Classifications

• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
  • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
  • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
  • C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
  • C03C17/3447—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a halide
  • C03C17/3452—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a halide comprising a fluoride
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
  • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
  • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10431—Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
  • B32B17/10467—Variable transmission
  • B32B17/10495—Variable transmission optoelectronic, i.e. optical valve
  • B32B17/10513—Electrochromic layer
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
  • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
  • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
  • C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
  • C03C17/3441—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising carbon, a carbide or oxycarbide
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
  • G02F1/153—Constructional details
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
  • G02F1/153—Constructional details
  • G02F1/161—Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2327/00—Polyvinylhalogenides
  • B32B2327/12—Polyvinylhalogenides containing fluorine
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C2217/00—Coatings on glass
  • C03C2217/90—Other aspects of coatings
  • C03C2217/94—Transparent conductive oxide layers [TCO] being part of a multilayer coating
• • C—CHEMISTRY; METALLURGY
  • C03—GLASS; MINERAL OR SLAG WOOL
  • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
  • C03C2217/00—Coatings on glass
  • C03C2217/90—Other aspects of coatings
  • C03C2217/94—Transparent conductive oxide layers [TCO] being part of a multilayer coating
  • C03C2217/948—Layers comprising indium tin oxide [ITO]
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition

Definitions

• the invention relates to electrocontrollable devices with variable optical and / or energetic properties. She is more particularly interested in devices using electrochromic or viologen systems, operating in transmission or in reflection. It can also be applied to other systems of the electroluminescent type, optical valves, etc. Examples of viologenic systems are described in the US-5 patents.
• Electrochromic systems have been widely studied. They generally comprise, in known manner, two layers of electrochromic materials separated by an electrolyte and surrounded by two electrodes. Each of the electrochromic layers, under the effect of an electrical supply, can reversibly insert cations, which results in a modification in its properties (for example for tungsten oxide, a coloring from a pale blue to a midnight blue ).
• electrochromic systems are “all solid” systems, that is to say those in which all the layers, and very particularly the electrolyte, are essentially mineral in nature: it is indeed possible to deposit successively on the same substrate all layers, by the same type of technique, in particular cathode sputtering.
• all solid systems are detailed in patents EP-867,752, EP-831,360, WO 00/03289 and WO 00/57243.
• electrochromic systems in particular those in which the electrolyte is a layer based on a polymer or a gel, the other layers being generally mineral (reference may be made for example to patents EP-253,713 and EP-670,346).
• electrochromic systems where all the layers are based on polymers, so we speak of "all polymer " systems .
• the invention is particularly interested in so-called “all solid” electrochromic systems. Many applications have already been envisaged for these systems. It was a question, most generally, of using them as glazing for the building or as glazing for vehicle, in particular as a car roof, or else, then functioning in reflection and no longer in transmission, as a rear view mirror glare. These systems have in common the fact that they can, on a more or less large scale, be sensitive to mechanical, chemical aggressions, in contact with water, to exchanges with the outside. This is the reason why, to preserve their good functioning, these “active” systems are usually arranged between two rigid protective substrates.
• all the layers of the system are generally deposited on a glass substrate, which is then laminated to a second glass with a thermoplastic sheet, so that the system active is between two glasses.
• the electrolyte is made of polymer
• part of the mineral layers is generally deposited on one of the glasses, the rest on the other glass, and the two glasses are then assembled using of polymer electrolyte film. (You can then leaf through the whole to a third glass with a thermoplastic sheet).
• the active system is therefore, in particular in these two cases, perfectly protected, the glass being a particularly inert material, constituting in particular an excellent barrier to water and gases in general.
• the invention firstly relates to an electrically controllable device with variable optical and / or energy properties of the electrochromic type, device comprising a functional film comprising a layer or a stack of layers.
• This functional film is placed between two external substrates which meet the following criteria: ® - at least one is essentially transparent, ⁇ - at least one is based on one (or a plurality of) films ( s) based on polymer (s),
• each of these two external substrates is a water vapor barrier, with a water vapor permeability of at most 1 g / m 2 / 24h, in particular at most 0.1 g / m 2 / 24h (according to standard NF-T30 018).
• the term "device” in particular means any glazing operating in transmission or in reflection (mirror) in the broad sense of the term, that is to say without necessarily involving a glass substrate. It can be a finished product, usable as it is, or an intermediate product, that is to say a product which can be used and handled as it is, but which is intended to be affixed to another surface, to a glazing conventional for example or a television or computer screen (or to be incorporated into a laminated or multiple glazing structure).
• a finished product usable as it is, or an intermediate product, that is to say a product which can be used and handled as it is, but which is intended to be affixed to another surface, to a glazing conventional for example or a television or computer screen (or to be incorporated into a laminated or multiple glazing structure).
