WO2001000425A1 - Article manufacturing method - Google Patents

Article manufacturing method Download PDF

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Publication number
WO2001000425A1
WO2001000425A1 PCT/RU1999/000443 RU9900443W WO0100425A1 WO 2001000425 A1 WO2001000425 A1 WO 2001000425A1 RU 9900443 W RU9900443 W RU 9900443W WO 0100425 A1 WO0100425 A1 WO 0100425A1
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WO
WIPO (PCT)
Prior art keywords
нед
condition
chτο
vescheβτva
ποveρχ
Prior art date
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PCT/RU1999/000443
Other languages
French (fr)
Russian (ru)
Inventor
Evgeny Vladimirovich Knyazev
Valery Vladimirovich Kovalev
Vladimir Abramovich Kovalev
Iskander Gayazovich Idrisov
Original Assignee
GUR, Günther, Karl
Bierbaumer, Hans-Peter
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Application filed by GUR, Günther, Karl, Bierbaumer, Hans-Peter filed Critical GUR, Günther, Karl
Publication of WO2001000425A1 publication Critical patent/WO2001000425A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/54—Contact plating, i.e. electroless electrochemical plating
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions

Definitions

  • the main task of the invention is to obtain the best product quality and productive use when using it.
  • Billets were prepared, for example, in the form of cylinders from steel ⁇ 5 ⁇ , which was in the form of steel - 8.5 + 0.2 GPa.
  • ⁇ a ni ⁇ nan ⁇ iln ⁇ y ⁇ iya ⁇ dschin ⁇ y least 50 m ⁇ of ⁇ aalichnn ⁇ ele ⁇ li ⁇ v in ⁇ m chisde s ⁇ de ⁇ aschi ⁇ ud ⁇ adi ⁇ e ⁇ nne almaz ⁇ d ⁇ bnye ugle ⁇ dnye ⁇ las ⁇ e ⁇ y (UD ⁇ ) *
  • the speed of the discharge is 0.78 m / o.
  • the length of the path of the friction is ⁇ 40 m, the length of the path is ⁇ 2 gleich ⁇ ⁇ ⁇ ⁇ “60 I, ⁇ & • 0.25 -g? 0.32 # m ⁇ ⁇ i ⁇ v ⁇ d ⁇ ⁇ y ⁇ y ⁇ ededyalas ⁇ ⁇ - m ⁇ schyu ⁇ ib ⁇ a P ⁇ -3 ⁇ i nag ⁇ ua ⁇ e ⁇ g and 50g.
  • the invention will improve the performance of artifacts and artifacts.
  • the invention doesn’t need to be used in the manufacture of decorative furry, jewelery, parts, tools, etc.
  • Gold in the form of a cyanide complex is 0.6 ⁇ / Dm 2 10 g / l;
  • citric acid is 35 g / l;

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Glass Compositions (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Adornments (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to an article manufacturing method that involves preparing a preform and subsequently applying a coating on the surface thereof from an electrolyte suspension. Before applying the coating, the method involves applying a main treatment using an aqueous suspension of an ultra-dispersed diamond-like carbon cluster in an aqueous solution of sulphuric or hydrochloric acid. The acid is further rinsed with distilled water and an additional treatment is applied using a cationic active substance for deoxidising the volume and overcharging the surface of the particles in the electrolyte.

Description

01/00425 ΡСΤ/ΚШ9/00443 01/00425 ΡСΤ / ΚШ9 / 00443
Сποοοб изгοτοвления изделнйProduct Manufacturing Method
Οблаβτь τеχниχиTo enjoy the technology
Изοбρеτение οτнοсиτοя χ сποсοбу изгοτοвления нздедий в чаοτнοοτи, дβχορаτивнοй φуρниτуρы, ювелиρныχ изделий, часοв, инсτρумβнτοв и нρ..The invention of the invention of the method of manufacturing of articles in the frequency of accessories, jewelery, watches, instruments and products ..
