WO2002015307A3 - Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage - Google Patents

Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage Download PDF

Info

Publication number
WO2002015307A3
WO2002015307A3 PCT/DE2001/002981 DE0102981W WO0215307A3 WO 2002015307 A3 WO2002015307 A3 WO 2002015307A3 DE 0102981 W DE0102981 W DE 0102981W WO 0215307 A3 WO0215307 A3 WO 0215307A3
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
fuel cell
anode
carbon dioxide
anode fluid
Prior art date
Application number
PCT/DE2001/002981
Other languages
English (en)
French (fr)
Other versions
WO2002015307A2 (de
Inventor
Walter Preidel
Original Assignee
Siemens Ag
Walter Preidel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Ag, Walter Preidel filed Critical Siemens Ag
Priority to JP2002520336A priority Critical patent/JP2004507050A/ja
Priority to CA002419468A priority patent/CA2419468A1/en
Priority to EP01960152A priority patent/EP1338047A2/de
Publication of WO2002015307A2 publication Critical patent/WO2002015307A2/de
Priority to US10/368,156 priority patent/US20030148151A1/en
Publication of WO2002015307A3 publication Critical patent/WO2002015307A3/de

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04156—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444—Concentration; Density
    • H01M8/04447—Concentration; Density of anode reactants at the inlet or inside the fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444—Concentration; Density
    • H01M8/0447—Concentration; Density of cathode exhausts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

Bei Brennstoffzellen (DMFC) wird Methanol der Brennstoff dem System zugeführt, wobei nach der Verbrennung Anodenflüssigkeit einschliesslich von Abgasen, wie Kohlendioxid od. dgl., weggeführt werden muss. Gemäss der Erfindung wird das Kohlendioxid, das an der Anode entsteht, nach Austritt aus der Anode des Brennstoffzellenstapels heiss von der Anodenflüssigkeit abgetrennt. Dabei wird der mit dem Kohlendioxid zusammen abgetrennte dampfförmige Brennstoff im Gegenstrom mit kaltem Wasser, das im Kondensator des Kathodenabgases gewonnen wird, abgereichert und das wärmere Wasser der Anodenflüssigkeit beigemischt. Bei der zugehörigen Anlage ist wenigstens für die Anodenflüssigkeit ein Kühler (4) mit nachfolgendem CO2-Abscheider (5) vorgesehen und ist eine Einheit (6) zur Rektifikation vorhanden, mit der dort enthaltener Brennstoff abgetrennt und in den Brennstoffkreislauf zurückgeführt wird.
PCT/DE2001/002981 2000-08-16 2001-08-03 Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage WO2002015307A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2002520336A JP2004507050A (ja) 2000-08-16 2001-08-03 燃料電池システムの作動方法および燃料電池装置
CA002419468A CA2419468A1 (en) 2000-08-16 2001-08-03 Method for operating a fuel cell system, and associated fuel cell installation
EP01960152A EP1338047A2 (de) 2000-08-16 2001-08-03 Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage
US10/368,156 US20030148151A1 (en) 2000-08-16 2003-02-18 Method for operating a fuel cell system, and associated fuel cell installation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10040088.4 2000-08-16
DE10040088A DE10040088A1 (de) 2000-08-16 2000-08-16 Verfahren zum Betrieb eines Brennstoffzellensystems und zugehörige Brennstoffzellenanlage

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/368,156 Continuation US20030148151A1 (en) 2000-08-16 2003-02-18 Method for operating a fuel cell system, and associated fuel cell installation

Publications (2)

Publication Number Publication Date
WO2002015307A2 WO2002015307A2 (de) 2002-02-21
WO2002015307A3 true WO2002015307A3 (de) 2003-05-22

Family

ID=7652661

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2001/002981 WO2002015307A2 (de) 2000-08-16 2001-08-03 Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage

Country Status (6)

