electrolyte adjustment means to a predetermined temperature when the heat of the electrolyte is exchanged; and a multistage demister installed in an upper portion of the electrolytic cell, for collecting Brown
• the Brown gas generator of the present invention has a structure in which the flat-type pole plate/insulating plate is coupled in pair with another flat-type pole plate/insulating plate, which is in interfacial contact with the flat-type pole plate/insulating plate, to thereby independently generate Brown gas.
• flat-type pole plate and corresponding insulating plate forms one unit to independently generate Brown gas without being influenced by other units, Brown gas can be efficiently generated without any electric loss.
• the electrolyte is independently supplied and circulated to the respective units, it is possible to maintain the optimal temperature for the generation of Brown gas.
• FIG. 1 is a view schematically showing an electrolytic cell of a conventional Brown gas generator
• FIG. 2 is a view showing a construction of a Brown gas generator in accordance with the present invention
• FIG. 3 is a side sectional view of the electrolytic cell installed within the Brown gas generator in accordance with the present invention, taken along the line A-A' ;
• FIG. 4 is a view of a demister installed in an upper portion of the electrolytic cell of the Brown gas generator in accordance with the present invention.
• FIG. 5 is a sectional view of an inside of the electrolytic cell including the water level sensor installed in the Brown gas generator of FIG.2, taken along the line B- B' .
• FIG. 2 is a view showing a construction of a Brown gas generator in accordance with the present invention.
• FIG 3 is a side sectional view of the electrolytic cell installed within the Brown gas generator of the present invention, taken along the line A-A' .
• FIG. 2 is a top view of the Brown gas generator, in which a demister is not shown in FIG. 2 so as to explain an inner structure of the electrolytic cell.
• FIG. 3 is a side sectional view illustrating a predetermined portion of the electrolytic cell of FIG. 2, the demister that is not shown in FIG. 2 is illustrated in FIG. 3.
• the Brown gas generator of the present invention includes: an electrolytic cell 12 having flat-type pole plates 20 and insulating plates 18 coupled to a middle fixing plate 32, in which an electrolyte consisting of water and electrolyte (KOH) is filled therein and the Brown gas is generated by electrolyzing the electrolyte using an induced current generated alternately between the flat-type pole plates 20; an electrolyte adjustment unit 16 for exchanging a heat of the electrolyte and replenishing a lack of the electrolyte, in which the electrolyte adjustment unit 16 includes a circulation pump 24 for circulating the electrolyte contained in the electrolytic cell 12, a quantitative pump 26 for supplying water, and a heat exchanger 28 for performing a heat exchange after the electrolyte introduced into a refrigerating unit 14 is cooled and circulating the electrolyte to the electrolytic cell 12; and the refrigerating unit 14 for automatically lowing a temperature of the electrolyte by refrigerating the heat exchanger 28 to a predetermined temperature when the heat
• the electrolytic cell 12 includes: a lower fixing plate 34; a plurality of flat-type pole plates 20 coupled to a middle fixing plate 32, an upper portion of the lower fixing plate 34 and a lower portion of the middle fixing plate 32 at regular intervals; and a plurality of insulating plates 18 coupled to an upper portion of the middle fixing plate 32 at the same intervals as the flat-type pole plates 20.
• multi-stage demister 30 for collecting the generated gas is installed in an upper portion of the electrolytic cell 12.
• a water prevention screen 44 is formed between the upper portion of the electrolytic cell 12 and the demister 30.
• a gas exhaust hole 46 is installed in the uppermost portion of the demister 30.
• a pressure sensor 38 is attached to a lateral outside of the electrolytic cell 12.
• a water level sensor (not shown) is internally installed in a predetermined space inside an electrolytic cell case 42 adjacent to a lateral side of the electrolytic cell 12.
• An electricity lead-in unit 40 passing through the electrolytic cell case 42 is installed in a lateral side of the electrolytic cell 12 and a lateral outside facing the electrolytic cell 12.
• the middle fixing plate 32 and the lower fixing plate 34 are formed of an insulator.
• the flat-type pole plate 20 functioning as an electrode is manufactured by plating a surface of mild steel with nickel in an electroless method.
