WO2001078661A2 - Mousse aerosol pour traitement capillaire - Google Patents

Mousse aerosol pour traitement capillaire Download PDF

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Publication number
WO2001078661A2
WO2001078661A2 PCT/EP2001/003799 EP0103799W WO0178661A2 WO 2001078661 A2 WO2001078661 A2 WO 2001078661A2 EP 0103799 W EP0103799 W EP 0103799W WO 0178661 A2 WO0178661 A2 WO 0178661A2
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WO
WIPO (PCT)
Prior art keywords
aerosol
aerosol foam
hair
foam according
cationic
Prior art date
Application number
PCT/EP2001/003799
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German (de)
English (en)
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WO2001078661A3 (fr
Inventor
Jean-Luc Galley
Johann Aeby
Original Assignee
Wella Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella Aktiengesellschaft filed Critical Wella Aktiengesellschaft
Priority to AU63833/01A priority Critical patent/AU6383301A/en
Publication of WO2001078661A2 publication Critical patent/WO2001078661A2/fr
Publication of WO2001078661A3 publication Critical patent/WO2001078661A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5428—Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic

Definitions

  • the invention relates to an aerosol foam for hair treatment containing at least one cationic, amphoteric or zwitterionic polymer, at least one surfactant, at least one defoamer, an aqueous or aqueous-alcoholic solvent system and at least one aerosol propellant.
  • the defoamer is preferably a silicone antifoam emulsion which contains physiologically indifferent active components based on polydimethylsiloxane / silica.
  • Aerosol foams for hair treatment are known and generally consist of hair-setting or hair-care substances, foaming agents and propellant gases and a suitable water-based solvent base.
  • Various demands are placed on the quality of such aerosol foams, which can be roughly divided into two groups.
  • One group of quality requirements relates to the quality of the foam, ie the nature of the foam. These include, for example, the fine or coarse pores, the compactness, the temporal stability of the foam, the incorporability and distributability on the hair, etc.
  • the second group of quality requirements relates to the effects that the foam has on the hair after incorporation into the hair , ie the hair care properties such as, for example, the handle of the hair when wet and dry, the combability, the strengthening, the stress on the hair, etc.
  • the problem with the optimization of aerosol foams is that although the addition of special active ingredients can improve some quality requirements, for example the foam quality, this is bought with a deterioration in other quality requirements, for example the hair-care properties.
  • the object was therefore to improve the foam quality of aerosol foams for hair treatment, the hair care properties not being impaired at the same time, but ideally also being improved.
  • the subject of the invention is therefore an aerosol foam for hair treatment containing
  • the polymer (A) is contained in the agent according to the invention preferably in an amount of 0.01 to 20, particularly preferably from 0.02 to 10, very particularly preferably from 0.1 to 5 percent by weight.
  • Suitable polymers (A) are those which, owing to cationic or cationizable groups, in particular primary, secondary, tertiary or preferably quaternary amine groups, have a substantivity to human hair.
  • Suitable polymers (A) are selected from polymers with cationic or cationizable groups, polymeric silicone compounds with cationic or cationizable groups and cationically derivatized proteins or protein hydrolyzates.
  • the suitable cationic polymers are hair-setting and / or hair-conditioning polymers.
  • Suitable polymers of component (A) preferably contain quaternary amine groups.
  • the cationic polymers can be homo- or copolymers, the quaternary nitrogen groups being contained either in the polymer chain or preferably as a substituent on one or more of the monomers.
