WO2000039242A1 - Composition pouvant se vaporiser - Google Patents

Composition pouvant se vaporiser Download PDF

Info

Publication number
WO2000039242A1
WO2000039242A1 PCT/GB1999/004332 GB9904332W WO0039242A1 WO 2000039242 A1 WO2000039242 A1 WO 2000039242A1 GB 9904332 W GB9904332 W GB 9904332W WO 0039242 A1 WO0039242 A1 WO 0039242A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
weight
refrigerant
component
vaporisable
Prior art date
Application number
PCT/GB1999/004332
Other languages
English (en)
Inventor
Stephen Forbes Pearson
Original Assignee
Star Refrigeration Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Star Refrigeration Limited filed Critical Star Refrigeration Limited
Priority to EP99962382A priority Critical patent/EP1147160B1/fr
Priority to JP2000591142A priority patent/JP2002533561A/ja
Priority to AU18747/00A priority patent/AU1874700A/en
Priority to DE69915126T priority patent/DE69915126D1/de
Priority to AT99962382T priority patent/ATE260327T1/de
Publication of WO2000039242A1 publication Critical patent/WO2000039242A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/122—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/128—Perfluorinated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/40—Replacement mixtures
    • C09K2205/43—Type R22
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/40—Replacement mixtures
    • C09K2205/47—Type R502