• the insulating plate 18 is formed of an insulator. Additionally, the flat-type pole plates 20 and the insulating plates 18 are coupled to the lower and upper portions of the middle fixing plate 32 at the same intervals.
• the flat-type pole plates 20 and the insulating plates 18, which are in interfacial contact with each other, are coupled in pair and each pair form one unit as an independent structure that generates Brown gas.
• one flat-type pole plate/insulating plate is coupled in pair with corresponding flat-type pole plate/insulating plate, which is in contact with the flat- type pole plate/insulating plate, and the respective pairs independently generate Brown gas.
• the flat-type pole plates 20 facing each other are alternately set to a positive pole (+) and a negative pole (-) due to a voltage applied to the electricity lead-in unit 40 passing through the lateral side of the electrolytic cell 12, and the electrolyte filled between them is electrolyzed to thereby generate Brown gas .
• the electrolyte filled within the electrolytic cell must maintain a water level higher than the uppermost portion of the flat-type pole plate, i.e., the lower portion of the middle fixing plate 32.
• the conventional Brown gas generator has a disadvantage that degrades the efficiency of gas generation considering the voltage applied from an exterior.
• the electrolytic cell 12 of the present invention makes the electrolyte not flow to the flat-type pole plates 20, which do not correspond to the insulating plates coupled to the middle fixing plate 32 at the same intervals as the flat-type pole plates 20, even when the electrolyte maintains the water level higher than the uppermost portion of the flat-type pole plate 20.
• the middle fixing plate 32 has holes between the flat-type pole plates 20 and the insulating plates 18, which are coupled at regular intervals, so that the electrolyte flows up and down the middle fixing plate 32 between the flat-type pole plates 20 and the insulating plates 18, which are coupled in pair.
• the electrolyte flows only in the independent structure in which the flat-type pole plate/insulating plate is coupled in pair with another flat- type pole plate/insulating plate, which is in interfacial contact with the flat-type pole/insulating plate, and the electrolyte does not flow in the flat-type pole plates that do not correspond to the insulating plates.
• the corresponding flat-type pole plates 20 electrolyze the electrolyte existing between them without any electric loss, thereby efficiently generating Brown gas .
• the insulating plate 18 is manufactured high enough.
• electrolytic cell 12 is about 50° to 60°. However, since the electrolytic cell 12 generates a high-temperature heat during the electrolysis, if the electrolytic cell 12 is not refrigerated, the generation amount of Brown gas is rapidly reduced due to the rising temperature.
• the refrigerating unit 14 is installed in an outside of the electrolytic cell 12. Also, the electrolyte contained in the electrolytic cell 12 is circulated through the heat exchanger 28 so that the heat exchanger 28 is refrigerated. As a result, since the temperature of the electrolyte is lowered, the temperature of the electrolytic cell 12 can be always maintained to a constant state.
• the electrolyte adjustment unit 16 performing the above function includes the circulation pump 24 for circulating the electrolyte contained in the electrolytic cell 12, the quantitative pump 26 for supplying water, and the heat exchanger 28 for performing a heat exchange after the electrolyte introduced into the refrigerating unit 14 is cooled and circulating the electrolyte to the electrolytic cell 12.
• FIG. 4 is a view of the demister installed in an upper portion of the electrolytic cell of the Brown gas generator in accordance with the present invention.
• the demister installed in the upper portion of the electrolytic cell will be described with reference to FIG. 4.
• the demisters 30 are installed in the respective electrolytic cells 12. As shown in FIG. 4, however, according to the present invention, the demister 30 that can collect all Brown gases generated in the electrolytic cell 12 in one place is installed in an upper portion of the electrolytic cell 12.
• the multi-layered water prevention screen 14 for preventing a splash of water is formed between the demister 30 and the upper portion of the electrolytic cell 12.
• a plurality of holes are formed in the water prevention screen 14, and Brown gas is discharged to the demister through the holes. Positions of the holes formed in the respective water prevention screen 44 are not overlapped with those formed in the water prevention screen 44 facing each other upward and downward. Therefore, water is not splashed at any place. If the water prevention screen 44 is formed in more layers, the splash of water can be minimized. However, if the water prevention screen 44 is formed in too much layers, the passage of Brown gas is obstructed so that it is difficult to collect Brown gas. Therefore, the water prevention screen 44 should be manufactured in consideration for that .
