WO2003050347A1 - Non-tisse composite, utilisation et procede de fabrication associes - Google Patents

Non-tisse composite, utilisation et procede de fabrication associes Download PDF

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Publication number
WO2003050347A1
WO2003050347A1 PCT/FI2002/000995 FI0200995W WO03050347A1 WO 2003050347 A1 WO2003050347 A1 WO 2003050347A1 FI 0200995 W FI0200995 W FI 0200995W WO 03050347 A1 WO03050347 A1 WO 03050347A1
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WO
WIPO (PCT)
Prior art keywords
fibers
nonwoven
hydrophobic
layers
web
Prior art date
Application number
PCT/FI2002/000995
Other languages
English (en)
Inventor
Heikki Bergholm
Erkki Lampila
Mari Rahkola
Margareta Huldén
Johanna Tiirikainen
Original Assignee
Suominen Nonwovens Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suominen Nonwovens Ltd. filed Critical Suominen Nonwovens Ltd.
Priority to EP02783133A priority Critical patent/EP1461489A1/fr
Priority to US10/497,166 priority patent/US20050090175A1/en
Priority to AU2002346783A priority patent/AU2002346783A1/en
Publication of WO2003050347A1 publication Critical patent/WO2003050347A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D04H1/4258—Regenerated cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/689—Hydroentangled nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697—Containing at least two chemically different strand or fiber materials
    • Y10T442/698—Containing polymeric and natural strand or fiber materials