Definitions

  • the present invention relates to a vaporisable composition for use inter alia as a refrigerant, a heat transfer material or an aerosol propellant and which has improved environmental properties.
  • the composition may be used as a replacement for the conventional widely used refrigerant R22 (CHClF 2 -chlorodifluoromethane) since its refrigerant properties are generally speaking equivalent to those of R22 but the environmental properties of the vaporisable composition particularly in terms of global warming potential (G P 100 ) and ozone depletion potential (ODP) are greatly improved.
  • R22 refrigerant
  • G P 100 global warming potential
  • ODP ozone depletion potential
  • R22 is a chlorine-containing molecule with a significant atmospheric residence time and therefore has a significant ozone depletion potential. For this reason, the use of R22 is likely to be proscribed in the future.
  • Compounds with significant global warming potentials are those which absorb strongly in the infrared region.
  • the refrigerant blends produced so far have a number of disadvantages. Firstly, they generally have low critical temperatures which reduces the thermodynamic efficiency of refrigeration systems using them. Secondly, they often have very high global warming potentials relative to R22. Thirdly, they generally operate at pressures higher than those associated with R22. Finally, some of them, not being azeotropes, have significant temperature glide which makes them unsuitable for use in refrigeration systems employing flooded evaporators (where refrigerant is present in the liquid state) . Temperature glide refers to the change in evaporation temperature which occurs due to the fractionation of a mixed refrigerant during evaporation.
  • a refrigerant preferably an azeotrope or near-azeotropic blend, which does not contain chlorine or bromine (which would tend to have a high ODP) , which has a short atmospheric life and thermodynamic properties tending to give refrigeration system efficiencies similar to those obtainable using R22.
  • Patent publication 094/20588 discloses two-component blends of R161 and R13I1 but does not suggest their use as R22 replacements; nor does it disclose three-component blends further including R218.
  • the present invention provides a vaporisable composition for use as a refrigerant, heat transfer material or aerosol propellant, which comprises;
  • composition may be a two-component composition consisting of R161 and R13I1 alone or may include further component (s) as described hereafter.
  • R161 is found to be a substance having essentially zero ODP and other suitable properties but it has a higher boiling temperature than R22 and is flammable.
  • the boiling point of R161 is -37.48°C and the critical temperature is 102.2°C.
  • R13I1 is known to have a short atmospheric lifetime and to be a very effective fire extinguishing compound. However, the boiling point of R13I1 is -22.52°C which is much higher than that of R22. The critical temperature is 122°C.
  • the difference in boiling point between R161 and R13I1 is about 15°C. It is known that compounds having close boiling points, tend to be more likely to produce azeotropes than compounds with greatly different boiling points. In the present instance, the difference in boiling points between R161 and R13I1 would be considered by a skilled man to make the formation of an azeotrope very unlikely. However, it has now been found that when mixing R161 and R13I1, despite the wide difference in boiling point, the pressure-temperature relationship of the composition produced is greater than that of either component. This indicates that, unexpectedly, an azeotrope is formed between these two substances.
  • the preferred near-azeotropic composition of about 80% R161 and 20% R13I1 by weight has a boiling point at atmospheric pressure of about -40°C and a pressure/temperature relationship very similar to that of R22.
  • the vapour pressure of the composition is higher than that of either of the components separately.
  • the vapour pressure of the composition lies within the range 3.5 to 6.0 bar, especially 4.25 to 5.25 bar and particularly 4.55 to 4.95 bar at 0°C.
  • the proportions of R161 in the composition is in the range 75-85% by weight, especially 78-82% by weight.
  • the proportions of R13I1 are in the range 15-25% by weight, especially 18-22% by weight.
  • R161 up to 95% by weight (e.g. 80 to 95%, especially 80 to 90%) of R161 may be included in the composition. It has also been shown that amounts of R13I1 as low as 5% by weight (e.g. 10 to 20%) may be useful.
  • a particularly useful property of the vaporisable compositions of the present invention is that they are miscible with mineral oil in essentially all proportions. Since mineral oil is the lubricant conventionally used in refrigeration systems, this means that there is no need to flush out and replace the existing mineral oil lubricant when the refrigerant is changed and replaced by a refrigerant according to the present invention. Some refrigerant compositions are not soluble with conventional mineral oil lubricants and thus require specialised expensive synthetic lubricating oils.
  • the vaporisable composition of the present invention may be a two-component composition or may comprise one or more further components.
  • a composition having a pressure-temperature relationship very similar to that of conventional refrigerant R502 may be produced by the inclusion of a minor amount of R218 octafluoropropane (CF,CF ; CF,-R218) in the composition.
  • the R218 may be present in amounts of 0-25%, particularly 2-20% and especially 5-15% by weight.
