WO1998049242A1 - Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung - Google Patents

Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung Download PDF

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Publication number
WO1998049242A1
WO1998049242A1 PCT/EP1998/002329 EP9802329W WO9849242A1 WO 1998049242 A1 WO1998049242 A1 WO 1998049242A1 EP 9802329 W EP9802329 W EP 9802329W WO 9849242 A1 WO9849242 A1 WO 9849242A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
coating material
binder
graphite
radiation
Prior art date
Application number
PCT/EP1998/002329
Other languages
German (de)
English (en)
French (fr)
Inventor
Helmut Reichelt
Original Assignee
Molekulare Energietechnik Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7827835&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1998049242(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to DE59804898T priority Critical patent/DE59804898D1/de
Priority to APAP/P/1999/001628A priority patent/AP1066A/en
Priority to AU73359/98A priority patent/AU721575B2/en
Priority to DK98920540T priority patent/DK0977816T3/da
Priority to BR9808700-2A priority patent/BR9808700C1/pt
Priority to EA199900677A priority patent/EA002928B1/ru
Priority to UA99095268A priority patent/UA53694C2/uk
Priority to EP98920540A priority patent/EP0977816B1/de
Priority to US09/381,146 priority patent/US6254922B1/en
Priority to KR10-1999-7007085A priority patent/KR100533115B1/ko
Priority to SI9830251T priority patent/SI0977816T1/xx
Priority to PL98335577A priority patent/PL188183B1/pl
Priority to NZ336934A priority patent/NZ336934A/en
Priority to IL13122498A priority patent/IL131224A/en
Priority to CA002283769A priority patent/CA2283769C/en
Priority to JP54655498A priority patent/JP2001523282A/ja
Priority to SK1261-99A priority patent/SK126199A3/sk
Priority to AT98920540T priority patent/ATE221107T1/de
Application filed by Molekulare Energietechnik Ag filed Critical Molekulare Energietechnik Ag
Publication of WO1998049242A1 publication Critical patent/WO1998049242A1/de
Priority to IS5135A priority patent/IS1909B/is
Priority to NO19994357A priority patent/NO320568B1/no
Priority to HK00104473A priority patent/HK1025346A1/xx

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/36Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/38Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith formed by a conductive layer on an insulating support
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D189/00Coating compositions based on proteins; Coating compositions based on derivatives thereof
    • C09D189/005Casein
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives

