WO2003002406A1 - Management of water ballast in marine vessels - Google Patents

Management of water ballast in marine vessels Download PDF

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Publication number
WO2003002406A1
WO2003002406A1 PCT/GB2002/002966 GB0202966W WO03002406A1 WO 2003002406 A1 WO2003002406 A1 WO 2003002406A1 GB 0202966 W GB0202966 W GB 0202966W WO 03002406 A1 WO03002406 A1 WO 03002406A1
Authority
WO
WIPO (PCT)
Prior art keywords
ballast
water
tanks
ballast water
copper
Prior art date
Application number
PCT/GB2002/002966
Other languages
French (fr)
Inventor
David Peters
Original Assignee
Wilson Taylor & Company Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wilson Taylor & Company Ltd filed Critical Wilson Taylor & Company Ltd
Publication of WO2003002406A1 publication Critical patent/WO2003002406A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63JAUXILIARIES ON VESSELS
    • B63J4/00Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for
    • B63J4/004Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for for treating sludge, e.g. tank washing sludge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B57/00Tank or cargo hold cleaning specially adapted for vessels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63JAUXILIARIES ON VESSELS
    • B63J4/00Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for
    • B63J4/002Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for for treating ballast water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4606Treatment of water, waste water, or sewage by electrochemical methods for producing oligodynamic substances to disinfect the water
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B11/00Interior subdivision of hulls
    • B63B11/04Constructional features of bunkers, e.g. structural fuel tanks, or ballast tanks, e.g. with elastic walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B2231/00Material used for some parts or elements, or for particular purposes
    • B63B2231/02Metallic materials
    • B63B2231/10Aluminium or aluminium alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B2231/00Material used for some parts or elements, or for particular purposes
    • B63B2231/02Metallic materials
    • B63B2231/12Copper or copper alloys
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/008Originating from marine vessels, ships and boats, e.g. bilge water or ballast water

Definitions

  • This invention relates to the management of water ballast in marine
  • vessels is a source of bio-contamination of marine and sometimes fresh water
  • ballast water discharges by viable marine organisms Treatment with
  • hypochlorite is effective, but handling the material such as avoiding contact with
  • An object of the invention is to provide a means for preventing damage or casualties should there be any failure.
  • hypochlorite to provide a safer alternative to the use hypochlorite.
  • ballast water in marine vessels includes the steps of admitting ballast water to one or more ballast tanks, subjecting the ballast water during admission to the tank or
  • the invention also provides apparatus for management of ballast water in
  • ballast tanks in a marine vessel, means for admitting ballast water to each of the ballast tanks, means for subjecting the ballast water during admission to the tank or tanks to attain a concentration of
  • non-viable are preferably copper.
  • the copper ions may be maintained at a
  • the copper ions may be released into the water in each ballast tank from
  • the current impressed on the copper alloy anodes is preferably controlled
  • a control circuit may be provided to vary current applied
  • discharging ballast water from the tanks may comprise inlet and outlet ports in
  • the hull of the vessel which are preferably dual purpose , with a coarse screen
  • the copper ion concentration maintained in the ballast tanks is such that
  • Figure 1 is a sectional view of a marine cargo vessel
  • FIG. 1 is a diagram showing the general arrangement of a ballast tank
  • a marine cargo vessel 10 has a hull 11 divided by
  • Ballast tanks 14 are provided in the lower part of the hull 13, and ballast tanks 14 in the lower part of the hull. Ballast tanks 14 are
  • conduits 15 with pumps 16 opening arranged to be filled and discharged by conduits 15 with pumps 16 opening to
  • each ballast tank 14 has an inlet conduit 15, an
  • the top of the tank 14 is
  • a cover 20 closed by a cover 20, through which protrude an array of electrodes, in the form of copper or copper-clad anodes 21. These are connected to a controller 23
  • a combination of CU+ or CU++ ions is preferably in the range of 2 micro
  • ballast water to the tank, to provide a once and for all dose to render bio matter
  • the ion concentration can then be allowed to decline, to render eventual discharge low enough in toxcity to meet environmental standards.
  • the method is applicable not only to use with sea water, but also with

Abstract

In order to reduce risks of bio-contamination being transmitted in ballast water, ballast water in a ballast tank is subjected to copper ions of a concentration such as to render a significant proportion of marine organisms non-viable. The treatment is carried out using copper or copper clad anodes to which current is impressed.

