EP1407055A1 - Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby - Google Patents
Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained therebyInfo
- Publication number
- EP1407055A1 EP1407055A1 EP02743624A EP02743624A EP1407055A1 EP 1407055 A1 EP1407055 A1 EP 1407055A1 EP 02743624 A EP02743624 A EP 02743624A EP 02743624 A EP02743624 A EP 02743624A EP 1407055 A1 EP1407055 A1 EP 1407055A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composite material
- titanium alloy
- production
- based composite
- alloy based
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1094—Alloys containing non-metals comprising an after-treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Definitions
- the present invention refers to the production of components obtained from Titanium alloy based components, to be used in the field of mechanics and of high temperature automotives in the presence of creep and of high specific stresses.
- EP-0 215 941 (Dynamet) teaches the manufacturing, by blending and sintering, of Titanium-based composite materials including a dispersion of Titanium carbide (TiC) powder.
- TiC Titanium carbide
- the end product obtained is free of a significant reaction at the TiC- matrix interface or of dilution regions exhibiting a composition gradient.
- the main restriction of this US process is that the product obtained has an interface exhibiting scarce chemical reaction, and therefore where the stresses are accordingly transferred by mechanical mechanisms.
- exposure to high temperatures fosters grain growth, a phenomenon that worsens the mechanical properties, especially the fatigue strength.
- object of the present invention is a process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature, wherein a Titanium alloy powder and a Titanium carbide powder are blended, hot-compacted and hot-rolled or extruded.
- the TiC content can range from 0.5 to 30% b/w.
- the granulometry of the Titanium alloy can be ⁇ 250 ⁇ m, preferably ⁇ 5 ⁇ m.
- the blending of the two powders may be carried out in the presence of the 50% b/v acetone (or other anti-clumping agent), optionally added separately to each one of the powders to be blended, prior to blending.
- the powder blending may be carried out under inert gas, e.g., Argon, atmosphere.
- the blending may be obtained by revolving in a vessel, containing the two powder types, at a high rate of rpm for a time ranging from 5 minutes to 8 hours.
- the hot compacting may be obtained by hot isostatic pressing (HIP) at temperatures ranging from 850 to 950°C, at pressures ranging from 80 to 130 MPa, for ⁇ 4 h times.
- the powders thus blended can be dried substantially under vacuum.
- the material resulting from the hot pressing is preferably heated to a temperature of about 1000°C and pressed to a thickness reduction of from 5 to 50%.
- the yielded pressed product is rolled, at temperatures comprised in the range 800-
- the process according to the present invention allows an optimum distribution of the TiC particulate and the diffusion thereof at the interface with the Titanium alloy matrix.
- the diffusion is measured from a Carbon (C) content of about 20% at 20 ⁇ m from a
- the carbon diffusion obtained by TiC particles/Titanium alloy matrix interface reaction is controlled via the thermal treatment of hot compacting.
- a 960°C temperature should be applied for 3 h with pressures of about 1100 MPa.
- Titanium carbide agglomerates These carbides, very uniformly dispersed, allow to overcome brittleness problems at room temperature, with breakaway of the bonds at the old particle edges in the unrolled material.
- the measured strength values are about 20-30% higher than those of the composite alloy of EP 0 215 941. This advantageous result could also be accounted for by the fact that inside of the matrix an evident dilution of the TiC has occurred, with a C concentration profile that drops from about the 50%, measured at the centre of a TiC particle, and stabilizes, after about 20 ⁇ m, to values of about 5%, measured also at about 60 ⁇ m from the edge of the TiC particle.
- Titanium alloys that yielded satisfactory results as matrices in the compounds according to the present invention are the following: Ti6A14V, Ti6A12Sn4Zr2MoO. ISi, Til5A13V3Sn3Cr, and Ti6242S.
- the present invention also refers to the composite material obtainable with the hereto-described process.
