WO2001039895A1

WO2001039895A1 - Method and apparatus of coating a moving substrate surface

Info

Publication number: WO2001039895A1
Application number: PCT/AU2000/001490
Authority: WO
Inventors: Udo Wolfgang Buecher
Original assignee: Bhp Steel (Jla) Pty Limited; Akzo Nobel Pty Ltd
Priority date: 1999-12-03
Filing date: 2000-12-01
Publication date: 2001-06-07
Also published as: US20030021899A1; CA2393284C; KR20020074453A; EP1233835A1; BR0016114A; TW474840B; KR100751970B1; MXPA02005312A; MY127892A; BR0016114B1; CN1169628C; AR026698A1; JP2003515444A; NZ519096A; CN1402654A; US6759092B2; SA00210627B1; EP1233835A4; CA2393284A1

Abstract

A method of providing a paint coat of an organic polymeric paint composition (7) on a surface of a moving substrate (4), comprises establishing a quantity (6) of the paint composition, in a high solids form at a temperature such that it is spreadable, in a nip defined by the substrate surface and a smoothing roll (3) to enable paint from the established quantity to pass through the nip as a paint layer on the substrate surface, wherein the smoothing roll has a surface roughness coefficient (Ra) of no more than 1.5, and wherein the maximum surface speed of the smoothing roll expressed as a percentage of the substrate speed bears a linear relationship to the substrate speed, such that the surface speed of the smoothing roll is no more than 1.2 percent of the substrate speed at an exemplary low substrate speed of 15 metres per minute and no more than 12 percent of the substrate speed at an exemplary substrate speed of 150 metres per minute.

Description

METHOD AND APPARATUS OF COATING A MOVING SUBSTRATE SURFACE

Technical Field

This invention 1 elates to the continuous application of organic polymeric compositions to moving substrate surfaces to form a thin coating of the composition on the surface. If the coating remains on the substrate surface to which it is applied and is caused oi allowed to harden or set, the process may be geneπcally referred to as painting the substrate surface

Moie paiticulaily, but not exclusively, the invention is directed towaids the continuous painting of moving metal, for example steel, strip in the context of an industrial production line for producing painted stock material in lai ge quantities

Background Art

Probably the most commonly adopted mass production processes for painting moving strip comprise applying a thin layer of liquid paint composition, for example pigmented organic polymeric particles and filler particles dispersed or dissolved in a liquid solvent, to the strip, and causing or allowing the solvent to evaporate to leave an adherent, solid coating on the strip The formation of the liquid layei on the strip may be effected in various ways, for example by dipping the strip into a bath of the paint composition followed by stripping surplus composition from the strip, spraying the paint composition onto the strip or by contacting the strip with a roller laden with the paint composition. Such piocesses using solvent rich, low viscosity compositions aie not entnely satisfactory In particulai , the solvents aie dangerous if inhaled, expensive and envnonmentally damaging, thus it is essential that they be drawn off and condensed foi reuse This requnes expensive equipment and otherwise unnecessary piecautionary pioceduies that complicate the painting operation itself Such piocesses do have the advantage that the tendency of the low viscosity liquid layer to flow before solidifying and the effect of suiface tension tend to flatten the surface of the liquid layer lesulting in an attractive smooth suiface on the finished painted product

Neveitheless the disadvantages of solvent based compositions aie such that processes utilising substantially solvent free paint compositions, so called high solids compositions, have been developed wheiein the composition has been rendered sufficiently fluid foi it to be spread upon the substrate by controlled heating of the composition immediately prior to its application to the substrate. It has been found that, in general, application of such compositions to a substrate at a temperature of less than 20°C is inappropriate because the viscosity of the composition is too high. The extent to which the viscosity may be lowered by heating is limited because of the deleterious effect of high temperatures or prolonged heating on the characteristics of the paint composition. The upper temperature at which the compositions can be applied to the substrate is usually about 200°C, although this temperature is somewhat dependent upon the particular composition being used. At these elevated temperatures, it has been found that excessive cross-linking can occur prior to paint film formation. This means that in processes using high solids compositions one cannot rely on the self leveling effect of a low viscosity liquid layer to produce a smooth surface on the finished coating to the same extent as one can in processes using solvent rich compositions. That problem is exacerbated if one takes full advantage of the accuracy with which the thickness of a paint coat may be determined when using high solids compositions to create thin coats (of the order of from 10 to 20 micrometres in thickness) as disclosed in, for example, the complete specification of Australian Patent No. 622948 (John Lysaght (Australia) Pty. Ltd. et al). Thin coats set quicker than thick ones and this further detracts from the self-leveling slumping of peaks in the surface of the applied coat.

