WO2002101104A1 - Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby - Google Patents
Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby Download PDFInfo
- Publication number
- WO2002101104A1 WO2002101104A1 PCT/IT2002/000358 IT0200358W WO02101104A1 WO 2002101104 A1 WO2002101104 A1 WO 2002101104A1 IT 0200358 W IT0200358 W IT 0200358W WO 02101104 A1 WO02101104 A1 WO 02101104A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composite material
- titanium alloy
- production
- based composite
- alloy based
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1094—Alloys containing non-metals comprising an after-treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Definitions
- the present invention refers to the production of components obtained from Titanium alloy based components, to be used in the field of mechanics and of high temperature automotives in the presence of creep and of high specific stresses.
- EP-0 215 941 (Dynamet) teaches the manufacturing, by blending and sintering, of Titanium-based composite materials including a dispersion of Titanium carbide (TiC) powder.
- TiC Titanium carbide
- the end product obtained is free of a significant reaction at the TiC- matrix interface or of dilution regions exhibiting a composition gradient.
- the main restriction of this US process is that the product obtained has an interface exhibiting scarce chemical reaction, and therefore where the stresses are accordingly transferred by mechanical mechanisms.
- exposure to high temperatures fosters grain growth, a phenomenon that worsens the mechanical properties, especially the fatigue strength.
- object of the present invention is a process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature, wherein a Titanium alloy powder and a Titanium carbide powder are blended, hot-compacted and hot-rolled or extruded.
- the TiC content can range from 0.5 to 30% b/w.
- the granulometry of the Titanium alloy can be ⁇ 250 ⁇ m, preferably ⁇ 5 ⁇ m.
- the blending of the two powders may be carried out in the presence of the 50% b/v acetone (or other anti-clumping agent), optionally added separately to each one of the powders to be blended, prior to blending.
- the powder blending may be carried out under inert gas, e.g., Argon, atmosphere.
- the blending may be obtained by revolving in a vessel, containing the two powder types, at a high rate of rpm for a time ranging from 5 minutes to 8 hours.
- the hot compacting may be obtained by hot isostatic pressing (HIP) at temperatures ranging from 850 to 950°C, at pressures ranging from 80 to 130 MPa, for ⁇ 4 h times.
- the powders thus blended can be dried substantially under vacuum.
- the material resulting from the hot pressing is preferably heated to a temperature of about 1000°C and pressed to a thickness reduction of from 5 to 50%.
- the yielded pressed product is rolled, at temperatures comprised in the range 800-
- the process according to the present invention allows an optimum distribution of the TiC particulate and the diffusion thereof at the interface with the Titanium alloy matrix.
- the diffusion is measured from a Carbon (C) content of about 20% at 20 ⁇ m from a
- the carbon diffusion obtained by TiC particles/Titanium alloy matrix interface reaction is controlled via the thermal treatment of hot compacting.
- a 960°C temperature should be applied for 3 h with pressures of about 1100 MPa.
- Titanium carbide agglomerates These carbides, very uniformly dispersed, allow to overcome brittleness problems at room temperature, with breakaway of the bonds at the old particle edges in the unrolled material.
- the measured strength values are about 20-30% higher than those of the composite alloy of EP 0 215 941. This advantageous result could also be accounted for by the fact that inside of the matrix an evident dilution of the TiC has occurred, with a C concentration profile that drops from about the 50%, measured at the centre of a TiC particle, and stabilizes, after about 20 ⁇ m, to values of about 5%, measured also at about 60 ⁇ m from the edge of the TiC particle.
- Titanium alloys that yielded satisfactory results as matrices in the compounds according to the present invention are the following: Ti6A14V, Ti6A12Sn4Zr2MoO. ISi, Til5A13V3Sn3Cr, and Ti6242S.
- the present invention also refers to the composite material obtainable with the hereto-described process.