• the demister 30 has a multi-stage structure and also has a structure for refrigerating Brown gas therewithin, moisture contained in Brown gas is removed so that pure Brown gas is collected. Since Brown gas exhausted from the gas exhaust hole 46 finally passes through the refrigerating unit, pure Brown gas can be obtained.
• an evaporation steam cooled at the demister 30 flows backward to the electrolytic cell 12, thereby preventing an increase in the temperature of the electrolyte contained in the electrolytic cell 12.
• FIG. 5 is a sectional view of the inside of the electrolytic cell including the water level sensor installed in the Brown gas generator of FIG.2, taken along the line B- B' .
• FIG. 5 is a sectional view of a predetermined portion of the electrolytic cell shown in FIG. 2, taken along the line A-A' , the demister that is not shown in FIG. 2 is illustrated in FIG. 5
• the inner structure of the electrolytic cell having the water level sensor will be described with reference to FIG. 5.
• a water gauge passing through a portion of the electrolytic cell case to maintain the same water level as the inside of the electrolytic cell is installed in an outside of the electrolytic cell case, and the water level sensor is attached to the inside of the water gauge.
• the same space as the inside of the electrolytic cell 12 is maintained by providing a predetermined space inside the electrolytic cell case 42, and the water level sensor 36 is attached to the predetermined space .
• the predetermined space is a space provided inside the electrolytic cell case 42, where the uppermost portion of the flat-type pole plate 20 is the lowest point and a predetermined height of the insulating plate 18 is the highest point .
• the water level sensor 36 can always correctly determine the water level of the inside of the electrolytic cell 12.
• the electrolytic cell case 42 is formed of an insulator, the voltage or current of the inside of the electrolytic cell 12 does not influence the outside of the electrolytic cell 12.
• the pressure sensor 38 determines the internal pressure of the electrolytic cell 12. If the internal pressure of the electrolytic cell 12 is larger than a predetermined pressure, the electricity supplied to the electrolytic cell 12 is cut off by applying a signal to a gas control unit 50. Meanwhile, if the internal pressure of the electrolytic cell 12 is smaller than the predetermined pressure, the electricity is again supplied to the electrolytic cell 12 to thereby generate Brown gas . INDUSTRIAL APPLICATION
• the Brown gas generator of the present invention has a structure in which the flat-type pole plate/insulating plate is coupled in pair with another flat-type pole plate/insulating plate, which is in interfacial contact with the flat-type pole plate/insulating plate, to thereby independently generate Brown gas.
• the flat-type pole plates and corresponding insulating plates form one unit to independently generate Brown gas without being influenced by other units, Brown gas can be efficiently generated without any electric loss.
• the electrolyte is independently supplied and circulated to the respective units, it is possible to maintain the optimal temperature for the generation of Brown gas.
• Brown gas since moisture contained in Brown gas is removed by cooling Brown gas collected by the water prevention screen and the multi-stage demister, it is possible to obtain pure Brown gas.
• the water level sensor is provided in the same space as the inside of the electrolytic cell, it is possible to correctly determine the variation of the water level according to the temporary pressure change in the inside of the electrolytic cell.

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• Chemical & Material Sciences (AREA)
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• Chemical Kinetics & Catalysis (AREA)
• Electrochemistry (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

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• 2002
  • 2002-02-04 KR KR10-2002-0006146A patent/KR100479472B1/ko active IP Right Grant
  • 2002-09-23 CN CNA028278445A patent/CN1617952A/zh active Pending
  • 2002-09-23 AU AU2002335555A patent/AU2002335555A1/en not_active Abandoned
  • 2002-09-23 CA CA002475215A patent/CA2475215A1/en not_active Abandoned
  • 2002-09-23 WO PCT/KR2002/001794 patent/WO2003066935A1/en active Application Filing
  • 2002-09-23 EP EP02806747A patent/EP1474547A4/en not_active Withdrawn
• 2004
  • 2004-08-04 US US10/910,634 patent/US20050006228A1/en not_active Abandoned

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