WO2003020867A1 - Perfumed coloured speckle composition and particulate laundry detergent compositions containing it - Google Patents
Perfumed coloured speckle composition and particulate laundry detergent compositions containing it Download PDFInfo
- Publication number
- WO2003020867A1 WO2003020867A1 PCT/EP2002/009051 EP0209051W WO03020867A1 WO 2003020867 A1 WO2003020867 A1 WO 2003020867A1 EP 0209051 W EP0209051 W EP 0209051W WO 03020867 A1 WO03020867 A1 WO 03020867A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- perfume
- composition
- granular
- detergent composition
- speckles
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Definitions
- the present invention relates to coloured perfumed speckles for use in granular laundry detergent compositions and a process for making them.
- perfume is added to improve aesthetic appeal by imparting a pleasing odour both during storage and in use. Additionally it may impart a pleasing odour to the washed fabrics.
- perfumes are highly volatile and the amount remaining on the washed clothes by the end of the washing process is usually a small fraction of that which was added at the beginning.
- WO 9734981 discloses a porous zeolite into which the perfume is absorbed and trapped by a release inhibitor which hydrolyses during the wash thereby releasing the perfume in a controlled manner.
- WO 9842818 discloses a porous core particle encapsulated in a glassy material and coated in a water-soluble or dispersible compound. Preferably a perfume is supported or contained within the porous carrier.
- EP 466235 discloses a process of combining a perfume with one or more non-ionic emulsifiers to form a non-aqueous phase which is then mixed with an aqueous phase to form a structured emulsion containing liquid-crystal structures.
- the emulsified perfume is added to a detergent powder and is said to enhance perfume delivery and possibly deposition.
- US 5 605 883 discloses a colourant speckle which exhibits reduced spotting of teated fabrics. It also states that the speckle may be used as a vehicle for carrying cosurfactants, enzymes, oxidants, bleach activators and fragrances .
- US 4 097 418 discloses a granular coloured speckle having reduced staining properties and may comprise up to 3% of enzymes, bleaching agents, antimicrobial agents, corrosion inhibitors and perfume.
- the delivery of perfume may be significantly enhanced and prolonged if the perfume is included in coloured speckles.
- Especially advantageous perfume delivery can be achieved if the perfume is incorporated in the speckles in aqueous emulsion form.
- the colouration of the speckles may provide an association with the enhanced perfume delivery in the mind of the consumer, thus reinforcing the consumer's appreciation of the wash process.
- the present invention provides a perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition which comprises at least 1 wt% perfume.
- the present invention provides a process for the manufacture of a perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition, comprising the steps of:
- the present invention provides a perfumed particulate laundry detergent composition comprising a minor proportion of a coloured speckle composition wherein at least 10 wt% of the total amount of perfume in the detergent composition is located in the speckles.
- the speckles (perfumed coloured granular composition) comprise a perfume, preferably in aqueous emulsion form, and a colourant, on an inorganic granular carrier material.
- the speckles comprise at least 1 wt% perfume and preferably comprise at least 1.5 wt%.
- the perfume before drying, is present in the form of an aqueous emulsion.
- the speckles suitably comprise emulsifier. It is preferred that the speckles are obtainable from a process as defined in detail below.
- perfume denotes one or a mixture of perfume components, optionally mixed with a suitable solvent, diluent or carrier, which is used to impart a desired odour to the particulate laundry detergent composition in the package and/or in use and/or to the fabrics that are washed.
- the perfume is preferably incorporated in the speckles as an aqueous emulsion.
- aqueous emulsions suitably contain from 1 to 50 wt% of perfume, from 1 to 30 wt% of one or more non-ionic emulsifiers and from 20 to 98 wt% of water or an aqueous mixture containing water-soluble and/or water-dispersible materials, hereinafter jointly referred to as "aqueous phase".
- aqueous phase containing water-soluble and/or water-dispersible materials
- the weight ratio of total emulsifier to perfume lies within the range of from 1:5 to 3:1 and the weight ratio of non-aqueous phase to aqueous phase lies within the range of from 1:2 to 4:3, preferably within the range of from 1:2 to 1:1.
- Non- ionic emulsifiers suitable for use in the present invention are exemplified in EP 466 235 B, for example the primary and secondary alcohol ethoxylates, especially the C 8 -C 20 aliphatic alcohols ethoxylated with an average of from
- Non-ethoxylated nonionic surfactants include alkylpoly- glycosides, glycerol monoethers, and polyhydroxyamides (glucamide) .