Definitions

  • the present invention relates to composite nonwovens, to their use and to a method of manufacture of the composite nonwovens. More particularly, it discloses a new entangled composite nonwoven material comprising at least three layers.
  • the nonwoven material according to the invention can be used as a substrate for wiping articles, especially for use as a substrate for wet wipes, where good liquid absorption and release properties are needed.
  • Typical fibers used are cellulose-based fibers such as cotton, pulp or viscose, as well as synthetic fibers such as polyester (typically polyethylene terephtalate).
  • a widely used fiber mixture ratio is 30-70% viscose fibers and 70%-30% polyester fibers by weight of the web.
  • Hydroentangled nonwovens have been used as substrates for pre-moistened wipes, i.e. so- called wet wipes.
  • the liquid in the pre-moistened wipe is to be released onto the surface that is wiped, for example for cleaning or polishing the surface.
  • the liquid that is released should provide some special function on the surface, such as moisturising of skin or disinfecting the surface.
  • the substrate used for wet wipes, such as a hydroentangled nonwoven should possess both desirable liquid absorption and retention characteristics, as well as sufficient liquid release properties.
  • nonwoven substrates comprising viscose and polyester fibers provide good liquid absorption and retention characteristics, these substrates release typically less than 50% of the moisturising liquid during a wiping action. This means that only a small amount of the added liquid contributes to the intended function, such as cleaning, polishing or disinfecting function. Thus, there exists a need to improve the liquid release properties of nonwoven substrates used to manufacture especially wet wipes.
  • hydrophobic fibers such as polypropylene (PP) fibers there are in a nonwoven material
  • Hydrophobic fibers are characterized by having a water contact angle greater than 90°. Due to the hydrophobic fibers, the capillary pressure of water-based liquids is low or even negative in the nonwoven material. Consequently, water-based liquids can be easily released from the nonwoven during a wiping action and the amount of residual liquid in the wiping article after the wiping is minimized.
  • the water absorption properties of a nonwoven containing PP fibers are significantly poorer than the absorption properties of nonwovens containing more hydrophilic fibers.
  • the amount of hydrophobic polypropylene fibers is increased in the nonwoven, the spontaneous absorption of water-based liquids decreases. This can be observed e.g. as an increasing runoff of liquid on the nonwoven surface, when the material is being wetted.
  • hydrophobic polypropylene fibers in nonwovens to be used as substrates for wiping articles is limited as the liquid absorption properties decrease when the amount of polypropylene fibers increases. Due to the chemical nature of polypropylene, fibers made of polypropylene have a low-energy surface with a water contact angle of about 105°. The hydrophobic nature of a nonwoven material containing PP fibers thus results in non-optimal cleaning properties of the nonwoven used as a wiping article. The liquid absorption capacity and absorption rate of the nonwoven are low, resulting also in a relatively poor drying ability of the nonwoven during a wiping action. Composite and layered nonwoven fabrics are known from the prior art.
  • a layered composite structure is meant a nonwoven fabric, which has at least two layers containing at least partly different fibers or fiber compositions. Typically the different nonwoven layers are first manufactured separately and then combined e.g. by calander bonding.
  • the patent application WO 98/03713 discloses a multiple layer nonwoven basesheet to be used as a substrate for a wet wipe, wherein the various layers can contain different types of fibers. The properties of the obtained products can be altered by e.g. choosing suitable fiber combinations and treatments. In order to e.g. bond fibers together, one or more of the separate layers can be treated thermally before bringing together with the other layers.
  • the Japanese patent application JP2001336053 discloses a nonwoven consisting of a hydrophobic, thermally bonded middle layer and outer layers containing hydrophilic fibers.
  • the composite nonwoven fabrics can also be formed on-line, i.e. the various layers (e.g. carded webs) are formed and brought together one on top of the other, whereafter the layers are bonded together.
  • different bonding methods can be used.
  • the EP 0 531 096 discloses the use of a large number (ten) of carding devices, which are fed with different fiber compositions or different fibers and the webs are typically entangled by hydraulic entangling.
  • the present invention concerns a composite nonwoven formed from fibrous layers bonded together by entanglement of fibers of the layers, wherein the fibrous layers comprise first and second outer layers each comprising a mixture of hydrophobic and hydrophilic fibers, as well as an intermediate layer of hydrophobic fibers sandwiched between the first and the second outer layers, the weight ratio between the hydrophobic and hydrophilic fibers in the first and the second layers being 20:80 to 80:20.
  • the fibrous webs that are used to form the layers of the composite consist of non-bonded fibers, i.e. are free of fibers which e.g. have been thermally bonded or bonded with e.g. a binder or an adhesive, i.e. they are binder-free.
  • the webs combined to form the layered composite are mutually bonded or interlocked solely by hydroentangling the fibers.
  • the hydroentangled and dried composite product may, if desired, be further treated, for example by patterning or embossing to form a patterned or embossed composite nonwoven.
  • the composite nonwoven according to the invention is intended to be used as a substrate for wiping articles, especially wet wipes.
  • the said composite nonwoven material has improved liquid absorption properties, as well as improved liquid release properties.
  • An object of the invention is also a method of manufacturing a composite nonwoven comprising the steps of forming a layered web comprising first and second outer layers each comprising a mixture of hydrophobic and hydrophilic fibers and an intermediate layer of hydrophobic fibers sandwiched between the first and the second outer layers, whereby the ratio of hydrophobic to hydrophilic fibers is 20:80 to 80:20 in the first and second outer layers, hydroentangling the layered web to bond the layers by entanglement of fibers, drying the hydroentangled web.
  • Figure 1 shows a hydroentanglement production line with three carding stations
  • Figure 2 shows the cumulative volume of filled pores, measured during receding run
  • Figure 4 shows the cumulative liquid release of wet samples measured with a wiping device
  • Figure 5 shows the wiping efficiency of dry samples measured with a wiping device
  • Figure 6 shows the pore volume distribution
  • Figure 7 shows the cumulative volume of filled pores, measured during advancing run.
