Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
  • A61Q19/10—Washing or bathing preparations
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
  • A61K8/04—Dispersions; Emulsions
  • A61K8/06—Emulsions
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
  • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
  • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
  • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
  • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/731—Cellulose; Quaternized cellulose derivatives
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/73—Polysaccharides
  • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
  • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
  • A61P17/00—Drugs for dermatological disorders
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/02—Preparations for cleaning the hair
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/54—Polymers characterized by specific structures/properties
  • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
  • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/54—Polymers characterized by specific structures/properties
  • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
  • A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/12—Preparations containing hair conditioners

Definitions

• the present invention relates personal cleansing compositions comprising a cleansing component together with a conditioning component.
• shampooing the hair cleans by removing excess soil and sebum.
• the shampooing process has disadvantages in that the hair is left in a wet, tangled and generally unmanageable state.
• Shampooing can also result in the hair becoming dry or "frizzy", and a loss of luster, due to removal of natural oils or other hair moisturizing materials.
• the hair can also suffer from a loss of "softness” perceived by the user upon drying.
• the hair can also suffer from increased levels of static upon drying after shampooing. This can interfere with combing and can result in fly-away hair.
• a variety of approaches have been developed to alleviate the after-shampoo problems.
• hair rinses are generally liquid in nature and must be applied in a separate step following the shampooing, left on the hair for a length of time, and rinsed with fresh water. This, of course, is time consuming and is not as convenient as shampoos containing both cleaning and hair conditioning ingredients.
• Cationic conditioning agents are highly desirable for use in hair conditioning due to their abilities to control static, improve wet detangling, and provide a silky wet hair feel to the user.
• One problem which has been encountered in shampoos relates to compatibility problems between good cleaning anionic surfactants and the many conventional cationic agents which historically have been used as conditioning agents. Efforts have been made to minimize adverse interaction through the use of alternate surfactants and improved cationic conditioning agents.
• Cationic surfactants which provide good overall conditioning in hair rinse products in general, tend to complex with anionic cleaning surfactants and provide poor conditioning in a shampoo context.
• soluble cationic surfactants that form soluble ionic complexes do not deposit well on the hair.
• Soluble cationic surfactants that form insoluble ionic complexes deposit on the hair but do not provide good hair conditioning benefits, and tend to cause the hair to have a dirty, coated feel.
• insoluble cationic surfactants e.g., tricetyl methyl ammonium chloride
• insoluble cationic surfactants e.g., tricetyl methyl ammonium chloride
• Many cationic polymers tend to build up on the hair, resulting in an undesirable, "unclean" coated feel.
• Cationic polymers therefore, conventionally, are preferably used at limited levels to minimize this problem. This, however, can limit the overall conditioning benefits that are obtained.
• cationic conditioning agents commonly do not provide optimal overall conditioning benefits, particularly in the area of "softness", especially when delivered as an ingredient in a shampoo composition.
• Nonionic silicones Silicones in shampoo compositions have been disclosed in a number of different publications. Such publications include U.S. Patent 2,826,551, Geen, issued March 11, 1958; U.S. Patent 3,964,500, Drakoff, issued June 22, 1976; U.S. Patent 4,364,837, Pader, issued December 21, 1982; and British Patent 849,433, Woolston, issued September 28, 1960. While these patents disclose silicone containing compositions, they also did not provide a totally satisfactory product in that it was difficult to maintain the silicone well dispersed and suspended in the product. Recently, stable, insoluble silicone-containing hair conditioning shampoo compositions have been described in U.S. Patent 4,741,855, Grote and Russell, issued May 3, 1988 and U.S. Patent 4,788,066, Bolich and Williams, issued November 29, 1988. These shampoo compositions can deliver excellent overall conditioning benefits to the hair while maintaining excellent cleaning performance, even with the use of anionic detersive surfactants, for a wide variety of hair types.
• HEI 1[1987]- 168612 Horie et al., discloses detergent compositions containing cationic surfactant and/or cationic polymer, anionic surfactant, and specific esters of the formula RCOOR' wherein R and R' are straight or branched chain alkyls.
• compositions combining certain nonionic or anionic polymers in combination with surfactants and a minimum level of a phase separation initiator form stable aqueous emulsions - wherein the emulsion comprises aqueous polymer phase droplets suspended in an aqueous surfactant phase.
• the dispersed, concentrated polymer phase provides improved hair and skin conditioning without sacrificing clean feel.
• These compositions can be made into any of a number of conventional forms including, but not limited to, conditioning shampoos, foams, mousses, gels, lotions, sprays and the like.
• nonionic or anionic polymer and surfactant system emulsion of the present invention is also useful for incorporation into a wide variety of personal skin cleansing compositions or used in conjunction with lathering instruments.
• These compositions provide a skin conditioning component which is more easily and uniformly deposited upon the skin and feel good upon the skin.
• Such compositions include liquid soaps, shower gels, lotions and the like.
• Suitable lathering instruments include nonwoven substrates, woven substrates, hydroentangled substrates, air entangled substrates, natural sponges, synthetic sponges, polymeric netted meshes, and the like. Accordingly, it is an object of this invention to provide personal cleansing compositions providing improved lathering and conditioning.
• Another object of the present invention is to provide improved personal cleansing compositions comprising a nonionic or anionic polymer, a surfactant system and a minimum amount of a phase separation initiator.
• One other object of the present invention is to provide personal cleaning compositions which exist as an emulsion comprising a polymer concentrated aqueous phase in an aqueous surfactant phase.
• Still another object of the present invention is to provide personal cleansing compositions which can comprise lower or reduced levels of surfactant.
• Another object of the present invention is to provide all in one shampoo plus conditioner compositions which can provide excellent cleaning performance and improved levels of conditioning while minimizing any adverse side effects associated with build-up due to the use of excess conditioning agent.
• the present invention relates to personal cleansing compositions in the form of a stable aqueous emulsion, comprising: a.) from about 4% to about 50%, by weight, of an aqueous surfactant system; b.) from above about 0.1 % to less than 1.0%, by weight, of a nonionic or anionic, water soluble polymer; c.) from about 0.1% to about 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof; and e.) from about 50% to about 95%, by weight, of water wherein said polymer forms visually distinct aqueous droplets in the aqueous surfactant system.
• the present invention further relates to methods of using the personal cleansing compositions.
