WO2003010356A1 - Method for manufacturing pipe formed product and pipe formed product - Google Patents

Method for manufacturing pipe formed product and pipe formed product Download PDF

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Publication number
WO2003010356A1
WO2003010356A1 PCT/JP2002/007454 JP0207454W WO03010356A1 WO 2003010356 A1 WO2003010356 A1 WO 2003010356A1 JP 0207454 W JP0207454 W JP 0207454W WO 03010356 A1 WO03010356 A1 WO 03010356A1
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WIPO (PCT)
Prior art keywords
plating
pipe
layer
molded
product
Prior art date
Application number
PCT/JP2002/007454
Other languages
French (fr)
Japanese (ja)
Inventor
Kenichi Henmi
Original Assignee
Sanoh Kogyo Kabushiki Kaisha
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Publication date
Application filed by Sanoh Kogyo Kabushiki Kaisha filed Critical Sanoh Kogyo Kabushiki Kaisha
Publication of WO2003010356A1 publication Critical patent/WO2003010356A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/32Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M55/00Fuel-injection apparatus characterised by their fuel conduits or their venting means; Arrangements of conduits between fuel tank and pump F02M37/00
    • F02M55/02Conduits between injection pumps and injectors, e.g. conduits between pump and common-rail or conduits between common-rail and injectors
    • F02M55/025Common rails
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60KARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
    • B60K15/00Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
    • B60K15/01Arrangement of fuel conduits

Definitions

  • the present invention relates to a method for producing a pipe molded product and a pipe molded product, and more particularly to a method for producing a highly corrosion-resistant pipe molded product such as a fuel delivery pipe used for parts of an automobile, and a pipe molded product.
  • the aluminum material has strong corrosion resistance against oxidation and the like, so that the inside of the fuel delivery pipe does not need to be plated.
  • Ni plating was not applied to the surface of the mouth material used during welding. ( If the Ni plating was thick, bending cracking could cause plating cracks. Gasoline may come into direct contact with the steel material on the side surfaces, and the Ni layer, which is a barrier layer, is interrupted on the outer side surface, resulting in a problem of reduced corrosion resistance.
  • An object of the present invention is to provide a method for manufacturing a pipe molded product that solves the above-mentioned problems of the prior art and enables the manufacture of a tubular product such as a highly corrosion-resistant fuel delivery pipe.
  • the present invention relates to a method for producing a pipe molded product having a pipe-shaped portion, comprising: Forming; and dipping the completed shaped body in a Ni plating liquid to perform electroless Ni plating.
  • the method is characterized by comprising, following the electroless Ni plating step, a step of applying a Zn plating or a Zn alloy plating, a step of performing a chromate treatment, and a step of performing an organic coating treatment.
  • a pipe molded product having a pipe-shaped portion, and in a state where a completed shape to be the pipe molded product is formed, an electroless N formed on a surface of the completed shape is formed. It is characterized by having a Ni plating layer by i plating.
  • the Ni plating layer is formed on the inner surface and the outer surface of the completed shape, and the Zn formed on the Ni plating layer on the outer surface of the completed shape is formed. It is characterized by comprising a Zn plating layer formed by plating or a Zn alloy alloy, a chromate treatment layer formed on the Zn plating layer, and an organic coating treatment layer formed on the chromate treatment layer.
  • the Ni plating layer is formed on an inner surface and an outer surface of the completed shape, and the Ni plating on the inner surface and the outer surface of the completed shape.
  • the pipe molding is a fuel delivery pipe.
  • the pipe molded product is characterized in that the pipe length is at least three times the pipe diameter.
  • the finished shape is formed by processing and forming the steel material, and the finished shape is subjected to the electroless Ni plating. Also, since it is not necessary to newly perform a bending process or the like, it is possible to eliminate the occurrence of cracks, and since there is no need to dispose electrodes, the inner surface of the pipe-shaped portion is not required. Also Ni plating can be applied.
  • FIG. 1 is a perspective view showing a fuel delivery pipe pipe as an example of a molded pipe.
  • FIG. 2 is a diagram showing a manufacturing process of a molded pipe.
  • FIG. 3 is a cross-sectional view showing the surface of the molded pipe.
  • FIG. 1 shows a schematic configuration of a fuel delivery pipe 1 as an example of a tubular product.
  • the fuel delivery pipe 1 includes a plurality of cylindrical pipes 2 and a long and thin connecting pipe 3 for connecting the pipes 2 to each other to feed and discharge fuel.
  • the pipe part 2 is connected to the connecting pipe 3 like a branch pipe, and a branch part is formed at the connecting part of the connecting pipe 3 of the connecting pipe 3. Fuel is supplied from the B side and sent out to the A side.
