WO2003022783A2 - Low humidity uptake solid pyrotechnic compositions, and methods for making the same - Google Patents
Low humidity uptake solid pyrotechnic compositions, and methods for making the same Download PDFInfo
- Publication number
- WO2003022783A2 WO2003022783A2 PCT/US2002/021566 US0221566W WO03022783A2 WO 2003022783 A2 WO2003022783 A2 WO 2003022783A2 US 0221566 W US0221566 W US 0221566W WO 03022783 A2 WO03022783 A2 WO 03022783A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pyrotechnic composition
- solid pyrotechnic
- weight percent
- composition according
- particles
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 179
- 239000007787 solid Substances 0.000 title claims abstract description 124
- 238000000034 method Methods 0.000 title claims abstract description 32
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 80
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 40
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 33
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011593 sulfur Substances 0.000 claims abstract description 18
- 239000003610 charcoal Substances 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims description 136
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 82
- 150000001875 compounds Chemical class 0.000 claims description 45
- 239000007800 oxidant agent Substances 0.000 claims description 43
- 150000003839 salts Chemical class 0.000 claims description 38
- 239000011230 binding agent Substances 0.000 claims description 32
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 31
- -1 poly(vinyl acetate) Polymers 0.000 claims description 18
- 229910001485 alkali metal perchlorate Inorganic materials 0.000 claims description 17
- 229910001963 alkali metal nitrate Inorganic materials 0.000 claims description 16
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 claims description 11
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 claims description 11
- 229910001487 potassium perchlorate Inorganic materials 0.000 claims description 11
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 9
- 239000011118 polyvinyl acetate Substances 0.000 claims description 8
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 7
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229910017604 nitric acid Inorganic materials 0.000 claims description 6
- 150000002989 phenols Chemical class 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000020 Nitrocellulose Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229920001054 Poly(ethylene‐co‐vinyl acetate) Polymers 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 44
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052796 boron Inorganic materials 0.000 abstract description 18
- 230000008569 process Effects 0.000 abstract description 5
- 230000001747 exhibiting effect Effects 0.000 abstract description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 24
- 238000009472 formulation Methods 0.000 description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 150000002823 nitrates Chemical class 0.000 description 6
- 229920002274 Nalgene Polymers 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- APAJFZPFBHMFQR-UHFFFAOYSA-N anthraflavic acid Chemical compound OC1=CC=C2C(=O)C3=CC(O)=CC=C3C(=O)C2=C1 APAJFZPFBHMFQR-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical group [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- JSOGDEOQBIUNTR-UHFFFAOYSA-N 2-(azidomethyl)oxirane Chemical compound [N-]=[N+]=NCC1CO1 JSOGDEOQBIUNTR-UHFFFAOYSA-N 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 206010035745 Pneumonitis chemical Diseases 0.000 description 1
- 206010037423 Pulmonary oedema Diseases 0.000 description 1
- 208000005392 Spasm Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 201000009408 aspiration pneumonitis Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 210000000621 bronchi Anatomy 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 210000000867 larynx Anatomy 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002921 oxetanes Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 208000005333 pulmonary edema Diseases 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- RTHYXYOJKHGZJT-UHFFFAOYSA-N rubidium nitrate Inorganic materials [Rb+].[O-][N+]([O-])=O RTHYXYOJKHGZJT-UHFFFAOYSA-N 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- KHAUBYTYGDOYRU-IRXASZMISA-N trospectomycin Chemical compound CN[C@H]([C@H]1O2)[C@@H](O)[C@@H](NC)[C@H](O)[C@H]1O[C@H]1[C@]2(O)C(=O)C[C@@H](CCCC)O1 KHAUBYTYGDOYRU-IRXASZMISA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C9/00—Chemical contact igniters; Chemical lighters