Description

Manaqement of Water Ballast in Marine vessels
This invention relates to the management of water ballast in marine
vessels, particularly for the purpose of limiting the transportation of viable bio-
matter between habitats.
It is now recognised that the discharge of water ballast from marine
vessels is a source of bio-contamination of marine and sometimes fresh water
habits by the introduction of species to foreign environments. This poses a substantial ecological threat, as introduced species can proliferate at the
expense of existing species, or produce vigorous hybrids with local similar species which disturb the balance of the ecology adversely.
This problem is being increasingly recognised, and is summarised in the UNDP and International Marine Organisation leaflet "Stopping the Ballast Water
Stowaway" (March 2001). The program will result in international agreements,
and national legislation which will regulate the discharge of water ballast with the
objective of effectively reducing or preventing the accidental introduction of
invasive species.
Accordingly, it is desirable to be able to provide an effective method and
apparatus for management of water ballast in marine vessels which can meet this objective, and which is not unduly burdensome on ship operators.
Marine organisms almost all have a life cycle stage where they form part
of the zoo-plankton, as larvae or eggs for example. Filtration, however, is not a
viable method of eliminating this material as the pressure drop across a filter medium having a pore size sufficiently small to trap the smallest plankton, such
as eggs, leads to a significant slowing of the intake and/or discharge of water to
or from the ballast tanks, and in addition, the filter elements must be cleared by
removal of filtrate and are also vulnerable to bio-encrustation. It is thus necessary to consider non-mechanical methods of eliminating
viable marine organisms from ballast water and it is an object of the invention to
provide a method and apparatus for management of ballast water in marine
vessels which will effectively eliminate, or substantially reduce contamination of
ballast water discharges by viable marine organisms. Treatment with
hypochlorite is effective, but handling the material such as avoiding contact with
acids, whilst well understood, places a burden on operators and runs the risks of'
damage or casualties should there be any failure. An object of the invention is
to provide a safer alternative to the use hypochlorite.
In accordance with the invention, a method of management of ballast
water in marine vessels includes the steps of admitting ballast water to one or more ballast tanks, subjecting the ballast water during admission to the tank or
tanks to a concentration of metal ions in the water sufficient to render a
significant proportion of marine organisms non-viable, containing the water in
the tanks as required and discharging the ballast water with marine organisms
present in non-viable forms.
The invention also provides apparatus for management of ballast water in
marine vessels comprising one or more ballast tanks in a marine vessel, means for admitting ballast water to each of the ballast tanks, means for subjecting the ballast water during admission to the tank or tanks to attain a concentration of
ions in the water sufficient to render a significant proportion of marine
organisms non-viable, and means for discharging the ballast water from the tank
or tanks with marine organisms present in non-viable forms.
The metal ions provided in the ballast water to render marine organisms
non-viable are preferably copper. The copper ions may be maintained at a
concentration in the water of from 2 micro grams per litre to 100 micro grams per
litre, preferably up to 45 micro grams per litre.
The copper ions may be released into the water in each ballast tank from
a copper device which is immersed in the ballast water.
The current impressed on the copper alloy anodes is preferably controlled
so as to attain a concentration of copper ions in the ballast water within the range of 2 micro grams per litre to 100 micro grams per litre, preferably up to 45
micro grams per litre. A control circuit may be provided to vary current applied
to the anodes to increase or reduce the output of copper ions in direct proportion
to the level of current applied.
The means for admitting ballast water to the ballast tanks, and for
discharging ballast water from the tanks may comprise inlet and outlet ports in
the hull of the vessel, which are preferably dual purpose , with a coarse screen
cover to prevent ingress of large particle size floating or swimming matter or
organisms, conduits connecting the inlet and outlet ports to the ballast tanks, and pumps for impelling the ballast water to fill or empty the ballast tanks.
The copper ion concentration maintained in the ballast tanks is such that
whilst a significant proportion of marine organisms in the tanks are rendered
non-viable (that is either killed, or prevented from growing or reproducing) on
discharge of the ballast water, the concentration will be diluted well below
hazardous levels in the wider marine environment, and also the ions will be
quickly neutralised and thus reduced in effectiveness as a poison.
A preferred method and embodiment of apparatus according to the
invention for management of ballast water in marine vessels will now be
described by way of example, with reference to the accompanying, wherein:-
Figure 1. is a sectional view of a marine cargo vessel;
Figure 2. is a diagram showing the general arrangement of a ballast tank
equipped with means according to the invention.
As shown in Figure 1. , a marine cargo vessel 10 has a hull 11 divided by
internal bulkheads into spaces such as a cargo hold 12, propeller shaft tunnel
13, and ballast tanks 14 in the lower part of the hull. Ballast tanks 14 are
arranged to be filled and discharged by conduits 15 with pumps 16 opening to
the underwater environment at 17. These openings are closed by mesh grills in
the usual way to exclude large sized water borne matter and fish.
As shown in Figure 2., each ballast tank 14 has an inlet conduit 15, an
overflow conduit 18, and an inspection access 19. The top of the tank 14 is
closed by a cover 20, through which protrude an array of electrodes, in the form of copper or copper-clad anodes 21. These are connected to a controller 23
which controls the current supplied to the electrodes in order to attain a
preferred optimum concentration of copper ions in the ballast water during
admission to the tank. A combination of CU+ or CU++ ions is preferably in the range of 2 micro
grams per litre to 100 micro grams per litre, for example about 45 micro grams
per litre. This is sufficient to render a significant proportion of marine organisms
such as algae, larvae, eggs, mirco organisms and other plankton non viable, in
the sense that they either killed or rendered incapable of further development -
ie. eggs will not hatch, nor larvae proceed to the adult stage, or adult organisms
are effectively sterilised. It is to be noted that it is unlikely that even the most
effective biocide will render 100% of all organisms non-viable in every trial.
Typical results in various circumstances range from about half, to well over 90%.
This copper ion concentration is attained at the time of admission of the
ballast water to the tank, to provide a once and for all dose to render bio matter
non viable. The ion concentration can then be allowed to decline, to render eventual discharge low enough in toxcity to meet environmental standards.
By use of this method, it is possible to meet current and expected future
requirements for preventing contamination of environments by accidental
introduction of invasive species from marine vessel ballast water.
The levels of copper ions in discharged ballast water is well below levels
considered to represent even a low level risk, so that the method can be used repeatedly to prevent invasion by foreign species.
The method is applicable not only to use with sea water, but also with
fresh water such as might be taken in on the American great lakes, or inland
ship canals.
Details of the electrode materials are set out below: -
Anode Materials:
Copper: 99.9% pure electrolytic copper C101 as taken from BS2874 C101
ELECTRICALLY TOUGH PITCH HIGH CONDUCTIVITY COPPER.
Chemical Composition
COPPER (Sliver being counted as copper); Not less than 99.09%
Last 0.01% are called impurities. The British standard states the material must
not contain impurities in excess of the amounts stated for:
BISMUTH Not more than 0.0010%
LEAD Not more than 0.005%
TOTAL (Excluding Sliver SOxygen) Not more than 0.03%

