WO2003048670A1 - Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle - Google Patents
Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle Download PDFInfo
- Publication number
- WO2003048670A1 WO2003048670A1 PCT/US2002/034606 US0234606W WO03048670A1 WO 2003048670 A1 WO2003048670 A1 WO 2003048670A1 US 0234606 W US0234606 W US 0234606W WO 03048670 A1 WO03048670 A1 WO 03048670A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tubes
- headers
- parallel
- heat exchanger
- fins
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/047—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/02—Tubular elements of cross-section which is non-circular
- F28F1/022—Tubular elements of cross-section which is non-circular with multiple channels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/047—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag
- F28D1/0477—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag the conduits being bent in a serpentine or zig-zag
- F28D1/0478—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being bent, e.g. in a serpentine or zig-zag the conduits being bent in a serpentine or zig-zag the conduits having a non-circular cross-section
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/02—Tubular elements of cross-section which is non-circular
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/126—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element consisting of zig-zag shaped fins
- F28F1/128—Fins with openings, e.g. louvered fins
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2309/00—Gas cycle refrigeration machines
- F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
- F25B2309/061—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0068—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for refrigerant cycles
- F28D2021/0073—Gas coolers
Definitions
- This invention relates to heat exchangers, and more particularly, to heat exchangers that provide supercritical cooling of a working fluid in a transcritical cooling cycle.
- One common form of a heat exchanger includes a so called “core” made up of tubes and interconnecting fins. One fluid is passed through the tubes of the core while a second fluid is passed through the core itself in the spaces between the fins and tubes.
- the opposite ends of the tubes are connected to a pair of parallel manifolds or "tanks", with one of the manifolds being an inlet manifold and the other manifold being an outlet manifold which direct one of the fluids into and out of the tubes, respectively.
- Heat exchangers of this general type are used for a large variety of purposes, such as radiators, condensers, evaporators, charge air coolers, oil coolers, etc., all of which may be utilized in a vehicle.
- C0 2 utilized as a refrigerant in such systems could be claimed from the atmosphere at the outset with the result that if it were to leak from the system back to the atmosphere, there would be no net increase in atmospheric C0 2 content.
- C0 2 is undesirable from the standpoint of a greenhouse effect, it does not affect the ozone layer and would not cause an increase in the greenhouse effect since there would be no net increase in the atmospheric C0 2 content as a result of leakage.
- An exemplary embodiment of the invention achieves at least some of the foregoing objects in a heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle.
- the heat exchanger includes a pair of elongated headers having longitudinal axis disposed substantially parallel to each other, a plurality of elongated tubes spaced in side by side relation along the longitudinal axis of the headers, with each of the tubes being folded upon itself to define at least two parallel legs of the tube so that the working fluid flows serially through at least two parallel passes from one of the headers to the other, and serpentine fins extending between adjacent pairs of the tubes, with each of the fins having a length extending parallel to the parallel legs of the adjacent tubes.
- Each of the tubes has a flat cross-section with a major dimension and a minor dimension.
- the major dimensions of the parallel legs of each of the tubes lie in a common plane that is substantially transverse to the longitudinal axes of the headers.
- Each of the tubes has a first end connected to one of the headers and a second end connected to the other header to transfer the working fluid between the headers.
- each of the serpentine fins has a transverse width extending across the parallel legs of the adjacent tubes.
- Each of the fins includes a plurality of alternating tabs and elongated separations extending parallel to the parallel legs, with the tabs and separations located between the parallel legs of the adjacent tubes to divide the width of each fin into a plurality of discrete fin elements that are connected to each other by the tabs.
- Each of the fin elements corresponds to and extends along one of the parallel legs of each of the adjacent tubes.
- the parallel legs of each of the tubes are spaced from each other.
- each of the tubes is folded upon itself at least twice to define at least three parallel legs of the tube so that the working fluid flows serially through at least three parallel fluid passes from one of the headers to the other.
- each of the tubes is a multi-port tube with a hydraulic diameter in the range of .015 inch to .040 inch.
- the major dimension of each of the tubes is no greater than .500 inch and the minor dimension is no greater than .100 inch.
- each of the fins has a fin height extending from one of the tubes to an adjacent one of the tubes, parallel to the longitudinal axes of the headers, and the major dimension of the tubes is no greater than the fin height.
- the major dimensions of the tubes extend parallel to the longitudinal axes of the headers at the location where the tube end is connected to the header.
- Fig.1 is a somewhat diagrammatic elevation view of a cooling system including a heat exchanger embodying the present invention
- Fig. 2 is an elevation view of the heat exchanger shown in Fig. 1 ;
- Fig. 3 is a side view of the heat exchanger shown in Fig. 2;
- Fig.4 is a top view of the heat exchanger shown in Fig. 2;
- Fig. 5 is an enlarged, partial section view taken along line 5-5 in Fig. 3;
- Fig. 6 is an enlarged, partial view of a tube employed in the heat exchanger shown in Figs. 1-5; and
- Fig.7 is a perspective view showing a tube and a fin utilized in a heat exchanger embodying the invention.