• compositions of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well any of the additional or optional ingredients, components, or limitations described herein.
• phase separation means the formation of two thermodynamically stable liquid phases which exist, not as distinct bulk layers, but as a stable emulsion comprising droplets of one phase dispersed in another phase.
• visually distinct refers to droplets or droplet phases suspended in a continuous phase such that, optically, the droplets or droplet phases are visually separate and distinct from the continuous phase when viewed by the unaided eye.
• water soluble refers to any material that is sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentrations of 1.0% or more by weight of the material in the water at 25°C.
• water insoluble refers to all materials that are not sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of about 1.0% or more by weight of the insoluble material in water at 25°C.
• compositions of the present invention including the essential and optional components thereof, are described in detail hereinafter.
• compositions of the present invention comprise as an essential component a suitable surfactant system.
• the surfactant system of the present invention is preferably present in the personal cleansing compositions at a level of from about 4% to about 50%, more preferably from about 4% to about 40%. still more preferably from about 4% to about 30%, even more preferably from about 5% to about 20% and most preferably from about 6% to about 16%. It should be recognized , however, that the concentration of the surfactant system may vary with the cleaning or lather performance desired, the surfactants incorporated into the surfactant system, the desired product concentration, the presence of other components in the composition, and other factors well known in the art.
• the surfactant system of the present invention comprises primary detersive surfactants selected from the group consisting of anionic surfactants, amphoteric surfactants and mixtures thereof as well as additional detersive surfactants selected from the group consisting of nonionic surfactants, cationic surfactants or mixtures thereof.
• the purpose of the detersive surfactant is to provide cleaning performance to the composition.
• Amphoteric surfactant components useful in the present composition include those known to be usefiil in personal cleansing compositions, and which, preferably, contain a group that is anionic at the pH of the compositions of the present invention.
• the concentration of such surfactant components in the surfactant system of the present invention preferably ranges from about 0.5 % to about 20%, more preferably from about 1 % to about 10%, and most preferably from about 2% to about 7% by weight of the surfactant system.
• amphoteric surfactants suitable for use in the personal cleansing composition herein are described in U.S. Patents 5,104,646 (Bolich Jr. et al.), U.S. Patent 5,106,609 (Bolich
• amphoteric detersive surfactants which can be used in the compositions of the present invention are those which are broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water solubilizing group, e.g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
• Examples of compounds falling within this definition are sodium 3-dodecyl-aminopropionate, sodium 3- dodecylaminopropane sulfonate, sodium lauroamphoacetate, N-alkyltaurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of U.S. Patent 2,658,072, N-higher alkyl aspartic acids such as those produced according to the teaching of U.S. Patent 2,438,091, and the products sold
• MIRANOL under the trade name "MIRANOL" and described in U.S. Patent 2,528,378.
• amphoterics sometimes classified as zwitterionics, such as betaines can also be used in the present invention.
• Such zwitterionics are considered as amphoterics in the present invention where the zwitterionic has an attached group that is anionic at the pH of the composition.
• betaines useful herein include the high alkyl betaines, such as coco dimethyl carboxymethyl betaine, cocoamidopropyl betaine, cocobetaine. lauryl amidopropyl betaine, oleyl betaine, lauryl dimethyl carboxymethyl betaine.
• lauryl dimethyl alphacarboxyethyl betaine cetyl dimethyl carboxymethyl betaine, lauryl bis-(2-hydroxyethyl) carboxymethyl betaine, stearyl bis-(2-hydroxypropyl) carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alpha-carboxyethyl betaine.
• the sulfobetaines may be represented by coco dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxyethyl) sulfopropyl betaine and the like; amidobetaines and amidosulfobetaines, wherein the RCONH(CH ) radical is attached to the nitrogen atom of the betaine are also useful in this invention. Most preferred for use herein is cocoamidopropyl betaine.
• Suitable anionic surfactants include alkyl sulfate, alkyl ethoxylated sulfate, or a mixture thereof. These materials have the respective formulae (I) ROSO3M and (II) RO(C2H4O) x SO3M, wherein R is alkyl or alkenyl of from about 8 to about 30 carbon atoms, x is 1 to 10, and M is H or a salt-forming cation such as ammonium, alkanolamine containing C1-C3 alkyl groups such as triethanolamine, and monovalent and polyvalent metals such as the alkaline and alkaline earth metals. Preferred metals include sodium, potassium, magnesium, and calcium.
• the cation M, of the anionic surfactant should preferably be chosen such that the anionic surfactant component is water soluble. Solubility of anionic surfactants, in general, will depend upon the particular anionic surfactants and cations chosen. As an aid to determining appropriate mixtures of anionic surfactants, the anionic surfactants should be chosen such that the Krafft temperature is about 15°C or less, preferably about 10°C or less, more preferably about 0°C or less. It is also preferred that the anionic surfactant be soluble in the composition hereof.
• R has from about 10 to about 18 carbon atoms in both the alkyl and alkyl ethoxylated sulfates.
• the alkyl ethoxylated sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from about 8 to about 24 carbon atoms.
• the alcohols can be derived from fats, e.g., coconut oil, palm kernel oil, or tallow, or can be synthetic.
• Such alcohols are preferably reacted with about 1 to about 10, more preferably from about 1 to about 4, most preferably from about 2 to about 3.5, molar proportions of ethylene oxide and the resulting mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol, is sulfated and neutralized.
• alkyl ether sulfates which may be used in the present invention are sodium and ammonium salts of coconut alkyl triethylene glycol ether sulfate; tallow alkyl triethylene glycol ether sulfate, and tallow alkyl hexaoxyethylene sulfate.
• Highly preferred alkyl ether sulfates are those comprising a mixture of individual compounds, said mixture having an average alkyl chain length of from about 12 to about 16 carbon atoms and an average degree of ethoxylation of from about 1 to about 4 moles of ethylene oxide.
• the sulfate surfactant is preferably comprised of a combination of ethoxylated and nonethoxylated sulfates.
• Alkyl sulfates can provide excellent cleaning and lather performance.
• Alkyl ethoxylated sulfates can provide excellent cleaning performance and are mild to the skin.