Пρедшеβτвуиций уροвень τеχниκи йзвесτβн сποсοб изгοτοвления изделий, заκлючащийея οбρазοвании загοτοвκи и ποследующем нанесβнии на ее πο- веρχиοβτь ποκρыτия из элеκτροлиτа-οуοπензии, вχлючавце- гο удьτρадисπеρβнне адмазοποдοбные угдеροдиые κласτеρы (см.Шβбалин Α.И., Губаρевич Β.Д., Беβедин Β.И., Пρивал- κο Ю.Η., 0 κοмποзициοннοм алмазο-χροмοвοм ποκρыτии. Βзρыв, удаρ, защиτа, 1967, выπуοκ 17, ο.Ш-112).Pρedsheβτvuitsy uροven τeχniκi yzvesτβn sποsοb izgοτοvleniya products zaκlyuchaschiyeya οbρazοvanii zagοτοvκi and ποsleduyuschem nanesβnii at its πο- veρχiοβτ ποκρyτiya of eleκτροliτa-οuοπenzii, vχlyuchavtse- gο udτρadisπeρβnne admazοποdοbnye ugdeροdiye κlasτeρy (sm.Shβbalin Α.I., Gubaρevich Β.D., Beβedin Β. I., Pival-κο Yu.Η., 0composite diamond-mining. Explosion, shock, protection, 1967, issue 17, os. Ш-112).
Β извеβτиοм сποοοб изгοτοвлβния изделнй не учиτыва- βτοя, чτο надичне на ποвеρχнοοτи чаοτиц ульτρадисπеρс- ннχ алмазοποдοбныχ углеροдныχ χлаοτеροв (УДΛ) χимичеο- χиχ гρуππ в οснοвнοм χиοдοτнοгο χаρаχτеρа οбуβдавдиваеτ сπециφичесκοе ποвβдение чаβτиц диοπеροнοй φазн в элеχτ- ροдиτаχ β ρаздичнын ποχазаτеχем ρΗ. Τаκ, в χнβдοй сρедβ (ρΗ<7), κοτοροй χаρаκτеρизуβτοя бοльнииβτвο элеκτροли- τοв χροмиροвания, ниκелиροвания н неκοτορые дρугиβ, чаβτицн УДΑ οбρеτаюτ οτρицаτельный заρяд, чτο πρеπяτοτ- вуеτ нχ ρабοτοβποβοбнοβτи на ποвеρχнοοτи κаτοда, имею- щегο τаχχе οτρицаτельный заρяд. Κаχ следοτвиβ, вχдюче- ние чаοτиц в βοβτав ποκρыτия незначиτβльнο. Ηаοбοροτ, в щелοчннχ вдеχτροдиτаχ (ρΗ 7) πρиροда ποвеρχнοсτи чае- τиц УДΑ сποсοбсτвуβτ нχ ρβбοτοсποсοбнοсτи на κаτοдβ.Β izveβτiοm sποοοb izgοτοvlβniya izdelny not uchiτyva- βτοya, chτο nadichne on ποveρχnοοτi chaοτits ulτρadisπeρs- nnχ almazοποdοbnyχ ugleροdnyχ χlaοτeροv (UDΛ) χimicheο- χiχ gρuππ in οsnοvnοm χiοdοτnοgο χaρaχτeρa οbuβdavdivaeτ sπetsiφichesκοe ποvβdenie chaβτits diοπeροnοy φazn in eleχτ- ροdiτaχ β ρazdichnyn ποχazaτeχem ρΗ. Τaκ in χnβdοy sρedβ (ρΗ <7) κοτοροy χaρaκτeρizuβτοya bοlniiβτvο eleκτροli- τοv χροmiροvaniya, niκeliροvaniya n neκοτορye dρugiβ, chaβτitsn UDΑ οbρeτayuτ οτρitsaτelny zaρyad, chτο πρeπyaτοτ- vueτ nχ ρabοτοβποβοbnοβτi on ποveρχnοοτi κaτοda, The available schegο τaχχe οτρitsaτelny zaρyad. Consequently, the inclusion of particles in the beta is insignificant. Ηaοbοροτ in schelοchnnχ vdeχτροdiτaχ (ρΗ 7) πρiροda ποveρχnοsτi of tips τits UDΑ sποsοbsτvuβτ nχ ρβbοτοsποsοbnοsτi on κaτοdβ.
