WO2002081606A1 - Cupua seed-origin fat, process for producing the same and use thereof - Google Patents

Cupua seed-origin fat, process for producing the same and use thereof Download PDF

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Publication number
WO2002081606A1
WO2002081606A1 PCT/JP2002/003472 JP0203472W WO02081606A1 WO 2002081606 A1 WO2002081606 A1 WO 2002081606A1 JP 0203472 W JP0203472 W JP 0203472W WO 02081606 A1 WO02081606 A1 WO 02081606A1
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Prior art keywords
cupuas
fat
kupuas
crude
oil
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PCT/JP2002/003472
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French (fr)
Japanese (ja)
Inventor
Makoto Nagasawa
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Cupuacu International, Inc.
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Publication of WO2002081606A1 publication Critical patent/WO2002081606A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/48Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/34Cocoa substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/105Plant extracts, their artificial duplicates or their derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/04Drugs for disorders of the alimentary tract or the digestive system for ulcers, gastritis or reflux esophagitis, e.g. antacids, inhibitors of acid secretion, mucosal protectants
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/02Pretreatment
    • C11B1/04Pretreatment of vegetable raw material
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/06Production of fats or fatty oils from raw materials by pressing

Definitions

  • the present invention relates to a cupuas oil product such as a health food such as a chocolate-like confection, which contains a cupuas oil derived from cupuacu (Cupuacu-Theobroma grandfi florum (Wi1 derow ex Sprengel) Schumann).
  • Cupuacu is the common name of Theobroma grandf iflorum (Wi1 l derow ex Sprenge l) Schumann and is a tropical plant belonging to the genus Theobroma of the family Stercul i aceae. This family includes almost 50 genera and 75 species of trees (including arboreal and shrub), of which almost all species are tropical.
  • the genus Theobroma is broadly classified into six subgenus, Androretalum, Glossos talum, Oreanthes> Telmatocarpus, and Theobroma, and is further classified into 22 species.
  • Kupuas is a cultivar of the sub-genus Glososore t alum, a tree species belonging to Theobromas, and is currently grown natively or on a very small scale in the Amazon River basin in South America. In addition to being used by local residents, the flesh is processed into juice, nectar, jelly, sorbet, ice cream, yogurt, etc., on a small scale.
  • the tree is an evergreen shrub that is well adapted to shade and is therefore suitable for symbiosis with other plants. Open white or pale yellow flowers throughout the year, and then produce 1.2 to 1.3 kg of fruit. The pulp of the fruit accounts for about 40% of the total weight and contains an average of 30 to 40 seeds. Seeds have traditionally been discarded as useless or, at best, used as livestock feed. Disclosure of the invention
  • the Kupuas tree is a shrub that is native to the Amazon and highly shade-adapted as described above, that is, it has a high symbiotic ability with other tree species in the tropical rainforest, and for example, planting eucalyptus and palm trees suitable for greening
  • agroforestry is particularly suitable for planting trees to restore the revegetation of the degraded rainforest, and we believe that it can greatly contribute to the preservation and restoration of rainforests and the promotion of local industries.
  • Kupuas seeds Although the pulp of Kupuas seeds is used by small indigenous people for small-scale consumption, the fruits of Kupuas have large and large amounts of seeds as described above, and the weight of the seeds is approximately 17- Despite reaching 18%, Kupuas seeds are usually disposed of by landfill. If a valuable and effective use of the Kupuas seeds is found, the value of the Kupuas tree will increase, which will increase the cultivation of the Kupuas tree and prevent the deforestation of the rainforest.
  • the present inventors have conducted intensive studies on the effective use of currently almost worthless cupuas seeds and found that the seeds of cupuas contain a large amount of low-melting high-quality oils and fats.
  • the seeds of the cupuas are collected, which are, for example, washed, fermented (may be washed before fermentation), dried, roasted by a specific treatment, unhulled by a specific treatment, and crushed. It has been found that, for example, crude or refined cupuas oils and fats useful for the production of health foods, medicaments, and cosmetics of the present invention can be industrially advantageously produced by subjecting them to each step such as squeezing and pressing.
  • cupace in the present invention may be not only a naturally occurring cupath but also a variant thereof. That is, any of the varieties of cupuas obtained by crossing a cupuas with another plant or by genetic processing of a cupuas can be any of the cupuas according to the present invention as long as the following crude cupuas or purified cupuas fat can be produced therefrom.
  • the fat or oil obtained from such a Kupuas variety is the cupuas fat or oil in the present invention.
  • the present inventors have obtained the purified cupuas fat, melting point is 29 to 32 t:
  • refined cupuas fat can be used as required for refined cupuas fat, for example, sugar, powdered milk, vegetable oil (palm oil, coconut oil, nayu oil, etc.)
  • vegetable oil can be used to obtain chocolate-like confectionery that has excellent flavor and taste, and to mix processed foods such as margarine and whipped cream with an appropriate amount of refined cupuas fats and oils.
  • the first characteristic of crude or purified cupuas fat is that it does not substantially contain physiologically active substances having a strong stimulating arousal effect, such as caffeine and theopromin, and has a human body temperature of 29 to 33 with a melting point of 29 to 33. Its melting characteristics are extremely sharp, exhibit supercooling properties, accompany volume shrinkage upon solidification, and exhibit a polycrystalline form.
  • the typical physicochemical properties and fatty acid composition are as shown below, and the content of arachidic acid is about 9 times or more and the content of oleic acid and linoleic acid is about 1.3 times that of cocoa butter. It can be seen that the ratio of saturated fatty acids / unsaturated fatty acids is high and is therefore between 1.0 and 1.1.
  • cupuas fat is useful as a health food that contributes to prevention of lifestyle-related diseases and maintenance of health, since it is less susceptible to oxidation by water and has the same activity of lowering cholesterol and neutral fat in blood. According to the present invention, a chocolate-like confection can be produced using the cupuas fat as described above.
  • cocoa butter which is a raw material for chocolate
  • cocoa butter does not substantially contain stimulants such as caffeine and theopromine.
  • foods such as chocolate-like confections using cupuas fat are less than thiocholate. Are also preferred over health.
  • chocolate contains stimulants, stimulants or stimulants such as caffeine and theopromine
  • Coffee-like confections made using cupuas seed-derived fats and oils instead of cocoa butter have a similar taste and flavor to thiocholate, so pregnant women can use chocolate-like confections (kupuas chocolates) made from cupuas fats and oils.
  • kupuas chocolates chocolate-like confections
  • Milk chocolate has the problem of lactose allergy. Milk contains lactose, and eating milk and milk-containing milk chocolate, for example, produces hives and allergies that cause diarrhea.
  • Cupuas chocolate has a mild flavor, similar to milk chocolate, without the need to actively add milk to produce it. Therefore, eating chocolate-like confections made from kupuas fats helps maintain or improve health over eating chocolate. This is also a new discovery of the present inventors.
  • the present inventors have further conducted intensive studies on cupuas oils and fats and tychocholate-like confections produced therefrom. Workability is improved, and the chocolate-like confectionery produced has a smooth tongue-like flavor, and the melting point of cupuas fat is low. In such a case, if cocoa butter is blended with cupuas oil or fat or chocolate-like confectionery as a melting point modifier, such problems can be solved. discovered.
  • the present inventors have studied a first step in which Kupuas oil or fat is fermented with Kupuas seeds to obtain Kupuas beans, roasting Kupuas beans, threshing and collecting endosperm, and grinding this to obtain crude Kupuas. It has been found that the production can be carried out industrially by a production method including a second step of obtaining a purified cupuas by pressing a crude cupuas fat and oil, if desired, and a purified step.
  • the inventors of the present invention have repeated studies on a more industrially advantageous method for producing cupuas fats and oils.
  • the cacao beans after fermentation are used in a hot air roasting machine or a direct fire roasting machine. It was found that roasting in a roasting machine easily peels the hull and allows easy collection of endosperm, but it is not as easy as in cocoa beans to collect endosperm from cupuas seeds.
  • the hull of the cupuas seed after fermentation is different from the hull of cocoa beans, but it is elastic but thick and hard, and unlike cocoa beans, the hull does not come off easily even when roasted.
  • the endosperm and the hull are separated by mechanical means such as a crusher or the like, but the endosperm adheres to the hull at a high rate, and the yield of endosperm alone is low. Because the outer skin is sour and the tongue feels bad, endosperm with a hull is not good for food.
  • the hull with the endosperm is crushed by the above mechanical means, the endosperm, the hull and the hull with the endosperm are separated, and the hull with the endosperm is crushed by the mechanical means and repeated.
  • the yield is as low as about 40%, and the operation becomes complicated and takes time.
  • the present inventors have found that, in the case of cupuas seed, unlike the case of cocoa beans, a large amount of oil exists between the endosperm and the hull, and this oil adheres the endosperm and the hull, and the endosperm is We found that it was difficult to separate.
  • fermented cupuas seeds i.e., cupuas beans
  • Roasting cupuas beans using coconut oil causes unexpected separation of endosperm from hull It has been found that the above-mentioned problems can be solved.
  • the present inventors unexpectedly contacted the cupuas beans with high-temperature water or heated water steam, then cut the outer skin of the cupuas beans and removed the endosperm from the cuts or removed the outer skin.
  • the problem was solved, and it was found that this operation enables industrially more advantageous production of cupuas fats and oils. That is, the present invention
  • a healthy diet characterized by containing the crude cupuas fat or oil according to the above (1) or (2) and the purified cupuas fat and lecithin or cacao butter;
  • the health food according to the above (3) further comprising at least one selected from the group consisting of sugar, powdered milk, palm oil, coconut oil, and pine oil.
  • the health food according to the above (3) or (4) which is a chocolate-like confection or a chocolate substitute,
  • the crude Kupuas fat is separated from the refined Kupuas fat by pressure treatment.
  • Fig. 1 shows a typical production process of Kupuas fat by Method A.
  • Fig. 2 shows the production process of crude Kupuas fat and refined Kupuasu fat by Method B.
  • FIG. 3 shows a preferred embodiment of the present invention according to the C method. BEST MODE FOR CARRYING OUT THE INVENTION
  • Fig. 1 shows a typical production process of Kupuas oil and fat.
  • the fruits collected from the Kupuas tree are drupes, with an average weight of about 1 kg as described above, of which the pulp accounts for almost 40%, and the content of pectin and cuenic acid. It is high in taste and delicious, so it can be served as it is, and is suitable for use as a raw material in the production of processed foods such as juice, ice cream, jelly, and yogurt. By collecting them, the collection and collection of by-produced seeds can be made extremely easy and sanitary.
  • cupuas seed thus collected and sorted can be subjected to, for example, the following kupuasu production process starting from the following fermentation and drying to obtain a crude kupuas fat or a refined kupuas fat.
  • the seeds are stored in a sealable wooden or plastic box of an appropriate size, and if sealed, the attached yeast grows naturally and ferment. Starts. ⁇ The fermentation proceeds for 5-7 days, Instead, the polysaccharides contained in the fibrous pulp are decomposed into alcohol by the alcohol fermentation, and acetic acid is generated by the acetic acid fermentation.
  • the Kupuas seeds that have passed through the fermentation process are then spread on appropriate mats and subjected to solar drying or forced drying under heating to dry the water content from about 55% to almost 6% or less. Thus, storage and storage are possible.
  • Kupuasu seeds after fermentation are removed, for example, by sifting dirt and dust attached during drying. They are then filled into bags of appropriate size, such as jute or hemp, and stored and transported until used in the cupuas oil production process.
  • pebbles, metals, garbage, dust, etc. mixed in fermented and dried cupuas seeds, as well as contaminants such as flat beans and double beans, are screened with a filtration device, an electromagnet, compressed air, or the like. It is removed by using a small dust collector in combination as appropriate.
  • Kupuas seeds that have completed the purification process are also referred to as Kupuas beans.
  • the cleaning and purifying step may be performed before the fermentation step.
  • the purified Kupuas seeds (Kupuas beans) are roasted in the roasting process, and as a result, the water content of the Kupuas seeds is reduced from almost 6% to 2%, and the subsequent shelling process Facilitates the separation of the fibrous outer shell and endosperm.
  • the temperature of the cupuas seeds is raised to a high temperature of about 130 to 150 using a hot-air or direct-fired roasting machine commonly used for roasting coffee, cocoa, and the like. Performed by holding for 30 minutes.
  • the roasted Kupuas seeds are crushed in a crusher, and then sieved to remove the fibrous shell (skin) to separate and obtain endosperm.
  • the crusher treatment and the sieving treatment are repeated as appropriate until the outer skin becomes about 5% by weight or less.
  • the thus obtained cupuas seed endosperm is poured into a mill and usually subjected to a two-stage grinding treatment to obtain a crude cupuas fat. In the first stage, the average particle size is 150 micron through a blade mill. In the second stage, it is ground by a ball mill to an average particle size of about 75 microns.
  • cupuas oils and fats are also produced by fermenting and drying cupuas seeds, pulverizing under pressure without removing the outer shell (skin), and filtering under pressure. .
  • the fat content of the crude or purified cupuas fat is about 40 to 65% by weight.
  • Method A the outer skin is softened and boiled before the roasting of the cupuas beans obtained by fermentation and drying, so that the endosperm is taken out, and then the endosperm is taken out.