• the term “external substrates” includes the substrates which frame, delimit the device, those of which one of the faces is likely to be in contact with the ambient atmosphere. It may in particular be on the one hand the substrate carrying the functional film (the one on which all or some of the layers which compose it have been deposited) and on the other hand the counter-substrate, that intended to protect the functional film from the opposite side to the carrier substrate. Different configurations will be detailed later.
• the invention therefore consisted in choosing for one of the external substrates at least one polymer-based material rather than glass.
• the advantages of plastic substrates in the broad sense are numerous: they are lighter, break less easily. They make it possible to eliminate a laminating operation between two glasses, an operation requiring heating and pressurizing of the various components considered. They can also take very different forms particular, very pronounced curvatures. They cut to ad hoc dimensions generally easily. However, they do not usually offer the sealing, the inertia that the glass guarantees, and this especially with respect to water, in particular in vapor form. However, it turned out that it was very important that the functional film, especially when it is an electrochromic film, be isolated from the surrounding moisture, in liquid form but also in gaseous form. The invention therefore consisted in selecting polymer substrates which are nevertheless capable of offering a very high water vapor tightness, in any case sufficient not to deteriorate the properties of the functional film.
• one of the two external substrates is the substrate on which at least part of the layers of the functional film, in particular all of the layers, has been deposited, either by contact direct, either through an adhesion layer. It all depends on the type of substrate and the type of layers. Thus, on glass, it is possible to deposit mineral layers directly, by pyrolysis or by cathode sputtering. On the other hand, on polymer-based substrates, it may be necessary to first deposit a layer intended to allow the deposition at the attachment of these mineral layers. This “adhesive” layer can also be very thin, and even discontinuous. It can be grafted onto the surface of the substrate. It can be replaced or supplemented by a surface treatment of the substrate (of the texturing type or others) to which we will return later.
• the functional film can advantageously be one of the electrochromic films described in the preamble to the present application, in particular an “all solid” electrochromic film.
• the invention can however be applied in a similar manner to other electrically controllable systems, of the viologen type, of the electroluminescent type (an example is described in patent FR-2 770 222), of the optical valve type (an example is described in patent WO 93/09460), of the liquid crystal system type (examples of which are described in patents EP-88,126, EP-268,877, EP-238,164, EP-357,234, EP-409,442, EP-964,288). It thus applies to any system / glazing comprising at least one thin layer liable to deteriorate on contact with species gaseous from the ambient atmosphere, especially water vapor.
• one of the exterior substrates is made of glass, it inherently has the required level of water vapor tightness, especially in the usual thicknesses (1 to 8 mm for example).
• the invention proposes several variants so that they also reach the required level.
• At least one of the external substrates comprises a sheet of halogenated polymer, in particular polyhalogenated (containing at least two different types of halogen).
• This type of polymer tends to be hydrophobic, and also to serve as an effective barrier to water vapor.
• PCTFE polychlorotrifluoroethylene
• PCTFE indeed presents a vapor permeability of the order of water from 0.01 to 0.1 g / m 2 / 24h for a thickness of the order of 20 to 300 or 250 micrometers (particularly 100 at 200 micrometers), and it has the great advantage of being transparent.
• this type of polymer also tends to have a low surface energy, which explains why it tends to adhere insufficiently to other materials, in particular here to the materials of the functional film (that the polymer sheet acts as a substrate- carrier or counter substrate). It is therefore advantageous to treat the halogenated polymer sheet, the treatment being intended to increase the surface energy of the material: it is possible to treat only the face intended to be turned towards the functional film, for example by a surface treatment which can consist of a chemical treatment, an electrical treatment by Corona discharge, or any other treatment making it possible to obtain a surface texturing. It can also be provided with an adhesive layer.
• the term “adhesive layer” can be understood to mean a true continuous layer, for example a double-sided adhesive or a so-called adhesive.
• the halogenated polymer film can be made to adhere satisfactorily to the functional film, or even deposit the functional film on the latter, for example by sputtering.
• at least one of the external substrates consists of at least one film based on polymer (s), the permeability of which is lowered to the level required by depositing on at least one of its faces a or more thin mineral layers.
• thin layers of interference thickness, that is to say in particular between 5 nm and 1 ⁇ m, in particular between 10 and 500 nm.
• these layers are chosen to be transparent and sufficiently dense. In addition to their density, it is important to choose them so that they do not present any defect breaking their continuity.
• They can be chosen from silicon derivatives such as silicon oxide, oxycarbide or silicon oxynitride, silicon nitride and / or aluminum derivatives such as oxide, oxynitride or nitride d 'aluminum.
• the layers based on silicon derivatives may also contain a little of a metal such as aluminum or boron (additives making it possible to make the silica target sufficiently conductive in the event of deposition by reactive sputtering in the presence of oxidizing agents and / or nitriding agents).