- Figure 1 shows the microstructure of an embodiment of the homogeneous blend of
- Titanium alloy powder and TiC powder prior to the hot compacting.
- Figure 2 shows the increase of the mechanical properties, at ⁇ 600°C temperatures, of a compound obtained with an embodiment of the process according to the invention with respect to the material obtained with the same powders by sintering and hot compacting.
- the powders to be blended according to the invention are prepared by gas atomizing from 500 mm high, 45 mm 0 ingots. The end sizes of the particles obtained are
- Titanium carbide
- Table 1 shows the composition of the Titanium alloy powder with respect to that of the starting ingot.
- the Table also reports the average size (in ⁇ m) of the Ti6242S powder, the flow rate and the size (in ⁇ m) of the TiC particles.
- Ti6242S and TiC powders are blended in a rotary cylinder with movable blades, instead of resorting to a mechanical alloying that produces more superficial fractures and, therefore, more reaction sites with C, O, N.
- This procedure, as well as the mechanical alloying, provides optimum reinforcing material/matrix homogeneousness.
- Figure 1 shows the 200x SEM (Scanning Electron Microscopy) microphotography of the homogenate blend.
- the blended powders are introduced in a steel cylinder that is sealed and welded to the lid by TIG (Tungsten Inert Gas) welding.
- the cylinder lid is provided with a port and a piping for carrying out the evacuation.
- the cylinder-shaped container was designed in order to resist fractures during the HIP process.
- the evacuation takes place with a rotary pump, obtaining vacuums in the order of 10 "5 mBar.
- the powder is isostatically pressed, with no prior consolidation, for 5 h at a 1000°C temperature and with a pressure peak of 1500 Bar. Then, tensile test samples of the yielded composite material are obtained, with their axes parallel to the cylinder generatrix. After heating to 1100°C, the composite material is hot-rolled, with an 80% thickness reduction.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02743624A EP1407055A1 (en) | 2001-06-08 | 2002-06-03 | Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby |
US10/479,881 US20050008524A1 (en) | 2001-06-08 | 2002-06-03 | Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITRM2001A000320 | 2001-06-08 | ||
IT2001RM000320A ITRM20010320A1 (en) | 2001-06-08 | 2001-06-08 | PROCEDURE FOR THE PRODUCTION OF A TITANIUM ALLOY COMPOSITE REINFORCED WITH TITANIUM CARBIDE, AND REINFORCED COMPOSITE SO OCT |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002101104A1 true WO2002101104A1 (en) | 2002-12-19 |
Family
ID=11455579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IT2002/000358 WO2002101104A1 (en) | 2001-06-08 | 2002-06-03 | Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby |
Country Status (4)
Country | Link |
---|---|
US (1) | US20050008524A1 (en) |
EP (1) | EP1407055A1 (en) |
IT (1) | ITRM20010320A1 (en) |
WO (1) | WO2002101104A1 (en) |
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US20080101977A1 (en) * | 2005-04-28 | 2008-05-01 | Eason Jimmy W | Sintered bodies for earth-boring rotary drill bits and methods of forming the same |
US20050211475A1 (en) | 2004-04-28 | 2005-09-29 | Mirchandani Prakash K | Earth-boring bits |
US9428822B2 (en) | 2004-04-28 | 2016-08-30 | Baker Hughes Incorporated | Earth-boring tools and components thereof including material having hard phase in a metallic binder, and metallic binder compositions for use in forming such tools and components |
US20060024140A1 (en) * | 2004-07-30 | 2006-02-02 | Wolff Edward C | Removable tap chasers and tap systems including the same |