• anionic detersive surfactants include, but are not limited to water-soluble salts of organic, sulfiiric acid reaction products of the general formula [R1-SO3-M] where R ⁇ is selected from the group consisting of a straight or branched chain, saturated aliphatic hydrocarbon radical having from about 8 to about 24, preferably about 10 to about 18, carbon atoms; and M is a cation such as ammonium, alkanolamines, such as triethanolamine, monovalent metals, such as sodium and potassium, and polyvalent metal cations, such as magnesium, and calcium.
• the cation M, of the anionic detersive surfactant should be chosen such that the detersive surfactant component is water soluble.
• Solubility will depend upon the particular anionic detersive surfactants and cations chosen.
• detersive surfactants are the salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, and n-paraffins, having about 8 to about 24 carbon atoms, preferably about 10 to about 18 carbon atoms and a sulfonating agent, e.g., SO3, H2SO4, obtained according to known sulfonation methods, including bleaching and hydrolysis.
• a sulfonating agent e.g., SO3, H2SO4
• anionic detersive surfactants suitable for use in the present invention are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide where, for example, the fatty acids are derived from coconut oil or palm kernal oil; sodium, ammonium, tetraethylammonium or potassium salts of fatty acid amides of methyl tauride in which the fatty acids, for example, are derived from coconut oil or palm kernal oil.
• Other similar anionic surfactants are described in U.S. Patent 2,486,921; U.S. Patent 2,486,922; and U.S. Patent 2,396,278, which descriptions are incorporated herein by reference.
• anionic detersive surfactants suitable for use in the present invention are the succinnates, examples of which include disodium N- octadecylsulfosuccinnate; disodium lauryl sulfosuccinate; diammonium lauryl sulfosuccinate; tetrasodium N-(l ,2-dicarboxyethyl)-N-octadecylsulfosuccinnate; diamyl ester of sodium sulfosuccinic acid; dihexyl ester of sodium sulfosuccinic acid; dioctyl esters of sodium sulfosuccinic acid.
• alkyl glyceryl ether sulfonate surfactants also referred to herein as an "AGS" surfactant
• AGS surfactants are derived from an alkyl glyceryl ether containing a sulfonate or sulfonate salt group.
• These compounds generally can be described as an alkyl monoether of glycerol that also contains a sulfonate group.
• AGS surfactants can be described as generally conforming to the following structures:
• R is a saturated or unsaturated straight chain, branched chain, or cyclic alkyl group having from about 10 to about 18 carbon atoms, preferably from about 11 to about 16 carbon atoms, and most preferably from about 12 to about 14 carbon atoms
• X is a cation selected from the group consisting of ammonium; mono- alkylsubstituted ammonium; di-alkylsubstituted ammonium; tri-alkylsubstituted ammonium; tetra-alkylsubstituted ammonium; alkali metal; alkaline metal; and mixtures thereof. More preferably, the alkyl radicals, R in the above formulas, are saturated and straight chain.
• alkyl chain lengths in the AGS surfactant has some effect on the character of the overall cleansing composition.
• a satisfactory distribution can be achieved in a commercially practicable way by using fatty alcohols derived from coconut oil and tallow.
• An equivalent distribution of alkyl chain lengths can be achieved using other starting materials.
• the middle cut of the coconut oil is taken. The higher boiling cut can be retained with the middle cut coconut oils if desired.
• a hydrogenation step is included to insure that they are substantially saturated.
• the preferred AGS compounds are those where the alkyl group is derived from at least about 50% from alcohols of about 10 to about 18 carbons, having mainly monoglyceryl radicals present, with less than about 30% of diglyceryl radicals present.
• the AGS used in the Examples described below contains about 15% of diglyceryl ether sulfonates, and is preferred because of the ease of manufacturing this material.
• the term "AGS" is intended to include monoglyceryl, diglyceryl, and traces of the higher glyceryl compounds. Small amounts, that is less than about 3% total, of triglyceryl ether sulfonates and tetraglyceryl ether sulfonates can be present. Also included are AGS's derived from glyceryl ethers having branched or mixed branched and straight chain lengths that emulate the straight chain lengths.
• olefin sulfonates having about 10 to about 24 carbon atoms.
• olefin sulfonates is used herein to mean compounds which can be produced by the sulfonation of alpha- olefins by means of uncomplexed sulfur trioxide, followed by neutralization of the acid reaction mixture in conditions such that any sulfones which have been formed in the reaction are hydrolyzed to give the corresponding hydroxy-alkanesulfonates.
• the sulfur trioxide can be liquid or gaseous, and is usually, but not necessarily, diluted by inert diluents, for example by liquid SO 2 , chlorinated hydrocarbons, etc., when used in the liquid form, or by air, nitrogen, gaseous SO 2 , etc., when used in the gaseous form.
• inert diluents for example by liquid SO 2 , chlorinated hydrocarbons, etc., when used in the liquid form, or by air, nitrogen, gaseous SO 2 , etc., when used in the gaseous form.
• the alpha-olefins from which the olefin sulfonates are derived are mono- olefins having about 10 to about 24 carbon atoms, preferably about 12 to about 16 carbon atoms. Preferably, they are straight chain olefins.
• the olefin sulfonates can contain minor amounts of other materials, such as alkene disulfonates depending upon the reaction conditions, proportion of reactants, the nature of the starting olefins and impurities in the olefin stock and side reactions during the sulfonation process.
• alpha-olefin sulfonate mixture of the above type is described more fully in the U.S. Patent 3,332,880. which description is incorporated herein by reference.
• Another class of anionic detersive surfactants suitable for use in the present invention are the beta-alkyloxy alkane sulfonates. These compounds have the following formula:
• R ⁇ is a straight chain alkyl group having from about 6 to about 20 carbon atoms
• R2 is a lower alkyl group preferably having from about 1 to about 3 carbon atoms
• M is a water-soluble cation as hereinbefore described.
• Preferred additional anionic detersive surfactants for use in the present invention include alkyl glyceryl ether sulfonate, ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl s
• the anionic detersive surfactants are preferably present in the surfactant system of the present invention at a concentration level of from about 3% to about 20%, more preferably from about 4% to about 17%, most preferably from about 6% to about 14%.
• fatty acid soaps Another class of anionic surfactants is fatty acid soaps. Though useful to the present invention, high concentrations of these surfactants in the presence of hard water tend to result in significant buildup on the hair and skin, adversely affecting cleansing and hair and skin feel. Accordingly, if added to the compositions of the present invention, the level of the fatty acid soaps is preferably incorporated at concentration levels of less than about 3%, more preferably less than about 1%.
