WO2002086405A2 - Slagging combustion furnace - Google Patents
Slagging combustion furnace Download PDFInfo
- Publication number
- WO2002086405A2 WO2002086405A2 PCT/JP2002/003907 JP0203907W WO02086405A2 WO 2002086405 A2 WO2002086405 A2 WO 2002086405A2 JP 0203907 W JP0203907 W JP 0203907W WO 02086405 A2 WO02086405 A2 WO 02086405A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- combustion
- slagging
- combustion chamber
- combustible gas
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C7/00—Combustion apparatus characterised by arrangements for air supply
- F23C7/02—Disposition of air supply not passing through burner
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
- F23G5/165—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber arranged at a different level
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/32—Incineration of waste; Incinerator constructions; Details, accessories or control therefor the waste being subjected to a whirling movement, e.g. cyclonic incinerators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J9/00—Preventing premature solidification of molten combustion residues
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/10—Combustion in two or more stages
- F23G2202/101—Combustion in two or more stages with controlled oxidant supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/10—Combustion in two or more stages
- F23G2202/104—Combustion in two or more stages with ash melting stage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/20—Medical materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/26—Biowaste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/28—Plastics or rubber like materials
- F23G2209/281—Tyres
Definitions
- the present invention relates to a waste treatment system for treating wastes including municipal wastes, industrial wastes, biomass wastes, medical wastes, automobile wastes such as waste tires or shredder dust, and the like, and more particularly to a slagging combustion furnace and a method of supplying gas for combustion in the slagging combustion furnace in a gasification and slagging combustion system in which the above wastes are gasified to produce combustible gas in a gasification furnace, and the produced combustible gas is combusted or gasified together with unburned carbon accompanied by the produced combustible gas to generate ash or molten slag in a swirling-type slagging combustion furnace.
- FIG. 1 of the accompanying drawings schematically shows essential elements of a conventional gasification and slagging combustion system having a waste heat boiler.
- the conventional gasification and slagging combustion system comprises a waste supply device 1, a fluidized-bed gasification furnace 2, and a swirling-type slagging combustion furnace 3 having a primary combustion chamber 4, a secondary combustion chamber 5, and a tertiary combustion chamber 6.
- the gasification and slagging combustion system further comprises a waste heat boiler 7, an economizer 8, a bag filter 9, an exhaust gas reheater 10, a catalytic reaction tower 11, and a stack 12.
- the conventional gasification and slagging combustion system shown in FIG. 1 operates as follows: Wastes a supplied from the waste supply device 1 into the fluidized-bed gasification furnace 2 are pyrolyzed and gasified to produce combustible gas b in a fluidized bed where a fluidized medium c (such as sand) is fluidized by fluidizing air g introduced from a bottom of the fluidized- bed gasification furnace 2.
- a fluidized medium c such as sand
- the gas b produced in the fluidized-bed gasification furnace 2 is introduced into the swirling-type slagging combustion furnace 3.
- the produced gas b is mixed with gas f for combustion in the primary combustion chamber 4 and combusted at a high temperature of about 1350°C in the secondary combustion chamber 5 to combust char contained in the produced gas b, thus melting ash contained in the char.
- the produced gas b is further mixed with gas f for combustion in the tertiary combustion chamber 6 and combusted therein to generate exhaust gas e.
- the exhaust gas e having a high temperature of about 1350 °C is then introduced into the waste heat boiler 7.
- Incombustibles d which are contained in the wastes a and are not gasified are discharged from the lower part of the fluidized bed in the fluidized-bed gasification furnace 2 to the outside.
- the ash melted in the swirling-type slagging combustion furnace 3 is discharged as molten slag h from the swirling-type slagging combustion furnace 3 to the outside.
- the high-temperature exhaust gas e passes successively through the waste heat boiler 7 and the economizer 8, and thus is cooled to a temperature of about 160°C.
- the cooled exhaust gas e is introduced into the bag filter 9 where dust such as fly ash contained in the exhaust gas e is removed. Then, the exhaust gas e is preheated to a temperature (200°C to 210°C) enough to cause a catalytic reaction.
- NOx and SOx contained in the exhaust gas e are removed through a reaction with ammonia in the catalytic reaction tower 11, and then the exhaust gas e is discharged from the stack 12 into the atmosphere.
- steam produced in the waste heat boiler 7 is supplied to a steam turbine (not shown) coupled to a generator to generate electric power.
- the generated electric power is used for operating various equipment in the gasification and slagging combustion system to save energy and also to reduce the running cost.
- the produced gas b from the fluidized-bed gasification furnace 2 is introduced into the primary combustion chamber 4 of the swirling-type slagging combustion furnace 3 in a direction tangential to an inner wall surface thereof from a high-temperature duct 21 connected to a gas inlet port 20 defined in an upper portion of the inner wall surface of the primary combustion chamber 4, thus generating a swirling flow of the gas in the primary combustion chamber 4.
- the gas f for combustion is supplied to the produced gas b in the primary combustion chamber 4 at a certain angle to the swirling flow of the produced gas b from a plurality of (eight in FIGS.
- gas supply nozzles 22 which are mounted on the side wall of the primary combustion chamber 4 and are open at the inner wall surface of the primary combustion chamber 4 downstream of the gas inlet port 20.