  • the structure of the nonwoven according to the invention thus comprises a first and a second outer layer, as well as a third layer, the outer surfaces of which each faces an outer surface of the first and second outer layer, respectively, forming a sandwich structure, with the third layer being sandwiched between the first and second layer.
  • the absorption and release properties of such a structure are favourable for the purpose of wet wipe applications.
  • the present invention provides a nonwoven composite material that surprisingly has good release properties for water based liquids. Also the absorption properties and bulkiness of the material are good.
  • the fibers are staple fibers from which a carded fibrous web can be formed.
  • Typical hydrophobic fibers for use in the nonwoven, in the outer layers and/or to form the fibers in the intermediate layer are for example polyolefin fibers such as polypropylene and/or polyethylene fibers.
  • polypropylene fibers are used.
  • Polypropylene fibers have many advantages, such as low density as well as low shear and elastic moduli. In hydroentangled nonwovens, these properties of polypropylene fibers result in soft and bulky nonwoven materials.
  • Suitable hydrophobic fibers for producing hydroentangled nonwovens are fibers having a titer of 1.3-3.8 dtex. According to a preferred embodiment of the invention, the hydrophobic fibers in the first and second outer layers are the same hydrophobic fiber as in the intermediate layer.
  • hydrophobic fibers made from a hydrophilic synthetic or natural polymer can be used as hydrophobic fibers, if a water contact angle of greater than 90° is achieved by a suitable surface treatment.
  • surface treatments can be for example chemical surface treatments with a wax, fluorocarbon or silicone.
  • the hydrophobic fibers can also be multicomponent fibers including a hydrophilic or a hydrophobic core polymer and a hydrophobic surface.
  • the hydrophilic absorbing fibers are selected from the group of cellulose based fibers, such as viscose, cotton or pulp fibers.
  • cellulose based fibers such as viscose, cotton or pulp fibers.
  • viscose or lyocell are used as the hydrophilic fibers.
  • Hydrophilic fibers are here defined as fibers having an average water contact angle of less than 90°.
  • the weight ratio between the hydrophobic and hydrophilic fibers in the first and second outer layers is 30:70 to 70:30.
  • the first and second outer layers are the same, that is, they are made from the same fiber mixture.
  • the first and the second outer layers consist of polyolefin, such as polypropylene, and viscose fibers.
  • the intermediate layer consists of polyolefin, such as polypropylene fibers.
  • the first and second outer layers consist of polypropylene and viscose fibers in a weight ratio of appr. 50:50, the intermediate layer consisting of polypropylene fibers.
  • the nonwoven material consists of three layers, that is of a first and second outer layer, as well as a third layer, the outer surfaces of which each faces an outer surface of the first and second outer layer, respectively, forming a sandwich structure.
  • the weight of each layer can be 10 - 80 g/m .
  • the weight of the intermediate layer can often be greater than the weight of each outer layer.
  • the nonwoven composite material according to the invention is made by a hydroentanglement process that involves the general steps of forming a layered web of fibers, hydroentangling the web, drying the web and winding the hydroentangled nonwoven material.
  • the layered web can be formed by providing a first and a second web each comprising a mixture of hydrophobic and hydrophilic fibers, providing a third web of hydrophobic fibers, conveying the so formed webs as such to join the webs in a facing relationship with each other so as to sandwich the third web between the first and the second webs.
  • a hydroentanglement production line for making a three-layered web is schematically shown in Figure 1, where the parts are as follows: (11A, 1 IB, 11C) are fiber feeders for the webs A, B and C, respectively.
  • the fibers can be staple fibers crimped and cut from polymer filaments.
  • the reference numbers (12A, 12B, 12C) denote carding stations for the same webs, and (13) denotes the 1 st hydroentanglement station, (14) the 2 nd hydroentanglement station, (15) is the dryer and (16) a nonwoven winder.
  • the separate webs A, B and C consisting of carded fibers, are conveyed as such to the 1 st hydroentanglement station (13) without additional intermediate treatments, i.e. mechanical (e.g. compacting), chemical and/or thermal treatments.
  • mechanical e.g. compacting
  • thermal treatments i.e. mechanical (e.g. compacting), chemical and/or thermal treatments.
  • Each of the separate webs A, B and C are brought together in contact prior to the first hydroentanglement station, the web B being sandwiched between webs A and C, where the layers are bonded by entanglement, leading to a bonded product where some of the fibers from one layer may extend into the adjacent layer to secure the layers together.
  • This mechanical interlocking of the layers leads to a composite structure with a hydrophobic intermediate zone which increases in hydrophilicity in a direction towards the outer zones and surfaces of the composite structure, which structure gives the product its beneficial properties.
  • Liquid is mostly absorbed and retained in nonwoven materials in the capillaries which are formed between the fibers in the nonwovens.
  • the ability of a porous material, such as a nonwoven, to absorb and retain liquid can be characterized by the capillary pressure of liquid in the pores of the material.
  • the capillary pressure is defined by the Laplace equation that is well known in the art:
  • A is the cross-sectional area and L is length of the capillary, ⁇ is the liquid viscosity.
  • liquid should be released from the wipe on the surface as completely as possible.
  • the pressure that is needed to release liquid from a wet wipe is directly proportional to the capillary pressure of the liquid in the capillaries of the wipe.
  • the capillary pressure can also be decreased by increasing the average pore size of the nonwoven material.
  • One method of increasing the average pore size is to increase the diameter (denier) of the fibers that are used for manufacturing the nonwoven material. Pore size distribution depends also on the process technology and process settings such as hydroentanglement energy used for the production of the nonwoven.
  • the pore volume distribution of nonwovens can be determined e.g. by liquid porosimetry.
  • the pore volume distribution is measured using the technique developed at the Textile Research Institute (TRI) in Princeton, New Jersey, USA. The technique is described more in detail by Miller and Tyomkin in the Journal of Colloid and Interface Science, volume 162 (1994), pages 163-170, which is included herein for reference. The use of this technique is described in more detail in the Examples.
  • the nonwovens according to the invention can be characterized by their pore volume distribution.
  • at least 70% of the total pore volume is associated with pores having an effective radius of greater than 125 ⁇ m, or equivalently a capillary pressure smaller than 530 Pa during liquid absorption.
  • They can further be characterized by at least 30% of the total pore volume being associated with pores having an effective radius of greater than 150 ⁇ m or equivalently a capillary pressure smaller than 440 Pa during liquid absorption.