  • large proportions of R218 are to be avoided because of its high global warming potential.
  • Tests of a blend containing 18% by weight R218 indicated refrigerating effects greater than those of R22. The efficiency was about 12% higher than would have been obtained using R22.
  • the low index of compression of R218 may lead to improved chemical stability of the composition in practical use.
  • vapour pressure at 0°C of a three component R161/R13I1/R218 composition lies in the range 4.9 to 5.6 bar at 0°C.
  • the invention also extends to a process for producing refrigeration or heating which involves using the vaporisable composition of the present invention in a vapour compression refrigeration system or heat pump.
  • a composition comprising 80% R161 and 20% by weight R13I1 was transferred to a specially prepared cylinder having an accurate resistance thermometer fitted within an internal pocket and having a calibrated pressure transducer connected to the cylinder.
  • the cylinder was immersed in a low temperature mixture of solid carbon dioxide and acetone and allowed to warm up slowly.
  • the pressure-temperature relationship obtained is shown in Figure 1, which also shows for comparison the individual pressure-temperature relationships of R161 and R13I1 alone.
  • the pressure- temperature relationship of the 80:20 blend is very similar to that of R22 (not shown) .
  • EXAMPLE 2 Two-Component Composition
  • the refrigeration effect was measured using a calorimeter and methodology as described in "Automatic Calorimeter for Mixed Refrigerants” S.F. Pearson, 19th International Congress of Refrigeration 1995; Proceedings volume IVa. The measured data is used to determine coefficients of performance (COP) .
  • COP coefficients of performance
  • the refrigerating effect was determined by measuring the electrical input to a secondary refrigerant calorimeter.
  • the refrigerant under test is compressed using a compressor in a vapour compression system.
  • the refrigerant is condensed in a water cooled condenser at a selected condenser temperature (e.g. 40°C or 55°C). From the condenser the liquid refrigerant is passed through an expansion valve and the evaporating temperature downstream thereof is noted.
  • the evaporating temperature may be varied by varying the amount of refrigerant charged into the system.
  • the associated refrigerating effect produced is measured in the secondary refrigerant calorimeter, wherein the required electrical input to counter-balance the refrigerating effect produced is measured (kW) .
  • the automatic calorimeter was charged with the 80:20 R161/R13I1 composition and was operated at evaporating temperatures in the range -35°C to -5°C with the refrigerant condensing at +40°C.
  • the same calorimeter with the same compressor and lubricant was also operated on R22 under similar conditions for comparison.
  • FIG. 2 shows the refrigerating effect (kW) of the R161/R13I1 composition of the present invention and R22 for comparison. It can be seen that the refrigerating effects of the two refrigerants are very similar.
  • FIG. 3 shows the co-efficient of performance (COP) of the two refrigerants.
  • COP is defined as the ratio of refrigerating effect (kW) to power required to drive the compressor (kW) and is therefore a dimensionless ratio. It can be seen that the COP of the system using the 2-component composition is significantly higher than that obtained using conventional R22.
  • FIG 4 shows the refrigerating effect (kW) of the three-component composition in comparison to conventional R22. It can be seen that the refrigerating effect of the composition of the present invention is significantly greater.
  • Figure 5 shows the COP of the three-component composition and this is also significantly better than that of conventional R22.
  • the effect of adding the R218 as a third component is to increase the GWP100 to about 1,300, which is similar to that of pure R134a (CH : FCF, tetrafluoroethane) .
  • the GWP 100 of the two-component 80:20 blend is believed to be less than 10, which is similar to natural refrigerants (such as ammonia, carbon dioxide etc. ) .
  • vapour pressures of binary R161 and R13I1 compositions of varying proportions were measured at 0°C using an experimental procedure analogous to that described in Example 1. Measurements were carried out on two series of compositions.
  • Figure 6 shows that the vapour pressure goes through a maximum in the region 10 to 15wt % R13I1 indicating an azeotrope in that region.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Lubricants (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Sorption Type Refrigeration Machines (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Cette composition pouvant se vaporiser est utile en tant que composition remplaçant des frigorigènes classiques R22 et R502, et elle comprend 40-90 % en poids de fluoroéthane (R161) et 10-60 % en poids de trifluoro-iodométhane (R13I1). Elle peut en outre comprendre de l'octafluoropropane (R218).
PCT/GB1999/004332 1998-12-29 1999-12-20 Composition pouvant se vaporiser WO2000039242A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP99962382A EP1147160B1 (fr) 1998-12-29 1999-12-20 Composition pouvant se vaporiser
JP2000591142A JP2002533561A (ja) 1998-12-29 1999-12-20 蒸発性組成物
AU18747/00A AU1874700A (en) 1998-12-29 1999-12-20 Vaporisable composition
DE69915126T DE69915126D1 (de) 1998-12-29 1999-12-20 Verdampfbare zusammensetzung
AT99962382T ATE260327T1 (de) 1998-12-29 1999-12-20 Verdampfbare zusammensetzung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9828737.8A GB9828737D0 (en) 1998-12-29 1998-12-29 Vaporisable composition
GB9828737.8 1998-12-29