- the produced gas b is mixed with the gas f for combustion, and combusted at a high temperature in the secondary combustion chamber 5 and the tertiary combustion chamber 6.
- the primary combustion chamber 4 has a burner 23 mounted on its top wall for assisting the combustion of the produced gas b in the primary combustion chamber 4.
- FIGS. 2A and 2B The structure shown in FIGS. 2A and 2B is disadvantageous in that, as shown in FIGS. 3A and 3B, a clinker K, which is made from the melted ash, is adhered (or attached) to and deposited on the inner wall surface of the primary combustion chamber 4 in the vicinity of the gas supply nozzles 22, where the gas is in the state within a transitional temperature range, which is uncertain range, between melting and solidifying of solid material constituting the ash in the gas.
- a transitional temperature range which is uncertain range
- molten slag is produced at a temperature of 1300°C, preferably around 1350°C for the quality of slag. If the combustible gas containing lots of solid material exists around this nozzle 22 in the space which is within the transitional temperature between melting and solidifying of solid material constituting the ash in the gas. In the transitional temperature, a part of the ash in the gas is in a melting state, and a part of the ash remains in a solid state. Because the ambient temperature of the solid material is lower than the start temperature of slag formation, for example, 1300°C and higher than the start temperature of slag fusion, for example, 1000°C, the melting state and the solid state of the material occur, and the material becomes highly viscous.
- the present invention has been made in view of the above drawbacks. It is therefore an object of the present invention to provide a slagging combustion furnace for use in a gasification and slagging combustion system which can prevent a clinker from being adhered to an inner wall surface of the slagging combustion furnace for thereby preventing supply nozzles for supplying gas for combustion such as combustion air and a primary combustion chamber from being clogged, and allows the gasification and slagging combustion system to operate continuously stably.
- a slagging combustion furnace comprising: a side wall and a top wall; a gas inlet port formed in an upper portion of the side wall for introducing combustible gas to produce a swirling flow of the combustible gas; and a plurality of gas supply nozzles, which are open at an inner surface of the side wall and an inner surface of the top wall, for supplying gas for combustion; wherein the gas for combustion is blown from the gas supply nozzles into the swirling flow of the combustible gas.
- the gas for combustion is blown from the gas supply nozzles which are open at the inner surface of the side wall and the inner surface of the top wall, into the produced combustible gas to mix the gas for combustion well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the time of the gas which passes through the transitional temperature range, i.e., allowing the gas to pass through such transitional temperature range as quickly as possible, and minimizing the space, in the slagging combustion furnace, where the atmosphere is within the transitional temperature range, i.e., making such space as small as possible.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the slagging combustion furnace.
- a clinker is prevented from being adhered (or attached) to the inner wall surface of the slagging combustion furnace.
- a slagging combustion furnace comprising: a side wall and a top wall; a gas inlet port formed in an upper portion of the side wall for introducing combustible gas to produce a swirling flow of the combustible gas; and a gas supply nozzle, which is open at an inner surface of the side wall near the gas inlet port, for supplying the combustible gas; wherein the gas for combustion is blown from the gas supply nozzle into the combustible gas introduced from the gas inlet port.
- the gas for combustion is blown from the gas supply nozzle which is open at the inner surface of the side wall near the gas inlet port for supplying the produced gas to mix the gas for combustion well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the time of the gas which passes through the transitional temperature range, i.e., allowing the gas to pass through such transitional temperature range as quickly as possible, and minimizing the space, in the slagging combustion furnace, where the atmosphere is within the transitional temperature range, i.e., making such space as small as possible.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the slagging combustion furnace.
- a clinker is prevented from being adhered or attached to the inner wall surface of the slagging combustion furnace.
- the gas supply nozzle forms a swirling flow of the gas for combustion.
- the gas for combustion is introduced from the gas supply nozzle as a swirling flow into the produced gas, the gas for combustion is mixed well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the time of the gas which passes through the transitional temperature range, i.e., allowing the gas to pass through such transitional temperature range as quickly as possible, and minimizing the space, in the slagging combustion furnace, where the atmosphere is within the transitional temperature range, i.e., making such space as small as possible.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the slagging combustion furnace.
- a clinker is further prevented from being adhered to the inner wall surface of the slagging combustion furnace.
- a slagging combustion furnace comprising: a side wall and a top wall; a gas inlet port formed in the side wall for introducing combustible gas; and a gas supply nozzle, which is open at an inner surface of the side wall near the gas inlet, for supplying the combustible gas; wherein the gas for combustion is blown from the gas supply nozzle into the combustible gas introduced from the gas inlet port.
- a method of supplying gas for combustion into a slagging combustion furnace comprising: introducing combustible gas from a gas inlet port formed in an upper portion of a side wall of the slagging combustion furnace to produce a swirling flow of the combustible gas; and introducing gas for combustion from a plurality of gas supply nozzles which are open at an inner surface of the side wall and an inner surface of a top wall, into the swirling flow of the combustible gas.
- the gas for combustion is introduced from the gas supply nozzles which are open at the inner surface of the side wall and the inner surface of the top wall of the slagging combustion furnace, into the swirling flow of the produced gas, a clinker is prevented from being adhered to the side and top walls of the slagging combustion furnace.