- An especially preferred nonionic emulsifier is C 10 - 15 , preferably C 12 -C 15 , aliphatic alcohol ethoxylated with an average of from 4 to 9 moles of ethylene oxide, preferably 5 to 7, per mole of alcohol.
- the emulsion may be produced by forming a non-aqueous phase comprising the perfume, a non-ionic emulsifier or mixture based on non-ionic emulsifiers, and optionally other adjuncts, which is mixed at a temperature at which the non- aqueous phase forms a homogeneous liquid; forming an aqueous phase consisting of water or an aqueous solution of water- soluble or water-dispersible materials; and finally mixing the two phases under shear conditions.
- the perfumed coloured granular composition for use as speckles in a particulate laundry detergent composition according to the present invention may be manufactured by the following process:
- the colourant may be a pigment or a water-dispersible dye.
- the inorganic carrier material may be layered prior to step (i) with a finely divided porous particulate material. This step may be particularly advantageous when the inorganic carrier material has a low liquid carrying capacity, for example sodium chloride.
- the speckle composition may be prepared using any suitable mixing apparatus.
- the mixer should preferably have a stainless steel or other inert interior surface especially when a corrosive carrier material, for example, sodium chloride, is used.
- the granular carrier material may be any suitable material compatible with granular detergent compositions, such as for example hydratable alkaline inorganic salts such as sodium tripolyphosphate, sodium carbonate or sodium tetraborate; solid surfactant e.g. highly ethoxylated nonionic surfactant; alpha-hydroxy carboxylic acids e.g. citric acid; or other materials such as sodium chloride, crystalline alkali metal aluminosilicate, sodium sulphate, soap, sodium metasilicate, clays and corn starch. Sodium chloride is especially preferred.
- the granular carrier material should have a particle size similar to that of a typical detergent powder. Typically it has a number average particle size of at least 100 microns.
- a porous particulate layering material is then used to provide a dry layer to protect the emulsified perfume and to provide a flowable powder.
- the layering material may suitably comprise at least one highly absorbent material selected from silicas, silicates and crystalline alkali metal aluminosilicates .
- the porous particulate layering material advantageously comprises a material having an oil absorption capacity of at least 0.4 ml/g.
- the porous particulate layering material has a number average particle size of at most 100 microns.
- the total amount of layering agent is suitably from 0.1 to 10 wt%, preferably from 0.2 to 1 wt% based on the speckles.
- the speckle composition may also contain a binder.
- Preferred binders are polymers, for example, cellulosic materials, for example, sodium carboxymethyl cellulose, or acrylic polymers, for example, acrylic/maleic copoly ers such as Sokalan (Trade Mark) CP5 ex BASF.
- Other organic film-forming materials may be envisaged, for example, polyethylene glycols or highly ethoxylated nonionic surfactants.
- An especially preferred binder is sodium carboxymethyl cellulose.
- the binder is suitably present in an amount of from 0.05 to 5 wt%, preferably from 0.1 to 1 wt%.
- the coloured speckle composition of the invention is suitable for use in both white and coloured detergent compositions, provided that there is sufficient contrast between the colour of the major proportion of the powder and the colour of the speckles.
- the detergent composition may comprise a major proportion of white or light -coloured particles and a minor proportion of the coloured speckle composition.
- the detergent composition may comprise a major proportion of particles having a first colour, for example, blue, and a minor proportion of the coloured speckle composition having a second colour contrasting with the first colour, for example, red, or having a darker shade of the same colour.
- the speckle composition is preferably present in an amount of from 1 to 10 wt% and preferably from 2 to 8 wt%.
- the detergent composition of the present invention comprises a minor proportion of a coloured speckle composition wherein at least 10 wt% of the total amount of perfume in the detergent composition is located in the speckles. Preferably at least 20 wt%, more preferably at least 30 wt% of the perfume is located in the speckles. Any remaining perfume may be incorporated in the bulk powder by any suitable method. It is believed that this may provide a particularly satisfactory perfume release profile. It is preferred that the detergent composition of the present invention comprises a speckle composition as described above and/or a speckle composition obtainable by a process as described above .
- the detergent compositions of the invention may be in powder or tablet form.