- Figure 1 shows the microstructure of an embodiment of the homogeneous blend of
- Titanium alloy powder and TiC powder prior to the hot compacting.
- Figure 2 shows the increase of the mechanical properties, at ⁇ 600°C temperatures, of a compound obtained with an embodiment of the process according to the invention with respect to the material obtained with the same powders by sintering and hot compacting.
- the powders to be blended according to the invention are prepared by gas atomizing from 500 mm high, 45 mm 0 ingots. The end sizes of the particles obtained are
- Titanium carbide
- Table 1 shows the composition of the Titanium alloy powder with respect to that of the starting ingot.
- the Table also reports the average size (in ⁇ m) of the Ti6242S powder, the flow rate and the size (in ⁇ m) of the TiC particles.
- Ti6242S and TiC powders are blended in a rotary cylinder with movable blades, instead of resorting to a mechanical alloying that produces more superficial fractures and, therefore, more reaction sites with C, O, N.
- This procedure, as well as the mechanical alloying, provides optimum reinforcing material/matrix homogeneousness.
- Figure 1 shows the 200x SEM (Scanning Electron Microscopy) microphotography of the homogenate blend.
- the blended powders are introduced in a steel cylinder that is sealed and welded to the lid by TIG (Tungsten Inert Gas) welding.
- the cylinder lid is provided with a port and a piping for carrying out the evacuation.
- the cylinder-shaped container was designed in order to resist fractures during the HIP process.
- the evacuation takes place with a rotary pump, obtaining vacuums in the order of 10 "5 mBar.
- the powder is isostatically pressed, with no prior consolidation, for 5 h at a 1000°C temperature and with a pressure peak of 1500 Bar. Then, tensile test samples of the yielded composite material are obtained, with their axes parallel to the cylinder generatrix. After heating to 1100°C, the composite material is hot-rolled, with an 80% thickness reduction.
Abstract
Object of the present invention is a process for the production of a Titanium alloy based composite material with satisfactory mechanical features at high temperature, characterised in that Titanium alloy powders and Titanium carbide powders are blended, hot-pressed and hot-rolled or extruded. The invention also encompasses a composite material obtainable with said process.
Description
"PROCESS FOR THE PRODUCTION OF A TΓΓANIUM ALLOY BASED
COMPOSITE MATERIAL REINFORCED WITH TITANIUM CARBIDE, AND
REINFORCED COMPOSITE MATERIAL OBTAINED THEREBY"
DESCRIPTION The present invention refers to the production of components obtained from Titanium alloy based components, to be used in the field of mechanics and of high temperature automotives in the presence of creep and of high specific stresses. EP-0 215 941 (Dynamet) teaches the manufacturing, by blending and sintering, of Titanium-based composite materials including a dispersion of Titanium carbide (TiC) powder. The end product obtained is free of a significant reaction at the TiC- matrix interface or of dilution regions exhibiting a composition gradient. The main restriction of this US process is that the product obtained has an interface exhibiting scarce chemical reaction, and therefore where the stresses are accordingly transferred by mechanical mechanisms. Moreover, exposure to high temperatures fosters grain growth, a phenomenon that worsens the mechanical properties, especially the fatigue strength.
Therefore, in the specific field there subsists the demand for a manufacturing process allowing to overcome the abovementioned drawbacks. The process subject of the present invention surmounts all of the abovementioned drawbacks, further providing other advantages that will be mentioned hereinafter.
In fact, object of the present invention is a process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature, wherein a Titanium alloy powder and a Titanium carbide powder are blended, hot-compacted and hot-rolled or extruded. The TiC content (concentration) can range from 0.5 to 30% b/w.
The granulometry of the Titanium alloy can be <250 μm, preferably <5 μm. The blending of the two powders may be carried out in the presence of the 50% b/v acetone (or other anti-clumping agent), optionally added separately to each one of the powders to be blended, prior to blending. The powder blending may be carried out under inert gas, e.g., Argon, atmosphere.