- a method of supplying gas for combustion into a slagging combustion furnace further comprises introducing gas for combustion from a gas supply nozzle which is open at an inner surface of the side wall near the gas inlet port, into the combustible gas.
- a gas supply nozzle which is open at an inner surface of the side wall near the gas inlet port, into the produced gas, a clinker is further prevented from being adhered to the side and top walls of the primary combustion chamber of the slagging combustion furnace.
- a method of supplying gas into a slagging combustion furnace comprising a primary combustion chamber, a secondary combustion chamber coupled to the primary combustion chamber, and a tertiary combustion chamber coupled to the secondary combustion chamber, the method comprising: introducing combustible gas produced at an air ratio ranging from 0.2 to 0.3 from a gas inlet port formed in an upper portion of a side wall of the primary combustion chamber; and adjusting the amount of gas for combustion introduced respectively into the primary combustion chamber, the secondary combustion chamber, and the tertiary combustion chamber such that the air ratio in an upper portion of the primary combustion chamber is approximately 1.0.
- the tertiary combustion chamber is adjusted such that the air ratios in the secondary and tertiary combustion chambers increase from 1.0 to 1.5.
- the air ratio in the upper portion of the primary combustion chamber is approximately 1.0, and hence the temperature in the primary combustion chamber near the gas inlet port for introducing the produced gas is maintained at a high value of about 1300°C, thus minimizing the time of the gas which passes through the transitional temperature range, i.e., allowing the gas to pass through such transitional temperature range as quickly as possible, and minimizing the space, in the slagging combustion furnace, where the atmosphere is within the transitional temperature range, i.e., making such space as small as possible.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the slagging combustion furnace. If the air ratio were greater than 1.0, the temperature in the primary combustion chamber is lowered, thus tending to approach to the temperature range in which a clinker is adhered to the inner wall surface of the primary combustion chamber.
- the amount of gas for combustion is adjusted such that the air ratios in the secondary and tertiary combustion chambers increase progressively from 1.0 to 1.5, and hence the produced gas and unburned materials such as char contained therein are completely combusted, and the temperature in the slagging combustion furnace is kept at a high value for thereby increasing the percentage of slagging.
- a gasification and slagging combustion system comprising: a fluidized-bed gasification furnace for gasifying wastes to produce combustible gas; and a slagging combustion furnace for combusting the combustible gas and melting ash contained in the combustible gas to generate molten slag;
- the slagging combustion furnace comprising: a side wall and a top wall; a gas inlet port formed in an upper portion of the side wall for introducing combustible gas to produce a swirling flow of the combustible gas; and a plurality of gas supply nozzles, which are open at an inner surface of the side wall and an inner surface of the top wall, for supplying gas for combustion; wherein the gas for combustion is blown from the gas supply nozzles into the swirling flow of the combustible gas.
- a gasification and slagging combustion system comprising: a fluidized-bed gasification furnace for gasifying wastes to produce combustible gas; and a slagging combustion furnace for combusting the combustible gas and melting ash contained in the combustible gas to generate molten slag;
- the slagging combustion furnace comprising: a side wall and a top wall; a gas inlet port formed in an upper portion of the side wall for introducing combustible gas to produce a swirling flow of the combustible gas; and a gas supply nozzle, which is open at an inner surface of the side wall near the gas inlet port, for supplying gas for combustion; wherein the gas for combustion is blown from the gas supply nozzle into the combustible gas introduced from the gas inlet port.
- FIG. 1 is a schematic diagram of essential elements of a conventional gasification and slagging combustion system having a waste heat boiler;
- FIG. 2A is a side elevational view of a slagging combustion furnace in the conventional gasification and slagging combustion system
- FIG. 2B is a plan view of a primary combustion chamber of the slagging combustion furnace shown in FIG. 2A;
- FIG. 3A is a cross-sectional view taken along line A-A of FIG . 3B ;
- FIG. 3B is a plan view showing how a clinker is adhered to and deposited on an inner wall surface of the primary combustion chamber of the slagging combustion furnace shown in FIG. 2A;
- FIG. 4A is a side elevational view of a slagging combustion furnace in a gasification and slagging combustion system according to an embodiment of the present invention
- FIG. 4B is a plan view of a primary combustion chamber of the slagging combustion furnace shown in FIG. 4A;
- FIG. 5A is a side elevational view of a slagging combustion furnace in a gasification and slagging combustion system according to another embodiment of the present invention
- FIG. 5B is a plan view of a primary combustion chamber of the slagging combustion furnace shown in FIG. 5A;
- FIG. 6A is a side elevational view of a slagging combustion furnace in a gasification and slagging combustion system according to still another embodiment of the present invention.
- FIG. 6B is a plan view of a primary combustion chamber of the slagging combustion furnace shown in FIG. 6A;
- FIG. 7A is a side elevational view of a slagging combustion furnace in a gasification and slagging combustion system according to still another embodiment of the present invention.
- FIG. 7B is a plan view of a primary combustion chamber of the slagging combustion furnace shown in FIG. 7A;
- FIG. 8 is a view showing a gas supply nozzle for supplying gas for combustion used in the slagging combustion furnace according to the present invention.
- FIG. 9A is a side elevational view, partly in cross section, of a swirler of the gas supply nozzle shown in FIG. 8 ;
- FIG. 9B is a front elevational view of the swirler shown in FIG. 9A;
- FIG. 10A is a side elevational view of a system for introducing gas for combustion into combustion chambers of the slagging combustion furnace according to the present invention.