  • the pores have an effective radius of not greater than 800 ⁇ m. It should be noted however that these values for pore radius and capillary pressure refer to the values measured during liquid absorption (advancing cycle).
  • the pore volume distribution of the composite structure represents the average value of all the layers.
  • the pore volume distribution of the final product is effected by a number of process parameters, including the used raw materials, the fiber dimensions, carding conditions, hydroentanglement conditions, such as pressures used etc the choice of which are known to or can be determined by the person skilled in the art.
  • the products of the invention can also be characterized by the cumulative volume of filled pores, such volume being less than 35%, preferably less than 30% of the total pore volume as measured from liquid desorption at a pressure of 1650 Pa (corresponding to a pore radius of 40 ⁇ m). At an increased pressure of 3300 Pa (pore radius 20 ⁇ m) the cumulative volume is decreased to less than 10%, preferably less than 8%.
  • Composite structure The outermost webs of the composite structure consist of a mixture of 50 % polypropylene and 50 % viscose and the basis weight of these webs is 15 g/m 2 . In the middle of the structure, sandwiched between the outermost layers there is a layer of 100 % polypropylene (20 g/m 2 ). Thus, the polypropylene content of the whole structure is 70 % and the entire grammage is 50 g/m 2 .
  • the composite structure was made in an apparatus corresponding to that of Figure 1 by feeding the appropriate fiber mixtures to the different fiber feeding stations.
  • the different webs are entangled together by water jets during which the layers are mixed to some degree, basically forming an intermediate zone with a high degree of hydrophobicity which gradually becomes more hydrophilic in a direction towards the outer zones of the hydroentangled web.
  • the layers are bonded together and cannot be separated.
  • the reference sample consists of an essentially uniform mixture of 70 % polypropylene and 30 % viscose.
  • the basis weight is also 50 g/m 2 .
  • the reference sample is manufactured with three cards but all the cards are fed with the same fiber composition.
  • the composite and reference samples are used as such in the following tests, without any further treatment. Test methods
  • a 5.5x5.5 cm 2 specimen was cut from the nonwoven samples and it was covered with a plexiglass plate having the same dimensions and a weight of 23.9 g (corresponding to a pressure of about 80 Pa).
  • the measurements were carried out in the pore radius range of 5-800 ⁇ m corresponding to pressure range of 13200-83 Pa.
  • the measurement can comprise both the advancing (liquid absorption) and the receding (liquid desorption) measuring cycles.
  • a blank measurement without the sample was subtracted from the original data.
  • the Figure 6 shows the pore volume distribution during liquid absorption and desorption and Figure 7 shows the cumulative pore volume during absorption for the above mentioned composite and reference sample.
  • Dynamic wiping tests The dynamic tests were carried out with a wiping device. There were two different test types, which were used for testing wet and dry wiping properties.
  • the sample (7 cm x 10 cm) consisting of 4 g test liquid/g nonwoven was affixed to the bottom side of a 2.4 kg sled (corresponds to a load of 4.8 kPa).
  • the liquid used was a 0.1 wt% water solution of Triton X-100 (surface tension 33 mN/m).
  • the sample which dimensions were 10,3 cm x 16,8 cm was affixed to the bottom side of a 1,3 kg (1,0 kPa) sled.
  • the liquid which in this case was water, was spred evenly to the steel base with a pipette.
  • Two different amounts of liquid were used for each sample: 10 ml, and the volume which was 75 % of the absorption capacity of the sample.
  • the sled was pulled at a rate of 20 cm/s against the base and the amount of liquid absorbed to the sample during the pull was measured with a balance.
  • the basis weight of the nonwoven was determined according to the Edana Recommended Test Method ERT 40.3-90. The reported values are averages of 10 individual measurements.
  • the thickness of the nonwoven was determined according to the Edana Recommended Test
  • the tensile strength and the elongation of the nonwoven materials were determined according to the Edana Recommended Test Method ERT 20.2-89, expect that the extension rate was 300 mm/min. The reported values are averages of 5 individual measurements.
  • This test method which is based on the SFS-ISO 1833 (1991) standard, is applicable to binary mixtures of polypropylene fibers with viscose, polyester, wool, cotton etc.
  • the required amount of nonwoven was taken and the dimensions of the sample were measured.
  • the weight of the sample was determined by using an analytical balance.
  • the viscose was dissolved from the nonwoven with 60 % sulphuric acid at a temperature of 60 °C.
  • the sample was mixed with a glass rod and the dissolving time was six minutes. After dissolving, the sample was rinsed carefully with deionized water and it was dried for one to two hours at 105 °C in a ventilated oven.
  • the sample was cooled at room temperature for about one hour and the mass of insoluble component (PP) was expressed as a percentage and gsm of the total mass of fiber in the mixture.
  • the proportion of soluble component e.g viscose was calculated from the loss in mass.
  • the number of parallel measurements was four.
  • the liquid porosimeter was employed in both advancing and receding modes. During the advancing run, the sample was wetted by the test liquid and the receding part was used to determine the liquid release properties. Cumulative volumes of the filled pores are shown in Figure 2. The pore radius range 5-50 ⁇ m corresponds to the pressure range 13200-1320 Pa. Cumulative volumes of filled pores at 10, 20, 30, 40 and 50 ⁇ m as a percentage (correspond to the pressures of 6600, 3300, 2200, 1650 and 1320 Pa) are presented in Table III. The selection of this pressure range is based on the estimate of pressures used during the wiping procedure in different wiping applications (baby wet wipe, household etc.). From Figure 2 and Table III it is seen that the amount of filled pores in the composite structure is smaller than in the reference sample. Thus, according to the liquid porosimeter measurements, the release properties of the composite structure are better as compared to the reference sample. Table III.
  • the wiping test with wet samples indicated the difference between the composite structure and the reference sample ( Figure 4).
  • the liquid release is higher for the composite structure than for the reference sample. For example, after three consecutive releases the composite structure retained about 10% less liquid than the reference sample.
  • the results from the wiping test with dry samples showed that the wiping efficiency was better for the composite structure (Figure 5).
  • the composite structure is capable of absorbing 12.4 - 16.7% more liquid during the wiping test than the reference sample.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Abstract