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/02—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
- C06B31/08—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a metal oxygen-halogen salt, e.g. inorganic chlorate, inorganic perchlorate
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
- C06B31/30—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with vegetable matter; with resin; with rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Air Bags (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02789146A EP1427683A2 (en) | 2001-01-12 | 2002-01-11 | Low humidity uptake solid pyrotechnic compositions, and methods for making the same |
JP2003526862A JP3981356B2 (en) | 2001-01-12 | 2002-01-11 | Solid pyrotechnic composition with low moisture uptake and method for producing the same |
AU2002353766A AU2002353766A1 (en) | 2001-01-12 | 2002-01-11 | Low humidity uptake solid pyrotechnic compositions, and methods for making the same |
CA002434730A CA2434730A1 (en) | 2001-01-12 | 2002-01-11 | Low humidity uptake solid pyrotechnic compositions, and methods for making the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26111101P | 2001-01-12 | 2001-01-12 | |
US60/261,111 | 2001-01-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2003022783A2 true WO2003022783A2 (en) | 2003-03-20 |
WO2003022783A3 WO2003022783A3 (en) | 2004-04-01 |
Family
ID=22991995
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2002/021566 WO2003022783A2 (en) | 2001-01-12 | 2002-01-11 | Low humidity uptake solid pyrotechnic compositions, and methods for making the same |
Country Status (6)
Country | Link |
---|---|
US (2) | US20020148541A1 (en) |
EP (1) | EP1427683A2 (en) |
JP (1) | JP3981356B2 (en) |
AU (1) | AU2002353766A1 (en) |
CA (1) | CA2434730A1 (en) |
WO (1) | WO2003022783A2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1029465C2 (en) * | 2005-07-06 | 2007-01-09 | Tno | A pyrotechnic composition. |
CN103880570A (en) * | 2014-03-15 | 2014-06-25 | 南京理工大学 | Pyrotechnic composition oxidant |
CN106588522B (en) * | 2016-11-29 | 2018-05-29 | 湖北航天化学技术研究所 | Low melting point thermoplastic propellant and preparation method thereof |
CN113354493A (en) * | 2021-07-16 | 2021-09-07 | 关秀琼 | Pyrotechnic propellant and preparation method thereof |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE840821C (en) * | 1946-11-22 | 1952-06-05 | Heaters Ltd | Additive for flammable gas-generating charges or heating mixtures from explosive cartridges |
US3862866A (en) * | 1971-08-02 | 1975-01-28 | Specialty Products Dev Corp | Gas generator composition and method |
US3902934A (en) * | 1972-06-08 | 1975-09-02 | Specialty Products Dev Corp | Gas generating compositions |
GB1601392A (en) * | 1978-04-12 | 1981-10-28 | Pyrodex Corp | Gas generating compositions |
WO1990015788A2 (en) * | 1989-06-13 | 1990-12-27 | F. Hoffmann-La Roche Ag | Explosive and propellant composition |
WO1994008918A2 (en) * | 1992-10-13 | 1994-04-28 | Anthony Cioffe | Propellant and explosive composition and method of making same |
US5320691A (en) * | 1993-07-08 | 1994-06-14 | The United States Of America As Represented By The Secretary Of The Army | Charcoal-free black powder type granules and method of production |
WO1998042640A1 (en) * | 1997-03-21 | 1998-10-01 | Cordant Technologies, Inc. | Method for manufacture of black powder and black powder substitute |
DE19840993A1 (en) * | 1998-09-08 | 2000-03-09 | Trw Airbag Sys Gmbh & Co Kg | Use of a mixture of non-hygroscopic organic fuel and inorganic nitrate, chlorate or perchlorate oxidizing agent as the igniter for gas generators in safety devices, especially vehicle air-bag systems |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2441248A (en) * | 1941-08-07 | 1948-05-11 | Ici Ltd | Fast burning delay fuze |
US3026674A (en) * | 1958-02-24 | 1962-03-27 | Phillips Petroleum Co | Solid propellant rocket motor |
US3282146A (en) * | 1958-03-11 | 1966-11-01 | Walter S Baker | Method of making combustible cartridge cases |
US3770524A (en) * | 1958-10-22 | 1973-11-06 | Rohm & Haas | Composite propellants containing polymers of trinitratopentaerythrityl acrylate |
US3388554A (en) * | 1959-11-02 | 1968-06-18 | Solid Fuels Corp | Organic fusible solid fuel binders and stabilizers and method of extruding and burning |
US3728173A (en) * | 1969-10-17 | 1973-04-17 | Intermountain Res & Eng Co Inc | Dense explosive slurry compositions of high energy containing a gum mixture |
US4047987A (en) * | 1973-02-27 | 1977-09-13 | Director-General Of The Agency Of Industrial Science And Technology | Underwater blasting explosives |
US4128443A (en) * | 1975-07-24 | 1978-12-05 | Pawlak Daniel E | Deflagrating propellant compositions |