- FIG. 10B is a cross-sectional view taken along line A-A of FIG. 10A.
- FIGS. 4A and 4B through 10A and 10B show slagging combustion furnaces in a gasification and slagging combustion system according to various embodiments of the present invention. Those parts of the slagging combustion furnaces shown in FIGS. 4A and 4B through
- FIGS. 4A and 4B show a slagging combustion furnace in a gasification and slagging combustion system according to an embodiment of the present invention.
- the slagging combustion furnace comprises a swirling- type slagging combustion furnace 3 having a primary combustion chamber 4, a secondary combustion chamber 5, and a tertiary combustion chamber 6.
- the swirling-type slagging combustion furnace 3 has a high-temperature duct 21 connected to a gas inlet port 20 defined in an upper portion of the inner wall surface of the primary combustion chamber 4.
- the high-temperature duct 21 serves to introduce the produced gas b supplied from the fluidized-bed gasification furnace 2 (see FIG. 1).
- the swirling-type slagging combustion furnace 3 also has a plurality of (six in FIGS. 4A and 4B) gas supply nozzles 24 which are mounted on the top wall of the primary combustion chamber 4 and are open at the inner wall surface of the primary combustion chamber 4, and a plurality of (four in FIGS. 4A and 4B) gas supply nozzles 25 which are mounted on the side wall of the primary combustion chamber 4 and are open at the inner wall surface of the primary combustion chamber 4 near the gas inlet port 20.
- the gas supply nozzles for supplying gas for combustion are disposed at the introduction part of the produced gas b supplied from the gasification furnace in the slagging combustion furnace.
- the amount of the gas for combustion supplied from the gas supply nozzles is such an amount that the supplied produced gas is substantially completely combusted (in case of air, the air ratio is 1.0), and hence combustion of the produced gas caused by supply of the gas for combustion raises rapidly the ambient temperature of the introduction part in the slagging combustion furnace to 1350°C. Therefore, the number of the gas supply nozzles is different depending on the size of the system and is not so important, and may be one or two or more.
- the produced gas b is introduced from the high-temperature duct 21 through the gas inlet port 20 into the primary combustion chamber 4 to generate a swirling flow of the produced gas b therein.
- gas f for combustion comprising air, oxygen-enriched air, or oxygen is introduced from the gas supply nozzles 24 whose tip ends are open at the inner wall surface of the top wall, into the swirling flow in a direction perpendicular to the swirling flow of the produced gas b.
- gas f for combustion is introduced from the gas supply nozzles 25 whose tip ends are open at the inner wall surface of the side wall, into the swirling flow of the produced gas b at a certain angle to the swirling flow.
- the gas f for combustion is introduced from the gas supply nozzles 24 and 25 on the top and side walls of the primary combustion chamber 4, it is well mixed with the produced gas b, thus allowing the produced gas b to be combusted quickly and achieving temperature rise quickly, and minimizing the time of the gas which passes through the transitional temperature range, i.e., allowing the gas to pass through such transitional temperature range as quickly as possible, and minimizing the space, in the slagging combustion furnace, where the atmosphere is within the transitional temperature range, i.e., making such space as small as possible.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the primary combustion chamber 4 and furthermore the inner wall surface toward the outlet where the melted ash (i.e. slag) is discharged.
- FIGS. 5A and 5B show a slagging combustion furnace in a gasification and slagging combustion system according to another embodiment of the present invention.
- the slagging combustion furnace shown in FIGS. 5A and 5B differs from the slagging combustion furnace shown in FIGS. 4A and 4B in that it additionally has a vertical array of (three in FIGS. 5A and 5B) gas supply nozzles 26 which are mounted on the side wall of the primary combustion chamber 4 and are open at the inner wall surface of the primary combustion chamber 4 on one side of the gas inlet port 20 in the vicinity of the gas inlet port 20.
- the gas supply nozzles 26 serve to introduce gas f for combustion comprising air, oxygen-enriched air, or oxygen so as to be across the gas inlet port 20.
- the gas f for combustion supplied from the gas supply nozzles 26 allows the produced gas b to be combusted efficiently for thereby achieving high temperature quickly.
- the slagging combustion furnace shown in FIGS. 5A and 5B also offers the advantage that it is capable of preventing a clinker from being adhered to the vicinity of the gas inlet port 20.
- FIGS. 6A and 6B show a slagging combustion furnace in a gasification and slagging combustion system according to still another embodiment of the present invention.
- the slagging combustion furnace shown in FIGS. 6A and 6B differs from the slagging combustion furnace shown in FIGS. 5A and 5B in that it additionally has two vertical arrays of (six in FIGS. 6A and 6B) gas supply nozzles 26 and 27 which are mounted on the side wall of the primary combustion chamber 4 and are open at the inner wall surface of the primary combustion chamber 4 on both sides of the gas inlet port 20 in the vicinity of the gas inlet port 20.
- the gas supply nozzles 26 serve to introduce the gas f for combustion comprising air, oxygen-enriched air, or oxygen so as to be across the gas inlet port 20, and the gas supply nozzles 27 serve to introduce the gas f for combustion at a certain angle to the swirling flow of the produced gas .
