WO2000049067A1 - Composition comprenant une emulsion huile dans l'eau et un agent inorganique - Google Patents
Composition comprenant une emulsion huile dans l'eau et un agent inorganique Download PDFInfo
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- WO2000049067A1 WO2000049067A1 PCT/FR2000/000343 FR0000343W WO0049067A1 WO 2000049067 A1 WO2000049067 A1 WO 2000049067A1 FR 0000343 W FR0000343 W FR 0000343W WO 0049067 A1 WO0049067 A1 WO 0049067A1
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- Prior art keywords
- weight
- emulsion
- composition
- composition according
- inorganic
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- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 19
- 239000007764 o/w emulsion Substances 0.000 title description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 32
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 26
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012736 aqueous medium Substances 0.000 claims abstract description 5
- 230000000295 complement effect Effects 0.000 claims abstract description 3
- 239000003213 antiperspirant Substances 0.000 claims description 15
- 239000002537 cosmetic Substances 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 239000001023 inorganic pigment Substances 0.000 claims description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 16
- 229940008099 dimethicone Drugs 0.000 description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 14
- 239000012071 phase Substances 0.000 description 10
- 239000003755 preservative agent Substances 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 230000002335 preservative effect Effects 0.000 description 8
- 230000001166 anti-perspirative effect Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- 229940048506 aluminum zirconium tetrachlorohydrex gly Drugs 0.000 description 6
- ZYYRAHJUNAIHTP-UHFFFAOYSA-A dialuminum;zirconium(4+);heptachloride;heptahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Zr+4].[Zr+4] ZYYRAHJUNAIHTP-UHFFFAOYSA-A 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MGQIWUQTCOJGJU-UHFFFAOYSA-N [AlH3].Cl Chemical compound [AlH3].Cl MGQIWUQTCOJGJU-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000008240 homogeneous mixture Substances 0.000 description 3
- 235000013980 iron oxide Nutrition 0.000 description 3
- 239000012074 organic phase Substances 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 244000186140 Asperula odorata Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 235000008526 Galium odoratum Nutrition 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 101000981993 Oncorhynchus mykiss Myelin proteolipid protein Proteins 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical group 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- NNCAWEWCFVZOGF-UHFFFAOYSA-N mepiquat Chemical compound C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- AZOOXWWPWARTFV-UHFFFAOYSA-N zirconium hydrochloride Chemical compound Cl.[Zr] AZOOXWWPWARTFV-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- JNAYPSWVMNJOPQ-UHFFFAOYSA-N 2,3-bis(16-methylheptadecanoyloxy)propyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C JNAYPSWVMNJOPQ-UHFFFAOYSA-N 0.000 description 1
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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- 235000017060 Arachis glabrata Nutrition 0.000 description 1
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- 244000125300 Argania sideroxylon Species 0.000 description 1
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- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
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- 244000020551 Helianthus annuus Species 0.000 description 1
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
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- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
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- UJNOLBSYLSYIBM-WISYIIOYSA-N [(1r,2s,5r)-5-methyl-2-propan-2-ylcyclohexyl] (2r)-2-hydroxypropanoate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)[C@@H](C)O UJNOLBSYLSYIBM-WISYIIOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000005157 alkyl carboxy group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
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- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
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- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 1
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- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
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- 239000008271 cosmetic emulsion Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
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- 239000002781 deodorant agent Substances 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
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- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
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- 229930182470 glycoside Natural products 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 239000001257 hydrogen Substances 0.000 description 1
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940077397 octyldodecyl lactate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229940057874 phenyl trimethicone Drugs 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/068—Microemulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
Definitions
- the present invention relates to compositions comprising an oil-in-water emulsion and an inorganic agent, said compositions having improved stability and being usable in cosmetics.
- compositions for example, to combat sweating problems, antiperspirants are used which usually contain an astringent aluminum salt.
- mineral sunscreens are also introduced into the cosmetic compositions, which often have properties superior to those of organic filters.
- the cosmetic compositions can also comprise mineral pigments, in particular makeup compositions.
- the compositions comprising these inorganic agents are compositions based on a water in oil emulsion, the organic phase of this emulsion being a silicone compound. These emulsions, in the presence of the inorganic agent, are very unstable.
- a silicone emulsifier of a particular type generally a polysiloxane, more particularly, dimethylpolysiloxane, comprising polyoxyalkylenated (polyoxyethylenated and / or polyoxypropylenated) -dimethicone chains copolyok
- Oil-in-water emulsion compositions are generally more stable. However, these emulsions are produced from emulsifiers of the nonionic surfactant type, and the latter are not compatible with the inorganic agents introduced into the composition. This mixture leads to unstable cosmetic compositions having a tacky effect ("high tack") and which is difficult to spread.