  • the tubular product targeted by the embodiment of the present invention has a longer length in the flow direction than the diameter of a pipe forming a fluid flow path, such as a fuel delivery pipe 1, for example.
  • a pipe forming a fluid flow path such as a fuel delivery pipe 1, for example.
  • Whose length in the channel direction is at least 3 times longer than the pipe diameter It is. If the length in the direction of the flow path is three times or more longer than the diameter of the pipe in this way, when the product Ni (electroformed Ni) is subjected to electrolytic Ni plating via a pair of electrodes, Even if one electrode is attached to the product shape and an electric field is applied, the electric field does not spread sufficiently to the back of the tube due to the shielding effect of the cylindrical conductor.
  • the electrolytic plating reaction occurs only in a length range of about 1.5 times the pipe diameter from the pipe end, and it is impossible to perform uniform plating on the inner wall surface of the product shape without unevenness.
  • the diameter of the pipe refers to the thickness of the cylindrical body such as a rectangular parallelepiped.
  • an iron plate material and an iron tube material are cut and formed into a predetermined shape according to a known processing method.
  • the formed parts are connected to each other by welding to finish the finished product.
  • a product shape body that has been completed in shape to become the fuel delivery pipe 1 is placed in a predetermined plating solution tank, and electroless Ni plating is performed by a known method.
  • the electroless Ni plating is a plating performed using, for example, a Ni—P alloy.
  • the product shape (finished shape) is rotated in the plating liquid tank or the plating liquid in the plating liquid tank is stirred so that the Ni plating liquid flows into the inside of the product shape.
  • the Ni plating is an electroless plating, it is not necessary to pass a current through the electrode, and the uniform distribution is achieved simply by applying a mechanical relative movement between the Ni plating liquid and the product. It is possible to apply the Ni plating without.
  • the Ni mask is applied to both the outer surface and the inner surface of the product shape body.
  • the Ni surface is applied to the inner surface of the product shape
  • the Ni surface, the Zn alloy plating or Zn surface, and the chromate treatment are applied to the outer surface of the product shape.
  • An organic coating process is performed.
  • post-processing of the surface treatment is performed to obtain a fuel delino linophil 1 as a finished product.
  • the product shape is subjected to electroless Ni plating.
  • Ni plating can also be applied to the surface of the brazing material, and it is not necessary to perform new bending, etc., so that cracking does not occur even when the thickness of the Ni plating is large. Gasoline can be prevented from directly touching the steel material inside, and the corrosion resistance is reduced on the outer surface because the Ni layer, which is the barrier layer, is interrupted.
  • the Ni plating is an electroless plating, by performing a mechanical relative movement between the Ni plating liquid and the product shape without disposing an electrode, Inner surface of product It can be subjected to a uniform dark circles without N i plated.
  • the pipe molded product is composed of an electroless Ni plating Ni layer 11 formed on the outer surface and the inner surface of the steel material 10, and a Ni plating layer 11 formed on the Ni material.
  • the Zn plating layer 12 formed by the formed Zn plating or Zn alloy alloy, the chromate treatment layer 13 formed on the Zn plating layer 12, and the chromate treatment layer 13 formed on the Zn plating layer 13 And an organic coating treatment layer 14 formed.
  • the outer surface of the product is treated with Zn alloy plating or Zn plating, chromate treatment, and organic coating treatment only on the outer surface of the product. Performance can be efficiently enhanced.
  • the molded pipe is provided with a Ni plating layer 11 made of an electroless Ni plating on the inner surface of the steel 10 and a Ni plating made of the electroless Ni plating on the outer surface of the steel 10.
  • the pipe molded product is not limited to a tubular one such as a cylindrical tube, but may be any one having a cavity (dent) formed therein. It may have openings at both ends.
  • the fuel delivery pipe 1 is taken as an example of the high corrosion resistant pipe, but the high corrosion resistance pipe is not limited to this, and any pipe having a recess therein may be used. Further, the fuel delivery pipe is not limited to the cylindrical pipe shown in FIG. 1, but may be formed in a rectangular parallelepiped by sheet metal and have openings at both ends.
  • the steel material may be iron or an alloy of iron and another metal as long as it is an iron material that corrodes when it comes into direct contact with gasoline or the like.
  • the Zn plating may be a Zn alloy or a plating of Zn metal.
  • a completed shape is formed by processing and forming a steel material, and the completed shape is subjected to electroless Ni plating. Things can be manufactured. Further, by forming a Zn plating layer, a chromate treatment layer, and an organic coating treatment layer on the electroless Ni plating Ni plating layer, a highly corrosion resistant pipe molded product can be supplied.