Hitherto that disadvantage of using high solids compositions has been addressed by contacting an initial deposit of paint composition on the moving substrate surface with a so called smoothing roll (as disclosed in the mentioned Australian patent specification), which is positioned to make a near approach to the substrate surface to form a nip therewith, through which nip the deposit moves. This has the effect of spreading and smoothing the initial deposit. It may also limit the thickness of the deposit carried away from the nip on the substrate surface. That prior art procedure is referred to as "a method of the kind described" hereinafter.

Disclosure of the Invention

An object of the present invention is to provide a thin paint coat on a substrate surface, by a continuous coating procedure utilising high solids, organic polymeric paint compositions, having a smoother surface than has been attainable by such procedures hitherto. For the purposes of the invention a high solids composition may be defined as one having a so-called volume solids of at least 80 percent, preferably more than 95 percent. The term "volume solids" is a reference to the volume of the solids in the composition expressed as a percentage of the volume of the total composition.

The invention attains that object by the selection of parameters controlling the operation of methods of the kind described

The invention consists in a method of pioviding a paint coat of an organic polymeric paint composition on a moving substrate surface, of the kind comprising establishing a quantity of the paint composition, in a high solids form at a temperatuie such that it is spreadable, in a nip defined by the substrate surface and a smoothing roll to enable paint from the established quantity to pass thiough the nip as a paint layer on the substrate surface, wheiein the smoothing l oil has a surface roughness coefficient (usually lefened to by the symbol R_d ) of no more than 1 5, and wheiein the maximum surface speed of the smoothing loll expressed as a percentage of the substrate speed beais a linear relationship to the substrate speed, such that the surface speed of the smoothing roll is no more than 1.2 percent of the substrate speed at an exemplary low substrate speed of 15 metres per minute and no more than 12 percent of the substrate speed at an exemplary substrate speed of 150 meties per minute.

In preferred embodiments of the invention the R is no moie than 0 8 The term sui face loughness coefficient or R_a is a term of art defined, with leference to a sectional piofile oi a sui face, as the ai ithmetic mean of the depaiture distances of the peaks and troughs of the piofile from the mean line of the profile, expressed in micrometies Thus the smallei is the value of R_a then the smoothei is the surface

Foi pieference the direction of movement of the suiface of the smoothing loll at the nip is the same as that of the substrate It will be noted that the invention includes within its ambit the instance of a stationaiy smoothing roll having zeio suiface speed and instances wherein the direction of movement of the smoothing i oil surface is opposite to that of the substrate

By way of example two embodiments of the above-described invention aie described in more detail hereinafter with refeience to the accompanying drawings Brief Description of the Drawings

Figure 1 is a diagrammatic longitudinal sectional elevation of an apparatus whereby the method of the invention may be performed.