The blending may be obtained by revolving in a vessel, containing the two powder types, at a high rate of rpm for a time ranging from 5 minutes to 8 hours. The hot compacting may be obtained by hot isostatic pressing (HIP) at temperatures ranging from 850 to 950°C, at pressures ranging from 80 to 130 MPa, for <4 h times. The powders thus blended can be dried substantially under vacuum.
The material resulting from the hot pressing is preferably heated to a temperature of about 1000°C and pressed to a thickness reduction of from 5 to 50%.
The yielded pressed product is rolled, at temperatures comprised in the range 800-
1000°C, with <5% reduction passages, down to the desirable total thickness reduction, e.g. of about 80%.
The process according to the present invention allows an optimum distribution of the TiC particulate and the diffusion thereof at the interface with the Titanium alloy matrix.
The diffusion is measured from a Carbon (C) content of about 20% at 20 μm from a
TiC particle.
The carbon diffusion obtained by TiC particles/Titanium alloy matrix interface reaction is controlled via the thermal treatment of hot compacting.
In particular, in order to obtain a C content of about 17% in atom percent, at a 20-μm distance from a TiC particle, a 960°C temperature should be applied for 3 h with pressures of about 1100 MPa.
This significant dissolving of the TiC inside of the Titanium alloy matrix is accountable for the increase of the mechanical properties attained with the present invention.
With respect to the composite material disclosed in EP 0 215 941, for the composite material of the present invention the rolling step advantageously suffices to eliminate
Titanium carbide agglomerates; these carbides, very uniformly dispersed, allow to overcome brittleness problems at room temperature, with breakaway of the bonds at the old particle edges in the unrolled material. The measured strength values are about 20-30% higher than those of the composite alloy of EP 0 215 941. This advantageous result could also be accounted for by the fact that inside of the matrix an evident dilution of the TiC has occurred, with a C concentration profile that drops from about the 50%, measured at the centre of a TiC particle, and stabilizes, after about 20 μm, to values of about 5%, measured also at about 60 μm from the edge of the TiC particle.
The Titanium alloys that yielded satisfactory results as matrices in the compounds according to the present invention are the following: Ti6A14V, Ti6A12Sn4Zr2MoO. ISi, Til5A13V3Sn3Cr, and Ti6242S.
The present invention also refers to the composite material obtainable with the hereto-described process.
So far, a general description of the present invention was given. With the aid of the attached figures and of the following example, a more detailed description of specific embodiments of the invention, aimed at making better understood the objects, the features, the advantages and the operation modes thereof will be provided hereinafter.
Figure 1 shows the microstructure of an embodiment of the homogeneous blend of
Titanium alloy powder and TiC powder, prior to the hot compacting.
Figure 2 shows the increase of the mechanical properties, at <600°C temperatures, of a compound obtained with an embodiment of the process according to the invention with respect to the material obtained with the same powders by sintering and hot compacting.
EXAMPLE
The powders to be blended according to the invention are prepared by gas atomizing from 500 mm high, 45 mm 0 ingots. The end sizes of the particles obtained are
<200 μm for the Ti6242S alloy, utilized in the example, and <10 μm for the
Titanium carbide.
Table 1 shows the composition of the Titanium alloy powder with respect to that of the starting ingot. The Table also reports the average size (in μm) of the Ti6242S powder, the flow rate and the size (in μm) of the TiC particles.
Table 1
Ti6242S Alloy Al Sn Zn Mo O N H
% % % % ppm ppm ppm
Pre-atomizing samples 6.1 1.4 3.7 1.6 646 218 nd
Powder samples 6.3 1.3 3.8 1.7 1096 496 90
Ti6242S and TiC powders are blended in a rotary cylinder with movable blades, instead of resorting to a mechanical alloying that produces more superficial fractures and, therefore, more reaction sites with C, O, N. This procedure, as well as the mechanical alloying, provides optimum reinforcing material/matrix homogeneousness. Figure 1 shows the 200x SEM (Scanning Electron Microscopy) microphotography of the homogenate blend.