- Detergent compositions according to the invention contain, as well as the speckle composition, conventional detergent ingredients, notably detergent-active materials (surfactants), and preferably also detergency builders.
- conventional detergent ingredients notably detergent-active materials (surfactants), and preferably also detergency builders.
- Laundry detergent compositions in accordance with the invention may suitably comprise from 5 to 60 wt% of detergent-active surfactant, from 10 to 80 wt% of detergency builder, from 1 to 10 wt% of the speckles, and optionally other detergent ingredients to 100 wt%.
- the detergent compositions will contain, as essential ingredients, one or more detergent active compounds (surfactants) which may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- suitable detergent active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Ber
- Non-soap anionic surfactants are especially preferred.
- Non-soap anionic surfactants are well-known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; primary and secondary alkylsulphates, particularly C 8 -C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates.
- Sodium salts are generally preferred.
- a preferred anionic surfactant is linear alkylbenzene sulphonate.
- Nonionic surfactants may optionally be present. These include the primary and secondary alcohol ethoxylates, especially the C 8 -C 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C 10 -C 15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
- Non-ethoxylated nonionic surfactants include alkylpoly- glycosides, glycerol monoethers, and polyhydroxyamides (glucamide) .
- Cationic surfactants may optionally be present. These include quaternary ammonium salts of the general formula
- R 1 R 2 R 3 R 4 N X wherein the R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising anion (for example, compounds in which Ri is a C 8 -C 22 alkyl group, preferably a Cs-Cio or C 12 -C 14 alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups) ; and cationic esters (for example, choline esters) .
- R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups
- X is a solubilising anion (for example, compounds in which Ri is a C 8 -C 22 alkyl group, preferably a Cs-Cio or C 12 -C 14 alkyl group, R
- Ri represents a C ⁇ -Cio or C 12 -
- R 2 and R 3 represent methyl groups
- R 4 presents a hydroxyethyl group
- X represents a halide or methosulphate ion.
- amphoteric surfactants for example, amine oxides
- zwitterionic surfactants for example, betaines
- the quantity of anionic surfactant is in the range of from 5 to 50% by weight of the total composition. More preferably, the quantity of anionic surfactant is in the range of from 8 to 35 wt%, most preferably from 10 to 30 wt%.
- Nonionic surfactant if present, in addition to any which may be present as emulsifier in the speckles, is preferably used in an amount within the range of from 1 to 20 wt% in addition to that which may be present in the structured emulsion.
- the total amount of surfactant present is preferably within the range of from 5 to 60 wt%.
- the compositions may suitably contain from 10 to 80 wt%, preferably from 15 to 70 wt%, of detergency builder.
- the quantity of builder is in the range of from 15 to 50 wt%.
- the detergent compositions may contain as builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite) .
- a crystalline aluminosilicate preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite) .
- the zeolite used as a builder may be the commercially available zeolite A (zeolite 4A) now widely used in laundry detergent powders.
- the zeolite may be maximum aluminium zeolite P (zeolite MAP) as described and claimed in EP 384 070B (Unilever) , and commercially available as Doucil (Trade Mark) A24 from Crosfield Chemicals Ltd, UK.
- Zeolite MAP is defined as an alkali metal aluminosilicate of zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, preferably within the range of from 0.90 to 1.20.
- zeolite MAP having a silicon to aluminium ratio not exceeding 1.07, more preferably about 1.00.
- the particle size of the zeolite is not critical. Zeolite A or zeolite MAP of any suitable particle size may be used.
- phosphate builders especially sodium tripolyphosphate . This may be used in combination with sodium orthophosphate, and/or sodium pyrophosphate .
- inorganic builders that may be present additionally or alternatively include sodium carbonate, layered silicate, amorphous aluminosilicates .
- the builder is selected from sodium tripolyphosphate, zeolite, sodium carbonate, and combinations thereof.
- Organic builders may optionally be present. These include polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers; polyaspartates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates , carboxy-methyloxymalonates , dipicolinates, hydroxyethyl iminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts.
- polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers
- polyaspartates monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates , carboxy-methyloxymalonates , dipicolinates, hydroxyethy
- Organic builders may be used in minor amounts as supplements to inorganic builders such as phosphates and zeolites.