L'invention concerne un non-tissé composite constitué de couches fibreuses liées ensemble par enchevêtrement des fibres de celles-ci, les couches fibreuses comprenant des première et seconde couches externes, chacune renfermant un mélange de fibres hydrophobes et hydrophiles, ainsi qu'une couche intermédiaire de fibres hydrophobes prise en sandwich entre les première et seconde couches externes, le rapport pondéral entre les fibres hydrophobes et hydrophiles dans les première et seconde couches étant compris entre 20:80 et 80:20. L'invention concerne également la fabrication du non-tissé, ainsi que l'utilisation de celui-ci, notamment comme chiffon humide.
PCT/FI2002/000995 2001-12-10 2002-12-05 Non-tisse composite, utilisation et procede de fabrication associes WO2003050347A1 (fr)

Priority Applications (3)

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EP02783133A EP1461489A1 (fr) 2001-12-10 2002-12-05 Non-tisse composite, utilisation et procede de fabrication associes
US10/497,166 US20050090175A1 (en) 2001-12-10 2002-12-05 Composite nonwoven its use and method of manufacture
AU2002346783A AU2002346783A1 (en) 2001-12-10 2002-12-05 Composite nonwoven, its use and method of manufacture

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Application Number Priority Date Filing Date Title
FI20012426 2001-12-10
FI20012426A FI116226B (fi) 2001-12-10 2001-12-10 Kuitukangaskomposiitti, sen käyttö ja menetelmä sen valmistamiseksi

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WO2003050347A1 true WO2003050347A1 (fr) 2003-06-19

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EP (1) EP1461489A1 (fr)
AU (1) AU2002346783A1 (fr)
FI (1) FI116226B (fr)
WO (1) WO2003050347A1 (fr)