Then, the blended powders are introduced in a steel cylinder that is sealed and
welded to the lid by TIG (Tungsten Inert Gas) welding. The cylinder lid is provided with a port and a piping for carrying out the evacuation. The cylinder-shaped container was designed in order to resist fractures during the HIP process. The evacuation takes place with a rotary pump, obtaining vacuums in the order of 10"5 mBar.
Post-evacuation, the powder is isostatically pressed, with no prior consolidation, for 5 h at a 1000°C temperature and with a pressure peak of 1500 Bar. Then, tensile test samples of the yielded composite material are obtained, with their axes parallel to the cylinder generatrix. After heating to 1100°C, the composite material is hot-rolled, with an 80% thickness reduction.
Samples of the rolled material thus obtained are subjected to tensile tests. The test results highlight an increase of the tensile strength of the material at <600°C temperatures and a decrease of this parameter at >600°C temperatures. Figure 2 shows the increase of the mechanical properties of the rolled composite material of the invention with respect to that of the material merely sinterized and compacted by HIP.
Claims
1. A process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature, characterised in that a Titanium alloy powder and a Titanium carbide powder are blended, hot-compacted and hot- rolled, or extruded.
2. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 1, wherein the concentration of the Titanium carbide expressed in % b/w ranges from 0.5 to 30%.
3. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 1 or 2, wherein the granulometry of the Titanium alloy is <250 μm.
4. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to any one of the preceding claims, wherein the granulometry of the Titanium carbide is <5 μm.
5. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to any one of the preceding claims, wherein the blending of the two powders is carried out in the presence of 50% b/v acetone, or of other anti-clumping agent, optionally added separately to each of the powders to be blended.
6. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to any one of the preceding claims, wherein the blending of the two powders is carried out under inert gas, preferably Argon, atmosphere.
7. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 6, wherein the blending is obtained by revolving a vessel, containing the two powders, at a high rate of rpm for a time ranging from 5 min to 8 h.
8. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 7, wherein the blended powders are dried under vacuum.
9. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to any one of the preceding claims, wherein the hot compacting is obtained by isostatic hot pressing at temperatures ranging from 850 to 950°C, at pressures ranging from 80 to
130 MPa, for <4h times.
10. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 9, wherein the resulting material is heated to a temperature of about 1000°C and pressed to a thickness reduction of from 5 to 50%.
11. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to any one of the preceding claims, wherein the resulting compound is hot-rolled in the range from 800 to 1000°C with <5% reduction passages, down to the desirable total thickness reduction.
12. The process for the production of a Titanium alloy based composite material having satisfactory mechanical features at high temperature according to claim 11, wherein the total thickness reduction is of about 80%.