  • You may roast. That is, a crude cupuas fat and oil and a purified cupuas may be produced according to the process diagram shown in FIG. 2 (sometimes abbreviated as method B).
  • the yield of the cupuas oil and fat is surprisingly improved by about 30% as compared with the case according to the first process chart.
  • the processes of “fermentation”, “drying”, “roasting”, “threshing”, “milling” and “pressing” in Method B may be performed in the same manner as the corresponding processes in Method A.
  • the “roasting” treatment in the method B may be roasting using a far-infrared ray device described below, but may be roasting treatment using a hot-air roasting machine or a direct-fired roasting machine. Roasting and open fire roasting may be performed similarly to roasting cocoa beans. Contacting the cupuas with hot water or steam is preferably done by boiling the cupuas in water. A preferred embodiment in this case is described below.
  • the boil treatment may be performed according to a means known per se, and may be performed under normal pressure or under pressure.
  • fermented and dried cupuas beans are boiled in boiling water for about 5 to 30 minutes under normal pressure, preferably for about 10 to 20 minutes.
  • the filled beans are placed on a colander, for example, to drain the water.
  • a heating steam treatment may be performed.
  • the heating steam treatment may be performed by a method known per se, may be performed under normal pressure, or may be performed under pressure.
  • the temperature is usually about 100 or more, preferably about 100: to about 200.
  • a cut is usually made in the epidermis while the epidermis is soft, for example, using a mechanical means such as a cutlery or a knife.
  • the removed endosperm is dried using, for example, a dryer, usually until the water content is about 6% by weight or less, and the endosperm is roasted by the above-mentioned means until the water content is about 2% by weight or less, for example, a grinder.
  • the endosperm is ground using, a crude cupuas is obtained, and this is pressed to produce a purified cupuas. Further, a preferred embodiment of the present invention is shown in FIG. 3 (abbreviated as method C).
  • Cupuas beans are roasted using a far-infrared ray device in the roasting process.
  • the far-infrared device may be any device that can irradiate far-infrared rays and roast cupuas beans.
  • the wavelength of far-infrared rays is preferably about 1 to 100, preferably about 4 to 50 m, and the number of units of the apparatus depends on the throughput of cupuas beans. Although it cannot be said unconditionally because it is greatly different, usually about 1,000 to 10,000 is sufficient.
  • the infrared source ceramic is preferably used as the heat source.
  • the temperature of the surface of the heat source is about 300 to 40 Ot, more preferably about 360 to 380, and the temperature of the cupuas beans at the time of irradiation with far infrared rays is about 100 to 15 Preferably, it is about 110 to 120.
  • the average distance between the far-infrared ray source and the cup beans is preferably about 5 to 15 cm.
  • the far-infrared irradiation time also depends on the amount of processing ⁇ Kupuas bean. Therefore, it is not possible to say unconditionally.
  • the irradiation time in such a case is usually about 5 to 30 minutes.
  • the cupuas beans are put into a hopper, from which they are fed, for example using a vibrator, preferably on a mesh conveyor.
  • the cupus beans on the mesh conveyor travel at a constant speed toward the far-infrared heater.
  • the mesh conveyor preferably oscillates in the traveling direction, its vertical direction and the vertical direction at least during the irradiation of far-infrared rays, and one or more grains of the cupuas beans on the mesh conveyor rotate slowly and distant. Be able to receive infrared rays evenly.
  • the fibrous outer shell (skin) and endosperm are separated from the endosperm in the subsequent threshing process in the case of roasting using a hot air roasting device or an open flame roasting device. It is much easier than.
  • the use of the far-infrared roasting process not only makes the threshing process easier than the roasting process using hot air or direct heat, and also allows the processed cupuas beans to have a better flavor. Become.
  • Threshing is carried out by removing the outer skin from roasted Kupuas beans.
  • roasted cupuas beans are crushed, for example, by using a crusher, and then, for example, sieved to remove the fibrous shell (skin), thereby separating and obtaining endosperm.
  • the crusher treatment and the sieving treatment may be repeated as appropriate until the hull of the endosperm is reduced to about 5% by weight or less.
  • far-infrared roasted cupuas beans The frequency of the above-mentioned repetition is remarkably reduced as compared with the case of using hot-air roasting or direct-fire roasting cupuas beans. This is a significantly different phenomenon from cocoa beans.
  • the endosperm thus obtained is subjected to a grinding treatment to produce a crude cupuas fat.
  • the thus obtained cupuas soybean endosperm is put into a mill and usually subjected to a two-stage grinding treatment to obtain a crude cupuas fat. That is, the first step is grinding through a blade mill to an average particle size of about 150 microns, and then the second step is grinding treatment by a ball mill to an average particle diameter of about 75 microns.
  • the first step is grinding through a blade mill to an average particle size of about 150 microns
  • the second step is grinding treatment by a ball mill to an average particle diameter of about 75 microns.
  • about 54 to 59% of fats and oils contained in the cupuas endosperm are dissolved by frictional heat, resulting in the formation of a paste, liquid or oil.
  • a refined cupuas is obtained.
  • the obtained crude Kupuas fat is subjected to squeezing treatment using, for example, an oil press to obtain a purified Kupuasu fat.
  • the refined cupuas fat is filtered under pressure.
  • the refined cupuas fat is filtered in a liquid state under pressure, and is liquid at about 4 Ot: or more under normal pressure, but becomes solid when the temperature is cooled. Therefore, the purified cupuas fat is separated and obtained in a liquid or solid state.
  • the crude cupuas fat is subjected to a squeezing treatment step, the crude cupuas fat is separated into a cake containing the purified cupuas fat and fiber.
  • the powder obtained by grinding this cake can be enjoyed as a fragrant drink, similar to cocoa.
  • Cupuas fat has a melting point higher than that of cocoa butter used in the production of tiyocholate.
  • a refined cupuas fat or a mixture of a crude cupuas fat and a refined cupuas fat with a low level of citrus-like confectionery when it is desired to increase the softening point of the thiocholate-like confection, May be replaced with cocoa butter.
  • the mixing ratio of the cupuas oil and fat to the cocoa butter is about 97: 3 to 60:40 by weight.
  • vegetable oil may be added to the above kneaded material in addition to milk powder, sugar and surfactant.
  • vegetable oils include palm oil, coconut oil, rapeseed oil and the like.
  • One or more of these additives may be blended.
  • a preferred example of a kneaded product in which such an additive is blended is as follows: 100 to 100 parts by weight of the kneaded product, crude Kupuas: 5 to 90 parts by weight, more preferably 10 to 80 parts by weight, purified Kupuas: 10 to 50 parts by weight, more preferably 20 to 40 parts by weight, sugar: 15 to 60 parts by weight, more preferably 20 to 50 parts by weight, lecithin: 0.01 to 1 part by weight Parts, more preferably 0.2 to 0.6 parts by weight.
  • cocoa butter When chocolate is produced from cocoa butter, a part of the cocoa butter may be replaced by cupuas fat.
  • the above kneaded material or a mixture thereof with puffs or nuts may be mixed and filled in a mold to produce a cupuas chocolate confectionery.
  • cream, nuts, biscuits, liqueurs, and the like are poured and filled into the cooled cupuas oil chocolate shell, and the lid is obtained, whereby a shellkua fat oil chocolate can be obtained.
  • (Saturated fatty acid / unsaturated fatty acid weight ratio) 1.121 1.754 The above numerical values can vary depending on the production area of the cupuas tree, cultivation conditions, and the like.
  • the weight ratio of saturated fatty acids to unsaturated fatty acids can vary from about 0.8 to 1.4.
  • the index of refraction can also exceed the range of 1.456 to 1.485 and vary within the range of 1.3 to 1.5.
  • refined cupuas fat can be mixed with oil-based processed foods such as margarine to improve quality and develop new health foods. It can be used as an suppository or ointment base as it is or after a slight hydrogenation-reduction treatment because it can improve the skin protection effect when incorporated into oily cosmetics and has a melting point close to human body temperature.
  • Seeds are collected from cupuas grown in a plantation near Manaus, the capital of the Brazilian Amazon river basin, and are fermented by a bacterium attached to the cupuas seeds in a fermenter for 5 to 7 days while the pulp remains attached. The pH dropped to 5.0-5.3 and the temperature rose to 42-45. Then transfer to a tray and dry in the sun for 7 days. Seeds with a major axis of 20 to 3 Omm, a minor axis of 16 to 2 Omm and a weight of 2 .:! To 2.5 gZ (varied within this range) ), A cupuas seed having a water content of 6 to 7% was obtained.
  • the fermented and dried cupuas seeds were cleaned by removing foreign substances with an electromagnet and removing dust with compressed air.
  • the cupuas beans thus obtained are put into a hopper, from which they are supplied to a mesh conveyor using a vibrator.
  • This mesh conveyor vibrates up and down, left and right, and in the direction of travel so that each and every cupuas bean receives heat of far-infrared rays evenly.
  • Ceramics are used as far infrared rays.
  • the number of cuts of the far-infrared heater was about 2000 W, the wavelength was 4 to 50 mm, the current was 10 A, and the distance between the cupuas beans and the heater was 8 cm on average.
  • the roasting conditions were controlled by the transit time and temperature of the far infrared plate.
  • the passing time (irradiation time) of the far-infrared heater was 10 minutes, and the temperature was 170 ° C.
  • the state of the outer skin (epidermis) became clearer, unlike the hot-air roast method.
  • good results can be obtained.
  • the obtained Kupuas endosperm is subjected to a primary grinding treatment by a blade mill, followed by a two-stage grinding treatment by a secondary grinding treatment by a ball mill or a one-stage fine grinding treatment to be applied to a pulverizer.
  • the liquid was reduced to 75 microns or less to obtain a liquid, and thus a crude cupuas fat was obtained.
  • the crude oil was further subjected to a hydraulic filter press to obtain a refined cupuas oil. Representative physical property values of the obtained purified cupuas oil and fat are shown in the above Test Examples.
  • Seeds were collected from Kupuas grown in a plantation near the city of Manaus in the Brazilian Amazon basin, and fermented with yeast attached to Kupuas seeds in a fermenter for 5-7 days while the pulp remained attached However, the pH dropped from 5.0 to 5.3, and the temperature rose from 42 to 45. Then transfer to a tray and dry in the sun for 7 days, major axis 20 to 30 mm, minor axis 16 to 20 m A cupuas seed having m and an average weight of 2.1 to 2.5 g_ / seed (varies in this range) and a water content of 6 to 7% was obtained.
  • the fermented and dried cupuas seeds are cleaned by removing foreign substances with an electromagnet and removing dust with compressed air.Then, they are put into a continuous roasting apparatus and almost heated with hot air at 130-150. Roasted for 20-30 minutes. As a result, the cupus seeds had an aromatic flavor with the water content reduced to almost 2%.
  • the roasted Kupuas seeds were sieved to remove dust and cracked beans, and then crushed to peel the endosperm shell, and then sieved with an 80-mesh sieve to obtain Kupuas endosperm. The sieved residue was returned to the first sieving step and crushed again.
  • the resulting cupuas endosperm has an average particle size of 75 microns by performing a primary milling treatment with a blade mill followed by a secondary milling process with a ball mill or a single-stage milling process with a fine mill. The following procedure was carried out to obtain a liquid, and thus a crude cupuas fat was obtained. The crude oil was further subjected to a hydraulic filter press to obtain a refined cupuas oil. Representative physical property values of the obtained refined cupuas oil and fat are shown in the above Test Examples.
  • Example 3 Production of chocolate-like confectionery (cupuas chocolate):
  • a prescribed amount of each of the above-mentioned raw material components is weighed and put into a mixer, mixed for 10 to 20 minutes at a temperature of 40 to 45 "C for 10 to 20 minutes according to the recipe, refined, and kneaded, and then the temperature is adjusted. After that, it was poured into a mold and then cooled to 10 to 15 to obtain each chocolate-like confectionery (Kupuas Chocolate) product.
  • Example 4 Compared to Western confectionery.
  • Boiling of Kupuas beans was performed in the following manner to produce crude Kupuas fats and oils.
  • the fermented and dried cupuas beans are boiled in boiling water for about 10 to 20 minutes. Put the boiled beans on top and drain. While the outer skin of the cupuas bean is soft, make a cut with a cutter and remove the endosperm.
  • the extracted endosperm is dried using a dryer until the water content is reduced to 6% by weight or less, then roasted in a hot air roasting machine until the water content is reduced to about 2% by weight or less, using a grinder. And grind.
  • a crude cupuas fat is obtained.
  • Example 1 To obtain a purified cupuas fat from the crude cupuas fat.
  • Example 3 Each type of chocolate-like confectionery (cupuaschocolate) was produced in exactly the same manner as in Example 3 except that the following formulation was used instead of the formulation of Example 3. This product is excellent in flavor and taste, comparable to chocolate-based western confectionery.
  • Example 3 Each type of chocolate-like confectionery (cupuaschocolate) was produced in exactly the same manner as in Example 3 except that the following formulation was used instead of the formulation of Example 3. This product is excellent in flavor and taste, comparable to chocolate-based western confectionery.
  • the unit of the compounding amount is all weight%.
  • tannic acid and 20 g of sodium bisulfite were finely ground into a powder in a mortar.
  • 50 g of potassium aluminum sulfate, 20 g of lidocaine and 20 g of dragon brain were ground into a powder in a mortar and sieved to collect particles of a certain particle size.