- a heat exchanger 10 embodying the present invention is shown in connection with a basic cooling system 12 that operates a transcritical cooling cycle.
- the heat exchanger 10 is shown in the form of a gas cooler 13 that provides supercritical cooling to the working fluid or refrigerant, such as C0 2 , of the cooling system 12 by rejecting heat to a medium, such as an air flow A, on the fin side of the heat exchanger.10.
- the cooling system 12 includes the heat exchanger 10, a compressor 14, that compresses gaseous phase refrigerants to a supercritical pressure for delivery to the heat exchanger 10, an expansion device 16, that reduces the pressure in the refrigerant received from the heat exchanger 10 so at least some of the refrigerant enters the liquid phase, an evaporator 17 that transfers heat from one medium into the refrigerant to change the refrigerant from the liquid phase to the gaseous phase, an accumulator 18 (optional), and a suction line heat exchanger 19 that transfers heat from the refrigerant exiting the heat exchanger 10 into the refrigerant exiting the evaporator 17, or accumulator 18 if used.
- the heat exchanger 10 may find use in other types of cooling systems, and in other configurations of cooling systems that perform a transcritical cooling cycle, and is not limited to use with the specific cooling system shown in Fig. 1 unless specifically recited in the claims. Further, while the disclosed heat exchanger 10 can provide distinct advantages when used as a gas cooler 13, it may also prove advantageous when used for other purposes, such as a condenser or an evaporator, regardless of whether it is used in connection with a transcritical cooling cycle.
- the heat exchanger 10 includes a pair of elongated tubular headers 20 and 22 having longitudinal axes 24 and 26, respectively, disposed substantially parallel to each other; a plurality of elongated tubes 28 spaced in side-by-side relations along the longitudinal axes 24, 26 of the headers 20, 22; and serpentine fins 30 extending between adjacent pairs of the tubes 28.
- each fin 30 extends over a length L of the tubes 28, but the middle portions of the lengths are not shown in Fig. 2 for convenience of illustration.
- the fins 30 are louvered.
- each of the tubes 28 has a first end 31 connected to the header 20 and a second end 32 connected to the header 22 to transfer the refrigerant between the headers 20, 22.
- Each of the tubes 28 has a flattened cross-section with a major dimension D and a minor dimension d, as best seen in Fig. 5.
- Each of the tubes 28 is preferably a multi-port tube and, in highly preferred embodiments, a multi-port tube having a hydraulic diameter in the range of
- each of the tubes has four ports 34.
- the tubes are configured to withstand a burst pressure of at least 6500 PSI, at 70°F ambient, such as may be required for operation as a gas cooler in a transcritical C0 2 cooling system.
- the major dimension D of each of the tubes 28 is nominally no greater than 0.500 inch and the minor dimension d is nominally no greater than 0.100 inch, while in some highly preferred embodiments the minor dimension d is nominally no greater than 0.060 inch and the major dimension D is nominally no greater than 0.320 inch.
- reducing the major dimension D can offer a number of advantages. For example, because each of the tubes 28 includes at least two parallel legs 36, the depth of the heat exchanger 10 becomes highly dependent upon the size of the major dimension D and will be reduced with the reduction in the major dimension D.
- the diameter of the headers 20, 22 can be reduced in a construction where the major dimension D of the tube ends 31 , 32 extends transverse to the longitudinal axes 24, 26 of the headers 20, 22 at the locations where the ends 31, 32 are connected to the headers 20, 22, rather than the parallel construction shown in Figs. 1-4.
- the length of the headers 20, 22, can be reduced in a construction wherein the major dimension D of the tube ends 31 , 32 extend parallel to the longitudinal axes 24, 26 of the headers 20, 22, such as shown in Figs. 1-4.
- a reduction in the major dimension D can allow for a reduction in the fin height in some preferred embodiments. However, it should be understood that larger fin heights may offer advantages with respect to air side efficiency.
- each of the tubes 28 is folded upon itself to define at least two parallel legs 36 of the tube 28 so that the refrigerant flows serially through at least two parallel fluid passes 38 from the header 20 to the header 22.
- the inlet and outlet headers 20, 22 be selected so that the heat exchanger 10 operates in a cross-counterflow configuration relative to the fluid flow on the fin side of the heat exchanger 10 when operating as a gas cooler.
- Each pair of the parallel legs is joined by a fold 39 that is twisted 90° relative to the legs 36 at the location of the fold 39 so that the major dimension D extends parallel to the axes 26, 24 at the location of the fold 39, rather than transverse.
- the fold 39 is formed by first twisting the legs 36 90° relative to the portion of the tube 28 at the location of the fold 39, and then bending the tube through approximately 180° at the location of the fold 39 to form the fold 39.