- An object of the present invention is therefore to produce stable compositions comprising:
- compositions having a low tack Another object is to produce such compositions having a low tack.
- the invention relates to a composition comprising:
- compositions according to the invention derives from the nature of the organic phase of the oil in water emulsion.
- This organic phase is a linear polydimethylsiloxane with a viscosity between 1 and 5000 mPa.s at 25 ° C.
- the viscosity of the polydimethylsiloxane is measured using a capillary viscometer according to the method described in the Dow Corning Corporate Test Method CTM004 July 20, 1970.
- polydimethylsiloxanes having a viscosity of between 5 and 50 mPa.s at 25 ° C.
- linear polydimethylsiloxane is known under the name of Dimethicone according to the CTFA nomenclature.
- the particles of the emulsion having a size of at most 1 ⁇ m.
- the particle size of the emulsion is measured by particle size analysis by laser diffraction using a LA-910 Horiba particle size analyzer.
- the particles of the emulsion have a size of between 0.2 and 0.8 ⁇ m.
- the polydimethylsiloxane content represents more particularly from 20 to 80% by weight of the emulsion.
- said emulsion can comprise at least one surfactant.
- the surfactants which may be used will be described in detail below.
- this is more particularly between 0 and 10% by weight of the emulsion.
- the aqueous phase of the emulsion consists of water, optionally combined with at least one monoalcohol or at least one polyalcohol, or their mixtures.
- at least one monoalcohol or at least one polyalcohol or their mixtures.
- the emulsion preferably represents 20 to 50% by weight of the composition, even more preferably 20 to 30% by weight.
- the inorganic agent of the composition according to the invention can be chosen from at least one of the following agents: inorganic pigments, mineral filters absorbing UVA and / or UVB rays, antiperspirant agents.
- inorganic pigment there may be mentioned: - titanium dioxide (rutile or anatase) optionally surface-treated, and codified in the Color Index under the reference CI77891,
- inorganic pigments white pearlescent pigments such as micas coated with titanium oxide or bismuth oxide, or else pearly colored pigments such as colored mica-titanium with iron oxides and mica-titanium colored with an organic pigment.
- composition according to the invention can comprise 5 to 50% by weight of at least one inorganic pigment, preferably 20 to 30%.
- compositions according to the invention comprising inorganic pigments can be compositions for making up the face, foundations or lipsticks.
- the mineral filters absorbing UVA and / or UVB rays can be chosen from metal oxides such as titanium dioxide (rutile or anatase, acicular or not), zinc oxide, iron oxide.
- these are titanium dioxide particles having a size of between 20 and 200 nm and covered on the surface with a mineral or organic coating. Mention may very particularly be made of aqueous dispersions of nanometric particles of titanium dioxide of size less than 100 nm having an inorganic treatment based on silica and alumina. This type of dispersion is described in particular in patents WO 97/30130 and WO 98/01392.
- composition according to the invention can comprise 1 to 20% by weight of at least one mineral filter absorbing UVA and / or UVB rays, preferably 2 to 8%.
- Compositions according to the invention comprising mineral filters absorbing UVA and / or UVB rays can be sun compositions, day cream compositions or body lotions.
- the function of antiperspirants is to reduce, or even eliminate, traces of perspiration on the surface of the skin. They are described in Woodruffs ingredients & formulary Handbook (J. Woodruff-First Ed 1997 III p 89).
- They can be aluminum chloride, aluminum sulphate, aluminum hydrochloride, basic aluminum bromide, zirconium chloride, zirconium hydroxide, zirconium hydrochloride, or complexes of type:
- the preferred antiperspirant active agents are the complexes of aluminum and zirconium hydrochlorides, for example: aluminum and zirconium trichlorohydrate, aluminum and zirconium tetrachlorohydrate and aluminum and zirconium pentachlorohydrate, the names of which are defined. according to the CTFA nomenclature.
- the latter complexes can be combined with glycine.
- composition according to the invention may comprise 5 to 40% by weight of at least one antiperspirant agent, preferably 15 to 25%.
- an antiperspirant composition it is preferably in the form of a roll-on applicator because of its low viscosity.
- composition according to the invention generally has a viscosity of at most 100,000 mPa.s at 25 ° C, preferably at most 5000 mPa.s, even more preferably at most 1000 mPa.s
- the aqueous medium of the composition consists at least of water. But preferably, this aqueous medium comprises additives.