- the slagging combustion furnace shown in FIGS. 6A and 6B also offers the advantage that it is capable of effectively preventing a clinker from being attached to the inner wall surface of the primary combustion chamber 4 in the vicinity of the gas inlet port 20.
- FIGS. 7A and 7B show a slagging combustion furnace in a gasification and slagging combustion system according to still another embodiment of the present invention.
- the slagging combustion furnace shown in FIGS. 7A and 7B differs from the slagging combustion furnace shown in FIGS. 6A and 6B in that the gas supply nozzles 27 have tip ends 27a bent so as to cause the gas f for combustion introduced therefrom to flow in substantially the same direction as the produced gas b introduced from the gas inlet port 20.
- the slagging combustion furnace shown in FIGS. 7A and 7B also offers the advantage that it is capable of more effectively preventing a clinker from being adhered to the inner wall surface of the primary combustion chamber 4 in the vicinity of the gas inlet port 20.
- FIGS. 8, 9A and 9B show one of the gas supply nozzles 25 which supply gas for combustion and are identical to each other.
- the gas supply nozzle 25 has an outer tube 25a, an inner tube 25c disposed in the outer tube 25a, and a swirler 25b attached to a distal end of the inner tube 25c.
- An outlet tube 25e is connected to the swirler 25d and disposed in the outer tube 25a which is open at the inner wall surface of the primary combustion chamber 4.
- a gas inlet tube 25g for introducing the gas f for combustion is connected to the outer tube 25a, and the outer tube 25a has a rear end closed by a lid 25b remotely from the primary combustion chamber 4. As shown in FIGS.
- the swirler 25d comprises a boss 25d-3 fixed to the tip end of the inner tube 25c, a ring plate 25d-l disposed around the boss 25d-3, and a plurality of swirling vanes 25d-2 disposed between and joined to the boss 25d-3 and the ring plate 25d-l for producing a swirling flow of the gas for combustion.
- the gas supply nozzle 25 operates as follows: The gas f for combustion introduced from the gas inlet tube 25g passes through the gap between the outer tube 25a and the inner tube 25c to the swirler 25d, and is turned by the swirling vanes 25d-2 into a helical swirling flow. Then, the gas f for combustion is introduced in the swirling flow through the outlet tube 25e into the primary combustion chamber 4.
- each of the gas supply nozzles 24, 26 and 27 described above should preferably be of a structure identical or similar to the gas supply nozzle 25 shown in FIGS. 8, 9A and 9B.
- the swirling- type slagging combustion furnace 3 is of a substantially U- shaped configuration in which the primary combustion chamber 4, the secondary combustion chamber 5, and the tertiary combustion chamber 6 are successively arranged.
- the swirling-type slagging combustion furnace according to the present invention is not limited to the illustrated structure, but may be of any structure capable of introducing produced combustible gas from a gas inlet port in a side wall thereof and generating a swirling flow of the produced combustible gas.
- FIGS. 10A and 10B show a system for introducing gas for combustion into the combustion chamber of the slagging combustion furnace according to the present invention.
- FIG. 10A is a side cross-sectional view of the slagging combustion furnace
- FIG. 10B is a cross- sectional view taken along line A-A. As shown in FIG.
- the system includes a blower 30 for supplying gas f (mainly air) for combustion, a damper 31 connected to the blower 30, and flow control valves 32, 33, 34 and 35 connected to the damper 31 for supplying the gas f for combustion to the gas inlet port 20, the primary combustion chamber 4 coupled to the gas inlet port 20, the secondary combustion chamber 5 coupled to the primary combustion chamber 4, and the tertiary combustion chamber 6 coupled to the secondary combustion chamber 5.
- gas f mainly air
- damper 31 connected to the blower 30, and flow control valves 32, 33, 34 and 35 connected to the damper 31 for supplying the gas f for combustion to the gas inlet port 20, the primary combustion chamber 4 coupled to the gas inlet port 20, the secondary combustion chamber 5 coupled to the primary combustion chamber 4, and the tertiary combustion chamber 6 coupled to the secondary combustion chamber 5.
- the produced gas b flows through the high-temperature duct 21 and is introduced from the gas inlet port 20 at a speed of 15 m/s to 25 m/s, preferably 18 m/s to 20 m/s into the primary combustion chamber 4, and the gas f for combustion is introduced from the gas supply nozzles 26 and 27 into the gas inlet port 20, thereby forming flames 39 in the primary combustion chamber 4 of the swirling-type slagging combustion furnace 3.
- the gas f for combustion is blown such that the air ratio A-R in the upper portion of the primary combustion chamber 4 is in the range of 0.8 to 1.1, preferably 0.9 to 1.0.
- the air ratio is defined as the ratio of the amount of supplied air to the amount of air, which is set to 1.0, required to completely convert combustibles in the wastes into H 2 0 and C0 2 by way of combustion.
- the surface area of adhesion or attachment of clinker to the inner wall of the slagging combustion furnace is minimized, resulting in the prevention of adhesion or attachment to the inner wall surface of the slagging combustion furnace. If the air ratio were greater than 1.0, the amount of air which does not contribute to combustion would increase, and the cooling effect caused by air would also increase, thus lowering the temperature in the primary combustion chamber 4 and tending to expand the temperature range in which a clinker is adhered to the inner wall surface of the primary combustion chamber 4.