• the surfactant system of the present invention may also include nonionic surfactants, cationic surfactants, and combinations thereof.
• Suitable classes of nonionic surfactants include: 1.
• the alkyl substituent in such compounds may be derived from polymerized propylene, diisobutylene, octane, or nonane, for example.
• Those derived from the condensation of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine products which may be varied in composition depending upon the balance between the hydrophobic and hydrophilic elements which is desired.
• compounds containing from about 40% to about 80%) polyoxyethylene by weight and having a molecular weight of from about 5,000 to about 11,000 resulting from the reaction of ethylene oxide groups with a hydrophobic base constituted of the reaction product of ethylene diamine and excess propylene oxide, said base having a molecular weight of the order of about 2,500 to about 3,000, are satisfactory.
• ethylene oxide e.g., a coconut alcohol ethylene oxide condensate having from about 10 to about 30 moles of ethylene oxide per mole of coconut alcohol, the coconut alcohol fraction having from about 10 to about 14 carbon atoms.
• R]R R3 N ⁇ 0 wherein R ⁇ contains an alkyl, alkenyl or monohydroxy alkyl radical of from about 8 to about 18 carbon atoms, from 0 to about 10 ethylene oxide moieties, and from 0 to about 1 glyceryl moiety, and R 2 and R3 contain from about 1 to about 3 carbon atoms and from 0 to about 1 hydroxy group, e.g., methyl, ethyl, propyl, hydroxyethyl, or hydroxypropyl radicals.
• the arrow in the formula is a conventional representation of a semipolar bond.
• amine oxides suitable for use in this invention include dimethyl-dodecylamine oxide, oleyldi(2- hydroxyethyl) amine oxide, dimethyloctylamine oxide, dimethyl- decylamine oxide, dimethyl-tetradecylamine oxide, 3,6,9- trioxaheptadecyldiethylamine oxide, di(2-hydroxyethyl)-tetradecylamine oxide, 2-dodecoxyethyldimethylamine oxide, 3-dodecoxy-2- hydroxypropyldi(3-hydroxypropyl) amine oxide, dimethylhexadecylamine oxide.
• R contains an alkyl, alkenyl or monohydroxyalkyl radical ranging from about 8 to about 18 carbon atoms in chain length, from 0 to about 10 ethylene oxide moieties and from 0 to about 1 glyceryl moiety and R' and R" are each alkyl or monohydroxyalkyl groups containing from about 1 to about 3 carbon atoms.
• the arrow in the formula is a conventional representation of a semipolar bond.
• phosphine oxides examples include: dodecyldimethylphosphine oxide, tetradecyldimethylphosphine oxide, tetradecylmethylethylphosphine oxide, 3,6,9,-trioxaoctadecyldimethylphosphine oxide, cetyldimethylphosphine oxide, 3-dodecoxy-2-hydroxypropyldi(2- hydroxyethyl) phosphine oxide, stearyldimethylphosphine oxide, cetylethylpropylphosphine oxide, oleyldiethylphosphine oxide, dodecyldiethylphosphine oxide, tetradecyldiethylphosphine oxide, dodecyldipropylphosphine oxide, dodecyldi(hydroxymethyl)phosphine oxide, dodecyldi(2-hydroxyethyl)phosphine oxide
• Examples include: octadecyl methyl sulfoxide, 2-ketotridecyl methyl sulfoxide, 3,6,9,-trixaoctadecyl 2-hydroxyethyl sulfoxide, dodecyl methyl sulfoxide, oleyl 3-hydroxypropyl sulfoxide, tetradecyl methyl sulfoxide, 3-methoxytridecyl methyl sulfoxide, 3- hydroxytridecyl methyl sulfoxide, 3-hydroxy-4-dodecoxybutyl methyl sulfoxide. 7. Polyalkylene oxide modified dimethylpolysiloxanes, also known as dimethicone copolyols. These materials include the polyalkylene oxide modified dimethylpolysiloxanes of the following formulae:
• R is hydrogen, an alkyl group having from 1 to about 12 carbon atoms, an alkoxy group having from 1 to about 6 carbon atoms or a hydroxyl group
• R' and R" are alkyl groups having from 1 to about 12 carbon atoms
• x is an integer of from 1 to 100, preferably from 20 to 30
• y is an integer of 1 to 20, preferably from 2 to 10
• a and b are integers of from 0 to 50, preferably from 20 to 30.
• dimethicone copolyols useful herein, include
• Rhodorsil 70646 Fluid manufactured by
• Cationic surfactants are also useful in compositions of the present invention and typically contain amino or quaternary ammonium hydrophilic moieties which are positively charged when dissolved in the aqueous composition of the present invention.
• Cationic surfactants among those useful herein are disclosed in the following documents, all incorporated by reference herein: M.C. Publishing Co.,
• the cationic surfactant must not interfere with the in-use performance and end-benefits of the personal cleansing composition.
• quaternary ammonium-containing cationic surfactant materials useful herein are those of the general formula:
• R1 -R4 are independently an aliphatic group of from about 1 to about 22 carbon atoms, or an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkylaryl group having from about 12 to about 22 carbon atoms; and X is an anion selected from halogen, acetate, phosphate, nitrate and alkylsulfate radicals.
• the aliphatic groups may contain, in addition to carbon and hydrogen atoms, ether linkages, and other groups such as amino groups.
• R ⁇ is an aliphatic group having from about 16 to about 22 carbon atoms
• R 2 , R3, R4, R5, and Rg are selected from hydrogen and alkyl having from about 1 to about 4 carbon atoms
• X is an ion selected from halogen, acetate, phosphate, nitrate and alkyl sulfate radicals.
• quaternary ammonium salts include tallow propane diammonium dichloride.
• Preferred quaternary ammonium salts include monoalkyltrimethylammonium chlorides and dialkyldimethylammonium chlorides and trialkyl methyl ammonium chlorides, wherein at least one of the alkyl groups have from about 12 to about 22 carbon atoms and are derived from long-chain fatty acids, such as hydrogenated tallow fatty acid (tallow fatty acids yield quaternary compounds wherein the long chain alkyl groups are predominately from 16 to 18 carbon atoms).