US7513320B2 (en) * | 2004-12-16 | 2009-04-07 | Tdy Industries, Inc. | Cemented carbide inserts for earth-boring bits |
US8637127B2 (en) | 2005-06-27 | 2014-01-28 | Kennametal Inc. | Composite article with coolant channels and tool fabrication method |
US7687156B2 (en) | 2005-08-18 | 2010-03-30 | Tdy Industries, Inc. | Composite cutting inserts and methods of making the same |
US7703555B2 (en) | 2005-09-09 | 2010-04-27 | Baker Hughes Incorporated | Drilling tools having hardfacing with nickel-based matrix materials and hard particles |
US7597159B2 (en) * | 2005-09-09 | 2009-10-06 | Baker Hughes Incorporated | Drill bits and drilling tools including abrasive wear-resistant materials |
US7776256B2 (en) | 2005-11-10 | 2010-08-17 | Baker Huges Incorporated | Earth-boring rotary drill bits and methods of manufacturing earth-boring rotary drill bits having particle-matrix composite bit bodies |
US8002052B2 (en) * | 2005-09-09 | 2011-08-23 | Baker Hughes Incorporated | Particle-matrix composite drill bits with hardfacing |
US7997359B2 (en) | 2005-09-09 | 2011-08-16 | Baker Hughes Incorporated | Abrasive wear-resistant hardfacing materials, drill bits and drilling tools including abrasive wear-resistant hardfacing materials |
US7807099B2 (en) | 2005-11-10 | 2010-10-05 | Baker Hughes Incorporated | Method for forming earth-boring tools comprising silicon carbide composite materials |
US8770324B2 (en) | 2008-06-10 | 2014-07-08 | Baker Hughes Incorporated | Earth-boring tools including sinterbonded components and partially formed tools configured to be sinterbonded |
US7784567B2 (en) * | 2005-11-10 | 2010-08-31 | Baker Hughes Incorporated | Earth-boring rotary drill bits including bit bodies comprising reinforced titanium or titanium-based alloy matrix materials, and methods for forming such bits |
US7802495B2 (en) * | 2005-11-10 | 2010-09-28 | Baker Hughes Incorporated | Methods of forming earth-boring rotary drill bits |
US8312941B2 (en) | 2006-04-27 | 2012-11-20 | TDY Industries, LLC | Modular fixed cutter earth-boring bits, modular fixed cutter earth-boring bit bodies, and related methods |
CA2662966C (en) | 2006-08-30 | 2012-11-13 | Baker Hughes Incorporated | Methods for applying wear-resistant material to exterior surfaces of earth-boring tools and resulting structures |
US8007922B2 (en) | 2006-10-25 | 2011-08-30 | Tdy Industries, Inc | Articles having improved resistance to thermal cracking |
US7846551B2 (en) | 2007-03-16 | 2010-12-07 | Tdy Industries, Inc. | Composite articles |
US8790439B2 (en) | 2008-06-02 | 2014-07-29 | Kennametal Inc. | Composite sintered powder metal articles |
CN102112642B (en) * | 2008-06-02 | 2013-11-06 | Tdy工业有限责任公司 | Cemented carbide-metallic alloy composites |
US8261632B2 (en) | 2008-07-09 | 2012-09-11 | Baker Hughes Incorporated | Methods of forming earth-boring drill bits |
US8025112B2 (en) | 2008-08-22 | 2011-09-27 | Tdy Industries, Inc. | Earth-boring bits and other parts including cemented carbide |
US8322465B2 (en) | 2008-08-22 | 2012-12-04 | TDY Industries, LLC | Earth-boring bit parts including hybrid cemented carbides and methods of making the same |
US8272816B2 (en) | 2009-05-12 | 2012-09-25 | TDY Industries, LLC | Composite cemented carbide rotary cutting tools and rotary cutting tool blanks |
US8201610B2 (en) | 2009-06-05 | 2012-06-19 | Baker Hughes Incorporated | Methods for manufacturing downhole tools and downhole tool parts |
US8308096B2 (en) | 2009-07-14 | 2012-11-13 | TDY Industries, LLC | Reinforced roll and method of making same |
US9643236B2 (en) * | 2009-11-11 | 2017-05-09 | Landis Solutions Llc | Thread rolling die and method of making same |