  • the two powders thus obtained were combined and thoroughly mixed until uniform. This mixture was further finely ground and mixed well, and then the refined cupuas oil melted was added thereto so that the total amount became 1000 g, and the resulting mixture was stirred to sufficiently melt the mixture.
  • This was placed in a suppository container to make a suppository formulation.
  • the weight of one suppository formulation was 1.5 g.
  • One suppository contains 0.15 g of succinic acid, 0.075 g of potassium aluminum sulfate, 0.03 g of lidocaine and 0.03 g of dragon brain.
  • Suppositories produced in this way are not only effective in treating rectal lesions based on mild hemorrhoids, etc., but also in the light of complications that occur after rectal and anal surgery, mainly post-operative sphincter spasm. It is effective in preventing pain caused by, controlling bacteriostats, inflammation, causing swelling, stopping pain, promoting normal and rapid growth of granulation cells, and promoting wound healing.

Abstract

Cupua fat originating in cupua seeds which is free from any excitants such as caffeine or theobromine and contributes to good health and health foods such as chocolate produced by using the same.

Description

明 細 書 クプアス種子由来の油脂、 その製造方法及びその用途 技術分野  Description Oils and fats derived from cupuas seeds, method for producing the same and uses thereof
本発明は、 クプ /ス (Cupuacu - Theobroma grandf i f l orum (Wi 1 l derow ex Sprengel) Schumann)由来のクプアス油脂を含有する例えばチョコレート様菓子 等健康食品などのクプアス油脂製品に係る。 背景技術  The present invention relates to a cupuas oil product such as a health food such as a chocolate-like confection, which contains a cupuas oil derived from cupuacu (Cupuacu-Theobroma grandfi florum (Wi1 derow ex Sprengel) Schumann). Background art
クプ,ス(Cupuacu)は、 Theobroma grandf i f lorum (Wi 1 l derow ex Sprenge l) Schumann の俗称であり、 Stercul i aceae科の Theobroma属に属する熱帯性植物 である。 この科は、 ほぼ 5 0の属と 7 5 0種の樹木(喬木及び灌木を含む)を包 含するが、その殆ど全ての樹種が熱帯性である。 Theobroma属は、 Androretalum、 Gl ossore t alum, Oreanthes> Te lmatocarpus, 及び Theobromaの六つの亜属に大 別され、 更に 2 2種に分類される。  Cupuacu is the common name of Theobroma grandf iflorum (Wi1 l derow ex Sprenge l) Schumann and is a tropical plant belonging to the genus Theobroma of the family Stercul i aceae. This family includes almost 50 genera and 75 species of trees (including arboreal and shrub), of which almost all species are tropical. The genus Theobroma is broadly classified into six subgenus, Androretalum, Glossos talum, Oreanthes> Telmatocarpus, and Theobroma, and is further classified into 22 species.
クプアスは、 Gl ossore t alum亜属の一品種であり、 Theobroma類に属する樹種 であって、 現在では南米アマゾン河流域において自生しまたは極く小規模なが ら栽培されており、 主として果肉が現地住民の食用に供されているほか、 小規 模ながら果肉がジュース、 ネクター、 ゼリー、 シャーベット、 アイスクリーム、 ヨーグルトなどにも加工されている。 この樹木は常緑の低木性であり、 日陰に よく適応し、 従って他の植物との共生に適しているとされている。 年間を通し て白または淡黄色の花を開き、 その後 1 . 2乃至 1 . 3 k gの実をつける。 こ の果実の果肉は全重量のほぼ 4 0 %程度を占め、 平均 3 0乃至 4 0個の種子を 含む。 種子は従来無用なものとして廃棄されるか、 せいぜい家畜の飼料とされ るのみであった。 発明の開示 Kupuas is a cultivar of the sub-genus Glososore t alum, a tree species belonging to Theobromas, and is currently grown natively or on a very small scale in the Amazon River basin in South America. In addition to being used by local residents, the flesh is processed into juice, nectar, jelly, sorbet, ice cream, yogurt, etc., on a small scale. The tree is an evergreen shrub that is well adapted to shade and is therefore suitable for symbiosis with other plants. Open white or pale yellow flowers throughout the year, and then produce 1.2 to 1.3 kg of fruit. The pulp of the fruit accounts for about 40% of the total weight and contains an average of 30 to 40 seeds. Seeds have traditionally been discarded as useless or, at best, used as livestock feed. Disclosure of the invention
本発明者らは、 クプアス樹が、 上述したようにアマゾン原産の日陰適応の高 い低木であり、 つまり熱帯雨林において他の樹種との共生能力が高く、 例えば 緑化に適したユーカリ、 ヤシなど植樹する所謂"ァグロフォレストリ"によって 熱帯雨林の荒廃跡地の緑化回復のために植林するのに特に適し、 熱帯雨林の保 存 ·回復と地域産業の振興に大いに寄与し得ると考えた。  The present inventors have proposed that the Kupuas tree is a shrub that is native to the Amazon and highly shade-adapted as described above, that is, it has a high symbiotic ability with other tree species in the tropical rainforest, and for example, planting eucalyptus and palm trees suitable for greening The so-called “agroforestry” is particularly suitable for planting trees to restore the revegetation of the degraded rainforest, and we believe that it can greatly contribute to the preservation and restoration of rainforests and the promotion of local industries.
クプアス種子の果肉は小規模ながら原住民によって食用に利用されているが、 クプアスの果実は既述したように大きくて多量の種子を有しており、 種子の重 量は果実のほぼ 1 7〜 1 8 %にも達するものの、 クプアス種子は、 通常埋め立 て処理によって廃棄されているのが現状である。 このクプアス種子の価値ある 有効利用が見出されれば、 クプアス樹の価値が上がることによって、 クプアス 樹の栽培が盛んとなり、 熱帯雨林の荒廃をも防ぐことが可能となる。  Although the pulp of Kupuas seeds is used by small indigenous people for small-scale consumption, the fruits of Kupuas have large and large amounts of seeds as described above, and the weight of the seeds is approximately 17- Despite reaching 18%, Kupuas seeds are usually disposed of by landfill. If a valuable and effective use of the Kupuas seeds is found, the value of the Kupuas tree will increase, which will increase the cultivation of the Kupuas tree and prevent the deforestation of the rainforest.
本発明者らは、 かかる状況に鑑みて現在殆ど無価値のクプアス種子の有効利 用について鋭意検討を重ねた結果、 クプアスの種子は、 低融点の良質の油脂を 多量に含んでいることを知見し、 さらに、 クプアスの種子を採集し、 これを例 えば洗浄、醱酵(醱酵前に洗浄を行ってもよい)、乾燥、特定の処理のよる焙煎、 特定の処理のよる脱殻、 粉砕および圧搾等の各工程に供することによって、 例 えば、 本発明の健康食品、 医薬、 化粧品の製造に有用な粗製又は精製クプアス 油脂が工業的に有利に製造出来ることを知見した。 なお、 本発明におけるクプ ァスは従来天然に存在するクプアスのみならず、 その変種であってよい。 すな わち、 クプアスと他の植物との交配又はクプァスの遺伝子技術処理によって得 られるクプアスの変種は下記する粗製クプアス又は精製クプアス油脂がそれか ら製造可能である限り、 いずれも本発明におけるクプアスであり、 このような クプアス変種から得られる油脂は本発明におけるクプアス油脂である。  In view of this situation, the present inventors have conducted intensive studies on the effective use of currently almost worthless cupuas seeds and found that the seeds of cupuas contain a large amount of low-melting high-quality oils and fats. In addition, the seeds of the cupuas are collected, which are, for example, washed, fermented (may be washed before fermentation), dried, roasted by a specific treatment, unhulled by a specific treatment, and crushed. It has been found that, for example, crude or refined cupuas oils and fats useful for the production of health foods, medicaments, and cosmetics of the present invention can be industrially advantageously produced by subjecting them to each step such as squeezing and pressing. In addition, the cupace in the present invention may be not only a naturally occurring cupath but also a variant thereof. That is, any of the varieties of cupuas obtained by crossing a cupuas with another plant or by genetic processing of a cupuas can be any of the cupuas according to the present invention as long as the following crude cupuas or purified cupuas fat can be produced therefrom. The fat or oil obtained from such a Kupuas variety is the cupuas fat or oil in the present invention.
さらに本発明者らは、 得られた精製クプアス油脂は、 融点が 2 9乃至 3 2 t: と体温に近く、 独特の脂肪酸組成を有すること、 精製クプアス油脂のこのよう な特徴を活かして、 精製クプアス油脂に所望により例えば砂糖、 粉乳、 植物油 (パーム油、 ココナツ油、 ナ夕ネ油など) 等の添加物を配合混入することによ つて優れた風味と味覚を有するチョコレート様の菓子類が得られること、 また マーガリン、 ホイップクリーム等の加工食品に精製クプアス油脂を適量配合す ればこれら加工食品の品質改良が可能であり、 さらに精製クプアス油脂は皮膚 保護効果の高いクリーム、 リップスティック等の油性化粧品、 例えば座薬、 軟 膏などの医薬の基剤としても有用であることを知見した。 なお粗製クプアス油 脂も精製クプアス製品と同様の有用性を有するので、 粗製クプアス油脂は単独 であるいは精製クプアス油脂と組合わせて、 精製クプアスと同様に油脂原料と して種々の分野で使用することができる。 Furthermore, the present inventors have obtained the purified cupuas fat, melting point is 29 to 32 t: By taking advantage of these characteristics of refined cupuas fat, it has a unique fatty acid composition that is close to body temperature, and refined cupuas fat can be used as required for refined cupuas fat, for example, sugar, powdered milk, vegetable oil (palm oil, coconut oil, nayu oil, etc.) Can be used to obtain chocolate-like confectionery that has excellent flavor and taste, and to mix processed foods such as margarine and whipped cream with an appropriate amount of refined cupuas fats and oils. It has been found that it is possible to improve the quality of foods, and that refined cupuas fat is also useful as a base for oily cosmetics such as creams and lipsticks with high skin protection effects, and pharmaceuticals such as suppositories and ointments. Crude cupuas fats have the same utility as refined cupuas products, so crude cupuas fats alone or in combination with refined cupuas fats should be used in various fields as raw fats and oils like refined cupuass. Can be.
さらに、 本発明者らは下記する知見をも得た。  Furthermore, the present inventors have also obtained the following findings.
粗製クプアス油脂又は精製クプアス油脂の第一の特徴は、 カフエインゃテオ プロミンなど刺激性の強い覚醒作用を有する生理活性物質を実質的に含有しな いこと及び融点が 2 9〜 3 3 というヒト体温に近いことにあり、 その融解特 性は極めてシャープであり、 スーパークーリング性を示し、 固化時に体積収縮 を伴い、 また多結晶形を示す。 またその代表的な物理化学的性状および脂肪酸 組成が下記に示す通りであり、 カカオバターと比較してァラキジン酸含有量が ほぼ 9倍以上またォレイン酸とリノール酸の含有量も 1 . 3倍程度高く、 従つ て飽和脂肪酸/不飽和脂肪酸比率は 1 . 0〜1 . 1であることが分かる。 ォレイ ン酸、 リノール酸、 ァラキジン酸やべヘン酸含量が有意に高いのであるが、 特 にォレイン酸とリノール酸等一価不飽和脂肪酸は、 多価不飽和脂肪酸に比べて 生体内で活性酸素による酸化を受けにくく而も血液中のコレステロールや中性 脂肪を低下させる活性は同等であるので、 精製クプアス油脂は、 生活習慣病な どの予防や健康維持に資する健康食品として有用である。 本発明に従えば、 上 記したようにクプアス油脂を使用してチョコレート様菓子が製造できる。 クプ ァス油脂は、 チョコレートの原料となるカカオバターとは異なり、 例えばカフ エインゃテオプロミン等の覚醒物質を実質的に含まない、 従って、 クプアス油 脂を使用してチョコレート様菓子等の食品はチヨコレートよりも健康上より好 ましい。 The first characteristic of crude or purified cupuas fat is that it does not substantially contain physiologically active substances having a strong stimulating arousal effect, such as caffeine and theopromin, and has a human body temperature of 29 to 33 with a melting point of 29 to 33. Its melting characteristics are extremely sharp, exhibit supercooling properties, accompany volume shrinkage upon solidification, and exhibit a polycrystalline form. The typical physicochemical properties and fatty acid composition are as shown below, and the content of arachidic acid is about 9 times or more and the content of oleic acid and linoleic acid is about 1.3 times that of cocoa butter. It can be seen that the ratio of saturated fatty acids / unsaturated fatty acids is high and is therefore between 1.0 and 1.1. Although the contents of oleic acid, linoleic acid, arachidic acid and behenic acid are significantly higher, monounsaturated fatty acids such as oleic acid and linoleic acid are more active oxygen in vivo than polyunsaturated fatty acids. Purified cupuas fat is useful as a health food that contributes to prevention of lifestyle-related diseases and maintenance of health, since it is less susceptible to oxidation by water and has the same activity of lowering cholesterol and neutral fat in blood. According to the present invention, a chocolate-like confection can be produced using the cupuas fat as described above. Kupu Unlike cocoa butter, which is a raw material for chocolate, for example, cocoa butter does not substantially contain stimulants such as caffeine and theopromine.Therefore, foods such as chocolate-like confections using cupuas fat are less than thiocholate. Are also preferred over health.