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WO2005065516A2 (fr) * 2003-12-30 2005-07-21 Kimberly-Clark Worldwide, Inc. Lingette humide presentant un faible ajout de liquide
WO2005124001A1 (fr) * 2004-06-18 2005-12-29 Suominen Nonwovens Ltd. Procede et appareil pour la fabrication d'un non-tisse
WO2006004871A1 (fr) * 2004-06-29 2006-01-12 The Procter & Gamble Company Lingette humide de faible grammage et de toucher agreable
WO2009010939A2 (fr) * 2007-07-17 2009-01-22 The Procter & Gamble Company Structures fibreuses et leurs procédés de réalisation
EP2264242A1 (fr) * 2009-06-16 2010-12-22 Ahlstrom Corporation Produits en tissu non tissés avec des propriétés de transfert améliorées
US7972986B2 (en) 2007-07-17 2011-07-05 The Procter & Gamble Company Fibrous structures and methods for making same
WO2014026207A1 (fr) * 2012-08-17 2014-02-20 Lenzing Ag Produits non tissés comprenant des fibres artificielles cellulosiques hydrophobes
US8852474B2 (en) 2007-07-17 2014-10-07 The Procter & Gamble Company Process for making fibrous structures
US8921244B2 (en) 2005-08-22 2014-12-30 The Procter & Gamble Company Hydroxyl polymer fiber fibrous structures and processes for making same
EP2013391B1 (fr) 2006-05-01 2015-06-17 The Procter and Gamble Company Lingette comprenant une structure fibreuse hydromoulée
US9458573B2 (en) 2009-11-02 2016-10-04 The Procter & Gamble Company Fibrous structures and methods for making same
US9631321B2 (en) 2010-03-31 2017-04-25 The Procter & Gamble Company Absorptive fibrous structures
US10895022B2 (en) 2009-11-02 2021-01-19 The Procter & Gamble Company Fibrous elements and fibrous structures employing same
US11414798B2 (en) 2007-07-17 2022-08-16 The Procter & Gamble Company Fibrous structures

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JP5388535B2 (ja) * 2008-10-17 2014-01-15 ユニ・チャーム株式会社 化粧パフ
WO2011053946A1 (fr) * 2009-11-02 2011-05-05 The Procter & Gamble Company Structures fibreuses faiblement pelucheuses et leurs procédés de fabrication
AU2010313169A1 (en) * 2009-11-02 2012-05-24 The Procter & Gamble Company Fibrous structures that exhibit consumer relevant property values
US20110117353A1 (en) * 2009-11-17 2011-05-19 Outlast Technologies, Inc. Fibers and articles having combined fire resistance and enhanced reversible thermal properties
US20130052401A1 (en) * 2011-08-30 2013-02-28 VaproShield, LLC Recyclable air barrier building membrane
US11186985B2 (en) 2013-07-22 2021-11-30 VaproShield, LLC Vapor permeable, water resistive, air barrier polyester membrane having a polyacrylic coating with porous pressure sensitive adhesive added to the rear surface of the membrane
US11485112B2 (en) 2013-07-22 2022-11-01 VaproShield, LLC Building membrane with porous pressure sensitive adhesive
CA2962420A1 (fr) * 2014-09-24 2016-03-31 Georgia-Pacific Consumer Products Lp Produits de type lingettes humides prealablement humidifiees sous forme de rouleau perfore, constitues de substrats a base de tissu
US11525265B2 (en) 2018-09-18 2022-12-13 VaproShield, LLC Permeable water resistive roof underlayment
US11512473B2 (en) 2018-12-13 2022-11-29 Vaproshield Llc Permeable water-resistive sloped roof underlayment/air barrier
CN114190616A (zh) * 2021-12-03 2022-03-18 厦门悠派无纺布制品有限公司 一种抗菌一次性无纺布内裤及其制备方法
CN115177439B (zh) * 2022-07-05 2023-05-23 杭州诺邦无纺股份有限公司 一种可冲散全降解卫生巾、护垫的制备方法
CN115671797B (zh) * 2022-12-12 2024-10-18 四川大学 一种高效抗污乳液分离材料及其制备方法和应用

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Cited By (31)