Figure 2 is a view similar to figure 1 of a second apparatus whereby the method of the invention may be performed

Figure 3 is a graph representing the relationship between substrate speed and the maximum surface speed of the smoothing roll over a range of substrate speeds including the exemplary substrate speed values referred to in the definition of the method of the invention. It should be noted that figures 1 and 2 aie explanatoiy diagrams rathei than repiesentational views of actual apparatus. They are not to scale In particular the rolls aie diminished in size and thus display much smaller ladn of curvatuie than they would have in reality and the thicknesses of the paint layers are greatly enlarged

Modes of Carrying out the Invention The apparatus lllustiated by figure 1 is adapted for carrying out the method of the invention in instances where the surface to be painted is itself the substrate surface That apparatus comprises a smoothing roll 3 forming a nip with a moving substrate metal strip 4 to be painted The roll 3 and strip 4 are caused to move by conventional means in the directions of the arrows appearing thereon The smoothing roll is preferably furnished with at least a surface layer of elastomeric material For example, roll 3 may comprise a surface layer of a heat resistant sihcone rubber upon a steel core Although resilient, the elastomeric surface of the smoothing roll is relatively hard, foi example it may have a Shore A hardness of from 35 to 90 In accordance with the invention the smoothing I oil 3 is a very smooth loll, with an R_d of no more than 1.5, with a preferred value, having legard to the difficulty and expense of obtaining very smooth surfaces, of 0.8 A back-up loll (not shown) is provided on the opposite side of the strip from the smoothing roll 3 at the nip, to support the strip against the considerable force applied to it by the smoothing roll

A relatively rough surfaced layei 5 of a high solids organic polymenc paint composition is deposited on the strip 4 at a position upstream of the nip between it and the roll 3 The deposition of the layer 5 may be effected by any conventional means Preferably, the deposition rate is adjusted to suit the desired usage rate, having regaid to the strip speed and the desired thickness of the finished paint coat on the strip, so as to avoid excessive spillage or overflow at the smoothing station Nevertheless a small reserve quantity 6 of paint composition is pieferably established immediately upstream of the nip In alternative embodiments the reserve quantity may be established by direct deposit into the nip or by deposit onto the smoothing roll for transfer thereby into the reserve quantity.

In a further alternative embodiment, the paint composition is deposited directly in the nip oi is deposited directly into a pool of point composition established in the nip Having passed through the nip, the paint composition emerges as two streams, namely a smooth surfaced, still fluid, paint coat 7 carried away on the strip 4 and a thin film 8 carried away on the suiface of the roll 3 and returned by it to the lesei ve quantity 6 The paint coat 7 may have a thickness of from 10 to 60 miciometres, pieferably from 12 to 25 micrometres. In commercial metal strip continuous painting lines the strip speed may typically be within the range of from 15 to 120 metres per minute In accordance with the invention, the surface speed of the roll 3 is no more than 1.2 percent of the substrate surface speed oi 15 meties per minute, rising to no more than 9 6 percent of the substrate speed at 120 meties per minute This would place corresponding maximum roll suiface speeds within the range of from 0.18 to 1 1.52 metres per minute For preference however the actual suiface speed of the roll in any instance would be less than those maxima and may be zeio

Basically, one may say that a speed relationship meeting the requπements of the invention is satisfied for any point below the graph line of figure 3 Having said that, it should be pointed out that zero speed is not preferred for reasons relating to commercial practicality Occasionally a large adventitious particle may be present in the painl composition If the smoothing roll is stationary, such a particle may not pass thiough the nip for a lengthy period causing a corresponding flaw in a long length of finished pioduct Also rotation, including very slow rotation, spreads the weai of the smoothing i oil ovei its entne surface, leading to a longer opeiational life than would be the case with a stationaiy roll Therefoie prefeired embodiments of the invention utilise loll surface speeds of the ordei of from 0 025 to 0 2 metres per minute It is known in the circi mstances of the illustrated apparatus that the slower the smoothing roll surface speed is lelative to the substrate surface speed then the thinner is the film carried from the nip on the smoothing roll In preferred embodiments the speed differential between the two moving surfaces is such that the film 8 may have an average thickness of 1 micrometre or less. Paint films of that thickness are difficult to discern with the naked eye