- the 90° twist of each of the legs 36 relative to the fold 39 can be in the same direction as shown in
- the parallel legs 36 of each of the tubes 28 are preferably spaced from each other by a distance X, With the major dimension D of each of the parallel legs 36 lying in a common plane, illustrated by dashed line P in Figs. 2 and 5, that is substantially transverse to the longitudinal axes 24, 26 of the headers 20, 22. This allows the major dimension D to extend parallel to the direction of the flow of the medium through the fins 30.
- the spacing X reduces heat conduction from one leg 36 to the other, which can be advantageous when the heat exchanger 10 is providing supercritical cooling because the temperature of the refrigerant can vary substantially as it flows through the tube 28 from one header 20 to the other header 22.
- the distance X is sufficient to minimize or prevent the closing of the space between adjacent parallel legs 36 by braze material during brazing of the heat exchanger 10, but not so large so as to unduly increase the depth of the heat exchanger 10. While it is preferred that the adjacent parallel legs 36 of each tube 28 be spaced from each other, in some applications this spacing may not be required and/or desirable
- each of the fins 30 has a fin height H equal to the spacing between adjacent tubes 28, i.e. a fin height H extending from one of the tubes 28 to an adjacent tube 28 parallel to the longitudinal axes 24, 26 of the headers 20, 22.
- each of the tube ends 31 , 32 can be twisted 90° relative to the parallel legs 36 from which they extend so that the major dimension D of the end 31 , 32 extends parallel to the longitudinal axes 24, 26 of the headers 20, 22 at the location where the tube ends 31 and 32 are connected to the headers 20 and 22, as seen in Fig. 2.
- This can be important in high pressure applications, such as gas coolers used in transcritical refrigeration systems, where it is desirable that the diameter of the headers 20, 22 be as small as possible. It is conceivable, even likely, in such constructions that the major dimension D will be greater than the inner diameter of either of the headers 20, 22.
- each of the serpentine fins 30 has a length
- each of the fins 30 includes a plurality of alternating tabs 40 and elongated separations 42 extending parallel to the parallel legs 36 and located between the parallel legs 36 of the adjacent tubes 28 to divide the width W of each fin 30 into two or more discrete fin strips or elements 44 that are connected to each other by the tabs 40.
- Each of the fin elements 44 corresponds to and extends along one of the parallel legs 36 of each of the adjacent tubes 28.
- the separations 42 are generally straight line and have opposed edges 45 that face one another and are generally transverse to the direction of the medium flow through the fins 30. While Fig. 7 illustrates the fin 30 for tubes 28 having two parallel legs 36, it should be understood that the above construction including the tabs 40, separations 42 and fin elements 44 is utilized in constructions of the heat exchanger 10 having more than two parallel legs 36 in each of the tubes 28, such as the constructions shown in Figs. 2-5.
- each of the fins 30 preferably extends across all of the parallel legs 36 with a fin element 44 corresponding to and extending along each of the parallel legs 36 of each of the adjacent tubes 28, and the tabs 40 and separations 42 provided between each of the fin elements 44.
- the alternating tabs 40 in each of the fins 30 serve to restrict movement of the fin elements 44 relative to each other so that each fin 30 remains a unitary component during the assembly of the heat exchanger 10 and, furthermore, to better maintain the fin elements 44 in alignment with each other to minimize the pressure drop on the fin side of the heat exchanger.
- the purpose of the elongated separations 42 is to minimize the heat conduction from each of the parallel legs 36 to any adjacent parallel leg 36 of each tube 28 by interrupting, and thus minimizing, the heat conduction between the fin elements 44 associated with each of the parallel legs 36. This is desirable in applications, such as the gas cooler 13 of Figs. 2-4, where the working fluid temperature entering the heat exchanger 10 is significantly different from the desired temperature for the working fluid leaving the heat exchanger 10.
- each of the elongated separations 42 it is desirable for each of the elongated separations 42 to extend uninterrupted as far as possible along the length of the fin 30 and for the number and size of the tabs 40 to be minimized to that which is required to prevent each of the fin elements 44 from separating during assembly and to maintain an acceptable degree of alignment between the fin elements 44 of each of the fins 30 during assembly. From the foregoing, It should be understood that a number of configurations are possible for the tabs 40 and the elongated separations 42.
- each of the tabs 40 extends approximately 0.020 inch along the length of the fin 30 and each of the elongated separations 42 of a fin 30 made of aluminum extends approximately 8.0 inches along the length of the unfolded fin 30.
- the tabs 40 and the separations 44 have lengths extending parallel with the length of the fin 30 in the unfolded state and the ratio of the length of the separations 42 to the length of the tabs 40 is in the range of 200 to 600.
- each of the elongated separations 42 extends uninterrupted from one of the tabs 40 over 10 to 14 of the folds 46 to the next tab 40 with the fin 30 in the folded condition.
- the tabs 40 and the separations 42 can be formed in a number of ways, it is preferred that the separations 42 be formed as cuts or slits in the fin material that do not require removal of fin material during formation in the fin 30.