又さらに、 チョコレートはカフェイン及びテオプロミンなどの刺激作用物質、 興奮作用物質乃至覚醒物質を含むために妊婦がチョコレートを摂食することは 嫌がられるが、 このような作用物質を実質的に含まないクプアス種子由来の油 脂をカカオバターの代わりに用いて製造したチョコレ一ト様菓子はチヨコレー トと類似した味、 風味を有するから、 妊婦がクプアス油脂から製造したチョコ レート様菓子 (クプアスチョコレート) をチョコレート菓子の代用として食し ても何ら問題が無い。 ミルクチョコレートにはラクト一スアレルギーの問題が ある。 ミルクにはラクトースが含まれ、 ミルクやミルクを含有する例えばミル クチョコレートを喫食するとじんましんが出たり、 下痢症状を引き起こすァレ ルギー症状が存在する。 クプアスチョコレートはミルクを積極的に加えて製造 しなくとも、 マイルドな風味があって、 ミルクチョコレートとよく似た風味を 呈する。 従って、 クプアス油脂から製造したチョコレート様菓子を食すること は、 チョコレートを食するよりも健康の維持もしくは増進に役立つ。 このこと も本発明者らの新発見である。  Furthermore, since chocolate contains stimulants, stimulants or stimulants such as caffeine and theopromine, pregnant women are reluctant to eat chocolate, but they do not substantially contain such agents. Chocolate-like confections made using cupuas seed-derived fats and oils instead of cocoa butter have a similar taste and flavor to thiocholate, so pregnant women can use chocolate-like confections (kupuas chocolates) made from cupuas fats and oils. There is no problem eating it as a substitute for chocolate confectionery. Milk chocolate has the problem of lactose allergy. Milk contains lactose, and eating milk and milk-containing milk chocolate, for example, produces hives and allergies that cause diarrhea. Cupuas chocolate has a mild flavor, similar to milk chocolate, without the need to actively add milk to produce it. Therefore, eating chocolate-like confections made from kupuas fats helps maintain or improve health over eating chocolate. This is also a new discovery of the present inventors.
本発明者らは、 さらにクプアス油脂並びにそれから製造されるチヨコレート 様菓子について鋭意検討を重ねた結果、 クプアス油脂を用いてチョコレート様 菓子を製造するに際して、 さらにレシチンを配合するとクプアス油脂の粘度が 下がって作業性がよくなるうえ、 製造されたチョコレート様菓子に滑らかな舌 ざわりの風味を与えること、 クプアス油脂の融点が低く、 地域によってあるい は気温によってはクプアス油脂及びチヨコレート様菓子の取り扱いが困難とな る場合があるが、 このような場合、 融点調整剤としてカカオバターをクプアス 油脂又はチョコレート様菓子に配合するとこのような問題点が解決することを 発見した。 The present inventors have further conducted intensive studies on cupuas oils and fats and tychocholate-like confections produced therefrom. Workability is improved, and the chocolate-like confectionery produced has a smooth tongue-like flavor, and the melting point of cupuas fat is low. In such a case, if cocoa butter is blended with cupuas oil or fat or chocolate-like confectionery as a melting point modifier, such problems can be solved. discovered.
本発明者らは、 クプアス油脂が、 クプアス種子を醱酵させてクプアス豆を得 る第 1工程と、 クプアス豆を焙煎し、 脱穀して胚乳を採取し、 これを磨砕して 粗製クプアスを得る第 2工程と、 さらに所望により粗製クプアス油脂を圧搾し て精製クプアスを得る第 3工程を含む製造方法によって工業的に製造できるこ とを知見した。  The present inventors have studied a first step in which Kupuas oil or fat is fermented with Kupuas seeds to obtain Kupuas beans, roasting Kupuas beans, threshing and collecting endosperm, and grinding this to obtain crude Kupuas. It has been found that the production can be carried out industrially by a production method including a second step of obtaining a purified cupuas by pressing a crude cupuas fat and oil, if desired, and a purified step.
又、 本発明者らは、 クプアス油脂のさらに工業的に有利な製造方法について 検討を重ねた結果、 カカオ豆の場合は醱酵後のカカオ豆を常用の熱風式焙煎機 又は直火式焙煎機で焙煎することにより外皮が簡単にはがれ、 胚乳を容易に採 取することができるが、 クプアス種子から胚乳を採取するのはカカオ豆の場合 のように容易ではないことを知見した。  In addition, the inventors of the present invention have repeated studies on a more industrially advantageous method for producing cupuas fats and oils. As a result, in the case of cacao beans, the cacao beans after fermentation are used in a hot air roasting machine or a direct fire roasting machine. It was found that roasting in a roasting machine easily peels the hull and allows easy collection of endosperm, but it is not as easy as in cocoa beans to collect endosperm from cupuas seeds.
すなわち、 醃酵後のクプアス種子の外皮は、 カカオ豆の外皮とは異なり、 弾 力性があるが分厚くて硬く、 カカオ豆と異なり焙煎しても外皮は容易にはがれ ない。 クラッシャー等の機械的手段で粗砕して破碎された胚乳と外皮を分別す るが胚乳が外皮にくっつく割合が高く、 胚乳のみの収率は低い。 外皮は渋く、 舌ざわりが悪いので、 外皮がくつついている胚乳は食用としては好ましくない。 そこで胚乳がくっついている外皮を上記機械手段で破砕して、 胚乳、 外皮と胚 乳がついた外皮とを分別し、 さらに胚乳がついた外皮を機械的手段で破砕し、 分別する操作を繰り返すことによって、 胚乳を収率よく取得することを試みて も収率は約 4 0 %程度と低く、 操作が複雑となり、 時間もかかる。 本発明者ら は、 クプアス種子の場合は、 カカオ豆の場合とは異なり、 胚乳と外皮との間に 油分が多く存在し、 この油分が胚乳と外皮とを固着していて、 胚乳が外皮と離 れにくくしていることを知見した。  In other words, the hull of the cupuas seed after fermentation is different from the hull of cocoa beans, but it is elastic but thick and hard, and unlike cocoa beans, the hull does not come off easily even when roasted. The endosperm and the hull are separated by mechanical means such as a crusher or the like, but the endosperm adheres to the hull at a high rate, and the yield of endosperm alone is low. Because the outer skin is sour and the tongue feels bad, endosperm with a hull is not good for food. Therefore, the hull with the endosperm is crushed by the above mechanical means, the endosperm, the hull and the hull with the endosperm are separated, and the hull with the endosperm is crushed by the mechanical means and repeated. Thus, even if an attempt is made to obtain endosperm with a high yield, the yield is as low as about 40%, and the operation becomes complicated and takes time. The present inventors have found that, in the case of cupuas seed, unlike the case of cocoa beans, a large amount of oil exists between the endosperm and the hull, and this oil adheres the endosperm and the hull, and the endosperm is We found that it was difficult to separate.
本発明者らは、 この問題点を解決するために鋭意検討を重ねた結果、 醱酵後 のクプアス種子すなわち、 クプアス豆を熱風式焙煎機や直火式焙煎機を用いず、 遠赤外線を用いてクプアス豆を焙煎することにより予想外に胚乳が外皮と離れ 易くなり、 上記問題点が解決されることを知見した。 As a result of intensive studies to solve this problem, the present inventors have found that fermented cupuas seeds, i.e., cupuas beans, are not far-infrared without using a hot-air roasting machine or a direct-fired roasting machine. Roasting cupuas beans using coconut oil causes unexpected separation of endosperm from hull It has been found that the above-mentioned problems can be solved.
又さらに、 本発明者らは思いがけなくも、 クプアス豆を高温水又は加熱水蒸 気と接触させた後、 クプアス豆の外皮に切れ目を入れ、 切れ目部分から胚乳を 取り出すかあるいは外皮を取り除くことによって上記問題点が解決され、 この 操作によってクプアス油脂が工業的にさらに有利に製造できることを知見した。 すなわち、 本発明は  Furthermore, the present inventors unexpectedly contacted the cupuas beans with high-temperature water or heated water steam, then cut the outer skin of the cupuas beans and removed the endosperm from the cuts or removed the outer skin. The problem was solved, and it was found that this operation enables industrially more advantageous production of cupuas fats and oils. That is, the present invention
( 1 ) クプアス種子を醱酵させてクプアス豆を得る第 1工程と、 クプアス豆 を遠赤外線で焙煎し、 脱穀して胚乳を採取、 これを磨砕して粗製クプアスを得 る第 2工程と、 さらに所望により粗製クプアス油脂を圧搾して精製クプアス油 脂を得る第 3工程からなるクプアス油脂の製造方法、  (1) First step of fermenting cupuas seeds to obtain cupuas beans, second step of roasting cupuas beans with far-infrared rays, threshing and collecting endosperm, and grinding this to obtain crude cupuas And, if desired, a method for producing a cupuas fat comprising a third step of squeezing the crude cupuas fat to obtain a purified cupuas fat.
( 2 ) クプアス種子を醱酵させてクプアス豆を得る第 1工程と、 クプアス豆 を高温水又は加熱水蒸気と接触させた後、 クプアス豆の表皮に切れ目を入れ、 クプアス豆表皮の切れ目部分から胚乳を採取し、 これを焙煎し、 次いで磨砕し て粗製クプアス油脂を得る第 2工程と、 さらに所望により粗製クプアス油脂を 圧榨して精製クプアス油脂を得る第 3工程からなるクプアス油脂の製造方法、 (2) The first step of fermenting Kupuas seeds to obtain Kupuas beans, and after bringing Kupuas beans into contact with high-temperature water or heated steam, make a cut in the epidermis of Kupuas beans, And then roasting and then grinding to obtain a crude Kupuas fat, and, if desired, a third step of compressing the crude Kupuas fat to obtain a refined Kupuasu fat and oil. Method,
( 3 ) 前記 (1 ) 又は (2 ) に記載の粗製クプアス油脂又はノ及び精製クプ ァス油脂とレシチン又は 及びカカオバタ一を含有することを特徴とする健康 食 cm、 (3) a healthy diet characterized by containing the crude cupuas fat or oil according to the above (1) or (2) and the purified cupuas fat and lecithin or cacao butter;
( 4 ) さらに砂糖、 粉乳、 パ一ム油、 ココナツ油及びナ夕ネ油からなる群か ら選ばれる 1種以上を含有することを特徴とする前記(3 )に記載の健康食品、 ( 5 ) チョコレート様菓子又はチョコレート代替物である前記( 3 )又は( 4 ) に記載の健康食品、  (4) The health food according to the above (3), further comprising at least one selected from the group consisting of sugar, powdered milk, palm oil, coconut oil, and pine oil. ) The health food according to the above (3) or (4), which is a chocolate-like confection or a chocolate substitute,
( 6 ) 粗製クプアス油脂又は精製クプアスを含有することを特徴とする加工 食品、 医薬品又は化粧品、 及び  (6) Processed foods, pharmaceuticals or cosmetics characterized by containing crude kupuas fats or refined kupuas, and
( 7 ) 粗製クプアス油脂の加圧処理によって精製クプアス油脂から分離され る繊維質を含有するケーキ又はそれを粉砕して得られる粉状物、 (7) The crude Kupuas fat is separated from the refined Kupuas fat by pressure treatment. Cake containing fibrous material or powder obtained by crushing it,
に関する。 図面の簡単な説明 About. BRIEF DESCRIPTION OF THE FIGURES
第 1図は A方法による、 クプアス油脂の代表的製造工程図を示す。  Fig. 1 shows a typical production process of Kupuas fat by Method A.
第 2図は B方法による、 粗製クプアス油脂及び精製クプアス油脂の製造工程 図を示す。  Fig. 2 shows the production process of crude Kupuas fat and refined Kupuasu fat by Method B.
第 3図は C方法による、 本発明の好ましい実施態様を示す。 発明を実施するための最良の形態  FIG. 3 shows a preferred embodiment of the present invention according to the C method. BEST MODE FOR CARRYING OUT THE INVENTION
クプアス油脂の代表的製造工程図を第 1図に示す。  Fig. 1 shows a typical production process of Kupuas oil and fat.
本発明の好ましい実施の態様を下記に詳述する。 ただし以下の説明で 「%」 は 「重量%」 を表わす。  Preferred embodiments of the present invention are described in detail below. However, in the following description, “%” represents “% by weight”.
クプアスの樹から採取された果実は核果であり、 既述したように平均重量が 1 k g前後であり、 そのうち果肉の占める割合はほぼ 4 0 %近くに達し、 ぺク チンとクェン酸の含有率が高く、 美味であり、 したがってそのまま生食に供さ れるほか、 ジュース、 アイスクリーム、 ゼリー、 ヨーグルトなどの加工食品の 製造に原料として用いるのに適しており、 このような加工食品の製造装置を設 置することによって、 副生する種子の採集 ·集荷は極めて容易かつ衛生的とす ることができる。  The fruits collected from the Kupuas tree are drupes, with an average weight of about 1 kg as described above, of which the pulp accounts for almost 40%, and the content of pectin and cuenic acid. It is high in taste and delicious, so it can be served as it is, and is suitable for use as a raw material in the production of processed foods such as juice, ice cream, jelly, and yogurt. By collecting them, the collection and collection of by-produced seeds can be made extremely easy and sanitary.