  • the monomers containing ammonium groups can be copolymerized with non-cationic monomers.
  • Suitable cationic monomers are unsaturated, free-radically polymerizable compounds which carry at least one cationic group, in particular ammonium-substituted vinyl monomers such as, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers containing cyclic, cationic nitrogenous substances Groups such as pyridinium, imidazolium or quaternary pyrrolidones, for example alkylvinylimidazolium, alkylvinylpyridinium, or alylvinylpyrrolidone salts.
  • the alkyl groups of these monomers are preferably lower alkyl groups such as, for example, Cl to C7 alkyl groups, particularly preferably Cl to C3 alkyl groups.
  • the monomers containing ammonium groups can be copolymerized with non-cationic monomers.
  • Suitable non-cationic comonomers are, for example, acrylamide, methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl caprolactam, vinyl pyrrolidone, vinyl ester, e.g. Vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably being Cl to C7 alkyl groups, particularly preferably Cl to C3 alkyl groups.
  • Suitable polymers with quaternary amine groups are, for example, the polymers described in the CTFA Cosmetic Ingredient Dictionary under the names Polyquaternium, such as dimethyldiallylammonium chloride / acrylic acid copolymer (Polyquaternium-22), methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinylpyramethyl-acrylate / vinylpyramethyl-copolymerized Polyquaternium-11) and quaternary silicone polymers or oligomers such as silicone polymers with quaternary end groups (Quaternium-80).
  • Polyquaternium such as dimethyldiallylammonium chloride / acrylic acid copolymer (Polyquaternium-22), methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinylpyramethyl-acrylate / vinylpyramethyl-copolymerized Polyquaternium-11
  • Other cationic polymers include those from BASF,
  • Gaffix VC 713 sold terpolymer of vinyl pyrrolidone, dimethylaminoethyl methacrylate and vinyl caprolactam and that from Gaf under the
  • Suitable cationic polymers derived from natural polymers are cationic derivatives of polysaccharides, for example cationic derivatives of cellulose, starch or guar. Chitosan and chitosan derivatives are also suitable.
  • Cationic polysaccharides have the general formula (I)
  • G is an anhydroglucose residue, e.g. starch or cellulose anhydroglucose;
  • B is a divalent Linking group, for example alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene;
  • R a , R b and R c are independently of one another alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl each having up to 18 C atoms, the total number of C atoms in R a , R b and R c preferably being a maximum of 20 is;
  • X is a common counter anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride.
  • a cationic cellulose is sold under the name Polymer JR by Amerchol and has the INCI name Polyquaternium-10.
  • Another cationic cellulose has the INCI name Polyquaternium-24 and is sold under the trade name Polymer LM-200 by
  • a suitable cationic guar derivative is sold under the trade name Jaguar R and has the INCI name guar hydroxypropyltrimonium chloride.
  • Particularly preferred cationic substances are chitosan, chitosan salts and chitosan derivatives.
  • the chitosans to be used according to the invention are completely or partially deacetylated chitins.
  • the production of chitosan is preferably based on the chitin contained in the shell remains of crustaceans, which is available in large quantities as a cheap and natural raw material.
  • the molecular weight of the chitosan can be distributed over a broad spectrum, for example from 20,000 to about 5 million g / mol.
  • a low molecular weight chitosan with a molecular weight of 30,000 to 70,000 g / mol is suitable.
  • the molecular weight is preferably above 100,000 g / mol, particularly preferably from 200,000 to 700,000 g / mol.
  • the degree of deacetylation is preferably 10 to 99%, particularly preferably 60 to 99%.