Publications (1)

Publication Number Publication Date
WO2000039242A1 true WO2000039242A1 (fr) 2000-07-06

Family

ID=10845099

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/004332 WO2000039242A1 (fr) 1998-12-29 1999-12-20 Composition pouvant se vaporiser

Country Status (7)

Country Link
EP (1) EP1147160B1 (fr)
JP (1) JP2002533561A (fr)
AT (1) ATE260327T1 (fr)
AU (1) AU1874700A (fr)
DE (1) DE69915126D1 (fr)
GB (1) GB9828737D0 (fr)
WO (1) WO2000039242A1 (fr)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021675A1 (fr) * 2003-08-27 2005-03-10 Solvay Fluor Gmbh Utilisation d'un melange de refrigerants
WO2005103192A1 (fr) * 2004-04-16 2005-11-03 Honeywell International, Inc. Compositions de type azeotrope de tetrafluoropropene et de trifluoroiodomethane
WO2006069362A3 (fr) * 2004-12-21 2007-03-01 Honeywell Int Inc Compositions d'iodocarbone stabilisees
JP2008504374A (ja) * 2004-04-16 2008-02-14 ハネウェル・インターナショナル・インコーポレーテッド テトラフルオロプロペンおよびトリフルオロヨードメタンの共沸混合物様組成物
US7345209B2 (en) 2004-04-29 2008-03-18 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene
US7465698B2 (en) 2004-04-16 2008-12-16 Honeywell International Inc. Azeotrope-like compositions of difluoromethane and trifluoroiodomethane
US7479477B2 (en) 2004-04-16 2009-01-20 Honeywell International Inc. Azeotrope-like compositions of difluoromethane and trifluoroiodomethane
US7605117B2 (en) 2004-04-16 2009-10-20 Honeywell International Inc. Methods of replacing refrigerant
US7622435B2 (en) 2004-04-16 2009-11-24 Honeywell International Inc. Methods of replacing refrigerant
US7659434B2 (en) 2004-04-29 2010-02-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7674939B2 (en) 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7880040B2 (en) 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
CN102032620A (zh) * 2010-12-15 2011-04-27 广东美的电器股份有限公司 一种制冷设备
US7951982B2 (en) 2004-04-29 2011-05-31 Honeywell International Inc. Method for producing fluorinated organic compounds
CN101636466B (zh) * 2004-04-16 2012-06-13 霍尼韦尔国际公司 四氟丙烯和三氟碘甲烷的类共沸组合物
US8383867B2 (en) 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
ITTO20121099A1 (it) * 2012-12-18 2014-06-19 Tazzetti S P A Nuove miscele refrigeranti a basso impatto ambientale
US9175201B2 (en) 2004-12-21 2015-11-03 Honeywell International Inc. Stabilized iodocarbon compositions
US9308199B2 (en) 2004-04-29 2016-04-12 Honeywell International Inc. Medicament formulations
US9920230B2 (en) 2004-12-21 2018-03-20 Honeywell International Inc. Use of low GWP refrigerants comprising CF3I with stable lubricants
CN109852348A (zh) * 2019-01-10 2019-06-07 珠海格力电器股份有限公司 环保混合工质
CN110317575A (zh) * 2019-07-22 2019-10-11 珠海格力电器股份有限公司 制冷剂组合物及其制备方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7155804B2 (ja) * 2018-09-21 2022-10-19 株式会社富士通ゼネラル 圧縮機及び冷凍サイクル装置
JP2020051418A (ja) * 2018-09-28 2020-04-02 株式会社富士通ゼネラル 圧縮機及び冷凍サイクル装置

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04323294A (ja) * 1991-04-22 1992-11-12 Daikin Ind Ltd 熱伝達用流体
WO1994020588A1 (fr) * 1993-03-05 1994-09-15 Ikon Corporation Melanges de fluoroiodocarbure remplacant les cfc et l'halon
GB2298866A (en) * 1995-03-11 1996-09-18 Star Refrigeration Refrigerant composition comprising fluoroethane
WO1997015637A1 (fr) * 1995-10-20 1997-05-01 Tsinghua University Refrigerant

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69300998T2 (de) * 1992-04-04 1996-07-04 Star Refrigeration Kühlzusammensetzung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04323294A (ja) * 1991-04-22 1992-11-12 Daikin Ind Ltd 熱伝達用流体
WO1994020588A1 (fr) * 1993-03-05 1994-09-15 Ikon Corporation Melanges de fluoroiodocarbure remplacant les cfc et l'halon
GB2298866A (en) * 1995-03-11 1996-09-18 Star Refrigeration Refrigerant composition comprising fluoroethane
WO1997015637A1 (fr) * 1995-10-20 1997-05-01 Tsinghua University Refrigerant

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199252, Derwent World Patents Index; Class E16, AN 1992-427930, XP002132864 *
PATENT ABSTRACTS OF JAPAN vol. 17, no. 162 (C - 1042) 30 March 1993 (1993-03-30) *