Abstract

A method for manufacturing a pipe formed product such as a fuel delivery pipe having a pipe-shaped portion capable of applying Ni plating also on the surface of brazing material at a weld part to prevent cracks in plating from occurring, characterized by comprising the steps of forming a complete-shaped body to form the pipe formed product by working and forming steel materials and applying non-electrolyte Ni plating to the complete-shaped body by immersing the complete- shaped body in Ni plating solution.

Description

明 細 書 パイプ成形物の製造方法及びパイプ成形物 技術分野  Description Method for producing pipe molded product and pipe molded product
本発明は、 パイプ成形物の製造方法及びパイプ成形物に係り、 特に、 例えば自 動車の部品に用いるフユ一エルデリバリパイプ等の高耐蝕性のパイプ成形物の製 造方法及びパイプ成形物に関する。 背景技術  The present invention relates to a method for producing a pipe molded product and a pipe molded product, and more particularly to a method for producing a highly corrosion-resistant pipe molded product such as a fuel delivery pipe used for parts of an automobile, and a pipe molded product. Background art
フユ一エルデリバリパイプの内部にはガソリン等の燃料が流通するため、 内部 が酸化等により耐蝕されたりするとさび片等がエンジンの内部に搬送される恐れ があり、 この好ましくない。 このため、 フユ一エルデリバリパイプの内部には高 い耐蝕性が要求される。  Since fuel such as gasoline flows inside the fuel delivery pipe, if the inside is eroded by oxidation or the like, rust pieces and the like may be conveyed into the engine, which is not preferable. Therefore, high corrosion resistance is required inside the fuel delivery pipe.
フユ一エルデリバリパイプをアルミ材等を用い型成型する場合は、 アルミ材が 酸化等に対する強い耐蝕性を有するので、 フユ一エルデリバリパイプの内部をメ ツキ処理する必要がない。  When the fuel delivery pipe is molded using an aluminum material or the like, the aluminum material has strong corrosion resistance against oxidation and the like, so that the inside of the fuel delivery pipe does not need to be plated.
しかしながら、 鉄材を用いてフユ一エルデリバリパイプを構成する場合には、 酸化等を防止するために内部をメッキ処理する必要がある。 フユ一エルデリバリ パイプを鉄材を用いて構成する場合に、 フユ一エルデリバリパイプを形成した後 にはその内部に複雑な凹部が形成されているため、 フユ一エルデリバリパイプの 内部全体を均一にメッキ処理することは容易ではない。  However, when a fuel delivery pipe is made of an iron material, it is necessary to plate the inside of the fuel delivery pipe to prevent oxidation and the like. When the fuel delivery pipe is made of an iron material, after forming the fuel delivery pipe, a complicated concave portion is formed inside the pipe, so that the entire inside of the fuel delivery pipe is uniformly formed. Plating is not easy.
そこで、 従来は、 フユ一エルデリバリパイプの製造にあたり、 鉄の板材ゃ管材 を予め N iメツキしておき、 その後に曲げ加工及び溶接を行い製品形状体を形成 していた。 そして、 その製品外面に Z nまたは Z n N i等のメヅキ処理を行い、 その後にクロメート処理をしていた。 この場合、 フューエルデリバリパイプの内 側面は N iメヅキされ、 外側面は N iメツキ、 Z nまたは Z n N i等のメヅキ、 及びクロメート処理される。 また、 これらのメヅキ処理において、 無電解 N iメ ツキ処理されることはなく、 電解 N iメツキ処理が行われていた。 従来は、 予め N iメツキされた鉄の板材ゃ管材を切断加工等を行っていたので、 切断面に N iメツキが施されない、 という問題があった。 Therefore, in the past, in the manufacture of fuel delivery pipes, an iron plate and a pipe were subjected to Ni plating in advance, followed by bending and welding to form a product shaped body. Then, the outer surface of the product is subjected to a printing process such as Zn or ZnNi, and then a chromate process. In this case, the inner surface of the fuel delivery pipe is subjected to Ni plating, and the outer surface thereof is subjected to plating such as Ni plating, Zn or ZnNi, and chromate treatment. In addition, in these plating processes, the electroless Ni plating process was not performed, and the electrolytic Ni plating process was performed. Conventionally, there has been a problem that the Ni plate is not applied to the cut surface because the cutting process or the like is performed on the iron plate material or the tube material which has been previously plated with Ni.
溶接時に使用した口一材表面に N iメツキが施されない、 という問題があった ( N iメヅキの厚さが厚い場合には、 曲げ加工によりメッキ割れが生じることが あった。 このため、 内側面については鉄鋼材にガソリンが直接触れることがあり、 外側面についてはバリア層である N i層が途切れるため耐蝕性が低下するという 問題があった。 発明の開示 There was a problem that the Ni plating was not applied to the surface of the mouth material used during welding. ( If the Ni plating was thick, bending cracking could cause plating cracks. Gasoline may come into direct contact with the steel material on the side surfaces, and the Ni layer, which is a barrier layer, is interrupted on the outer side surface, resulting in a problem of reduced corrosion resistance.