• doped semiconductor oxides such as layers of indium oxide doped with ITO tin, tin oxide doped for example with Sn0 2 fluorine: F, zinc oxide doped for example with aluminum ZnO: Al.
• These layers can advantageously be deposited, in a known manner, by non-reactive sputtering, using in particular oxide targets, or reactive, using Si targets (doped Al or B for example as mentioned above) or A1 and reactive atmospheres containing, depending on the case, an oxidizing agent and / or a nitriding agent and / or a carbonaceous agent.
• these can also advantageously fulfill the role of electrode within the functional film, having the appropriate characteristics and thickness.
• At least one of the external substrates comprises a nanocomposite film.
• a nanocomposite film By this is meant an organo-mineral composite film, comprising a polymer matrix into which mineral compounds of nanometric size and high form factor have been introduced. These include clay sheared, in a polymer matrix before extrusion, for example. These mineral compounds make it possible to increase the diffusion path of water through the film, and thus to make it more impermeable while retaining most of its transparency, if it is transparent in the absence of the latter. .
• At least one of the external substrates comprises a plurality of films based on polymers of different water vapor permeabilities, the combination of the films making it possible to globally reach the required level of permeability and possibly adhesion. sufficient for the functional film when said external substrate and the functional film are in direct contact.
• the association of several polymer films can be done at the time of manufacture of the device as a whole, or be carried out beforehand, by co-calendering, co-extrusion.
• the device according to the invention has a rigid or semi-rigid structure, with at least one of the two external substrates comprising a glass, a rigid polymer substrate such as polycarbonate PC or polymethacrylate of methyl PMM (if one chooses PMMA or PC rather than glass, one plans to associate it with a barrier with water vapor according to one of the variants exposed above. It can then contain only only one of these rigid substrates, with a configuration of the type: Rigid external substrate 1 / optional adhesive / functional film / optional adhesive / external substrate based on flexible polymer (s) Compared to a configuration with two glasses, l The relief obtained is already quite significant in this configuration.
• a rigid polymer substrate such as polycarbonate PC or polymethacrylate of methyl PMM
• the device according to the invention has a flexible structure, with the two external substrates in the form of film (s) based on flexible polymer (s).
• a whole new type of “glazing” in the broad sense, which we can manipulate, fold, roll up, unroll at will, which opens up the field to many new applications.
• the device according to the invention can have additional functionalities, independently of those conferred by the functional film. It can thus comprise at least one of the following coatings: coating reflecting at least part of the wavelengths located in the infrared (anti-solar or low-emissive coating), hydrophilic or hydrophobic coating, photocatalytic coating with anti-fouling properties (for example comprising Ti0 2 crystallized anatase), an anti-reflective coating, a magnetic shielding coating, etc.
• the device according to the invention can operate in transmission (glazing), or in reflection (mirror).
• one of the external substrates can be reflective or be made reflective using an appropriate coating.
• this type of device can be the aeronautical field, to make portholes, windscreens (for example in the form of a strip only present in the upper part), partitions between different aircraft areas. It can also be in the building sector, for making exterior glazing, doors or partitions, in new buildings or for renovations. It can also be the automotive field, with mirrors, car roofs, glazing and especially the upper part of the windshields, or any other means of air, land (train) or maritime locomotion.
• the devices according to the invention can also be used as a projection or display screen, as a contrast enhancer / anti-glare element for a television screen or computer or mobile phone or any other device. display device.
• the glazing incorporating the device according to the invention may be laminated glazing or multiple glazing of the double-glazing type.
• laminated glazing it may be a conventional laminating with two glass sheets assembled by a sheet of thermoplastic polymer. They can then be functionalized by affixing a protected functional film between two polymer substrates. It can also be a so-called asymmetrical lamination, using a single sheet of glass and at least one sheet of polymer of polyurethane type with energy absorption properties possibly combined with another sheet of polymer with self-healing properties.
• glass (1) conventional clear soda-lime silica glass, thickness 0.5 to 6 mm, here 2.1 mm, dimensions 50 x 50 cm 2 - functional film (2): “all solid” electrochromic system comprising the following stack:> - a lower conducting layer 2, which is a bilayer consisting of a first SiOC layer of 50 nm topped by a second layer of SnO 2 : F of 400 nm (two layers preferably deposited successively by CVD on float glass before cutting), alternatively it may be a bilayer with a first layer of SiON: B of 20 nm topped with a layer of ITO of 150 nm - a first layer of anodic electrochromic material in iridium oxide (hydrated) from 40 to 100 nm or nickel oxide hydrate from 40 nm to 400 n m
• tungsten oxide of 100 nm - a second layer of hydrated tantalum oxide or hydrated silica oxide of 100 nm, alternatively it may be a layer of antimony oxide or zirconium or an alloy with at least one of these oxides (preferably hydrated)
• It can in particular comprise a network of conductive wires in contact with the upper electrode, as described in patent EP-1,078,299.