13. A Titanium alloy based composite material reinforced with Titanium carbide, characterised in that it is obtainable with the process of claims 1 to 12.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2001RM000320A ITRM20010320A1 (en) | 2001-06-08 | 2001-06-08 | PROCEDURE FOR THE PRODUCTION OF A TITANIUM ALLOY COMPOSITE REINFORCED WITH TITANIUM CARBIDE, AND REINFORCED COMPOSITE SO OCT |
ITRM20010320 | 2001-06-08 | ||
PCT/IT2002/000358 WO2002101104A1 (en) | 2001-06-08 | 2002-06-03 | Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1407055A1 true EP1407055A1 (en) | 2004-04-14 |
Family
ID=11455579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02743624A Withdrawn EP1407055A1 (en) | 2001-06-08 | 2002-06-03 | Process for the production of a titanium alloy based composite material reinforced with titanium carbide, and reinforced composite material obtained thereby |
Country Status (4)
Country | Link |
---|---|
US (1) | US20050008524A1 (en) |
EP (1) | EP1407055A1 (en) |
IT (1) | ITRM20010320A1 (en) |
WO (1) | WO2002101104A1 (en) |
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US20080101977A1 (en) * | 2005-04-28 | 2008-05-01 | Eason Jimmy W | Sintered bodies for earth-boring rotary drill bits and methods of forming the same |
US9428822B2 (en) | 2004-04-28 | 2016-08-30 | Baker Hughes Incorporated | Earth-boring tools and components thereof including material having hard phase in a metallic binder, and metallic binder compositions for use in forming such tools and components |
US20050211475A1 (en) | 2004-04-28 | 2005-09-29 | Mirchandani Prakash K | Earth-boring bits |
US20060024140A1 (en) * | 2004-07-30 | 2006-02-02 | Wolff Edward C | Removable tap chasers and tap systems including the same |
US7513320B2 (en) * | 2004-12-16 | 2009-04-07 | Tdy Industries, Inc. | Cemented carbide inserts for earth-boring bits |
US8637127B2 (en) | 2005-06-27 | 2014-01-28 | Kennametal Inc. | Composite article with coolant channels and tool fabrication method |
US7687156B2 (en) | 2005-08-18 | 2010-03-30 | Tdy Industries, Inc. | Composite cutting inserts and methods of making the same |
US7597159B2 (en) | 2005-09-09 | 2009-10-06 | Baker Hughes Incorporated | Drill bits and drilling tools including abrasive wear-resistant materials |
US8002052B2 (en) * | 2005-09-09 | 2011-08-23 | Baker Hughes Incorporated | Particle-matrix composite drill bits with hardfacing |
US7703555B2 (en) | 2005-09-09 | 2010-04-27 | Baker Hughes Incorporated | Drilling tools having hardfacing with nickel-based matrix materials and hard particles |
US7776256B2 (en) | 2005-11-10 | 2010-08-17 | Baker Huges Incorporated | Earth-boring rotary drill bits and methods of manufacturing earth-boring rotary drill bits having particle-matrix composite bit bodies |
US7997359B2 (en) | 2005-09-09 | 2011-08-16 | Baker Hughes Incorporated | Abrasive wear-resistant hardfacing materials, drill bits and drilling tools including abrasive wear-resistant hardfacing materials |
US7807099B2 (en) | 2005-11-10 | 2010-10-05 | Baker Hughes Incorporated | Method for forming earth-boring tools comprising silicon carbide composite materials |
US8770324B2 (en) | 2008-06-10 | 2014-07-08 | Baker Hughes Incorporated | Earth-boring tools including sinterbonded components and partially formed tools configured to be sinterbonded |
US7784567B2 (en) * | 2005-11-10 | 2010-08-31 | Baker Hughes Incorporated | Earth-boring rotary drill bits including bit bodies comprising reinforced titanium or titanium-based alloy matrix materials, and methods for forming such bits |
US7802495B2 (en) * | 2005-11-10 | 2010-09-28 | Baker Hughes Incorporated | Methods of forming earth-boring rotary drill bits |
EP2327856B1 (en) | 2006-04-27 | 2016-06-08 | Kennametal Inc. | Modular fixed cutter earth-boring bits, modular fixed cutter earth-boring bit bodies, and related methods |