Definitions

  • the invention relates to a coating material for radiation surfaces
  • Such coating materials are on radiation surfaces of
  • the electromagnetic waves generated by the radiator in cooperation with the coating material serve e.g. for cooling and heating a material brought into the radiation area of the lamp.
  • a coating material for radiation surfaces for generating electromagnetic waves and a method for its production are already known from DD-208 029.
  • the coating material is a mixture of binding agent, insulating agent, dispersing agent, water and graphite.
  • a polyvinyl acetate and / or a polyacrylate and / or a polypeptide is used as the binder, while an insulating carbon black is used as the insulating agent.
  • Graphite, carbon black and binders form electrical dipoles in the coating material, which emit electromagnetic waves when excited.
  • the process for producing this coating material essentially comprises mixing these substances by means of a stirrer and the application of pressure to crush the soot and graphite particles.
  • the binder is composed of
  • the coating material itself is composed of 55 to 65% by weight of a basic substance and 35 to 45% by weight parts of graphite, the basic substance consisting of a mixture of 39 to 49% by weight of binder, 18 to 23% by weight of insulation, 18 to 24% by weight of dispersant and 12 to 16% by weight of distilled water.
  • the coating material forms a multiplicity of uniformly distributed, smallest electrical dipoles, which are formed by the insulating agent, the graphite and the binder.
  • the main component of the binder is distilled water which, depending on the amount added, ensures at least a viscous consistency of the binder. As a result, the individual components of the binder can be mixed well with one another.
  • the sulfated oil and optionally a leveling agent serve as a solubilizer and bring about a uniform and stable distribution of the individual substances in the binder, as well as the good film formation of the coating material on a carrier material.
  • the phenols or benzisothiazolinone contained in the binder favor the attachment of particles even in small amounts.
  • the casein is to be regarded as a binder in the binder and causes the individual components to accumulate within the binder.
  • the urea is also used in the binder as a solubilizer, i.e. it favors the even distribution of the individual components in the binder.
  • the binder also contains a diluent for homogenization and caprolactam as a building material.
  • the basic substance comprises, as the main component, the binding agent to which the particles of the insulating agent attach as one part of the electrical dipole.
  • the dispersing agent facilitates the dispersing and thus the even distribution of the binding agent together with the particles of the insulating agent in the basic substance.
  • the distilled water mixed with the basic substance serves to liquefy the basic substance.
  • the graphite added in the course of the mixture of the coating material finally also accumulates with its individual particles on the binder that already binds the insulation agent and forms together with the insulation agent a large number of smallest electrical dipoles, which are evenly distributed in the coating material.
  • the graphite can already be added in the ground state with a very small particle size. This further promotes a uniform distribution of the graphite in the coating material and thus the formation of a large number of electrical dipoles.
  • This coating material thus achieves a high degree of radiation with regard to the generation and emission of electromagnetic radiation.
  • a radiation surface coated with such a coating material emits electromagnetic radiation with a correspondingly high frequency when there is high-frequency excitation.
  • the coating material preferably has an at least viscous, brushable consistency and dries after the coating of a radiation surface, preferably a continuously crack-free surface being produced.
  • sulfated oils such as B. sulfated olive oil, sulfated sesame oil or sulfated palm oil can be used.
  • the sulfated oil is preferably sulfated castor oil, which is known as sulforicinate or as Turkish red oil. This sulfated castor oil is particularly suitable because of its surface-active properties.
  • the phenols are preferably carbonized, by
  • Phenols produced by cracking which are particularly suitable for particle attachment. Instead of the phenols, benzisothiazolinone should preferably be used.
  • the diluent is a solvent based on flavor and / or alcohol and / or ester and / or ketone, for.
  • the insulating agent is preferably an insulating carbon black.
  • This carbon black is advantageously added in the ground state with a very small particle size. This promotes a uniform distribution of the soot in the base substance and thus the formation of a large number of electrical dipoles in the coating material.
  • the dispersing and thus the uniform distribution of the binder together with the particles of the insulating agent in the base substance facilitating dispersant is an organic, monomeric and / or polymeric substance.
  • the coating material in a preferred embodiment contains a thixotropic agent.