そこで発明の目的は、 上記従来技術の有する問題を解消し、 高耐蝕性のフユ一 エルデリバリパイプ等の管状製品の製造を可能にするパイプ成形物の製造方法を 提供することである。  SUMMARY OF THE INVENTION An object of the present invention is to provide a method for manufacturing a pipe molded product that solves the above-mentioned problems of the prior art and enables the manufacture of a tubular product such as a highly corrosion-resistant fuel delivery pipe.
上記目的を達成するために、 本発明は、 パイプ状に成形された部分を有するパ ィプ成型物の製造方法であって、 鉄鋼材を加工成形してパイプ成形物となるべき 完成形状体を形成する工程と、 前記完成形状体を N iメツキ液につけて無電解 N iメツキする工程と、 を備えることを特徴とする。  In order to achieve the above object, the present invention relates to a method for producing a pipe molded product having a pipe-shaped portion, comprising: Forming; and dipping the completed shaped body in a Ni plating liquid to perform electroless Ni plating.
また、 前記無電解 N iメヅキする工程の次に、 Z nメツキあるいは Z n系合金 メツキを施す工程と、 クロメート処理を施す工程と、 有機被膜処理を施す工程と を備えることを特徴とする。  Further, the method is characterized by comprising, following the electroless Ni plating step, a step of applying a Zn plating or a Zn alloy plating, a step of performing a chromate treatment, and a step of performing an organic coating treatment.
また、 パイプ状に成形された部分を有するパイプ成型物であって、 前記パイプ 成型物となるべき完成形状体が形成された状態で、 前記完成形状体の表面上に形 成された無電解 N iメツキによる N iメツキ層を備えることを特徴とする。  Further, it is a pipe molded product having a pipe-shaped portion, and in a state where a completed shape to be the pipe molded product is formed, an electroless N formed on a surface of the completed shape is formed. It is characterized by having a Ni plating layer by i plating.
また、 前記 N iメツキ層は前記完成形状体の内側表面上及び外側表面上に形成 されており、 前記完成形状体の前記外側表面上の前記 N iメッキ層の上に形成さ れた Z nメツキあるいは Z n系合金メヅキによる Z nメツキ層と、 この Z nメヅ キ層上に形成されたクロメート処理層と、 このクロメート処理層上に形成された 有機被膜処理層とを備えることを特徴とする。  The Ni plating layer is formed on the inner surface and the outer surface of the completed shape, and the Zn formed on the Ni plating layer on the outer surface of the completed shape is formed. It is characterized by comprising a Zn plating layer formed by plating or a Zn alloy alloy, a chromate treatment layer formed on the Zn plating layer, and an organic coating treatment layer formed on the chromate treatment layer. And
また、 前記 N iメッキ層は前記完成形状体の内側表面上及び外側表面上に形成 されており、 前記完成形状体の前記内側表面上及び前記外側表面上の前記 N iメ ツキ層の上に形成された Z nメツキあるいは Z n系合金メツキによる Z nメツキ 層と、 この Z nメツキ層上に形成されたクロメート処理層と、 このクロメート処 理層上に形成された有機被膜処理層とを備えることを特徴とする。 The Ni plating layer is formed on an inner surface and an outer surface of the completed shape, and the Ni plating on the inner surface and the outer surface of the completed shape. A Zn plating layer formed on the plating layer by Zn plating or Zn alloy plating; a chromate treatment layer formed on the Zn plating layer; and an organic layer formed on the chromate treatment layer. And a coating treatment layer.
また、 前記パイプ成形物は、 フューエルデリパリパイプであることを特徴とす る。  Further, the pipe molding is a fuel delivery pipe.
また、 前記パイプ成形物のパイプ長さがパイプ直径より 3倍以上であることを 特徴とする。  Further, the pipe molded product is characterized in that the pipe length is at least three times the pipe diameter.
上述の発明において、 鉄鋼材を加工成形して完成形状体を形成し、 完成形状体 を無電解 N iメツキするようにしたので、 溶接部の口一材表面にも N iメツキを 施すことができ、 また、 新たに曲げ加工等を施す必要がないのでメツキ割れを生 じさせることを無くすることができ、 また電極を配設することがないのでパイプ 状に成形された部分の内側面にも N iメッキを施すことができる。 図面の簡単な説明  In the above invention, the finished shape is formed by processing and forming the steel material, and the finished shape is subjected to the electroless Ni plating. Also, since it is not necessary to newly perform a bending process or the like, it is possible to eliminate the occurrence of cracks, and since there is no need to dispose electrodes, the inner surface of the pipe-shaped portion is not required. Also Ni plating can be applied. BRIEF DESCRIPTION OF THE FIGURES
図 1はパイプ成形物の一例であるフユ一エルデリバリパイプパイプを示す斜視 図である。  FIG. 1 is a perspective view showing a fuel delivery pipe pipe as an example of a molded pipe.
