WO2003053560A1 - Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne - Google Patents

Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne Download PDF

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Publication number
WO2003053560A1
WO2003053560A1 PCT/FR2002/004453 FR0204453W WO03053560A1 WO 2003053560 A1 WO2003053560 A1 WO 2003053560A1 FR 0204453 W FR0204453 W FR 0204453W WO 03053560 A1 WO03053560 A1 WO 03053560A1
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Prior art keywords
iron
dispersion
colloidal dispersion
internal combustion
combustion engines
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PCT/FR2002/004453
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English (en)
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WO2003053560A9 (fr
Inventor
Gilbert Blanchard
Jean-Yves Chane-Ching
Bruno Tolla
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Rhodia Electronics And Catalysis
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8870868&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003053560(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to ES02799830.1T priority Critical patent/ES2559847T3/es
Priority to US10/499,559 priority patent/US7459484B2/en
Priority to BR0215211A priority patent/BR0215211A/pt
Priority to KR20047009857A priority patent/KR100633813B1/ko
Priority to JP2003554314A priority patent/JP4117844B2/ja
Application filed by Rhodia Electronics And Catalysis filed Critical Rhodia Electronics And Catalysis
Priority to MXPA04005943A priority patent/MXPA04005943A/es
Priority to CA 2470410 priority patent/CA2470410C/fr
Priority to AU2002364467A priority patent/AU2002364467A1/en
Priority to EP02799830.1A priority patent/EP1458471B1/fr
Publication of WO2003053560A1 publication Critical patent/WO2003053560A1/fr
Publication of WO2003053560A9 publication Critical patent/WO2003053560A9/fr
Priority to NO20042537A priority patent/NO338487B1/no

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0004—Preparation of sols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
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    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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Definitions

  • At least 85%, more particularly at least 90%, and even more preferably at least 95%, of the particles are primary particles.
  • primary particle is meant a particle which is perfectly individualized and which is not aggregated with
  • Avail ' ⁇ rsionfdeil'i ⁇ vention 1 may be of' isotropic morphology *, including '' they present a report peuvent- 1 * (greater

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Colloid Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Catalysts (AREA)
  • Cosmetics (AREA)
  • Compounds Of Iron (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

La dispersion colloidale de l'invention est caractérisée en ce qu'elle comprend une phase organique; des particules d'un composé du fer sous forme amorphe et au moins un agent amphiphile.Elle est préparée par un procédé dans lequel on fait réagir avec une base soit un sel de fer en présence d'un complexant du fer soit un complexe du fer, en maintenant le pH du milieu réactionnel ô une valeur d'au plus 8 ce par quoi on obtient un précipité, le complexant du fer étant choisi parmi les acides carboxyliques hydrosolubles présentant une constante de complexation K telle que le pK soit d'au moins 3 et le complexe du fer étant choisi parmi les produits de la réaction des sels de fer avec lesdits acides; puis on met en contact le précipité ainsi obtenu ou une suspension contenant ce précipité avec une phase organique en présence d'un agent amphiphile ce par quoi on obtient la dispersion en phase organique.La dispersion de l'invention peut être utilisée comme adjuvant de combustion dans les combustibles ou carburants liquides.