Applicant does not assert that the following hypothesis is correct, nevertheless it is suggested that the film 8 is so thin that it constitutes a boundary layer that moves through the nip at substantially the constant speed of the smoothing roll surface Furthermoie the layer 7 of paint composition on the strip is earned away fiom the nip at the relatively high speed of the strip Thus it is suggested that the bulk of the paint composition travels thiough the nip at or very near the speed of the strip It follows that a very high shear strain is produced in a very thin layer of the composition identified by the broken line shown within the reserve quantity 6. It is hypothesised that the very small amount of composition in that thin layer of high shear strain coupled with the smoothness of the surface of the film defining one side of it (due to its thinness and the smoothness of the roll surface) produces a corresponding smoothness in the surface of the composition stream (appearing as paint coat 7) departing from the nip Be that as it may, the lesults of expenmental tests leading to the piesent invention show conclusively that a superior smoothness is exhibited by the finished paint coat on the substrate by methods within the stipulated parameteis of the invention, by comparison with similar methods of the prior art not complying with those pai ameters

In support of that statement, the results of a numbei of such tests aie listed in Table 1 below The data, operational conditions and results recorded in Table 1 do not necessanly represent optimum production parameters that would be used commercially Rather, the examples of Table 1 were designed to illustrate the scope and iange of the pai ameters identified in the invention. Furthermore, production line availability meant that the number of examples at high strip speed was limited. Table 1 also includes examples that fall within the present invention, being Sample

Nos 2, 3, 4, 9, 12, 13, 15, 18, 19, 21 , 23, 24 and 26 As can be seen, each of these examples produces a coating having a visually assessed smoothness of good or better. The remaining Sample Nos, which do not fall within the scope of the present invention, have a visually assessed smoothness of poor or very poor.

Table 1

Sample No Smoothing Smoothing Smoothing Strip Substrate Coating

Roll Roll Roll Speed- Speed Ctg Thcknss Smoothness

Ra Speed mpm % of Strip mpm μm Vis Rating

Speed

1 1.42 0.23 1.5% 15 20 5

2 1.40 0.17 1.1% 15 19 3

3 1.27 0.17 1.2% 15 19 3

4 0.71 0.15 1.0% 15 19 2

5 1.76 0.85 2.8% 30 18 5

6 1.76 0.66 2.2% 30 19 4

7 1.62 0.67 2.2% 30 19 4

8 1.33 0.87 2.9% 30 18 5

9 0.72 0.68 2.3% 30 19 3

10 1.78 1.23 3.1% 40 18 4

11 1.35 1.55 3.9% 40 18 5

12 1.28 1.24 3.1% 40 19 3

13 0.77 0.75 1.9% 40 23 2

14 0.62 1.63 4.1 % 40 18 4

15 0.61 0.19 0.5% 40 19 1

16 1.70 0.94 1.9% 50 19 4

17 1.37 2.48 4.9% 50 19 5

18 1.29 0.94 1.9% 50 20 3

19 0.78 0.94 1.9% 50 22 2

20 0.75 2.52 5.0% 50 18 4

21 0.65 1.88 3.8% 50 20 3

22 1.80 8.74 8.7% 100 20 4

23 1.19 5.10 5.1% 100 20 3

24 0.78 2.05 2.1% 100 21 1

25 0.60 14.79 12.3% 120 21 4

26 0.58 2.40 1.6% 150 28 1 isual Rating No ribbing visible at cms

1 Excellent 20

2 Very good 30

3 Good 50

4 Poor 80

5 Very poor 100

Samples rated 4 or 5 have smoothing roll Ra or speed parameters outside claim scope.