図 2はパイプ成形物の製造工程を示す図である。  FIG. 2 is a diagram showing a manufacturing process of a molded pipe.
図 3はパイプ成形物の表面を示す断面図である。 発明を実施するための最良の形態  FIG. 3 is a cross-sectional view showing the surface of the molded pipe. BEST MODE FOR CARRYING OUT THE INVENTION
以下に図面を参照して、 本発明の実施の形態について説明する。  Hereinafter, embodiments of the present invention will be described with reference to the drawings.
図 1に、 管状製品の一例としてフユ一エルデリバリパイプ 1の概略構成を示す。 フューエルデリバリパイプ 1は、 複数の円筒状の管部 2と、 管部 2と管部 2との 間を接続し燃料を送り込み送り出すための長細い連結管 3とを備えている。 管部 2は枝管のように連結管 3に接続されており、 連結管 3の管部 2の接続部には分 岐部が形成されている。 B側から燃料が供給され、 A側へ送り出される。  FIG. 1 shows a schematic configuration of a fuel delivery pipe 1 as an example of a tubular product. The fuel delivery pipe 1 includes a plurality of cylindrical pipes 2 and a long and thin connecting pipe 3 for connecting the pipes 2 to each other to feed and discharge fuel. The pipe part 2 is connected to the connecting pipe 3 like a branch pipe, and a branch part is formed at the connecting part of the connecting pipe 3 of the connecting pipe 3. Fuel is supplied from the B side and sent out to the A side.
ここで、 本発明の実施の形態が対象とする管状製品は、 例えばフユ一エルデリ バリパイプ 1のように、 流体の流路を形成するパイプの直径に比べて流路方向の 長さが長く、 例えば、 パイプの直径に比べて流路方向の長さが 3倍以上長いもの である。 このようにパイプの直径に比べて流路方向の長さが 3倍以上長い場合に は、 製品形状体 (完成形状体) に対し一対の電極を介して電解 N iメツキを行お うとすると、 一方の電極を製品形状体に取り付け電界をかけても、 筒状の導電体 によるシールド効果等に起因して電界が筒状体の奥方向にまで十分に行き渡らな い.。 このため、 電解メツキ反応は、 パイプ端部からパイプ直径の 1 . 5倍程度の 長さ範囲においてしか生じず、 製品形状体の内壁面をムラなく均一にメツキを行 うことを不可能である。 なお、 ここで、 パイプの直径とは、 例えば直方体のよう な筒体に対しては筒体の太さ寸法をいう。 Here, the tubular product targeted by the embodiment of the present invention has a longer length in the flow direction than the diameter of a pipe forming a fluid flow path, such as a fuel delivery pipe 1, for example. , Whose length in the channel direction is at least 3 times longer than the pipe diameter It is. If the length in the direction of the flow path is three times or more longer than the diameter of the pipe in this way, when the product Ni (electroformed Ni) is subjected to electrolytic Ni plating via a pair of electrodes, Even if one electrode is attached to the product shape and an electric field is applied, the electric field does not spread sufficiently to the back of the tube due to the shielding effect of the cylindrical conductor. For this reason, the electrolytic plating reaction occurs only in a length range of about 1.5 times the pipe diameter from the pipe end, and it is impossible to perform uniform plating on the inner wall surface of the product shape without unevenness. . Here, the diameter of the pipe refers to the thickness of the cylindrical body such as a rectangular parallelepiped.
フユ一エルデリバリパイプ 1を製造するにあたっては、 図 2に示すように、 ま ず、 S T 1で、 公知の加工成型法に従って、 鉄板材ゃ鉄管材を切断加工し、 所定 の形状に成形加工し、 成形加工した部分同士を溶接によって連結し、 形状的に完 成した製品形状体に仕上げる。  When manufacturing the fuel delivery pipe 1, as shown in FIG. 2, first, in ST 1, an iron plate material and an iron tube material are cut and formed into a predetermined shape according to a known processing method. The formed parts are connected to each other by welding to finish the finished product.