Claims

1. A method of management of ballast water in marine vessels
including the step of:-
- admitting ballast water to one or more ballast tanks;
subjecting the ballast water during admission to the tank or tanks to a
concentration of metal wires in the water sufficient to render marine organisms non-viable,
containing the water in the tanks as required; and
- discharging the ballast water with marine organisms present in non-
viable forms.
2. A method according to claim 2 when the metal ions to which the
water is subjected are copper.
3. A method according to claim 2 when the copper ions are maintained
at a concentration in the water of from 2 micrograms per litre to 100
micrograms per litre.
4. A method according to claim 3 wherein the copper ions be
maintained at a concentration of in the order of 45 micrograms per
litre. 5. A method according to claim 2, 3 or 4 wherein the copper ions are
released into the water in each ballast tank from a copper anode
device which is immersed in the ballast water.
. A method according to claim 1 , wherein the ballast water is substantially
diluted on discharge, from the tanks.
7. Apparatus for management of ballast water in marine vessels, comprising
one or more ballast tanks in a marine vessel; means for admitting ballast
water to each of the ballast tank; means for subjecting the ballast water
during admission to the tank or tanks to attain a concentration of ions in
the water sufficient to render marine organisms non-viable, and means
for
discharging the ballast water from the tank or tanks with marine
organisms present in non-viable forms.
8. Apparatus according to claim 7 wherein copper urns are released into the
water by one or more copper alloy anodes immersed in the ballast water.
9. Apparatus according to claim 8 wherein control apparatus is provided to
control the current control impressed upon the alloy anodes to attain a
concentration of copper ions in the ballast water within the range of 2
micrograms per litre to 100 micrograms per litre.
10. Apparatus according to claim 8 wherein the control apparatus comprises
a control circuit to vary current applied to the anodes to increase or reduce the output of copper ions in direct proportion to the level of
current applied.
11.Apparatus according to claim 7 wherein the means for admitting ballast
water to the ballast tanks and for discharging ballast water from the tanks compose inlet and outlet ports on the hull of the vessel, each having a coarse screen cover to prevent ingress of large particle size floating or swimming matter or organisms; conduits connecting the inlet and outlet ports to the ballast tanks and pumps for impelling the ballast water to fill or empty the ballast tanks.
PCT/GB2002/002966 2001-06-29 2002-06-27 Management of water ballast in marine vessels WO2003002406A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0115968A GB0115968D0 (en) 2001-06-29 2001-06-29 Management of water ballast in marine vessels
GB0115968.0 2001-06-29