- One way of achieving such slits or cuts is to use a splitter disk in the fin roll die to create a simple cut in the fin 30 as the fin 30 is formed from a strip of sheet material. The split could be eliminated for a small portion of the disk in every revolution to form the tabs 40 to ensure that each fin element 44 stays attached to the adjoining fin element 44 of the fin 30. This provides a physical cut or slit in the fin 30, with no loss of fin surface. In one such construction the edges 45 are virtually, but not quite, in abutment with each other.
- fin elements 44 might braze together during the brazing process.
- One approach to minimize this concern is to locate the braze material on the side walls of the tube legs 36 that abut the fins 30, rather than cladding the braze material onto the fins 30.
- Another approach to minimize this concern is to offset adjacent fin elements 44 of the fin 30 at locations remote from the tab 40, which may allow for clad fins.
- Another approach would be to bend the edges 45 formed by the slits slightly apart, forming a very small louver, which may also allow for clad fins.
- Yet another approach is to coin each of the tab portions 40 to further separate the fin elements 44 from each other. Again, this last approach may allow for clad fins.
- the separations 42 may be formed as slots that do require removal of fin material when formed in the fins 30. In this regard, it would probably be sufficient for the slots to have a width of a few thousands of an inch parallel to the width W of the fin 30. While it is preferred that the fins 30 include the tabs 40 and separations 44, in some applications the tabs 40 and separations 42 may not be desirable and/or required.
- the fins 30 be louvered, many forms of which are known.
- the exact configuration of the louvers will be highly dependent on the parameters of the particular application such as, for example, the fluid on the fin side of the heat exchanger 10, the available pressure drop on the fin side of the heat exchanger 10, the number of parallel iegs 36 in each of the tubes 28, and whether there is an odd or even number of parallel legs 36 in each of the tubes 28.
- the heat exchanger 10 when operating as a gas cooler 13 in the system 12, the heat exchanger 10 will typically provide supercritical cooling of the refrigerant; however, there may be some conditions of operation wherein the ambient temperature is below the critical temperature, in which case the heat exchanger 10 will operate as a condenser that provides subcritical cooling for the refrigerant.
- the illustrated heat exchanger 10 includes 12 parallel legs 36 for each of, the tubes 28.
- the optimum number of parallel legs for each application of the heat exchanger 10 will be highly dependent upon the specific parameters for the particular application such as, for example, the working fluid of the system 12, the envelope and environment into which the heat exchanger 10 must be packaged, and the function of the heat exchanger, i.e., as a gas cooler, condenser, or evaporator for use in either an AC or heat pump system.
- one or more baffles can be provided within either or both of the headers 20, 22 to direct the refrigerant from the header 20 through a subset of the tubes 28 to the header 22 and then back through a different subset of the tubes 28 to the header 20 and so on for as many passes from one header to the other as may be needed to provide the performance dictated by each particular application.
- the headers 20, 22 may be provided with any suitable embodiment of the headers 20, 22 to direct the refrigerant from the header 20 through a subset of the tubes 28 to the header 22 and then back through a different subset of the tubes 28 to the header 20 and so on for as many passes from one header to the other as may be needed to provide the performance dictated by each particular application.
- the headers 20, 22 may be provided within either or both of the headers 20, 22 to direct the refrigerant from the header 20 through a subset of the tubes 28 to the header 22 and then back through a different subset of the tubes 28 to the header 20 and so on for as many passes from one header to the other as may be
- a heat exchanger 10 illustrated in Figs. 1-3 is shown so that the longitudinal axes 24, 26 of the headers 20, 22 extend in a horizontal direction, and the parallel legs 36 of the tubes 28 extend in a vertical direction, it may be desirable in some applications for a heat exchanger 10 to have a different orientation, such as, for an example, an orientation wherein the axes 24, 26 extend in a vertical direction and the parallel legs 36 extend in a horizontal direction.
- the headers 20, 22 of the heat exchanger 10 illustrated in Figs. 1 -3 are located on the same side of the heat exchanger 10, it may be desirable in some applications for the headers 20, 22 to be located on opposite sides of the heat exchanger 10.