- Especially preferred supplementary organic builders are citrates, suitably used in amounts of from 5 to 30 wt%, preferably from 10 to 25 wt%; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt%, preferably from 1 to 10 wt%.
- Builders both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
- Detergent compositions according to the invention may also suitably contain a bleach system, although non-bleaching formulations are also within the scope of the invention.
- the bleach system is preferably based on peroxy bleach compounds, for example, inorganic persalts or organic peroxyacids, capable of yielding hydrogen peroxide in aqueous solution.
- Suitable peroxy bleach compounds include organic peroxides such as urea peroxide, and inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates .
- Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate.
- the peroxy bleach compound is suitably present in an amount of from 5 to 35 wt%, preferably from 10 to 25 wt%.
- the peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures.
- the bleach precursor is suitably present in an amount of from 1 to 8 wt%, preferably from 2 to 5 wt%.
- Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and peroxybenzoic acid precursors; and peroxycarbonic acid precursors.
- An especially preferred bleach precursor suitable for use in the present invention is N,N,N',N'- tetracetyl ethylenediamine (TAED) .
- a bleach stabiliser (heavy metal sequestrant) may also be present.
- Suitable bleach stabilisers include ethylenediamine tetraacetate (EDTA) and the polyphosphonates such as Dequest (Trade Mark) , EDTMP.
- the detergent compositions may also contain one or more enzymes. Suitable enzymes include the proteases, amylases, cellulases, oxidases, peroxidases and lipases usable for incorporation in detergent compositions.
- Preferred proteolytic enzymes are catalytically active protein materials which degrade or alter protein types of stains when present as in fabric stains in a hydrolysis reaction. They may be of any suitable origin, such as vegetable, animal, bacterial or yeast origin.
- Proteolytic enzymes or proteases of various qualities and origins and having activity in various pH ranges of from 4-12 are available. Proteases of both high and low isoelectric point are suitable.
- lipases include amylases, and cellulases including high-activity cellulases such as Carezyme (Trade Mark) ex Novo .
- detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used in any effective amount.
- Antiredeposition agents for example, cellulose esters and ethers, for example sodium carboxymethyl cellulose, may also be present .
- compositions may also contain soil release polymers, for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
- soil release polymers for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
- Especially preferred soil release polymers are the sulphonated non-end-capped polyesters described and claimed in WO 95 32997A (Rhodia Chimie) .
- the detergent compositions may also include one or more inorganic salts other than builder salts. These may include, for example, sodium bicarbonate, sodium silicate, sodium sulphate, magnesium sulphate, calcium sulphate, calcium chloride and sodium chloride. Preferred inorganic salts are sodium sulphate, sodium chloride, and combinations thereof.
- the coloured speckle composition is especially suitable for incorporation in detergent compositions which contain sodium chloride in addition to that which may be present in the speckle composition.
- the detergent compositions may also contain other inorganic materials, for example, calcite, silica, amorphous aluminosilicate, or clays.
- Other ingredients that may be present include solvents, hydrotropes, fluorescers, dyes, photobleaches, foam boosters or foam controllers (antifoams) as appropriate, fabric conditioning compounds, and perfumes.
- Powders of low to moderate bulk density may be prepared by spray-drying a slurry, and optionally postdosing (dry- mixing) further ingredients.
- “Concentrated” or “compact” powders may be prepared by mixing and granulating processes, for example, using a high-speed mixer/granulator, or other non-tower processes. In both types of powder, the speckle composition may be incorporated by postdosing (dry mixing) .
- the detergent composition of the invention may alternatively be in tablet form. Tablets may be prepared by compacting powders, especially "concentrated” or “compact” powders, prepared as described above. The speckle composition is then included in the powder prior to compaction.
- a speckle composition was prepared to the formulation given in Table 1 :
- composition was prepared as follows. The ingredients were introduced into a stainless steel mixer in the following order:
- the ingredients were mixed for a period of time sufficient to ensure homogeneity.
- the resulting material was subsequently layered in the following stages:
- the speckles were of an attractive pink colour and had a pleasant odour.