かくして集荷選別したクプアス種子は、 例えば下記する醱酵、 乾燥から始ま るクプアス製造プロセスに供することによって粗製クプアス油脂また更には精 製クプアス油脂とすることができる。  The cupuas seed thus collected and sorted can be subjected to, for example, the following kupuasu production process starting from the following fermentation and drying to obtain a crude kupuas fat or a refined kupuas fat.
即ち、 クプアス種子を所望により水で濯いだ後、 適宜の大きさの密閉可能な 木製またはプラスチック製の箱に収納し、 密閉すれば、 付着している酵母が自 然に増殖して醱酵が開始する。 醱酵は 5〜7日進行するが、 クプアス種子のま わりについた繊維質のパルプに含まれた多糖類がアルコール醱酵によってアル コールに分解され、 さらに酢酸醱酵によって酢酸が生じ、 その結果腐敗しやす レ 余分な繊維質が除去される。 That is, after rinsing the cupuas seeds with water as desired, the seeds are stored in a sealable wooden or plastic box of an appropriate size, and if sealed, the attached yeast grows naturally and ferment. Starts.醱 The fermentation proceeds for 5-7 days, Instead, the polysaccharides contained in the fibrous pulp are decomposed into alcohol by the alcohol fermentation, and acetic acid is generated by the acetic acid fermentation.
醱酵工程を経たクプアス種子は、 ついで適宜のマツト上に広げて天日乾燥又 は加温下の強制乾燥に供され、 含水率が 5 5 %程度からほぼ 6 %以下になるま で乾燥され、 かくして貯蔵保管が可能な状態となる。 醱酵が終了したクプアス 種子は、 例えば乾燥中に付着したゴミ、 埃などをふるい等で除去する。 そして ジユートまたは麻製などの適宜の大きさの袋に充填し、 クプアス油脂製造プロ セスに供するまで貯蔵、 輸送される。  ク The Kupuas seeds that have passed through the fermentation process are then spread on appropriate mats and subjected to solar drying or forced drying under heating to dry the water content from about 55% to almost 6% or less. Thus, storage and storage are possible.ク Kupuasu seeds after fermentation are removed, for example, by sifting dirt and dust attached during drying. They are then filled into bags of appropriate size, such as jute or hemp, and stored and transported until used in the cupuas oil production process.
清浄浄化工程においては、 醱酵乾燥処理したクプアス種子の中に混入した小 石、 金属類、 塵芥、 粉塵などのほかフラット豆、 ダブル豆などの挟雑物をフル ィ装置、 電磁石や圧縮空気また小型の除塵機などを適宜に組み合わせて利用し て除去するのである。 清浄浄化工程を終えたクプアス種子はクプアス豆とも称 される。 なお清浄浄化工程は醱酵工程前に行なってもよい。  In the purification process, pebbles, metals, garbage, dust, etc. mixed in fermented and dried cupuas seeds, as well as contaminants such as flat beans and double beans, are screened with a filtration device, an electromagnet, compressed air, or the like. It is removed by using a small dust collector in combination as appropriate. Kupuas seeds that have completed the purification process are also referred to as Kupuas beans. The cleaning and purifying step may be performed before the fermentation step.
清净浄化処理されたクプアス種子 (クプアス豆) は、 焙煎工程において焙煎 され、 その結果クプアス種子の含水率はほぼ 6 %から 2 %にまで低下せしめら れ、 この後の工程である脱殻工程において繊維性の外殻シェルと胚乳の分離を 容易にする。 かかる焙煎は、 通常コーヒー、 ココアなどの焙煎で常用される熱 風式あるいは直火式焙煎機を用いてクプアス種子の品温をほぼ 1 3 0〜 1 5 0 の高温に 2 0乃至 3 0分間保持することによって行われる。  The purified Kupuas seeds (Kupuas beans) are roasted in the roasting process, and as a result, the water content of the Kupuas seeds is reduced from almost 6% to 2%, and the subsequent shelling process Facilitates the separation of the fibrous outer shell and endosperm. In such roasting, the temperature of the cupuas seeds is raised to a high temperature of about 130 to 150 using a hot-air or direct-fired roasting machine commonly used for roasting coffee, cocoa, and the like. Performed by holding for 30 minutes.
かくして焙煎処理されたクプアス種子は、 クラッシャーにかけて粗砕し、 つ いでフルィ処理して繊維性のシェル (外皮) を剥離除去して胚乳を分別取得す る。 なお、 クラッシャー処理とフルイ処理は、 外皮が約 5重量%程度以下にな るまで適宜反復繰り返して行う。 かくして得られたクプアス種子胚乳は、 ミル の中に投じて通常は二段階の磨砕処理を行うことによって粗製クプアス油脂が 得られる。 すなわち、 第一段階はブレードミルを通して平均粒径 1 5 0ミクロ ン程度にまで磨砕し、 次いで第二段階としてボールミルにより平均粒径 7 5ミ クロン程度にまで磨砕処理するのである。 このような磨砕処理においては、 摩 擦熱によってクプアス胚乳中にほぼ 5 4〜 5 9 %含まれる油脂が溶解して、 ぺ 一スト状又は液状乃至油状を呈するに至る。 得られる粗製クプアス油脂を、 例 えば油圧プレスを用いて圧搾処理すれば精製クプアス油脂が得られる。 このェ 程によって、 精製クプアス油脂が加圧下に濾過される。 精製クプアス油脂は加 圧下に液状で濾過され、 常圧下約 4 0 以上では液状であるが、 温度が冷える と固状となる。 従って精製クプアス油脂は液状又は固状で分離取得される。 さ らに、 粗製又は精製クプアス油脂はクプアス種子を醱酵処理して乾燥し、 外殻 (外皮) を除去することなく、 そのまま加圧下に粉碎し、 加圧濾過することに よっても製造される。 このようにして例えば上記二方法によって製造される。 粗製又は精製クプアス油脂の油脂含量は約 4 0〜 6 5重量%程度である。 The roasted Kupuas seeds are crushed in a crusher, and then sieved to remove the fibrous shell (skin) to separate and obtain endosperm. The crusher treatment and the sieving treatment are repeated as appropriate until the outer skin becomes about 5% by weight or less. The thus obtained cupuas seed endosperm is poured into a mill and usually subjected to a two-stage grinding treatment to obtain a crude cupuas fat. In the first stage, the average particle size is 150 micron through a blade mill. In the second stage, it is ground by a ball mill to an average particle size of about 75 microns. In such a grinding treatment, about 54 to 59% of fats and oils contained in the cupuas endosperm are dissolved by the frictional heat, resulting in the formation of a paste or liquid or oil. If the obtained crude Kupuas fat is subjected to squeezing treatment using, for example, a hydraulic press, a purified Kupuasu fat is obtained. By this process, the refined cupuas fat is filtered under pressure. Refined cupuas fat is filtered in liquid form under pressure, and is liquid at about 40 or more under normal pressure, but becomes solid when the temperature is cooled. Therefore, the purified cupuas fat is separated and obtained in a liquid or solid state. In addition, crude or refined cupuas oils and fats are also produced by fermenting and drying cupuas seeds, pulverizing under pressure without removing the outer shell (skin), and filtering under pressure. . Thus, for example, it is manufactured by the above two methods. The fat content of the crude or purified cupuas fat is about 40 to 65% by weight.
さらに、 上記の製造方法 (以下 A方法路略称する) において、 醱酵および乾 燥して得られるクプアス豆を焙煎前にボイルすることにより外皮を柔らかく、 剥ぎ易くした後に胚乳を取り出し、 胚乳を焙煎してもよい。 すなわち第 2図に 示す工程図に従って粗製クプアス油脂および精製クプアスを製造してもよい (B方法と略称することもある)。 この場合は、 最初の工程図による場合に比し て、 クプアス油脂の収率が驚くべきことに約 3 0 %程度向上する。 B方法における 「醱酵」、 「乾燥」、 「焙煎」、 「脱穀」、 「磨碎」 及び 「圧搾」 の 処理は A方法における対応する処理を同様に行われてよい。  Further, in the above production method (hereinafter abbreviated as Method A), the outer skin is softened and boiled before the roasting of the cupuas beans obtained by fermentation and drying, so that the endosperm is taken out, and then the endosperm is taken out. You may roast. That is, a crude cupuas fat and oil and a purified cupuas may be produced according to the process diagram shown in FIG. 2 (sometimes abbreviated as method B). In this case, the yield of the cupuas oil and fat is surprisingly improved by about 30% as compared with the case according to the first process chart. The processes of “fermentation”, “drying”, “roasting”, “threshing”, “milling” and “pressing” in Method B may be performed in the same manner as the corresponding processes in Method A.
B方法における 「焙煎」 処理は下記する遠赤外線装置を使用する焙煎であつ てもよいが、 熱風式焙煎機又は直火式焙煎機を使用する焙煎処理であってよく、 熱風焙煎と直火焙煎は、 カカオ豆の焙煎と同様に行われてよい。 クプアス豆の 熱水又は加熱水蒸気との接触は好ましくはクプアス豆を水中ボイルすることに よって行われる。 この場合の好ましい実施の態様を以下に記載する。 The “roasting” treatment in the method B may be roasting using a far-infrared ray device described below, but may be roasting treatment using a hot-air roasting machine or a direct-fired roasting machine. Roasting and open fire roasting may be performed similarly to roasting cocoa beans. Contacting the cupuas with hot water or steam is preferably done by boiling the cupuas in water. A preferred embodiment in this case is described below.
ボイル処理は自体公知の手段に従って行ってよく、 常圧下若しくは加圧下に 行ってよい。 通常は醱酵、 乾燥したクプアス豆を常圧下約 5〜3 0分程度、 好 ましくは約 1 0〜2 0分程度、 沸縢している水中でボイルする。 好ましくはポ ィルした豆を例えばザル等にのせ水分を切る。  The boil treatment may be performed according to a means known per se, and may be performed under normal pressure or under pressure. Usually, fermented and dried cupuas beans are boiled in boiling water for about 5 to 30 minutes under normal pressure, preferably for about 10 to 20 minutes. Preferably, the filled beans are placed on a colander, for example, to drain the water.
上記のボイリング処理の代わりに、 加熱水蒸気処理してもよい。 加熱水蒸気 処理は自体公知の手段で行ってもよく、 常圧下で行ってもよいし、 加圧下に行 つてもよい。 温度は通常は 1 0 O 以上好ましくは約 1 0 0 :〜 2 0 0で程度 である。  Instead of the above-described boiling treatment, a heating steam treatment may be performed. The heating steam treatment may be performed by a method known per se, may be performed under normal pressure, or may be performed under pressure. The temperature is usually about 100 or more, preferably about 100: to about 200.
表皮に切れ目を入れるのは、 通常は表皮が柔らかいうちに例えばカツ夕一、 ナイフ等の機械的手段で表皮に切れ目を入れる。 人力又は機械で切れ目の部分 から胚乳を取り出す。 好ましくは取り出した胚乳を例えば乾燥機を使用して、 通常は水分が約 6重量%以下になるまで乾燥し、 胚乳を上記手段により水分が 約 2重量%以下となるまで焙煎し、 例えばグラインダーを用いて、 胚乳を磨砕 して、 粗製クプアスを得て、 これを圧搾することによって精製クプアスを製造 する。 さらに、 本発明の好ましい実施態様を第 3図に示す (C方法と略記する)。 C方法を下記に詳述する。 ただし以下の説明で「%」 は「重量%」 を表わす。 C方法において、 「醱酵」、 「乾燥」、 「脱穀」、 「磨砕」 及び 「圧搾」 は A方法又 は B方法と同様に行われてよい。 従って、 クプアス種子を醱酵及び乾燥処理し てクプアス豆を製造する工程は A方法又は B方法と同じでよい。  A cut is usually made in the epidermis while the epidermis is soft, for example, using a mechanical means such as a cutlery or a knife. Remove the endosperm from the cut with human power or machine. Preferably, the removed endosperm is dried using, for example, a dryer, usually until the water content is about 6% by weight or less, and the endosperm is roasted by the above-mentioned means until the water content is about 2% by weight or less, for example, a grinder. The endosperm is ground using, a crude cupuas is obtained, and this is pressed to produce a purified cupuas. Further, a preferred embodiment of the present invention is shown in FIG. 3 (abbreviated as method C). The C method is described in detail below. However, in the following description, “%” represents “% by weight”. In method C, “fermentation”, “drying”, “threshing”, “milling” and “pressing” may be performed in the same manner as in method A or method B. Therefore, the step of fermenting and drying the cupuas seeds to produce cupuas beans may be the same as the method A or the method B.