US4238253A (en) * | 1978-05-15 | 1980-12-09 | Allied Chemical Corporation | Starch as fuel in gas generating compositions |
USH72H (en) * | 1984-01-23 | 1986-06-03 | The United States Of America As Represented By The Secretary Of The Army | Organic substitutes for charcoal in black powder |
US4570540A (en) * | 1984-08-09 | 1986-02-18 | Morton Thiokol, Inc. | LOVA Type black powder propellant surrogate |
US4915755A (en) * | 1987-10-02 | 1990-04-10 | Kim Chung S | Filler reinforcement of polyurethane binder using a neutral polymeric bonding agent |
US5034073A (en) * | 1990-10-09 | 1991-07-23 | Aerojet General Corporation | Insensitive high explosive |
US5569875A (en) * | 1992-03-16 | 1996-10-29 | Legend Products Corporation | Methods of making explosive compositions, and the resulting products |
US5531845A (en) * | 1994-01-10 | 1996-07-02 | Thiokol Corporation | Methods of preparing gas generant formulations |
AU1597195A (en) * | 1994-01-19 | 1995-08-08 | Thiokol Corporation | Metal complexes for use as gas generants |
US5725699A (en) * | 1994-01-19 | 1998-03-10 | Thiokol Corporation | Metal complexes for use as gas generants |
US5756929A (en) * | 1996-02-14 | 1998-05-26 | Automotive Systems Laboratory Inc. | Nonazide gas generating compositions |
US5726378A (en) * | 1996-04-01 | 1998-03-10 | Hodgdon Powder Company, Inc. | Unitary propellant charge for muzzle loading firearms |
US6221187B1 (en) * | 1996-05-14 | 2001-04-24 | Talley Defense Systems, Inc. | Method of safely initiating combustion of a gas generant composition using an autoignition composition |
US5670098A (en) * | 1996-08-20 | 1997-09-23 | Thiokol Corporation | Black powder processing on twin-screw extruder |
US5917146A (en) * | 1997-05-29 | 1999-06-29 | The Regents Of The University Of California | High-nitrogen energetic material based pyrotechnic compositions |
US6093269A (en) * | 1997-12-18 | 2000-07-25 | Atlantic Research Corporation | Pyrotechnic gas generant composition including high oxygen balance fuel |
US6045638A (en) * | 1998-10-09 | 2000-04-04 | Atlantic Research Corporation | Monopropellant and propellant compositions including mono and polyaminoguanidine dinitrate |
US6214139B1 (en) * | 1999-04-20 | 2001-04-10 | The Regents Of The University Of California | Low-smoke pyrotechnic compositions |
-
2002
- 2002-01-11 CA CA002434730A patent/CA2434730A1/en not_active Abandoned
- 2002-01-11 EP EP02789146A patent/EP1427683A2/en not_active Withdrawn
- 2002-01-11 WO PCT/US2002/021566 patent/WO2003022783A2/en active Search and Examination
- 2002-01-11 US US10/046,008 patent/US20020148541A1/en not_active Abandoned
- 2002-01-11 AU AU2002353766A patent/AU2002353766A1/en not_active Abandoned
- 2002-01-11 JP JP2003526862A patent/JP3981356B2/en not_active Expired - Lifetime
-
2005
- 2005-08-26 US US11/213,416 patent/US20060042731A1/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE840821C (en) * | 1946-11-22 | 1952-06-05 | Heaters Ltd | Additive for flammable gas-generating charges or heating mixtures from explosive cartridges |
US3862866A (en) * | 1971-08-02 | 1975-01-28 | Specialty Products Dev Corp | Gas generator composition and method |
US3902934A (en) * | 1972-06-08 | 1975-09-02 | Specialty Products Dev Corp | Gas generating compositions |
GB1601392A (en) * | 1978-04-12 | 1981-10-28 | Pyrodex Corp | Gas generating compositions |
WO1990015788A2 (en) * | 1989-06-13 | 1990-12-27 | F. Hoffmann-La Roche Ag | Explosive and propellant composition |
WO1994008918A2 (en) * | 1992-10-13 | 1994-04-28 | Anthony Cioffe | Propellant and explosive composition and method of making same |
US5320691A (en) * | 1993-07-08 | 1994-06-14 | The United States Of America As Represented By The Secretary Of The Army | Charcoal-free black powder type granules and method of production |
WO1998042640A1 (en) * | 1997-03-21 | 1998-10-01 | Cordant Technologies, Inc. | Method for manufacture of black powder and black powder substitute |
DE19840993A1 (en) * | 1998-09-08 | 2000-03-09 | Trw Airbag Sys Gmbh & Co Kg | Use of a mixture of non-hygroscopic organic fuel and inorganic nitrate, chlorate or perchlorate oxidizing agent as the igniter for gas generators in safety devices, especially vehicle air-bag systems |
Also Published As
Publication number | Publication date |
---|---|
JP3981356B2 (en) | 2007-09-26 |
EP1427683A2 (en) | 2004-06-16 |
CA2434730A1 (en) | 2003-03-20 |
WO2003022783A3 (en) | 2004-04-01 |
AU2002353766A1 (en) | 2003-03-24 |
US20060042731A1 (en) | 2006-03-02 |
US20020148541A1 (en) | 2002-10-17 |
JP2005506945A (en) | 2005-03-10 |
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