- a construction with the headers 20, 22 on the same side of the heat exchanger will typically result in an even number of parallel legs 36 for each of the tubes 28, while a construction with the headers 20,
- header plates fitted with tanks could be employed in lieu of the tubular headers 20, 22 if desired for a particular application.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Geometry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003549821A JP2005512009A (en) | 2001-11-30 | 2002-10-30 | A heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
BR0214479-4A BR0214479A (en) | 2001-11-30 | 2002-10-30 | Heat exchanger to provide supercritically cooling working fluid in a transcritically cooled cycle |
CA002467137A CA2467137A1 (en) | 2001-11-30 | 2002-10-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
AU2002365762A AU2002365762B2 (en) | 2001-11-30 | 2002-10-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
MXPA04004660A MXPA04004660A (en) | 2001-11-30 | 2002-10-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle. |
EP02804409A EP1448945A1 (en) | 2001-11-30 | 2002-10-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/013,018 | 2001-11-30 | ||
US10/013,018 US20030102113A1 (en) | 2001-11-30 | 2001-11-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003048670A1 true WO2003048670A1 (en) | 2003-06-12 |
Family
ID=21757888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2002/034606 WO2003048670A1 (en) | 2001-11-30 | 2002-10-30 | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle |
Country Status (13)
Country | Link |
---|---|
US (1) | US20030102113A1 (en) |
EP (1) | EP1448945A1 (en) |
JP (1) | JP2005512009A (en) |
KR (1) | KR20050058253A (en) |
CN (2) | CN101089533A (en) |
AR (1) | AR037428A1 (en) |
AU (1) | AU2002365762B2 (en) |
BR (1) | BR0214479A (en) |
CA (1) | CA2467137A1 (en) |
MX (1) | MXPA04004660A (en) |
RU (1) | RU2319094C2 (en) |
TW (1) | TW200301815A (en) |
WO (1) | WO2003048670A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2907887A1 (en) * | 2006-10-25 | 2008-05-02 | Valeo Systemes Thermiques | Heat exchanger for motor vehicle, has fin portions respectively fixed in contact with fluid circulation tubes, where tubes are covered with filler metal plating at level of contact and fin portions are free from plating near rupture |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2003263182A1 (en) * | 2002-07-26 | 2004-02-23 | Behr Gmbh And Co. | Device for heat exchange |
DE10352337A1 (en) * | 2002-11-07 | 2004-05-27 | Behr Gmbh & Co. Kg | Heat exchanger for use in motor vehicle, especially in air-conditioning system, has fluid supply line and fluid outlet line, two heat exchanger units, and flow-connecting device |
DE10306848A1 (en) * | 2003-02-18 | 2004-08-26 | Behr Gmbh & Co. Kg | Flat tube with bend section forming heat exchanger for gas cooler or evaporator has bent over section with main bend axis parallel to flat tube plane and at definable angle to pipe length |
GB2400648A (en) * | 2003-03-19 | 2004-10-20 | Calsonic Kansei Uk Ltd | An automotive heat exchanger |
US7261151B2 (en) * | 2003-11-20 | 2007-08-28 | Modine Manufacturing Company | Suction line heat exchanger for CO2 cooling system |
DE102004001786A1 (en) * | 2004-01-12 | 2005-08-04 | Behr Gmbh & Co. Kg | Heat exchanger, especially for supercritical refrigeration cycle |
US7343965B2 (en) * | 2004-01-20 | 2008-03-18 | Modine Manufacturing Company | Brazed plate high pressure heat exchanger |
DE102004038640A1 (en) | 2004-08-09 | 2006-02-23 | Linde Kältetechnik GmbH & Co. KG | Refrigeration circuit and method for operating a refrigeration cycle |
DE102004056557A1 (en) * | 2004-11-23 | 2006-05-24 | Behr Gmbh & Co. Kg | Dimensionally optimized heat exchange device and method for optimizing the dimensions of heat exchange devices |
CN1333228C (en) * | 2005-01-26 | 2007-08-22 | 清华大学 | Microchannel slab internal heat exchanger of overcritical Co2 refrigerating circulation |
FR2894656B1 (en) * | 2005-12-14 | 2010-04-16 | Valeo Systemes Thermiques | PERFECTED COLLECTOR BOX FOR HEAT EXCHANGER OF AIR CONDITIONING CIRCUIT |
US7921904B2 (en) * | 2007-01-23 | 2011-04-12 | Modine Manufacturing Company | Heat exchanger and method |
JP5081558B2 (en) * | 2007-09-28 | 2012-11-28 | 三洋電機株式会社 | Projection display device |
US8087256B2 (en) * | 2007-11-02 | 2012-01-03 | Cryomechanics, LLC | Cooling methods and systems using supercritical fluids |