Country Link
US (1) US20030148151A1 (de)
EP (1) EP1338047A2 (de)
JP (1) JP2004507050A (de)
CA (1) CA2419468A1 (de)
DE (1) DE10040088A1 (de)
WO (1) WO2002015307A2 (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE344975T1 (de) * 2002-07-01 2006-11-15 Sfc Smart Fuel Cell Ag Regelung des wasserhaushalts in brennstoffzellensystemen
DE10231349A1 (de) * 2002-07-11 2004-01-29 Zf Friedrichshafen Ag Mehrstufengetriebe
JP2004265787A (ja) * 2003-03-03 2004-09-24 Toshiba Corp 直接型メタノール燃料電池システム
DE10330123A1 (de) * 2003-07-04 2005-01-20 Volkswagen Ag Brennstoffzellensystem und Verfahren zum Betrieb desselben
US7655331B2 (en) * 2003-12-01 2010-02-02 Societe Bic Fuel cell supply including information storage device and control system
DE102004036020A1 (de) * 2004-07-23 2006-02-16 Behr Gmbh & Co. Kg Wärmeübertrager, insbesondere Kondensator
CN100369307C (zh) * 2004-08-17 2008-02-13 比亚迪股份有限公司 燃料电池的质子交换膜增湿方法及装置
DE102005033821B4 (de) * 2005-07-11 2011-03-10 Deutsches Zentrum für Luft- und Raumfahrt e.V. Direktoxidations-Brennstoffzellensystem und Verfahren zur Steuerung/Regelung des Wasserhaushalts eines Direktoxidations-Brennstoffzellensystems
US7781114B2 (en) * 2005-10-05 2010-08-24 Panasonic Corporation High electrical performance direct oxidation fuel cells & systems
DE102006048825B4 (de) * 2006-10-09 2017-02-09 Deutsches Zentrum für Luft- und Raumfahrt e.V. Direktoxidations-Brennstoffzellensystem und Verfahren zum Betrieb eines Direktoxidations-Brennstoffzellensystems
KR100805529B1 (ko) * 2007-02-21 2008-02-20 삼성에스디아이 주식회사 연료전지 스택 및 연료전지 시스템
KR100982324B1 (ko) * 2008-01-24 2010-09-15 삼성에스디아이 주식회사 연료전지 시스템
US8735008B2 (en) * 2009-02-17 2014-05-27 Samsung Sdi Co., Ltd. Fuel cell system
DE102011116679B4 (de) 2011-10-21 2016-02-25 Otto-Von-Guericke-Universität Magdeburg Portables Brennstoffzellensystem mit Flüssigkeitsabscheidern und Verwendung, Verfahren zur Rückgewinnung einer Flüssigkeit sowie Simulationsmodell
CN102723516B (zh) * 2012-06-15 2014-05-14 东营杰达化工科技有限公司 一种以液态金属锡为阳极的直碳燃料电池装置
US9954235B2 (en) * 2014-12-22 2018-04-24 Intelligent Energy Limited Anode chambers with variable volumes

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3826955A1 (de) * 1988-08-09 1990-02-15 Krupp Gmbh Verfahren und vorrichtung zum eintragen von sauerstoff in fluessigkeiten
US5573866A (en) * 1995-05-08 1996-11-12 International Fuel Cells Corp. Direct methanol oxidation polymer electrolyte membrane power system
DE19807878A1 (de) * 1998-02-25 1999-08-26 Dbb Fuel Cell Engines Gmbh Brennstoffzellensystem
WO1999044253A1 (en) * 1998-02-25 1999-09-02 Ballard Power Systems Inc. Direct dimethyl ether fuel cells
DE19954546A1 (de) * 1999-11-12 2001-05-31 Daimler Chrysler Ag Verfahren und Anordnung zur Wiedergewinnung eines wasserläslichen Brennstoffs aus einem Abgasstrom einer Direkt-Brennstoff-Brennstoffzelle