  • This thixotropic agent has the effect that the coating material has a viscous consistency, ie it is easy to spread while being applied to a radiation surface, but is so viscous in the idle state that no drops or tears can form on the surface. This enables a precise application of the coating material to a radiation surface.
  • the coating material is after
  • Claim 8 applied to a radiation surface of a radiator with which electromagnetic radiation can be emitted at a frequency which is in the order of magnitude of the molecular natural frequency of the material which can be introduced into the radiation region of the radiator for heating or cooling.
  • This emitter has a large area and is delimited by two feed lines which are arranged parallel to one another and are at a distance from one another which corresponds to an integral multiple of the wavelength emitted by the emitter.
  • this radiator it is possible to emit both a frequency in the range of the molecular natural frequency of the material to be heated or cooled, and a corresponding suitable frequency for a liquid or gaseous medium additionally arranged in the room. This means that this medium can also be included in the process of temperature change.
  • the interaction of the radiator with the material to be heated or cooled in the region of its resonance frequency with the molecular natural frequencies achieves a high degree of efficiency.
  • the coating material according to the invention with its large number of dipoles here contributes to providing an overall effective radiation system for electromagnetic waves with a high degree of radiation.
  • the substances are mixed in the individual process steps by means of mixing and / or kneading tools, for example screw mixers, roller mixers, centrifugal mixers which ensure particularly thorough mixing.
  • these mixers also comminute the added particles, in particular the particles of the insulating agent added in the second process step and the graphite particles added in the third process step.
  • These particles are therefore fine and, above all, evenly distributed in the coating material and form a multitude of smallest electrical dipoles for the generation of electromagnetic waves with a high degree of radiation. In this way, the coating material is simple and therefore inexpensive to produce.
  • sulfated castor oil is preferably used as the sulfated oil in the binder, which is particularly suitable because of its surface-active properties.
  • Carbonized phenols or benzisothiazolinones produced by cracking are preferably used as phenols in the binder.
  • an aromatic-based and / or alcohol-based and / or ester-based and / or ketone-based solvent is used as a diluent in the binder in the preferred production process.
  • an insulating carbon black is preferably used as the insulating agent, which is advantageously added in the ground state with a very small particle size.
  • an inorganic and / or organic, monomeric and / or polymeric substance is used as the dispersant, which facilitates the dispersion and thus the uniform distribution of the binder together with the particles of the insulating agent in the base substance.
  • a thixotropic agent is additionally mixed into the coating material. This thixotropic agent causes the coating material to be easily spreadable while it is being applied to a radiation surface, but is so tough when at rest that no drop formation can occur on the surface.
  • the coating material which can be spread after production is sprayed, brushed or knife-coated onto a beam. applied surface of a radiator and dried there.
  • the order amount is chosen so that a dry layer of z. B. 60 to 80 microns layer thickness.
  • An electromagnetic radiation can then be emitted with the radiator at a frequency which is in the order of magnitude of the molecular natural frequency of the material that can be introduced into the radiation region of the radiator for heating or cooling.
  • a preferred composition of the coating material is shown below using a specific example:
  • a binder is produced by mixing
  • a base substance is then produced in a second process step by mixing
  • a coating material is produced by mixing
  • This coating material was applied to a radiation surface of a radiator, air-dried and the radiator was then excited.
  • the electromagnetic radiation measured thereby had a high degree of radiation.
  • the individual components are mixed in a concrete process in a mixer with e.g. 2000 rpm mixed for 10 to 20 minutes.
  • the second process step e.g. 2000 revolutions / min mixed for 10 to 20 minutes, in addition to which pressures of 6 to 18 MPa can also be applied to the base substance, which cause the soot particles to be reduced to a particle size of less than 40 micrometers.
  • the substances are also used in e.g. 2000 revolutions / min mixed for 10 to 20 minutes, wherein additional interval-like pressures of the order of 6 to 18 MPa can be applied to the coating material, which result in shear forces which favor an elongated arrangement of the dipoles in the coating material.
  • the ultrasound dispersion technique can be used for the preferred dispersion of the individual components, which ensures a particularly fine distribution of the particles and thus the dipoles.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
  • Aerials With Secondary Devices (AREA)
  • Resistance Heating (AREA)
  • Adhesives Or Adhesive Processes (AREA)
PCT/EP1998/002329 1997-04-28 1998-04-21 Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung WO1998049242A1 (de)