CN101776357B (en) * | 2009-01-09 | 2011-12-28 | 三花丹佛斯(杭州)微通道换热器有限公司 | Heat exchanger |
CN101776403B (en) * | 2009-01-13 | 2012-07-04 | 三花丹佛斯(杭州)微通道换热器有限公司 | Heat exchanger |
DE102009047620C5 (en) * | 2009-12-08 | 2023-01-19 | Hanon Systems | Heat exchanger with tube bundle |
CN101846465B (en) * | 2010-04-13 | 2011-11-09 | 三花丹佛斯(杭州)微通道换热器有限公司 | Heat exchanger |
WO2014133395A1 (en) * | 2013-03-01 | 2014-09-04 | Norsk Hydro Asa | Fin solution related to micro channel based heat exchanger |
JP6687967B2 (en) | 2014-03-24 | 2020-04-28 | 株式会社デンソー | Heat exchanger |
EP3224565B1 (en) * | 2014-11-26 | 2023-12-27 | Carrier Corporation | Frost tolerant microchannel heat exchanger |
CN106643263B (en) * | 2015-07-29 | 2019-02-15 | 丹佛斯微通道换热器(嘉兴)有限公司 | Fin component for heat exchanger and the heat exchanger with the fin component |
EP3330657B1 (en) | 2016-12-01 | 2020-10-28 | Modine Manufacturing Company | Air fin for a heat exchanger, and method of making the same |
US11692479B2 (en) | 2019-10-03 | 2023-07-04 | General Electric Company | Heat exchanger with active buffer layer |
US11519356B2 (en) * | 2020-10-22 | 2022-12-06 | Southwest Research Institute | Techniques for engine cooling using supercritical fluids and a combustion engine system implementing the same |
Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58214793A (en) * | 1982-06-09 | 1983-12-14 | Mitsubishi Electric Corp | Heat exchanger |
JPS58217195A (en) * | 1982-06-10 | 1983-12-17 | Mitsubishi Electric Corp | Heat exchanger |
EP0431917A1 (en) * | 1989-12-07 | 1991-06-12 | Showa Aluminum Kabushiki Kaisha | Consolidated duplex heat exchanger |
US5036909A (en) * | 1989-06-22 | 1991-08-06 | General Motors Corporation | Multiple serpentine tube heat exchanger |
EP0448183A2 (en) * | 1988-09-14 | 1991-09-25 | Showa Aluminum Kabushiki Kaisha | A condenser |
US5076354A (en) * | 1989-04-26 | 1991-12-31 | Diesel Kiki Co., Ltd. | Multiflow type condenser for car air conditioner |
US5531268A (en) | 1993-11-24 | 1996-07-02 | Showa Aluminum Corporation | Heat exchanger |
US5730212A (en) * | 1992-11-25 | 1998-03-24 | Nippondenso Co., Ltd. | Refrigerant condenser |
EP0845648A2 (en) * | 1996-11-27 | 1998-06-03 | Behr GmbH & Co. | Flat tube heat exchanger, particularly serpentine condenser |
JPH11159987A (en) * | 1997-11-29 | 1999-06-15 | Toyo Radiator Co Ltd | Corrugate fin for compound heat exchanger |
DE19830863A1 (en) * | 1998-07-10 | 2000-01-13 | Behr Gmbh & Co | Flat tube with transverse offset reversing bend section and thus built-up heat exchanger |
DE10007159A1 (en) * | 1999-03-08 | 2000-09-14 | Denso Corp | Method for manufacturing heat exchangers for super critical refrigeration circuits has flat multi-bore tubes between manifolds and finned plates joining them |
FR2793013A1 (en) * | 1999-04-28 | 2000-11-03 | Valeo Thermique Moteur Sa | Heat exchanger assembly for an automobile, utilises a cross flow configuration between the fluid supply and sump assemblies via tubular plate type heat exchange fins |
US6308527B1 (en) * | 1998-12-10 | 2001-10-30 | Denso Corporation | Refrigerant evaporator with condensed water drain structure |
EP1231448A2 (en) * | 2001-02-07 | 2002-08-14 | Modine Manufacturing Company | Heat exchanger |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3416600A (en) * | 1967-01-23 | 1968-12-17 | Whirlpool Co | Heat exchanger having twisted multiple passage tubes |
US4688394A (en) * | 1985-03-14 | 1987-08-25 | Technology Un, Ltd. | Automotive heater and air conditioner and process therefor |
US5279360A (en) * | 1985-10-02 | 1994-01-18 | Modine Manufacturing Co. | Evaporator or evaporator/condenser |
JPH0645155Y2 (en) * | 1988-10-24 | 1994-11-16 | サンデン株式会社 | Heat exchanger |
US5245836A (en) * | 1989-01-09 | 1993-09-21 | Sinvent As | Method and device for high side pressure regulation in transcritical vapor compression cycle |
JPH02140166U (en) * | 1989-04-24 | 1990-11-22 | ||
DE3938842A1 (en) * | 1989-06-06 | 1991-05-29 | Thermal Waerme Kaelte Klima | CONDENSER FOR A VEHICLE AIR CONDITIONING REFRIGERANT |
US5529116A (en) * | 1989-08-23 | 1996-06-25 | Showa Aluminum Corporation | Duplex heat exchanger |
US5197539A (en) * | 1991-02-11 | 1993-03-30 | Modine Manufacturing Company | Heat exchanger with reduced core depth |
US5205347A (en) * | 1992-03-31 | 1993-04-27 | Modine Manufacturing Co. | High efficiency evaporator |