Description

Figure imgf000003_0001
Figure imgf000004_0001
Figure imgf000005_0001
' ' Se îlo <n u ,ne autre c 'aractéristique ' de l'i 'nvention,', au' moins 85%, plus particulièrement au, moiris 90% et encore plus particulièrement au moins 95% des particules sont des particules primaires. On entend par particule primaire une particule qui est parfaitement individualisée e qui n'est pas agrégée avec
5 une autre ou plusieurs autres particules. Cette caractéristique peut être mise en évidence en examinant la dispersion par MET (microscopie électronique à transmission haute résolution). < ( , ι On peut aussi utiliser la technique de cryo-MET pour, déterminer l'état d'agrégation des particules élémentaires. Elle permet d'observer par
10 microscopie électronique à transmission (MET) des échantillons maintenus congelés dans leur milieu naturel quif est soit de l'eau soit des diluants lorganiques tels que les solvants aromatiques ou aliphatiques, comme par exemple le Solvesso et l'Isopar Pli bjeh certains alcools tel que éthario | u > t ' La 'cbhgélatib s'effectûe sur des filιι&»minθes d'environ' 5Ohiτisà 1O0hrn
15 d-épâisse soîfr dans l'éthàne (liquider pour leέ échantillons aqueμχ< soitr dans l'azote liquide' pour les'autres, *" i >»"' -V,-' -k » » > l!j- ι ' ,' '{ !s ι' . ,
* ' Par Gryo-MET Tétati de dispersion dës particuleg est* bienj'.p1résêrvékët représentatif de celui nrésent dans le ïmilieutréeU A> r,γ '5,< n ' *>* l >9i >U ι 'b ' iCette caractérlstiquevdes particules de la dispersion contribue à sa
20 stabilité! H 9 • >r ' ! , ' l l b. h<.< M- ]- -lN"< l ^ t >r i f •! -' t> « Par* ailleurs, les? partidules
Figure imgf000006_0001
dispersion de l'inventionf présentent une 1 granuloπiétrie"
Figure imgf000006_0002
possèdent lin tlso''
Figure imgf000006_0003
îl rinruet
5nm, lus particulièrement entre^SnhreMnm. >•• u , T ^ ι^ Α< ,n> s' s La^granUlométrie- est" déterminée, .fpar microscbpiefkf électronique, à 25 transmission- (MET)) rnanière*blàssique, ur?ϋn*échantiIIθrï> 'préalablement séché< mμhe biembrarte de*cartJon% sujpôrtée*sûr gfiïlé €tecûWre.J/ - 4 î »(« ιi> 'i. " Cette ftecbrilque Ide pfépatiatibn
Figure imgf000006_0004
préférée ιcàr«elle
Figure imgf000006_0005
préëisîon 'de le mesure de la taille 'des particules? Les zones* <<Ghdlsieè o κles l mesufesπrsohtu' celles^ quiH,lpréseritent ' un')' étatô dé 30 disperéio βertiiblablê à celui observé en cn0" ETi .<« ' •• 'f ι« ' >il ,s'
' "' Lés particules de! là 'dîsp'ërsionfdeil'iπvention1 peuvent être de' morphologie * Isotrope, notamment'' elles peuvent-1 présenter Un rapport* (plus grande
-dime slonyï '(plus petite dimértsibή d'aè,pluâl2.fe b . ' »v.-> - a -"b Λ K S » ^
J i ?J Isa' 'dîspeiîsion
Figure imgf000006_0007
selon
Figure imgf000006_0006
la
35
Figure imgf000006_0008
agento phiphile.'1 x '" t -< 'l ι,ι If '"> '. r f Cet
Figure imgf000006_0009
pêϋr êWun 7â*cideïïcarfooxy1îque fqur -'comporte
* 'a géhéfalement'ldë~ O*:à 5^âfônes^e^c bb e^ eftp1léérënbe,'dëfe'l5 'â.'-25
! .,«
Figure imgf000007_0001
Figure imgf000008_0001
Figure imgf000009_0001
llàeidëi^^iquèï^
Figure imgf000010_0001
Figure imgf000011_0001
Figure imgf000013_0001
Figure imgf000014_0001
Figure imgf000015_0001

Claims

Figure imgf000016_0001
Figure imgf000017_0001
PCT/FR2002/004453 2001-12-21 2002-12-19 Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne WO2003053560A1 (fr)

