WO2002005761A1 - Composition cosmetique pulverulente longue tenue comprenant un materiau adhesif particulier - Google Patents
Composition cosmetique pulverulente longue tenue comprenant un materiau adhesif particulier Download PDFInfo
- Publication number
- WO2002005761A1 WO2002005761A1 PCT/FR2001/002207 FR0102207W WO0205761A1 WO 2002005761 A1 WO2002005761 A1 WO 2002005761A1 FR 0102207 W FR0102207 W FR 0102207W WO 0205761 A1 WO0205761 A1 WO 0205761A1
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- Prior art keywords
- adhesive material
- temperature
- frequency
- composition
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
Definitions
- the present invention relates to a pulverulent composition comprising an adhesive material intended in particular for the cosmetic and hygienic fields. More specifically, the invention relates to a long-lasting powdery composition without transfer for making up and / or caring for the skin both of the face and of the human body.
- This composition can be in particular in the form of a free or compact powder for making up the face and more especially the cheeks and the eyelids. It is in particular in the form of blush, eyeshadow, blush, or even in the form of face, body or deodorant powder. It can be compacted, pressed or poured, in the form of a stick, a cup or any other form.
- Face powders are often used to mattify the skin and / or color the skin. They generally contain a large quantity of pulverulent compounds formed of pigments and / or fillers, linked together using a phase called a binder, this phase being generally fatty and comprising an oil or a mixture of oils, liquids at room temperature. This fatty phase can also include waxes and possibly additives such as cosmetic or dermatological active ingredients. The powders can also contain surfactants.
- the powders when applied to the skin or the lips, have the drawback of transferring, that is to say of depositing at least in part, leaving traces, on certain supports with which they can be brought into contact, and in particular a garment or the skin or a glass, a cup, a cigarette.
- This transfer occurs in particular during a friction. It follows a mediocre persistence of the applied product, requiring to regularly renew the application of the powder or the make-up.
- the appearance of these traces unacceptable especially on shirt collars may exclude some women from the use of this type of makeup.
- these powders tend to disappear from the face or from the human body, due to the production of sweat and sebum by the skin.
- face or blush powders the migration of the powder results in a marking of certain deep wrinkles, showing the age of the user as well as a disappearance of the color.
- the makeup then becomes unsightly and heterogeneous.
- porous fillers and possibly fluorinated binders are generally used "repelling" sebum and sweat or fillers and pigments coated with fluorides.
- This type of powder has in particular the disadvantages of being expensive, not allowing the general public.
- these fluorinated compounds often present safety and toxicity problems.
- binders comprising compounds which have a certain sticky character such as, for example, petroleum jelly. But very often then, the composition is too cohesive, too sticky and it is very difficult to disintegrate: the user cannot easily take off with the finger or the puff the part of powder which she wishes to use.
- the Applicant has found, quite surprisingly, that the use of a particular adhesive material in a cosmetic or physiological powder composition made it possible to obtain a makeup of very good hold, not transferable at all, resistant to water, the composition also being easily disintegrable.
- the subject of the present invention is therefore a cosmetic and / or physiological pulverulent composition
- a cosmetic and / or physiological pulverulent composition comprising at least one binder and at least one pulverulent compound, characterized in that the binder comprises at least one adhesive material meeting the following conditions:
- - G '(2 10 "2 Hz, 35 ° C) is the elastic shear modulus of said adhesive material, measured at the frequency of 2 10 " 2 Hz and at the temperature of 35 ° C
- - G '(35 ° C) is the elastic shear modulus of said adhesive material, measured at the temperature of 35 ° C, for any frequency between 2 10 "2 and 2 Hz
- EP 0 850 649 describes adhesive articles for the treatment of the skin. However, this document does not describe the use of adhesive materials according to the present invention in make-up powders for the face or for the body.
- the composition according to the invention has excellent hold properties on the skin and "non-transfer". It adheres well to the skin. It is resistant to friction, sweat, sebum, water. It disintegrates easily. It allows a uniform deposition over time on the skin and a uniform makeup. Once applied to the skin, it does not migrate and exhibits very good color fastness over time. The composition spreads out, easily and is very comfortable. It is pleasant to apply and to wear throughout the day. It is non-greasy and does not shine over time. It has a smooth and pleasant touch.
- Another object of the invention is the use in or for the manufacture of a cosmetic or physiological pulverulent composition, of at least one adhesive material as defined above to reduce, or even eliminate, the transfer and / or migration and / or increasing the resistance of the composition deposited on the skin of human beings towards a support brought into contact with the deposit.