US5186244A (en) * | 1992-04-08 | 1993-02-16 | General Motors Corporation | Tube design for integral radiator/condenser |
US5289874A (en) * | 1993-06-28 | 1994-03-01 | General Motors Corporation | Heat exchanger with laterally displaced louvered fin sections |
US5348081A (en) * | 1993-10-12 | 1994-09-20 | General Motors Corporation | High capacity automotive condenser |
ES2127472T3 (en) * | 1994-04-12 | 1999-04-16 | Showa Aluminum Corp | STACKED DUPLEX HEAT EXCHANGER. |
US5725047A (en) * | 1995-01-13 | 1998-03-10 | Lytron Incorporated | Heat exchanger |
US5509199A (en) * | 1995-01-17 | 1996-04-23 | General Motors Corporation | Method of making a dual radiator and condenser assembly |
JP3485379B2 (en) * | 1995-04-06 | 2004-01-13 | サンデン株式会社 | Vehicle air conditioner |
DE19519633C2 (en) * | 1995-05-30 | 2000-06-21 | Behr Industrietech Gmbh & Co | Intercooler |
US5529117A (en) * | 1995-09-07 | 1996-06-25 | Modine Manufacturing Co. | Heat exchanger |
US5992514A (en) * | 1995-11-13 | 1999-11-30 | Denso Corporation | Heat exchanger having several exchanging portions |
DE69713708T2 (en) * | 1996-10-22 | 2002-10-17 | Denso Corp | Heat exchangers for motor vehicles |
US5910167A (en) * | 1997-10-20 | 1999-06-08 | Modine Manufacturing Co. | Inlet for an evaporator |
JP4019113B2 (en) * | 1997-11-13 | 2007-12-12 | 株式会社ティラド | Integrated heat exchanger fin and method of manufacturing the same |
JP4117429B2 (en) * | 1999-02-01 | 2008-07-16 | 株式会社デンソー | Heat exchanger fins |
US6374911B1 (en) * | 1999-06-17 | 2002-04-23 | Modine Manufacturing Company | Charge air cooler and method of making the same |
JP4207331B2 (en) * | 1999-09-29 | 2009-01-14 | 株式会社デンソー | Double heat exchanger |
EP1167909A3 (en) * | 2000-02-08 | 2005-10-12 | Calsonic Kansei Corporation | Core structure of integral heat-exchanger |
FR2812382B1 (en) * | 2000-07-25 | 2003-02-07 | Valeo Thermique Moteur Sa | METHOD FOR MANUFACTURING A HEAT EXCHANGER FIN, FINS ACCORDING TO THE METHOD AND EXCHANGE MODULE COMPRISING THESE FINS |
US20030075307A1 (en) * | 2001-10-22 | 2003-04-24 | Heatcraft, Inc. | Exchanger of thermal energy with multiple cores and a thermal barrier |
US20030106677A1 (en) * | 2001-12-12 | 2003-06-12 | Stephen Memory | Split fin for a heat exchanger |
-
2001
- 2001-11-30 US US10/013,018 patent/US20030102113A1/en not_active Abandoned
-
2002
- 2002-10-30 CA CA002467137A patent/CA2467137A1/en not_active Abandoned
- 2002-10-30 WO PCT/US2002/034606 patent/WO2003048670A1/en active Application Filing
- 2002-10-30 CN CNA2007101049458A patent/CN101089533A/en active Pending
- 2002-10-30 AU AU2002365762A patent/AU2002365762B2/en not_active Expired - Fee Related
- 2002-10-30 MX MXPA04004660A patent/MXPA04004660A/en unknown
- 2002-10-30 EP EP02804409A patent/EP1448945A1/en not_active Withdrawn
- 2002-10-30 BR BR0214479-4A patent/BR0214479A/en active Search and Examination
- 2002-10-30 CN CNB028236556A patent/CN100380081C/en not_active Expired - Fee Related
- 2002-10-30 JP JP2003549821A patent/JP2005512009A/en not_active Ceased
- 2002-10-30 KR KR1020047008270A patent/KR20050058253A/en not_active Application Discontinuation
- 2002-10-30 RU RU2004117856/06A patent/RU2319094C2/en not_active IP Right Cessation
- 2002-11-13 TW TW091133260A patent/TW200301815A/en unknown
- 2002-11-25 AR ARP020104527A patent/AR037428A1/en not_active Application Discontinuation
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58214793A (en) * | 1982-06-09 | 1983-12-14 | Mitsubishi Electric Corp | Heat exchanger |
JPS58217195A (en) * | 1982-06-10 | 1983-12-17 | Mitsubishi Electric Corp | Heat exchanger |
EP0448183A2 (en) * | 1988-09-14 | 1991-09-25 | Showa Aluminum Kabushiki Kaisha | A condenser |
US5076354A (en) * | 1989-04-26 | 1991-12-31 | Diesel Kiki Co., Ltd. | Multiflow type condenser for car air conditioner |
US5036909A (en) * | 1989-06-22 | 1991-08-06 | General Motors Corporation | Multiple serpentine tube heat exchanger |
EP0431917A1 (en) * | 1989-12-07 | 1991-06-12 | Showa Aluminum Kabushiki Kaisha | Consolidated duplex heat exchanger |
US5730212A (en) * | 1992-11-25 | 1998-03-24 | Nippondenso Co., Ltd. | Refrigerant condenser |
US5531268A (en) | 1993-11-24 | 1996-07-02 | Showa Aluminum Corporation | Heat exchanger |
EP0845648A2 (en) * | 1996-11-27 | 1998-06-03 | Behr GmbH & Co. | Flat tube heat exchanger, particularly serpentine condenser |
JPH11159987A (en) * | 1997-11-29 | 1999-06-15 | Toyo Radiator Co Ltd | Corrugate fin for compound heat exchanger |