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EP02799830.1A EP1458471B1 (fr) 2001-12-21 2002-12-19 Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne
US10/499,559 US7459484B2 (en) 2001-12-21 2002-12-19 Organic colloidal dispersion of iron particles, method for preparing same and use thereof as fuel additive for internal combustion engines
BR0215211A BR0215211A (pt) 2001-12-21 2002-12-19 dispersão coloidal, processo de preparação e utilização da mesma e combustìvel para motores de combustão interna
KR20047009857A KR100633813B1 (ko) 2001-12-21 2002-12-19 철 입자의 유기 콜로이드성 분산액, 그의 제조 방법, 및내연 엔진을 위한 연료 첨가제로서 그의 용도
JP2003554314A JP4117844B2 (ja) 2001-12-21 2002-12-19 鉄粒子の有機コロイド分散体、その調製方法及び内燃機関用エンジン燃料の添加剤としてのその使用
ES02799830.1T ES2559847T3 (es) 2001-12-21 2002-12-19 Dispersión coloidal orgánica de partículas de hierro, procedimiento para la preparación de la misma y su uso como aditivo de combustibles para motores de combustión interna
MXPA04005943A MXPA04005943A (es) 2001-12-21 2002-12-19 Dispersion coloidal organica de particulas de hierro, un proceso para su preparacion y su empleo como un aditivo de combustible para motores de combustion interna.
CA 2470410 CA2470410C (fr) 2001-12-21 2002-12-19 Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne
AU2002364467A AU2002364467A1 (en) 2001-12-21 2002-12-19 Organic colloidal dispersion of iron particles, method for preparing same and use thereof as fuel additive for internal combustion engines
NO20042537A NO338487B1 (no) 2001-12-21 2004-06-17 Kolloidal dispersjon omfattende en organisk fase, partikler av en jernforbindelse og minst et amfifilt middel, fremgangsmåte for fremstilling av slike samt anvendelse av slike som brennstoffadditiv for forbrenningsmotorer

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FR0116710A FR2833862B1 (fr) 2001-12-21 2001-12-21 Dispersion colloidale organique de particules de fer, son procede de preparation et son utilisation comme adjuvant de carburant pour moteurs a combustion interne