クプアス豆は焙煎工程において遠赤外線装置を用いて焙煎される。 遠赤外線 装置は、 遠赤外線を照射し、 クプアス豆を焙煎することができるものであれば どのようなものでもよい。 遠赤外線の波長は好ましくは約 1〜 1 0 0 程度、 好ましくは 4〜 5 0 m程度で、 装置のヮット数はクプアス豆の処理量によつ て大きく異なるため一概にはいえないが、 通常は約 1 , 0 0 0〜1 0, 0 0 0 程度でよい。 赤外線源としては、 セラミックをヒー夕一として用いるのが好ま しい。 ヒー夕一表面の温度は約 3 0 0〜4 0 O t程度、 より好ましくは約 3 6 0〜3 8 0 程度とし、 遠赤外線照射時のクプアス豆の品温を約 1 0 0〜 1 5 、 好ましくは約 1 1 0〜1 2 0でとするのが好ましい。 遠赤外線源とクプ ァス豆との距離は平均約 5〜1 5 c m程度が好ましい。 遠赤外線照射時間も処 理量ゃクプアス豆の状態により異なるため、 一概にはいえないがクプアス豆の 含水量が約 6 %から 2 %程度以下になるまで遠赤外線を照射する。 そのような 場合の照射時間は通常 5〜 3 0分程度である。 Cupuas beans are roasted using a far-infrared ray device in the roasting process. The far-infrared device may be any device that can irradiate far-infrared rays and roast cupuas beans. The wavelength of far-infrared rays is preferably about 1 to 100, preferably about 4 to 50 m, and the number of units of the apparatus depends on the throughput of cupuas beans. Although it cannot be said unconditionally because it is greatly different, usually about 1,000 to 10,000 is sufficient. As the infrared source, ceramic is preferably used as the heat source. The temperature of the surface of the heat source is about 300 to 40 Ot, more preferably about 360 to 380, and the temperature of the cupuas beans at the time of irradiation with far infrared rays is about 100 to 15 Preferably, it is about 110 to 120. The average distance between the far-infrared ray source and the cup beans is preferably about 5 to 15 cm. The far-infrared irradiation time also depends on the amount of processing ゃ Kupuas bean. Therefore, it is not possible to say unconditionally. The irradiation time in such a case is usually about 5 to 30 minutes.
クプアス豆をホッパーに投入して、 そこから例えばバイブレーターを用いて 好ましくはメッシュコンベア上に、 供給する。 メッシュコンベア上のクプァス 豆は一定速度で遠赤外線ヒーターに向かって進行する。 少なくとも遠赤外線の 照射を受ける間、 メッシュコンベアは好ましくは進行方向、 その垂直方向及び 上下方向に振動して、 メッシュコンベア上のクプアス豆の一粒、 一粒がゆつく りと回転して、 遠赤外線を均等に受けられるようにする。  The cupuas beans are put into a hopper, from which they are fed, for example using a vibrator, preferably on a mesh conveyor. The cupus beans on the mesh conveyor travel at a constant speed toward the far-infrared heater. The mesh conveyor preferably oscillates in the traveling direction, its vertical direction and the vertical direction at least during the irradiation of far-infrared rays, and one or more grains of the cupuas beans on the mesh conveyor rotate slowly and distant. Be able to receive infrared rays evenly.
この遠赤外線焙煎処理により、 この後の工程である脱穀工程における繊維性 の外殻シェル (外皮) と胚乳との分離が熱風式焙煎装置又は直火式焙煎装置を 用いる焙煎の場合に比して随分と容易にある。  By this far-infrared roasting process, the fibrous outer shell (skin) and endosperm are separated from the endosperm in the subsequent threshing process in the case of roasting using a hot air roasting device or an open flame roasting device. It is much easier than.
このように、 遠赤外線焙煎処理を用いると、 熱風又は直火による焙煎処理に 比して、 脱穀処理がより簡単なものとなるばかりでなく、 処理されたクプアス 豆がより優れた風味になる。  As described above, the use of the far-infrared roasting process not only makes the threshing process easier than the roasting process using hot air or direct heat, and also allows the processed cupuas beans to have a better flavor. Become.
脱穀処理は、 焙煎処理したクプアス豆から外皮を除去することにより行われ る。 通常は焙煎したクプアス豆を例えばクラッシャーにかけて粗砕し、 次いで 例えばフルイ処理して繊維性のシェル(外皮)を除去して胚乳を分別取得する。 クラッシャー処理とフルイ処理は、 胚乳についている外皮が約 5重量%以下に. なるまで適宜繰り返してよい。 遠赤外線焙煎処理したクプアス豆を用いると、 熱風焙煎処理又は直火焙煎処理したクプアス豆を用いる場合に比して、 上記の 繰り返しの頻度が顕著に減少する。 カカオ豆とは顕著に異なる現象である。 このようにして得られる胚乳を、 磨碎処理して粗製クプアス油脂を製造する。 好ましくは、 かくして得られたクプアス豆胚乳は、 ミルの中に投じて通常は 二段階の磨砕処理を行うことによって粗製クプアス油脂が得られる。 すなわち、 第一段階はブレードミルを通して平均粒径 1 5 0ミクロン程度にまで磨砕し、 次いで第二段階としてボールミルにより平均粒径 7 5ミクロン程度にまで磨砕 処理するのである。 このような磨碎処理においては、 摩擦熱によってクプアス 胚乳中にほぼ約 5 4〜 5 9 %程度含まれる油脂が溶解して、 ペースト状又は液 状乃至油状を呈するに至る。 Threshing is carried out by removing the outer skin from roasted Kupuas beans. Usually, roasted cupuas beans are crushed, for example, by using a crusher, and then, for example, sieved to remove the fibrous shell (skin), thereby separating and obtaining endosperm. The crusher treatment and the sieving treatment may be repeated as appropriate until the hull of the endosperm is reduced to about 5% by weight or less. Using far-infrared roasted cupuas beans, The frequency of the above-mentioned repetition is remarkably reduced as compared with the case of using hot-air roasting or direct-fire roasting cupuas beans. This is a significantly different phenomenon from cocoa beans. The endosperm thus obtained is subjected to a grinding treatment to produce a crude cupuas fat. Preferably, the thus obtained cupuas soybean endosperm is put into a mill and usually subjected to a two-stage grinding treatment to obtain a crude cupuas fat. That is, the first step is grinding through a blade mill to an average particle size of about 150 microns, and then the second step is grinding treatment by a ball mill to an average particle diameter of about 75 microns. In such grinding treatment, about 54 to 59% of fats and oils contained in the cupuas endosperm are dissolved by frictional heat, resulting in the formation of a paste, liquid or oil.
このようにして得られる粗製クプアス油脂を圧搾処理に付することにより精 製クプアスが得られる。 好ましくは、 得られる粗製クプアス油脂を、 例えば油 圧プレスを用いて圧搾処理すれば精製クプアス油脂が得られる。 この工程によ つて、 精製クプアス油脂が加圧下に濾過される。 精製クプアス油脂は加圧下に 液状で濾過され、 常圧下約 4 O t:以上では液状であるが、 温度が冷えると固状 となる。 従って精製クプアス油脂は液状又は固状で分離取得される。  By subjecting the thus-obtained crude cupuas fat and oil to a squeezing treatment, a refined cupuas is obtained. Preferably, the obtained crude Kupuas fat is subjected to squeezing treatment using, for example, an oil press to obtain a purified Kupuasu fat. In this step, the refined cupuas fat is filtered under pressure. The refined cupuas fat is filtered in a liquid state under pressure, and is liquid at about 4 Ot: or more under normal pressure, but becomes solid when the temperature is cooled. Therefore, the purified cupuas fat is separated and obtained in a liquid or solid state.
なお、 粗製クプアス油脂を圧搾処理工程に付すると粗製クプアス油脂は精製 クプアス油脂と繊維質を含有するケーキに分離する。 このケーキを磨砕して得 られる粉状物は、 ココアと同様にして香り高い飲み物として喫することができ る。  When the crude cupuas fat is subjected to a squeezing treatment step, the crude cupuas fat is separated into a cake containing the purified cupuas fat and fiber. The powder obtained by grinding this cake can be enjoyed as a fragrant drink, similar to cocoa.
クプアス油脂に例えばレシチン等の界面活性剤、 さらに所望により香料等を 加え、 よく混合した後、 ロールの間を通して粒子を微細にし、 さらに約 4 0〜 4 5 で混練機にかけてよく練って混練物を得る。 レシチンを配合するとクプ ァス油脂の粘度が下がって作業性がよくなる上、 製造されたチョコレート菓子 に滑らかな舌ざわりの風味を与える。  After adding a surfactant such as lecithin and, if desired, a fragrance, etc. to the cupuas fat and oil, and mixing well, finely pulverize the particles between the rolls, further knead the mixture with a kneader at about 40 to 45, and knead the mixture. obtain. Incorporation of lecithin lowers the viscosity of cupfas fats and oils, improving workability and imparting a smooth tongue-like flavor to the manufactured chocolate confectionery.
クプアス油脂は、 チヨコレートの製造に使用されるカカオバターよりも融点 が低い精製クプアス油脂又は粗製クプアス油脂と精製クプアス油脂の混合物を 使用してチヨコレート様の菓子を製造する場合に、 該チヨコレート様菓子の軟 化点を上げることを所望するときには、 クプアス油脂の一部をカカオバターで 置き換えてもよい。 そのような場合の使用されるクプアス油脂とカカオバター の配合割合は、 重量比で約 9 7 : 3〜6 0 : 4 0程度である。 Cupuas fat has a melting point higher than that of cocoa butter used in the production of tiyocholate. In the case of using a refined cupuas fat or a mixture of a crude cupuas fat and a refined cupuas fat with a low level of citrus-like confectionery, when it is desired to increase the softening point of the thiocholate-like confection, May be replaced with cocoa butter. In such a case, the mixing ratio of the cupuas oil and fat to the cocoa butter is about 97: 3 to 60:40 by weight.
さらに所望により、 上記の混練物には、 粉乳、 砂糖、 界面活性剤以外に植物 油を配合してもよい。 そのような植物油としては、 パ一ム油、 ココナツ油、 ナ タネ油等があげられる。 これらの添加物の一以上を配合してもよい。  If desired, vegetable oil may be added to the above kneaded material in addition to milk powder, sugar and surfactant. Such vegetable oils include palm oil, coconut oil, rapeseed oil and the like. One or more of these additives may be blended.
このような添加物を配合した混練物の好ましい一例を挙げると、 混練物 1 0 0重量部中、 粗製クプアス: 5〜9 0重量部、 より好ましくは 1 0〜8 0重量 部、 精製クプアス: 1 0〜5 0重量部、 より好ましくは 2 0〜4 0重量部、 砂 糖: 1 5〜6 0重量部、 より好ましくは 2 0〜5 0重量部、 レシチン: 0 . 0 1〜1重量部、 より好ましくは 0 . 2〜0 . 6重量部が含まれる。  A preferred example of a kneaded product in which such an additive is blended is as follows: 100 to 100 parts by weight of the kneaded product, crude Kupuas: 5 to 90 parts by weight, more preferably 10 to 80 parts by weight, purified Kupuas: 10 to 50 parts by weight, more preferably 20 to 40 parts by weight, sugar: 15 to 60 parts by weight, more preferably 20 to 50 parts by weight, lecithin: 0.01 to 1 part by weight Parts, more preferably 0.2 to 0.6 parts by weight.
なお、 カカオバターからチョコレートを製造する場合に、 カカオバターの一 部をクプアス油脂によって置き換えてもよい。  When chocolate is produced from cocoa butter, a part of the cocoa butter may be replaced by cupuas fat.
上記の混練物又はこれにさらにパフ類又はナッツ類とを混合し、 型 (モール ド) に充填し、 クプアスチョコレート菓子を製造してよい。 又、 さらに冷却さ れたクプアス油脂チョコレートのシェルの中にクリーム、ナッツ、 ビスケット、 リキュール類などを注入、 充填し、 ふたをすればシェルクプアス油脂チョコレ —卜が得られる。  The above kneaded material or a mixture thereof with puffs or nuts may be mixed and filled in a mold to produce a cupuas chocolate confectionery. In addition, cream, nuts, biscuits, liqueurs, and the like are poured and filled into the cooled cupuas oil chocolate shell, and the lid is obtained, whereby a shellkua fat oil chocolate can be obtained.
又さらに、 ビスケット、 ナッツ、 クリームなどの固体を網コンベアに乗せ、 温度調整した上記混練物を滝のように流下させ、 余分な混連物を風力で吹き落 として、 冷却することによつてもクプアス油脂チョコレートが製造できる。 かくして製造される精製クプアス油脂の代表的物性 (参考としてカカオバタ —の数値を示す) 〔試験例〕 In addition, solids such as biscuits, nuts, and cream are placed on a net conveyor, the temperature-adjusted kneaded material is allowed to flow down like a waterfall, and excess mixed material is blown down by wind power to cool. Kupuas fat chocolate can be produced. Typical physical properties of the refined cupuas fat thus produced (the value of cocoa butter is shown for reference) (Test example)
項目 精製クプアス油脂 カカオバター  Item Refined cupuas oil and cocoa butter
外観 淡黄色 淡黄色  Appearance pale yellow pale yellow
融点、 32 34  Melting point, 32 34
比重 0.917 0.904  Specific gravity 0.917 0.904
鹼化価 187 193  Chemical value 187 193
ヨウ素価 43 35  Iodine value 43 35
屈折率 1.475 1.461  Refractive index 1.475 1.461
脂肪酸組成、  Fatty acid composition,
パルミチン酸 7.2 25.7  Palmitic acid 7.2 25.7
ステアリン酸 32.9 36.3  Stearic acid 32.9 36.3
ォレイン酸 43.0 33.2  Oleic acid 43.0 33.2
リノール酸 3.4 2.6  Linoleic acid 3.4 2.6
リノレイン酸 痕跡量  Trace amount of linoleic acid
ァラキドン酸 10.7 1.2  Arachidonic acid 10.7 1.2
1.7 0.2  1.7 0.2
(飽和脂肪酸/不飽和脂肪酸重量比) 1.121 1.754 上記の数値は、クプアス樹の産地、栽培条件等により変動しうるものである。 例えば飽和脂肪酸と不飽和脂肪酸との重量比率も約 0. 8〜1. 4の範囲で変 動しうる。 屈折率も 1. 456〜1. 485の範囲を超えて、 1. 3〜1. 5 の範囲内で変動しうる。  (Saturated fatty acid / unsaturated fatty acid weight ratio) 1.121 1.754 The above numerical values can vary depending on the production area of the cupuas tree, cultivation conditions, and the like. For example, the weight ratio of saturated fatty acids to unsaturated fatty acids can vary from about 0.8 to 1.4. The index of refraction can also exceed the range of 1.456 to 1.485 and vary within the range of 1.3 to 1.5.