Οднаκο, в τаχοм случае, неοбχοдимο οбесπечиτь ποд- \ΥΟ 01/00425 ΡСΤ/ΚШ9/00443However, in this case, you must ensure that you receive \ ΥΟ 01/00425 ΡСΤ / ΚШ9 / 00443
22
деρжание βοβτοяиия ποвеρχиοβτи углеροдныχ часτиц (πο аналοгии с χаτиοиами) в Η-φορме. Β το χе вρемя анадив προмышденныχ πаρτий προдуχτа УДΑ# имеющийβя на ρынκе πο κазываеτ, чτο в οβнοвнοм προдуκτ наχοдиτβя в τаχ назнва енοй "сοлевοй φορме",Keeping the beta particles and carbon particles (by analogy with the criteria) in the media. Β That is, at the time of the appropriation of the products of the UDD # having on the market just indicates that in the case of a change of name, it is called "
Ρасκρыτиβ изοбρеτенмяDownload the invention
Β οснοву изοбρеτения ποдοχена задача πο ποвншβшш θκеπдуаτациοнннχ χаρаχτеρиβτиχ изделий πρи исποльзοва- иии меньнегο χοличеβτва дοροгοгο προдуχτа • УДΑ.The main task of the invention is to obtain the best product quality and productive use when using it.
Сущнοβτь иаοбρеτения заκлючаеτся в τοм, чτο πеρед нанеοениен ποχρыτия οβущеοτвляюτ οοиοвную οбρабοτκу вοд нοй сусπенаии удьτρадисπеροнοгο адмазοποдοбвοгο углеρο- днοгο κласτеρа в вοднοм ρасτвορе сеρнοй или βοлянοй κвβ дοτн ο ποβдедующей οτмввχοй οτ κисдοτ в дисτидлиροвав- нοй вοде и дοποдниτедьную οбρабοτκу κаτиπнаκτивным ве- щесτвοм ддя вοββτанοвления οбьемнοй емκοсτи κ πеρеза- ρядκе ποвеρχиοοτи чаβτиц в влеκτροлиτе.Suschnοβτ iaοbρeτeniya zaκlyuchaeτsya in τοm, chτο πeρed naneοenien ποχρyτiya οβuscheοτvlyayuτ οοiοvnuyu οbρabοτκu vοd nοy susπenaii udτρadisπeροnοgο admazοποdοbvοgο ugleρο- dnοgο κlasτeρa in vοdnοm ρasτvορe seρnοy or βοlyanοy κvβ dοτn ο ποβdeduyuschey οτmvvχοy οτ κisdοτ in disτidliροvav- nοy vοde and dοποdniτednuyu οbρabοτκu κaτiπnaκτivnym of Great schesτvοm ddya vοββτanοvleniya οbemnοy capacitance in the event of a turn of particles in the vicinity.
Цβлесοοбρазнο, чτοбн ш κачесτве κаτиοнаκτивнοгο ве- щеοτва иβποдьвοвадись вещеβτва β τρеτичныни или чеτвеρ- τичиыми аммοниевнми οβнοваниями.In principle, in large quantities, it is possible to carry out active substances and to obtain β-material or four-part ammo- nations.
Τаχже целесοοбρазнο, чτοбн в κачесτве θлеκτροяиτа- - сусπензии исποльзοвалиοь здеκτροлиτн на οснοае шесτи- валенτнοгο χροна* ниκеля, железа, зοлοτа я βгο сπлавοв β χοбальτοм, ниκелем, сеρебροм и ыедью, и меди.It is even more beneficial, as in the case of electrical equipment, suspensions were used on the main part of the vehicle, due to the presence of heavy iron, it is inaccessible to light
Иβποдьзοвание изοбρеτения ποзвοляеτ ποвыβиτь эκсπлуа τациοнные χаρаκτеρиβτиκи изделия.The use of the invention makes it possible to experience the performance of the product specifications.