Priority Applications (21)

Application Number Priority Date Filing Date Title
APAP/P/1999/001628A AP1066A (en) 1997-04-28 1998-04-21 Coating material for radiation surfaces to produce electromagnetic waves and a method for manufacturing said material.
PL98335577A PL188183B1 (pl) 1997-04-28 1998-04-21 Materiał powłokowy na powierzchnie promieniowaniadla wytwarzania fal elektromagnetycznych i sposóbwytwarzania tego materiału
SI9830251T SI0977816T1 (en) 1997-04-28 1998-04-21 Coating material for radiation surfaces to produce electromagnetic waves and a method for manufacturing said material
DK98920540T DK0977816T3 (da) 1997-04-28 1998-04-21 Coatingsmateriale til strålingsoverflader til opnåelse af elektromagnetiske bølger og fremgangsmåde til dets fremstilling
BR9808700-2A BR9808700C1 (pt) 1997-04-28 1998-04-21 Arranjo para aquecimento
EA199900677A EA002928B1 (ru) 1997-04-28 1998-04-21 Материал покрытия для излучающих поверхностей, вырабатывающих электромагнитные волны, и способ его получения
UA99095268A UA53694C2 (uk) 1997-04-28 1998-04-21 Матеріал покриття випромінювальних поверхонь для генерування електромагнітних хвиль та спосіб одержання такого матеріалу
EP98920540A EP0977816B1 (de) 1997-04-28 1998-04-21 Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung
US09/381,146 US6254922B1 (en) 1997-04-28 1998-04-21 Composition and method for coating radiation surfaces
NZ336934A NZ336934A (en) 1997-04-28 1998-04-21 A coating material for radiation surfaces to produce electromagnetic waves composed of a binding agent, insulating agent, dispersing agent, water and graphite
AU73359/98A AU721575B2 (en) 1997-04-28 1998-04-21 Coating material for radiation surfaces to produce electromagnetic waves and a method for manufacturing said material
DE59804898T DE59804898D1 (de) 1997-04-28 1998-04-21 Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung
KR10-1999-7007085A KR100533115B1 (ko) 1997-04-28 1998-04-21 전자파를 생성하기 위한 방사면의 코팅물 및 그 코팅물의 제조방법
IL13122498A IL131224A (en) 1997-04-28 1998-04-21 Expected material for projection surface for generating electromagnetic waves and method of forming it
CA002283769A CA2283769C (en) 1997-04-28 1998-04-21 Coating material for radiation surfaces to produce electromagnetic waves and a method for manufacturing said material
JP54655498A JP2001523282A (ja) 1997-04-28 1998-04-21 電磁波を発生する放射表面のための被覆材料とその製造方法
SK1261-99A SK126199A3 (en) 1997-04-28 1998-04-21 Coating material for radiation surfaces to produce electromagnetic waves and a method for manufacturing said material
AT98920540T ATE221107T1 (de) 1997-04-28 1998-04-21 Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung
IS5135A IS1909B (is) 1997-04-28 1999-07-27 Húðunarefni fyrir geislunaryfirborð til að mynda rafsegulbylgjur og aðferð til að framleiða nefnt efni
NO19994357A NO320568B1 (no) 1997-04-28 1999-09-08 Belegningsmateriale for stralingsflater for fremstilling av elektromagnetiske bolger, fremgangsmate for fremstilling av materialet og anvendelser derav
HK00104473A HK1025346A1 (en) 1997-04-28 2000-07-20 Coating material for radiation surfaces to produceelectromagnetic waves and a method for manufacturing said material.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19717682.8 1997-04-28
DE19717682A DE19717682A1 (de) 1997-04-28 1997-04-28 Beschichtungsmaterial für Strahlungsflächen zur Erzeugung elektromagnetischer Wellen und Verfahren zu dessen Herstellung

Publications (1)

Publication Number Publication Date
WO1998049242A1 true WO1998049242A1 (de) 1998-11-05

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PCT/EP1998/002329 WO1998049242A1 (de) 1997-04-28 1998-04-21 Beschichtungsmaterial für strahlungsflächen zur erzeugung elektromagnetischer wellen und verfahren zu dessen herstellung

Country Status (44)