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5235846A (en) * 1991-12-30 1993-08-17 International Fuel Cells Corporation Fuel cell leakage detection technique
US5599638A (en) * 1993-10-12 1997-02-04 California Institute Of Technology Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane
DE19701560C2 (de) * 1997-01-17 1998-12-24 Dbb Fuel Cell Engines Gmbh Brennstoffzellensystem
DE19911016C2 (de) * 1999-03-12 2001-07-26 Daimler Chrysler Ag Brennstoffzellensystem mit kathodenseitigen Wasserabtrennmitteln
JP2001126742A (ja) * 1999-10-27 2001-05-11 Sanyo Electric Co Ltd 燃料電池発電装置
NL1014585C2 (nl) * 2000-03-08 2001-09-21 Kema Nv Brandstofcel met een verbeterd rendement voor het opwekken van elektrische energie.
US6686078B1 (en) * 2000-09-29 2004-02-03 Plug Power Inc. Method of reformer operation to prevent fuel cell flooding
US6869716B2 (en) * 2001-06-14 2005-03-22 Mti Microfuel Cells Inc. Flow through gas separator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3826955A1 (de) * 1988-08-09 1990-02-15 Krupp Gmbh Verfahren und vorrichtung zum eintragen von sauerstoff in fluessigkeiten
US5573866A (en) * 1995-05-08 1996-11-12 International Fuel Cells Corp. Direct methanol oxidation polymer electrolyte membrane power system
DE19807878A1 (de) * 1998-02-25 1999-08-26 Dbb Fuel Cell Engines Gmbh Brennstoffzellensystem
WO1999044253A1 (en) * 1998-02-25 1999-09-02 Ballard Power Systems Inc. Direct dimethyl ether fuel cells
DE19954546A1 (de) * 1999-11-12 2001-05-31 Daimler Chrysler Ag Verfahren und Anordnung zur Wiedergewinnung eines wasserläslichen Brennstoffs aus einem Abgasstrom einer Direkt-Brennstoff-Brennstoffzelle

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NARAYANAN S R ET AL: "DESIGN AND OPERATION OF AN ELECTROCHEMICAL METHANOL CONCENTRATION SENSOR FOR DIRECT METHANOL FUEL CELL SYSTEMS", ELECTROCHEMICAL AND SOLID-STATE LETTERS, IEEE SERVICE CENTER, PISCATAWAY, NJ, US, vol. 3, no. 3, March 2000 (2000-03-01), pages 117 - 120, XP000966183, ISSN: 1099-0062 *

Also Published As

Publication number Publication date
DE10040088A1 (de) 2002-04-25
JP2004507050A (ja) 2004-03-04
US20030148151A1 (en) 2003-08-07
EP1338047A2 (de) 2003-08-27
CA2419468A1 (en) 2003-02-14
WO2002015307A2 (de) 2002-02-21

Similar Documents

Publication Publication Date Title
WO2002015307A3 (de) Verfahren zum betrieb eines brennstoffzellensystems und zugehörige brennstoffzellenanlage
WO2004086536A3 (en) Solid oxide fuel cell with selective anode tail gas circulation
WO2007014127A3 (en) Fuel cell system with partial recycling of anode exhaust
WO2004006369A3 (en) Fuel cell power plant
US7479169B2 (en) Gas supplying system and gas supplying method
WO2002035623A8 (en) Systems and processes for providing hydrogen to fuel cells
CA2339508A1 (en) Fuel cell system
WO2003094263A3 (en) Hydrogen production and water recovery system for a fuel cell
WO2002061867A3 (de) Brennstoffzellen mit integrierter befeuchtung sowie verfahren zum befeuchten von brennstoffzellen-prozessgas
US6541139B1 (en) Septic battery
WO2001091206A3 (en) Fuel cell for downhole power systems
EP1416559A3 (de) Brennstoffzellenstapel mit Wärmeaustauscher
WO2004013924A3 (de) Verbundbrennstoffzellenanlage
WO2004086547A3 (en) Cathode inlet gas humidification system and method for a fuel cell system
WO2005043658A3 (en) Fuel cell system and water recovery method thereof
WO2006022981A3 (en) Fuel cell stack design and method of operation
WO2002075833A3 (de) Brennstoffzelle mit integriertem wärmetauscher
US20040043266A1 (en) Solid polymer type fuel cell system
WO2007022467A3 (en) Mixed reactant fuel cell system with vapor recovery and method of recovering vapor
WO2003041201A3 (en) Fuel cell system and its startup control
WO2004091022A3 (en) Fuel cell system
WO2005122304A3 (en) Compact multi-functional modules for a direct methanol fuel cell system
AU5429001A (en) Plant with high temperature fuel cells
WO2001059863A3 (de) Brennstoffzellenblock mit einem an betriebsgaszuleitung angeschlossenen kondenswasserabscheider
WO2002015306A3 (de) Verfahren zur abtrennung von brennstoff aus einem abgas und zugehörige vorrichtung

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): CA CN JP US

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2001960152

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2002520336

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 018140041

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2419468

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 10368156

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 2001960152

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2001960152

Country of ref document: EP