- additives there may be mentioned in particular anionic surfactants. These compounds are particularly advantageous, in particular in the case of compositions of low viscosity, that is to say of viscosity less than 5000 mPa.s.
- anionic surfactants can be used: - the alkyl esters sulfonates of formula R-CH (SO 3 M) -COOR ', where R represents an alkyl radical in C 8 -C 2 n, preferably in C 10 -C 16 , R 'a C-rC ⁇ , preferably C-
- RCONHR'OSO 3 M where R represents a C 2 -C 22 , preferably C 6 -C 20 , alkyl radical, R ′ a C 2 -C 3 alkyl radical, M representing a d atom hydrogen or a cation of the same definition as above, as well as their ethoxylenated (OE) and / or propoxylenated (OP) derivatives, preferably having 1 to 20 OE units,
- C 8 -C 24 preferably C 1 -C 20 saturated or unsaturated fatty acids, Cg-C 2 o alkylbenzenesulfonates. as well as their ethoxylenated (OE) and / or propoxylenated (OP) derivatives, preferably having 1 to 20 OE units,
- GB-A-1 082 179 paraffin sulfonates, N-acyl N-alkyltaurates, mono- and dialkylphosphates, alkylisethionates, alkylsuccinamates, alkylsulfosuccinates, monoesters or diesters of sulfosuccinates, N-acyl sarcosinates, alkyl glycoside sulfates, polyethoxycarboxylates, the cation being an alkali metal (sodium, potassium, lithium), a substituted or unsubstituted ammonium residue (methyl-, dimethyl-, trimethyl-, tetramethylammonium, dimethylpiperidinium) or an alkanolamine derivative ( monoethanolamine, diethanolamine, triethanolamine).
- alkali metal sodium, potassium, lithium
- a substituted or unsubstituted ammonium residue methyl-, dimethyl-, trimethyl-, tetramethylammoni
- the preferred surfactants are chosen from: C 6 -C 22 alkyl ethercarboxylates . C -C 23 alkyl ether sulfate carboxylates, alkyl ether sulfates comprising 1 to 23 EO and / or OP units per molecule.
- surfactants their content represents at most 5% by weight of the composition. Preferably this content is between 0.01 and 5% by weight.
- composition according to the invention may also contain at least one amphoteric surfactant, for example chosen from alkyl betaines, alkyl amidopropyl betaines, alkyl sulfobetaines, alkyl amidopropyl hydroxysultaines, alkyl glycinates, alkyl carboxy glycinates, in which the alkyl groups contain 8 to 18 carbon atoms.
- amphoteric surfactant for example chosen from alkyl betaines, alkyl amidopropyl betaines, alkyl sulfobetaines, alkyl amidopropyl hydroxysultaines, alkyl glycinates, alkyl carboxy glycinates, in which the alkyl groups contain 8 to 18 carbon atoms.
- the content of amphoteric surfactant in the composition is at most 5% by weight of said composition.
- the content of amphoteric surfactant is between 0.01 and 5% by weight.
- the composition according to the invention can also comprise the additives usually introduced into cosmetic compositions, for example:
- emollients such as:
- alkylmonoglycerides such as oils extracted from plants and plants (palm, copra, cottonseed, soybean, sunflower, olive, grapeseed, sesame, d (peanut, castor, argan) or oils of marine origin (fish oils), derivatives of these oils such as hydrogenated oils, lanolin derivatives, mineral oils or hydrocarbon oils such as paraffin oils, squalane, squalene, petrolatum,
- esters such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, isononyl isononanoate, 2-ethyl hexyl palmitate, 2-ethyl hexyl laurate, 2-octyl decyl palmitate, 2-octyl dodecyl mysristate, 2-diethylhexyl succinate, diisostearyl malate, 2-octyl dodecyl lactate, ethyl-2-hexyl cocoate, myristyl myristate, glycerine triisostearate, silicone oils such as polymethylsiloxanes, polymethylphenylsiloxanes, polydiphenylsiloxanes, polyorganosiloxanes or polymethylsiloxanes modified with fatty acids, fatty alcohols, fluorinated groups, silicone oils grouping polydimethyls
- perfumes • alcohols such as ethanol, glycerol, propylene glycol,
- solubilizers such as dipropylene glycolmonopropyl ether
- Fillers such as hydrated magnesium silicates, aluminosilicates, modified or unmodified starch, silica, alumina, powders of synthetic polymers (polyethylene, polyester, polyamide, polystyrene),
- cooling agents such as menthol, menthyl lactate and other menthol derivatives, • deodorants, different from perfumes, which eliminate the microbial flora on the surface of the skin, in particular that which is smelly, for example 2,4,4'-trichloro-2'-hydroxydiphenyl ether (also known under the name DP300 or Triclosan®) "of preservatives.