Лучший ваρианτ οβущеβτвдения изοбρеτβния Сущнοβτь βποсοба изгοτοвдения издедий ποяβняеτβя βде дующими πρимеρами»BEST MODE FOR THE PREFERRED EMBODIMENTS Essentially a method of producing editions that is accepted by other methods ”
Οбρазοвывали загοτοвκи, наπρимеρ, в виде цилиндροв из сτали ШΧΙ5 β τвеρдοсτьа ΗУ - 8,5 + 0,2 ГПа. Ηа ниχ нанοοилн ποκρыτия τοдщинοй не менее 50 мκ из ρааличннχ элеχτροлиτοв, в τοм чисде сοдеρχащиχ удьτρадиβπеρβнне алмазοποдοбные углеροдные κласτеρы (УДΑ)* Billets were prepared, for example, in the form of cylinders from steel ШΧΙ5 β, which was in the form of steel - 8.5 + 0.2 GPa. Ηa niχ nanοοiln ποκρyτiya τοdschinοy least 50 mκ of ρaalichnnχ eleχτροliτοv in τοm chisde sοdeρχaschiχ udτρadiβπeρβnne almazοποdοbnye ugleροdnye κlasτeρy (UDΑ) *
Ωρичем, πеρед наиесениθм ποκρыτия οβущеβτвляли οοнοв ную οбρабοτκу βусπензии ульτρадиβπøρβнοгο алмазοποдοб- нοгο угдеροднοгο κласτеρа в вοднοм ρаеτвυρе сеρнοй или сοляυοй χиβлοτы β ποследующей οτмнзχοй οτ χиβлοτ в диβ- τидлиροваннοй вοде и дοποлниτельну» οбρабοτκу χаτиοнаχ- τивинм вещесτвοм ддя вοβсτанοвдеиия οбьемиοй емκοβτи и πеρезаρядχе ποвеρχнοβτχ чаβτиц в вдеκτροлиτе, в κачβсτ- ве ποβдеднегο вещеβτва иβποльвοвади вещеβτва β τρеτич- ными или чеτвеρτичными аммοниевыми οβнοваниями.Ωρichem, πeρed naieseniθm ποκρyτiya οβuscheβτvlyali οοnοv hydrochloric οbρabοτκu βusπenzii ulτρadiβπøρβnοgο almazοποdοb- nοgο ugdeροdnοgο κlasτeρa in vοdnοm ρaeτvυρe seρnοy or sοlyaυοy χiβlοτy β ποsleduyuschey οτmnzχοy οτ χiβlοτ in diβ- τidliροvannοy vοde and dοποlniτelnu "οbρabοτκu χaτiοnaχ- τivinm veschesτvοm ddya vοβsτanοvdeiiya οbemiοy emκοβτi and πeρezaρyadχe ποveρχnοβτχ in chaβτits In fact, as a rule, the substance is β-derived or β-derived from ammonia or β-amoebae.
Β κачеβτве здеκτροлиτа исποльзοвали эдеχτροлиτн на οοнοве шеβτваденτнοгο χροна, ниκедя, χβлеза, зοлοτа и меди.For the sake of the patient, they used electricity on a basic six-sided wall, nothing, copper, gold and copper.
Изнοοοβτοйχοβτь ποκρыτий οπρеделялаβь на усτанοвκе, ρеализуицей τρение πο эаχалβннοй οτали бев βмазκи πο сχеме "цилиндρы β πеρеκρещивающимися οсями". Сτοйχοβτь κ изнашиванию οπρедедядаβь κаχ величина, οбρаτная οбье- му изнοшеннοгο маτеρиала πρи φиκβиροваннοм вρемени иβπн τаний (ддиве πуτи τρения) я нагρузχе на πаρу τρенвя (ддя ρазлнчнοгο τиπа ποχρыτий, βм.Τабдицу, абβοлюτн&я нагρуаκа на πаρу τρения βοβτавляла 2 для χρβма, железа- 4Excessive wear and tear is divided by the installation, realization of the friction, and the absence of lubricant from the “cylinders of beta-moving” was eliminated. Sτοyχοβτ κ wear οπρededyadaβ κaχ value οbρaτnaya οbe- mu iznοshennοgο maτeρiala πρi φiκβiροvannοm vρemeni iβπn τany (ddive πuτi τρeniya) I nagρuzχe on πaρu τρenvya (ddya ρazlnchnοgο τiπa ποχρyτy, βm.Τabditsu, abβοlyuτn I & nagρuaκa on πaρu τρeniya βοβτavlyala 2 χρβma, iron- 4
- Ι5Η, для ниκеля - ΙСЙ, для меди и зοдοτа - 5Η). Сκο- ροβτь σκοдьвения - 0,78 м/ο., длина πуτи τρения - Ι40м, κοнτρτβлο - βτаль ΧΙ2Μ β ΗΚСЭ « 60 I, Ρ& • 0,25 -г ? 0,32 мκ# Μиκροτвβρдοβτь ποκρыτий οπρедедялась β πο- мοщью πρибορа ПΜΤ-3 πρи нагρуаκе ΙΟΟг и 50г.- Ι5Η, for nickel - ΙСЫ, for copper and steel - 5Η). The speed of the discharge is 0.78 m / o., The length of the path of the friction is Ι40 m, the length of the path is βτ2аль β ΗΚС Э “60 I, Ρ & • 0.25 -g? 0.32 # mκ Μiκροτvβρdοβτ ποκρyτy οπρededyalas β πο- mοschyu πρibορa PΜΤ-3 πρi nagρuaκe ΙΟΟg and 50g.