- Another object of the invention is the use in or for the manufacture of a cosmetic or physiological pulverulent composition, of at least one adhesive material as defined above to increase the color fastness of the composition in the time.
- the subject of the invention is also a non-therapeutic process for making up and / or caring for human skin, consisting in applying to the skin a cosmetic composition as defined above.
- the composition according to the invention comprises a binder comprising at least one particular adhesive material.
- binder in the sense of the present invention, a liquid or semi-solid phase at room temperature (25 ° C) preferably having a viscosity ranging from 10 "3 Pa.s to 10 5 Pa.s, this viscosity being measured during torsional / shear flow tests on a "Haake RS50" rheometer at a temperature of 25 ° C for a shear rate of 2 s "1 , for example in cone-plane geometry.
- the binder is a non-pulverulent phase, intended to bind the solid particles of the pulverulent phase and to ensure their homogeneous dispersion and their cohesion within the final composition.
- the term material means a polymer or a polymer system which may comprise one or more polymers of different natures. This adhesive material must have a certain tackiness defined by its viscoelastic properties.
- the adhesive materials which can be used according to the present invention have viscoelastic properties which are measured at a reference temperature of 35 ° C. and within a certain frequency range.
- the elastic modulus of the material is measured at three different frequencies:
- the adhesive materials which can be used according to the present invention meet the following four conditions:
- - G '(35 ° C) is the elastic shear modulus of said adhesive material, measured at the temperature of 35 ° C, for any frequency between 2 10 "2 and 2 Hz,
- - G "(0.2 Hz, 35 ° C) is the viscous shear modulus of said adhesive material, measured at the frequency of 0.2 Hz and at the temperature of 35 ° C
- - G '(0.2 Hz, 35 ° C) is the elastic shear modulus of said adhesive material, measured at the frequency of 0.2 Hz and at the temperature of 35 ° C.
- the adhesive materials according to the invention meet the following four conditions:
- the adhesive materials according to the invention can be chosen from the “Pressure Sensitive Adhesives” type adhesives, for example such as those mentioned in the “Handbook of Pressure Sensitive Adhesive Technology” 3 rd edition, D. Satas.
- the pro-adhesive materials according to the invention are preferably adhesive polymers chosen from block or random copolymers comprising at least a monomer or a combination of monomers in which the resulting polymer has a glass transition temperature below ambient temperature (25 ° C.), these monomers or combinations of monomers can be chosen from butadiene, ethylene, propylene, isoprene, isobutylene, a silicone, and mixtures thereof.
- Such materials are block polymers of the styrene-butadiene-styrene, styrene- (ethylene-butylene) -styrene, styrene-isoprene-styrene type, such as those sold under the trade name "Kraton” of Shell Chemical Co. or "Vector From Exxon.
- the pro-adhesive materials according to the invention are preferably adhesive polymers chosen from:
- the adhesive materials are chosen from polyisobutylenes having a relative molar mass Mv greater than or equal to 10,000 and less than or equal to 150,000. More preferably, this relative molar mass is greater than or equal to 18,000 and less than or equal to 150,000.
- the relative molar mass Mv can also be evaluated by GPC (Gel Permission Chromatography) according to the following protocol: 200 ⁇ l of a solution of polymer (adhesive material) at 0.5% is injected using a “Waters” type pump. 6000 A ”, the eluent being a 100% THF solution, flow rate 1 ml / min, at room temperature, through a set of 8 columns: ⁇ styragel 500 ⁇ + 10 4 ⁇ + 2x10 3 ⁇ + styragel HR0.5 + 2xHR1 + HR5E (300 x 7.8mm). The detection is done on a “Waters 410” type refractometer and on a “Waters 490” type UV detector at the wavelength 254 nm.
- GPC Gel Permission Chromatography
- the adhesive material according to the invention can also be a mixture of one or more polyisobutylenes of relative molar mass less than or equal to 10,000 and of one or more polyisobutylenes of mass relative molar greater than 150,000.
- polyisobutylenes with a relative molar mass of less than or equal to 10,000 there may be mentioned the polyisobutylene with a molar mass 455 to 2000 sold under the trade name "Napvis” by the company BP Chemicals or the polyisobutylene sold under the name "Parleam” by the Ets B. Rossow et Cie.