- perfumes which eliminate the microbial flora on the surface of the skin, in particular that which is smelly, for example 2,4,4'-trichloro-2'-hydroxydiphenyl ether (also known under the name DP300 or Triclosan®) "of preservatives.
- composition according to the invention can be prepared by dilution in water, of the oil-in-water emulsion previously prepared, at the desired content and viscosity. Then, the inorganic agent, and optionally the anionic surfactant and the other additives, are added. It is possible to produce transparent compositions according to the invention by implementing a method which adjusts the refractive index; such processes are described in Woodruffs Ingredients & Formulary Handbook (J. Woodruff-First Ed. 1997, III, p. 89).
- This type of transparent formulations is particularly advantageous in the case of compositions comprising an antiperspirant agent.
- the invention also relates to the use of this composition as a cosmetic composition. It is usually applied directly to the skin.
- An oil-in-water emulsion is prepared based on Mirasil DM20® sold by Rhodia Chimie which is a Dimethicone with a viscosity of 20 mPa.s.
- An anionic surfactant is used for the emulsification: ethoxylated lauric alcohol, sold by Rhodia Chimie, comprising 8 units of ethylene oxide in a content of 4% by weight relative to the emulsion.
- the emulsion obtained has a dimethicone content of 66% by weight and a particle size of 0.47 ⁇ m.
- the dimethicone emulsion is mixed with water and Laureth-8 carboxylate until a homogeneous mixture is obtained. Then added P "Aluminum zirconium tetrachlorohydrex gly" marketed by REHEIS which is an antiperspirant agent, the mixture is stirred until complete dissolution of this agent.
- composition obtained has a low viscosity, good spreading and a complete absence of tack.
- An oil-in-water emulsion is prepared based on Mirasil DM20® sold by Rhodia Chimie.
- An anionic surfactant is used for the emulsification: isotrideceth-7.
- the emulsion has a dimethicone content of 66% by weight and a particle size of 0.47 ⁇ m.
- the emulsion is stabilized by the addition of Laureth-8 carboxylate in an amount of 0.05% by weight relative to the emulsion.
- the dimethicone emulsion is mixed with water until a homogeneous mixture is obtained.
- the contents by weight of the various components of the composition are as follows:
- composition obtained is stable: no syneresis or sedimentation of the antiperspirant agent is observed during storage. It has a very weak sticky effect when it is deposited on the skin.
- Example 1 The dimethicone emulsion of Example 1 is mixed with water until a homogeneous mixture is obtained. Then added "Aluminum zirconium tetrachlorohydrex gly", the mixture is stirred until complete dissolution of the agent. Finally, add the fragrance and the preservative.
- the contents by weight of the various components of the composition are as follows:
- composition is translucent and is easily deposited on the skin. It does not stick and remains stable during storage.
- Example 4 Long-lasting liquid foundation.
- a dimethicone emulsion is prepared according to Example 1, then two phases A and B are prepared by mixing their components.
- Phase A The proportions of the various components relative to the final composition are as follows: Phase A:
- Phase B Phenyltrimethicone 2% by weight
- Phase B is added to phase A and the mixture is homogenized. Then, 12% by weight is introduced relative to the final composition of Color Chart
- the foundation obtained is easily deposited on the skin, has no sticky effect and has a long duration.
- a Dimethicone emulsion is prepared according to Example 1, then two phases A and B are prepared by mixing their components
- Phase A - Dimethicone emulsion 20% by weight
- Phase B is added to phase A and the mixture is homogenized. Then, 11.75% by weight is introduced relative to the final composition of Golden Color Chart which is a mixture of Covasop pigments in propylene glycol sold by Wackherr Dyes.
- the foundation obtained is easily deposited on the skin, does not have a sticky effect and has a long duration.