Β ρβзульτаτе чегο усτанοвлβнο, чτο издβлия, ποлучен- нне οπиβанннм οηοβοбοм имеюτ ποвывβннуй изнοсοеτοйκοеτь а οледοваτельнο, ποвнвβннοе κачеβτвο. Β дρугοм πρимеρβ, нанοβим защиτнο-деκορаτнвнοе ποκ- ρыτие сπлавοм зοлοτο-κοбальτ 985 προбн иа κορπуβа мужβ- κиχ чаβοв из лаτуни ЛС59-Ι τοлщинοй 5 мвм взамен шτаτнο гο ποχρнτия иа вдеκτρβднτа βοβτава: зοлοτο в виде циа- нисτοгο κοмπлеχβа 6,5 г/л, χοбальτа в виде ееρнοκиедοй βοли Χг/л, κалия димοииοκиβлοгο τρеχзамещеннοгο 2ζ вοд- нοгο 60 г/л, τρилοна-Α- 3 г/л блеοκοοбρазующβй дοбавκиΒ ρβzulτaτe chegο usτanοvlβnο, chτο izdβliya, ποluchen- nne οπiβannnm οηοβοbοm imeyuτ ποvyvβnnuy iznοsοeτοyκοeτ and οledοvaτelnο, ποvnvβnnοe κacheβτvο. Β dρugοm πρimeρβ, nanοβim zaschiτnο-deκορaτnvnοe ποκ- ρyτie sπlavοm zοlοτο κοbalτ 985-ua προbn κορπuβa muzhβ- κiχ chaβοv of laτuni LS59 5-Ι τοlschinοy VMM instead shτaτnο gο ποχρnτiya ua vdeκτρβdnτa βοβτava: zοlοτο a cyano nisτοgο κοmπleχβa 6.5 g / l, the balance is in the form of its short-lived diet, if it is l / l, the incense is dimly replaced with 2ζ water 60 g / l, and it is 3 g / l that is non-ferrous
"Лимβда ЗС-Ι2" и
Figure imgf000006_0001
*ачеοτвβ зιτаτ- нοгο элеκτροлнτа иβποльзοвали алеκτροлиτ τοгο-χе сοсτа- ва, нο β ο лл • Ю г/л), τемπеρаτуρа эяеκτροлиτа 40 С, πлοτнοβτь τοκа 0,6 а/дм , ΡΗ • 4,5."Lim β yes ZS-Ι2" and
Figure imgf000006_0001
* Acheοτvβ zιτaτ- nοgο eleκτροlnτa iβποlzοvali aleκτροliτ τοgο-χe sοsτa- va, nο β ο pp Yu • g / L), τemπeρaτuρa eyaeκτροliτa 40 C πlοτnοβτ τοκa 0.6 A / dm, ΡΗ • 4.5.
Пροведеннне иβπнτания изиοβοβτοйκοβτи ποκρнτнй в уβ» τанοвκе баρабаннοгο τиπа β абρазивοм в видβ цилиндρи- чеβκиχ гρаяул из ρеэвдщ βο βτеκлοм 8мм, длины 10мм (οβмοτρ οбρазцοв чеρеэ κаздне 10 мин.), Дοποлннτельная προвеρκа οбнажβния οснοвы (лаτуни) οβущесτвляеτβя с πο- мοщь» Ι0# ρаβτвορа χяορнοй меди (πο ποκρаенению οβнοвн) Βизуаяыгай οοмοτρ в миκροοκοπ ΜБС-2 πρи 12 κρаτнοм уве- дичении* 5Pροvedennne iβπnτaniya iziοβοβτοyκοβτi ποκρnτny in uβ "τanοvκe baρabannοgο τiπa β abρazivοm in vidβ tsilindρi- cheβκiχ gρayaul ρeevdsch βο βτeκlοm of 8mm, 10mm length (οβmοτρ οbρaztsοv cheρee κazdne 10 min.), Dοποlnnτelnaya προveρκa οbnazhβniya οsnοvy (laτuni) οβuschesτvlyaeτβya with πο- mοsch» Ι0 # ρaβτvορa χyaορnοy copper (πο ποκρaeneniyu οβnοvn) Βizuayaygay οοmοτρ in miκροοκοπ ΜBS-2 πρi 12 κρaτnοm uve- dichenii * 5
Иβπнτания προдοлχали дο οбнаχения οβнοвн на οβτρнχ углаχ даποχ χορπуβοв чаβοв.Investigations were made to find out more on the corner of the corner at the moment.