- polyisobutylenes of relative molar mass greater than 150,000 mention may be made of polyisobutylenes of respective relative molar masses 200,000, 400,000 and 1,110,000 sold under the respective trade names “Oppanol B 30 SF”, “Oppanol B 50 SF” and “Oppanol B 100" by BASF, polyisobutylenes with relative molar masses of between 900,000 and 2,200,000 sold under the trade name “Vistanex MM” by the company Exxon, and their mixtures.
- the adhesive materials are preferably present in the composition according to the invention at a content ranging from 0.1 to 99%, preferably from 0.1 to 30%, and more preferably from 0.1 to 10% by weight, relative to the total weight of the composition.
- the binder can comprise, in addition to the above adhesive material, any water-soluble, water-dispersible, liposoluble, or lipodispersible compound which is cosmetically acceptable and conventionally used in cosmetics.
- the binder can be in the form of an anhydrous fatty phase (gel or solution), in the form of an aqueous phase (gel or solution), in the form of a dispersion, in the form of a dispersion aqueous of particles such as a latex or a pseudo-latex, in the form of a nonaqueous dispersion of particles, in the form of an O / W or W / O emulsion, or of a multiple emulsion, optionally stabilized by one or more organized systems.
- the adhesive material according to the invention can be found within the binder in the dissolved form or in the dispersed form, in an aqueous phase or in an anhydrous phase.
- the adhesive material according to the invention can thus be in the form of an aqueous dispersion of particles or in the form of an oily dispersion of particles.
- the binder according to the invention comprises a fatty phase, this can preferably comprise at least one cosmetically or physiologically acceptable oil, in particular chosen from oils of mineral, animal, vegetable or synthetic origin, carbonaceous, hydrocarbon and / or silicone, and mixtures thereof, insofar as they are compatible with the intended use.
- hydrocarbon oils such as paraffin or petroleum jelly oil, mink oil, turtle oil, soybean oil, perhydrosqualene, sweet almond oil, calophyllum oil, palm oil, grape seed oil , sesame, corn, macaw, rapeseed, sunflower, cotton, apricot, castor, avocado, jojoba, olive or cereal sprouts; esters of lanolic acid, oleic acid, lauric acid, stearic acid; fatty esters, such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethyl palmitate -hexyl, 2-hexyl-decyl laurate, 2-octyl-decyl palmitate, 2-octyl-dodecyl myristate or lactate, 2-diethy
- At least one volatile oil can be used at room temperature.
- volatile oil is meant an oil capable of evaporating from the skin, at room temperature in less than an hour.
- the volatile oil has a viscosity ranging from 0.5 to 25 centistokes at 25 ° C. After evaporation of these oils, we obtain a deposit of particles, not sticky on the skin or mucous membranes.
- oils are used whose flash point is high enough to allow the use of these oils in formulation. These volatile oils also facilitate the application of the composition to the skin.
- oils can be hydrocarbon oils, silicone oils optionally comprising alkyl or alkoxy groups at the end of the silicone or pendant chain.
- volatile silicone oil which can be used in the invention, mention may be made of linear or cyclic silicones having from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms. Mention may in particular be made of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane and / or their mixtures.
- C 8 -C 16 isoparaffins such as isooctane, isododecane, isodecane, heptane, isohexadecane and / or mixtures thereof.
- volatile oils may be present in the composition according to the invention at a content ranging from 0.1 to 99% by weight, preferably from 0.1 to 60%, and more preferably from 0.1 to 40%, relative to the total weight of the composition.
- the weight ratio of volatile oil to the adhesive material according to the invention ranges from 1 to 20, more preferably from 1 to 10, and better still from 2 to 4.
- the fatty phase can also comprise at least one wax, at least one gum and / or at least one pasty fatty substance, of vegetable, animal, mineral or synthetic origin, or even silicone, and their mixtures.
- solid waxes at room temperature which may be present in the composition according to the invention, mention may be made of hydrocarbon waxes such as beeswax, Carnauba, Candellila, Ouricoury, Japanese wax, cork fiber or cane wax, paraffin wax, lignite wax, microcrystalline wax, lanolin wax , Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch synthesis, hydrogenated oils, fatty esters and concrete glycerides at 25 ° C. It is also possible to use silicone waxes, among which mention may be made of alkyl, alkoxy and or esters of polymethylsiloxane.