- the detergent composition according to Table 2 was made by spray-drying a slurry followed by post-dosing.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR0212135-2A BR0212135A (pt) | 2001-08-31 | 2002-08-13 | Composição granular colorida perfumada, processo para fabricação da mesma, e, composição detergente particulada perfumada para lavagem de roupa |
EP02758462A EP1421167B1 (en) | 2001-08-31 | 2002-08-13 | Process for manufacture of perfumed coloured speckle compositoin for particulate laundry detergent compositions containing it |
DE60229532T DE60229532D1 (de) | 2001-08-31 | 2002-08-13 | Verfahren zur herstellung einer parfümierte gefärb teilchenförmige waschmitteln |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0121176.2 | 2001-08-31 | ||
GBGB0121176.2A GB0121176D0 (en) | 2001-08-31 | 2001-08-31 | Perfumed coloured speckle composition and particulate laundry detergent compositions containing it |
Publications (1)
Publication Number | Publication Date |
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WO2003020867A1 true WO2003020867A1 (en) | 2003-03-13 |
Family
ID=9921340
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/009051 WO2003020867A1 (en) | 2001-08-31 | 2002-08-13 | Perfumed coloured speckle composition and particulate laundry detergent compositions containing it |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP1421167B1 (es) |
CN (1) | CN1578828A (es) |
AR (1) | AR036308A1 (es) |
AT (1) | ATE412044T1 (es) |
BR (1) | BR0212135A (es) |
DE (1) | DE60229532D1 (es) |
ES (1) | ES2314085T3 (es) |
GB (1) | GB0121176D0 (es) |
WO (1) | WO2003020867A1 (es) |
ZA (1) | ZA200400892B (es) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004083356A1 (en) * | 2003-03-19 | 2004-09-30 | Givaudan Sa | Fragrance delivery |
WO2005005591A1 (en) * | 2003-07-08 | 2005-01-20 | Quest International Services B.V. | Fabric freshener compositions |
WO2006010390A1 (de) * | 2004-07-22 | 2006-02-02 | Henkel Kommanditgesellschaft Auf Aktien | Niotensid und/oder parfüm aufweisende sodafreie partikel zur anwendung in wasch- oder reinigungsmitteln |
WO2007028477A1 (de) * | 2005-09-09 | 2007-03-15 | Henkel Kommanditgesellschaft Auf Aktien | Verbrauchsprodukte mit welchselnden geruchsbildern |
FR2905954A1 (fr) * | 2006-09-18 | 2008-03-21 | Roman Gerusz | Agent de nettoyage preventif et/ou curatif de materiaux mis en contact d'eau |
EP2206765A1 (en) | 2009-01-08 | 2010-07-14 | Unilever N.V. | Detergent composition |
US8927026B2 (en) | 2011-04-07 | 2015-01-06 | The Procter & Gamble Company | Shampoo compositions with increased deposition of polyacrylate microcapsules |
US8980292B2 (en) | 2011-04-07 | 2015-03-17 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
US9162085B2 (en) | 2011-04-07 | 2015-10-20 | The Procter & Gamble Company | Personal cleansing compositions with increased deposition of polyacrylate microcapsules |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
CN112654693A (zh) * | 2018-09-14 | 2021-04-13 | 雷克特本克斯尔菲尼施公司 | 用于洗涤剂组合物的颗粒物 |
WO2022104631A1 (en) * | 2020-11-19 | 2022-05-27 | The Procter & Gamble Company | Method of making detergent compositions comprising perfume |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0604676D0 (en) * | 2006-03-08 | 2006-04-19 | Reckitt Benckiser Nv | Method |
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JPS6166800A (ja) * | 1984-09-07 | 1986-04-05 | 花王株式会社 | 粒状洗剤の改質方法 |
US5605883A (en) * | 1993-02-24 | 1997-02-25 | Iliff; Robert J. | Agglomerated colorant speckle exhibiting reduced colorant spotting |
WO1997047720A2 (en) * | 1996-06-11 | 1997-12-18 | The Procter & Gamble Company | Process for producing a particulate laundry additive for perfume delivery having improved physical properties |
US6093258A (en) * | 1998-01-29 | 2000-07-25 | Mc Lean; Ildiko M. | Tint stain remover |