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Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007085562A1 (fr) 2006-01-30 2007-08-02 Rhodia Operations Composition lubrifiante comprenant une dispersion colloïdale de fer et son utilisation dans un moteur pour le traitement des gaz d'echappement
US7803201B2 (en) * 2005-02-09 2010-09-28 Headwaters Technology Innovation, Llc Organically complexed nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
FR2943927A1 (fr) * 2009-04-02 2010-10-08 Peugeot Citroen Automobiles Sa Filtre a particules pour moteur a combustion interne
US20100300079A1 (en) * 2007-03-06 2010-12-02 Virginie Harle Operation of diesel/lean-burn engines having easily regenerated particle filters in the exhaust systems therefor
WO2012084838A1 (fr) 2010-12-22 2012-06-28 Rhodia Operations Dispersion organique de particules à base de fer sous forme cristallisée
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US8641791B2 (en) 2007-03-28 2014-02-04 Infineum International Limited Method of supplying iron to the particulate trap of a diesel engine exhaust
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WO2015086996A1 (fr) 2013-12-12 2015-06-18 Filtrauto Filtre à carburant avec dispositif de libération d'additif
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FR3067948A1 (fr) * 2017-06-23 2018-12-28 Rhodia Operations Procede de preparation de nanoparticules d'un compose du fer et/ou du cerium
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Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2853261B1 (fr) * 2003-04-04 2006-06-30 Rhodia Elect & Catalysis Dispersion colloidale d'un compose d'une terre rare comprenant un agent anti-oxydant et son utilisation comme adjuvant de gazole pour moteurs a combustion interne
FR2860443B1 (fr) * 2003-10-03 2006-06-16 Rhodia Elect & Catalysis Dispersion colloidale organique de cerium et d'un element choisi parmi le rhodium et le palladium et son utilisation comme adjuvant de gazoles pour moteurs a combustion interne
US7856992B2 (en) * 2005-02-09 2010-12-28 Headwaters Technology Innovation, Llc Tobacco catalyst and methods for reducing the amount of undesirable small molecules in tobacco smoke
US7887771B2 (en) 2005-10-06 2011-02-15 Headwaters Technology Innovation, Llc Carbon nanorings manufactured from templating nanoparticles
US8133637B2 (en) * 2005-10-06 2012-03-13 Headwaters Technology Innovation, Llc Fuel cells and fuel cell catalysts incorporating a nanoring support
US7718155B2 (en) * 2005-10-06 2010-05-18 Headwaters Technology Innovation, Llc Carbon nanostructures manufactured from catalytic templating nanoparticles
FR2895277A1 (fr) * 2005-12-22 2007-06-29 Rhodia Recherches & Tech Organosols stabilises par des polymeres amphiphiles
FR2896824B1 (fr) * 2006-01-30 2008-03-07 Rhodia Recherches & Tech Procede de fonctionnement d'un moteur utilisant une composition lubrifiante comprenant une dispersion colloidale d'une terre rare pour catalyser la combustion des suies
US7935276B2 (en) * 2006-02-09 2011-05-03 Headwaters Technology Innovation Llc Polymeric materials incorporating carbon nanostructures
WO2008017679A1 (fr) * 2006-08-10 2008-02-14 Akzo Nobel Coatings International B.V. Procédé pour la préparation d'organosols d'oxyde de métal et utilisation desdits organosols dans l'enrichissement en nanoparticules de résines de revêtement
US7985398B2 (en) * 2006-12-12 2011-07-26 Honda Motor Co., Ltd. Preparation of iron or iron oxide nanoparticles
US7718156B2 (en) * 2006-12-20 2010-05-18 Headwaters Technology Innovation, Llc Method for manufacturing carbon nanostructures having minimal surface functional groups
GB0705922D0 (en) * 2007-03-28 2007-05-09 Infineum Int Ltd Process for the manufacture of a colloid of iron oxide
GB2447922C (en) * 2007-03-28 2011-03-09 Infineum Int Ltd Iron-containing polymer suitable for regenerating diesel exhaust particulate traps.
CN101500260B (zh) 2008-04-29 2011-09-14 华为技术有限公司 为用户分配应答信道的方法、装置和系统
KR101020236B1 (ko) * 2008-07-31 2011-03-07 한국에너지기술연구원 미연탄소 및 질소산화물 저감용 철계 나노유체 연료첨가제및 그 제조방법
US20100104555A1 (en) * 2008-10-24 2010-04-29 The Scripps Research Institute HCV neutralizing epitopes
MX2012000078A (es) 2009-06-23 2012-07-03 Rhodia Operations Detergente sinergico y combinacion de compuesto metalico activo.
KR100954362B1 (ko) 2009-08-25 2010-04-26 (주)켐텍인터내셔날 균일한 입도분포를 가지는 산화철 함유 연료첨가제의 제조방법
US20130192122A1 (en) 2012-01-30 2013-08-01 Cerion Technology, Inc. Rapid method for production of cerium-containing oxide organic colloids
CA2862337C (fr) 2012-01-30 2020-03-31 Cerion Enterprises Llc Procede perfectionne pour la production de colloides organiques d'oxyde de cerium stables
WO2013116647A2 (fr) 2012-02-01 2013-08-08 Cerion Enterprises Llc Procédé rapide pour la production de colloïdes organiques d'oxydes contenant du cérium
WO2013177512A1 (fr) 2012-05-25 2013-11-28 Cerion Enterprises Llc Dispersions de nanoparticules d'oxyde de fer et additifs pour carburant pour la combustion de la suie
PL3055359T3 (pl) * 2013-10-07 2023-08-14 Ppg Industries Ohio, Inc. Poddane obróbce wypełniacze, kompozycje zawierające je oraz wyroby z nich przygotowane
PL236704B1 (pl) 2014-11-19 2021-02-08 Inst Nafty I Gazu Panstwowy Inst Badawczy Stabilizowany modyfikator spalania do lekkich olejów opałowych
FR3043570B1 (fr) * 2015-11-13 2020-08-07 Ifp Energies Now Fluide pour la depollution des moteurs thermiques et modes de preparation desdits fluides par emulsification
CA3022886A1 (fr) * 2016-05-05 2017-11-09 Nfluids Inc. Transfert de phase destine a la preparation d'organosols nanometriques stables
EP4092098A1 (fr) * 2021-05-20 2022-11-23 Indian Oil Corporation Limited Composition additive servant d'améliorant de combustion pour combustibles liquides et gazeux
EP4180505B1 (fr) * 2021-11-15 2024-10-09 Infineum International Limited Ameliorations apportees a des carburants marins