- the air ratio A-R is increased successively in the secondary combustion chamber 5 and the tertiary combustion chamber 6.
- the air ratio A-R in the secondary combustion chamber 5 is set to a value ranging from 0.9 to 1.3, preferably from 1.0 to 1.2
- the air ratio A-R in the tertiary combustion chamber 6 is set to a value ranging from 1.2 to 1.7, preferably from 1.3 to 1.5.
- the air ratio A-R is set to a value ranging from 0.9 to 1.3, preferably from 1.0 to 1.2 until the molten slag h is discharged from a slag outlet port 40, the temperature in the secondary combustion chamber 5 up to the slag outlet port 40 is maintained at a maximum level, thus allowing the molten slag h to be discharged downwardly stably.
- adding the gas for combustion in the high temperature is effective to combust a small amount of unburned CO (carbon monoxide) in almost all combusted gas in the slagging combustion furnace.
- the air ratio is set to a value ranging from 1.2 to 1.7, preferably from 1.3 to 1.5, while keeping the slagging combustion furnace at a high temperature. That is, the air ratio A-R in the tertiary combustion chamber 6 is set to a large value ranging from 1.3 to 1.5, whereby unburned CO is effectively combusted, and pyrolyzed gas and char are completely combusted without lack of air for combustion, even if the wastes are fluctuated in the supplied amount or quality.
- the gas f for combustion is supplied in an excessive amount to absorb variations in the supplied amount of wastes and minimize any reduction in the temperature in the slagging combustion furnace 3. Therefore, the produced gas b and unburned materials such as char contained therein can be completely combusted, and the temperature in the slagging combustion furnace 3 can be kept at a high level for thereby increasing the percentage of slagging.
- thermometers 36, 37 and 38 are mounted on the top wall of the primary combustion chamber 4, the wall of the secondary combustion chamber 5, and the wall of the tertiary combustion chamber 6, respectively, for measuring the temperatures in these combustion chambers.
- Each of the thermometers 36, 37 and 38 may comprise a thermocouple or a radiation thermometer.
- the temperatures in the combustion chambers may alternatively be calculated from the temperature of the exhaust gas discharged from the slagging combustion furnace 3 using the amount of recovered heat and the amount of cooling air that is used. The above ranges of the air ratio can be controlled using the temperatures thus measured or calculated.
- the gas for combustion is blown from the gas supply nozzles which are open at the inner surface of the side wall and the inner surface of the top wall, into the produced combustible gas to mix the gas for combustion well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the temperature range in which a clinker is adhered (or attached) to the inner wall surface of primary combustion chamber of the slagging combustion furnace.
- a clinker is prevented from being adhered or attached to the inner wall surface of the slagging combustion furnace. Consequently, the gasification and slagging combustion system can be stably operated continuously.
- the gas for combustion is blown from the gas supply nozzle which is open at the inner surface of the side wall near the gas inlet port for supplying the produced gas to mix the gas for combustion well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the temperature range in which a clinker is adhered or attached to the inner wall surface of the slagging combustion furnace.
- a clinker is prevented from being adhered or attached to the inner wall surface of the slagging combustion furnace. Consequently, the gasification and slagging combustion system can be stably operated continuously.
- the gas for combustion is introduced from the gas supply nozzle as a swirling flow into the produced gas, the gas for combustion is mixed well with the produced gas for thereby increasing the temperature of the gas quickly and minimizing the temperature range in which a clinker is adhered to the inner wall surface of the slagging combustion furnace. As a result, a clinker is further prevented from being adhered to the inner wall surface of the slagging combustion furnace.
- the gas for combustion is introduced from the gas supply nozzles which are open at the inner surface of the side wall and the inner surface of the top wall of the slagging combustion furnace, into the swirling flow of the produced gas, a clinker is prevented from being adhered to the side and top walls of the slagging combustion furnace.
- the air ratio in the upper portion of the primary combustion chamber is approximately 1.0, and hence the temperature in the primary combustion chamber near the gas inlet port for introducing the produced gas is maintained at a high value of about 1300°C, thus minimizing the temperature range in which a clinker is adhered or attached to the inner wall surface of the primary combustion chamber. Further, the amount of gas for combustion is adjusted such that the air ratios in the secondary and tertiary combustion chambers increase progressively from 1.0 to 1.5, and hence the produced gas and unburned materials such as char contained therein are completely combusted, and the temperature in the slagging combustion furnace is kept at a high value for thereby increasing the percentage of slagging.