次に、 S T 2で、 この製品形状体の表面処理を行う。 この表面処理は、 フュー エルデリバリパイブ 1となるように形状的に完成された製品形状体を所定のメッ キ液槽につけ、 公知の手法によって無電解 N iメツキを行う。 無電解 N iメツキ は、 例えば N i— P合金を用いて行うメツキである。 メツキ液槽中で製品形状体 (完成形状体) を回転させあるいはメツキ液槽中のメヅキ液を撹拌させ、 N iメ ツキ液が製品形状体の内部にまで流れ込むようにする。 この場合、 N iメツキは 無電解メツキであるので電極を介して電流を流す必要がなく、 単に N iメツキ液 と製品形状体との間に機械的な相対移動運動を施すことによって均一に隈無く N iメツキを施すことができる。 そして、 製品形状体の外側表面と内側表面の両方 に渡って N iメヅキが施される。  Next, surface treatment of the product shape body is performed in ST2. In this surface treatment, a product shape body that has been completed in shape to become the fuel delivery pipe 1 is placed in a predetermined plating solution tank, and electroless Ni plating is performed by a known method. The electroless Ni plating is a plating performed using, for example, a Ni—P alloy. The product shape (finished shape) is rotated in the plating liquid tank or the plating liquid in the plating liquid tank is stirred so that the Ni plating liquid flows into the inside of the product shape. In this case, since the Ni plating is an electroless plating, it is not necessary to pass a current through the electrode, and the uniform distribution is achieved simply by applying a mechanical relative movement between the Ni plating liquid and the product. It is possible to apply the Ni plating without. Then, the Ni mask is applied to both the outer surface and the inner surface of the product shape body.
次に、 S T 3で、 主に製品形状体の外側表面を表面処理することを目的として、 無電解 N iメッキの後に、 N iメッキ層を保護するためにさらに Z n系合金メッ キあるいは Z nメツキを行う。 そして、 最終的な表面処理として、 クロメート処 理を行い、 さらに必要に応じて表面に有機被膜を形成する表面処理を行う。  Next, in ST 3, mainly for the purpose of surface treatment of the outer surface of the product shape, after the electroless Ni plating, an additional Zn alloy alloy or Z is added to protect the Ni plating layer. Perform n Meseki. Then, a chromate treatment is performed as a final surface treatment, and a surface treatment for forming an organic film on the surface is further performed as necessary.
この結果、 製品形状体の内側表面には N iメツキが施される一方、 製品形状体 の外側表面には、 N iメツキと、 Z n系合金メッキあるいは Z nメヅキと、 クロ メート処理と、 有機被膜処理とが施される。 次に、 S T 4で、 表面処理の事後処理を行い、 製品完成体であるフユ一エルデ リノ リノ ィプ 1が得られる。 As a result, while the Ni surface is applied to the inner surface of the product shape, the Ni surface, the Zn alloy plating or Zn surface, and the chromate treatment are applied to the outer surface of the product shape. An organic coating process is performed. Next, in ST4, post-processing of the surface treatment is performed to obtain a fuel delino linophil 1 as a finished product.
以上のように、 本実施の形態によれば、 形状的に完成した製品形状体を鉄鋼材 で加工整形仕上げした後に、 その製品形状体を無電解 N iメツキをするようにし たので、 溶接時におけるロー材表面にも N iメツキを施すことができ、 また、 新 たに曲げ加工等を施す必要がないので N iメツキの厚さが厚い場合にもメツキ割 れを生じさせることを無くすることができ、 内側にある鉄鋼材にガソリンが直接 触れるようなことを無くすることができ、 また、 外側面についてはバリア層であ る N i層が途切れるために耐蝕性が低下するということを回避することができる c また、 N iメヅキは、 無電解メツキであるので、 電極を配設することなく N i メツキ液と製品形状体との間に機械的な相対移動運動を施すことによって、 製品 形状体の内側面にも均一に隈無く N iメツキを施すことができる。  As described above, according to the present embodiment, after a shape-completed product shape is processed and finished with a steel material, the product shape is subjected to electroless Ni plating. Ni plating can also be applied to the surface of the brazing material, and it is not necessary to perform new bending, etc., so that cracking does not occur even when the thickness of the Ni plating is large. Gasoline can be prevented from directly touching the steel material inside, and the corrosion resistance is reduced on the outer surface because the Ni layer, which is the barrier layer, is interrupted. In addition, since the Ni plating is an electroless plating, by performing a mechanical relative movement between the Ni plating liquid and the product shape without disposing an electrode, Inner surface of product It can be subjected to a uniform dark circles without N i plated.