  • a suitable chitosan is, for example, from the company Kyowa Oil & Fat, Japan, under the trade name
  • Flonac distributed. It has a molecular weight of 300,000 to 700,000 g / mol and is 70 to 80% deacetylated.
  • a preferred chitosan salt is chitosonium pyrrolidone carboxylate, which is sold, for example, under the name Kytamer PC by Amerchol, USA.
  • the chitosan contained has a molecular weight of approx. 200,000 to 300,000 g / mol and is 70 to 85% deacetylated.
  • Quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl, hydroxypropyl or hydroxybutyl chitosan, are suitable as chitosan derivatives.
  • the chitosans or chitosan derivatives are preferably in neutralized or partially neutralized form.
  • the degree of neutralization for the chitosan or the chitosan derivative is preferably at least 50%, particularly preferably between 70 and 100%, based on the number of "free base groups.
  • Tion medium as Neutralisa- principle all cosmetically compatible inorganic or organic acids can be used such as formic acid , Tartaric acid, malic acid, lactic acid, citric acid, pyrrolidone carboxylic acid, hydrochloric acid and others, of which pyrrolidone carboxylic acid is particularly preferred.
  • Preferred polymers are those which have sufficient solubility in aqueous or aqueous-alcoholic solvent systems in order to be able to medium in completely dissolved form.
  • the cationic charge density is preferably 1 to 7 meq / g.
  • Suitable cationic silicone compounds preferably have either at least one amino group or at least one ammonium group.
  • Suitable silicone polymers with amino groups are known under the INCI name Amodimethicone. These are polydimethylsiloxanes with aminoalkyl groups. The aminoalkyl groups can be side or terminal.
  • Suitable aminosilicones are those of the general formula (II)
  • R 1 , R 2 , R 7 and R 8 are independently the same or different and are Cl- to CIO-alkyl, phenyl, hydroxy, hydrogen, Cl- to ClO-alkoxy or acetoxy, preferably C1-C4-alkyl, particularly preferred Methyl;
  • R 3 and R 9 are independently the same or different and are - (CH 2 ) a -NH 2 with a equal to 1 to 6, Cl to CIO alkyl, phenyl, hydroxy, hydrogen, Cl to ClO alkoxy or acetoxy , preferably C1-C4-alkyl, particularly preferably methyl;
  • R 4 , R 5 and R 6 are independently the same or different and are hydrogen, Cl- to C20-hydrocarbon, which can contain O and N atoms, preferably Cl- to CIO-alkyl or phenyl, particularly preferably Cl- bis C4 alkyl, especially methyl;
  • Q is -A-NR ⁇ R 11 , or -AN + R 10 R 1X R 12 where A is a divalent Cl to C20 alkylene linking group, which can also contain 0 and N atoms and OH groups, and R 10 , R 11 and R 12 are independently the same or different and are hydrogen, Cl to C22 hydrocarbon, preferably Cl to C-4 alkyl or Phenyl mean.
  • Preferred radicals for Q are
  • R 13 is a Cl to C22 alkyl radical, which may also have OH groups.
  • X represents a number between 1 and 10,000, preferably between 1 and 1,000;
  • Y represents a number between 1 and 500, preferably between 1 and 50.
  • the molecular weight of the aminosilicones is preferably between 500 and 100,000.
  • the amine content (meq / g) is preferably in the range from 0.05 to 2.3, particularly preferably from 0.1 to 0.5.
  • Suitable silicone polymers with two terminal quaternary ammonium groups are known under the INCI name Quaternium-80. These are dimethylsiloxanes with two terminal aminoalkyl groups. Suitable quaternary aminosilicones are those of the general formula (III)
  • R 13 is a Cl to C22 alkyl radical, which may also have OH groups;
  • R 1 , R 2 , R 4 and R 5 have the same meaning as given above for formula (II) and are preferably methyl;
  • R 14 , R 15 and R 16 independently of one another are C 1 to C 22 alkyl radicals which may contain hydroxyl groups and where preferably at least one of the radicals has at least 10 C atoms and the remaining radicals have 1 to 4 C atoms;
  • n is a number from 0 to 200, preferably 10 to 100.
  • Such diquaternary polydimethylsiloxanes are sold by GOLDSCHMIDT / Germany under the trade names Abil ® Quat 3270, 3272 and 3274.