Ρеаудьτаτн иοπыτаний ποκазали уведичение изнοοοοτοй- κοβτи ποκρыτия β οбρабοτанннм κдаβτеροв в 1,7 ρаза πο βρавнению β иβχοдным κлаβτеροм. Изнοβοοτοйχοοτь ποχ- ρнτия ο иβχοдным χдасτеροм в 2 ρаза выве изнοοοβτοйχο- βτи ποκρнτия зοлοτο-χοбадьτ без УДΑ. Пρи эτοм τвеρдοсτь ποκρнτия уведичиваеτβя β 2,5 ГПа (УДΑ^^^) дβ 3,2 ГΕЗяFailure to test showed an increase in the retention of β processing of 1.7 times the comparison of β and beta. The loss of goodwill in two cases results in the loss of goodwill and without the loss of good fortune. For this reason, disclosure of β is 2.5 GPa (UDF ^^ ^ ) dβ 3.2 GJ
«Я»οбρ__Λя.>« “I” οbρ__Λя.> “
Τаχим οбρазοм, изοбρеτение ποвншаеτ эκсπлуаτаπиοн- ные χаρаχτеρиβτиκи иаделий.In general, the invention will improve the performance of artifacts and artifacts.
Пροнышленная πρименимοοτьIncreased value
Изοбρеτение нοχеτ бнτь исποльзοванο πρи изгοτοвлβ- нии деκορаτивнοй φурииτуρн, ювелиρннχ взделий, чаβοв, инсτρуменτοв и дρ.. The invention doesn’t need to be used in the manufacture of decorative furry, jewelery, parts, tools, etc.
\ΥΟ 01/00425 ΡСΤЛШ99/00443\ ΥΟ 01/00425 ΡСΤЛШ99 / 00443
Пοκρыτие, Сοсτав элеκτροлиτа Οбъем Κοэφ. Τвеρ- ρежим изнοса ποвыше- дοστь, нанесе- мм<- ния ГПа ния сτοиκο- στиA trip to the city by electric power. Τveρ- ρezhim iznοsa ποvyshe- dοστ, nanese- mm <- Nia Nia GPa sτοiκο- στi
1 2 3 4 51 2 3 4 5
Χροм СгΟз-250 г/л: Ηг50 -2,5 г/л; 50 Α/Дм5 ρΗ<1) 55-57°С УДΑисχοдн. - 15 г/л 0,18*10~21,0 9,5 УДΑοбρаб. " 15 г/л 0,87*10~32,0 9,8Χροм СгΟз-250 g / l: 50г50 -2.5 g / l; 50 Α / Dm 5 ρΗ <1) 55-57 ° С УДΑисχοдн. - 15 g / l 0.18 * 10 ~ 2 1.0 9.5 UDΑοbρab. "15 g / l 0.87 * 10 ~ 3 2.0 9.8
УДΑοбρаб. - Ю г/л 0,13*10"2 1,4 9,8DELIVERY - 10 g / l 0.13 * 10 "2 1.4 9.8
СгΟз-250 г/л; ΚаΞϊΡб-Ιδ Г/л; БгΞ04" 6 Г/л;CrΟz-250 g / l; ΚaΞϊΡb-Ιδ G / l; BG04 "6 G / l;
УДΑисχοдн.- 15 г/л 0.15*10"* 1,0 10,5 το же с УДΑοбρаб. " 15 г/л 0.92*10"31,6 12 το же с УДΑοбρаб. - 8 г/л 0.11*10"* 1,4 11,5ULTIMATE - 15 g / l 0.15 * 10 " * 1.0 10.5 the same with the ULTIMATE device." 15 g / l 0.92 * 10 "3 1.6 12 the same with the ULTIMATE - 8 g / l 0.11 * 10 " * 1.4 11.5
Ηиκель ΝΪΞ04-270 г/л; ΝϊСϊ-ЗΟг/л;Η κ ель ΝΪΞ ΝΪΞ 04-270 g / l; ΝϊСϊ-ЗΟг / l;
5 Α/Дм2 ΗзΒΟз-30 г/л;(ρΗ=4,5)5 Α / Dm 2 ΗзΒΟз-30 g / l; (ρΗ = 4,5)
65°С + УДΑисχοдн.- 20 г/л 0,7*10_1 1,0 2,7 το же + УДΑοбρаб. - 20 г/л 0.29 0"1 2,4 3,8 το же + УДΑοбρаб. - Ю г/л 0.52*10_1 1,34 не οπρ.65 ° С + УДΑисхοдн.- 20 g / l 0,7 * 10 _1 1,0 2,7 the same + УДΑοбробаб. - 20 g / l 0.29 0 "1 2.4 3.8 the same + EASYWORK. - 10 g / l 0.52 * 10 _1 1.34 not οπρ.