かくして得られた粗製クプアス油脂、 精製クプアス油脂又はそれらを用い製 造される菓子類はいずれも刺激性、 覚醒性など不快な生理的副作用を有する力 フェイン、 テオプロミンなどを含有しない、 特に乳幼児や高齢者にとっても健 康的な食品又は嗜好品として有用である。 また、 精製クプアス油脂は、 マーガ リンなど油脂ベースの加工食品に配合すれば品質の改善、 新しい健康食品類の 開発が可能である。 油性化粧品に配合すれば皮膚保護効果を改善することが出 来また融点がヒト体温に近接しているので、 そのまま又は若干の水素添加還元 処理を行って座薬又は軟膏の基剤として使用出来る。 以下に実施例を記載して、 本発明をさらに詳細に説明する。 The crude cupuasu oil and fat thus obtained, the purified cupuasu oil and fats, and the confectionery produced using them all have unpleasant physiological side effects such as irritation and arousal.They do not contain fein, theopromine, etc. For the elderly Useful as a healthy food or luxury item. In addition, refined cupuas fat can be mixed with oil-based processed foods such as margarine to improve quality and develop new health foods. It can be used as an suppository or ointment base as it is or after a slight hydrogenation-reduction treatment because it can improve the skin protection effect when incorporated into oily cosmetics and has a melting point close to human body temperature. Hereinafter, the present invention will be described in more detail with reference to Examples.
実施例 1 精製クプアス油脂の製造: Example 1 Production of refined cupuas fat:
ブラジルアマゾン河流域の都巿マナウスの近郊に位置するプランテーション で栽培したクプアスから種子を採取し、 パルプ付着したまま醱酵釜の中で 5〜 7日間クプアス種子に付着したィ一スト菌によって醱酵させたところ、 p Hは 5 . 0〜5 . 3と低下し、 温度は 4 2〜4 5でに上昇した。 その後トレイに移 して 7日間天日乾燥させ、 長径が 2 0乃至 3 O mm、 短径が 1 6乃至 2 O mm かつ重量が 2 . :!〜 2 . 5 gZ種子(この範囲で変動した)、 含水率が 6乃至 7 % であるクプアス種子を得た。  Seeds are collected from cupuas grown in a plantation near Manaus, the capital of the Brazilian Amazon river basin, and are fermented by a bacterium attached to the cupuas seeds in a fermenter for 5 to 7 days while the pulp remains attached. The pH dropped to 5.0-5.3 and the temperature rose to 42-45. Then transfer to a tray and dry in the sun for 7 days. Seeds with a major axis of 20 to 3 Omm, a minor axis of 16 to 2 Omm and a weight of 2 .:! To 2.5 gZ (varied within this range) ), A cupuas seed having a water content of 6 to 7% was obtained.
醱酵乾燥させたクプアス種子は、 電磁石で金属類異物をのぞきまた圧縮空気 で塵芥を除去することによって清浄処理した。 かくして得られるクプアス豆を ホッパーに投入し、 そこからバイブレーターを用いてメッシュコンベア上にク プアス豆を供給する。 このメッシュコンベアは上下、 左右及び進行方向に振動 することにより、 クプアス豆の一粒一粒が遠赤外線の熱を均等に受けるように させる。 遠赤外線ヒー夕一としてセラミックを用いる。 遠赤外線ヒータ一のヮ ット数は約 2 0 0 0 W、 波長は 4〜5 0 ΠΙ、 電流 1 0 A、 クプアス豆とヒ一 ターとの距離は平均 8 c mであった。 焙煎条件は、 遠赤外線板の通過時間と品 温で管理した。 クプアス豆の場合、 遠赤外線ヒーター通過時間 (照射時間) は 1 0分間、 品温は 1 7 0 °Cで行った。 このようにすると外皮 (表皮) の状態に ついては、 明らかに熱風ロースト方式とは異なり剥離しやすくなつた。 風味に ついても良好な結果が得られる。 (4) The fermented and dried cupuas seeds were cleaned by removing foreign substances with an electromagnet and removing dust with compressed air. The cupuas beans thus obtained are put into a hopper, from which they are supplied to a mesh conveyor using a vibrator. This mesh conveyor vibrates up and down, left and right, and in the direction of travel so that each and every cupuas bean receives heat of far-infrared rays evenly. Ceramics are used as far infrared rays. The number of cuts of the far-infrared heater was about 2000 W, the wavelength was 4 to 50 mm, the current was 10 A, and the distance between the cupuas beans and the heater was 8 cm on average. The roasting conditions were controlled by the transit time and temperature of the far infrared plate. In the case of cupuas beans, the passing time (irradiation time) of the far-infrared heater was 10 minutes, and the temperature was 170 ° C. In this way, the state of the outer skin (epidermis) became clearer, unlike the hot-air roast method. To flavor Also, good results can be obtained.
これによつて、 クプアス種子は含水率はほぼ 2 %にまで低下すると同時に芳 香フレーバーを有するものとなった。 焙煎処理したクプアス豆を篩いかけして 塵芥や割れ豆を除去し、 次いで破砕機にかけて胚乳シェルを剥離し、 次に 8 0 メッシュの篩で篩い掛けしてクプアス胚乳を得た。 なお篩い残は第一の篩いェ 程に戻して再度破碎処理を行つた。  This reduced the water content of the Kupuas seeds to almost 2%, and at the same time, gave them a flavorful flavor. The roasted Kupuas beans were sieved to remove dust and cracked beans, then the crusher was used to peel the endosperm shell, and then sieved with an 80 mesh sieve to obtain Kupuas endosperm. The sieved residue was returned to the first sieving step and crushed again.
得られたクプアス胚乳は、 ブレードミルによる一次粉砕処理の後次いでボー ルミルによる二次粉砕処理による二段階粉砕処理又は微粉碎機に供する一段階 微粉砕処理を行うことによってクプアス胚乳の平均粒径を 7 5ミクロン以下に することによって液状とし、 かくして粗製クプアス油脂を得た。 さらにこの粗 製油脂を更に油圧式フィルタープレスにかけることによって精製クプアス油脂 が得られた。 得られた精製クプアス油脂の代表的物性値は、 上記試験例で示し た。  The obtained Kupuas endosperm is subjected to a primary grinding treatment by a blade mill, followed by a two-stage grinding treatment by a secondary grinding treatment by a ball mill or a one-stage fine grinding treatment to be applied to a pulverizer. The liquid was reduced to 75 microns or less to obtain a liquid, and thus a crude cupuas fat was obtained. The crude oil was further subjected to a hydraulic filter press to obtain a refined cupuas oil. Representative physical property values of the obtained purified cupuas oil and fat are shown in the above Test Examples.
なお、 クプアス果実から採取した生のクプアス種子 (平均含水率 6 8 %) 1 0 0 k gから、 ほぼ 4 5 k gの乾燥クプアス種子(平均含水率 6 %)が得られ、 焙煎処理することによって 4 3 k gの焙煎処理クプアス種子とし、 さらに破砕 処理によって 1 8 k gのクプアス胚乳が得られた。引き続いて微粉砕処理して粗 製クプアス油脂を製造し、 フィル夕一プレス処理によって約 1 0 k gの精製ク プアス油脂を得た。 実施例 2 精製クプアス油脂の製造:  From 100 kg of raw Kupuas seeds (average moisture content: 68%) collected from Kupuas fruits, approximately 45 kg of dried Kupuas seeds (average moisture content: 6%) were obtained. 43 kg of roasted Kupuas seeds and 18 kg of Kupuas endosperm were obtained by crushing. Subsequently, the resulting mixture was finely pulverized to produce a crude Kupuas fat, and about 10 kg of refined Kupuas fat was obtained by a Filu-Izu press treatment. Example 2 Production of refined cupuas oil and fat:
ブラジルアマゾン河流域の都市マナウスの近郊に位置するプランテーション で栽培したクプアスから種子を採取し、 パルプ付着したまま醱酵釜の中で 5〜 7日間クプアス種子に付着したィースト菌等によって醱酵させたところ、 p H は 5 . 0〜5 . 3と低下し、 温度は 4 2〜4 5 に上昇した。 その後トレイに 移して 7日間天日乾燥させ、 長径が 2 0乃至 3 0 mm、 短径が 1 6乃至 2 0 m mかつ平均重量が 2 . 1〜2 . 5 g_/種子 (この範囲で変動する)、 含水率が 6 乃至 7 %であるクプアス種子を得た。 Seeds were collected from Kupuas grown in a plantation near the city of Manaus in the Brazilian Amazon basin, and fermented with yeast attached to Kupuas seeds in a fermenter for 5-7 days while the pulp remained attached However, the pH dropped from 5.0 to 5.3, and the temperature rose from 42 to 45. Then transfer to a tray and dry in the sun for 7 days, major axis 20 to 30 mm, minor axis 16 to 20 m A cupuas seed having m and an average weight of 2.1 to 2.5 g_ / seed (varies in this range) and a water content of 6 to 7% was obtained.
醱酵乾燥させたクプアス種子は、 電磁石で金属類異物をのぞきまた圧縮空気 で塵芥を除去することによって清浄処理し、 次いで連続焙煎装置に入れて 1 3 0〜 1 5 0での熱風でほぼ 2 0〜3 0分間ローストした。 これによつて、 クプ ァス種子は含水率はほぼ 2 %にまで低下すると同時に芳香フレーバーを有する ものとなった。 焙煎処理したクプアス種子を篩いかけして塵芥や割れ豆を除去 し、 次いで破砕機にかけて胚乳シェルを剥離し、 次に 8 0メッシュの篩で篩い 掛けしてクプアス胚乳を得た。 なお篩い残は第一の篩い工程に戻して再度破砕 処理を行った。  ク The fermented and dried cupuas seeds are cleaned by removing foreign substances with an electromagnet and removing dust with compressed air.Then, they are put into a continuous roasting apparatus and almost heated with hot air at 130-150. Roasted for 20-30 minutes. As a result, the cupus seeds had an aromatic flavor with the water content reduced to almost 2%. The roasted Kupuas seeds were sieved to remove dust and cracked beans, and then crushed to peel the endosperm shell, and then sieved with an 80-mesh sieve to obtain Kupuas endosperm. The sieved residue was returned to the first sieving step and crushed again.
得られたクプアス胚乳は、 ブレードミルによる一次粉砕処理の後次いでボー ルミルによる二次粉砕処理による二段階粉碎処理又は微粉砕機に供する一段階 微粉砕処理を行うことによって平均粒径を 7 5ミクロン以下にすることによつ て液状とし、 かくして粗製クプアス油脂を得た。 さらにこの粗製油脂をさらに 油圧式フィルタープレスにかけることによって精製クプアス油脂が得られた。 得られた精製クプアス油脂の代表的物性値は、 上記試験例で示した。 実施例 3 チョコレート様菓子 (クプアスチョコレート) の製造:  The resulting cupuas endosperm has an average particle size of 75 microns by performing a primary milling treatment with a blade mill followed by a secondary milling process with a ball mill or a single-stage milling process with a fine mill. The following procedure was carried out to obtain a liquid, and thus a crude cupuas fat was obtained. The crude oil was further subjected to a hydraulic filter press to obtain a refined cupuas oil. Representative physical property values of the obtained refined cupuas oil and fat are shown in the above Test Examples. Example 3 Production of chocolate-like confectionery (cupuas chocolate):
前記した実施例 1において得られた粗製クプアス油脂及び精製クプアス油脂 を用いて下記処方に従って三種類の洋菓子を製造した。  Three types of Western confectionery were produced using the crude cupuas fat and oil obtained in Example 1 and the purified cupuas fat according to the following formulation.