  • cationic, hair-care compounds are cationically modified protein derivatives or cationically modified protein hydrolyzates and are known, for example, under the INCI names lauryldimonium hydroxypropyl hydrolyzed wheat protein, lauryldimonium hydroxypropyl hydrolyzed casein, lauryldimonium hydroxypropyl hydrolyzed collagen, lauryldimonium hydroxypropyl, and lauryldimonium hydroxypropyl , Lauryidimonium hydroxypropyl or hydroxypropyltrimonium Hydrolyzed Soy protein Hydrolyzed Wheat, hydroxypropyltrimonium Hydrolyzed casein, hydroxypropyltrimonium Hydrolyz "ed collagen, hydroxypropyltrimonium Hydrolyzed keratin, hydroxypropyltrimonium Hydrolyzed Rice Bran protein, hydroxypropyltrimonium Hydrolyzed Silk, hydroxypropyltrimonium Hydrolyzed Soy protein, Hydro
  • Suitable cationically derivatized protein hydrolyzates are mixtures of substances which are obtained, for example, by reacting alkaline, acidic or enzymatically hydrolyzed proteins with glycidyltrialkylammonium salts or 3-halo-2-hydroxypropyltrialkylammonium salts can be obtained.
  • Proteins that serve as starting materials for the protein hydrolyzates can be of both vegetable and animal origin. Common starting materials are, for example, keratin, collagen, elastin, soy protein, rice protein, milk protein,
  • the hydrolysis produces mixtures of substances with molecular weights in the range from approximately 100 to approximately 50,000. Usual average molecular weights are in the range from about 500 to about 1000.
  • the cationically derivatized protein hydrolyzates advantageously contain one or two long C8 to C22 alkyl chains and correspondingly two or a short Cl to C4 alkyl chain. Compounds containing a long alkyl chain are preferred.
  • Suitable amphoteric polymers are those which, in addition to cationic or cationizable basic groups, in particular primary, secondary, tertiary or quaternary amine groups, contain anionic or anionizable acidic groups as further functional groups.
  • Examples of these are copolymers formed from alkyl acrylamide (in particular octylacrylamide), alkylaminoalkyl methacrylate (in particular t-butylaminoethyl methacrylate) and two or more monomers consisting of acrylic acid, methacrylic acid or their esters (INCI name: octylacrylamides / acrylates / butylaminoethyl) Methacrylate copolymer), such as
  • amphomer ® LV-71 from NATIONAL STARCH, USA.
  • Further suitable amphoteric polymers are copolymers which are formed from at least one first type of monomer which has quaternary amine groups and at least one second type of monomer which has acid groups.
  • copolymers examples include copolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47), as are marketed, for example, by the company Calgon under the trade name Merquat "2001, copolymers of acrylamidopropyltrimethylammonium chloride and acrylates, as are used, for example, by the Stockhausen company are available under the trade name W 37194 or copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dirnethylaminopropylamine (INCI name: Polyquaternium-43), such as those from Societe Francaise
  • Bozequat 4000 Polymers with monomers bearing betaine groups, such as e.g. Copolymers of methacryloylethylbetaine and two or more monomers of acrylic acid or their simple esters, known under the INCI name Methacryloyl Ethyl Betaine / Acrylates Copolymer.
  • the surfactant (B) is contained in the agent according to the invention preferably in an amount of 0.01 to 15, particularly preferably 0.05 to 10 percent by weight.
  • Suitable surfactants have emulsifying, solubilizing, foam-forming or foam-enhancing properties and are preferably nonionic.
  • non-ionic surfactants are suitable for the hair treatment composition according to the invention if they have an HLB value of at most 20, preferably from 5 to 18.
  • Ethoxylated surfactants are preferred, the number of ethylene oxide units being between 1 and 1000, preferably between 1 and 300, particularly preferably between 1 and 15.