Figure 2 illustrates apparatus for effecting the method of the invention wherein the substrate surface on which the paint coat is formed is the surface of a rubber coated transfer roll 9 whereby the coat is transferred to a moving strip 4 on which it is caused or allowed to set to constitute the finished painted product. The remaining components in figuie 2 bear reference numerals corresponding to those on corresponding components of the figure 1 embodiment and are not further described herein. It is mentioned however that the smoothing roll 3 of this embodiment may be a steel roll or a very hard rubber surfaced roll

Claims

The claims defining the invention are as follows

1. A method of providing a paint coat of an organic polymeric paint composition on a surface of a moving substrate, of the kind comprising establishing a quantity of the paint composition, in a high solids form at a temperature such that it is spreadable, in a nip defined by the substrate surface and a smoothing roll to enable paint from the established quantity to pass through the nip as a paint layer on the substrate surface, wherein the smoothing roll has a surface roughness coefficient (R_a) of no more than 1.5, and wherein the maximum surface speed of the smoothing roll expressed as a percentage of the substrate speed bears a linear relationship to the substrate speed, such that the surface speed of the smoothing roll is no more than

1.2 percent of the substrate speed at an exemplary low substrate speed of 15 metres per minute and no more than 12 percent of the substrate speed at an exemplary substrate speed of 150 metres per minute.

2. A method according to claim 1 wherein the direction of movement of the surface of the smoothing roll at the nip is the same as that of the surface of the substrate.

3. A method according to claim 1 wherein the surface speed of the smoothing roll is zero.

4. A method according to claim 1 wherein the surface roughness coefficient (R_a) of the smoothing roll is no more than 0.8. 5. A method according to claim 1 wherein the step of establishing said quantity of paint composition in the nip is effected by depositing paint composition on the substrate at a position upstream of the nip between it and the smoothing roll at a deposition rate substantially equal to and not less than the rate at which paint composition is carried from the nip by the substrate. 6. A method according to claim 1 wherein the step of establishing said quantity of paint composition in the nip is effected by depositing paint composition on the smoothing roll at a position upstream of the nip between it and the substrate at a deposition rate substantially equal to and not less than the rate at which paint composition is carried from the nip by the substrate. 7 A method according to claim 1 wherein the step of establishing said quantity of paint in the nip is effected by depositing paint composition directly in the nip or directly into a pool of paint composition established in the nip 8. A method according to claim 1 wherein the speed differential between the substrate and the surface speed of the smoothing roll is selected to ensure that paint composition carried by the smoothing roll from the nip constitutes a film on the smoothing roll having an average thickness of no more than 1 miciometre.

9 A method according to claim 1 wherein the substrate surface is that of a strip to be painted

10 A method according to claim 1 wherein the substrate suiface is that of a ti ansfei loll, and which includes the fuither step of transferring the paint coat earned from the nip by the transfer loll to the surface of a strip to be painted

1 1 A method according to claim 10 wherein the transfer roll is a rubber surfaced roll 12 A method according to claim 1 wherein the temperatuie of the paint composition in the nip falls within the range of from 20°C to 200°C

13. Apparatus for performing the method of claim 1 comprising means foi supporting and translating a substrate strip, a smoothing roll mounted to form a nip with the stnp, means to deposit high solids paint composition in the nip and drive means to ti anslate the strip and rotate the smoothing roll at surface speeds conforming to the speeds required of the substrate and smoothing roll accoiding to the method, wherein the smoothing roll has a surface of elastomeric matenal with a suiface roughness coefficient ( R_d ) of no moie than 1 5 and a Shore A hardness of fiom 35 to 90.

14 Apparatus according to claim 13 wherein said surface toughness coefficient (R_a) is

15 Apparatus for performing the method of claim 1 comprising means foi suppoiting and tianslating a strip to be painted, a transfer roll having an elastomeric surface and mounted to make rolling contact with the strip, drive means to tianslate the strip and rotate the transfer roll at substantially equal surface speeds, a smoothing roll mounted to form a nip with the transfer roll, means to deposit high solids paint composition in the nip, drive means to rotate the smoothing roll at a surface speed relative to that of the transfer roll such that the surface speeds of the smoothing roll and the transfer roll conform to those required of a smoothing roll and substrate according to the method, wherein the smoothing roll has a surface roughness coefficient ( R_a ) of no more than 1.5.

Dated:28 November 2000

FREEEHILLS CARTER SMITH BEADLE

Patent Attorneys for the Applicant:

BHP INNOVATIONS PTY LTD and

AKZO NOBEL PTY LTD