RU2009111383A (en) | 2006-08-30 | 2010-10-10 | Бейкер Хьюз Инкорпорейтед (Us) | METHODS FOR APPLICATION OF WEAR-RESISTANT MATERIAL ON EXTERNAL SURFACES OF DRILLING TOOLS AND RELATED DESIGNS |
EP2078101A2 (en) | 2006-10-25 | 2009-07-15 | TDY Industries, Inc. | Articles having improved resistance to thermal cracking |
US7846551B2 (en) | 2007-03-16 | 2010-12-07 | Tdy Industries, Inc. | Composite articles |
US8790439B2 (en) | 2008-06-02 | 2014-07-29 | Kennametal Inc. | Composite sintered powder metal articles |
CA2725318A1 (en) * | 2008-06-02 | 2009-12-10 | Tdy Industries, Inc. | Cemented carbide-metallic alloy composites |
US8261632B2 (en) | 2008-07-09 | 2012-09-11 | Baker Hughes Incorporated | Methods of forming earth-boring drill bits |
US8025112B2 (en) | 2008-08-22 | 2011-09-27 | Tdy Industries, Inc. | Earth-boring bits and other parts including cemented carbide |
US8322465B2 (en) | 2008-08-22 | 2012-12-04 | TDY Industries, LLC | Earth-boring bit parts including hybrid cemented carbides and methods of making the same |
US8272816B2 (en) | 2009-05-12 | 2012-09-25 | TDY Industries, LLC | Composite cemented carbide rotary cutting tools and rotary cutting tool blanks |
US8201610B2 (en) | 2009-06-05 | 2012-06-19 | Baker Hughes Incorporated | Methods for manufacturing downhole tools and downhole tool parts |
US8308096B2 (en) | 2009-07-14 | 2012-11-13 | TDY Industries, LLC | Reinforced roll and method of making same |
US9643236B2 (en) * | 2009-11-11 | 2017-05-09 | Landis Solutions Llc | Thread rolling die and method of making same |
CN102985197A (en) | 2010-05-20 | 2013-03-20 | 贝克休斯公司 | Methods of forming at least a portion of earth-boring tools, and articles formed by such methods |
EP2571646A4 (en) | 2010-05-20 | 2016-10-05 | Baker Hughes Inc | Methods of forming at least a portion of earth-boring tools |
US8978734B2 (en) | 2010-05-20 | 2015-03-17 | Baker Hughes Incorporated | Methods of forming at least a portion of earth-boring tools, and articles formed by such methods |
US8800848B2 (en) | 2011-08-31 | 2014-08-12 | Kennametal Inc. | Methods of forming wear resistant layers on metallic surfaces |
US9016406B2 (en) | 2011-09-22 | 2015-04-28 | Kennametal Inc. | Cutting inserts for earth-boring bits |
US20130260166A1 (en) * | 2012-04-02 | 2013-10-03 | Kennametal Inc. | Coated Titanium Alloy Surfaces |
RU2492256C9 (en) * | 2012-05-16 | 2013-12-10 | Сергей Валерьевич Панин | Pure titanium-based nanostructured composite and method of its production |
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US4906430A (en) * | 1988-07-29 | 1990-03-06 | Dynamet Technology Inc. | Titanium diboride/titanium alloy metal matrix microcomposite material and process for powder metal cladding |
US4968348A (en) * | 1988-07-29 | 1990-11-06 | Dynamet Technology, Inc. | Titanium diboride/titanium alloy metal matrix microcomposite material and process for powder metal cladding |
JPH042742A (en) * | 1990-04-19 | 1992-01-07 | Fuso Off Service:Kk | Composite titanium alloy, multilayered titanium material, titanium cutter and their manufacture |
US5799238A (en) * | 1995-06-14 | 1998-08-25 | The United States Of America As Represented By The United States Department Of Energy | Method of making multilayered titanium ceramic composites |
US5897830A (en) * | 1996-12-06 | 1999-04-27 | Dynamet Technology | P/M titanium composite casting |
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2001
- 2001-06-08 IT IT2001RM000320A patent/ITRM20010320A1/en unknown
-
2002
- 2002-06-03 WO PCT/IT2002/000358 patent/WO2002101104A1/en not_active Application Discontinuation
- 2002-06-03 US US10/479,881 patent/US20050008524A1/en not_active Abandoned
- 2002-06-03 EP EP02743624A patent/EP1407055A1/en not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO02101104A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2002101104A1 (en) | 2002-12-19 |
ITRM20010320A1 (en) | 2002-12-09 |
US20050008524A1 (en) | 2005-01-13 |
ITRM20010320A0 (en) | 2001-06-08 |
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