WO2002010327A1 (en) * | 2000-07-31 | 2002-02-07 | Unilever Plc | Coloured speckle composition and particulate laundry detergent compositions containing it |
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2001
- 2001-08-31 GB GBGB0121176.2A patent/GB0121176D0/en not_active Ceased
-
2002
- 2002-08-13 DE DE60229532T patent/DE60229532D1/de not_active Expired - Lifetime
- 2002-08-13 CN CN02821453.6A patent/CN1578828A/zh active Pending
- 2002-08-13 AT AT02758462T patent/ATE412044T1/de not_active IP Right Cessation
- 2002-08-13 WO PCT/EP2002/009051 patent/WO2003020867A1/en not_active Application Discontinuation
- 2002-08-13 ES ES02758462T patent/ES2314085T3/es not_active Expired - Lifetime
- 2002-08-13 EP EP02758462A patent/EP1421167B1/en not_active Expired - Lifetime
- 2002-08-13 BR BR0212135-2A patent/BR0212135A/pt not_active Application Discontinuation
- 2002-08-29 AR ARP020103241A patent/AR036308A1/es active IP Right Grant
-
2004
- 2004-02-03 ZA ZA200400892A patent/ZA200400892B/en unknown
Patent Citations (5)
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JPS6166800A (ja) * | 1984-09-07 | 1986-04-05 | 花王株式会社 | 粒状洗剤の改質方法 |
US5605883A (en) * | 1993-02-24 | 1997-02-25 | Iliff; Robert J. | Agglomerated colorant speckle exhibiting reduced colorant spotting |
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Cited By (18)
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WO2004083356A1 (en) * | 2003-03-19 | 2004-09-30 | Givaudan Sa | Fragrance delivery |
CN100584934C (zh) * | 2003-03-19 | 2010-01-27 | 吉万奥丹股份有限公司 | 芳香剂的传递 |
WO2005005591A1 (en) * | 2003-07-08 | 2005-01-20 | Quest International Services B.V. | Fabric freshener compositions |
WO2006010390A1 (de) * | 2004-07-22 | 2006-02-02 | Henkel Kommanditgesellschaft Auf Aktien | Niotensid und/oder parfüm aufweisende sodafreie partikel zur anwendung in wasch- oder reinigungsmitteln |
WO2007028477A1 (de) * | 2005-09-09 | 2007-03-15 | Henkel Kommanditgesellschaft Auf Aktien | Verbrauchsprodukte mit welchselnden geruchsbildern |
FR2905954A1 (fr) * | 2006-09-18 | 2008-03-21 | Roman Gerusz | Agent de nettoyage preventif et/ou curatif de materiaux mis en contact d'eau |
EP2206765A1 (en) | 2009-01-08 | 2010-07-14 | Unilever N.V. | Detergent composition |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US11096875B2 (en) | 2010-04-28 | 2021-08-24 | The Procter & Gamble Company | Delivery particle |
US8980292B2 (en) | 2011-04-07 | 2015-03-17 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
US9162085B2 (en) | 2011-04-07 | 2015-10-20 | The Procter & Gamble Company | Personal cleansing compositions with increased deposition of polyacrylate microcapsules |
US9561169B2 (en) | 2011-04-07 | 2017-02-07 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
US8927026B2 (en) | 2011-04-07 | 2015-01-06 | The Procter & Gamble Company | Shampoo compositions with increased deposition of polyacrylate microcapsules |
US10143632B2 (en) | 2011-04-07 | 2018-12-04 | The Procter And Gamble Company | Shampoo compositions with increased deposition of polyacrylate microcapsules |
CN112654693A (zh) * | 2018-09-14 | 2021-04-13 | 雷克特本克斯尔菲尼施公司 | 用于洗涤剂组合物的颗粒物 |
US11746311B2 (en) | 2018-09-14 | 2023-09-05 | Reckitt Benckiser Finish B.V. | Granulate for detergent composition comprising nitrogen-containing builders |
WO2022104631A1 (en) * | 2020-11-19 | 2022-05-27 | The Procter & Gamble Company | Method of making detergent compositions comprising perfume |
Also Published As
Publication number | Publication date |
---|---|
CN1578828A (zh) | 2005-02-09 |
EP1421167A1 (en) | 2004-05-26 |
AR036308A1 (es) | 2004-08-25 |
ZA200400892B (en) | 2005-04-26 |
BR0212135A (pt) | 2004-08-24 |
EP1421167B1 (en) | 2008-10-22 |
ES2314085T3 (es) | 2009-03-16 |
GB0121176D0 (en) | 2001-10-24 |
ATE412044T1 (de) | 2008-11-15 |
DE60229532D1 (de) | 2008-12-04 |
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