DE19830863A1 (en) * | 1998-07-10 | 2000-01-13 | Behr Gmbh & Co | Flat tube with transverse offset reversing bend section and thus built-up heat exchanger |
US6308527B1 (en) * | 1998-12-10 | 2001-10-30 | Denso Corporation | Refrigerant evaporator with condensed water drain structure |
DE10007159A1 (en) * | 1999-03-08 | 2000-09-14 | Denso Corp | Method for manufacturing heat exchangers for super critical refrigeration circuits has flat multi-bore tubes between manifolds and finned plates joining them |
FR2793013A1 (en) * | 1999-04-28 | 2000-11-03 | Valeo Thermique Moteur Sa | Heat exchanger assembly for an automobile, utilises a cross flow configuration between the fluid supply and sump assemblies via tubular plate type heat exchange fins |
EP1231448A2 (en) * | 2001-02-07 | 2002-08-14 | Modine Manufacturing Company | Heat exchanger |
Non-Patent Citations (3)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 008, no. 064 (M - 285) 27 March 1984 (1984-03-27) * |
PATENT ABSTRACTS OF JAPAN vol. 008, no. 069 (M - 286) 31 March 1984 (1984-03-31) * |
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 11 30 September 1999 (1999-09-30) * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2907887A1 (en) * | 2006-10-25 | 2008-05-02 | Valeo Systemes Thermiques | Heat exchanger for motor vehicle, has fin portions respectively fixed in contact with fluid circulation tubes, where tubes are covered with filler metal plating at level of contact and fin portions are free from plating near rupture |
Also Published As
Publication number | Publication date |
---|---|
CN101089533A (en) | 2007-12-19 |
EP1448945A1 (en) | 2004-08-25 |
RU2319094C2 (en) | 2008-03-10 |
CA2467137A1 (en) | 2003-06-12 |
AU2002365762A1 (en) | 2003-06-17 |
MXPA04004660A (en) | 2004-08-13 |
TW200301815A (en) | 2003-07-16 |
AU2002365762B2 (en) | 2008-02-21 |
CN100380081C (en) | 2008-04-09 |
US20030102113A1 (en) | 2003-06-05 |
BR0214479A (en) | 2004-09-14 |
RU2004117856A (en) | 2005-04-27 |
JP2005512009A (en) | 2005-04-28 |
AR037428A1 (en) | 2004-11-10 |
KR20050058253A (en) | 2005-06-16 |
CN1596360A (en) | 2005-03-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2002365762B2 (en) | Heat exchanger for providing supercritical cooling of a working fluid in a transcritical cooling cycle | |
US20030183378A1 (en) | Heat exchanger and folded tube used therein | |
AU2002343716B2 (en) | Split fin for a heat exchanger | |
AU2012208123B2 (en) | Heat exchanger and air conditioner | |
US5765393A (en) | Capillary tube incorporated into last pass of condenser | |
EP0930477B1 (en) | Liquid cooled, two phase heat exchanger | |
JP2001091104A (en) | Assembled body of evaporator/accumulator/suction line heat exchanger | |
US20170343288A1 (en) | Multi-pass and multi-slab folded microchannel heat exchanger | |
US11656033B2 (en) | Combined core microchannel heat exchanger | |
US20080184734A1 (en) | Flat Tube Single Serpentine Co2 Heat Exchanger | |
EP3334991B1 (en) | Microchannel heat exchanger | |
JP2000257989A (en) | Heat exchanger | |
JP3911604B2 (en) | Heat exchanger and refrigeration cycle | |
US11988422B2 (en) | Microchannel heat exchanger drain | |
WO2021234961A1 (en) | Heat exchanger, outdoor unit for air conditioning device, and air conditioning device | |
EP1460364A2 (en) | Automotive heat exchangers | |
US20220299272A1 (en) | Microchannel heat exchanger | |
US20240011648A1 (en) | Microchannel heat exchanger for heat pump | |
US20220099343A1 (en) | Heat exchanger and refrigeration cycle apparatus | |
WO2016036732A1 (en) | Frost tolerant microchannel heat exchanger for heat pump and refrigeration applications | |
KR980010323A (en) | Heat exchanger structure of refrigeration cycle unit |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AU BR CA CN JP KR MX RU |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LU MC NL PT SE SK TR |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2002365762 Country of ref document: AU |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002804409 Country of ref document: EP Ref document number: 2003549821 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2467137 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2004/004660 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20028236556 Country of ref document: CN Ref document number: 1020047008270 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2002804409 Country of ref document: EP |