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US (1) US6254922B1 (US06559137-20030506-C00047.png)
EP (1) EP0977816B1 (US06559137-20030506-C00047.png)
JP (1) JP2001523282A (US06559137-20030506-C00047.png)
KR (1) KR100533115B1 (US06559137-20030506-C00047.png)
CN (1) CN1147544C (US06559137-20030506-C00047.png)
AP (1) AP1066A (US06559137-20030506-C00047.png)
AR (1) AR015613A1 (US06559137-20030506-C00047.png)
AT (1) ATE221107T1 (US06559137-20030506-C00047.png)
AU (1) AU721575B2 (US06559137-20030506-C00047.png)
BG (1) BG64601B1 (US06559137-20030506-C00047.png)
BR (1) BR9808700C1 (US06559137-20030506-C00047.png)
CA (1) CA2283769C (US06559137-20030506-C00047.png)
CU (1) CU22670A3 (US06559137-20030506-C00047.png)
CZ (1) CZ296028B6 (US06559137-20030506-C00047.png)
DE (2) DE19717682A1 (US06559137-20030506-C00047.png)
DK (1) DK0977816T3 (US06559137-20030506-C00047.png)
DZ (1) DZ2484A1 (US06559137-20030506-C00047.png)
EA (1) EA002928B1 (US06559137-20030506-C00047.png)
EG (1) EG21613A (US06559137-20030506-C00047.png)
ES (1) ES2181214T3 (US06559137-20030506-C00047.png)
HK (1) HK1025346A1 (US06559137-20030506-C00047.png)
HR (1) HRP980223B1 (US06559137-20030506-C00047.png)
HU (1) HUP0002785A2 (US06559137-20030506-C00047.png)
ID (1) ID23652A (US06559137-20030506-C00047.png)
IL (1) IL131224A (US06559137-20030506-C00047.png)
IN (1) IN189871B (US06559137-20030506-C00047.png)
IS (1) IS1909B (US06559137-20030506-C00047.png)
JO (1) JO2020B1 (US06559137-20030506-C00047.png)
MA (1) MA25137A1 (US06559137-20030506-C00047.png)
MY (1) MY116736A (US06559137-20030506-C00047.png)
NO (1) NO320568B1 (US06559137-20030506-C00047.png)
NZ (1) NZ336934A (US06559137-20030506-C00047.png)
OA (1) OA11604A (US06559137-20030506-C00047.png)
PE (1) PE93499A1 (US06559137-20030506-C00047.png)
PL (1) PL188183B1 (US06559137-20030506-C00047.png)
PT (1) PT977816E (US06559137-20030506-C00047.png)
SK (1) SK126199A3 (US06559137-20030506-C00047.png)
TN (1) TNSN98054A1 (US06559137-20030506-C00047.png)
TR (1) TR199902618T2 (US06559137-20030506-C00047.png)
TW (1) TW347409B (US06559137-20030506-C00047.png)
UA (1) UA53694C2 (US06559137-20030506-C00047.png)
WO (1) WO1998049242A1 (US06559137-20030506-C00047.png)
YU (1) YU49258B (US06559137-20030506-C00047.png)
ZA (1) ZA983320B (US06559137-20030506-C00047.png)

Cited By (1)

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AU762925B2 (en) * 1999-06-28 2003-07-10 Rovi Guides, Inc. System and method for utilizing EPG database for modifying advertisements

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DE10038730A1 (de) * 2000-08-01 2002-02-28 Burd Lifror Systems Gmbh Verfahren zur Herstellung von elektrischen Heizelementen und deren Verwendung
EP1202384A1 (de) * 2000-10-31 2002-05-02 Molekulare Energietechnik AG Funkantenne als Sendeantenne oder Empfangsantenne und Mobilfunksystem
DE10117006A1 (de) * 2001-04-05 2002-10-10 Broers Dieter Schichtmaterial
US7783361B2 (en) * 2004-09-03 2010-08-24 Ct Investments Ltd. Radiant therapeutic heater
WO2010115173A1 (en) 2009-04-03 2010-10-07 Vorbeck Materials Corp Polymer compositions containing graphene sheets and graphite
DE102011122630B4 (de) 2011-12-22 2020-03-26 Claus Beyer Verfahren zur Herstellung eines Beschichtungsmaterials für Strahlungsflächen zur Erzeugung und/oder Abstrahlung von elektromagnetischen Wellen, insbesondere einer Wärmestrahlung, sowie Beschichtungsmaterial für Strahlungsflächen
CN107601606A (zh) * 2017-09-30 2018-01-19 江苏迈克化工机械有限公司 一种板式脱氨塔
DE202018100685U1 (de) 2018-02-08 2018-02-26 Suncoat Gmbh Elektrisch betreibbares Flächenheizelement

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US4186294A (en) * 1978-02-03 1980-01-29 Bender Joseph M Radiant therapeutic heater
DD208029A1 (de) * 1982-05-28 1984-03-21 Halle Wohnungsbau Strahlungsflaeche zur erzeugung elektromagnetischer wellen und verfahren zu deren herstellung
EP0262630A1 (de) * 1986-10-03 1988-04-06 BASF Aktiengesellschaft Verfahren zur Vernetzung von Kaseinfilmen in der Lederzurichtung
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