• Examples of quaternary ammonium salts useful in the present invention include stearyl trimethyl ammonium chloride, ditallowdimethv 1 ammonium chloride, ditallowdimethyl ammonium methyl sulfate, dihexadecv l dimethyl ammonium chloride, di(hydrogenated tallow) dimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride, dieicosyl dimethv l ammonium chloride, didocosyl dimethyl ammonium chloride, di(hydrogenated tallow) dimethyl ammonium acetate, dihexadecyl dimethyl ammonium chloride, dihexadecyl dimethyl ammonium acetate, ditallow dipropyl ammonium phosphate, ditallow dimethyl ammonium nitrate, di(coconutalkyl) dimethyl ammonium chloride, and stearyl dimethyl benzyl ammonium chloride, ditallow
• surfactants known in the art for use in hair or personal cleansing products may be used in the surfactant system of the present invention, provided that the surfactant is also chemically and physically compatible with the essential components of the present invention, or does not otherwise unduly impair product performance, aesthetics or stability.
• Preferred for use in the surfactant system of the present invention are anionic and/or amphoteric surfactants.
• nonionic or cationic surfactants tend to reduce the lathering properties of soap and shampoo compositions.
• nonionic or cationic surfactants are preferably present at low concentrations.
• the surfactant system of the present invention will contain less than 3%, more preferably less than 1% of the nonionic and cationic surfactant.
• nonionic or anionic water-soluble polymer is a nonionic or anionic water-soluble polymer.
• Suitable nonionic polymers include such water soluble polymers as cellulose ethers (e.g., . hydroxybutyl methylcellulose, hydroxypropylcellulose, hydroxypropyl methylcellulose, ethylhydroxy ethylcellulose and hydroxyethylcellulose), propylene glycol alginates, polyacrylamide, poly(ethylene oxide), polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl guar gum, locust bean gum, amylose, hydroxyethyl amylose, starch and starch derivatives and mixtures thereof.
• cellulose ethers e.g. hydroxybutyl methylcellulose, hydroxypropylcellulose, hydroxypropyl methylcellulose, ethylhydroxy ethylcellulose and hydroxyethylcellulose
• propylene glycol alginates e.g., .
• Preferred nonionic polymers include hydroxyethyl cellulose, polyethylene oxide, polyvinyl pyrrolidone, polyvinyl alcohol, polyacrylamide, hydroxypropyl cellulose, ethylhydroxyethyl cellulose, dextran, polypropyleneoxide and hydroxypropyl guar.
• Suitable anionic water-soluble polymers include carboxymethyl cellulose, carrageenan, xanthum gum polystyrene sulfonate, gum agar, gum ghatti, gum karaya, pectins, alginate salts, as well as poly(acrylic acid) and acrylic or methacrylic acid derivatives such as the alkali metal and ammonium salts of acrylic acid, methacrylic acid. Mixtures of the above anionic water-soluble polymers may also be used.
• polymeric compositions may be homopolymers or they may be copolymers or terpolymers with other copolymerizing monomers known in the art.
• copolymerizing monomers known in the art include but are not limited to ethylene, propylene, isobutylene, styrene, polystyrene, alphamethylstyrene, vinyl acetate, vinyl formate, alkyl ethers, acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, the alkyl acrylates, the alkylmethacrylates, the alkyl fumarates, the alkyl maleates, and other olefinic monomers copolymerizable therewith as long as the resulting polymers are water soluble and phase separate in the compositions of this invention.
• Copolymers of anionic and nonionic monomers such as acrylic acid and methacrylic acid with acrylamide, methacrylamide, the N-alkyl substituted amides, the N-aminoalkylamides, the corresponding N-alkylaminoalkyl substituted amides, the aminoalkyl acrylates, the aminoalkyl methacrylamides, and the N-alkyl substituted aminoalkyl esters of either acrylic or methacrylic acids.
• Preferred anionic polymers include polyacrylic acid; sodium carboxy methyl cellulose; polyacrylates; polymethyl acrylate; polysulphates such as polyvinyl sulfate, polystyrene sulfonate, polyphosphates, sodium dextran sulfate, alginate salts and pectate
• the water-soluble nonionic or anionic polymer separates to form aqueous droplets suspended in a continuous aqueous phase.
• the number average particle size of the polymer droplets can be from 0.1 microns to about 10,000 microns, preferably from about 1.0 micron to about 5000 microns, most preferably from about 5 microns to about 1000 microns.
• ethyl hydroxyethyl cellulose Most preferred for use in the present invention are ethyl hydroxyethyl cellulose, hydroxyethyl cellulose, hydroxypropyl guar and polystyrene sulfonate.
• the herein described polymers are preferably present at a concentration level of from above about 0.1% to below 1.0%, more preferably from about 0.15% to about 0.75%, most preferably from about 0.2% to about 0.5%.
• Phase Separation Initiators are preferably present at a concentration level of from above about 0.1% to below 1.0%, more preferably from about 0.15% to about 0.75%, most preferably from about 0.2% to about 0.5%.
• phase separation initiators means electrolytes, amphiphiles or mixtures thereof capable of inducing phase separation when combined with compositions comprising a surfactant system and a nonionic or anionic water-soluble polymer.
• amphiphile means, generally, substances which contain both hydrophilic and hydrophobic (lipophilic) groups.
• Amphiphiles preferred for use in the present invention are those which generally do not form micelles or liquid crystal phases and include, but are not limited to: amides of fatty acids; fatty alcohols; fatty esters, glycol mono- and di- esters of fatty acids; glyceryl esters.
• Amides including alkanol amides, are the condensation products of fatty acids with primary and secondary amines or alkanolamines to yield products of the general formula:
• RCO is a fatty acid radical and R is Cg. 2 o
• X is an alkyl, aromatic or alkanol (CHR'CH 2 OH wherein R' is H or C ⁇ . alkyl)
• Y is H, alkyl, alkanol or X.
• Suitable amides include, but are not limited to , cocamide, lauramide, oleamide and stearamide.
• Suitable alkanolamides include, but are not limited to, cocamide DEA, cocamide MEA, cocamide MIPA, isostearamide DEA, isostearamide MEA, isostearamide MIPA, lanolinamide DEA, lauramide DEA, lauramide MEA, lauramide MIPA, linoleamide DEA, linoleamide MEA, linoleamide MIPA, myristamide DEA, myristamide MEA, myristamide MIPA, Oleamide DEA,
• Oleamide MEA Oleamide MIPA
• palmamide DEA palmamide
• palmamide MEA palmamide
• the condensation reaction may be carried out with free fatty acids or with all types of esters of the fatty acids, such as fats and oils, and particularly methyl esters.