- the present invention is applicable to a slagging combustion furnace in a gasification and slagging combustion system in which wastes including municipal wastes, industrial wastes, biomass wastes, medical wastes, automobile wastes such as waste tires or shredder dust, and the like are gasified to produce combustible gas in a gasification furnace, and the produced combustible gas is combusted or gasified together with unburned carbon accompanied by the combustible gas to generate ash or molten slag in a swirling- type slagging combustion furnace.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Gasification And Melting Of Waste (AREA)
- Incineration Of Waste (AREA)
- Furnace Details (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2002251494A AU2002251494A1 (en) | 2001-04-20 | 2002-04-19 | Slagging combustion furnace |
CA002443542A CA2443542A1 (en) | 2001-04-20 | 2002-04-19 | Slagging combustion furnace |
KR10-2003-7013640A KR20030092086A (en) | 2001-04-20 | 2002-04-19 | Slagging combustion furnace |
EP02720516A EP1379823A2 (en) | 2001-04-20 | 2002-04-19 | Slagging combustion furnace |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001-122859 | 2001-04-20 | ||
JP2001122859 | 2001-04-20 | ||
JP2001-195269 | 2001-06-27 | ||
JP2001195269A JP2003004214A (en) | 2001-04-20 | 2001-06-27 | Melting furnace for gasifying melting furnace facility and method of supplying combustion gas to the melting furnace |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2002086405A2 true WO2002086405A2 (en) | 2002-10-31 |
WO2002086405A3 WO2002086405A3 (en) | 2002-12-19 |
Family
ID=26613926
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/003907 WO2002086405A2 (en) | 2001-04-20 | 2002-04-19 | Slagging combustion furnace |
Country Status (7)
Country | Link |
---|---|
EP (2) | EP1379823A2 (en) |
JP (1) | JP2003004214A (en) |
KR (1) | KR20030092086A (en) |
AU (1) | AU2002251494A1 (en) |
CA (1) | CA2443542A1 (en) |
TW (1) | TWI229726B (en) |
WO (1) | WO2002086405A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009097169A2 (en) | 2008-01-28 | 2009-08-06 | The Mcburney Corporation | Boiler apparatus for combusting processed agriculture residues (par) and method |
EP2180254A1 (en) * | 2007-06-08 | 2010-04-28 | Kobelco Eco-Solutions Co., Ltd. | Gasification melting equipment and method of feeding air for combustion in melting furnace of gasification melting equipment |
CN109579014A (en) * | 2018-12-29 | 2019-04-05 | 义马环保电力有限公司 | Urban garbage treatment system and method |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006097918A (en) * | 2004-09-28 | 2006-04-13 | Hitachi Metals Ltd | Combustion furnace and waste treatment facility |
JP4548785B2 (en) * | 2005-09-14 | 2010-09-22 | 三菱重工環境・化学エンジニアリング株式会社 | Waste gasification melting apparatus melting furnace, and control method and apparatus in the melting furnace |
WO2010009231A2 (en) * | 2008-07-15 | 2010-01-21 | Covanta Energy Corporation | System and method for gasification-combustion process using post combustor |
JP2010236733A (en) * | 2009-03-31 | 2010-10-21 | Hitachi Zosen Corp | Gasification melting method and gasification melting facility for waste |
JP2011220541A (en) * | 2010-04-05 | 2011-11-04 | Mitsubishi Heavy Ind Ltd | Boiler facility |
JP5798728B2 (en) * | 2010-10-04 | 2015-10-21 | 株式会社キンセイ産業 | Dry distillation gasification incineration processing equipment |
US20140083478A1 (en) * | 2011-04-19 | 2014-03-27 | Hokkaido Tokushushiryou Kabushikikaisha | Combustion Device, Combustion Method, and Electric Power-Generating Device and Electric Power-Generating Method Using Same |
JP5783078B2 (en) * | 2012-02-10 | 2015-09-24 | Jfeエンジニアリング株式会社 | Waste gasification melting furnace clinker destruction and suppression device |
JP7270193B2 (en) * | 2021-04-15 | 2023-05-10 | 株式会社青南商事 | Gasification melting system |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3817712A (en) * | 1971-11-26 | 1974-06-18 | Sola Basic Ind Inc | Smoke abater |
FR2660415A1 (en) * | 1990-03-28 | 1991-10-04 | Stein Industrie | Process and device for the treatment of solid or liquid toxic or polluting waste |
EP0455624A2 (en) * | 1990-05-02 | 1991-11-06 | AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH | Method for burning dust-laden gases as well as a combustion chamber for use in such a process |
US5357879A (en) * | 1992-05-20 | 1994-10-25 | Ebara-Infilco Co., Ltd. | Dried sludge melting furnace |
EP0853215A2 (en) * | 1994-03-23 | 1998-07-15 | AWG Abfallwirtschaftsgesellschaft mit beschränkter Haftung Wuppertal | Combustion device for pulverent materials |
EP0908672A1 (en) * | 1996-06-25 | 1999-04-14 | Ebara Corporation | Method for fusion treating a solid waste for gasification |
EP0952393A1 (en) * | 1996-09-25 | 1999-10-27 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Method and apparatus for operating melting furnace in waste treatment facilities |
US6190429B1 (en) * | 1994-03-10 | 2001-02-20 | Ebara Corporation | Method and apparatus for treating wastes by gasification |
-
2001
- 2001-06-27 JP JP2001195269A patent/JP2003004214A/en not_active Withdrawn
-
2002
- 2002-04-19 WO PCT/JP2002/003907 patent/WO2002086405A2/en not_active Application Discontinuation
- 2002-04-19 TW TW091108050A patent/TWI229726B/en not_active IP Right Cessation
- 2002-04-19 AU AU2002251494A patent/AU2002251494A1/en not_active Abandoned