また、 無電解 N iメツキに加えて、 Z n系合金メッキあるいは Z nメヅキと、 クロメート処理と、 有機被膜処理を施すことによって、 外的環境に対する耐蝕性 をより強化することができる。 図 3に示すように、 パイプ成型物は、 鋼材 1 0の 外側表面上及び内側表面上に形成された無電解 N iメツキによる N iメツキ層 1 1と、 この N iメツキ層 1 1上に形成された Z nメヅキあるいは Z n系合金メッ キによる Z nメヅキ層 1 2と、 この Z nメツキ層 1 2上に形成されたクロメート 処理層 1 3と、 このクロメート処理層 1 3上に形成された有機被膜処理層 1 4と を備えている。  Further, in addition to the electroless Ni plating, a Zn-based alloy plating or Zn plating, a chromate treatment, and an organic coating treatment can further enhance corrosion resistance against an external environment. As shown in FIG. 3, the pipe molded product is composed of an electroless Ni plating Ni layer 11 formed on the outer surface and the inner surface of the steel material 10, and a Ni plating layer 11 formed on the Ni material. The Zn plating layer 12 formed by the formed Zn plating or Zn alloy alloy, the chromate treatment layer 13 formed on the Zn plating layer 12, and the chromate treatment layer 13 formed on the Zn plating layer 13 And an organic coating treatment layer 14 formed.
また、 無電解 N iメツキに加えて、 製品形状体の外側表面に対してのみに、 Z n系合金メッキあるいは Z nメヅキと、 クロメート処理と、 有機被膜処理を施す ことによって、 外表面の耐蝕性を効率的に強化することができる。 この場合、 パ イブ成型物は、 鋼材 1 0の内側表面上には無電解 N iメツキによる N iメツキ層 1 1を備え、 鋼材 1 0の外側表面上には無電解 N iメツキによる N iメヅキ層 1 1と、 この N iメヅキ層 1 1上に形成された Z nメヅキあるいは Z n系合金メヅ キによる Z nメツキ層 1 2と、 この Z nメツキ層 1 2上に形成されたクロメート 処理層 1 3と、 このクロメート処理層 1 3上に形成された有機被膜処理層 1 4と を備えている。 なお、 上述の説明において、 パイプ成形物とは、 円筒管のような管状のものに 限らず、 内部に空洞 (窪み) の形成されたものであればよく、 例えば、 板金で直 方体に形成し両端側に開口部を有するものであってもよい。 In addition to the electroless Ni plating, the outer surface of the product is treated with Zn alloy plating or Zn plating, chromate treatment, and organic coating treatment only on the outer surface of the product. Performance can be efficiently enhanced. In this case, the molded pipe is provided with a Ni plating layer 11 made of an electroless Ni plating on the inner surface of the steel 10 and a Ni plating made of the electroless Ni plating on the outer surface of the steel 10. The print layer 11, the Zn print layer 12 formed on the Ni print layer 11 by the Zn print or Zn alloy print, and the Zn print layer 12 formed on the Zn print layer 12. It has a chromate treatment layer 13 and an organic coating treatment layer 14 formed on the chromate treatment layer 13. In the above description, the pipe molded product is not limited to a tubular one such as a cylindrical tube, but may be any one having a cavity (dent) formed therein. It may have openings at both ends.
また、 高耐蝕性パイプ成形物として、 フューエルデリバリパイプ 1を例にして 取り上げたが、 高耐蝕性パイプ成形物としてはこれに限らず、 内部に窪みが形成 されたものであればなんでもよい。 また、 フユ一エルデリバリパイプは図 1に示 す円筒管に限らず、 板金で直方体に形成し両端側に開口部を有するものであって もよい。  Further, the fuel delivery pipe 1 is taken as an example of the high corrosion resistant pipe, but the high corrosion resistance pipe is not limited to this, and any pipe having a recess therein may be used. Further, the fuel delivery pipe is not limited to the cylindrical pipe shown in FIG. 1, but may be formed in a rectangular parallelepiped by sheet metal and have openings at both ends.
また、 鉄鋼材としては、 ガソリン等に直接接触した場合に腐蝕する鉄材であれ ば、 鉄であっても鉄と他の金属との合金であってもよい。  The steel material may be iron or an alloy of iron and another metal as long as it is an iron material that corrodes when it comes into direct contact with gasoline or the like.
また、 Z nメツキとしては、 Z n系合金でも Z n金属によるメツキでもよい。 以上のように、 本発明の構成によれば、 鉄鋼材を加工成形して完成形状体を形 成し、 完成形状体を無電解 N iメヅキするようにしたので、 高耐蝕性のパイプ成 形物を製造することができる。 また、 無電解 N iメヅキした N iメヅキ層上にさ らに Z nメツキ層とクロメート処理層と有機被膜処理層を形成することによって、 高耐蝕性のパイプ成形物を供給することができる。  Further, the Zn plating may be a Zn alloy or a plating of Zn metal. As described above, according to the configuration of the present invention, a completed shape is formed by processing and forming a steel material, and the completed shape is subjected to electroless Ni plating. Things can be manufactured. Further, by forming a Zn plating layer, a chromate treatment layer, and an organic coating treatment layer on the electroless Ni plating Ni plating layer, a highly corrosion resistant pipe molded product can be supplied.