• the reaction conditions and the raw material sources determine the blend of materials in the end product and the nature of any impurities.
• Fatty alcohols are higher molecular weight, nonvolatile, primary alcohols having the general formula:
• RCH 2 OH wherein R is a Cg_ 2 o alkyl.
• They can be produced from natural fats and oils by reduction of the fatty acid COOH- grouping to the hydroxyl function.
• identical or similarly structured fatty alcohols can be produced according to conventional synthetic methods known in the art.
• Suitable fatty alcohols include, but are not limited to, behenyl alcohol, C9.1 1 alcohols, Cj2-13 alcohols, Cj2-15 alcohols, C ⁇ 2 _i6 alcohols, C14.
• caprylic alcohol cetearyl alcohol, coconut alcohol, decyl alcohol, isocetyl alcohol, isostearyl alcohol, lauryl alcohol, oleyl alcohol, palm kernel alcohol, stearyl alcohol, cetyl alcohol, tallow alcohol, tridecyl alcohol or myristyl alcohol.
• Glyceryl esters comprise a subgroup of esters which are primarily fatty acid mono- and di-glycerides or triglycerides modified by reaction with other alcohols and the like. Preferred glyceryl esters are mono and diglycerides.
• Suitable glyceryl esters and derivatives thereof include, but are not limited to, acetylated hydrogenated tallow glyceride, glyceryl behenate, glyceryl caprate, glyceryl caprylate, glyceryl caprylate/caprate, glyceryl dilaurate, glyceryl dioleate, glyceryl erucate, glyceryl hydroxystearate, glyceryl isostearate, glyceryl lanolate, glyceryl laurate, glyceryl linoleate, glyceryl oleate, glyceryl stearate, glyceryl myristate, glyceryl distearate and mixtures thereof,
• amphiphiles in the present invention are long chain glycol esters or mixtures thereof. Included are ethylene glycol esters of fatty acids having from about 8 to about 22 carbon atoms. Fatty esters of the formula RCO-OR' also act as suitable amphiphiles in the compositions of the present invention, where one of R and R' is a Cg_ 22 alkyl and the other is a C 1.3 alkyl.
• amphiphiles of the present invention may also encompass a variety of surface active compounds such as nonionic and cationic surfactants. If incorporated into the compositions of the present invention, these surface active compounds become additional surfactants used as amphilphiles for the purpose of initiating phase separation and are separate and apart from the surfactants of the surfactant system and the alkyl glyceryl sulfonate surfactant of the present invention.
• Amphiphiles preferred for use herein include cocamide MEA, cetyl alcohol and stearyl alcohol.
• amphiphiles of the present invention are preferably present in the personal cleansing compositions at levels of from 0 to about 4%. preferably from about 0.5%) to about 2%.
• Suitable electrolytes include mono-, di- and trivalent inorganic salts as well as organic salts. Surfactant salts themselves are not included in the present electrolyte definition but other salts are. Suitable salts include, but are not limited to, phosphates, sulfates, nitrates, citrates and halides. The counter ions of such salts can be, but are not limited to, sodium, potassium, ammonium, magnesium or other mono-, di and tri valent cation. Electrolytes most preferred for use in the compositions of the present invention include sodium chloride, ammonium chloride, sodium citrate, and magnesium sulfate.
• salts may serve as thickening aids or buffering aids in addition to their role as a phase separation initiator.
• the amount of the electrolyte used will generally depend on the amount of the amphiphile incorporated, but may be used at concentration levels of from about 0.1% to about 4%>, preferably from about 0.2% to about 2%.
• phase separation initiator comprising the electrolyte and/or the amphiphile will vary with the type of surfactant and polymer, but is generally present at a level of from about 0.1 % to about 5%, preferably from about 0.2% to about 3%.
• compositions of the present invention are, preferably, substantially free of materials which would prevent the induction or formation of separate, liquid phases.
• substantially free means that the compositions of the present invention contain no more than about 0.5% of such materials, preferably less than 0.25%, more preferably zero.
• Such materials typically include ethylene glycol, propylene glycol, ethyl alcohol and the like.
• compositions of the present invention are also preferably substantially free of other ingredients which unduly minimize the formation of separate and distinct liquid phases, especially ingredients which do not provide a significant benefit to the present invention.
• the personal cleansing compositions of the present invention comprise from about 50%) to about 95%), preferably from about 60%) to about 90%, more preferably from about 15% to about 85%), by weight of water.
• compositions of the present invention may optionally include nonvolatile silicone conditioning components.
• silicone components are intermixed into aqueous personal cleansing compositions, forming a separate, discontinuous silicone phase.
• the silicone conditioning component will comprise a silicone fluid conditioning agent such as a silicone fluid and can also comprise other ingredients, such as a silicone resin to enhance silicone fluid deposition efficiency or enhance glossiness of the hair (especially when high refractive index (e.g. above about 1.46) silicone conditioning agents are used (e.g. highly phenylated silicones).
• nonvolatile refers to silicone material with little or no significant vapor pressure under ambient conditions, as is understood by those in the art. Boiling point under one atmosphere (atm) will preferably be at least about 250° C, more preferably at least about 275°C, most preferably at least about 300°C. Vapor pressure is preferably about 0.2mm Hg at 25°C or less, preferably about 0.1mm Hg at 25°C or less.
• the silicone conditioning agent phase may comprise volatile silicone, nonvolatile silicone, or mixtures thereof. Typically, if volatile silicones are present, it will be incidental to their use as a solvent or carrier for commercially available forms of nonvolatile silicone materials ingredients, such as silicone gums and resins.
• the silicone conditioning agents for use in the compositions of the present invention preferably have a viscosity of from about 20 to about 2,000,000 centistokes, more preferably from about 1,000 to about 1,800,000 centistokes, even more preferably from about 10,000 to about 1,500,000 centistokes, most preferably from about 30,000 to about 1,000,000 centistokes, at 25°C.
• the viscosity can be measured by means of a glass capillary viscometer as set forth in Dow Corning Corporate Test Method CTM0004, July 20, 1970.