- 2002-04-19 CA CA002443542A patent/CA2443542A1/en not_active Abandoned
- 2002-04-19 EP EP02720516A patent/EP1379823A2/en not_active Withdrawn
- 2002-04-19 EP EP04022570A patent/EP1489354A1/en not_active Withdrawn
- 2002-04-19 KR KR10-2003-7013640A patent/KR20030092086A/en not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3817712A (en) * | 1971-11-26 | 1974-06-18 | Sola Basic Ind Inc | Smoke abater |
FR2660415A1 (en) * | 1990-03-28 | 1991-10-04 | Stein Industrie | Process and device for the treatment of solid or liquid toxic or polluting waste |
EP0455624A2 (en) * | 1990-05-02 | 1991-11-06 | AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH | Method for burning dust-laden gases as well as a combustion chamber for use in such a process |
US5357879A (en) * | 1992-05-20 | 1994-10-25 | Ebara-Infilco Co., Ltd. | Dried sludge melting furnace |
US6190429B1 (en) * | 1994-03-10 | 2001-02-20 | Ebara Corporation | Method and apparatus for treating wastes by gasification |
EP0853215A2 (en) * | 1994-03-23 | 1998-07-15 | AWG Abfallwirtschaftsgesellschaft mit beschränkter Haftung Wuppertal | Combustion device for pulverent materials |
EP0908672A1 (en) * | 1996-06-25 | 1999-04-14 | Ebara Corporation | Method for fusion treating a solid waste for gasification |
EP0952393A1 (en) * | 1996-09-25 | 1999-10-27 | KABUSHIKI KAISHA KOBE SEIKO SHO also known as Kobe Steel Ltd. | Method and apparatus for operating melting furnace in waste treatment facilities |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2180254A1 (en) * | 2007-06-08 | 2010-04-28 | Kobelco Eco-Solutions Co., Ltd. | Gasification melting equipment and method of feeding air for combustion in melting furnace of gasification melting equipment |
EP2180254A4 (en) * | 2007-06-08 | 2014-05-07 | Kobelco Eco Solutions Co Ltd | Gasification melting equipment and method of feeding air for combustion in melting furnace of gasification melting equipment |
WO2009097169A2 (en) | 2008-01-28 | 2009-08-06 | The Mcburney Corporation | Boiler apparatus for combusting processed agriculture residues (par) and method |
EP2242951A2 (en) * | 2008-01-28 | 2010-10-27 | The Mcburney Corporation | Boiler apparatus for combusting processed agriculture residues (par) and method |
EP2242951A4 (en) * | 2008-01-28 | 2012-03-28 | Mcburney Corp | Boiler apparatus for combusting processed agriculture residues (par) and method |
CN109579014A (en) * | 2018-12-29 | 2019-04-05 | 义马环保电力有限公司 | Urban garbage treatment system and method |
Also Published As
Publication number | Publication date |
---|---|
WO2002086405A3 (en) | 2002-12-19 |
EP1489354A1 (en) | 2004-12-22 |
TWI229726B (en) | 2005-03-21 |
AU2002251494A1 (en) | 2002-11-05 |
CA2443542A1 (en) | 2002-10-31 |
EP1379823A2 (en) | 2004-01-14 |
JP2003004214A (en) | 2003-01-08 |
KR20030092086A (en) | 2003-12-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR20010033218A (en) | Fuel gasifying system | |
ES2260785T3 (en) | OVEN GASIFICATION AND COMBUSTION OF FLUIDIZED MILK AND METHOD. | |
EP1489354A1 (en) | Slagging combustion furnace | |
JP4126316B2 (en) | Operation control method of gasification and melting system and system | |
JP3936824B2 (en) | Waste heat recovery boiler and waste treatment facility | |
JP2007271203A (en) | Fluidized bed gasification furnace and its fluidized bed monitoring/controlling method | |
US6709636B1 (en) | Method and apparatus for gasifying fluidized bed | |
JP5611418B2 (en) | Combustion control method for gasification melting system and system | |
JP3770653B2 (en) | Gasification combustion method using fluidized bed furnace | |
JP4126317B2 (en) | Operation control method of gasification and melting system and system | |
JP2007163132A (en) | Method and apparatus for gasifying fluidized bed | |
JP4243764B2 (en) | Pyrolysis gasification melting system and its heating method | |
JP3989333B2 (en) | Operation method of waste incinerator | |
JP5086177B2 (en) | Gasification melting equipment and air supply method for combustion in combustion furnace of gasification melting equipment | |
JP2006194516A (en) | Secondary combustion control device for waste gasification melting furnace | |
JP3902123B2 (en) | Melting furnace temperature compensation apparatus and melting furnace temperature compensation method for gasification melting apparatus | |
JP4015878B2 (en) | Waste gasification and melting system | |
JP2006089628A (en) | Gasification furnace apparatus | |
JP4105963B2 (en) | Pyrolysis gasification melting system | |
JP2005314549A (en) | Gasification furnace apparatus | |
JP3838699B2 (en) | Cylindrical fluidized bed gasification combustion furnace | |
JP2004169955A (en) | Waste incinerator and method of operating the same | |
JP2004077014A (en) | Operation method of waste incinerator | |
JPH1180756A (en) | Fluidized-layer pressurized gasification furnace | |
JP3309586B2 (en) | Gasification and melting method of waste |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
AK | Designated states |
Kind code of ref document: A3 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2443542 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002720516 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020037013640 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2002720516 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2002720516 Country of ref document: EP |