Publications (1)

Publication Number Publication Date
WO2003002406A1 true WO2003002406A1 (en) 2003-01-09

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ID=9917642

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Application Number Title Priority Date Filing Date
PCT/GB2002/002966 WO2003002406A1 (en) 2001-06-29 2002-06-27 Management of water ballast in marine vessels

Country Status (2)

Country Link
GB (1) GB0115968D0 (en)
WO (1) WO2003002406A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1027928C2 (en) * 2004-12-30 2006-07-03 Dirk Peter Makkinje Ballast water control valve provides for selective coupling of pump to ballast tank of sea-going vessel and has displaceable valve body in valve chamber
WO2006099915A1 (en) * 2005-03-24 2006-09-28 Hydac Process Technology Gmbh Filter installation and method for operating one such filter installation
WO2009129670A1 (en) 2008-04-23 2009-10-29 青岛海德威船舶科技有限公司 A micro-current electrolysis sterilization algaecide device and method
WO2011120250A1 (en) 2010-03-30 2011-10-06 青岛海德威科技有限公司 Method and system for ship ballast water treatment
KR101280537B1 (en) * 2011-11-08 2013-07-02 삼성중공업 주식회사 Marine growth preventing system and sea water supplying system and ship having the same
CN104058535A (en) * 2014-07-17 2014-09-24 上海船研环保技术有限公司 Ship ballast water treatment system with biologic resurgence inhibition function

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB794698A (en) * 1956-09-11 1958-05-07 Dow Chemical Co Galvanic anode installation
GB2118972A (en) * 1982-04-21 1983-11-09 Elinca Limited Marine antifouling system
EP1000852A1 (en) * 1998-11-09 2000-05-17 Brunswick Corporation Apparatus and method for inhibiting fouling of an underwater surface
WO2000078605A1 (en) * 1999-06-17 2000-12-28 Scharf Eva Maria Method and device for preventing organism growth on sea-cases and seawater systems on ships, offshore platforms, etc.
EP1084948A1 (en) * 1999-09-17 2001-03-21 Magnus Kvant Method for inhibiting fouling of an underwater surface

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB794698A (en) * 1956-09-11 1958-05-07 Dow Chemical Co Galvanic anode installation
GB2118972A (en) * 1982-04-21 1983-11-09 Elinca Limited Marine antifouling system
EP1000852A1 (en) * 1998-11-09 2000-05-17 Brunswick Corporation Apparatus and method for inhibiting fouling of an underwater surface
WO2000078605A1 (en) * 1999-06-17 2000-12-28 Scharf Eva Maria Method and device for preventing organism growth on sea-cases and seawater systems on ships, offshore platforms, etc.
EP1084948A1 (en) * 1999-09-17 2001-03-21 Magnus Kvant Method for inhibiting fouling of an underwater surface

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1027928C2 (en) * 2004-12-30 2006-07-03 Dirk Peter Makkinje Ballast water control valve provides for selective coupling of pump to ballast tank of sea-going vessel and has displaceable valve body in valve chamber
WO2006099915A1 (en) * 2005-03-24 2006-09-28 Hydac Process Technology Gmbh Filter installation and method for operating one such filter installation
US7691274B2 (en) 2005-03-24 2010-04-06 Hydac Process Technology Gmbh Filter installation and method for operating one such filter installation
WO2009129670A1 (en) 2008-04-23 2009-10-29 青岛海德威船舶科技有限公司 A micro-current electrolysis sterilization algaecide device and method
WO2011120250A1 (en) 2010-03-30 2011-10-06 青岛海德威科技有限公司 Method and system for ship ballast water treatment
KR101280537B1 (en) * 2011-11-08 2013-07-02 삼성중공업 주식회사 Marine growth preventing system and sea water supplying system and ship having the same
CN104058535A (en) * 2014-07-17 2014-09-24 上海船研环保技术有限公司 Ship ballast water treatment system with biologic resurgence inhibition function

Also Published As

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