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51122107A (en) 1976-03-12 1976-10-26 Taihoo Kogyo Kk Process for preparing fuel oil additives
JPS62167393A (ja) 1986-01-21 1987-07-23 Taihoo Kogyo Kk 燃料添加剤
FR2780096A1 (fr) * 1998-06-22 1999-12-24 Rhodia Chimie Sa Procede de traitement par combustion des particules carbonees dans un circuit d'echappement d'un moteur a combustion interne
US6136048A (en) 1995-11-22 2000-10-24 Rhodia Chimie Organic sol comprising at least one oxygenated rare-earth compound, synthesis method therefor, and use of said sol for catalysis
FR2797199A1 (fr) * 1999-08-04 2001-02-09 Rhodia Terres Rares Dispersion colloidale organique de particules essentiellement monocristallines d'au moins un compose a base d'au moins une terre rare, son procede de preparation et son utilisation
US6271269B1 (en) 1985-06-20 2001-08-07 Rhodia Chimie Organic colloidal dispersions of acidic metal values
WO2001094262A1 (fr) 2000-06-05 2001-12-13 Rhodia Terres Rares Dispersion colloidale d'un compose de cerium ou d'un compose de cerium et d'au moins un autre element choisi parmi les terres rares et des metaux de transition et comprenant un acide amine

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU414197A1 (fr) 1972-05-26 1974-02-05
JPS6483522A (en) 1987-09-28 1989-03-29 Agency Ind Science Techn Porous and fine sphere of iron oxide and production thereof
JPH04117844A (ja) * 1990-09-07 1992-04-17 Matsushita Electric Ind Co Ltd Ｉｓｄｎ用端末装置
JPH06122519A (ja) 1991-05-27 1994-05-06 Toda Kogyo Corp 非晶質含水酸化第二鉄粒子粉末及びその製造法
DE69516569T2 (de) * 1994-02-18 2001-01-04 Rhodia Chimie, Courbevoie Organische Sole von vierwertigen Metalloxid und deren Verwendung in Kohlenwasserstoffzusammensetzungen
FR2789602B1 (fr) * 1999-02-17 2001-05-11 Rhodia Chimie Sa Sol organique et compose solide a base d'oxyde de titane et d'un compose amphiphile et procedes de preparation
FR2789601B1 (fr) * 1999-02-17 2001-05-11 Rhodia Chimie Sa Sol organique et compose solide a base d'oxyde de cerium et d'un compose amphiphile et procedes de preparation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51122107A (en) 1976-03-12 1976-10-26 Taihoo Kogyo Kk Process for preparing fuel oil additives
US6271269B1 (en) 1985-06-20 2001-08-07 Rhodia Chimie Organic colloidal dispersions of acidic metal values
JPS62167393A (ja) 1986-01-21 1987-07-23 Taihoo Kogyo Kk 燃料添加剤
US6136048A (en) 1995-11-22 2000-10-24 Rhodia Chimie Organic sol comprising at least one oxygenated rare-earth compound, synthesis method therefor, and use of said sol for catalysis
FR2780096A1 (fr) * 1998-06-22 1999-12-24 Rhodia Chimie Sa Procede de traitement par combustion des particules carbonees dans un circuit d'echappement d'un moteur a combustion interne
FR2797199A1 (fr) * 1999-08-04 2001-02-09 Rhodia Terres Rares Dispersion colloidale organique de particules essentiellement monocristallines d'au moins un compose a base d'au moins une terre rare, son procede de preparation et son utilisation
WO2001094262A1 (fr) 2000-06-05 2001-12-13 Rhodia Terres Rares Dispersion colloidale d'un compose de cerium ou d'un compose de cerium et d'au moins un autre element choisi parmi les terres rares et des metaux de transition et comprenant un acide amine