( 1 ) ビ夕一タイプ  (1) Biyuichi type
粗製クプアス油脂 4 5 重量部  Crude cupuas fat 4 5 parts by weight
精製クプアス油脂 1 2 "  Refined cupuas fat 1 2 "
粉乳  Milk powder
砂糖 4 3 ( 2 ) ミルクタイプ Sugar 4 3 (2) Milk type
粗製クプアス油脂 3 0 重量部  Crude cupuas fat 30 weight parts
精製クプアス油脂 1 6 "  Refined cupuas fat 1 6 "
粉乳 1 0 "  Milk powder 1 0 "
砂糖 4 4 "  Sugar 4 4 "
( 3 ) ホワイトタイプ  (3) White type
粗製クプアス油脂 0 重量部  Crude cupuas fat 0 parts by weight
精製クプアス油脂 4 1 "  Refined cupuas fat 4 1 "
粉乳 1 8 "  Milk powder 1 8 "
砂砂糖糖 : 4 1 "  Sugar sugar: 4 1 "
上記した各原料成分の所定量を秤量してミキサーに投入し、 温度 4 0〜4 5 "Cにおいて処方に従い 1 0乃至 2 0分間の異なる時間混合 ·微細化 ·混練処 理し、 次いで温度調整後、 モールド内に注型し、 その後 1 0〜1 5 に冷却し て、 それぞれのチョコレート様洋菓子 (クプアスチョコレート) 製品が得られ た。 これらの製品は風味ゃ呈味など品質面で従来のチョコレート系洋菓子類に 遜色することはなかった。 実施例 4  A prescribed amount of each of the above-mentioned raw material components is weighed and put into a mixer, mixed for 10 to 20 minutes at a temperature of 40 to 45 "C for 10 to 20 minutes according to the recipe, refined, and kneaded, and then the temperature is adjusted. After that, it was poured into a mold and then cooled to 10 to 15 to obtain each chocolate-like confectionery (Kupuas Chocolate) product. Example 4 Compared to Western confectionery.
下記要領にて、 クプアス豆のボイリング処理を行い、 粗製クプアス油脂を製 造した。  Boiling of Kupuas beans was performed in the following manner to produce crude Kupuas fats and oils.
実施例 1と同様に、 醱酵、 乾燥したクプアス豆を約 1 0〜2 0分間沸騰して いる水中でボイルする。 ボイルした豆をざるに乗せ水分を切る。 クプアス豆の 表皮が柔らかいうちにカッターで切れ目を入れ、 胚乳部分を取り出す。 取り出 した胚乳は、 乾燥機を使用して水分が、 6重量%以下になるまで乾燥し、 さら に水分が約 2重量%以下となるまで熱風式焙煎機で焙煎し、 グラインダーを用 いて磨砕する。 このようにして粗製クプアス油脂を得る。 実施例 1と同様にし て粗製クプアス油脂から精製クプアス油脂を得る。 As in Example 1, the fermented and dried cupuas beans are boiled in boiling water for about 10 to 20 minutes. Put the boiled beans on top and drain. While the outer skin of the cupuas bean is soft, make a cut with a cutter and remove the endosperm. The extracted endosperm is dried using a dryer until the water content is reduced to 6% by weight or less, then roasted in a hot air roasting machine until the water content is reduced to about 2% by weight or less, using a grinder. And grind. Thus, a crude cupuas fat is obtained. As in Example 1. To obtain a purified cupuas fat from the crude cupuas fat.
実施例 5 Example 5
実施例 3の処方の代わりに下記処方に従う以外は、 実施例 3に記載の方法と 全く同様にして、 それぞれのタイプのチョコレート様菓子 (クプアスチョコレ ート) を製造した。 チョコレート系洋菓子に遜色することなく、 風味、 呈味で 優れた製品である。  Each type of chocolate-like confectionery (cupuaschocolate) was produced in exactly the same manner as in Example 3 except that the following formulation was used instead of the formulation of Example 3. This product is excellent in flavor and taste, comparable to chocolate-based western confectionery.
第 1表 Table 1
Figure imgf000020_0001
Figure imgf000020_0001
実施例 6 Example 6
実施例 3の処方の代わりに下記処方に従う以外は、 実施例 3に記載の方法と 全く同様にして、 それぞれのタイプのチョコレート様菓子 (クプアスチョコレ ート) を製造した。 チョコレート系洋菓子に遜色することなく、 風味、 呈味で 優れた製品である。  Each type of chocolate-like confectionery (cupuaschocolate) was produced in exactly the same manner as in Example 3 except that the following formulation was used instead of the formulation of Example 3. This product is excellent in flavor and taste, comparable to chocolate-based western confectionery.
第 2表 ビタ一タイプ ミルクタイプ ホワイトタイプ Table 2 Vita type Milk type White type
(重量%) (重量%)  (% By weight) (% by weight)
粗製クプアス 40 10  Crude cupuas 40 10
精製クプアス 1 1. 5  Refined cupuas 1 1.5
粉乳 20 23  Milk powder 20 23
砂糖 47 45 45  Sugar 47 45 45
カカオパター 12. 5 24. 5 20  Cocoa putter 12.5 24.5 20
レシチン 0. 5 0. 5 0. 5 実施例 7 Lecithin 0.5 0.5 0.5 0.5 Example 7
〔口紅〕  (Lipstick)
No ポリエチレンワックス 7  No Polyethylene wax 7
2 4  twenty four
3 7  3 7
4 カルナバロウ 1  4 Carnavalow 1
5 精製クプアス油脂 20  5 Refined cupuas fat 20
6 流動パラフィン 26. 45 7 ジー 2—へプチルゥンデカン酸グリセリン 20  6 Liquid paraffin 26. 45 7 G2-glycerin heptyl pentadecanoate 20
8 チタンコーティ ドマイカ 5  8 Titanium Coated Domica 5
9 赤色酸化鉄 1  9 Red iron oxide 1
0 赤色 202号 3  0 Red No. 202 3
1 1 赤色 223号 0 2 12 だいだい色 201号 0  1 1 Red No. 223 0 2 12 Red No. 201 0
1 3 ジブチルヒドロキシトルエン  1 3 Dibutylhydroxytoluene
14 香料  14 spices
1 5 ビーガム 0. 1 5 gをべンジルジメチルステアリル 0. 25 アンモニゥムクロリド 0. 05 gと水添レシチン 0. 05 g で処理して得た有機変性粘土鉱物  15 Organically modified clay mineral obtained by treating 0.15 g of Vegum with 0.15 g of benzyldimethylstearyl 0.25 g of ammonium chloride and 0.055 g of hydrogenated lecithin
16 純水 3  16 Pure water 3
1 7 グリセリン 2  1 7 Glycerin 2
なお、 配合量の単位は全て重量%である。  In addition, the unit of the compounding amount is all weight%.
(製法) No. 7の 10重量%にNo. 1 5を室温下で分散し、 これに No. 16及び 1 7を徐々に添加し、 ディスパ一にて分散し、 W/O型エマルシヨン を得る。 一方、 No. :!〜 6及び No. 7の残部を 90でにて加熱溶解し、 そ の後 N o . 8〜 1 4を加えて 8 0 °Cにて分散した後、 これに先に得た WZO型 エマルシヨンを添加して分散混合する。 これを脱気後、 所定容器に充填する。 得られた口紅は、 のびも良く、 2 0名パネルで 1ヶ月間使用テストを行った結 果、 明らかな保湿効果が認められた。 また、 唇に塗布した場合においても発色 性、 色持ち共に非常に良い結果であった。 実施例 8 (Production method) Disperse No. 15 in 10% by weight of No. 7 at room temperature, gradually add No. 16 and No. 17 to this, and disperse with a disperser to obtain a W / O type emulsion. . On the other hand, the remainder of No .:! ~ 6 and No. 7 were heated and melted at 90, and Then, after adding No. 8 to 14 and dispersing at 80 ° C., the WZO type emulsion obtained above is added and dispersed and mixed. After degassing, it is filled into a specified container. The obtained lipstick had good growth and was used for one month in a panel of 20 persons. As a result, a clear moisturizing effect was recognized. Also, when applied to the lips, both the coloring and the color retention were very good. Example 8
〔座薬〕  (Suppository)
タンニン酸 100gおよび亜硫酸水素ナトリウム 20g を乳鉢で細かく磨り潰し て粉末にした。これとは別に、硫酸アルミニウムカリウム 50g、 リドカイン 20g および竜脳 20g を乳鉢で磨り潰して粉末とし、 篩に掛けて一定の粒度のものを 集めた。 このようにして得られた両方の粉末を合わせて均一になるまで十分に 混合した。 この混合物を更に細かく粉碎してよく混合した後、 これに溶融した 精製クプアス油脂を全量が 1000 gになるように添加し、 得られた配合物を撹拌 して混合物を十分に溶融した。 これを座薬用コンテナーに入れて座薬製剤を作 製した。 なお、 座薬製剤 1個の重量は 1.5 gとした。 その座薬 1個中には、 夕 ンニン酸 0.15g、 硫酸アルミニウムカリウム 0.075g、 リドカイン 0.03gおよび 竜脳 0.03gが含まれている。  100 g of tannic acid and 20 g of sodium bisulfite were finely ground into a powder in a mortar. Separately, 50 g of potassium aluminum sulfate, 20 g of lidocaine and 20 g of dragon brain were ground into a powder in a mortar and sieved to collect particles of a certain particle size. The two powders thus obtained were combined and thoroughly mixed until uniform. This mixture was further finely ground and mixed well, and then the refined cupuas oil melted was added thereto so that the total amount became 1000 g, and the resulting mixture was stirred to sufficiently melt the mixture. This was placed in a suppository container to make a suppository formulation. The weight of one suppository formulation was 1.5 g. One suppository contains 0.15 g of succinic acid, 0.075 g of potassium aluminum sulfate, 0.03 g of lidocaine and 0.03 g of dragon brain.
このようにして製造された座薬は、 軽症の痔等に基づく直腸病変組織を治療 するのに有効ばかりでなく、 直腸、 肛門の手術後に起こる合併症に照らして、 主に術後の括約筋の痙攣によって引き起こされる疼痛を防止し、 制菌、 消炎を し、 腫れを引き、 痛みを止め、 肉芽細胞の正常でかつ早急な発育を促し、 傷口 の癒合を促進するのに有効である。 産業上の利用可能性  Suppositories produced in this way are not only effective in treating rectal lesions based on mild hemorrhoids, etc., but also in the light of complications that occur after rectal and anal surgery, mainly post-operative sphincter spasm. It is effective in preventing pain caused by, controlling bacteriostats, inflammation, causing swelling, stopping pain, promoting normal and rapid growth of granulation cells, and promoting wound healing. Industrial applicability
本発明によって、 健康保持に有用なクプアス油脂並びにそれを使用した健康 食品を工業的有利に提供することができる t INDUSTRIAL APPLICABILITY According to the present invention, a cupuas fat or oil useful for maintaining health and health using the same T that can provide food industrially advantageously

Claims

請 求 の 範 囲 The scope of the claims
1 . クプアス種子を醱酵させてクプアス豆を得る第 1工程と、 クプアス豆を 遠赤外線で焙煎し、 脱穀して胚乳を採取、 これを磨砕して粗製クプアスを得る 第 2工程と、 さらに所望により粗製クプアス油脂を圧搾して精製クプアス油脂 を得る第 3工程からなるクプアス油脂の製造方法。 1. The first step of fermenting the cupuas seeds to obtain cupuas beans, the second step of roasting the cupuas beans with far-infrared rays, threshing and collecting the endosperm, and grinding this to obtain a crude cupuas, A method for producing a cupuas fat comprising a third step of, if desired, squeezing a crude cupuas fat to obtain a purified cupuas fat.
2 . クプアス種子を醱酵させてクプアス豆を得る第 1工程と、 クプアス豆を 高温水又は加熱水蒸気と接触させた後、 クプアス豆の表皮に切れ目を入れ、 ク プアス豆表皮の切れ目部分から胚乳を採取し、 これを焙煎し、 次いで磨碎して 粗製クプアス油脂を得る第 2工程と、 さらに所望により粗製クプアス油脂を圧 搾して精製クプアス油脂を得る第 3工程からなるクプアス油脂の製造方法。 2. First step of fermenting Kupuas seeds to obtain Kupuas beans, and after contacting Kupuas beans with high-temperature water or heated steam, make a cut in the epidermis of Kupuas beans, And then roasting and then grinding to obtain a crude Kupuas fat, and, if desired, a third step of compressing the crude Kupuasu fat to obtain a purified Kupuasu fat and oil. Method.
3 . 請求の範囲第 1又は 2項に記載の粗製クプアス油脂又はノ及び精製クプ ァス油脂とレシチン又は 及びカカオバターを含有することを特徴とする健康 食品。 3. A health food comprising the crude cupuas oil or fat according to claim 1 or 2, and a purified cupsu oil and lecithin or cocoa butter.
4. さらに砂糖、 粉乳、 パーム油、 ココナツ油及びナタネ油からなる群から 選ばれる 1種以上を含有することを特徴とする請求の範囲第 3項に記載の健康 食品。 4. The health food according to claim 3, further comprising at least one selected from the group consisting of sugar, powdered milk, palm oil, coconut oil, and rapeseed oil.
5 . チョコレート様菓子又はチョコレート代替物である請求の範囲第 3又は 4項に記載の健康食品。 5. The health food according to claim 3 or 4, which is a chocolate-like confection or a chocolate substitute.
6 . 粗製クプアス油脂又は精製クプアスを含有することを特徴とする加工食 品、 医薬品又は化粧品。 6. Processed foods, pharmaceuticals or cosmetics characterized by containing crude cupuas fats or refined cupuas.
7 . 粗製クプアス油脂の加圧処理によって精製クプアス油脂から分離される 繊維質を含有するケーキ又はそれを粉砕して得られる粉状物。 7. A cake containing fibrous material separated from refined kupuas fat by pressurizing a crude kupuas fat or oil, or a powdery substance obtained by pulverizing the cake.
PCT/JP2002/003472 2001-04-06 2002-04-05 Cupua seed-origin fat, process for producing the same and use thereof WO2002081606A1 (en)

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