  • Fatty acid glyceride ethoxylates, fatty alcohol ethoxylates, fatty amine ethoxylates, fatty acid alkanolamide ethoxylates and fatty acid ester ethoxylates each with 1 to 50 ethylene oxide units are preferred.
  • suitable fatty alcohol ethoxylates are oxyethylated lauryl, tetradecyl, cetyl, oleyl or stearyl alcohol, which can be used alone or in a mixture, and fatty alcohols of oxyethylated lanolin or oxyethylated lanolin.
  • the ethoxylated fatty alcohols which are marketed under the type name Dehydol by Henkel or under the type name Brij ® by ICI Surfactants, are also suitable for the hair treatment composition according to the invention.
  • diglyceride ethoxylates such as that from ICI are particularly worth mentioning
  • nonionic surfactants sold under the name Rewoderm ® LI.
  • Preferred nonionic surfactants are ethoxylated FettTexrezuckerester, in particular ethoxylated sorbitan fatty acid esters known as polysorbates, but not ethoxylated surfactants, such as the FettTexrezuckerester, sold by ICI Surfactants under the trade name Tween and Arlacel ®, as well as the alkyl polyglycosides, of the company
  • the defoamer (C) is preferably present in the aerosol hair foam according to the invention in an amount of 0.001 to 0.5, particularly preferably 0.005 to 0.1% by weight.
  • Non-organic defoamers are preferred, especially those based on physiologically indifferent active components such as polydimethylsiloxane / silica. Such active ingredients are known under the
  • Simethicone This is a mixture of dimethicones (polydimethylsiloxanes) with an average chain length of 200 to 350 dimethylsiloxane units and hydrated silica. They can be used in the form of silicone antifoam emulsions. These are aqueous emulsions of simethicones.
  • the agent according to the invention is confectioned in an aqueous or in an aqueous-alcoholic medium with preferably at least 10 percent by weight of water. kidney.
  • the solvent system is preferably contained in an amount of 50 to 98, particularly preferably 75 to 95 percent by weight.
  • the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes, such as ethanol and isopropanol, can be included as alcohols.
  • the agent according to the invention can be present in a pH range from 2.0 to 9.5. The pH range between 3.5 and 8 is particularly preferred.
  • Organic solvents or a mixture of solvents with a boiling point below 400 ° C. can be present as additional co-solvents in an amount of 0.1 to 15, preferably 1 to 10 percent by weight.
  • Unbranched or branched hydrocarbons such as pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane are particularly suitable as additional co-solvents.
  • Other particularly preferred water-soluble solvents are glycerol, ethylene glycol and propylene glycol.
  • the blowing agent (E) is preferably present in the aerosol hair foam according to the invention in an amount of 1 to 20, particularly preferably 2 to 10 percent by weight.
  • blowing agents are, for example, lower alkanes, such as n-butane, i-butane, propane, butane, or also their mixtures, and also dimethyl ether or fluorocarbons such as F 152a (1,1-difluoroethane) or F 134 (tetrafluoroethane) and further suitable at the pressures under consideration gaseous blowing agents, such as N 2 , N 2 0 and C0 2, as well as mixtures of the blowing agents mentioned above.
  • the agent according to the invention additionally contains 0.01 to 15 percent by weight, preferably 0.5 to 10 percent by weight, of at least one synthetic or natural nonionic film-forming polymer.
  • Particularly preferred are those polymers which have sufficient solubility in water or water / alcohol mixtures to be present in the agent according to the invention in completely dissolved form.
  • film-forming polymers are understood to mean those polymers which, when used in 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution, are able to deposit a polymer film on the hair.
