WO2002077334A1 - Thermoplastisches monofilament für borsten - Google Patents
Thermoplastisches monofilament für borsten Download PDFInfo
- Publication number
- WO2002077334A1 WO2002077334A1 PCT/EP2002/003364 EP0203364W WO02077334A1 WO 2002077334 A1 WO2002077334 A1 WO 2002077334A1 EP 0203364 W EP0203364 W EP 0203364W WO 02077334 A1 WO02077334 A1 WO 02077334A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- monofilament
- monofilament according
- core
- mixture
- bristles
- Prior art date
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 23
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 23
- 239000004952 Polyamide Substances 0.000 claims abstract description 67
- 229920002647 polyamide Polymers 0.000 claims abstract description 67
- 229920000728 polyester Polymers 0.000 claims abstract description 44
- 229920002959 polymer blend Polymers 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims description 32
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 12
- 239000002537 cosmetic Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000000806 elastomer Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 4
- -1 polyethylene terephthalate Polymers 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229920001281 polyalkylene Polymers 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000005452 bending Methods 0.000 description 7
- 230000001680 brushing effect Effects 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000000551 dentifrice Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 230000004001 molecular interaction Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
Definitions
- Auxiliary media such as dentifrice, water, etc., but also due to the increased air humidity prevailing at the place of use, e.g. in the bathroom, are constantly contaminated with moisture, especially since they dry out due to the thick bristles zes on the one hand and the environmental conditions on the other hand would only be possible over a very long period of time.
- High-quality polyamides meet the strength requirements in an excellent manner, but are known to absorb moisture to a not inconsiderable extent and thereby partially lose their favorable strength values. This deterioration in the strength properties leads to the failure of the bristle, the smaller its diameter, since the moisture quickly penetrates into the bristle Penetrated core of bristle.
- Today toothbrushes are often advertised based on the hardness of their bristles, for example as soft (soft), medium (medium) or hard, for which the bristle diameter is primarily responsible. This quality level no longer applies after a period of use due to the moisture load.
- the mixing ratio PA / PE can be varied within wide limits without significantly affecting the stability of the mixing phase.
- the mixing ratio PA / PE can vary between 10/90 mass% and 90/10 mass%, preferably it is between 20/80 mass% and 80/20 mass%.
- the PE portion will be increased to the disadvantage of the PA portion.
- a proportion of PA that is nevertheless adequate ensures improved re-erection ability in the dry state ("bend recovery").
- the ability to straighten up in extremely humid environmental conditions is adversely affected by a high proportion of PA, which can be explained by the greater water absorption of PA.
- the PA portion will be increased at the expense of the PE portion, which also means a gentler treatment of the surface to be cleaned and its surroundings (e.g. the enamel, the gums) accompanied.
- An optimized mixing ratio PA / PE which at least most closely corresponds to the requirement profile usual for toothbrushes, is with a PA proportion between 10 and 30 mass% or a PE proportion between 70 and 90 mass%.
- the thermoplastic polyester is preferably a polyalkylene terephthalate (PAT), in particular polyethylene terephthalate (PET) or polybutylene terephthalate (PBT) or a mixture thereof.
- PAT polyalkylene terephthalate
- PET polyethylene terephthalate
- PBT polybutylene terephthalate
- a high proportion of PAT also gives the opportunity to replace high-quality PA, at least in part, with low-value and inexpensive PA such as PA 6.
- the second layer and the second layer may consist nem single polyamide or mixture of polyamides from egg ⁇ , conversely, of a thermoplastic polyester or a mixture of such polyesters can be formed.
- the core can also consist only of a thermoplastic polyester or a polyester mixture, since it is not directly involved in the brushing effect, while the jacket consists of the polymer mixture according to the invention.