- hydrocarbon waxes such as beeswax, Carnauba, Candellila, Ouricoury, Japanese wax, cork fiber or cane wax, paraffin wax, lignite wax, microcrystalline wax, lanolin wax , Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch
- the waxes can be in the form of stable dispersions of colloidal particles of wax as they can be prepared according to known methods, such as those of "Microemulsions Theory and Practice", LM Prince Ed., Académie Press (1977) , pages 21-32.
- Menesojoba oil As liquid wax at room temperature, mention may be made of Jojoba oil.
- the waxes can be present in an amount of 0.1 to 30%, by weight, relative to the total weight of the composition.
- the pasty fatty compounds can be defined using at least one of the following physicochemical properties:
- compositions of the invention may also comprise at least one alkyl, alkoxy or phenyl-dimethicone such as, for example the product sold under the name of "Abil wax 2440" by the company GOLDSCHMIDT.
- compositions according to the invention can also comprise at least one silicone resin comprising a combination of the units R 3 SiO 1/2 , R 2 Si ⁇ 22 , RSiO 3/2 and SiO 4/2 , in which R denotes an alkyl radical having from 1 to 6 carbon atoms.
- the fatty phase can also contain at least one liposoluble dye.
- This fat-soluble dye is for example Sudan red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan brown, DC Yellow, 11, DC Violet 2, DC orange 5 , quinoline yellow, and mixtures thereof. It can represent from 0.01 to 20% of the total weight of the compositions and better still from 0.1 to 6%.
- the fatty phase can represent from 0.1 to 40%, preferably from 0.1 to 20%, by weight, relative to the total weight of the final composition.
- the binder according to the invention comprises an aqueous phase
- this can comprise water, a floral water such as blueberry water and / or a mineral water such as VITTEL water, LUCAS or LA ROCHE POSAY water and / or thermal water.
- the aqueous phase can also include solvents other than water, for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C ⁇ -C4) mono, di- or tripropylene glycol, mono, di- or triethylene glycol ether, and mixtures thereof.
- solvents other than water for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C ⁇ -C4) mono, di- or tripropylene glycol, mono, di- or triethylene glycol ether, and mixtures thereof.
- the aqueous phase can also comprise at least one water-soluble dye chosen from the usual dyes of the field under consideration such as the disodium salt of culvert, the disodium salt of alizarin green, quinoline yellow, the tri-sodium salt of amaranth, disodium salt of tartrazine, monosodium salt of rhodamine, disodium salt of fuchsin, xanthophyll, and mixtures thereof.
- the disodium salt of culvert the disodium salt of alizarin green, quinoline yellow
- the tri-sodium salt of amaranth disodium salt of tartrazine
- monosodium salt of rhodamine disodium salt of fuchsin, xanthophyll, and mixtures thereof.
- the aqueous phase can also comprise any water-soluble or water-dispersible compound compatible with an aqueous phase such as gelling agents, film-forming polymers, thickeners, surfactants and mixtures thereof.
- the aqueous phase is present in the compositions of the invention at a content ranging from 0.1 to 40% by weight, preferably from 0.1 to 20% by weight, relative to the total weight of the composition.
- the binder of the composition according to the invention can also comprise at least one O / W or W / O surfactant usually used in cosmetics.
- the composition according to the invention also comprises at least one pulverulent compound.
- the pulverulent compounds can be chosen from pigments and / or pearlescent agents and / or fillers and / or their mixtures usually used in cosmetic compositions.
- the pulverulent compounds are present at a content ranging from 60 to 99.9%, more preferably from 80 to 99.9% by weight, relative to the total weight of the composition.
- the pigments can be white or colored, mineral and / or organic.
- mineral pigments mention may be made of titanium dioxide, optionally surface-treated, zirconium or cerium oxides, as well as iron or chromium oxides, manganese violet, ultramarine blue, hydrate of chrome and ferric blue.
- organic pigments there may be mentioned carbon black, pigments of the D & C type, and lakes based on cochineal carmine, barium, strontium, calcium, aluminum.
- the pearlescent pigments can be chosen from white pearlescent pigments such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as mica titanium with iron oxides, mica titanium with especially ferric blue or chromium oxide, titanium mica with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.
- the fillers can be mineral or organic, lamellar or spherical.
- composition can also comprise any compound usually used in such compositions, such as thickeners, antioxidants, perfumes, preservatives, active agents.
- moisturizers As cosmetic, dermatological and hygienic active agents which can be used in the composition of the invention, mention may be made of moisturizers, vitamins, essential fatty acids, sphingolipids, sun filters. These active ingredients are present in an amount generally used in powders. In particular, they are present in an amount of 0.001 to 20% of the total weight of the composition.