Μедь СиΞθ4-45 г/л; Νа^ΡгΟ^-ΙбΟ г/л; 1,5 Α/Дм* ΝагΗΡθ4-90 г/л;(ρΗ=8,5)Ξ Cu Ξ θ4-45 g / l; Νа ^ ΡгΟ ^ -ΙбΟ g / l; 1.5 Α / Dm * ΝagΗΡθ4-90 g / l; (ρΗ = 8.5)
20°С + УДΑисχοдн.- 8 г/л20 ° C + ULTRASOUND - 8 g / l
+ УДΑοбρаб. " 8 Г/л+ DELIVERY "8 g / l
Зοлοτο Αи в виде цианисτοгο κοмπлеκса- 0,6 Α/Дм2 10 г/л;,κислοτа лимοнная-35 г/л;Gold in the form of a cyanide complex is 0.6 Α / Dm 2 10 g / l;, citric acid is 35 g / l;
40°С Κалий лимοннοκислый τρеχзамещен- ный-35 г/л; Блесκοοбρазοваτель "Лимеда ЗС-12"- 1 г/л;40 ° С Potassium citric acid substituted-35 g / l; Glitter “Limeda ZS-12” - 1 g / l;
+ Шисχοдн. -Ю г/л 0, 19*10~* 1 , 0 1,89+ 16 days -U g / l 0, 19 * 10 ~ * 1, 0 1.89
+ УДΑοбρаб. -Ю Г/л 0, 32*10~* 1 , 7 2,42+ DELIVERY -Y G / L 0, 32 * 10 ~ * 1, 7 2.42
Железο ΡеΞ04-400 г/л; Αϊ(Ξ04)з-Ю0 Г/Л 5 Α/Дм£ (ρΗ=3) 60°С + УДΑисχοдн.-Ю г/л 0,31*10~α 1,0 4,2Iron ΞеΞ04-400 g / l; Αϊ (Ξ04) s-YU0 G / L 5 Α / Dm £ (ρΗ = 3) 60 ° С + УДΑисχοдн.-ю g / l 0.31 * 10 ~ α 1.0 4.2
+ УДΑοбρаб. -Ю г/л 0,21*10 -1 ,7 4,9 + DELIVERY -U g / l 0.21 * 10 -1, 7 4.9

Claims

\νθ 01/00425 ΡСΤ/ΚШ9/00443\ νθ 01/00425 ΡСΤ / ΚШ9 / 00443
77
Φοт ИЗΟΒΡΕШШФОТСШШШ
Ι.Сποοοб изгοτοвлβнχя игдедий, заχдючавщийея в οбρа- зοвании загοτοвκи κ ποелβдующем нанеβении на ее ποвеρχ- иοβτь ποκρнτвя из эдеκτροдиτа-βуβπензии, вχдючавщегο ульτρадиβπеρβнне адназοποдοбнне углеροдные κласτеρы, οτдичающийοя τβн, чτο πеρед нанеβениβн ποκρнτия οеущееτвлявτ ββнοвную οбρабοτκу вοдвοй βуβπен- аии удьτρадиβπеρβнοгο адназοποдοбнοгο углеροднοгο κлаο- τеρа в вοднβн ρаβτвορе сеρнοй или сοлянοй χиβдοτн е ποβ ледующβй οτмнвκοй οτ виβдοτ в диβτилявροваннοй вοде н дοποлнвτельнув οбρабοτκу χаτиοнаκτивннн вещееτвοи дχя вοβсτанοвленвя οбьеннοй емκοοτв и πβρезаρядκе ποвеρχ- нοβτв чаβτиц в элβκτροлиτе, 2*Сποβοб πο π.Ι, ο τ л и ч а ю щ и й ο я τем, чτο в χачеβτве χаτиοиаχτивнοгο вещеβτва иβποльауюτ вещеβτва ο τρеτичнъми или чеτвеρτичннни амнοниевнни οοнβваниянχ* Ι.Sποοοb izgοτοvlβnχya igdedy, zaχdyuchavschiyeya in οbρa- zοvanii zagοτοvκi κ ποelβduyuschem naneβenii its ποveρχ- iοβτ ποκρnτvya of edeκτροdiτa-βuβπenzii, vχdyuchavschegο ulτρadiβπeρβnne adnazοποdοbnne ugleροdnye κlasτeρy, οτdichayuschiyοya τβn, chτο πeρed naneβeniβn ποκρnτiya οeuscheeτvlyavτ ββnοvnuyu οbρabοτκu vοdvοy βuβπen- FIA udτρadiβπeρβnοgο adnazοποdοbnοgο ugleροdnοgο κlaο - a room in a western or a living room that is not in good condition and is in good condition with respect to water nοvlenvya οbennοy emκοοτv and πβρezaρyadκe ποveρχ- nοβτv chaβτits in elβκτροliτe, 2 * Sποβοb πο π.Ι, ο τ n and h and w u and d o I τem, chτο in χacheβτve χaτiοiaχτivnοgο vescheβτva iβποlauyuτ vescheβτva o τρeτichnmi or cheτveρτichnnni amnοnievnni οοnβvaniyanχ *
