WO1998051160A1 - Pigment/dyestuff composition - Google Patents

Pigment/dyestuff composition Download PDF

Info

Publication number
WO1998051160A1
WO1998051160A1 PCT/SE1998/000885 SE9800885W WO9851160A1 WO 1998051160 A1 WO1998051160 A1 WO 1998051160A1 SE 9800885 W SE9800885 W SE 9800885W WO 9851160 A1 WO9851160 A1 WO 9851160A1
Authority
WO
WIPO (PCT)
Prior art keywords
sorbitan
polyoxyethylene
pigment
weight
dyestuff
Prior art date
Application number
PCT/SE1998/000885
Other languages
English (en)
French (fr)
Inventor
Göran RYDENFORS
Original Assignee
Ab Tripasin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ab Tripasin filed Critical Ab Tripasin
Priority to AU75598/98A priority Critical patent/AU7559898A/en
Publication of WO1998051160A1 publication Critical patent/WO1998051160A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22CPROCESSING MEAT, POULTRY, OR FISH
    • A22C13/00Sausage casings
    • A22C13/0013Chemical composition of synthetic sausage casings
    • A22C13/0016Chemical composition of synthetic sausage casings based on proteins, e.g. collagen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0001Post-treatment of organic pigments or dyes
    • C09B67/0004Coated particulate pigments or dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084Dispersions of dyes

Definitions

  • the present invention relates to a pigment/dyestuff composition for colouring of collagen-containing sausage casings, as well as the use thereof.
  • Collagen sausage casings are commonly used since they have certain advantages over natural sausage casings. One of the advantages is that they can be supplied in desired lengths and with a homogeneous cross-section and the desired strength. For a collagen sausage casing to have a uniform and attractive appearance as well, the collagen mass is usually coloured during the manufacture of the sausage casings.
  • Collagen sausage casings are manufactured by extrusion of an acid collagen mass, usually obtained from skin splitting, to a continuous tube, which is hardened and, optionally, dried before filling.
  • the colouring of collagen sausage casings is effected by adding pigments or dyestuffs to the collagen mass before extrusion. Since collagen in its acidified state is sensitive to the effect of pigments or dyestuffs, inorganic as well as organic, first the pigment must be dispersed or the dyestuff must be dissolved to a very weak dispersion/solution, usually with a content of pigment and dyestuff, respectively, of 0.5-1% by weight, before the dispersion/solution is slowly added during mixing (homogenisation) of the collagen mass. If the addition takes place too quickly, the collagen unswells or is denaturated, islands of the denaturated collagen and pigment or dyestuff forming in the mass. These islands deteriorate both the extruding properties of the mass and its appearance, which results in a spotted and patchy sausage casing. It is not possible to mix these islands with the mass.
  • a pigment/dyestuff composition is provided, which in the colouring of collagen sausage casings solves the above-mentioned problems .
  • the invention relates to a pigment/dyestuff composition for colouring of collagen-containing sausage casings, which comprises 2-10% by weight of pigment/dye- stuff, 3-30% by weight of polyoxyethylene sorbitan fatty acid ester, 1-10% by weight of sorbitan fatty acid ester, 0-70% by weight of dispersing agent, the balance being water and, optionally, other conventional additives.
  • the invention also relates to the use of such a com- position for colouring of collagen-containing sausage casings .
  • polyoxyethylene sorbitan fatty acid ester (so-called polysorbate) and sorbitan fatty acid ester forms with the pigment/dyestuff a stable dis- persion and "encapsulates" the pigment/dyestuff particles, such that they do not come into direct contact with the collagen during mixing with the collagen mass.
  • the dispersion of the pigment/dyestuff is improved by using a thicker dispersion.
  • glycerine can therefore be added as dispersing agent (thickening agent) .
  • the pigment/dyestuff composition By using the pigment/dyestuff composition accord- ing to the invention, the pigment/dyestuff can be added quickly and in concentrated form without causing the problems of unswelling/formation of islands.
  • a further advantage of the pigment/dyestuff composition according to the invention is that it is viscous and stable in terms of settling.
  • the combination of polysor- bate/sorbitan fatty acid ester results in a more intensive colour with the corresponding amount of pigment/dye- stuff, which implies that the amount of pigment/dyestuff can be reduced to a considerable extent, viz. by about 25%.
  • the use of the pigment/dyestuff composition gives additional positive effects in the form of a more ductile collagen mass with better extruding properties.
  • the polyoxyethylene sorbitan fatty acid ester is suitably selected from the group consisting of polyoxyethylene (20) sorbitan monolaurate, monopalmitate, mono- stearate, tristearate, monooleate, trioleate.
  • the used sorbitan fatty acid ester is suitably selected from the group consisting of sorbitan monolaurate, monopalmitate, monostearate, tristearate, monooleate, trioleate.
  • Polysorbate 80 polyoxyethylene (20) sorbitan monooleate
  • Polysorbate 40 polyoxyethylene (20) sorbitan monopalmitate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Meat, Egg Or Seafood Products (AREA)
  • Investigating Or Analysing Biological Materials (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
PCT/SE1998/000885 1997-05-16 1998-05-14 Pigment/dyestuff composition WO1998051160A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU75598/98A AU7559898A (en) 1997-05-16 1998-05-14 Pigment/dyestuff composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9701828A SE508907C2 (sv) 1997-05-16 1997-05-16 Pigment/färgämneskomposition för infärgning av kollageninnehållande korvskinn samt användning därav
SE9701828-7 1997-05-16

Publications (1)

Publication Number Publication Date
WO1998051160A1 true WO1998051160A1 (en) 1998-11-19

Family

ID=20406965

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1998/000885 WO1998051160A1 (en) 1997-05-16 1998-05-14 Pigment/dyestuff composition

Country Status (3)

Country Link
AU (1) AU7559898A (sv)
SE (1) SE508907C2 (sv)
WO (1) WO1998051160A1 (sv)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025335A1 (en) * 1999-10-04 2001-04-12 Ciba Specialty Chemicals Holding Inc. Sorbitan ester treated pigments for plastics applications
WO2015160949A1 (en) * 2014-04-16 2015-10-22 Nitta Casings Inc. Edible collagen casings finished with polysorbate
EP3282853A4 (en) * 2015-04-16 2018-12-26 Nitta Casings Inc. Collagen casings having increased final moisture content and method of production

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387983A (en) * 1964-06-11 1968-06-11 Allied Chem Organic color lakes
US4115594A (en) * 1977-03-30 1978-09-19 Union Carbide Corporation Extrudable collagen casing and method of preparation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387983A (en) * 1964-06-11 1968-06-11 Allied Chem Organic color lakes
US4115594A (en) * 1977-03-30 1978-09-19 Union Carbide Corporation Extrudable collagen casing and method of preparation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025335A1 (en) * 1999-10-04 2001-04-12 Ciba Specialty Chemicals Holding Inc. Sorbitan ester treated pigments for plastics applications
US6440206B1 (en) 1999-10-04 2002-08-27 Ciba Specialty Chemicals Corporation Sorbitan ester treated pigments for plastics applications
WO2015160949A1 (en) * 2014-04-16 2015-10-22 Nitta Casings Inc. Edible collagen casings finished with polysorbate
EP3282853A4 (en) * 2015-04-16 2018-12-26 Nitta Casings Inc. Collagen casings having increased final moisture content and method of production

Also Published As

Publication number Publication date
SE9701828D0 (sv) 1997-05-16
SE9701828L (sv) 1998-11-16
AU7559898A (en) 1998-12-08
SE508907C2 (sv) 1998-11-16

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