• Optional silicone fluid for use in the present compositions include ⁇ " "> oils which are flowable silicone materials with a viscosity of less than 1 ,000,000 centistokes, preferably between about 5 and 1 ,000,000 centistokes, more preferably between about 10 and about 600,000 centistokes, more preferably between about 10 and about 500,000 centistokes, most preferably between 10 and 300,000 centistokes at 25°C.
• Suitable silicone oils include polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and mixtures thereof. Other insoluble, nonvolatile silicone fluids having conditioning properties can also be used.
• Optional Silicone oils for use in the composition include polyalkyl or polyaryl siloxanes which conform to following formula:
• R is aliphatic, preferably alkyl or alkenyl, or aryl
• R can be substituted or unsubstituted
• x is an integer from 1 to about 8,000.
• Suitable unsubstituted R groups include alkoxy, aryloxy, alkaryl, arylalkyl, arylalkenyl, alkamino, and ether- substituted, hydroxyl-substituted, and halogen-substituted aliphatic and aryl groups.
• Suitable R groups also include cationic amines and quaternary ammonium groups.
• the aliphatic or aryl groups substituted on the siloxane chain may have any structure as long as the resulting silicones remain fluid at room temperature, are hydrophobic, are neither irritating, toxic nor otherwise harmful when applied to the hair or skin, are compatible with the other components of the herein described personal cleansing compositions, are chemically stable under normal use and storage conditions, are insoluble in the compositions of the present invention, and are capable of being deposited on and, of conditioning, the hair and skin.
• the two R groups on the silicon atom of each monomeric silicone unit may represent the same group or different groups.
• the two R groups represent the same group.
• Preferred alkyl and alkenyl substituents are C1-C5 alkyls and alkenyls, more preferably from C1-C4, most preferably from C ⁇ -C 2 .
• the aliphatic portions of other alkyl-, alkenyl-, or alkynyl-containing groups can be straight or branched chains and preferably have from one to five carbon atoms, more preferably from one to four carbon atoms, even more preferably from one to three carbon atoms, most preferably from one to two carbon atoms.
• the R substituents hereof can also contain amino functionalities, e.g.
• alkamino groups which can be primary, secondary or tertiary amines or quaternary ammonium. These include mono-, di- and tri- alkylamino and alkoxyamino groups wherein the aliphatic portion chain length is preferably as described above.
• the R substituents can also be substituted with other groups, such as halogens (e.g. chloride, fluoride, and bromide), halogenated aliphatic or aryl groups, and hydroxy (e.g. hydroxy substituted aliphatic groups).
• Suitable halogenated R groups could include, for example, tri-halogenated (preferably fluoro) alkyl groups such as -R ⁇ -C(F)3, wherein R ⁇ is C1-C3 alkyl.
• tri-halogenated (preferably fluoro) alkyl groups such as -R ⁇ -C(F)3, wherein R ⁇ is C1-C3 alkyl.
• polysiloxanes include polymethyl -3,3,3 trifluoropropylsiloxane.
• Suitable R groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl.
• the preferred silicones are polydimethyl siloxane, polydiethylsilox- ane, and polymethylphenylsiloxane. Polydimethylsiloxane is especially preferred.
• Other suitable R groups include methyl, methoxy, ethoxy, propoxy, and aryloxy.
• the three R groups on the end caps of the silicone may also represent the same or different groups.
• the nonvolatile polyalkylsiloxane fluids that may be used include, for example, polydimethylsiloxanes. These siloxanes are available, for example, from the Ge .eral El ⁇ ctric Company in their Viscasil R and SF 96 series, and from Dow Corning in their Dow Corning 200 series.
• the polyalkylaryl siloxane fluids that may be used also include, for example, polymethylphenylsiloxanes. These siloxanes are available, for example, from the General Electric Company as SF 1075 methyl phenyl fluid or from Dow Corning as 556 Cosmetic Grade Fluid.
• the polyether siloxane copolymers that may be used include, for example, a polypropylene oxide modified polydimethylsiloxane (e.g., Dow Corning DC- 1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide may also be used. The ethylene oxide and polypropylene oxide level must be sufficiently low to prevent solubility in water and the composition hereof.
• silicone fluids for use in the silicone conditioning agents are insoluble silicone gums. These gums are polyorganosiloxane materials having a viscosity at 25°C of greater than or equal to 1,000,000 centistokes. Silicone gums are described in U.S. Patent 4,152,416; Noll and Walter, Chemistry and Technology of Silicones. New York: Academic Press 1968; and in General Electric Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76, all of which are incorporated herein by reference.
• the silicone gums will typically have a mass molecular weight in excess of about 200,000, generally between about 200,000 and about 1,000,000, specific examples of which include polydimethylsiloxane, (polydimethylsiloxane) (methylvinylsiloxane) copolymer, poly(dimethylsiloxane) (diphenyl siloxane)(methylvinylsiloxane) copolymer and mixtures thereof.
• the silicone conditioning agent can also comprise a mixture of polydimethylsiloxane gum (viscosity greater than about 1,000,000 centistokes) and polydimethylsiloxane oil (viscosity from about 10 to about 100,000 centistokes), wherein the ratio of gum to fluid is from about 30:70 to about 70:30, preferably from about 40:60 to about 60:40.
• Silicone resins can be included in the silicone conditioning agent. These resins are highly crosslinked polymeric siloxane systems. The crosslinking is introduced through the incorporation of trifunctional and tetrafunctional silanes with monofunctional or difunctional, or both, silanes during manufacture of the silicone resin. As is well understood in the art, the degree of crosslinking that is required in order to result in a silicone resin will vary according to the specific silane units incorporated into the silicone resin. In general, silicone materials which have a sufficient level of trifunctional and tetrafunctional siloxane monomer units (and hence, a sufficient level of crosslinking) such that they dry down to a rigid, or hard, film are considered to be silicone resins.
• the ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a particular silicone material.
• Silicone materials which have at least about 1.1 oxygen atoms per silicon atom will generally be silicone resins herein.
• the ratio of oxygemsilicon atoms is at least about 1.2:1.0.
• Silanes used in the manufacture of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl-, and methylvinyl-chlorosilanes, and tetrachlorosilane, with the methyl-substituted silanes being most commonly utilized.
• Preferred resins are offered by General Electric as GE SS4230 and SS4267.