US8490674B2 (en) | 2010-05-20 | 2013-07-23 | Baker Hughes Incorporated | Methods of forming at least a portion of earth-boring tools |
WO2011146760A2 (en) | 2010-05-20 | 2011-11-24 | Baker Hughes Incorporated | Methods of forming at least a portion of earth-boring tools, and articles formed by such methods |
CA2799906A1 (en) | 2010-05-20 | 2011-11-24 | Baker Hughes Incorporated | Methods of forming at least a portion of earth-boring tools, and articles formed by such methods |
US8800848B2 (en) | 2011-08-31 | 2014-08-12 | Kennametal Inc. | Methods of forming wear resistant layers on metallic surfaces |
US9016406B2 (en) | 2011-09-22 | 2015-04-28 | Kennametal Inc. | Cutting inserts for earth-boring bits |
US20130260166A1 (en) * | 2012-04-02 | 2013-10-03 | Kennametal Inc. | Coated Titanium Alloy Surfaces |
RU2492256C9 (en) * | 2012-05-16 | 2013-12-10 | Сергей Валерьевич Панин | Pure titanium-based nanostructured composite and method of its production |
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US3756787A (en) * | 1970-11-20 | 1973-09-04 | Tno | Sistant objects manufactured from this hard metal method for preparing hard metal based on titanium carbide and wear re |
WO1986004930A1 (en) * | 1985-02-22 | 1986-08-28 | Dynamet Technology Inc. | Titanium carbide/titanium alloy composite and process for powder metal cladding |
JPH042742A (en) * | 1990-04-19 | 1992-01-07 | Fuso Off Service:Kk | Composite titanium alloy, multilayered titanium material, titanium cutter and their manufacture |
US5145506A (en) * | 1984-07-05 | 1992-09-08 | The United States Of America As Represented By The Secretary Of The Navy | Method of bonding metal carbides in non-magnetic alloy matrix |
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US4906430A (en) * | 1988-07-29 | 1990-03-06 | Dynamet Technology Inc. | Titanium diboride/titanium alloy metal matrix microcomposite material and process for powder metal cladding |
US5799238A (en) * | 1995-06-14 | 1998-08-25 | The United States Of America As Represented By The United States Department Of Energy | Method of making multilayered titanium ceramic composites |
US5897830A (en) * | 1996-12-06 | 1999-04-27 | Dynamet Technology | P/M titanium composite casting |
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2001
- 2001-06-08 IT IT2001RM000320A patent/ITRM20010320A1/en unknown
-
2002
- 2002-06-03 EP EP02743624A patent/EP1407055A1/en not_active Withdrawn
- 2002-06-03 WO PCT/IT2002/000358 patent/WO2002101104A1/en not_active Application Discontinuation
- 2002-06-03 US US10/479,881 patent/US20050008524A1/en not_active Abandoned
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US3756787A (en) * | 1970-11-20 | 1973-09-04 | Tno | Sistant objects manufactured from this hard metal method for preparing hard metal based on titanium carbide and wear re |
US5145506A (en) * | 1984-07-05 | 1992-09-08 | The United States Of America As Represented By The Secretary Of The Navy | Method of bonding metal carbides in non-magnetic alloy matrix |
WO1986004930A1 (en) * | 1985-02-22 | 1986-08-28 | Dynamet Technology Inc. | Titanium carbide/titanium alloy composite and process for powder metal cladding |
JPH042742A (en) * | 1990-04-19 | 1992-01-07 | Fuso Off Service:Kk | Composite titanium alloy, multilayered titanium material, titanium cutter and their manufacture |
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Also Published As
Publication number | Publication date |
---|---|
ITRM20010320A0 (en) | 2001-06-08 |
US20050008524A1 (en) | 2005-01-13 |
ITRM20010320A1 (en) | 2002-12-09 |
EP1407055A1 (en) | 2004-04-14 |
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