• the functional film, the PCTFE film and the adhesives are the same as in Example 1, the polycarbonate PC has a thickness of approximately 3 mm (2 to 5 mm).
• Glazing is obtained in which the two outer substrates are rigid, which is essential in certain applications, but possibly lighter than a glazing having two glasses.
• This type of glazing without glass can be used to equip means of transport, in particular in aeronautics and in armored vehicles, because PC and other similar plastic substrates are materials particularly adapted to resist shocks by energy absorption . It can also be advantageously used as a car roof.
• the functional film (2) is the same as in the previous cases, just like the adhesive (3).
• the two outer substrates are PET (polyethylene terephthalate) sheets 100 to 300 micrometers thick. They can be replaced by PC sheets from 0.2 to 1 mm thick.
• PET polyethylene terephthalate
• PC sheets from 0.2 to 1 mm thick.
• a flexible "plastic" glazing which constitutes an interesting intermediate product.
• One possibility is, in a subsequent step, to flip it between two glasses using thermoplastic polymer sheets.
• thermoplastic sheet such as polyvinyl butyral PVB or ethylene vinyl acetate EVA or certain PU polyurethanes
• Glazing flexible plastic according to the invention "/ new thermoplastic sheet / glass (2) or so-called asymmetrical laminated glazings with a single glass and one or more films based on polyurethane with energy absorption function and possibly self-healing ( details on this type of glazing are described in patents EP 132 198, EP 131 523, EP389 354), or glazings with a single glass, where the face of the functional film not facing the glass is protected by a suitable plastic substrate to form a barrier to water in vapor form according to one of the variants of the invention.
• This type of structure is advantageous for replacing glazing requiring laminating for safety reasons.
• Example 3 a flexible electrochromic glazing, without glass, but using as external substrates very efficient films in modified PCTFE, according to the following configuration: modified PCTFE (1) / functional film (2 ) / adhesive (3) / modified PCTFE (4)
• the functional film (2) is the same as in the previous cases, just like the adhesive (3).
• the modified PCTFE has been modified at the surface to increase its surface energy, for example by surface treatment with Corona discharge. Alternatively, it can be co-extruded to a sheet of polymer of the PET type.
• EXAMPLE 5 it is a question of functionalizing a conventional car roof based on a standard laminated glazing of the glass / thermoplastic sheet / glass type, by adding to it the functional film included in a structure of the PCTFE / adhesive / functional film / type. PET type polymer film. In this structure, the functional film is isolated from external humidity on one side by PCTFE and on the other by the laminating of PET to the glazing using a thermoplastic sheet or a double-sided adhesive.
• thermoplastic sheet / glass / thermoplastic or adhesive sheet / PET / functional film / adhesive / PCTFE can comprise stacks of thin layers reflecting the infrared / anti-solar: these layers make it possible to protect, if necessary, the functional film from solar radiation liable to degrade it in the long term. They can also serve to protect, if necessary, the polymer substrates according to their configuration in the glazing. These stacks consist in particular of two silver layers alternated with dielectric coatings. These stacks can be deposited on glass, or on plastic substrates such as PET.
• Patent EP 825 478 describes this type of combination, between an electroactive film of electrochromic type and layers with thermal function.
• the glasses, the functional film, the adhesive and the PCTFE are those used in the previous examples.
• the polymer is such that it has the permeability of at most 1 g / m 2 / 24h desired.
• the configuration of the mirror is: Glass / functional film / reflective layer / adhesive / PCTFE with PCTFE and the adhesive similar to those used in Example 2, and the reflective layer a metal layer, here in aluminum about 50 or 80 nm thick (20 to 100 nm in particular).
• electrochromic mirror This configuration of electrochromic mirror is original: here, the electrochromic system is deposited on the glass, and the reflective layer on the plastic substrate, whereas one generally does the opposite. However, depositing the electroactive system on the glass makes it easier to obtain a mirror of perfect optical quality, an essential point for this application in reflection.
• EXAMPLE 8 This is a mirror similar to that described in Example 7. The difference lies in the way in which the functional film is protected from water vapor: instead of using, on the side of the film opposite glass, a film in
• the reflective aluminum sheet is thickened until it reaches the water vapor permeability required according to the invention: here, it has a thickness of at least several micrometers, in particular at least 5 or 10 micrometers.
• the thickness chosen in this example is 12 micrometers.
• the configuration of the mirror is simplified:
• the composition of the exterior substrates of these glazings can be adapted, especially those made of polymer.

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  • 2001-07-12 FR FR0109315A patent/FR2827396B1/fr not_active Expired - Lifetime
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