• Commercially available silicone resins will generally be supplied in a dissolved form in a low viscosity volatile or nonvolatile silicone fluid.
• the silicone resins for use herein should be supplied and incorporated into the present compositions in such dissolved form, as will be readily apparent to those skilled in the art.
• Silicone materials and silicone resins in particular, can conveniently be identified according to a shorthand nomenclature system well known to those skilled in the art as "MDTQ" nomenclature. Under this system, the silicone is described according to presence of various siloxane monomer units which make up the silicone. Briefly, the symbol M denotes the monoftinctional unit (CEF ⁇ SiO 5; D denotes the difunctional unit (CH3) 2 SiO; T denotes the trifunctional unit (CH3)SiOj 5; and Q denotes the quadri- or tetra-ftmctional unit SiO 2 .
• MDTQ monoftinctional unit
• Primes of the unit symbols denote substituents other than methyl, and must be specifically defined for each occurrence. Typical alternate substituents include groups such as vinyl, phenyls, amines, hydroxyls, etc.
• the molar ratios of the various units either in terms of subscripts to the symbols indicating the total number of each type of unit in the silicone (or an average thereof) or as specifically indicated ratios in combination with molecular weight complete the description of the silicone material under the MDTQ system. Higher relative molar amounts of T, Q, T' and/or Q' to D, D', M and/or M' in a silicone resin is indicative of higher levels of crosslinking. As discussed before, however, the overall level of crosslinking can also be indicated by the oxygen to silicon ratio.
• the silicone resins for use herein which are preferred are MQ, MT, MTQ, MDT and MDTQ resins.
• the preferred silicone substituent is methyl.
• MQ resins wherein the M:Q ratio is from about 0.5:1.0 to about 1.5:1.0 and the average molecular weight of the resin is from about 1000 to about 10,000.
• the weight ratio of the nonvolatile silicone fluid, having refractive index below 1.46, to the silicone resin component, when used, is preferably from about 4:1 to about 400:1, preferably this ratio is from about 9:1 to about 200:1, more preferably from about 19:1 to about 100:1, particularly when the silicone fluid component is a polydimethylsiloxane fluid or a mixture of polydimethylsiloxane fluid and polydimethylsiloxane gum as described above.
• the silicone resin forms a part of the same phase in the compositions hereof as the silicone fluid, i.e. the conditioning active, the sum of the fluid and resin should be included in determining the level of silicone conditioning agent in the composition.
• the number average particle size of the optional silicone component can vary widely depending on the formulation and/or the desired characteristics. Number average particle sizes preferred for use in the present invention range from about 10 nanometers to about 100 microns, more preferably from about 30 nanometers to about 20 microns.
• Other Optional Components are also included in the present invention.
• the personal cleansing compositions of the present invention may further comprise one or more optional components known for use in shampoo, conditioning and other personal cleansing compositions, provided that the optional components are physically and chemically compatible with the essential component described herein, or do not otherwise unduly impair product stability, aesthetics or performance. Concentrations of such optional components typically range from about 0.001%) to about 30% by weight of the personal cleansing compositions.
• Optional components include anti static agents, cationic conditioning polymers such as polyquaterinum-10, dyes, organic solvents or diluents, emollient oils (such as polyisobutylene, mineral oil, petrolatum and isocetyl stearyl stearate), pearlescent aids, foam boosters, pediculocides, pH adjusting agents, perfumes, preservatives, proteins, antioxidants; chelators and sequestrants; and aesthetic components such as fragrances, colorings, essential oils, skin sensates, astringents, skin soothing agents, skin healing agents and the like, nonlimiting examples of these aesthetic components include panthenol and derivatives (e.g.
• pantothenic acid and its derivatives clove oil, menthol, camphor, eucalyptus oil, eugenol, menthyl lactate, witch hazel distillate, allantoin, bisabalol, dipotassium glycyrrhizinate and the like, suspending agents, styling polymers, sunscreens, thickeners, vitamins and derivatives thereof (e.g., ascorbic acid, vitamin E, tocopheryl acetate, retinoic acid, retinol. retinoids, and the like), and viscosity adjusting agents.
• This list of optional components is not meant to be exclusive, and other optional components can be used.
• compositions of the present invention in general, can be made by mixing together at elevated temperature, e.g., about 72°C water and surfactants along with any solids (e.g., amphiphiles) that need to be melted, to speed mixing into the personal cleansing composition. Additional ingredients including the electrolytes can be added either to this hot premix or after cooling the premix.
• the nonionic or anionic polymers can be added as a water solution after cooling the premix.
• the ingredients are mixed thoroughly at the elevated temperature and then pumped through a high shear mill and then through a heat exchanger to cool them to ambient temperature.
• the silicone may be emulsified at room temperature in concentrated surfactant and then added to the cooled product.
• the silicone conditioning agent can be mixed with anionic surfactant and fatty alcohol, such as cetyl and stearyl alcohols, at elevated temperature, to form a premix containing dispersed silicone.
• the premix can then be added to and mixed with the remaining materials of the personal cleansing composition, pumped through a high shear mill, and cooled.
• the personal cleansing compositions of the present invention are used in a conventional manner for cleansing and conditioning hair or skin.
• An effective amount of the composition for cleansing and conditioning the hair or skin is applied to the hair or skin, that has preferably been wetted with water, and then rinsed off.
• Such effective amounts generally range from about lg to about 50g, preferably from about lg to about 20g.
• Application to the hair typically includes working the composition through the hair such that most or all of the hair is contacted with the composition.
• This method for cleansing and conditioning the hair and skin comprises the steps of: a) wetting the hair and/or skin with water, b) applying an effective amount of the personal cleansing composition to the hair and or skin, and c) rinsing the composition from the hair and or skin using water. These steps can be repeated as many times as desired to achieve the desired cleansing and conditioning benefit.
• Examples I-X illustrate specific embodiments of the personal cleansing compositions of the present invention, but are not intended to be limiting thereof. Other modifications can be undertaken by the skilled artisan without departing from the spirit and scope of this invention. These exemplified embodiments of the personal cleansing compositions of the present invention provide cleansing of hair and/or skin and improved conditioning.
• compositions can be prepared by conventional formulation and mixing techniques.
• Component amounts are listed as weight percents and exclude minor materials such as diluents, filler, and so forth.
• the listed formulations therefore, comprise the listed components and any minor materials associated with such components.

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