  • Suitable synthetic, nonionic film-forming, hair-fixing polymers are homopolymers or copolymers which are composed of at least one of the following monomers: vinylpyrrolidone, vinylcaprolactam, vinyl esters such as e.g. Vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl and dialkylacrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably Cl to C7 alkyl groups, particularly preferably Cl to bis C3 are alkyl groups.
  • Homopolymers of vinyl caprolactam, vinyl pyrrolidone or N-vinyl formamide are suitable, for example.
  • Other suitable synthetic film-forming, non-ionic, hair-fixing polymers are, for example, copolymers of vinyl pyrrolidone and vinyl acetate, terpolymers of vinyl pyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides, for example under the trade names Akypomine "P 191 sold by the company CHEM-Y, Emmerich or Sepigel ® 305 by the company SEPPIC; polyvinyl alcohols, for example, under the
  • Suitable natural film-forming polymers are e.g. Cellulose derivatives, e.g. Hydroxypropyl cellulose with a molecular weight of 30,000 to 50,000 g / mol, which is sold, for example, under the trade name Nisso Sl ® by Lehmann & Voss, Hamburg.
  • the agent according to the invention can furthermore contain the additional ingredients customary for hair treatment agents, for example perfume oils in an amount of 0.01 to 0.5 percent by weight; Opacifiers, such as ethylene glycol distearate, in an amount of about 0.2 to 5.0 percent by weight; Preservatives such as parabens in an amount of 0.01 to 1.0 percent by weight; Buffer substances such as sodium citrate or sodium phosphate in an amount of 0.1 to 1.0 percent by weight; Care substances, such as plant and herbal extracts, protein and silk hydrolyzates, lanolin derivatives, in an amount of 0.1 to 5 percent by weight; physiologically compatible silicone derivatives, such as volatile or non-volatile silicone oils or highly molecular siloxane polymers in an amount of 0.05 to 20% by weight; Light stabilizers, antioxidants, radical scavengers, antidandruff agents, in an amount of about 0.01 to 2% by weight; direct hair dyes, hair dyes that are developed oxidatively, oxidizing agents, reducing agents,
  • the aerosol foam according to the invention is filled in a pressure-resistant aerosol packaging which is provided with an aerosol foam head.
  • a foam forms which can be worked into the hair particularly easily and which breaks down particularly quickly when it is worked into the hair.
  • the cosmetic agent according to the invention is applied by applying and incorporating it in an amount sufficient to achieve the desired hair-care or hair-fixing effect on damp, towel-dried hair and leaving it in the hair without rinsing. Then the hairstyle can be shaped in the usual way or the hair can be inserted and finally blow-dried. But it is also possible to use the product directly on dry hair.
  • a foam that breaks down very quickly on the hair can be obtained.
  • the care properties are not impaired by the very small amount used (for example 0.01-0.5% by weight) but even improved, especially the wet grip, the combability, the dry grip and the strain on dry hair.
  • the mixture of active ingredients was filled in a ratio of 92: 8 with propane / n-butane 4.8 bar as propellant in an aerosol can with a foam valve.
  • Pattern 1E has an improved foam quality compared to pattern IV, the foam breaks down faster and is less stable and compact.
  • the hair treated with pattern 1E has a better grip on damp hair than the hair treated with pattern IV.
  • the hair feels lighter and less greasy.
  • the hair treated with sample 1E has better combability than the hair treated with sample IV.
  • the hair treated with pattern 1E has a better grip on dry hair than the hair treated with pattern IV.
  • the hair feels lighter and less oily.
  • the hair treated with sample 1E has a lower load than the hair treated with sample IV.
  • the mixture of active ingredients was filled in a ratio of 94: 6 with propane / n-butane 4.8 bar as propellant in an aerosol can with a foam valve.
  • the mixture of active ingredients was filled in a ratio of 92: 8 with propane / n-butane 4.8 bar as propellant in an aerosol can with a foam valve.