- the polymer mixture according to the invention can be present both in the core and in the jacket, the mixing ratio in favor of the PE or PAT component being increased in the core, in the jacket in favor of the PA component.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Brushes (AREA)
- Artificial Filaments (AREA)
- Multicomponent Fibers (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES02732524T ES2407133T3 (es) | 2001-03-28 | 2002-03-26 | Monofilamento termoplástico para cerdas |
KR1020037012605A KR100891016B1 (ko) | 2001-03-28 | 2002-03-26 | 강모를 위한 열가소성 모노필라멘트 |
BRPI0208436-8B1A BR0208436B1 (pt) | 2001-03-28 | 2002-03-26 | Monofilamento termoplástico para cerdas |
AU2002304781A AU2002304781B2 (en) | 2001-03-28 | 2002-03-26 | Thermoplastic monofilament for bristles |
JP2002575365A JP2004523674A (ja) | 2001-03-28 | 2002-03-26 | ブラシ毛のための熱可塑性モノフィラメント |
MXPA03008688A MXPA03008688A (es) | 2001-03-28 | 2002-03-26 | Monofilamento termoplastico para cerdas. |
EP02732524A EP1381719B1 (de) | 2001-03-28 | 2002-03-26 | Thermoplastisches monofilament für borsten |
CA002441408A CA2441408A1 (en) | 2001-03-28 | 2002-03-26 | Thermoplastic monofilament for bristles |
US10/472,037 US6872449B2 (en) | 2001-03-28 | 2002-03-26 | Thermoplastic monofilament for bristles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10115556A DE10115556A1 (de) | 2001-03-28 | 2001-03-28 | Thermoplastisches Monofilament für Borsten |
DE10115556.5 | 2001-03-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002077334A1 true WO2002077334A1 (de) | 2002-10-03 |
Family
ID=7679545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/003364 WO2002077334A1 (de) | 2001-03-28 | 2002-03-26 | Thermoplastisches monofilament für borsten |
Country Status (17)
Country | Link |
---|---|
US (1) | US6872449B2 (de) |
EP (1) | EP1381719B1 (de) |
JP (1) | JP2004523674A (de) |
KR (1) | KR100891016B1 (de) |
CN (1) | CN1223711C (de) |
AR (1) | AR033018A1 (de) |
AU (1) | AU2002304781B2 (de) |
BR (1) | BR0208436B1 (de) |
CA (1) | CA2441408A1 (de) |
DE (1) | DE10115556A1 (de) |
EG (1) | EG23215A (de) |
ES (1) | ES2407133T3 (de) |
MX (1) | MXPA03008688A (de) |
PT (1) | PT1381719E (de) |
RU (1) | RU2287030C2 (de) |
TW (1) | TW585753B (de) |
WO (1) | WO2002077334A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10743647B2 (en) | 2015-07-07 | 2020-08-18 | Colgate-Palmolive Company | Oral care implement and monofilament bristle for use with the same |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7732017B2 (en) * | 2004-03-17 | 2010-06-08 | Akzo Nobel Coatings International B.V. | Effect paint |
KR101657575B1 (ko) * | 2010-04-30 | 2016-09-20 | 주식회사 엘지생활건강 | 치간 세정부재 및 이의 제조방법 |
CN103442615A (zh) * | 2011-04-07 | 2013-12-11 | 中村宪司 | 化妆用单丝、使用该单丝的化妆用刷毛材、使用该毛材的化妆用刷 |
KR101281635B1 (ko) | 2012-02-27 | 2013-07-03 | 비비씨 주식회사 | 내구성과 항균성 강화를 위해 제올라이트가 첨가된 블렌드 기법을 통한 칫솔모 및 그의 제조방법 |
USD754442S1 (en) | 2013-07-17 | 2016-04-26 | Colgate-Palmolive Company | Toothbrush |
US10702057B2 (en) | 2015-07-07 | 2020-07-07 | Colgate-Palmolive Company | Oral care implement and monofilament bristle for use with the same |
CN106435823A (zh) * | 2016-09-24 | 2017-02-22 | 乐昌市百丝塑料制品有限公司 | 一种人造猪鬃的制备方法 |
CN113638077A (zh) * | 2021-09-13 | 2021-11-12 | 四川大学 | 一种尼龙6和热塑性聚酯弹性体并列复合弹性纤维及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD103933A1 (de) * | 1973-05-15 | 1974-02-12 | ||
JPH03172132A (ja) * | 1989-11-29 | 1991-07-25 | Sanrain:Kk | 鞘芯型複合モノフィラメント |
WO1997014830A1 (en) * | 1995-10-18 | 1997-04-24 | E.I. Du Pont De Nemours And Company | Coextruded monofilaments |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2309021A (en) * | 1938-07-16 | 1943-01-19 | Johnson & Johnson | Method of treating bristles and product thereof |
GB980814A (en) * | 1960-04-11 | 1965-01-20 | Gilbert Shaw | Composite thermoplastic filaments |
US4150674A (en) * | 1977-12-27 | 1979-04-24 | Monsanto Company | Three-component blends of a polyamide, and a polyester and a lactam terpolymer |