- compositions according to the invention can be prepared in the usual manner by a person skilled in the art. They can be in the form of a compact powder, for example in the form a stick or a dish that can be used by finger or sponge: in particular, they find application as a blush, blush or eyeshadow, lip powder, care or make-up powder for the face or body or deodorant powder. They can also be in the form of a loose powder, in particular as a blush, care or make-up powder for the face or body or a deodorant powder.
- compositions for topical application can also constitute a cosmetic, dermatological, hygienic or protective, treatment or care composition for the face, for the neck, for the hands or for the body (for example anhydrous care powder, perfumed or not, sun powder), a makeup composition (for example makeup gel) or an artificial tanning composition.
- a cosmetic, dermatological, hygienic or protective, treatment or care composition for the face, for the neck, for the hands or for the body for example anhydrous care powder, perfumed or not, sun powder
- a makeup composition for example makeup gel
- an artificial tanning composition for topical application.
- composition 1 in the following powder form
- the binder (phase B) is produced in the following manner: the polyisobutylene are mixed with the isododecane with stirring at room temperature until a homogeneous liquid is obtained.
- phase A compounds are mixed in a turbine mixer. This mixture is then ground using a spindle mill or an air jet mill. Finally, the binder (phase B) is added dropwise to phase A with stirring in a turbine mixer whose temperature is kept constant. aunt at 20 ° C. The two phases are mixed until a homogeneous product is obtained.
- the composition obtained has excellent resistance over time. It does not transfer, we do not observe any migration phenomenon.
- composition 2 The Applicant has produced the following composition 2
- This composition was prepared according to the same method as in Example 1, the binder being prepared by mixing the polyisobutylenes with isododecane with stirring at room temperature until a homogeneous liquid is obtained.
- the adhesive material according to the invention is therefore the mixture of 0.8% of the polyisobutylene "Oppanol B100" and 3.2% of the polyisobutylene "Napvis D 07": this adhesive material has the following characteristics, measured according to the methods described in this request:
- a powder is obtained which has excellent resistance over time and on the skin.
- composition 3 (comparative)
- This composition was prepared according to the same method as in Example 1, the binder not comprising polyisobutylene.
- compositions 1 and 3 were tested on 10 models in the following manner: each composition was applied in comparison by half face and neck. After the makeup application, a fabric “collar” was placed around the neck. This tissue was removed 30 min later in order to visualize the quantity of powder transferred to the tissue.
- composition 1 In 70% o of the cases, the quantity of powder transferred to the fabric is much lower for composition 1 (example 1).
- the models are asked to note the effect without transfer on a scale of 0 to 7, the value 0 being given for a composition which does not transfer at all and the value 7 being given for a composition which transfers completely.
- Composition 1 according to the invention obtains an average of 3 against an average of 4.2 for comparative composition 3. This shows that the non-transfer properties of Example 1 (containing the adhesive) are significantly superior to those of Example 3 (without adhesive).
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01955390A EP1303247A1 (fr) | 2000-07-13 | 2001-07-09 | Composition cosmetique pulverulente longue tenue comprenant un materiau adhesif particulier |
US10/312,805 US20040047884A1 (en) | 2000-07-13 | 2001-07-09 | Long-lasting powder cosmetic composition comprising a specific adhesive material |
JP2002511695A JP2004503573A (ja) | 2000-07-13 | 2001-07-09 | 特定の接着性物質を含む長期持続性粉末状化粧品組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR00/09215 | 2000-07-13 | ||
FR0009215A FR2811548B1 (fr) | 2000-07-13 | 2000-07-13 | Composition cosmetique pulverulente longue tenue comprenant un materiau adhesif particulier |
Publications (1)
Publication Number | Publication Date |
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WO2002005761A1 true WO2002005761A1 (fr) | 2002-01-24 |