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

Mousse aérosol pour traitement capillaire, qui contient au moins un polymère cationique, amphotère ou zwittérionique, au moins un tensioactif, au moins un agent antimoussant, un système solvant aqueux ou eau-alcool et au moins un gaz propulseur d'aérosol. L'agent antimoussant est de préférence une émulsion antimoussante au silicone qui contient des constituants actifs physiologiquement indifférents à base de polydiméthylsiloxane/silice.
PCT/EP2001/003799 2000-04-18 2001-04-04 Mousse aerosol pour traitement capillaire WO2001078661A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU63833/01A AU6383301A (en) 2000-04-18 2001-04-04 Aerosol foam for treating hair

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2000119128 DE10019128A1 (de) 2000-04-18 2000-04-18 Aerosolschaum zur Haarbehandlung
DE10019128.2 2000-04-18

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WO2001078661A2 true WO2001078661A2 (fr) 2001-10-25
WO2001078661A3 WO2001078661A3 (fr) 2002-03-14

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JP (1) JP2001302468A (fr)
AU (1) AU6383301A (fr)
DE (1) DE10019128A1 (fr)
WO (1) WO2001078661A2 (fr)

Cited By (9)

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FR2834514A1 (fr) * 2002-01-10 2003-07-11 Oreal Dispositif aerosol contenant une emulsion eau-dans-huile stabilisee par un agent emulsionnant silicone
EP1391192A1 (fr) * 2002-08-12 2004-02-25 Beiersdorf Aktiengesellschaft Compositions cosmétiques post-moussantes
DE102004041294A1 (de) * 2004-08-25 2006-03-09 Beiersdorf Ag Mittel zur fixierenden Behandlung keratinischer Fasern mit einer Kombination aus fixierenden Polymeren mit bestimmten Molmassen
WO2006131401A2 (fr) * 2005-06-10 2006-12-14 Galderma S.A. Methode de liberation controlee d'un medicament a travers la peau
WO2007001843A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit destine a pulveriser des compositions contenant des ingredients de revitalisation des cheveux
WO2007002045A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit permettant d'atomiser des compositions capillaires cosmetiques contenant un polymere
WO2007002048A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit pour la pulverisation de compositions cosmetiques pour les cheveux contenant des polymeres cationiques
US10603261B2 (en) 2014-12-19 2020-03-31 The Procter And Gamble Company Composition for enhancing hair fiber properties
US11129780B2 (en) 2016-01-29 2021-09-28 The Procter And Gamble Company Composition for enhancing hair fiber properties

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DE10321373A1 (de) * 2003-05-13 2004-12-02 Beiersdorf Ag Versprühbare, beim Auftreffen des Sprühnebels auf eine Frisuroberfläche einen instabilen und rasch zerfallenden Schaum bildende polymerhaltige Zubereitung zur Frisurgestaltung
CN101703067A (zh) 2003-12-12 2010-05-12 拜尔农作物科学股份公司 协同杀虫混合物

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2834514A1 (fr) * 2002-01-10 2003-07-11 Oreal Dispositif aerosol contenant une emulsion eau-dans-huile stabilisee par un agent emulsionnant silicone
EP1391192A1 (fr) * 2002-08-12 2004-02-25 Beiersdorf Aktiengesellschaft Compositions cosmétiques post-moussantes
DE102004041294A1 (de) * 2004-08-25 2006-03-09 Beiersdorf Ag Mittel zur fixierenden Behandlung keratinischer Fasern mit einer Kombination aus fixierenden Polymeren mit bestimmten Molmassen
WO2006131401A2 (fr) * 2005-06-10 2006-12-14 Galderma S.A. Methode de liberation controlee d'un medicament a travers la peau
WO2006131401A3 (fr) * 2005-06-10 2007-03-15 Galderma Sa Methode de liberation controlee d'un medicament a travers la peau
AU2006256860B2 (en) * 2005-06-10 2012-04-19 Galderma S.A. Controlled release of a drug through skin on the basis of a topical composition comprising a drug, a film-forming silicone and at least one volatile solvent
WO2007001843A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit destine a pulveriser des compositions contenant des ingredients de revitalisation des cheveux
WO2007002045A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit permettant d'atomiser des compositions capillaires cosmetiques contenant un polymere
WO2007002048A1 (fr) * 2005-06-20 2007-01-04 The Procter & Gamble Company Systeme de liberation de produit pour la pulverisation de compositions cosmetiques pour les cheveux contenant des polymeres cationiques
US10603261B2 (en) 2014-12-19 2020-03-31 The Procter And Gamble Company Composition for enhancing hair fiber properties
US11129780B2 (en) 2016-01-29 2021-09-28 The Procter And Gamble Company Composition for enhancing hair fiber properties
US11986542B2 (en) 2016-01-29 2024-05-21 The Procter & Gamble Company Composition for enhancing hair fiber properties

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DE10019128A1 (de) 2001-11-15

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