- the sun protection index (SPF) measured in vitro (Optometrics) according to the Colipa recommendation, is 6.3 ⁇ 0.8.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU26761/00A AU2676100A (en) | 1999-02-18 | 2000-02-11 | Composition comprising an oil-in-water emulsion and an inorganic agent |
US09/890,964 US6616936B1 (en) | 1999-02-18 | 2000-02-11 | Composition comprising an oil-in-water emulsion and an inorganic agent |
EP00905114A EP1153064A1 (fr) | 1999-02-18 | 2000-02-11 | Composition comprenant une emulsion huile dans l'eau et un agent inorganique |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR99/02010 | 1999-02-18 | ||
FR9902010A FR2789997B1 (fr) | 1999-02-18 | 1999-02-18 | Composition comprenant une emulsion huile dans l'eau et un agent inorganique |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000049067A1 true WO2000049067A1 (fr) | 2000-08-24 |
Family
ID=9542213
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2000/000343 WO2000049067A1 (fr) | 1999-02-18 | 2000-02-11 | Composition comprenant une emulsion huile dans l'eau et un agent inorganique |
Country Status (5)
Country | Link |
---|---|
US (1) | US6616936B1 (fr) |
EP (1) | EP1153064A1 (fr) |
AU (1) | AU2676100A (fr) |
FR (1) | FR2789997B1 (fr) |
WO (1) | WO2000049067A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2882926A1 (fr) * | 2005-03-10 | 2006-09-15 | Oreal | Kit comprenant une emulsion cosmetique |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10205192A1 (de) * | 2002-02-08 | 2003-08-21 | Beiersdorf Ag | Diolhaltige Parfümkomposition |
ES2336570T3 (es) * | 2003-10-24 | 2010-04-14 | Cognis France, S.A.S. | Extracto vegetal y su utilizacion farmaceutica y cosmetica. |
JP2009527504A (ja) * | 2006-02-23 | 2009-07-30 | イオメディックス スリープ インターナショナル エスアールエル | 良質な睡眠の誘導および維持のための組成物および方法 |
US9592265B2 (en) * | 2012-04-10 | 2017-03-14 | The Regents Of The University Of California | Modulation of oxidative stress, inflammation, and impaired insulin sensitivity with grape seed extract |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0774482A2 (fr) * | 1995-11-20 | 1997-05-21 | Dow Corning Corporation | Microémulsions claires de silicone, spontanément formés |
WO1997030130A1 (fr) * | 1996-02-15 | 1997-08-21 | Rhodia Chimie | Particules de dioxyde de titane |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5729213B2 (fr) * | 1974-11-12 | 1982-06-21 | ||
US4797272A (en) * | 1985-11-15 | 1989-01-10 | Eli Lilly And Company | Water-in-oil microemulsions for cosmetic uses |
US5207998A (en) * | 1991-05-07 | 1993-05-04 | Richardson-Vicks Inc. | Suncare compositions |
FR2697025B1 (fr) * | 1992-10-20 | 1995-02-03 | Rhone Poulenc Chimie | Procédé de préparation d'émulsions aqueuses d'huiles et/ou de gommes et/ou de résines silicones. |
AU721618B2 (en) * | 1996-05-20 | 2000-07-13 | Shiseido Company Ltd. | Oil-in-water emulsified composition and oil-in-water emulsifying agent |
GB9706486D0 (en) * | 1997-03-27 | 1997-05-14 | Unilever Plc | Hair treatment composition |
JP3449886B2 (ja) * | 1997-06-02 | 2003-09-22 | 信越化学工業株式会社 | 被膜形成性組成物およびこれを用いた化粧料 |
GB9822518D0 (en) * | 1998-10-15 | 1998-12-09 | Unilever Plc | Antiperspirant compositions |
-
1999
- 1999-02-18 FR FR9902010A patent/FR2789997B1/fr not_active Expired - Fee Related
-
2000
- 2000-02-11 EP EP00905114A patent/EP1153064A1/fr not_active Withdrawn
- 2000-02-11 AU AU26761/00A patent/AU2676100A/en not_active Abandoned
- 2000-02-11 WO PCT/FR2000/000343 patent/WO2000049067A1/fr active Search and Examination
- 2000-02-11 US US09/890,964 patent/US6616936B1/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0774482A2 (fr) * | 1995-11-20 | 1997-05-21 | Dow Corning Corporation | Microémulsions claires de silicone, spontanément formés |
WO1997030130A1 (fr) * | 1996-02-15 | 1997-08-21 | Rhodia Chimie | Particules de dioxyde de titane |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2882926A1 (fr) * | 2005-03-10 | 2006-09-15 | Oreal | Kit comprenant une emulsion cosmetique |
Also Published As
Publication number | Publication date |
---|---|
EP1153064A1 (fr) | 2001-11-14 |
US6616936B1 (en) | 2003-09-09 |
AU2676100A (en) | 2000-09-04 |
FR2789997A1 (fr) | 2000-08-25 |
FR2789997B1 (fr) | 2004-12-03 |
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