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021675A1 (fr) * 2003-08-27 2005-03-10 Solvay Fluor Gmbh Utilisation d'un melange de refrigerants
EP2336266A1 (fr) * 2004-04-16 2011-06-22 Honeywell International Inc. Compositions de type azeotrope de tetrafluoropropene et de trifluoroiodomethane
TWI384062B (zh) * 2004-04-16 2013-02-01 Honeywell Int Inc 四氟丙烯及三氟碘甲烷之似共沸物組合物
JP2012067310A (ja) * 2004-04-16 2012-04-05 Honeywell Internatl Inc テトラフルオロプロペンおよびトリフルオロヨードメタンの共沸混合物様組成物
JP2008504374A (ja) * 2004-04-16 2008-02-14 ハネウェル・インターナショナル・インコーポレーテッド テトラフルオロプロペンおよびトリフルオロヨードメタンの共沸混合物様組成物
CN101636466B (zh) * 2004-04-16 2012-06-13 霍尼韦尔国际公司 四氟丙烯和三氟碘甲烷的类共沸组合物
US7465698B2 (en) 2004-04-16 2008-12-16 Honeywell International Inc. Azeotrope-like compositions of difluoromethane and trifluoroiodomethane
US7479477B2 (en) 2004-04-16 2009-01-20 Honeywell International Inc. Azeotrope-like compositions of difluoromethane and trifluoroiodomethane
US7605117B2 (en) 2004-04-16 2009-10-20 Honeywell International Inc. Methods of replacing refrigerant
US7622435B2 (en) 2004-04-16 2009-11-24 Honeywell International Inc. Methods of replacing refrigerant
CN1969028B (zh) * 2004-04-16 2012-05-16 霍尼韦尔国际公司 四氟丙烯和三氟碘甲烷的类共沸组合物
WO2005103190A1 (fr) * 2004-04-16 2005-11-03 Honeywell International Inc. Compositions azeotropiques de tetrafluoropropene et de trifluoroiodomethane
WO2005103192A1 (fr) * 2004-04-16 2005-11-03 Honeywell International, Inc. Compositions de type azeotrope de tetrafluoropropene et de trifluoroiodomethane
EP2292715A1 (fr) * 2004-04-16 2011-03-09 Honeywell International Inc. Compositions azéotropiques de tétrafluoropropène et de trifluoroiodométhane
US9308199B2 (en) 2004-04-29 2016-04-12 Honeywell International Inc. Medicament formulations
US7880040B2 (en) 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US7674939B2 (en) 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7659434B2 (en) 2004-04-29 2010-02-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7345209B2 (en) 2004-04-29 2008-03-18 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene
US8383867B2 (en) 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
US8395000B2 (en) 2004-04-29 2013-03-12 Honeywell International Inc. Method for producing fluorinated organic compounds
US7951982B2 (en) 2004-04-29 2011-05-31 Honeywell International Inc. Method for producing fluorinated organic compounds
US9061957B2 (en) 2004-04-29 2015-06-23 Honeywell International Inc. Method for producing fluorinated organic compounds
WO2006069362A3 (fr) * 2004-12-21 2007-03-01 Honeywell Int Inc Compositions d'iodocarbone stabilisees
US9920230B2 (en) 2004-12-21 2018-03-20 Honeywell International Inc. Use of low GWP refrigerants comprising CF3I with stable lubricants
US9175201B2 (en) 2004-12-21 2015-11-03 Honeywell International Inc. Stabilized iodocarbon compositions
CN102032620A (zh) * 2010-12-15 2011-04-27 广东美的电器股份有限公司 一种制冷设备
ITTO20121099A1 (it) * 2012-12-18 2014-06-19 Tazzetti S P A Nuove miscele refrigeranti a basso impatto ambientale
WO2014097161A1 (fr) 2012-12-18 2014-06-26 Tazzetti S.P.A. Mélanges de gaz réfrigérants à faible impact sur l'environnement
US9999794B2 (en) 2012-12-18 2018-06-19 Tazzetti S.P.A. Low environmental impact refrigerant gas mixtures
CN109852348A (zh) * 2019-01-10 2019-06-07 珠海格力电器股份有限公司 环保混合工质
CN110317575A (zh) * 2019-07-22 2019-10-11 珠海格力电器股份有限公司 制冷剂组合物及其制备方法

Also Published As

Publication number Publication date
GB9828737D0 (en) 1999-02-17
EP1147160A1 (fr) 2001-10-24
EP1147160B1 (fr) 2004-02-25
DE69915126D1 (de) 2004-04-01
JP2002533561A (ja) 2002-10-08
ATE260327T1 (de) 2004-03-15
AU1874700A (en) 2000-07-31

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