Family
ID=8852479
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/FR2001/002207 WO2002005761A1 (fr) | 2000-07-13 | 2001-07-09 | Composition cosmetique pulverulente longue tenue comprenant un materiau adhesif particulier |
Country Status (5)
Country | Link |
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US (1) | US20040047884A1 (fr) |
EP (1) | EP1303247A1 (fr) |
JP (1) | JP2004503573A (fr) |
FR (1) | FR2811548B1 (fr) |
WO (1) | WO2002005761A1 (fr) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811547B1 (fr) * | 2000-07-13 | 2003-09-26 | Oreal | Composition cosmetique longue tenue comprenant un materiau pro-adhesif particulier |
US8586016B2 (en) * | 2006-03-13 | 2013-11-19 | L'oreal | Hydrocarbon complex mascara |
US8673282B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a selective solvent for soft blocks |
US8778323B2 (en) * | 2006-05-03 | 2014-07-15 | L'oréal | Cosmetic compositions containing block copolymers, tackifiers and modified silicones |
US8557230B2 (en) * | 2006-05-03 | 2013-10-15 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and shine enhancing agents |
US8758739B2 (en) * | 2006-05-03 | 2014-06-24 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and gelling agents |
US8673283B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a solvent mixture |
US8673284B2 (en) * | 2006-05-03 | 2014-03-18 | L'oreal | Cosmetic compositions containing block copolymers, tackifiers and a selective solvent for hard blocks |
US8658141B2 (en) | 2007-01-12 | 2014-02-25 | L'oreal | Cosmetic composition containing a block copolymer, a tackifier, a silsesquioxane wax and/or resin |
JP4976179B2 (ja) * | 2007-03-30 | 2012-07-18 | 株式会社コーセー | 油性睫毛用化粧料 |
US20120219516A1 (en) | 2011-02-25 | 2012-08-30 | L'oreal S.A. | Cosmetic compositions having long lasting shine |
WO2015154804A1 (fr) * | 2014-04-09 | 2015-10-15 | Lvmh Recherche | Composition cosmétique de maquillage des yeux |
Citations (5)
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---|---|---|---|---|
US4496357A (en) * | 1981-06-10 | 1985-01-29 | Hollister Incorporated | Skin barrier composition |
US4668505A (en) * | 1984-04-13 | 1987-05-26 | L'oreal | Sunscreen method containing polyisobutylene for the protection of human epidermis against ultraviolet radiations |
EP0681832A2 (fr) * | 1994-05-11 | 1995-11-15 | Hüls Aktiengesellschaft | Solutions aqueuses et viscoélastiques d'agents tensioactifs pour le nettoyage de la peau et des cheveux |
EP0717979A2 (fr) * | 1994-11-24 | 1996-06-26 | L'oreal | Composition cosmétique sous forme de poudre compacte et procédé de préparation |
JPH09151111A (ja) * | 1995-11-30 | 1997-06-10 | Shiseido Co Ltd | 粉末プレス状メーキャップ化粧料 |
-
2000
- 2000-07-13 FR FR0009215A patent/FR2811548B1/fr not_active Expired - Fee Related
-
2001
- 2001-07-09 US US10/312,805 patent/US20040047884A1/en not_active Abandoned
- 2001-07-09 JP JP2002511695A patent/JP2004503573A/ja active Pending
- 2001-07-09 EP EP01955390A patent/EP1303247A1/fr not_active Withdrawn
- 2001-07-09 WO PCT/FR2001/002207 patent/WO2002005761A1/fr not_active Application Discontinuation
Patent Citations (5)
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US4496357A (en) * | 1981-06-10 | 1985-01-29 | Hollister Incorporated | Skin barrier composition |
US4668505A (en) * | 1984-04-13 | 1987-05-26 | L'oreal | Sunscreen method containing polyisobutylene for the protection of human epidermis against ultraviolet radiations |
EP0681832A2 (fr) * | 1994-05-11 | 1995-11-15 | Hüls Aktiengesellschaft | Solutions aqueuses et viscoélastiques d'agents tensioactifs pour le nettoyage de la peau et des cheveux |
EP0717979A2 (fr) * | 1994-11-24 | 1996-06-26 | L'oreal | Composition cosmétique sous forme de poudre compacte et procédé de préparation |
JPH09151111A (ja) * | 1995-11-30 | 1997-06-10 | Shiseido Co Ltd | 粉末プレス状メーキャップ化粧料 |
Non-Patent Citations (1)
Title |
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CHEMICAL ABSTRACTS, vol. 127, no. 4, 28 July 1997, Columbus, Ohio, US; abstract no. 55664, "Pressed powdery makeup cosmetics containing organosilicone resins and polybutene." XP002167271 * |
Also Published As
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US20040047884A1 (en) | 2004-03-11 |
FR2811548B1 (fr) | 2002-08-23 |
EP1303247A1 (fr) | 2003-04-23 |
JP2004503573A (ja) | 2004-02-05 |
FR2811548A1 (fr) | 2002-01-18 |
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