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Publication number Priority date Publication date Assignee Title
WO2005065516A3 (fr) * 2003-12-30 2007-01-25 Kimberly Clark Co Lingette humide presentant un faible ajout de liquide
WO2005065516A2 (fr) * 2003-12-30 2005-07-21 Kimberly-Clark Worldwide, Inc. Lingette humide presentant un faible ajout de liquide
WO2005124001A1 (fr) * 2004-06-18 2005-12-29 Suominen Nonwovens Ltd. Procede et appareil pour la fabrication d'un non-tisse
US8557722B2 (en) 2004-06-29 2013-10-15 The Procter & Gamble Company Low basis weight wet wipes with a pleasing hand
WO2006004871A1 (fr) * 2004-06-29 2006-01-12 The Procter & Gamble Company Lingette humide de faible grammage et de toucher agreable
US8921244B2 (en) 2005-08-22 2014-12-30 The Procter & Gamble Company Hydroxyl polymer fiber fibrous structures and processes for making same
EP2013391B1 (fr) 2006-05-01 2015-06-17 The Procter and Gamble Company Lingette comprenant une structure fibreuse hydromoulée
US11959225B2 (en) 2007-07-17 2024-04-16 The Procter & Gamble Company Fibrous structures and methods for making same
WO2009010939A2 (fr) * 2007-07-17 2009-01-22 The Procter & Gamble Company Structures fibreuses et leurs procédés de réalisation
US11326276B2 (en) 2007-07-17 2022-05-10 The Procter & Gamble Company Process for making fibrous structures
US10858785B2 (en) 2007-07-17 2020-12-08 The Procter & Gamble Company Fibrous structures and methods for making same
US8852474B2 (en) 2007-07-17 2014-10-07 The Procter & Gamble Company Process for making fibrous structures
US10513801B2 (en) 2007-07-17 2019-12-24 The Procter & Gamble Company Process for making fibrous structures
WO2009010939A3 (fr) * 2007-07-17 2009-03-12 Procter & Gamble Structures fibreuses et leurs procédés de réalisation
US7972986B2 (en) 2007-07-17 2011-07-05 The Procter & Gamble Company Fibrous structures and methods for making same
US11639581B2 (en) 2007-07-17 2023-05-02 The Procter & Gamble Company Fibrous structures and methods for making same
US11414798B2 (en) 2007-07-17 2022-08-16 The Procter & Gamble Company Fibrous structures
US9926648B2 (en) 2007-07-17 2018-03-27 The Procter & Gamble Company Process for making fibrous structures
US10024000B2 (en) 2007-07-17 2018-07-17 The Procter & Gamble Company Fibrous structures and methods for making same
US11346056B2 (en) 2007-07-17 2022-05-31 The Procter & Gamble Company Fibrous structures and methods for making same
EP2264242A1 (fr) * 2009-06-16 2010-12-22 Ahlstrom Corporation Produits en tissu non tissés avec des propriétés de transfert améliorées
WO2010146240A3 (fr) * 2009-06-16 2011-04-07 Ahlstrom Corporation Produits de tissu non-tissé présentant des propriétés améliorées de transfert
US9458573B2 (en) 2009-11-02 2016-10-04 The Procter & Gamble Company Fibrous structures and methods for making same
US10895022B2 (en) 2009-11-02 2021-01-19 The Procter & Gamble Company Fibrous elements and fibrous structures employing same
US9714484B2 (en) 2009-11-02 2017-07-25 The Procter & Gamble Company Fibrous structures and methods for making same
US11618977B2 (en) 2009-11-02 2023-04-04 The Procter & Gamble Company Fibrous elements and fibrous structures employing same
US10697127B2 (en) 2010-03-31 2020-06-30 The Procter & Gamble Company Fibrous structures and methods for making same
US10240297B2 (en) 2010-03-31 2019-03-26 The Procter & Gamble Company Fibrous structures and methods for making same
US9631321B2 (en) 2010-03-31 2017-04-25 The Procter & Gamble Company Absorptive fibrous structures
US11680373B2 (en) 2010-03-31 2023-06-20 The Procter & Gamble Company Container for fibrous wipes
WO2014026207A1 (fr) * 2012-08-17 2014-02-20 Lenzing Ag Produits non tissés comprenant des fibres artificielles cellulosiques hydrophobes

Also Published As

Publication number Publication date
AU2002346783A1 (en) 2003-06-23
EP1461489A1 (fr) 2004-09-29
US20050090175A1 (en) 2005-04-28
FI20012426A (fi) 2003-06-11
FI20012426A0 (fi) 2001-12-10
FI116226B (fi) 2005-10-14

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