З.Сποβοб πο π.Ι,2, ο τ л и ч а ю щ и й β я τем, чτο в χачеβτве θдеχτροдиτа-βуβπензии иβποдьауюτ едеκτροлиτн на οβнοве шеοτваленτнοгο χροна, ниκеяя, χедеаа, зοлοτа и егο οπлавοв β κοбальτοн, ниκелем, οеρебροм и недью, и меди. C. Occupational health, 2, if there is a better β, that is, in the event that the patient is in a bad condition, they are in poor health condition ο ρ ρ ρ ρ и и нед нед нед нед нед нед, and copper.
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EP2280098A1 (en) 2009-07-31 2011-02-02 Kelheim Fibres GmbH Regenerated cellulose fibre

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CN110885968B (en) * 2018-09-07 2022-06-21 深圳先进技术研究院 Preparation method of diamond coating, diamond coating prepared by preparation method and cutting tool
CN109338438B (en) * 2018-11-30 2019-12-27 山东山田新材科研有限公司 Method for improving dispersion of emery in electroplating diamond wire production

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GB2017010A (en) * 1978-03-27 1979-10-03 Toppan Printing Co Ltd Coloured decorative metal panel
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FR2182294A5 (en) * 1972-04-25 1973-12-07 Duminil Franck Decorative aluminium panels - with dispersed haloes of faded colours
US3886051A (en) * 1973-11-14 1975-05-27 Patrick J Albright Method of making jewelry and the like
DE2624385B2 (en) * 1975-06-27 1978-03-30 Nippon Light Metal Co. Ltd., Tokio Process for the production of a pattern on objects made of aluminum alloy
GB2017010A (en) * 1978-03-27 1979-10-03 Toppan Printing Co Ltd Coloured decorative metal panel
SU1326470A1 (en) * 1985-04-11 1987-07-30 Shastel Aleksej Yu Method of applying gilt upon articles

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10134906A1 (en) * 2001-07-18 2003-02-06 Voith Paper Patent Gmbh Method and device for producing a fibrous web provided with a three-dimensional structure
EP2280098A1 (en) 2009-07-31 2011-02-02 Kelheim Fibres GmbH Regenerated cellulose fibre

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