Claims

請 求 の 範 囲 The scope of the claims
1 . パイプ状に成形された部分を有するパイプ成型物の製造方法であって、 鉄鋼材を加工成形してパイプ成形物となるべき完成形状体を形成する工程と、 前記完成形状体を N iメツキ液につけて無電解 N iメツキする工程と、 を備えることを特徴とするパイプ成形物の製造方法。 1. A method for manufacturing a pipe molded product having a pipe-shaped portion, wherein a step of processing and forming a steel material to form a completed molded product to be a pipe molded product; A method of electroless Ni plating by dipping in a plating liquid.
2 . 前記無電解 N iメツキする工程の次に、 Z nメツキあるいは Z n系合金 メツキを施す工程と、 クロメート処理を施す工程と、 有機被膜処理を施す工程と を備える  2. Following the step of electroless Ni plating, a step of applying a Zn plating or Zn alloy plating, a step of performing a chromate treatment, and a step of performing an organic coating treatment are provided.
ことを特徴とする請求項 1に記載のパイプ成形物の製造方法。 The method for producing a pipe molded product according to claim 1, wherein:
3 . 前記パイプ成形物は、 フューエルデリバリパイプである  3. The molded pipe is a fuel delivery pipe
ことを特徴とする請求項 1に記載のパイプ成形物の製造方法。 The method for producing a pipe molded product according to claim 1, wherein:
4 . 前記パイプ成形物のパイプ長さがパイプ直径より 3倍以上である ことを特徴とする請求項 1に記載のパイプ成形物の製造方法。  4. The method for producing a molded pipe according to claim 1, wherein the length of the molded pipe is at least three times the diameter of the pipe.
5 . パイプ状に成形された部分を有するパイプ成型物であって、  5. A pipe molded product having a pipe-shaped portion,
前記パイプ成型物となるべき完成形状体が形成された状態で、 前記完成形状体 の表面上に形成された無電解 N iメツキによる N iメツキ層を備える  In the state where the completed shape to be formed into the pipe molded product is formed, a Ni plating layer formed by electroless Ni plating formed on the surface of the completed shape is provided.
ことを特徴とするパイプ成形物。 A molded pipe product characterized by the above-mentioned.
6 . 前記 N iメッキ層は前記完成形状体の内側表面上及び外側表面上に形成 されており、  6. The Ni plating layer is formed on an inner surface and an outer surface of the completed shape body,
前記完成形状体の前記外側表面上の前記 N iメッキ層の上に形成された Z nメ ツキあるいは Z n系合金メツキによる Z nメツキ層と、 この Z nメツキ層上に形 成されたクロメート処理層と、 このクロメート処理層上に形成された有機被膜処 理層とを備えることを特徴とする請求項 5に記載のパイプ成形物。  A Zn plating layer formed on the Ni plating layer on the outer surface of the completed shaped body by Zn plating or Zn plating alloy plating; and a chromate formed on the Zn plating layer. 6. The molded pipe according to claim 5, comprising a treatment layer and an organic coating treatment layer formed on the chromate treatment layer.
7 . 前記 N iメッキ層は前記完成形状体の内側表面上及び外側表面上に形成 されており、  7. The Ni plating layer is formed on an inner surface and an outer surface of the completed shape body,
前記完成形状体の前記内側表面上及び前記外側表面上の前記 N iメツキ層の上 に形成された Z nメヅキあるいは Z n系合金メヅキによる Z nメヅキ層と、 この Z nメツキ層上に形成されたクロメート処理層と、 このクロメート処理層上に形 成された有機被膜処理層とを備えることを特徴とする請求項 5に記載のパイプ成 形物。 . A Zn plating layer or a Zn plating alloy layer formed on the Ni plating layer on the inner surface and the outer surface of the completed shape body; and a Zn plating layer formed on the Zn plating layer. Chromated layer and the 6. The molded pipe according to claim 5, comprising a formed organic film treatment layer. .
8 . 前記パイプ成形物は、 フユ一エルデリバリパイプであることを特徴とす る請求項 5に記載のパイプ成形物。  8. The molded pipe according to claim 5, wherein the molded pipe is a fuel delivery pipe.
9 . 前記パイプ成形物のパイプ長さがパイプ直径より 3倍以上である ことを特徴とする請求項 5に記載のパイプ成形物。  9. The molded pipe according to claim 5, wherein the length of the molded pipe is at least three times the diameter of the pipe.
PCT/JP2002/007454 2001-07-23 2002-07-23 Method for manufacturing pipe formed product and pipe formed product WO2003010356A1 (en)

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