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 197650, Derwent World Patents Index; Class E31, AN 1976-93072X, XP002213257 *
DATABASE WPI Section Ch Week 198735, Derwent World Patents Index; Class E19, AN 1987-245999, XP002213258 *

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US7803201B2 (en) * 2005-02-09 2010-09-28 Headwaters Technology Innovation, Llc Organically complexed nanocatalysts for improving combustion properties of fuels and fuel compositions incorporating such catalysts
WO2007085562A1 (fr) 2006-01-30 2007-08-02 Rhodia Operations Composition lubrifiante comprenant une dispersion colloïdale de fer et son utilisation dans un moteur pour le traitement des gaz d'echappement
US20100300079A1 (en) * 2007-03-06 2010-12-02 Virginie Harle Operation of diesel/lean-burn engines having easily regenerated particle filters in the exhaust systems therefor
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FR3067949A1 (fr) * 2017-06-23 2018-12-28 Rhodia Operations Procede de preparation de nanoparticules d'un compose du fer et/ou du cerium
WO2019086383A1 (fr) 2017-11-01 2019-05-09 Rhodia Operations Utilisation d'une dispersion colloïdale pour limiter l'encrassement dans un moteur a essence
WO2019086385A1 (fr) 2017-11-01 2019-05-09 Rhodia Operations Utilisation d'une dispersion colloïdale comme additif de regeneration d'un gpf
WO2019106176A1 (fr) 2017-11-30 2019-06-06 Solvay Sa Élimination de contaminants d'un effluent d'eau à l'aide d'un composite d'hydroxyapatite
WO2019106175A1 (fr) 2017-11-30 2019-06-06 Solvay Sa Composite d'hydroxyapatite comprenant du charbon actif destiné à être utilisé pour éliminer des contaminants d'effluents et procédé de fabrication
WO2019106178A1 (fr) 2017-11-30 2019-06-06 Solvay Sa Composite d'hydroxyapatite destiné à être utilisé pour éliminer des contaminants d'effluents et procédés de fabrication
US11472706B2 (en) 2017-11-30 2022-10-18 Solvay Sa Hydroxyapatite composite for use in removal of contaminants from effluents and methods of making
WO2019207075A1 (fr) 2018-04-25 2019-10-31 Solvay Sa Élimination de complexes de cyanure métallique stables et d'ions métalliques d'un flux d'eau
EP3604234A1 (fr) 2018-08-02 2020-02-05 Solvay Sa Élimination des complexes métal-cyanure stables et des ions métalliques des effluents aqueux

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US20050039382A1 (en) 2005-02-24
CN101653713A (zh) 2010-02-24
KR100633813B1 (ko) 2006-10-13
EP1458471B1 (fr) 2015-11-11
CA2470410A1 (fr) 2003-07-03
ES2559847T3 (es) 2016-02-16
MXPA04005943A (es) 2004-09-13
RU2004122417A (ru) 2005-04-10
JP2005513204A (ja) 2005-05-12
RU2277510C2 (ru) 2006-06-10
JP2008144176A (ja) 2008-06-26
FR2833862B1 (fr) 2004-10-15
CA2470410C (fr) 2008-11-04
CN101653712A (zh) 2010-02-24
EP1458471A1 (fr) 2004-09-22
CN101653712B (zh) 2013-01-23
JP4799537B2 (ja) 2011-10-26
BR0215211A (pt) 2006-06-06
CN1617760A (zh) 2005-05-18
US7459484B2 (en) 2008-12-02
FR2833862A1 (fr) 2003-06-27
CN101653713B (zh) 2016-02-03
KR20040072673A (ko) 2004-08-18
WO2003053560A9 (fr) 2004-04-22
NO338487B1 (no) 2016-08-22
NO20042537L (no) 2004-09-21
AU2002364467A1 (en) 2003-07-09
JP4117844B2 (ja) 2008-07-16

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