US4507361A (en) * | 1983-07-18 | 1985-03-26 | Allied Corporation | Low moisture absorption bristle of nylon and polyester |
US5582913A (en) * | 1995-08-23 | 1996-12-10 | Hoechst Celanese Corporation | Polyester/polyamide composite fiber |
DE19640726A1 (de) * | 1996-10-02 | 1998-04-23 | Braun Ag | Borste für eine Zahnbürste |
DE19818345A1 (de) * | 1998-04-24 | 1999-10-28 | Pedex & Co Gmbh | Borste, Verfahren zu ihrer Herstellung und Gerät mit einer solchen Borste |
DE19841974A1 (de) * | 1998-09-14 | 2000-03-23 | Braun Gmbh | Borste für eine Zahnbürste, insbesondere für eine elektrische Zahnbürste, sowie Verfahren zu deren Herstellung |
DE19848505A1 (de) * | 1998-10-21 | 2000-04-27 | Basf Ag | Verwendung biologisch abbaubarer Polyester zur Herstellung von Borsten |
DE19942147A1 (de) * | 1999-09-03 | 2001-03-08 | Trisa Holding Ag Triengen | Einzelborste aus Kunststoff für eine Bürste, insbesondere eine Zahnbürste sowie ein Verfahren zur Herstellung einer Einzelborste |
-
2001
- 2001-03-28 DE DE10115556A patent/DE10115556A1/de not_active Ceased
-
2002
- 2002-03-19 TW TW091105194A patent/TW585753B/zh not_active IP Right Cessation
- 2002-03-26 CA CA002441408A patent/CA2441408A1/en not_active Abandoned
- 2002-03-26 WO PCT/EP2002/003364 patent/WO2002077334A1/de active Application Filing
- 2002-03-26 BR BRPI0208436-8B1A patent/BR0208436B1/pt not_active IP Right Cessation
- 2002-03-26 CN CNB028075668A patent/CN1223711C/zh not_active Expired - Fee Related
- 2002-03-26 ES ES02732524T patent/ES2407133T3/es not_active Expired - Lifetime
- 2002-03-26 MX MXPA03008688A patent/MXPA03008688A/es active IP Right Grant
- 2002-03-26 US US10/472,037 patent/US6872449B2/en not_active Expired - Lifetime
- 2002-03-26 EG EG20020315A patent/EG23215A/xx active
- 2002-03-26 RU RU2003131400/04A patent/RU2287030C2/ru not_active IP Right Cessation
- 2002-03-26 EP EP02732524A patent/EP1381719B1/de not_active Expired - Lifetime
- 2002-03-26 AU AU2002304781A patent/AU2002304781B2/en not_active Ceased
- 2002-03-26 PT PT2732524T patent/PT1381719E/pt unknown
- 2002-03-26 KR KR1020037012605A patent/KR100891016B1/ko active IP Right Grant
- 2002-03-26 JP JP2002575365A patent/JP2004523674A/ja not_active Withdrawn
- 2002-03-27 AR ARP020101126A patent/AR033018A1/es active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD103933A1 (de) * | 1973-05-15 | 1974-02-12 | ||
JPH03172132A (ja) * | 1989-11-29 | 1991-07-25 | Sanrain:Kk | 鞘芯型複合モノフィラメント |
WO1997014830A1 (en) * | 1995-10-18 | 1997-04-24 | E.I. Du Pont De Nemours And Company | Coextruded monofilaments |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 015, no. 413 (C - 0877) 22 October 1991 (1991-10-22) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10743647B2 (en) | 2015-07-07 | 2020-08-18 | Colgate-Palmolive Company | Oral care implement and monofilament bristle for use with the same |
US11241080B2 (en) | 2015-07-07 | 2022-02-08 | Colgate-Palmolive Company | Oral care implement and monofilament bristle for use with the same |
Also Published As
Publication number | Publication date |
---|---|
EG23215A (en) | 2004-08-31 |
KR20030097816A (ko) | 2003-12-31 |
EP1381719A1 (de) | 2004-01-21 |
BR0208436A (pt) | 2004-03-30 |
PT1381719E (pt) | 2013-05-08 |
EP1381719B1 (de) | 2013-02-20 |
CA2441408A1 (en) | 2002-10-03 |
MXPA03008688A (es) | 2003-12-12 |
AR033018A1 (es) | 2003-12-03 |
BR0208436B1 (pt) | 2013-10-08 |
TW585753B (en) | 2004-05-01 |
US6872449B2 (en) | 2005-03-29 |
RU2003131400A (ru) | 2005-01-27 |
JP2004523674A (ja) | 2004-08-05 |
KR100891016B1 (ko) | 2009-03-31 |
AU2002304781B2 (en) | 2006-12-21 |
CN1500163A (zh) | 2004-05-26 |
ES2407133T3 (es) | 2013-06-11 |
DE10115556A1 (de) | 2002-10-02 |
RU2287030C2 (ru) | 2006-11-10 |
US20040091704A1 (en) | 2004-05-13 |
CN1223711C (zh) | 2005-10-19 |
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